CN107141584A - A kind of PP composite material and its application in hydrophilic flexible non-woven fabrics is prepared - Google Patents
A kind of PP composite material and its application in hydrophilic flexible non-woven fabrics is prepared Download PDFInfo
- Publication number
- CN107141584A CN107141584A CN201710285391.XA CN201710285391A CN107141584A CN 107141584 A CN107141584 A CN 107141584A CN 201710285391 A CN201710285391 A CN 201710285391A CN 107141584 A CN107141584 A CN 107141584A
- Authority
- CN
- China
- Prior art keywords
- composite material
- methacrylic acid
- woven fabrics
- hydrophilic
- material according
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/10—Homopolymers or copolymers of propene
- C08L23/12—Polypropene
-
- D—TEXTILES; PAPER
- D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
- D04H—MAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
- D04H1/00—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres
- D04H1/40—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties
- D04H1/42—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties characterised by the use of certain kinds of fibres insofar as this use has no preponderant influence on the consolidation of the fleece
- D04H1/4282—Addition polymers
- D04H1/4291—Olefin series
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2203/00—Applications
- C08L2203/12—Applications used for fibers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
- C08L2205/025—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
Abstract
The invention belongs to technical field of composite materials, a kind of PP composite material and its application in hydrophilic flexible non-woven fabrics is prepared are disclosed.The composite is made up of the component of following mass parts：HOPP 48~62, atactic copolymerized polypropene 20~24, propylene-based elastomeric 8~15, ethylene methacrylic acid copolymer 5~10, ethylene methacrylic acid salt copolymer 1~5, hydrophilic lubrication agent 0~1.The preparation method is：HOPP, atactic copolymerized polypropene, propylene-based elastomeric, ethylene methacrylic acid copolymer, ethylene methacrylic acid salt copolymer and hydrophilic lubrication agent are pre-mixed, it is then added to melting extrusion in extruder to granulate, obtains the PP composite material.Non-woven fabrics prepared by the PP composite material of the present invention has excellent hydrophily and pliability, disclosure satisfy that the demand in the fields such as medical dressing and beauty mask.
Description
Technical field
The invention belongs to technical field of composite materials, and in particular to a kind of PP composite material and its hydrophilic soft preparing
Application in tough non-woven fabrics.
Background technology
Polypropylene has become one of leading products of China's high polymer material.2016, domestic polypropylene production capacity was
20,000,000 tons are broken through, yield is up to 1768.8 ten thousand tons.It is polyacrylic to be mainly used for production woven product, film article, injection system
Product, textile fabrics etc., are widely used in the fields such as automobile, electronics and household electrical appliances, building pipe, packaging, fiber.Wherein, polypropylene
Fiber material is mainly for the production of polypropylene fiber, and polypropylene fiber is broadly divided into polypropylene non-woven fabric by its purposes and (is also known as nonwoven
Cloth), BCF carpet silks, cigarette polypropylene tow etc., wherein output it is maximum for non-woven fabrics, account for more than the 70% of product population.
2016, the yield of domestic non-woven fabrics was at 3,000,000 tons or so.The production technology of non-woven fabrics is at present with melt-blown process and spunbond process
For main flow.In fact, domestic ultra-large type polypropylene non-woven fabric manufacturing enterprise has been completed the compound of melt-blown and spunbond process, with life
Produce based on multi-layer nonwoven fabrics.Non-woven fabrics is in industry extensive uses such as building, medical treatment, environmental protection, clothes, automobile, Aero-Space, mainly
Using concentrating on high-tech effusion and field of novel.Wherein, application of the polypropylene non-woven fabric in the field such as medical treatment and beauty
Higher rate of rise is presented.In recent years, continuing to develop with social economy's level, movement of population aggravation, all kinds of infectiousness
Disease repeatedly forms public health event, and medical protection rank, which rises, triggers Needs of public health to increase sharply, and non-woven fabrics industry is more
It is secondary to have welcome good opportunity to develop.In addition, with the progress of medical technology, traumatism treatment and rehabilitation swash to the demand of dressing
Increase.In addition, with the improvement of living standards, people are paid high attention to personal beauty, disappearing for facial mask beauty is put into every year
Growth more than double figures is presented in Fei Jun.In these application fields, polypropylene non-woven fabric shows excellent performance, and
It is with low cost.
