CN108204599B - DMF waste gas treatment system - Google Patents

DMF waste gas treatment system Download PDF

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Publication number
CN108204599B
CN108204599B CN201810101934.2A CN201810101934A CN108204599B CN 108204599 B CN108204599 B CN 108204599B CN 201810101934 A CN201810101934 A CN 201810101934A CN 108204599 B CN108204599 B CN 108204599B
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outlet
inlet
oxidation furnace
heating box
gas
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CN108204599A (en
Inventor
何群伟
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Suzhou Krantz Environment Technology Co ltd
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Suzhou Krantz Environment Technology Co ltd
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    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F23COMBUSTION APPARATUS; COMBUSTION PROCESSES
    • F23GCREMATION FURNACES; CONSUMING WASTE PRODUCTS BY COMBUSTION
    • F23G7/00Incinerators or other apparatus for consuming industrial waste, e.g. chemicals
    • F23G7/06Incinerators or other apparatus for consuming industrial waste, e.g. chemicals of waste gases or noxious gases, e.g. exhaust gases
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/02Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography
    • B01D53/06Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography with moving adsorbents, e.g. rotating beds
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/14Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by absorption
    • B01D53/1406Multiple stage absorption
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/14Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by absorption
    • B01D53/18Absorbing units; Liquid distributors therefor
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/26Drying gases or vapours
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F22STEAM GENERATION
    • F22BMETHODS OF STEAM GENERATION; STEAM BOILERS
    • F22B1/00Methods of steam generation characterised by form of heating method
    • F22B1/02Methods of steam generation characterised by form of heating method by exploitation of the heat content of hot heat carriers
    • F22B1/18Methods of steam generation characterised by form of heating method by exploitation of the heat content of hot heat carriers the heat carrier being a hot gas, e.g. waste gas such as exhaust gas of internal-combustion engines
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F24HEATING; RANGES; VENTILATING
    • F24HFLUID HEATERS, e.g. WATER OR AIR HEATERS, HAVING HEAT-GENERATING MEANS, e.g. HEAT PUMPS, IN GENERAL
    • F24H1/00Water heaters, e.g. boilers, continuous-flow heaters or water-storage heaters
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2259/00Type of treatment
    • B01D2259/40Further details for adsorption processes and devices
    • B01D2259/40083Regeneration of adsorbents in processes other than pressure or temperature swing adsorption
    • B01D2259/40086Regeneration of adsorbents in processes other than pressure or temperature swing adsorption by using a purge gas

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  • Engineering & Computer Science (AREA)
  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Analytical Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • General Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Combustion & Propulsion (AREA)
  • Environmental & Geological Engineering (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Sustainable Development (AREA)
  • Sustainable Energy (AREA)
  • Treating Waste Gases (AREA)

Abstract

The invention discloses a DMF waste gas treatment system, wherein a washing device receives process waste gas of a production line, an outlet of the DMF waste gas is connected with an inlet of a second washing device, an outlet of the second washing device is connected with a first inlet of a filtering device, an outlet of the filtering device is connected with a first inlet of a concentration rotating wheel, a first outlet of the filtering device is connected with the outside atmosphere through a chimney, a second outlet of the filtering device is connected with a first inlet of a mixed flow heating box, a second inlet of the filtering device is connected with a first outlet of the mixed flow heating box, a third outlet of the filtering device is connected with a first inlet of a heat accumulating type oxidation furnace, a first outlet of the heat accumulating type oxidation furnace is connected with a second inlet of the filtering device, and a second outlet of the filtering device is connected with a second inlet of the mixed flow heating box. The invention has the beneficial effects that: 1. the DMF is larger than the conventional one-step water washing by the two-step water washing, and the recovery amount is large; 2. the system treats the NOx emission of DMF gas to reach the standard; 3. the method of mixing the exhaust gas of the regenerative oxidation furnace and the exhaust gas after two water washes is used, so that the heating and dehumidifying effects are obvious, and the energy is saved.

