CN107141856A - A kind of preparation method with superpower radiation proof new material - Google Patents
A kind of preparation method with superpower radiation proof new material Download PDFInfo
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- CN107141856A CN107141856A CN201710294153.5A CN201710294153A CN107141856A CN 107141856 A CN107141856 A CN 107141856A CN 201710294153 A CN201710294153 A CN 201710294153A CN 107141856 A CN107141856 A CN 107141856A
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D4/00—Coating compositions, e.g. paints, varnishes or lacquers, based on organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond ; Coating compositions, based on monomers of macromolecular compounds of groups C09D183/00 - C09D183/16
- C09D4/06—Organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond in combination with a macromolecular compound other than an unsaturated polymer of groups C09D159/00 - C09D187/00
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D1/00—Coating compositions, e.g. paints, varnishes or lacquers, based on inorganic substances
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/18—Fireproof paints including high temperature resistant paints
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Abstract
The invention discloses a kind of preparation method with superpower radiation proof new material, comprise the following steps, S1：Raw material is weighed；S2：Preliminary operation；S3：Add powder；S4：Agitating procedure；S5：Solvent is added；S6：Merge process；S7：Molding procedure；The present invention is by adding organosilicon, dipentaerythritol, ethoxy ethanol, titanium dioxide, ceramic, novolac epoxy resin, acrylic acid double cyclopentenyl oxygen ethyl ester, alkali metal compound, curing agent and organic solvent, and this is reasonably processed, cooperated between each component, have complementary advantages, radiation protection ability can effectively be lifted, but also with price and environment-friendly advantage, and adhesive force is strong, ductility is good, high temperature resistant, service life are long, and application prospect is wide.
Description
Technical field
The present invention relates to radiation protection technology field, specially a kind of preparation method with superpower radiation proof new material.
Background technology
Radiation proof material turn into current material subject a big problem, with various high radiation devices appearance and extensively
Using the research of radiation proof material has caused the common concern of people.What the Japanese violent earthquake on March 11st, 2011 was triggered
Fukushima nuclear power station crisis, has also triggered people to the worry of nuclear radiation；And various radiation sources are present in people's life, also compel to make one
Attention to radiation proof material；Radiation is classified as the fourth-largest environment after water source, air, noise by the World Health Organization
Pollution sources, the stealth " killer " as harm human health, protection radiation turns into the task of top priority.
At present, radiation shielding coating is used mostly adds heavy metal or rare metal powder and its oxygen in coating composition
Compound, especially containing metallic compounds such as Ba, Pb, U, Lu, or uses composite deposite, but necessarily also brings constructional difficulties, attached
Put forth effort not enough, while the function defect such as not enough, thus radiation shielding coating also only applied in some special industries and special dimension, and
Using less in the fields such as the life of people, therefore it is badly in need of a kind of radiation proof material that use new material is made to meet people
The need for.
The content of the invention
It is an object of the invention to provide a kind of preparation method with superpower radiation proof new material, to solve above-mentioned background
The problem of being proposed in technology.