At present, applied to medical dressing and the polypropylene non-woven fabric of beauty mask base material, be mostly by hydrophilic modifying or
Super-fine fiber material prepared by composite spinning technology.Its hydrophilic modifying technique include corona treatment, hot graft N-vinyl-
2-Pyrrolidone (NVP), ultraviolet irradiation grafted methacrylic acid, interior addition durable hydrophilic auxiliary agent, PVA are modified, chitosan is hydrophilic
Modified, fibroin albumen modification etc., improves the hydrophily of polypropylene non-woven fabric, improves polypropylene non-woven to a certain extent
Comfort and laminating degree when cloth is with contact human skin, some products also addition of the appearance to healing potion or Cosmetic Ingredient
The amount of receiving.
But, polypropylene non-woven fabric is in the application process of medical dressing and beauty mask base material, it has been found that even if through
Cross the superfine polypropylene non-woven fabrics that hydrophilic modifying or composite spinning are modified, however it remains hydrophily, strong, hydrophily is not unstable,
The defect such as skin attachement is bad.It is relative that its subject matter is that used hydrophilic treatment process does not assign polypropylene non-woven fabric
Lasting hydrophily, such as addition small molecule hydrophilizing agent be not inherently good and be easy to move with non-polar polypropylene fibre compatibility
Go out；Plasma or laser treatment are the surface group for being modified polypropylene fibre, and modified effect and unstable；PET and PP
Blend spinning, the problem of inherently there is compatibility, and PET hydrophily are nor highly desirable.Therefore, if it is desirable to obtain parent
Aqueous stabilization and meet the polypropylene non-woven fabric of sufferer or beauty demand, it is necessary to select with polypropylene compatible it is good, with more preferable
Hydrophilicity and the high polymer material with good spinnability, are aided with necessary spin finish aid, are total to polypropylene base
Mixed modification, is made the hydrophilic flexible polypropylene dedicated composite of non-woven fabrics, and then coordinate suitable spinning technique acquired
The excellent hydrophilic flexible non-woven fabrics of energy.
The content of the invention
In place of the shortcoming and defect existed for prior art, primary and foremost purpose of the invention is that providing a kind of polypropylene answers
Condensation material.
Another object of the present invention is to provide the preparation method of above-mentioned PP composite material.
It is still another object of the present invention to provide above-mentioned PP composite material answering in hydrophilic flexible non-woven fabrics is prepared
With.
The object of the invention is achieved through the following technical solutions：
A kind of PP composite material, is made up of the component of following mass parts：
Preferably, the melt flow rate (MFR) (230 DEG C, 2.16kg) of the HOPP is 30~100g/10min.More
It is preferred that the fibrous polypropylene S2040 of Yanshan Petrochemical, its melt flow rate (MFR) (230 DEG C, 2.16kg) is in 38g/10min or so.
Preferably, the melt flow rate (MFR) (230 DEG C, 2.16kg) of the atactic copolymerized polypropene is 8~50g/10min.
The more preferably B4808 of Yanshan Petrochemical, its melt flow rate (230 DEG C, 2.16kg) is 10g/10min or so.
Preferably, ethylene contents are 8.5~16% in the propylene-based elastomeric, melt flow rate (MFR) (230 DEG C,
2.16kg) it is 2.2~18g/10min.The more preferably Vistamaxx 6202FL of Exxon Mobil Corporation.
Preferably, methacrylic acid content is 9~15wt% in the ethylene-methacrylic acid copolymer, and density is
0.93~0.94g/cm3, melt flow rate (MFR) (190 DEG C, 2.16kg) is 2.5~25g/10min.More preferably E.I.Du Pont Company
Nucrel925, its methacrylic acid content is 15wt%, and melt flow rate (MFR) (190 DEG C, 2.16kg) is 25g/10min.
Preferably, the molar content of methacrylic acid is 3.6 ± 0.5% in the ethylene-methyl methacrylate salt copolymer,
The degree of neutralization of methacrylic acid is 45%, and the metal ion for neutralizing into salt is sodium, potassium, magnesium or zinc ion, ethylene-methyl methacrylate
The density of copolymer is 0.93~0.96g/cm3.The Surlyn resins of optional E.I.Du Pont Company, including Surlyn1601,
Surlyn8020, Surlyn8920, Surlyn9320, Surlyn9950 etc., preferably Surlyn8920 (contain sodium salt of methacrylic acid
Copolymerization units).
Preferably, the hydrophilic lubrication agent is erucyl amide, and purity is weight/mass percentage composition more than 99%.
The preparation method of above-mentioned PP composite material, including following preparation process：
By HOPP, atactic copolymerized polypropene, propylene-based elastomeric, ethylene-methacrylic acid copolymer, ethene-
Methacrylate copolymer and hydrophilic lubrication agent are pre-mixed, and are then added to melting extrusion in extruder and are granulated, obtain
To the PP composite material.
Preferably, described premixing is carried out in high-speed mixer, and mixing temperature is 20~30 DEG C, and rotating speed is 200~300
Rev/min, incorporation time is 3~8 minutes.