Description

DMF waste gas treatment system
Technical Field
The invention belongs to the technical field of industrial waste gas treatment, and particularly relates to a DMF waste gas treatment system.
Background
A large amount of waste gas containing DMF can be generated in some industrial production processes, especially in the production industry of synthetic leather industry, the treatment of industrial DMF waste gas is mainly treated by adopting a water washing method, a recovery method, active carbon adsorption and other methods, and the emission of a large amount of residual DMF waste gas after condensation recovery by the recovery method and the residual VOCs insoluble in water after water washing by the water washing method still does not reach the standard, but the active carbon adsorption method is difficult to regenerate, generates secondary dangerous waste and has high operation cost.
In conclusion, the industrial DMF waste gas treatment problem is difficult to be effectively and thoroughly treated. The DMF waste gas pollution problem is difficult to be thoroughly treated by the traditional method, the emission is not up to standard, and secondary pollution is easy to be generated.
Disclosure of Invention
The invention aims to overcome the defects in the prior art and provide a DMF waste gas treatment system which can effectively treat DMF waste gas and reduce secondary pollution.
In order to solve the problems in the prior art, the invention discloses a DMF waste gas treatment system which comprises a primary washing device, a secondary washing device, a filtering device, a heat accumulating type oxidation furnace, a concentration rotating wheel and a mixed flow heating box;
the first water washing equipment receives production line process waste gas, the outlet of the first water washing equipment is connected with the inlet of the second water washing equipment, the outlet of the second water washing equipment is connected with the first inlet of the filtering equipment, the outlet of the filtering equipment is connected with the first inlet of the concentrating runner, the first outlet of the filtering equipment is connected with the outside atmosphere through a chimney, the second outlet of the filtering equipment is connected with the first inlet of the mixed flow heating box, the second inlet of the filtering equipment is connected with the first outlet of the mixed flow heating box, the third outlet of the filtering equipment is connected with the first inlet of the regenerative oxidation furnace, the first outlet of the regenerative oxidation furnace is connected with the second inlet of the filtering equipment, and the second outlet of the filtering equipment is connected with the second inlet of the mixed flow heating box.
As a preferable scheme, the device also comprises a heat exchanger and a hot water boiler, wherein the inlet of the hot water boiler is connected with the second outlet of the regenerative oxidation furnace, the outlet of the hot water boiler is connected with the hot flow inlet of the heat exchanger, and the hot flow outlet of the heat exchanger is connected with the second inlet of the filtering equipment.
Preferably, a first fan is connected between the third outlet of the concentration rotating wheel and the first inlet of the regenerative oxidation furnace.
Preferably, a second fan is connected between the first outlet of the concentrating runner and the chimney.
Preferably, the second outlet of the regenerative oxidation furnace is also connected with the external atmosphere through a chimney.
As a preferable scheme, a first air regulating valve is connected between a second outlet of the regenerative oxidation furnace and the chimney and close to the chimney, the regenerative oxidation furnace is provided with a first temperature sensor, and the first temperature sensor controls the opening of the first air regulating valve according to the detected temperature in the regenerative oxidation furnace.
Preferably, the first temperature sensor further controls the gas flow rate and the compressed air flow rate of the regenerative oxidation furnace based on the detected temperature in the regenerative oxidation furnace.
As a preferred scheme, a second air regulating valve is connected between a second outlet of the regenerative oxidation furnace and a second inlet of the mixed flow heating box at a position close to the mixed flow heating box, a second temperature sensor is arranged at a first outlet of the mixed flow heating box, and the opening degree of the second air regulating valve is controlled by the second temperature sensor according to the detected outlet temperature of the mixed flow heating box.
Preferably, the filtering device comprises at least three filter screens.
As a preferable scheme, the number of one water washing device is three, and the outlet of the water washing device is also connected with the external atmosphere through a chimney.
The invention has the beneficial effects that:
1. the DMF is larger than the conventional one-step water washing by the two-step water washing, and the recovery amount is large;
2. The system treats the NOx emission of DMF gas to reach the standard;
3. The method of mixing the exhaust gas of the regenerative oxidation furnace and the exhaust gas after two water washes is adopted, so that the heating and dehumidifying effects are obvious, and the energy is saved;
4. The heat accumulating type oxidation furnace heat bypass exhaust gas is used for heating a hot water boiler to generate water vapor to be recycled to a production line, so that the economic benefit conversion of redundant waste heat is realized.
Drawings
Fig. 1 is a schematic structural view of a preferred embodiment of the present invention.
Reference numerals:
1 a water washing device; 2 two water washing devices; 3a filtering device; 4, concentrating the rotating wheel; 5, a mixed flow heating box; 6, a heat accumulating type oxidation furnace; 7, a first fan; 8, a second fan; 9 a heat exchanger; 10a hot water boiler; 11 a first air regulating valve; a second air regulating valve 12; 13 a second temperature sensor; a first temperature sensor 14; 15 chimney.
Detailed Description
The invention is further described below with reference to the accompanying drawings. The following examples are only for more clearly illustrating the technical aspects of the present invention, and are not intended to limit the scope of the present invention.
As shown in fig. 1, a DMF exhaust gas treatment system comprises a primary water washing apparatus 1, a secondary water washing apparatus 2, a filtering apparatus 3, a regenerative oxidation furnace 6, a concentration runner 4 and a mixed flow heating box 5.
