CN107156164A - The Herbicidal combinations of flufenacet, flucarbazone and diflufenican - Google Patents

The Herbicidal combinations of flufenacet, flucarbazone and diflufenican Download PDF

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Publication number
CN107156164A
CN107156164A CN201710485993.XA CN201710485993A CN107156164A CN 107156164 A CN107156164 A CN 107156164A CN 201710485993 A CN201710485993 A CN 201710485993A CN 107156164 A CN107156164 A CN 107156164A
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Prior art keywords
agent
diflufenican
flucarbazone
flufenacet
active component
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CN201710485993.XA
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Chinese (zh)
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不公告发明人
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Beijing Agricultural Science And Technology Center
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Beijing Agricultural Science And Technology Center
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    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N47/00Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
    • A01N47/08Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having one or more single bonds to nitrogen atoms
    • A01N47/28Ureas or thioureas containing the groups >N—CO—N< or >N—CS—N<
    • A01N47/38Ureas or thioureas containing the groups >N—CO—N< or >N—CS—N< containing the group >N—CO—N< where at least one nitrogen atom is part of a heterocyclic ring; Thio analogues thereof
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/34Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom
    • A01N43/40Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom six-membered rings
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/72Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms
    • A01N43/82Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms five-membered rings with three ring hetero atoms

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  • Life Sciences & Earth Sciences (AREA)
  • Agronomy & Crop Science (AREA)
  • Pest Control & Pesticides (AREA)
  • Plant Pathology (AREA)
  • Health & Medical Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Dentistry (AREA)
  • General Health & Medical Sciences (AREA)
  • Wood Science & Technology (AREA)
  • Zoology (AREA)
  • Environmental Sciences (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)

Abstract

The invention provides a kind of synergistic herbicidal compositions containing flufenacet, flucarbazone and diflufenican, it is characterized in that including active components A, B and C, wherein, A is flufenacet, B is flucarbazone, and C is the auxiliary agent that can be used in diflufenican, in addition to Pesticide formulation, conventional pesticidal preparations are made, and applied to the unwanted plant of preventing and treating.