To achieve the above object, the present invention provides following technical scheme：A kind of preparation with superpower radiation proof new material
Method, comprises the following steps,
S1：Raw material is weighed, by organosilicon, dipentaerythritol, ethoxy ethanol, titanium dioxide, ceramic, novolac epoxy resin,
Acrylic acid double cyclopentenyl oxygen ethyl ester, alkali metal compound, curing agent and organic solvent are weighed according to certain ratio
Take；
S2：Preliminary operation, by load weighted dipentaerythritol, ethoxy ethanol, novolac epoxy resin and the bicyclic amylene of acrylic acid
Base oxygen ethyl ester is placed in same stirring vessel, then starts stirring, and whipping temp is 40-80 degree, and 10- is stirred clockwise
15 minutes, stirring 10-15 minutes, so stirred 3-8 times, obtain first part of raw material repeatedly counterclockwise；
S3：Powder is added, titanium dioxide and ceramic are added in first part of raw material, uniform stirring is carried out first, and
With ultrasonic disperse 30-40 minutes, second part of raw material is obtained；
S4：Agitating procedure, organosilicon and alkali metal compound are put into Mixing Machine, mixed, and the mixing is
Agitated machine is stirred with 500-800r/min speed and mixed, and obtains the 3rd part of raw material；
S5：Solvent is added, and adds organic solvents into the 3rd part of raw material, uniform stirring is then carried out again, mixing time is 15-
25 minutes, whipping temp 20-30 degree obtained the 4th part of raw material；
S6：Process is merged, second part of raw material and the 4th part of raw material are put together, and ultrasound is stirred under conditions of 40-80 degree
Mix 50-90 minutes；
S7：In molding procedure, the mixture that curing agent is put into second part of raw material and the 4th part of raw material, then finally stirred
Mix, clockwise stirring 30-45 minutes, counterclockwise stirring 30-50 minutes, so stir 5-10 times repeatedly, whipping temp is 50-
100 degree, the radiation proof material is finally made.
It is preferred that, organosilicon, dipentaerythritol, ethoxy ethanol, titanium dioxide, ceramic, phenolic aldehyde in the step S1
Mass ratio between epoxy resin, organic solvent, acrylic acid double cyclopentenyl oxygen ethyl ester, alkali metal compound and curing agent
For：Organosilicon 5-9%, dipentaerythritol 2-7%, ethoxy ethanol 3-10%, titanium dioxide 5-15%, ceramic 3-8%, phenolic aldehyde ring
Oxygen tree fat 2-5%, acrylic acid double cyclopentenyl oxygen ethyl ester 8-16%, alkali metal compound 10-18% and curing agent 1-4%, remaining
For organic solvent.
It is preferred that, the alkali metal compound in the step S1 is the mixture of magnesium sulfate, calcium sulfate and barium sulfate.
It is preferred that, the organic solvent in the step S1 is in ethyl acetate, butyl acetate, acetic acid alcohol and in ethylene glycol first
One kind.
Compared with prior art, the beneficial effects of the invention are as follows：The present invention is by adding organosilicon, dipentaerythritol, second
Ethoxy-ethanol, titanium dioxide, ceramic, novolac epoxy resin, acrylic acid double cyclopentenyl oxygen ethyl ester, alkali metal compound,
Curing agent and organic solvent, and this is reasonably processed, cooperated between each component, have complementary advantages, can effectively carry
Radiation protection ability is risen, but also with price and environment-friendly advantage, and adhesive force is strong, ductility is good, high temperature resistant, service life
Long, application prospect is wide.
Embodiment
The technical scheme in the embodiment of the present invention is clearly and completely described below in conjunction with the embodiment of the present invention,
Obviously, described embodiment is only a part of embodiment of the invention, rather than whole embodiments.Based in the present invention
Embodiment, the every other embodiment that those of ordinary skill in the art are obtained under the premise of creative work is not made, all
Belong to the scope of protection of the invention.
Embodiment one
The present invention provides a kind of technical scheme：A kind of preparation method with superpower radiation proof new material, comprises the following steps,
S1：Raw material is weighed, by organosilicon, dipentaerythritol, ethoxy ethanol, titanium dioxide, ceramic, novolac epoxy resin,
Acrylic acid double cyclopentenyl oxygen ethyl ester, alkali metal compound, curing agent and organic solvent are weighed according to certain ratio
Take；
S2：Preliminary operation, by load weighted dipentaerythritol, ethoxy ethanol, novolac epoxy resin and the bicyclic amylene of acrylic acid
Base oxygen ethyl ester is placed in same stirring vessel, then starts stirring, and whipping temp is 40 degree, 10 points of stirring clockwise
Clock, stirring 10 minutes, so stir 3 times, obtain first part of raw material repeatedly counterclockwise；
S3：Powder is added, titanium dioxide and ceramic are added in first part of raw material, uniform stirring is carried out first, and
With ultrasonic disperse 30 minutes, second part of raw material is obtained；
S4：Agitating procedure, organosilicon and alkali metal compound are put into Mixing Machine, mixed, and the mixing is
Agitated machine is stirred with 500r/min speed and mixed, and obtains the 3rd part of raw material；
S5：Solvent is added, and adds organic solvents into the 3rd part of raw material, uniform stirring is then carried out again, mixing time is 15
Minute, 20 degree of whipping temp obtains the 4th part of raw material；
S6：Process is merged, second part of raw material and the 4th part of raw material are put together, and the ultrasonic agitation 50 under conditions of 40 degree
Minute；
S7：In molding procedure, the mixture that curing agent is put into second part of raw material and the 4th part of raw material, then finally stirred
Mix, clockwise stirring 30 minutes, counterclockwise stirring 30 minutes, so stir 5 times repeatedly, whipping temp is 50 degree, final to be made
The radiation proof material.
