CN107158879A - The adjustable activated carbon adsorption/desorption complexes of Wet-dry - Google Patents

The adjustable activated carbon adsorption/desorption complexes of Wet-dry Download PDF

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Publication number
CN107158879A
CN107158879A CN201710409055.1A CN201710409055A CN107158879A CN 107158879 A CN107158879 A CN 107158879A CN 201710409055 A CN201710409055 A CN 201710409055A CN 107158879 A CN107158879 A CN 107158879A
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China
Prior art keywords
heat exchanger
desorption
nitrogen
activated carbon
wet
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CN201710409055.1A
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Chinese (zh)
Inventor
毛寅茨
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Zhangjiagang Eyre Environmental Protection Engineering Co Ltd
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Zhangjiagang Eyre Environmental Protection Engineering Co Ltd
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Priority to CN201710409055.1A priority Critical patent/CN107158879A/en
Publication of CN107158879A publication Critical patent/CN107158879A/en
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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/02Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography
    • B01D53/04Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography with stationary adsorbents
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2253/00Adsorbents used in seperation treatment of gases and vapours
    • B01D2253/10Inorganic adsorbents
    • B01D2253/102Carbon
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2259/00Type of treatment
    • B01D2259/40Further details for adsorption processes and devices
    • B01D2259/40083Regeneration of adsorbents in processes other than pressure or temperature swing adsorption
    • B01D2259/40086Regeneration of adsorbents in processes other than pressure or temperature swing adsorption by using a purge gas

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Analytical Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Treating Waste Gases (AREA)

Abstract

This application discloses a kind of adjustable activated carbon adsorption/desorption complexes of Wet-dry.The adjustable activated carbon adsorption/desorption complexes of the Wet-dry, including adsorbent equipment, desorption apparatus, control device and some pipelines and valve, the adsorbent equipment includes pneumatic filter, adsorption tanks, main fan and aiutage, the adsorption tanks are provided with exhaust gas inlet, waste gas outlet, nitrogen inlet and nitrogen outlet, the pneumatic filter outlet is connected to exhaust gas inlet by pipeline, the aiutage import is connected to waste gas outlet by pipeline, the main fan is connected between aiutage and waste gas outlet, the nitrogen inlet and nitrogen outlet are connected to desorption apparatus, the desorption apparatus not only can be desorbed but also can be desorbed with steam with nitrogen, each segment pipe is respectively equipped with valve, the valve passes through the control device centralized Control.The adjustable activated carbon adsorption/desorption complexes of the Wet-dry are used using steam and nitrogen as desorption medium.