Description

The Herbicidal combinations of flufenacet, flucarbazone and diflufenican
Technical field
The invention belongs to pesticides application technical field, it is related to a kind of composition pesticide, specifically flufenacet, fluorine azoles Sulphur is grand and the Herbicidal combinations of diflufenican, applied to preventing and kill off unwanted plant.
Background technology
In agricultural production process, it is not necessary to plant (weeds) occur serious, the target crop such as damage to crops, forest life It is long, and influence undesirable vegetation plot (such as bare place, railway, highway, forest fire protection road, industrial sites, threshing ground) is just Often use.Herbicide is to prevent and kill off the most economic, the quick and effective method for not needing plant.
Single herbicide is limited using easily developing immunity to drugs or preventing and treating spectrum, can not solve well in produce reality not Need the harm of plant.Mixture herbicide, which has, can expand preventing and treating spectrum, enhancing preventive effect, delay the advantages such as herbicide resistance, in life Turn into most popular application form in production practice.Especially have between the herbicide of synergy, each active principle of herbicide Interaction, makes combination aging fruit better than the theoretical summation of effect is used alone, thus can play in actual use the work(of thing half Effect again, is more welcome by user.
Flufenacet (flufenacet) is a kind of selective herbicide of overseas enterprise's exploitation, category cell division and elongation Inhibitor.It can be handled in weeds before seedling after seedling early stage, prevent and kill off corn and soybean, tomato, potato, sunflower, wheat and paddy rice etc. Grassy weed and part broad leaved weed in the crop fields.CAS accession number is 142459-58-3.Its structural formula is as follows:
Flucarbazone (flucarbazone-sodium) is also a kind of before seedling after seedling processing weeding of overseas enterprise's exploitation Agent, is mainly used in preventing and kill off grassy weed and the part broad leaved weed of the various crop Tanaka such as wheat, barley.CAS accession number is 181274–17–9。
Diflufenican (diflufenican) is also a kind of before seedling after seedling processing herbicide of overseas enterprise's exploitation, mainly Grassy weed and broad leaved weed for preventing and kill off the various crop such as wheat, barley, paddy rice field.CAS accession number be 83164-33- 4。
The present invention is studied by substantial amounts of formulation screening test and found, when flufenacet, flucarbazone and diflufenican When being combined with arbitrary proportion, surprising herbicidal effect is shown, that is, shows good synergy, actual herbicidal effect The theoretical summation of exclusive use is substantially better than, there is application prospect widely in production.
The content of the invention
The present invention relates to synergistic herbicidal compositions, including active components A, B and C, described active components A is fluorine thiophene grass Amine, B is flucarbazone, and C is diflufenican.In addition, also including the auxiliary agent that can be used in Pesticide formulation.
The composition especially good effect can be used to prevent and treat the weeds in various useful crops, the useful crop Including but not limited to conventional breeding crop, genetically modified crops, asexually propagated crop and asexual propagation material, domesticating and cultivating it is wild Plant etc., is particularly suitable for use in preventing and kill off in the crop fields such as wheat, barley, corn, paddy rice, soybean, tomato, potato and sunflower Weeds, or in the undesirable vegetation growth plot such as bare place, railway, highway, forest fire protection road, industrial sites, threshing ground Weeds.
The instantiation that can be mentioned that can use the representative grassy weed of composition for preventing and controlling of the invention, broad-leaved miscellaneous for some Grass and nutgrass flatsedge, the example are not limited to specified genus kind.It should be noted that the invention is not limited in example in detail below, also Other unwanted plants can be extended in the same manner:
Including but not limited to following category or the broad leaved weed of section:Abutilon, Amaranthus, Portulaca, Acalypha, lamb's-quarters Category, pulse family, Polygonum, Stellaria, Euphorbia, Bedstraw, Descurainia, shepherd's purse category, Eclipta prostrata category, Viola, Xanthium, Veronica Shu, pivots store category, Kochia, Myosoton, Senecio, Solanum, Lithospermum, lyrate hemistepta herb category, sandwort category, silene, led a cow Category, Brassica genus, Urtica, mallow, Plantago, lespedeza, Ambrosia, Bidens, bitter fleabane category, small fluffy category, sonchus oleraceus Category, pearlwort, Datura, carpetweed, ox achyranthes chrysanthemum spp, black clover category, japanese bearbind genus, Hibiscus;The grass of following category Section weeds:Echinochloa, knotgrass, setaria, Poa L., Avena, Panicum, lolium temulentum category, Brome, wild Panicum, amur foxtail Category, yard grass category, cogon, Brachiaria, speedwell category, ladder forage spp, caput grass Shu, Wang grass category, hard grass category, sandbur Category, Lolium, indian rorippa herbs category;The sedge weed of following category:Cyperus.