Organosilicon in step S1, dipentaerythritol, ethoxy ethanol, titanium dioxide, ceramic, novolac epoxy resin, have
Mass ratio between machine solvent, acrylic acid double cyclopentenyl oxygen ethyl ester, alkali metal compound and curing agent is：Organosilicon 5%,
Dipentaerythritol 2%, ethoxy ethanol 3%, titanium dioxide 5%, ceramic 3%, novolac epoxy resin 2%, acrylic acid double cyclopentenyl
Oxygen ethyl ester 8%, alkali metal compound 10% and curing agent 1%, remaining is organic solvent.
Alkali metal compound in step S1 is the mixture of magnesium sulfate, calcium sulfate and barium sulfate.
Organic solvent in step S1 is ethyl acetate.
Embodiment two
The present invention provides a kind of technical scheme：A kind of preparation method with superpower radiation proof new material, comprises the following steps,
S1：Raw material is weighed, by organosilicon, dipentaerythritol, ethoxy ethanol, titanium dioxide, ceramic, novolac epoxy resin,
Acrylic acid double cyclopentenyl oxygen ethyl ester, alkali metal compound, curing agent and organic solvent are weighed according to certain ratio
Take；
S2：Preliminary operation, by load weighted dipentaerythritol, ethoxy ethanol, novolac epoxy resin and the bicyclic amylene of acrylic acid
Base oxygen ethyl ester is placed in same stirring vessel, then starts stirring, and whipping temp is 50 degree, 11 points of stirring clockwise
Clock, stirring 11 minutes, so stir 4 times, obtain first part of raw material repeatedly counterclockwise；
S3：Powder is added, titanium dioxide and ceramic are added in first part of raw material, uniform stirring is carried out first, and
With ultrasonic disperse 32 minutes, second part of raw material is obtained；
S4：Agitating procedure, organosilicon and alkali metal compound are put into Mixing Machine, mixed, and the mixing is
Agitated machine is stirred with 550r/min speed and mixed, and obtains the 3rd part of raw material；
S5：Solvent is added, and adds organic solvents into the 3rd part of raw material, uniform stirring is then carried out again, mixing time is 17
Minute, 23 degree of whipping temp obtains the 4th part of raw material；
S6：Process is merged, second part of raw material and the 4th part of raw material are put together, and the ultrasonic agitation 60 under conditions of 50 degree
Minute；
S7：In molding procedure, the mixture that curing agent is put into second part of raw material and the 4th part of raw material, then finally stirred
Mix, clockwise stirring 35 minutes, counterclockwise stirring 36 minutes, so stir 7 times repeatedly, whipping temp is 65 degree, final to be made
The radiation proof material.
Organosilicon in step S1, dipentaerythritol, ethoxy ethanol, titanium dioxide, ceramic, novolac epoxy resin, have
Mass ratio between machine solvent, acrylic acid double cyclopentenyl oxygen ethyl ester, alkali metal compound and curing agent is：Organosilicon 7%,
Dipentaerythritol 4%, ethoxy ethanol 5%, titanium dioxide 8%, ceramic 5%, novolac epoxy resin 3%, acrylic acid double cyclopentenyl
Oxygen ethyl ester 10%, alkali metal compound 12% and curing agent 2%, remaining is organic solvent.