Description

The adjustable activated carbon adsorption/desorption complexes of Wet-dry
Technical field
The application is related to exhaust-gas treatment field, and more particularly to a kind of adjustable activated carbon adsorption/desorption of Wet-dry is into suit Put.
Background technology
Activated carbon has preferable specific surface area and very strong absorption, decolourized and the performance that eliminates the unusual smell, therefore usually by conduct The adsorbing medium of circulating purification system, to absorb poisonous, the polluter in waste gas, waste water, activated carbon can be with after desorption It is used for multiple times, is adsorbed and two processes of desorption so existing, adsorption process is as follows:Waste gas removes small outstanding by air cleaner After floating particles, into the top of adsorption tanks, after charcoal absorption in tank, harmful components are removed, meet the net of discharge standard Change gas, be discharged into through blower fan in air;Desorption and regeneration process is as follows:After activated carbon has used a period of time, its surface is inhaled Attached a certain amount of solvent (use time length, depending on the content of body weight and production time length) is, it is necessary to be desorbed Regeneration, existing desorption apparatus is generally simple dry method desorption or wet method desorption, when desorption apparatus breaks down, do not have it is standby can Choosing, can only stop being desorbed work.So needing to propose to improve.
The content of the invention
It is existing to overcome it is an object of the invention to provide a kind of adjustable activated carbon adsorption/desorption complexes of Wet-dry There is the deficiency in technology.
To achieve the above object, the present invention provides following technical scheme:
The embodiment of the present application discloses a kind of adjustable activated carbon adsorption/desorption complexes of Wet-dry,
Including adsorbent equipment, desorption apparatus, control device and some pipelines and valve, the adsorbent equipment includes gas mistake Filter, adsorption tanks, main fan and aiutage, the adsorption tanks go out provided with exhaust gas inlet, waste gas outlet, nitrogen inlet and nitrogen Mouthful, the pneumatic filter outlet is connected to exhaust gas inlet by pipeline, and the aiutage import is connected to waste gas by pipeline Outlet, the main fan is connected between aiutage and waste gas outlet, and the nitrogen inlet and nitrogen outlet are connected to Desorption apparatus;
The desorption apparatus includes displacement blower fan, circulating fan, First Heat Exchanger, the second heat exchanger, the 3rd heat exchanger, the Four heat exchangers, drainer, condenser pump, incinerator, nitrogen device and steam unit, the displacement blower fan two ends pass through pipeline respectively The gaseous phase outlet of nitrogen inlet and drainer is connected to, the liquid-phase outlet of the drainer is connected to the burning by pipeline Stove, the condenser pump is arranged between the drainer and incinerator, and the circulating fan two ends are connected to by pipeline respectively Nitrogen outlet and First Heat Exchanger import, the nitrogen device and the 4th heat exchanger import are parallel to the circulated air by pipeline Between machine and First Heat Exchanger, the outlet of the First Heat Exchanger and the 4th heat exchanger is connected to nitrogen by pipeline respectively and entered Mouthful, the second heat exchanger import is connected to waste gas outlet by pipeline, and second heat exchanger exit is connected to by pipeline 3rd heat exchanger import, the 3rd heat exchanger exit is connected to drainer gas phase import, second heat exchanger, the 3rd heat exchange Device and the 4th heat exchanger are by the use of external source as heat transferring medium, and the steam unit is connected to suction by First Heat Exchanger Attached tank and steam unit;
Each segment pipe is respectively equipped with valve, and the valve passes through the control device centralized Control.
It is preferred that, in the above-mentioned adjustable activated carbon adsorption/desorption complexes of Wet-dry, in the adsorption tanks Adsorbent is activated carbon.
It is preferred that, in the above-mentioned adjustable activated carbon adsorption/desorption complexes of Wet-dry, at the main fan In explosion-proof closed environment.
It is preferred that, in the above-mentioned adjustable activated carbon adsorption/desorption complexes of Wet-dry, the nitrogen outlet connects It is connected to containing oxygen detection.
It is preferred that, in the above-mentioned adjustable activated carbon adsorption/desorption complexes of Wet-dry, pass through the test number According to also including some Shower taps in the adsorption tanks.
It is preferred that, in the above-mentioned adjustable activated carbon adsorption/desorption complexes of Wet-dry, the locomotive is provided with Camera, the Shower tap is connected to fire water supply and industrial water source simultaneously.
It is preferred that, in the above-mentioned adjustable activated carbon adsorption/desorption complexes of Wet-dry, the First Heat Exchanger From the adjustable heat exchanger of temperature.
Compared with prior art, the advantage of the invention is that:The adjustable activated carbon adsorption/desorption of the Wet-dry is into suit Putting realizes the high efficiency desorption parsing after charcoal absorption.Steam and two kinds of desorption mediums of nitrogen are mutually standby, and system can It is stronger by property stability, meanwhile, designed by the use of industrial water source and fire water supply as the spray of double-safety, it can be ensured that system Safety is perfectly safe, and not only treatment effeciency is high for this device, the organic substance that can efficiently go in removing exhaust gas, and the effect of the device is not only National waste gas emission standard can be reached and operation and maintenance cost is low, security highest.