In order to solve the above-mentioned technical problem, the present invention, which is adopted the following technical scheme that, is achieved:
The present composition component A, B and C can be with arbitrary proportion mixtures, and a kind of usual active component content is lived higher than remaining Property composition, preferably mixing ratio is (1~100):(1~100):(1~100) or (1~50):(1~50):(1~50).
The present composition can be by the way that active component be mixed with the auxiliary agent that can be used in Pesticide formulation, with known Method is prepared as conventional preparation, missible oil, suspending agent, dispersible oil-suspending agent, water dispersible granules, aqueous emulsion, microemulsion, wettable Property pulvis, granule, suspension emulsion, microcapsule suspending agent etc..The active component of 0.1~95% weight is typically contained in preparation, preferably The active component of 0.5~90% weight.
The auxiliary agent that can be used in Pesticide formulation includes but is not limited to:Water, solvent, filler, various surfactants (emulsifying agent, dispersant, wetting agent etc.), adhesive, film forming agent, colouring agent, antifreezing agent, thickener, suspending agent, disintegrant, disappear Infusion, bleeding agent, warning coloration, synergist, stabilizer, wall capsule material, pH adjusting agent, preservative etc..Also, suitably, in order to Improve to specific crop tolerance, safener can be properly added;Or sometimes for crop growth is promoted, can be in mixture group Conventional agriculture fertilizer is added in compound, medicament-fertilizer mixture is made.These auxiliary agents be all commonly use in pesticidal preparations or allow to use into Point, it is not particularly limited, one or more auxiliary agent may be selected and constitutes, specific composition and consumption pass through letter according to recipe requirements Single experiment is determined.
The production technology of the various application forms of composition belongs to existing known technology, will not be repeated here.
The present composition can be used in a variety of ways, be such as watered spraying in a usual manner and used, or directly spread fertilizer over the fields or ditch Apply, or mix pesticide-clay mixture and spread fertilizer over the fields, can be used in early days before weeds emerge or after emerging.Dosage can change in relative broad range, And depending on the situation of soil, application method, crop, weeds species to be prevented and kill off and seedling age size, weather conditions at that time And other factors.The present composition is generally applied with the consumption of 0.001~1.5kg mixture of active principles/hectare, more excellent Selection of land, is applied with the consumption of 0.02~0.8kg mixture of active principles/hectare.
The present invention compared with prior art, has the following technical effect that:
1st, mixture composition has good synergy, and application effect is substantially better than single dose theoretical effect summation, that is, had There is super superposition, dominant weed occurrence injury can be better controled over;
2nd, there is good complementarity in control of weeds spectrum between mixture composition active component, preventing and treating can be expanded very well Spectrum, synthesis effectively controls various weeds occurrence injuries;
3rd, mixture composition has good synergy, can reduce medicament usage amount, and reduction use cost and environment are dirty Dye, improves the security to crop.
Embodiment
Specific embodiment of the invention given below is, it is necessary to which explanation is that the invention is not limited in implement in detail below Example, all equivalents done on the basis of technical scheme each fall within protection scope of the present invention.
Embodiment 1:48% missible oil
Being formulated composition is:Active components A is 36%, and active component B is 9%, and active component C is 3%, emulsifying agent alkyl virtue Base polyoxyethylene polyoxypropylene ether 5%, emulsifier polyoxyethylene sorbitan fatty acid ketone 3%, solvent xylene is complemented to 100%.
Preparation method is:All materials are put into batching kettle, stirring and dissolving after chemical examination is qualified, is shifted to fully transparent It is filling to storage tank.
Embodiment 2:57% suspending agent
Being formulated composition is:Active components A is 36%, and active component B is 3%, and active component C is 18%, wetting agent alkyl Phenol polyethenoxy ether formaldehyde condensation products sulfate 4%, dispersant EO-PO block polyethers 5%, antifreezing agent glycerine 5%, thickener Xanthans 0.2%, water complements to 100%.
Preparation method is:By in active component and wetting agent, dispersant, antifreezing agent and water input stirred tank, it is sufficiently stirred for Afterwards, material is pumped into sand mill and be fully ground, after the completion of grinding, be pumped into high-speed shearing machine, add after thickener, enter Row high speed shear, is made suspending agent after the completion of shearing.