Alkali metal compound in step S1 is the mixture of magnesium sulfate, calcium sulfate and barium sulfate.
Organic solvent in step S1 is butyl acetate.
Embodiment three
The present invention provides a kind of technical scheme：A kind of preparation method with superpower radiation proof new material, comprises the following steps,
S1：Raw material is weighed, by organosilicon, dipentaerythritol, ethoxy ethanol, titanium dioxide, ceramic, novolac epoxy resin,
Acrylic acid double cyclopentenyl oxygen ethyl ester, alkali metal compound, curing agent and organic solvent are weighed according to certain ratio
Take；
S2：Preliminary operation, by load weighted dipentaerythritol, ethoxy ethanol, novolac epoxy resin and the bicyclic amylene of acrylic acid
Base oxygen ethyl ester is placed in same stirring vessel, then starts stirring, and whipping temp is 70 degree, 14 points of stirring clockwise
Clock, stirring 14 minutes, so stir 6 times, obtain first part of raw material repeatedly counterclockwise；
S3：Powder is added, titanium dioxide and ceramic are added in first part of raw material, uniform stirring is carried out first, and
With ultrasonic disperse 35 minutes, second part of raw material is obtained；
S4：Agitating procedure, organosilicon and alkali metal compound are put into Mixing Machine, mixed, and the mixing is
Agitated machine is stirred with 700r/min speed and mixed, and obtains the 3rd part of raw material；
S5：Solvent is added, and adds organic solvents into the 3rd part of raw material, uniform stirring is then carried out again, mixing time is 23
Minute, 28 degree of whipping temp obtains the 4th part of raw material；
S6：Process is merged, second part of raw material and the 4th part of raw material are put together, and ultrasound is stirred under conditions of 40-80 degree
Mix 80 minutes；
S7：In molding procedure, the mixture that curing agent is put into second part of raw material and the 4th part of raw material, then finally stirred
Mix, clockwise stirring 41 minutes, counterclockwise stirring 45 minutes, so stir 8 times repeatedly, whipping temp is 90 degree, final to be made
The radiation proof material.
Organosilicon in step S1, dipentaerythritol, ethoxy ethanol, titanium dioxide, ceramic, novolac epoxy resin, have
Mass ratio between machine solvent, acrylic acid double cyclopentenyl oxygen ethyl ester, alkali metal compound and curing agent is：Organosilicon 8%,
Dipentaerythritol 6%, ethoxy ethanol 8%, titanium dioxide 12%, ceramic 6%, novolac epoxy resin 3%, the bicyclic amylene of acrylic acid
Base oxygen ethyl ester 14%, alkali metal compound 16% and curing agent 3%, remaining is organic solvent.
Alkali metal compound in step S1 is the mixture of magnesium sulfate, calcium sulfate and barium sulfate.
Organic solvent in step S1 is in acetic acid alcohol.
Example IV
The present invention provides a kind of technical scheme：A kind of preparation method with superpower radiation proof new material, comprises the following steps,
S1：Raw material is weighed, by organosilicon, dipentaerythritol, ethoxy ethanol, titanium dioxide, ceramic, novolac epoxy resin,
Acrylic acid double cyclopentenyl oxygen ethyl ester, alkali metal compound, curing agent and organic solvent are weighed according to certain ratio
Take；
S2：Preliminary operation, by load weighted dipentaerythritol, ethoxy ethanol, novolac epoxy resin and the bicyclic amylene of acrylic acid
Base oxygen ethyl ester is placed in same stirring vessel, then starts stirring, and whipping temp is 80 degree, 15 points of stirring clockwise
Clock, stirring 15 minutes, so stir 8 times, obtain first part of raw material repeatedly counterclockwise；
S3：Powder is added, titanium dioxide and ceramic are added in first part of raw material, uniform stirring is carried out first, and
With ultrasonic disperse 40 minutes, second part of raw material is obtained；
S4：Agitating procedure, organosilicon and alkali metal compound are put into Mixing Machine, mixed, and the mixing is
Agitated machine is stirred with 800r/min speed and mixed, and obtains the 3rd part of raw material；
S5：Solvent is added, and adds organic solvents into the 3rd part of raw material, uniform stirring is then carried out again, mixing time is 25
Minute, 30 degree of whipping temp obtains the 4th part of raw material；
S6：Process is merged, second part of raw material and the 4th part of raw material are put together, and the ultrasonic agitation 90 under conditions of 80 degree
Minute；
S7：In molding procedure, the mixture that curing agent is put into second part of raw material and the 4th part of raw material, then finally stirred
Mix, clockwise stirring 45 minutes, counterclockwise stirring 50 minutes, so stir 10 times repeatedly, whipping temp is 100 degree, final system
Obtain the radiation proof material.