The first water washing equipment 1 receives production line process waste gas, the outlet of the first water washing equipment 1 is connected with the inlet of the second water washing equipment 2, the outlet of the second water washing equipment 2 is connected with the first inlet of the filtering equipment 3, the outlet of the filtering equipment 3 is connected with the first inlet of the concentration rotating wheel 4, the first outlet of the first water washing equipment is connected with the outside atmosphere through a chimney 15, the second outlet of the first water washing equipment is connected with the first inlet of the mixed flow heating box 5, the second inlet of the first water washing equipment is connected with the first outlet of the mixed flow heating box 5, the third outlet of the first water washing equipment is connected with the first inlet of the regenerative oxidation furnace 6, the first outlet of the regenerative oxidation furnace 6 is connected with the second inlet of the filtering equipment 3, and the second outlet of the first water washing equipment is connected with the second inlet of the mixed flow heating box 5.
As a preferred solution, the filter device further comprises a heat exchanger 9 and a hot water boiler 10, wherein the inlet of the hot water boiler 10 is connected with the second outlet of the regenerative oxidation furnace 6, the outlet of the hot water boiler is connected with the hot flow inlet of the heat exchanger 9, and the hot flow outlet of the heat exchanger 9 is connected with the second inlet of the filter device 3.
Preferably, a first fan 7 is connected between the third outlet of the concentrating runner 4 and the first inlet of the regenerative oxidation furnace 6.
Preferably, a second fan 8 is connected between the first outlet of the concentrating runner 4 and the chimney 15.
Preferably, the second outlet of the regenerative oxidizing furnace 6 is also connected to the outside atmosphere through a chimney 15.
Preferably, a first damper 11 is connected between the second outlet of the regenerative oxidation furnace 6 and the chimney 15 at a position close to the chimney 15, the regenerative oxidation furnace 6 is provided with a first temperature sensor 14, and the first temperature sensor 14 controls the opening of the first damper 11 according to the detected temperature in the regenerative oxidation furnace 6.
Preferably, the first temperature sensor 14 also controls the gas flow rate and the compressed air flow rate of the regenerative oxidizing furnace 6 based on the detected temperature inside the regenerative oxidizing furnace 6.
As a preferable scheme, a second air regulating valve 12 is connected between a second outlet of the regenerative oxidation furnace 6 and a second inlet of the mixed flow heating box 5 at a position close to the mixed flow heating box 5, a second temperature sensor 13 is arranged at a first outlet of the mixed flow heating box 5, and the second temperature sensor 13 controls the opening degree of the second air regulating valve 12 according to the detected outlet temperature of the mixed flow heating box 5.
Preferably, the filtering device 3 comprises at least three filtering screens.
Preferably, the number of the water washing devices 1 is three, and the outlets of the water washing devices are also connected with the external atmosphere through a chimney 15.
The working principle and the process of the invention are as follows:
If the industrial waste gas is applied to the synthetic leather industry, most of the waste gas enters the system by three versions of process waste gas, firstly, the waste gas passes through a water washing device 1, and an emergency bypass pipeline is arranged at the device to lead to a chimney 15. After the DMF-containing waste gas is subjected to one water washing, most DMF is dissolved in water, a small part of undissolved DMF waste gas and other VOCs waste gas which is not easy to be water, such as toluene, continue to enter the two-channel water washing equipment 2, and DMF waste water is led to a waste water treatment process. The residual little DMF waste gas and other VOCs waste gas which is not easy to water are mixed with the hotter clean gas discharged from the regenerative oxidation furnace 6 after passing through the two-channel water washing device 2, pass through the multiple filtering device 3 and finally enter the concentration rotating wheel 4. The system selects proper concentration ratio according to specific working conditions of the process, and after the gas passes through the concentration rotating wheel 4, most of the gas reaching the standard is directly discharged to the chimney 15, and the other part of the gas enters the mixed flow heating box 5. The small amount of gas is sufficiently mixed with the high-temperature clean gas discharged from the thermal bypass of the regenerative oxidizing furnace 6 to become the desorption gas of the concentration wheel 4 having a proper temperature, and the gas passes through the desorption region of the concentration wheel 4. The concentrated exhaust gas is fed into a regenerative oxidation furnace 6 and subjected to a sufficiently high-temperature reaction. Subsequently, a portion of the clean gas is exhausted through a thermal bypass, which serves as two points: part of the gas is used for heating the hot water boiler 10 to generate hot water vapor for a production line, and the gas is mixed with clean gas discharged by the regenerative oxidation furnace 6 after passing through the hot water boiler 10 and enters the filtering equipment 3 together and returns to the concentration rotating wheel 4 again, so that the problem of high intermittent discharge concentration of the regenerative oxidation furnace 6 is solved, and meanwhile, redundant waste heat is fully utilized to generate economic benefit; the other path of clean hot air which is bypassed by the heat accumulating type oxidation furnace 6 passes through the mixed flow heating box 5 and is mixed with cooler gas which enters the concentration rotating wheel 4 through multiple filtration to become desorption gas of the concentration rotating wheel 4. And most of the clean gas after full reaction in the regenerative oxidation furnace 6 is introduced into the filtering equipment 3.
The foregoing is merely a preferred embodiment of the present invention, and it should be noted that modifications and variations could be made by those skilled in the art without departing from the technical principles of the present invention, and such modifications and variations should also be regarded as being within the scope of the invention.

