CN107142713A - A kind of method of modifying to fabric face - Google Patents
A kind of method of modifying to fabric face Download PDFInfo
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- CN107142713A CN107142713A CN201710507192.9A CN201710507192A CN107142713A CN 107142713 A CN107142713 A CN 107142713A CN 201710507192 A CN201710507192 A CN 201710507192A CN 107142713 A CN107142713 A CN 107142713A
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- fabric
- microwave plasma
- microwave
- gas
- reative cell
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- 239000004744 fabric Substances 0.000 title claims abstract description 54
- 238000000034 method Methods 0.000 title claims abstract description 21
- 238000006116 polymerization reaction Methods 0.000 claims abstract description 16
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 11
- 238000001994 activation Methods 0.000 claims abstract description 10
- 239000000126 substance Substances 0.000 claims abstract description 6
- 238000004132 cross linking Methods 0.000 claims abstract description 4
- 238000004381 surface treatment Methods 0.000 claims abstract description 4
- 239000007789 gas Substances 0.000 claims description 26
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 19
- XKRFYHLGVUSROY-UHFFFAOYSA-N Argon Chemical compound [Ar] XKRFYHLGVUSROY-UHFFFAOYSA-N 0.000 claims description 16
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims description 15
- 238000001035 drying Methods 0.000 claims description 13
- 239000003607 modifier Substances 0.000 claims description 13
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims description 12
- 238000002203 pretreatment Methods 0.000 claims description 10
- -1 amino, carbonyl Chemical group 0.000 claims description 9
- 238000012545 processing Methods 0.000 claims description 9
- 229910052786 argon Inorganic materials 0.000 claims description 8
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 8
- 239000001301 oxygen Substances 0.000 claims description 8
- 229910052760 oxygen Inorganic materials 0.000 claims description 8
- 230000004913 activation Effects 0.000 claims description 7
- 239000002253 acid Substances 0.000 claims description 6
- 239000003570 air Substances 0.000 claims description 6
- 239000001307 helium Substances 0.000 claims description 6
- 229910052734 helium Inorganic materials 0.000 claims description 6
- SWQJXJOGLNCZEY-UHFFFAOYSA-N helium atom Chemical compound [He] SWQJXJOGLNCZEY-UHFFFAOYSA-N 0.000 claims description 6
- 239000001257 hydrogen Substances 0.000 claims description 6
- 229910052739 hydrogen Inorganic materials 0.000 claims description 6
- 125000004435 hydrogen atom Chemical class [H]* 0.000 claims description 6
- 229910052757 nitrogen Inorganic materials 0.000 claims description 6
- 230000000740 bleeding effect Effects 0.000 claims description 5
- 125000004122 cyclic group Chemical group 0.000 claims description 5
- 239000007788 liquid Substances 0.000 claims description 5
- 238000005406 washing Methods 0.000 claims description 5
- 125000003368 amide group Chemical group 0.000 claims description 3
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 claims description 3
- 150000001875 compounds Chemical class 0.000 claims description 3
- 125000002887 hydroxy group Chemical group [H]O* 0.000 claims description 3
- 150000003242 quaternary ammonium salts Chemical class 0.000 claims description 3
- 229910019142 PO4 Inorganic materials 0.000 claims description 2
- 150000008052 alkyl sulfonates Chemical class 0.000 claims description 2
- 238000004140 cleaning Methods 0.000 claims description 2
- 239000010452 phosphate Substances 0.000 claims description 2
- 239000000835 fiber Substances 0.000 abstract description 14
- 210000004243 sweat Anatomy 0.000 abstract description 8
- 230000002209 hydrophobic effect Effects 0.000 abstract description 4
- 238000010521 absorption reaction Methods 0.000 abstract description 2
- 238000007599 discharging Methods 0.000 abstract description 2
- 230000010148 water-pollination Effects 0.000 abstract 2
- 239000002657 fibrous material Substances 0.000 abstract 1
- 239000000243 solution Substances 0.000 description 7
- 229940093430 polyethylene glycol 1500 Drugs 0.000 description 4
- 229920002994 synthetic fiber Polymers 0.000 description 4
- 239000012209 synthetic fiber Substances 0.000 description 4
- 229920002972 Acrylic fiber Polymers 0.000 description 3
- 230000008859 change Effects 0.000 description 3
- 230000018044 dehydration Effects 0.000 description 3