Brief description of the drawings
, below will be to embodiment or existing in order to illustrate more clearly of the embodiment of the present application or technical scheme of the prior art There is the accompanying drawing used required in technology description to be briefly described, it should be apparent that, drawings in the following description are only this Some embodiments described in application, for those of ordinary skill in the art, on the premise of not paying creative work, Other accompanying drawings can also be obtained according to these accompanying drawings.
Fig. 1 show the operation principle schematic diagram of desorption apparatus in the specific embodiment of the invention.
Fig. 2 show the operation principle schematic diagram that adsorption device is adsorbed in the specific embodiment of the invention.
Embodiment
Below in conjunction with the accompanying drawing in the embodiment of the present invention, detailed retouch is carried out to the technical scheme in the embodiment of the present invention State, it is clear that described embodiment is only a part of embodiment of the invention, rather than whole embodiments.Based on the present invention In embodiment, the every other implementation that those of ordinary skill in the art are obtained on the premise of creative work is not made Example, belongs to the scope of protection of the invention.
Join shown in Fig. 1 and Fig. 2, the adjustable activated carbon adsorption/desorption complexes of Wet-dry in the present embodiment, including Adsorbent equipment 1000, desorption apparatus 2000, control device (being not drawn into figure) and some pipelines (non-label in figure) and valve (figure In non-label), the adsorbent equipment 1000 include pneumatic filter 1010, adsorption tanks 1020, main fan 1030 and aiutage 1040, adsorption tanks 1020 are provided with exhaust gas inlet 1021, waste gas outlet 1022, nitrogen inlet 1023 and nitrogen outlet 1024, gas The outlet of filter 1010 is connected to exhaust gas inlet 1021 by pipeline, and the import of aiutage 1040 is connected to waste gas outlet by pipeline 1022, main fan 1030 is connected between aiutage 1040 and waste gas outlet 1022, nitrogen inlet 1023 and nitrogen outlet 1024 are connected to desorption apparatus 2000;
The desorption apparatus 2000 includes displacement blower fan 2010, circulating fan 2020, First Heat Exchanger 2030, second and exchanged heat Device 2040, the 3rd heat exchanger 2050, the 4th heat exchanger 2060, drainer 2070, condenser pump 2080, incinerator 2090, nitrogen dress 2100 and steam unit 2110 are put, displacement blower fan 2010 two ends are connected to nitrogen inlet 1023 and drainer by pipeline respectively 2070 gaseous phase outlet, the liquid-phase outlet of drainer 2070 is connected to incinerator 2090 by pipeline, and condenser pump 2080 is arranged at Between drainer 2070 and incinerator 2090, the two ends of circulating fan 2020 are connected to nitrogen outlet 1024 and by pipeline respectively The import of one heat exchanger 2030, nitrogen device 2100 and the import of the 4th heat exchanger 2060 are parallel to the He of circulating fan 2020 by pipeline Between First Heat Exchanger 2030, the outlet of the heat exchanger 2060 of First Heat Exchanger 2030 and the 4th is connected to nitrogen by pipeline respectively Import 1023, the import of the second heat exchanger 2040 is connected to waste gas outlet 1022 by pipeline, and the outlet of the second heat exchanger 2040 passes through Pipeline is connected to the import of the 3rd heat exchanger 2050, and the outlet of the 3rd heat exchanger 2050 is connected to the gas phase import of drainer 2070, second Heat exchanger 2040, the 3rd heat exchanger 2050 and the 4th heat exchanger 2060 are used as heat transferring medium, steam unit by the use of external source 2110 are connected to adsorption tanks 1020 and steam unit 2110 by First Heat Exchanger 2030;
Each segment pipe is respectively equipped with valve, and valve passes through control device centralized Control.
In the technical scheme, how control device controls a valve to belong to prior art, does not just repeat one by one, the dry and wet two The high efficiency desorption parsing after charcoal absorption is realized with adjustable activated carbon adsorption/desorption complexes.Steam and nitrogen Two kinds of desorption mediums are mutually standby, and system reliability stability is stronger, meanwhile, protected by the use of industrial water source and fire water supply as double The spray design of dangerous formula, it can be ensured that system is perfectly safe safely, not only treatment effeciency is high for this device, can efficiently go in removing exhaust gas Organic substance, the effect of the device can not only reach national waste gas emission standard and operation and maintenance cost is low, and security is most It is high.
Further, the adsorbent in adsorption tanks 1020 is activated carbon.
In the technical scheme, adsorbent in adsorption tanks 1020 is that can enter after activated carbon, charcoal absorption harmful substance Row desorption, i.e., activated carbon can be utilized repeatedly, save the energy.
Further, main fan 1030 is in explosion-proof closed environment.
In the technical scheme, main fan 1030 is in explosion-proof closed environment, and main fan 1030 is directly contacted with waste gas.