Claims (5)

1. A DMF exhaust treatment system, characterized by: comprises a first water washing device (1), a second water washing device (2), a filtering device (3), a heat accumulating type oxidation furnace (6), a concentration rotating wheel (4) and a mixed flow heating box (5);
The first water washing equipment (1) receives production line process waste gas, an outlet of the first water washing equipment is connected with an inlet of the second water washing equipment (2), an outlet of the second water washing equipment (2) is connected with a first inlet of the filtering equipment (3), an outlet of the filtering equipment (3) is connected with a first inlet of the concentrating rotating wheel (4), a first outlet of the filtering equipment is connected with the outside atmosphere through a chimney (15), a second outlet of the filtering equipment is connected with a first inlet of the mixed flow heating box (5), a second inlet of the filtering equipment is connected with a first outlet of the mixed flow heating box (5), a third outlet of the filtering equipment is connected with a first inlet of the heat accumulating type oxidation furnace (6), a first outlet of the heat accumulating type oxidation furnace (6) is connected with a second inlet of the filtering equipment (3), and a second outlet of the filtering equipment is connected with a second inlet of the mixed flow heating box (5);
The device also comprises a heat exchanger (9) and a hot water boiler (10), wherein the inlet of the hot water boiler (10) is connected with the second outlet of the regenerative oxidation furnace (6), the outlet of the hot water boiler is connected with the hot flow inlet of the heat exchanger (9), and the hot flow outlet of the heat exchanger (9) is connected with the second inlet of the filtering equipment (3);
Waste gas concentrated by the concentrating rotating wheel (4) is fed into the regenerative oxidation furnace (6) and subjected to a sufficiently high-temperature reaction, and then a part of clean gas is discharged through a thermal bypass, and the part of clean gas is divided into two paths: one path of gas is used for heating a hot water boiler (10) to generate hot water vapor for a production line to use, and the gas is mixed with clean gas discharged by a regenerative oxidation furnace (6) after passing through the hot water boiler (10), enters a filtering device (3) together and returns to a concentration rotating wheel (4) again; the other path of the gas is mixed with cooler gas which enters the concentration rotating wheel (4) through multiple filtration by a mixed flow heating box (5) to become desorption gas of the concentration rotating wheel (4); other parts of clean gas after full reaction in the regenerative oxidation furnace (6) are introduced into the filtering equipment (3);
The second outlet of the regenerative oxidation furnace (6) is also connected with the external atmosphere through the chimney (15);
A first air regulating valve (11) is connected between a second outlet of the regenerative oxidation furnace (6) and the chimney (15) and close to the chimney (15), the regenerative oxidation furnace (6) is provided with a first temperature sensor (14), and the first temperature sensor (14) controls the opening of the first air regulating valve (11) according to the detected temperature in the regenerative oxidation furnace (6);
The first temperature sensor (14) also controls the gas flow and air flow of the regenerative oxidation furnace (6) according to the detected temperature in the regenerative oxidation furnace (6);
the second air regulating valve (12) is connected between the second outlet of the regenerative oxidation furnace (6) and the second inlet of the mixed flow heating box (5) and is close to the position of the mixed flow heating box (5), a second temperature sensor (13) is arranged at the first outlet of the mixed flow heating box (5), and the second temperature sensor (13) controls the opening degree of the second air regulating valve (12) according to the detected outlet temperature of the mixed flow heating box (5).
2. A DMF exhaust treatment system according to claim 1, wherein: a first fan (7) is connected between the third outlet of the concentration rotating wheel (4) and the first inlet of the regenerative oxidation furnace (6).
3. A DMF exhaust treatment system according to claim 1, wherein: a second fan (8) is connected between the first outlet of the concentration rotating wheel (4) and the chimney (15).
4. A DMF exhaust treatment system according to claim 1, wherein: the filter device (3) comprises at least three filter screens.
5. A DMF exhaust treatment system according to claim 1, wherein: the number of the water washing devices (1) is three, and the outlets of the water washing devices are also connected with the outside atmosphere through the chimney (15).
CN201810101934.2A 2018-02-01 2018-02-01 DMF waste gas treatment system Active CN108204599B (en)