Organosilicon in step S1, dipentaerythritol, ethoxy ethanol, titanium dioxide, ceramic, novolac epoxy resin, have
Mass ratio between machine solvent, acrylic acid double cyclopentenyl oxygen ethyl ester, alkali metal compound and curing agent is：Organosilicon 9%,
Dipentaerythritol 7%, ethoxy ethanol 10%, titanium dioxide 15%, ceramic 8%, novolac epoxy resin 5%, the bicyclic amylene of acrylic acid
Base oxygen ethyl ester 16%, alkali metal compound 18% and curing agent 4%, remaining is organic solvent.
Alkali metal compound in step S1 is the mixture of magnesium sulfate, calcium sulfate and barium sulfate.
Organic solvent in step S1 is ethylene glycol first.
It can be learnt according to more than contrast four embodiments, can make this with superpower radiation proof new material, the present invention is logical
Cross addition organosilicon, dipentaerythritol, ethoxy ethanol, titanium dioxide, ceramic, novolac epoxy resin, acrylic acid bicyclic penta
Alkenyl oxygen ethyl ester, alkali metal compound, curing agent and organic solvent, and this is reasonably processed, between each component
Cooperate, have complementary advantages, can effectively lift radiation protection ability, but also with price and environment-friendly advantage, and adhesive force it is strong,
Ductility is good, high temperature resistant, service life are long, and application prospect is wide.
Although an embodiment of the present invention has been shown and described, for the ordinary skill in the art, can be with
A variety of changes, modification can be carried out to these embodiments, replace without departing from the principles and spirit of the present invention by understanding
And modification, the scope of the present invention is defined by the appended.
Claims (4)
1. a kind of preparation method with superpower radiation proof new material, it is characterised in that：Comprise the following steps,
S1：Raw material is weighed, by organosilicon, dipentaerythritol, ethoxy ethanol, titanium dioxide, ceramic, novolac epoxy resin,
Acrylic acid double cyclopentenyl oxygen ethyl ester, alkali metal compound, curing agent and organic solvent are weighed according to certain ratio
Take；
S2：Preliminary operation, by load weighted dipentaerythritol, ethoxy ethanol, novolac epoxy resin and the bicyclic amylene of acrylic acid
Base oxygen ethyl ester is placed in same stirring vessel, then starts stirring, and whipping temp is 40-80 degree, and 10- is stirred clockwise
15 minutes, stirring 10-15 minutes, so stirred 3-8 times, obtain first part of raw material repeatedly counterclockwise；
S3：Powder is added, titanium dioxide and ceramic are added in first part of raw material, uniform stirring is carried out first, and
With ultrasonic disperse 30-40 minutes, second part of raw material is obtained；
S4：Agitating procedure, organosilicon and alkali metal compound are put into Mixing Machine, mixed, and the mixing is
Agitated machine is stirred with 500-800r/min speed and mixed, and obtains the 3rd part of raw material；
S5：Solvent is added, and adds organic solvents into the 3rd part of raw material, uniform stirring is then carried out again, mixing time is 15-
25 minutes, whipping temp 20-30 degree obtained the 4th part of raw material；
S6：Process is merged, second part of raw material and the 4th part of raw material are put together, and ultrasound is stirred under conditions of 40-80 degree
Mix 50-90 minutes；
S7：In molding procedure, the mixture that curing agent is put into second part of raw material and the 4th part of raw material, then finally stirred
Mix, clockwise stirring 30-45 minutes, counterclockwise stirring 30-50 minutes, so stir 5-10 times repeatedly, whipping temp is 50-
100 degree, the radiation proof material is finally made.