Further, nitrogen outlet is connected with containing oxygen detection 1050.
In the technical scheme, nitrogen outlet is connected with containing oxygen detection 1050, useless in using nitrogen displacement adsorption tanks During gas, by carrying out on-line checking containing oxygen detection, it is ensured that waste gas is completely displaced in adsorption tanks.
Further, some Shower taps 1025 are also included in adsorption tanks 1020.
In the technical scheme, some Shower taps 1025 are also included in adsorption tanks 1020, when occurring unexpected fire accidents, Can directly it be put out a fire in the very first time, it is to avoid fire expands.
Further, Shower tap 1025 is connected to fire water supply 5000 and industrial water source 6000 simultaneously.
In the technical scheme, Shower tap is connected to fire water supply 5000 and industrial water source 6000, fire water supply simultaneously 5000 design with industrial water source 6000 as the spray of double-safety, it can be ensured that perfectly safe safely during fire extinguishing.
Further, First Heat Exchanger 2030 selects the adjustable heat exchanger of temperature.
In the technical scheme, First Heat Exchanger selects the adjustable heat exchanger of temperature, according to the different waste gas of processing, can adjust The different temperature of section, accelerates the efficiency of desorption.
Adsorption process:Waste gas is after the pretreatment of pneumatic filter 1010, and adsorption tanks 1020 are in explosion-proof closed main ventilation The lower negative pressure operation of the effect of machine 1030, activated carbon trapping that organic solvent is adsorbed in tank 1020, adsorbs and concentrates, it is purified after Waste gas is discharged into air through aiutage 1040.
Desorption process:Charcoal absorption organic matter in adsorption tanks 1020 is reached after saturation state, stops waste gas input.Examine Consider the device for treating desorption with dry clean nitrogen before the factors such as control desorption process hydrolysis generation, device desorption to be purged Displacement, displacement blower fan 2010 is opened.The waste gas gone out using nitrogen displacement in the tank body of adsorption tanks 1020, by containing oxygen detection 1050 On-line checking is carried out, when oxygen content is less than setting value 0.1%, ON cycle blower fan 2020, nitrogen is through being connected with high-temperature vapor First Heat Exchanger 2030 be desorbed by circulating-heating (temperature is adjustable, is individually set according to different VOCS compositions), will be organic Thing is desorbed from activated carbon, and activated carbon recovers its activity in adsorption tanks, and the high-temp waste gas for during which being desorbed out, which enters, is connected with industry The second heat exchanger 2040 and the second heat exchanger 2050 of water and chilled water are constantly condensed, organic gas condensing in waste gas extremely In lime set tank 2070, condensate liquid is delivered in incinerator 2090 by lime set pump 2080, adsorption tanks and pipe after waste gas has been condensed High temperature nitrogen containing high concentration in road, in the presence of circulating fan 2020, by the 4th heat exchanger 2060 high temperature nitrogen Closed to be cooled to normal temperature, adsorption tanks desorption is just completed, the input of correspondence nitrogen and output.If there is event in nitrogen device 2010 Barrier, closes nitrogen device.Close the import and export of nitrogen valve of First Heat Exchanger 2030.The steam of steam unit 2100 is through direct Enter after the heating of one heat exchanger 2030 and steam desorption is carried out in adsorption tanks, blowdown is carried out by unified drainage.
In summary, after the adjustable activated carbon adsorption/desorption complexes of the Wet-dry realize charcoal absorption High efficiency desorption parsing.Steam and two kinds of desorption mediums of nitrogen are mutually standby, and system reliability stability is stronger, meanwhile, utilize Industrial water source and fire water supply are designed as the spray of double-safety, it can be ensured that system is perfectly safe safely, and this device is not only Treatment effeciency is high, and the organic substance that can efficiently go in removing exhaust gas, the effect of the device can not only reach national waste gas emission standard And operation and maintenance cost is low, security highest.
It should be noted that herein, such as first and second or the like relational terms are used merely to a reality Body or operation make a distinction with another entity or operation, and not necessarily require or imply these entities or deposited between operating In any this actual relation or order.Moreover, term " comprising ", "comprising" or its any other variant are intended to Nonexcludability is included, so that process, method, article or equipment including a series of key elements not only will including those Element, but also other key elements including being not expressly set out, or also include being this process, method, article or equipment Intrinsic key element.In the absence of more restrictions, the key element limited by sentence "including a ...", it is not excluded that Also there is other identical element in process, method, article or equipment including the key element.
Described above is only the embodiment of the application, it is noted that for the ordinary skill people of the art For member, on the premise of the application principle is not departed from, some improvements and modifications can also be made, these improvements and modifications also should It is considered as the protection domain of the application.