- 238000006297 dehydration reaction Methods 0.000 description 3
- 239000000203 mixture Substances 0.000 description 3
- 230000004048 modification Effects 0.000 description 3
- 238000012986 modification Methods 0.000 description 3
- 239000004753 textile Substances 0.000 description 3
- IQXJCCZJOIKIAD-UHFFFAOYSA-N 1-(2-methoxyethoxy)hexadecane Chemical compound CCCCCCCCCCCCCCCCOCCOC IQXJCCZJOIKIAD-UHFFFAOYSA-N 0.000 description 2
- 206010013786 Dry skin Diseases 0.000 description 2
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 2
- 239000004952 Polyamide Substances 0.000 description 2
- 229920002535 Polyethylene Glycol 1500 Polymers 0.000 description 2
- 239000004743 Polypropylene Substances 0.000 description 2
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 2
- 239000007864 aqueous solution Substances 0.000 description 2
- 230000009286 beneficial effect Effects 0.000 description 2
- 229950009789 cetomacrogol 1000 Drugs 0.000 description 2
- 238000006243 chemical reaction Methods 0.000 description 2
- 238000007872 degassing Methods 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 238000011156 evaluation Methods 0.000 description 2
- 238000002474 experimental method Methods 0.000 description 2
- 239000007791 liquid phase Substances 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 238000002156 mixing Methods 0.000 description 2
- 229920002647 polyamide Polymers 0.000 description 2
- 229920000728 polyester Polymers 0.000 description 2
- 229920002523 polyethylene Glycol 1000 Polymers 0.000 description 2
- 229920001155 polypropylene Polymers 0.000 description 2
- 238000009987 spinning Methods 0.000 description 2
- 238000012360 testing method Methods 0.000 description 2
- 229920002334 Spandex Polymers 0.000 description 1
- 239000005864 Sulphur Substances 0.000 description 1
- 229920004933 Terylene® Polymers 0.000 description 1
- 229910000147 aluminium phosphate Inorganic materials 0.000 description 1
- 239000012752 auxiliary agent Substances 0.000 description 1
- 238000007385 chemical modification Methods 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 238000005265 energy consumption Methods 0.000 description 1
- 238000003912 environmental pollution Methods 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- 238000001704 evaporation Methods 0.000 description 1
- 230000008020 evaporation Effects 0.000 description 1
- 238000010559 graft polymerization reaction Methods 0.000 description 1
- 238000007654 immersion Methods 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- 238000009940 knitting Methods 0.000 description 1
- 238000004806 packaging method and process Methods 0.000 description 1
- NBIIXXVUZAFLBC-UHFFFAOYSA-N phosphoric acid Substances OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 1
- 239000005020 polyethylene terephthalate Substances 0.000 description 1
- 239000004800 polyvinyl chloride Substances 0.000 description 1
- 229920000915 polyvinyl chloride Polymers 0.000 description 1
- 230000008569 process Effects 0.000 description 1
- 239000005871 repellent Substances 0.000 description 1
- 239000004759 spandex Substances 0.000 description 1
- 239000002912 waste gas Substances 0.000 description 1
- 239000002351 wastewater Substances 0.000 description 1
- 239000002759 woven fabric Substances 0.000 description 1
Classifications
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M10/00—Physical treatment of fibres, threads, yarns, fabrics, or fibrous goods made from such materials, e.g. ultrasonic, corona discharge, irradiation, electric currents, or magnetic fields; Physical treatment combined with treatment with chemical compounds or elements
- D06M10/04—Physical treatment combined with treatment with chemical compounds or elements
- D06M10/08—Organic compounds
- D06M10/10—Macromolecular compounds
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M10/00—Physical treatment of fibres, threads, yarns, fabrics, or fibrous goods made from such materials, e.g. ultrasonic, corona discharge, irradiation, electric currents, or magnetic fields; Physical treatment combined with treatment with chemical compounds or elements
- D06M10/02—Physical treatment of fibres, threads, yarns, fabrics, or fibrous goods made from such materials, e.g. ultrasonic, corona discharge, irradiation, electric currents, or magnetic fields; Physical treatment combined with treatment with chemical compounds or elements ultrasonic or sonic; Corona discharge
- D06M10/025—Corona discharge or low temperature plasma
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
- D06M11/32—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond
- D06M11/36—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond with oxides, hydroxides or mixed oxides; with salts derived from anions with an amphoteric element-oxygen bond
- D06M11/38—Oxides or hydroxides of elements of Groups 1 or 11 of the Periodic Table
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/53—Polyethers
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
- D06M2101/16—Synthetic fibres, other than mineral fibres
- D06M2101/18—Synthetic fibres consisting of macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- D06M2101/26—Polymers or copolymers of unsaturated carboxylic acids or derivatives thereof
- D06M2101/28—Acrylonitrile; Methacrylonitrile
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
- D06M2101/16—Synthetic fibres, other than mineral fibres
- D06M2101/30—Synthetic polymers consisting of macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- D06M2101/32—Polyesters
Landscapes
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Physics & Mathematics (AREA)
- Plasma & Fusion (AREA)
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Chemical Or Physical Treatment Of Fibers (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
Abstract
The invention discloses a kind of method of modifying to fabric face, it is graft-polymerized including being combined by the surface treatment of microwave plasma dry type and chemical assistant, so that fiber and its fabric have higher hydrophily, so as to possess moisture absorption sweat discharging functions, mainly include microwave plasma surface activation process, dip finishing agent graft crosslinking, Miccrowave plasma polymerization.The present invention passes through the surface treatment of microwave plasma dry type and chemical assistant is combined and is graft-polymerized so that hydrophobic fibrous material or fabric possess hydrophily, and repeatedly wash and still can show excellent performance.
Description
Technical field
The present invention relates to a kind of method of modifying to fabric face.
Background technology
With the improvement of people ' s living standards, the development of garment material progressively turns to comfortableness and feature, synthetic fibers
Its excellent performance has obtained the welcome of consumers in general, especially fine with hydrophobicitys such as polyester fiber, polyamide fibre, polypropylene fibre, acrylic fibers
Wesy's amount is very big, but this this kind of fiber possesses hydrophobicity, thus regain is low, hygroscopicity is weak, is worn in people's daily life
This kind of clothes, largely motion causes dress sultry uncomfortable because the sweat that human skin produces can not be excluded, meanwhile,
Low hygroscopicity is easy to assemble a large amount of electric charges generation electrostatic, therefore it is especially heavy that water-repellent fabrics are carried out with moisture absorption sweat discharging functions modification
Will.
At present, the moisture absorbing and sweat releasing of hydrophobic fabric is modified, mainly three kinds modes：
The first, the physical modification of fiber.When preparing synthetic fibers, by changing the shape of spinning nozzle, increase fiber
Surface area, moisture is preserved using the increased groove of fiber surface as far as possible, while increasing fiber surface is also beneficial to moisture
Evaporation and dissipation.
Second of chemical modification.Final finishing modification is carried out using the chemical assistant containing hydrophilic radical, in Final finishing
During can produce a large amount of waste water, waste gas, energy consumption is big, and environmental pollution is serious.
The third blending or the change of fabric structure.Blending is carried out by the fiber of synthetic fibers and high-hygroscopicity
Increase the moisture absorbing and sweat releasing performance of fabric.
The content of the invention
The technical problems to be solved by the invention are to provide a kind of be surface-treated by microwave plasma dry type and chemistry
Auxiliary agent joint is graft-polymerized, and repeatedly washs and still can show excellent performance.
The present invention is achieved through the following technical solutions：A kind of method of modifying to fabric face, including by micro-
Ripple plasma dry is surface-treated and chemical assistant combines graft polymerization, is mainly included at microwave plasma surface active
Reason, dip finishing agent graft crosslinking, Miccrowave plasma polymerization.