Embodiment 3:76% water dispersible granules
Being formulated composition is:Active components A is 48%, and active component B is 24%, and active component C is 4%, wetting agent 12 Sodium alkyl sulfate 5%, dispersant naphthalenesulfonic acid-formaldehyde condensate 7%, disintegrant sodium sulphate 5%, adhesive polyethylene glycol 0.5%, filler diatomite complements to 100%.
Preparation method is:After all materials are well mixed, crush, be well mixed again through airslide disintegrating mill, then, plus Enter a certain amount of water to mediate this mixture, extruder grain, through drying screening, that is, obtain water dispersible granules.
Embodiment 4:15% aqueous emulsion
Being formulated composition is:Active components A is 5%, and active component B is 5%, and active component C is 5%, solvent xylene 10%, solvent cyclohexanone 3%, emulsifying agent styryl phenol polyethenoxy polyethenoxy ether 4%, emulsifying agent aliphatic alcohol polyethenoxy Ether 4%, antifreezing agent propane diols 4%, water complements to 100%.
Preparation method is:After active components A, B and C solvents are fully dissolved, input emulsifying agent is formed after being sufficiently stirred for Oil phase;Antifreezing agent is added to the water dissolving, aqueous phase is formed;Aqueous phase is slowly added in oil phase, sheared using high-speed shearing machine, i.e., Aqueous emulsion can be obtained.
Embodiment 5:25% microemulsion
Being formulated composition is:Active components A is 1%, and active component B is 16%, and active component C is 8%, solvent xylene 10%, solvent cyclohexanone 5%, emulsifying agent styryl phenol polyethenoxy ether 9%, emulsifying agent dodecyl sulphate calcium 5% is antifreeze Agent propane diols 5%, water complements to 100%.
Preparation method is:After active components A, B and C solvents are fully dissolved, input emulsifying agent and antifreezing agent mixing are equal It is even, deionized water is eventually adding, high speed shear is carried out, you can microemulsion is obtained.
Embodiment 6:80% wettable powder
Being formulated composition is:Active components A is 5%, and active component B is 15%, and active component C is 60%, wetting agent bay Alcohol sodium sulphate 7%, dispersant APES formaldehyde condensation product sulfonate 5%, filler attapulgite is complemented to 100%.
Preparation method is:Active component and each auxiliary agent are well mixed, carry out just smashing in the mechanical disintegrating machine of input, afterwards Crushed through airslide disintegrating mill, remix uniform, i.e., obtained wettable powder.
Embodiment 7:5% granule
Being formulated composition is:Active components A is 3%, and active component B is 1%, and active component C is 1%, wetting agent oil sulphur Sour sodium 0.7%, dispersant sodium lignin sulfonate 1%, colouring agent Viride Nitens (peacock green) 0.3%, filler bentonite is complemented to 100%.
Preparation method is:After all materials are well mixed, add a certain amount of water and mediate this mixture, extruding is made Grain, through drying screening, that is, obtains granule.
Embodiment 8:38% dispersible oil-suspending agent
Being formulated composition is:Active components A is 2%, and active component B is 4%, and active component C is 32%, emulsifying agent castor oil APEO 6%, emulsifying agent disecoctylmaleate sodium sulfonate 8%, dispersant polycarboxylate 3%, thickener hard charcoal Black 1.5%, decentralized medium methyl oleate complements to 100%.
Preparation method is:By in active component and emulsifying agent, dispersant and decentralized medium input stirred tank, it is sufficiently stirred for Afterwards, it is pumped into high-speed shearing machine, carries out high speed shear, then pump is fully sanded into sand mill, and qualified rear add is sanded and increases Thick dose, stir and produce dispersible oil-suspending agent.
Embodiment 9:22% microcapsule suspending agent
Being formulated composition is:Active components A is 16%, and active component B is 2%, and active component C is 4%, solvent xylene 10%, solvent dibutyl phthalate 5%, oiliness capsule skin 4,4- methyl diphenylene diisocyanates 6%, aqueous capsule skin second two Amine 3%, emulsifying agent alkylbenzenesulfonate 7%, dispersant hydroxy alkyl cellulose 6%, thickener aluminium-magnesium silicate 0.3% disperses to be situated between Matter water complements to 100%.
Preparation method is:After active components A, B and C solvents are fully dissolved, oiliness capsule skin is added, is sufficiently stirred for being formed Oil phase;It is poured into and is mixed with the aqueous phase of emulsifying agent and dispersant, carry out high speed shear, then add aqueous capsule skin, stirring is equal It is even, then raise temperature to 70 DEG C of heat preservation solidifications 2 hours, microcapsules are made, thickener is eventually adding, stirs and produces microcapsule suspension Agent.
Embodiment 10:60% suspension emulsion