Preferably, the melting extrusion granulation is carried out in three-screw extruder (screw diameter 35.2mm, draw ratio 28),
100~300 revs/min of screw speed, 10~50 revs/min of feeding machine rotating speed, 160~200 DEG C of temperature of each section of extruder.
Application of the above-mentioned PP composite material in hydrophilic flexible non-woven fabrics is prepared.
The present invention principle be：The simple non-woven fabrics made of fibre-grade HOPP, even if fibre number reaches work
Skill is ultimate attainment, and its water imbibition and flexibility are also limited.In the present invention, add atactic copolymerized polypropene and propylene-based elastomeric is (real
Border is also the random copolymer of ethylene-propylene) purpose, partly in order to the pliability of reinforced polypropylene composite fibre, separately
Partly in order to increase hydrophilic resin ethylene-methacrylic acid copolymer and hydrophilic hardening agent ethylene-methyl methacrylate salt
The compatibility of copolymer and matrix resin HOPP, because these resins all contain a certain proportion of ethene segment.These
Component can realize that sufficient dispersion mixing and good distribution are mixed because of similar compatibility in three-screw extruder mixing process
Close, so as to play effect of each component to greatest extent.The addition of hydrophilic lubrication agent erucyl amide, not only improves raising polypropylene
The hydrophilicity of composite, is conducive to the raising of the composite spinnability again, can preferably make performance stable, hydrophilic
The excellent polypropylene non-woven fabric of property, pliability, meets the demand in the fields such as medical dressing and beauty mask.
Brief description of the drawings
Fig. 1 is the SEM figures of the hydrophilic flexible non-woven fabrics of PP composite material preparation in embodiment 3；
Fig. 2 is the optical photograph figure of the hydrophilic flexible non-woven fabrics of PP composite material preparation in embodiment 3.
Embodiment
With reference to embodiment, the present invention is described in further detail, but the implementation of the present invention is not limited to this.
In following examples, HOPP resin selects the fibrous polypropylene S2040 of Yanshan Petrochemical, its melt flows
Speed (230 DEG C, 2.16kg) is in 38g/10min or so；Atactic copolymerized polypropene selects the B4808 of Yanshan Petrochemical, its melt flow
Dynamic speed (230 DEG C, 2.16kg) is 10g/10min or so；Propylene-based elastomeric selects the Vistamaxx of Exxon Mobil Corporation
6202FL, its Ethylene mass percentage composition is 15.0%, and melt flow rate (MFR) (230 DEG C, 2.16kg) is in 18g/10min or so；
Ethylene-methacrylic acid copolymer selects the Nucrel925 of E.I.Du Pont Company, and its methacrylic acid content is 15wt%, melt flow
Dynamic speed (190 DEG C, 2.16kg) is in 25g/10min or so；Mole of the methacrylic acid of ethylene-methyl methacrylate salt copolymer
Content is 3.6 ± 0.5%, and alkali neutralization ratio accounts for 45 moles of % of methacrylic acid, and density is 0.93~0.96g/cm3, selection Du
The Surlyn8920 (copolymerization units containing sodium salt of methacrylic acid) of company of nation；Hydrophilic lubrication agent is commercially available erucyl amide, purity
More than 99%.
Embodiment 1
Each raw material is weighed according to following proportioning：Polypropylene S2040 is 62 mass parts, and atactic copolymerized polypropene B4808 is 24
Mass parts, VistaMaxx 6202FL are 8 mass parts, and Surlyn8920 is 1 mass parts, and Nucrel 925 is 5 mass parts, is not added with
Erucyl amide.By polypropylene S2040, atactic copolymerized polypropene B4808, propylene-based elastomeric VistaMaxx 6202FL, ethene-
Methacrylate copolymer Surlyn8920, ethylene-methacrylic acid copolymer Nucrel 925 sequentially add mixed at high speed
Machine is pre-mixed, and mixing temperature is 20 DEG C, and rotating speed is 300 revs/min, and incorporation time is 3 minutes.Then, this is pre-mixed
Good material adds three-screw extruder (screw diameter 35.2mm, draw ratio 28), melting extrusion granulation, technique bar from feeding machine
Part is set as：200 revs/min of screw speed, 30 revs/min of feeding machine rotating speed, 160~200 DEG C of temperature of each section of extruder.Produce
To PP composite material.
At 200~250 DEG C with meltblown spinning-drawing machine prepared by dried PP composite material pellet into grammes per square metre to exist
80g/m2The hydrophilic flexible non-woven fabrics of left and right.The properties of the hydrophilic flexible non-woven fabrics of test gained, test result is shown in Table 1.