Comprise the following steps that：
Step 1: fabric pre-treatment：Alkalescence (solution such as NaOH, KOH etc., including but not limited to) immersion certain time, then
Neutralized and cleaned with weak acid, is then dehydrated, then dry for standby；
Step 2: surface active：Fabric after pre-treatment is put into microwave plasma reative cell, body vacuum is taken out and exists
5Pa-120Pa, with 0.6L/h-10L/h flow be passed through non-polymeric class gas air, oxygen, nitrogen, hydrogen, argon gas, helium,
Several mixed gas of vapor one of which or more, opens microwave source switch and excites microwave plasma to carry out fabric face work
Change and reative cell vacuum is kept in 0.5min-10min, processing procedure in 20Pa-320Pa；
Step 3: configuration 0.5wt%-20wt% hydrophilic modifier, 5g/L-30g/L JFC bleeding agents, by bath raio 1：5-
1：40, the fabric 10min-120min after 30-60 degree water bath with thermostatic control impregnating actives, take out, are dehydrated, and are 2455MHz in frequency
Rotary microwave drier in drying 0.5min-8min cause liquid carrying rate in 10%-60%；
Step 4: plasma polymerization：Preliminary drying fabric is placed in microwave plasma reative cell, body vacuum is taken out and exists
10-300Pa, is passed through non-polymeric class gas air, oxygen, nitrogen, hydrogen, argon gas, helium gas and water with 1L/h-6L/h flow and steams
Several mixed gas of gas one of which or more, opens microwave source switch and excites microwave plasma to carry out fabric face activation
Reative cell vacuum is kept in 3min-12min, processing procedure in 50Pa-280Pa；
Step 5: hot water wash：By the fabric after plasma polymerization in 80-100 DEG C of hot water cyclic washing
It is dehydrated after 0.5min-3min, is placed in the rotary microwave drier that frequency is 2455MHz and dries.
As preferred technical scheme, hydrophilic modifier is to contain carboxyl, hydroxyl, amide groups, amino, carbonyl, alkyl sulphur
The compound one of which or wherein several combination solutions of the hydrophilic radicals such as hydrochlorate, alkyl phosphate or quaternary ammonium salt.
The beneficial effects of the invention are as follows：It is poly- by the surface treatment of microwave plasma dry type and chemical assistant joint grafting
Close so that hydrophobic synthetic fibers have higher moisture absorbing and sweat releasing performance, and repeatedly wash still can show it is excellent
Performance.
Brief description of the drawings
In order to illustrate more clearly about the embodiment of the present invention or technical scheme of the prior art, below will be to embodiment or existing
There is the accompanying drawing used required in technology description to be briefly described, it should be apparent that, drawings in the following description are only this
Some embodiments of invention, for those of ordinary skill in the art, on the premise of not paying creative work, can be with
Other accompanying drawings are obtained according to these accompanying drawings.
Fig. 1 is process chart of the invention.
Embodiment
All features disclosed in this specification, or disclosed all methods or during the step of, except mutually exclusive
Feature and/or step beyond, can combine in any way.
Any feature disclosed in this specification (including any accessory claim, summary and accompanying drawing), except non-specifically is chatted
State, can alternative features equivalent by other or with similar purpose replaced.I.e., unless specifically stated otherwise, each feature
It is an example in a series of equivalent or similar characteristics.
As shown in figure 1, including pretreatment, microwave plasma surface activation process, dip finishing agent graft crosslinking, microwave
Plasma polymerization, microwave drying, hot water cleaning and clear water rinse dewatered drying, packaging, comprise the following steps that：Institute of the present invention
The hydrophobic fabric being related to is referred to by regain less than 4.5%, the textile material that hygroscopicity is weaker, including polyester fiber, polyamide fibre,
The pure spinning of spandex, polypropylene fibre, polyvinyl chloride fibre, acrylic fibers one of which or several blend fabric.