Being formulated composition is:Active components A is 4%, and active component B is 48%, and active component C is 8%, solvent xylene 8%, emulsifying agent sorbitan ester 6%, wetting agent dialkyl succinylsuccinate sulfonate 5%, dispersant EO-PO block polyethers 3% are prevented Jelly agent ethylene glycol 5%, thickener aluminium-magnesium silicate 0.2%, water complements to 100%.
Preparation method is:Active component B, C, wetting agent, dispersant, antifreezing agent and water are put into stirred tank, fully stirred After mixing, material is pumped into sand mill and is fully ground, suspending agent is made;After active components A solvent is fully dissolved with Emulsifying agent is well mixed, and then it is added under the conditions of high speed shear in Manufactured suspending agent, adds thickener, is carried out High speed shear, is made suspension emulsion after the completion of shearing.
Application effect example:
1st, test method
Reference《NY/T 1155.3-2006 farm-chemical indoor determination test rule herbicide third portions:Determination of activity is tried Test soil spray-on process》Carry out.
Experiment is located under greenhouse experiment and carried out.Choose several generations in grassy weed, broad leaved weed and sedge weed Table weeds caput grass, shepherd's purse, chufa, bromegrass, amur foxtail, Elsholtzia densa, Itanlian rye are for examination weeds.Chufa is Perennial weeds, underground rhizome breeding is taken from field, and remaining several weeds is annual grassy weeds, and weed seed is gathered from field Breeding.
Experiment soil is quantitatively filled at the 4/5 of basin alms bowl.Choose full, uniform, the caput grass that has no mechanical damage, shepherd's purse, Bromegrass, amur foxtail, Elsholtzia densa or Itanlian rye seed, with clear water soak 24h after, by its uniform broadcasting in equipped with soil, A diameter of 30cm round plastic nutritive cube surface, 30~40, earthing 1.0cm are broadcast per basin.Perennial weeds chufa is from field Between take underground rhizome (long-rhizome such as 3cm), per basin plant 10 sections.With the bottom infiltrating irrigation mode moisturizing of basin alms bowl, make soil completely wet Moisten to saturation state.Sow the decoction prepared progress soil spraying after 24h.Then move into culture in controllable heliogreenhouse. Often processing set 4 repetitions, every time repeat 5 basins, using without chemicals treatment as blank control.
21d after chemicals treatment, using absolute value (number is surveyed) investigation method investigation records activity of weeding, with weighing each processing weeds Upper part fresh weight, calculates actual preventive effect, and act synergistically according to the evaluation of Colby methods.Referring to COLBY, S.R.:" calculate herbicide The collaboration of combination and Antagonistic reaction ", Weeds 15, p.20~22,1967:
According to survey data, the actual preventive effect of each processing is calculated by formula (1), unit is percentage (%), result of calculation Retain 2 significant digits.
In formula:
E-actual preventive effect;
C-control weeds aerial part fresh weight;
T-processing weeds aerial part fresh weight.
Colby methods:Theoretical preventive effect (it is expected that preventive effect) E of Mixed Pharmacy0(2) formula is calculated:
In formula:
Actual preventive effect when the consumption of X-herbicide 1 is P;
Actual preventive effect when the consumption of Y-herbicide 2 is Q;
Actual preventive effect when the consumption of Z-herbicide 3 is R;
E0The consumption of-herbicide 1 is that the consumption of P+ herbicides 2 is theoretical preventive effect when the consumption of Q+ herbicides 3 is R, i.e. mixture is removed The expection preventive effect of careless agent;
E-herbicide 1,2 and 3 presses actual preventive effect during different ratio mixture;
As E > E0When, should if that is, the actual preventive effect of Mixed Pharmacy exceedes the theoretical preventive effect (it is expected that preventive effect) calculated Combination just has super superposition, that is, acts synergistically.
2nd, result of the test
Result of the test refers to table 1~7, it is seen then that active components A (flufenacet), active component B (flucarbazone) and activity After composition C (diflufenican) medicament mixture, actual preventive effect is all higher than theoretical preventive effect (it is expected that preventive effect), illustrate active components A, Active component B has synergy with active component C mixtures.
The synergy effect of the flufenacet of table 1, flucarbazone and diflufenican mixture to caput grass
The synergy effect of the flufenacet of table 2, flucarbazone and diflufenican mixture to shepherd's purse
The synergy effect of the flufenacet of table 3, flucarbazone and diflufenican mixture to chufa
The synergy effect of the flufenacet of table 4, flucarbazone and diflufenican mixture to bromegrass
The synergy effect of the flufenacet of table 5, flucarbazone and diflufenican mixture to amur foxtail
The synergy effect of the flufenacet of table 6, flucarbazone and diflufenican mixture to Elsholtzia densa
The synergy effect of the flufenacet of table 7, flucarbazone and diflufenican mixture to Itanlian rye