Claims (7)

1. a kind of adjustable activated carbon adsorption/desorption complexes of Wet-dry, it is characterised in that the Wet-dry adjusting flexible Property charcoal adsorption/desorption complexes, including adsorbent equipment, desorption apparatus, control device and some pipelines and valve, the absorption Device includes pneumatic filter, adsorption tanks, main fan and aiutage, and the adsorption tanks are provided with exhaust gas inlet, waste gas outlet, nitrogen Gas import and nitrogen outlet, the pneumatic filter outlet are connected to exhaust gas inlet by pipeline, and the aiutage import passes through Pipeline is connected to waste gas outlet, and the main fan is connected between aiutage and waste gas outlet, the nitrogen inlet and nitrogen Outlet is connected to desorption apparatus;
The desorption apparatus is changed including displacement blower fan, circulating fan, First Heat Exchanger, the second heat exchanger, the 3rd heat exchanger, the 4th Hot device, drainer, condenser pump, incinerator, nitrogen device and steam unit, the displacement blower fan two ends are connected by pipeline respectively In nitrogen inlet and the gaseous phase outlet of drainer, the liquid-phase outlet of the drainer is connected to the incinerator, institute by pipeline State condenser pump to be arranged between the drainer and incinerator, the circulating fan two ends are connected to nitrogen by pipeline respectively and gone out Mouthful and First Heat Exchanger import, the nitrogen device and the 4th heat exchanger import are parallel to the circulating fan and the by pipeline Between one heat exchanger, the outlet of the First Heat Exchanger and the 4th heat exchanger is connected to nitrogen inlet by pipeline respectively, described Second heat exchanger import is connected to waste gas outlet by pipeline, and second heat exchanger exit is connected to the 3rd heat exchange by pipeline Device import, the 3rd heat exchanger exit is connected to drainer gas phase import, second heat exchanger, the 3rd heat exchanger and the 4th Heat exchanger is by the use of external source as heat transferring medium, and the steam unit is connected to adsorption tanks and steaming by First Heat Exchanger Vapour device;
Each segment pipe is respectively equipped with valve, and the valve passes through the control device centralized Control.
2. the adjustable activated carbon adsorption/desorption complexes of Wet-dry according to claim 1, it is characterised in that:It is described Adsorbent in adsorption tanks is activated carbon.
3. the adjustable activated carbon adsorption/desorption complexes of Wet-dry according to claim 1, it is characterised in that:It is described Main fan is in explosion-proof closed environment.
4. the adjustable activated carbon adsorption/desorption complexes of Wet-dry according to claim 1, it is characterised in that:It is described Nitrogen outlet is connected with containing oxygen detection.
5. the adjustable activated carbon adsorption/desorption complexes of Wet-dry according to claim 1, it is characterised in that:It is described Also include some Shower taps in adsorption tanks.
6. the adjustable activated carbon adsorption/desorption complexes of Wet-dry according to claim 5, it is characterised in that:It is described Shower tap is connected to fire water supply and industrial water source simultaneously.
7. the adjustable activated carbon adsorption/desorption complexes of Wet-dry according to claim 1, it is characterised in that:It is described First Heat Exchanger selects the adjustable heat exchanger of temperature.
CN201710409055.1A 2017-06-02 2017-06-02 The adjustable activated carbon adsorption/desorption complexes of Wet-dry Pending CN107158879A (en)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109046251A (en) * 2018-10-09 2018-12-21 上海汉磊环保科技有限公司 A kind of activated carbon adsorption detachment assays device

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CN202169134U (en) * 2011-07-27 2012-03-21 山东电力工程咨询院有限公司 Novel desulphurization accident flue gas spray cooling system
CN202724967U (en) * 2012-05-14 2013-02-13 武汉旭日华科技发展有限公司 Tail gas adsorbing device of mixed bed layer
CN103585854A (en) * 2013-10-29 2014-02-19 嘉园环保股份有限公司 Technology for recovering and processing organic exhaust gas by activated carbon adsorption and N2 desorption
CN203577580U (en) * 2013-11-20 2014-05-07 苏州巨联科技有限公司 Activated carbon adsorption recovery device taking nitrogen as desorption medium
JP2015000381A (en) * 2013-06-17 2015-01-05 東洋紡株式会社 Organic solvent recovery system
CN206094118U (en) * 2016-09-19 2017-04-12 南通海阳节能环保科技有限公司 An organic waste gas purifier
CN206778138U (en) * 2017-06-02 2017-12-22 张家港市艾尔环保工程有限公司 The adjustable activated carbon adsorption/desorption complexes of Wet-dry

Patent Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN202169134U (en) * 2011-07-27 2012-03-21 山东电力工程咨询院有限公司 Novel desulphurization accident flue gas spray cooling system
CN202724967U (en) * 2012-05-14 2013-02-13 武汉旭日华科技发展有限公司 Tail gas adsorbing device of mixed bed layer
JP2015000381A (en) * 2013-06-17 2015-01-05 東洋紡株式会社 Organic solvent recovery system
CN103585854A (en) * 2013-10-29 2014-02-19 嘉园环保股份有限公司 Technology for recovering and processing organic exhaust gas by activated carbon adsorption and N2 desorption
CN203577580U (en) * 2013-11-20 2014-05-07 苏州巨联科技有限公司 Activated carbon adsorption recovery device taking nitrogen as desorption medium
CN206094118U (en) * 2016-09-19 2017-04-12 南通海阳节能环保科技有限公司 An organic waste gas purifier
CN206778138U (en) * 2017-06-02 2017-12-22 张家港市艾尔环保工程有限公司 The adjustable activated carbon adsorption/desorption complexes of Wet-dry

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109046251A (en) * 2018-10-09 2018-12-21 上海汉磊环保科技有限公司 A kind of activated carbon adsorption detachment assays device

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Application publication date: 20170915