1. fabric pre-treatment：5g/L-20g/L sodium hydroxide solutions handle fabric 10min-40min at 80-100 DEG C, weak
Acid is neutralized, then is cleaned, and dewatered drying is standby；
2. surface active：Fabric after pre-treatment is put into microwave plasma reative cell, body vacuum is taken out in 5Pa-
120Pa, is passed through non-polymeric class gas air, oxygen, nitrogen, hydrogen, argon gas, helium gas and water with 0.6L/h-10L/h flow and steams
Several mixed gas of gas one of which or more, opens microwave source switch and excites microwave plasma to carry out fabric face activation
Reative cell vacuum is kept in 0.5min-10min, processing procedure in 20Pa-320Pa；
3. impregnate hydrophilic modifier：0.5wt%-20wt% hydrophilic modifier, 5g/L-30g/L JFC bleeding agents is configured,
By bath raio 1：5-1：40, the fabric 10min-120min after 30-60 degree water bath with thermostatic control impregnating actives, take out, are dehydrated, in frequency
Cause liquid carrying rate in 10%-60% to dry 0.5min-8min in 2455MHz rotary microwave drier；
Above-mentioned hydrophilic modifier is to contain carboxyl, hydroxyl, amide groups, amino, carbonyl, alkylsulfonate, alkyl phosphoric acid
The compound one of which or wherein several combination solutions of the hydrophilic radical such as ester or quaternary ammonium salt；
4. preliminary drying fabric is placed in microwave plasma reative cell by plasma polymerization, body vacuum is taken out in 10-
300Pa, with 1L/h-6L/h flow be passed through non-polymeric class gas air, oxygen, nitrogen, hydrogen, argon gas, helium, vapor its
In one or more of several mixed gas, open microwave source switch and excite microwave plasma to carry out fabric face activation 3min-
Reative cell vacuum is kept in 12min, processing procedure in 50Pa-280Pa；
5. hot water wash by the fabric after plasma polymerization 80-100 degree hot water wash cyclic washing 0.5min-
It is dehydrated after 3min, is placed in the rotary microwave drier that frequency is 2455MHz and dries.
Embodiment 1
Example is modified as with terylene woven fabric moisture absorbing and sweat releasing.
1. fabric pre-treatment：5g/L sodium hydroxide solutions handle fabric 30min under 100 degree, and weak acid is neutralized, then cleans de-
Water dry for standby.
2. surface active：Fabric after pre-treatment is put into microwave plasma reative cell, body vacuum is taken out in 5Pa,
Oxygen is passed through with 4L/h flow, microwave source switch is opened and excites microwave plasma to carry out fabric face activation 3min, treat
Reative cell vacuum is kept in journey in 80Pa.
3. impregnate hydrophilic modifier：2wt% hydrophilic modifier, 10g/L JFC bleeding agents is configured, by bath raio 1：30, adopt
With liquid phase degassing method in the way of negative pressure is sucked by modifying agent sucting reaction room, 60 DEG C of constant temperature impregnate 120min, take out, dehydration,
Drying 1min causes liquid carrying rate 10% in frequency is 2455MHz rotary microwave drier.
Above-mentioned hydrophilic modifier is the mixture of cetomacrogol 1000 (PEG1000) and polyethylene glycol 1500 (PEG1500)
The aqueous solution, ratio is 6:4.
Preliminary drying fabric is placed in microwave plasma reative cell by 4 plasma polymerizations, body vacuum is taken out in 5Pa, with 2L/
H flow is passed through argon gas, opens microwave source switch and excites microwave plasma protected in fabric face polymerization 5min, processing procedure
Reative cell vacuum is held in 60Pa.
5. the fabric after plasma polymerization is dehydrated by hot water wash after 80 DEG C of hot water wash cyclic washing 3min, put
Dried in frequency is 2455MHz rotary microwave drier.
After above-mentioned flow, according to national standard GB T 21655.1-2008 textile absorbing fast-dryings evaluation the 1st
Divide the test of individual event combination experiment method.Its result meets the technical indicator (see the table below 1) of the standard.
Table 1
Embodiment 2
Example is modified as with acrylic fibers knitting fabric moisture absorbing and sweat releasing.
1. fabric pre-treatment：5g/L sodium hydroxide solutions handle fabric 30min under 100 degree, and weak acid is neutralized, dehydration, 100
Spend dry for standby.
2. surface active：Acrylic fabric after pre-treatment is put into microwave plasma reative cell, body vacuum is taken out and exists
5Pa, oxygen is passed through with 4L/h flow, is opened microwave source switch and is excited microwave plasma to carry out fabric face activation 2 minutes 20
Second, reative cell vacuum is kept in processing procedure in 60Pa.
3. impregnate hydrophilic modifier：5wt% hydrophilic modifier, 10g/L JFC bleeding agents is configured, by bath raio 1：30, adopt
With liquid phase degassing method in the way of negative pressure is sucked by modifying agent sucting reaction room, 60 degree of constant temperature impregnate 100 minutes, take out, dehydration,
Drying causes acrylic fabric liquid carrying rate 10% for 15 seconds 1 minute in frequency is 2455MHz rotary microwave drier.