Claims (4)

1. a kind of herbicidal composition, it is characterised in that including active components A, B and C.
2. herbicidal composition as claimed in claim 1, it is characterised in that described active components A is flufenacet, B is Flucarbazone, C is diflufenican.
3. herbicidal composition as claimed in claim 1 or 2, it is characterised in that in addition to active components A, B and C, in addition to The auxiliary agent that can be used in Pesticide formulation.
4. the herbicidal composition as described in claim 1,2 or 3, it is characterised in that be applied to the unwanted plant of preventing and treating Thing.
CN201710485993.XA 2017-06-23 2017-06-23 The Herbicidal combinations of flufenacet, flucarbazone and diflufenican Withdrawn CN107156164A (en)

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107960422A (en) * 2017-12-06 2018-04-27 江苏省农业科学院 A kind of herbicide decrement control careless method of dispenser prevention and control Wheat after rice time of infertility crop smothering
CN109418274A (en) * 2018-06-01 2019-03-05 青岛清原化合物有限公司 A kind of ternary weeding composition and its application

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2003028467A1 (en) * 2001-09-27 2003-04-10 Syngenta Participations Ag Herbicidal composition
JP2010163411A (en) * 2008-12-17 2010-07-29 Bayer Cropscience Ag Herbicidal composition
CN105557733A (en) * 2015-12-11 2016-05-11 汤云鹤 Pesticide composition containing flucarbazone and flufenacet and application of pesticide composition in control of weeds in wheat field
CN106818834A (en) * 2017-02-24 2017-06-13 江苏省农用激素工程技术研究中心有限公司 Composition pesticide and its application containing diflufenican, flufenacet and flucarbazone

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2003028467A1 (en) * 2001-09-27 2003-04-10 Syngenta Participations Ag Herbicidal composition
JP2010163411A (en) * 2008-12-17 2010-07-29 Bayer Cropscience Ag Herbicidal composition
CN105557733A (en) * 2015-12-11 2016-05-11 汤云鹤 Pesticide composition containing flucarbazone and flufenacet and application of pesticide composition in control of weeds in wheat field
CN106818834A (en) * 2017-02-24 2017-06-13 江苏省农用激素工程技术研究中心有限公司 Composition pesticide and its application containing diflufenican, flufenacet and flucarbazone

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107960422A (en) * 2017-12-06 2018-04-27 江苏省农业科学院 A kind of herbicide decrement control careless method of dispenser prevention and control Wheat after rice time of infertility crop smothering
CN109418274A (en) * 2018-06-01 2019-03-05 青岛清原化合物有限公司 A kind of ternary weeding composition and its application
WO2019228215A1 (en) * 2018-06-01 2019-12-05 青岛清原化合物有限公司 Ternary herbicidal composition and application thereof

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Application publication date: 20170915