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Publication number Priority date Publication date Assignee Title
TWI701409B (en) * 2019-04-12 2020-08-11 華懋科技股份有限公司 Reflux heat recovery high-efficiency organic waste gas treatment system and method

Citations (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
TW316494U (en) * 1996-07-19 1997-09-21 United Microelectronics Corp Exhaust processing system
CN102512902A (en) * 2011-12-09 2012-06-27 青岛华世洁环保科技有限公司 Method and device for purifying organic waste gas and utilizing residual heat in printing ink workshop
TW201428216A (en) * 2013-01-04 2014-07-16 Wuxi Zhong Shun Cheng Environmental Technology Co Ltd Zero energy consumption purification apparatus of volatile organic compounds and method thereof
CN205127672U (en) * 2015-09-22 2016-04-06 江苏中研宜普科技有限公司 Two energy -saving concentrated runners and RTO's organic waste gas processing system
CN206414916U (en) * 2016-12-28 2017-08-18 越研环境工程盐城有限公司 A kind of paint booth exhaust treatment system
CN206463735U (en) * 2017-01-17 2017-09-05 恩国环保科技(上海)有限公司 A kind of coating emission-control equipment based on thermal accumulating incinerator
CN107497262A (en) * 2017-09-14 2017-12-22 苏州克兰茨环境科技有限公司 A kind of organic waste gas treatment system
CN208090693U (en) * 2018-02-01 2018-11-13 苏州克兰茨环境科技有限公司 A kind of DMF exhaust treatment systems

Patent Citations (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
TW316494U (en) * 1996-07-19 1997-09-21 United Microelectronics Corp Exhaust processing system
CN102512902A (en) * 2011-12-09 2012-06-27 青岛华世洁环保科技有限公司 Method and device for purifying organic waste gas and utilizing residual heat in printing ink workshop
TW201428216A (en) * 2013-01-04 2014-07-16 Wuxi Zhong Shun Cheng Environmental Technology Co Ltd Zero energy consumption purification apparatus of volatile organic compounds and method thereof
CN205127672U (en) * 2015-09-22 2016-04-06 江苏中研宜普科技有限公司 Two energy -saving concentrated runners and RTO's organic waste gas processing system
CN206414916U (en) * 2016-12-28 2017-08-18 越研环境工程盐城有限公司 A kind of paint booth exhaust treatment system
CN206463735U (en) * 2017-01-17 2017-09-05 恩国环保科技(上海)有限公司 A kind of coating emission-control equipment based on thermal accumulating incinerator
CN107497262A (en) * 2017-09-14 2017-12-22 苏州克兰茨环境科技有限公司 A kind of organic waste gas treatment system
CN208090693U (en) * 2018-02-01 2018-11-13 苏州克兰茨环境科技有限公司 A kind of DMF exhaust treatment systems

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