Above-mentioned hydrophilic modifier is the mixture of cetomacrogol 1000 (PEG1000) and polyethylene glycol 1500 (PEG1500)
The aqueous solution, than being classified as 6:4.
Preliminary drying fabric is placed in microwave plasma reative cell by 4 plasma polymerizations, body vacuum is taken out in 5Pa, with 3L/
H flow is passed through argon gas, opens microwave source switch and excites microwave plasma protected in fabric face polymerization 8min, processing procedure
Reative cell vacuum is held in 40Pa.
6. the fabric after plasma polymerization is dehydrated by hot water wash after 80 degree of hot water wash cyclic washing 3min, put
Dried in frequency is 2455MHz rotary microwave drier.
After above-mentioned flow, according to national standard GB T 21655.1-2008 textile absorbing fast-dryings evaluation the 1st
Divide the test of individual event combination experiment method.Its result meets the technical indicator (see the table below 2) of the standard.
Table 2
The foregoing is only a specific embodiment of the invention, but protection scope of the present invention is not limited thereto, any
The change or replacement expected without creative work, should all be included within the scope of the present invention.Therefore, it is of the invention
Protection domain should be determined by the scope of protection defined in the claims.
Claims (3)
1. a kind of method of modifying to fabric face, it is characterised in that：Including by microwave plasma dry type surface treatment and
Chemical assistant joint is graft-polymerized, and mainly includes microwave plasma surface activation process, dip finishing agent graft crosslinking, microwave
Plasma polymerization.
2. the method for modifying as claimed in claim 1 to fabric face, it is characterised in that：Comprise the following steps that：
Step 1: fabric pre-treatment：NaOH (alkalescence) solution soaks certain time, then with cleaning and being neutralized with weak acid, then dries
Dry standby, weak acid is neutralized, and is dehydrated and dry for standby；
Step 2: surface active：Fabric after pre-treatment is put into microwave plasma reative cell, body vacuum is taken out in 5Pa-
120Pa, is passed through non-polymeric class gas, such as with 0.6L/h-10L/h flow：Air, oxygen, nitrogen, hydrogen, argon gas, helium,
One or more of mixed gas in vapor, open microwave source switch and excite microwave plasma to carry out fabric face activation
Reative cell vacuum is kept in 0.5min-10min, processing procedure in 20Pa-320Pa；
Step 3: configuration 0.5wt%-20wt% hydrophilic modifier, 5g/L-30g/L JFC bleeding agents, by bath raio 1：5-1：
40, the fabric 10min-120min after 30-60 degree water bath with thermostatic control impregnating actives, take out, are dehydrated, and are 2455MHz's in frequency
0.5min-8min is dried in rotary microwave drier causes liquid carrying rate in 10%-60%；
Step 4: plasma polymerization：Preliminary drying fabric is placed in microwave plasma reative cell, base vacuum is taken out to 10-
300Pa, non-polymeric class gas is passed through with 1L/h-6L/h flow, and such as air, oxygen, nitrogen, hydrogen, argon gas, helium gas and water are steamed
One or more of mixed gas in gas, open microwave source switch and excite microwave plasma to carry out fabric face activation 3min-
Reative cell vacuum is kept in 12min, processing procedure in 50Pa-280Pa；
Step 5: hot water wash：By the fabric after plasma polymerization in 80-100 DEG C of hot water cyclic washing 0.5min-
It is dehydrated after 3min, is placed in the rotary microwave drier that frequency is 2455MHz and dries.