2. a kind of preparation method with superpower radiation proof new material according to claim 1, it is characterised in that：The step
Organosilicon, dipentaerythritol, ethoxy ethanol, titanium dioxide, ceramic, novolac epoxy resin, organic solvent, propylene in rapid S1
Mass ratio between sour double cyclopentenyl oxygen ethyl ester, alkali metal compound and curing agent is：Organosilicon 5-9%, dipentaerythritol
2-7%, ethoxy ethanol 3-10%, titanium dioxide 5-15%, ceramic 3-8%, novolac epoxy resin 2-5%, the bicyclic amylene of acrylic acid
Base oxygen ethyl ester 8-16%, alkali metal compound 10-18＆ and curing agent 1-4%, remaining is organic solvent.
3. a kind of preparation method with superpower radiation proof new material according to claim 1, it is characterised in that：The step
Alkali metal compound in rapid S1 is the mixture of magnesium sulfate, calcium sulfate and barium sulfate.
4. a kind of preparation method with superpower radiation proof new material according to claim 1, it is characterised in that：The step
Organic solvent in rapid S1 is one kind in ethyl acetate, butyl acetate, acetic acid alcohol and in ethylene glycol first.
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| CN201710294153.5A CN107141856A (en) | 2017-04-28 | 2017-04-28 | A kind of preparation method with superpower radiation proof new material |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN112080168A (en) * | 2020-09-29 | 2020-12-15 | 衡阳凌云特种材料有限公司 | Environment-friendly radiation-proof composite coating and preparation method thereof |
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| CN102585697A (en) * | 2012-02-21 | 2012-07-18 | 广州秀珀化工股份有限公司 | Nuclear radiation-resistant coating and preparation method thereof |
| CN105820718A (en) * | 2016-04-27 | 2016-08-03 | 黄河科技学院 | Anti-corrosion anti-radiation ceramic coating and preparation method thereof |
| CN105860621A (en) * | 2016-04-27 | 2016-08-17 | 黄河科技学院 | Corrosion-resistant radiation-resistant novolac epoxy resin paint and preparation method thereof |
| CN106189573A (en) * | 2016-07-19 | 2016-12-07 | 芜湖昊轩环保新材料有限公司 | Radiation shielding coating and preparation method thereof |
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2017
- 2017-04-28 CN CN201710294153.5A patent/CN107141856A/en active Pending
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| CN101195740A (en) * | 2007-12-27 | 2008-06-11 | 同济大学 | New purpose of alkaline earth metal sulfate |
| CN102585697A (en) * | 2012-02-21 | 2012-07-18 | 广州秀珀化工股份有限公司 | Nuclear radiation-resistant coating and preparation method thereof |
| CN105820718A (en) * | 2016-04-27 | 2016-08-03 | 黄河科技学院 | Anti-corrosion anti-radiation ceramic coating and preparation method thereof |
| CN105860621A (en) * | 2016-04-27 | 2016-08-17 | 黄河科技学院 | Corrosion-resistant radiation-resistant novolac epoxy resin paint and preparation method thereof |
| CN106189573A (en) * | 2016-07-19 | 2016-12-07 | 芜湖昊轩环保新材料有限公司 | Radiation shielding coating and preparation method thereof |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN112080168A (en) * | 2020-09-29 | 2020-12-15 | 衡阳凌云特种材料有限公司 | Environment-friendly radiation-proof composite coating and preparation method thereof |
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Application publication date: 20170908 |