3. the method for modifying as claimed in claim 2 to fabric face, it is characterised in that：Hydrophilic modifier be containing carboxyl,
The compound of the hydrophilic radicals such as hydroxyl, amide groups, amino, carbonyl, alkylsulfonate, alkyl phosphate or quaternary ammonium salt wherein one
Plant or wherein several combination solutions.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710507192.9A CN107142713A (en) | 2017-06-28 | 2017-06-28 | A kind of method of modifying to fabric face |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710507192.9A CN107142713A (en) | 2017-06-28 | 2017-06-28 | A kind of method of modifying to fabric face |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN107142713A true CN107142713A (en) | 2017-09-08 |
Family
ID=59785139
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201710507192.9A Pending CN107142713A (en) | 2017-06-28 | 2017-06-28 | A kind of method of modifying to fabric face |
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Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108858974A (en) * | 2018-05-31 | 2018-11-23 | 宁波帅特龙集团有限公司 | A kind of preparation method of car door handle |
| CN108914327A (en) * | 2018-07-18 | 2018-11-30 | 广西南宁桂尔创环保科技有限公司 | A kind of antibiotic radiation proof silk fabric and preparation method thereof |
| CN109651942A (en) * | 2018-12-14 | 2019-04-19 | 江苏盛纳凯尔医用科技有限公司 | A kind of preparation method of super hydrophilic antimicrobial coating |
| CN110629569A (en) * | 2018-06-22 | 2019-12-31 | 广东欣丰科技有限公司 | Fabric coloring method and colored fabric |
| CN113862990A (en) * | 2021-09-18 | 2021-12-31 | 东华大学 | Modified fiber fabric and preparation method thereof |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1171412A (en) * | 1996-06-19 | 1998-01-28 | 希尔斯股份公司 | Hydrophilic coating surfaces of polymeric substrates |
| CN1380460A (en) * | 2001-04-12 | 2002-11-20 | 中国科学院化学研究所 | Superamphipathatic fabric fibre and its preparation method and application |
| CN101148821A (en) * | 2007-11-07 | 2008-03-26 | 陈成泗 | Chemical fiber plus material normal pressure plasma treatment method |
| CN102061610A (en) * | 2009-11-13 | 2011-05-18 | 北京服装学院 | Finishing method for improving hydrophilicity of polyester fabric |
-
2017
- 2017-06-28 CN CN201710507192.9A patent/CN107142713A/en active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1171412A (en) * | 1996-06-19 | 1998-01-28 | 希尔斯股份公司 | Hydrophilic coating surfaces of polymeric substrates |
| CN1380460A (en) * | 2001-04-12 | 2002-11-20 | 中国科学院化学研究所 | Superamphipathatic fabric fibre and its preparation method and application |
| CN101148821A (en) * | 2007-11-07 | 2008-03-26 | 陈成泗 | Chemical fiber plus material normal pressure plasma treatment method |
| CN102061610A (en) * | 2009-11-13 | 2011-05-18 | 北京服装学院 | Finishing method for improving hydrophilicity of polyester fabric |
Non-Patent Citations (8)
| Title |
|---|
| 倪红: "《服装材料学》", 31 December 2016, 中国纺织出版社 * |
| 张高会主编: "《中级物理实验》", 31 January 2014, 兵器工业出版社 * |
| 王国全: "《聚合物改性》", 31 May 2017, 中国轻工业出版社 * |
| 王际平等: "《中国纺织品整理及进展 第二卷》", 31 May 2015, 中国轻工业出版社 * |
| 赵青: "《等离子体技术及应用》", 28 February 2009, 国防工业出版社 * |
| 陈森: "涤纶织物的低温等离子体表面亲水化改性", 《万方数据知识服务平台》 * |
| 陈英等: "等离子体接枝反应对涤纶织物亲水性能的影响", 《纺织学报》 * |
| 高淑珍等: "《生态染整技术》", 30 June 2003, 化学工业出版社 * |
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108858974A (en) * | 2018-05-31 | 2018-11-23 | 宁波帅特龙集团有限公司 | A kind of preparation method of car door handle |
| CN110629569A (en) * | 2018-06-22 | 2019-12-31 | 广东欣丰科技有限公司 | Fabric coloring method and colored fabric |
| US11505860B2 (en) | 2018-06-22 | 2022-11-22 | Guangdong Rising Well Science & Technology Co., Ltd. | Fabric coloring method and colored fabric |
| CN108914327A (en) * | 2018-07-18 | 2018-11-30 | 广西南宁桂尔创环保科技有限公司 | A kind of antibiotic radiation proof silk fabric and preparation method thereof |
| CN109651942A (en) * | 2018-12-14 | 2019-04-19 | 江苏盛纳凯尔医用科技有限公司 | A kind of preparation method of super hydrophilic antimicrobial coating |
| CN113862990A (en) * | 2021-09-18 | 2021-12-31 | 东华大学 | Modified fiber fabric and preparation method thereof |
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