Embodiment 2
Each raw material is weighed according to following proportioning：Polypropylene S2040 is 56.5 mass parts, and atactic copolymerized polypropene B4808 is
20 mass parts, VistaMaxx 6202FL are 10 mass parts, and Surlyn8920 is 3 mass parts, and Nucrel 925 is 10 mass parts,
Erucyl amide is 0.5 mass parts.By polypropylene S2040, atactic copolymerized polypropene B4808, propylene-based elastomeric VistaMaxx
6202FL, ethylene-methyl methacrylate salt copolymer Surlyn8920, ethylene-methacrylic acid copolymer Nucrel 925, erucic acid
Acid amides sequentially adds high-speed mixer and is pre-mixed, and mixing temperature is 30 DEG C, and rotating speed is 250 revs/min, and incorporation time is 5
Minute.Then, the material this premix got togather adds three-screw extruder (screw diameter 35.2mm, draw ratio from feeding machine
28), melting extrusion is granulated, and process conditions are set as：200 revs/min of screw speed, 40 revs/min of feeding machine rotating speed, extruder
Each section of 160~200 DEG C of temperature.Obtain PP composite material.
At 200~250 DEG C with meltblown spinning-drawing machine prepared by dried PP composite material pellet into grammes per square metre to exist
80g/m2The hydrophilic flexible non-woven fabrics of left and right.The properties of the hydrophilic flexible non-woven fabrics of test gained, test result is shown in Table 1.
Embodiment 3
Each raw material is weighed according to following proportioning：Polypropylene S2040 is 48 mass parts, and atactic copolymerized polypropene B4808 is 23
Mass parts, VistaMaxx 6202FL are 15 mass parts, and Surlyn8920 is 5 mass parts, and Nucrel 925 is 8 mass parts, mustard
Sour acid amides is 1 mass parts.By polypropylene S2040, atactic copolymerized polypropene B4808, propylene-based elastomeric VistaMaxx
6202FL, ethylene-methyl methacrylate salt copolymer Surlyn8920, ethylene-methacrylic acid copolymer Nucrel 925, erucic acid
Acid amides sequentially adds high-speed mixer and is pre-mixed, and mixing temperature is 25 DEG C, and rotating speed is 250 revs/min, and incorporation time is
3.5 minute.Then, the material this premix got togather adds three-screw extruder (screw diameter 35.2mm, draw ratio from feeding machine
28), melting extrusion is granulated, and process conditions are set as：300 revs/min of screw speed, 50 revs/min of feeding machine rotating speed, extruder
Each section of 160~200 DEG C of temperature.Obtain PP composite material.
At 200~250 DEG C with meltblown spinning-drawing machine prepared by dried PP composite material pellet into grammes per square metre to exist
80g/m2The hydrophilic flexible non-woven fabrics of left and right.The properties of the hydrophilic flexible non-woven fabrics of test gained, test result is shown in Table 1.This
The SEM figures and optical photograph figure difference of hydrophilic flexible non-woven fabrics obtained by embodiment are as depicted in figs. 1 and 2.
Comparative example 1
HOPP S2040 is added into three-screw extruder (screw diameter 35.2mm, draw ratio 28) from feeding machine, melted
Melt extruding pelletization, process conditions are set as：200 revs/min of screw speed, 25 revs/min of feeding machine rotating speed, each section of temperature of extruder
160~200 DEG C of degree.Obtain polypropylene material.
Dried polypropylene granules are prepared into grammes per square metre in 80g/m at 200~250 DEG C with meltblown spinning-drawing machine2Left and right
Non-woven fabrics.The properties of polypropylene non-woven fabric are tested, test result is shown in Table 1.
Comparative example 2
Each raw material is weighed according to following proportioning：Polypropylene S2040 is 65 mass parts, and atactic copolymerized polypropene B4808 is 35
Mass parts.Polypropylene S2040, atactic copolymerized polypropene B4808 addition high-speed mixer are pre-mixed, mixing temperature is 25
DEG C, rotating speed is 250 revs/min, and incorporation time is 3.5 minutes.Then, the material this premix got togather adds three spiral shells from feeding machine
Bar extruder (screw diameter 35.2mm, draw ratio 28), melting extrusion granulation, process conditions are set as：200 turns of screw speed/
Minute, 25 revs/min of feeding machine rotating speed, 160~200 DEG C of temperature of each section of extruder.Produce PP composite material.
At 200~250 DEG C with meltblown spinning-drawing machine prepared by dried PP composite material pellet into grammes per square metre to exist
80g/m2The composite polypropylene non-woven fabrics of left and right.The properties of test gained composite polypropylene non-woven fabrics, test result is shown in Table
1。
Comparative example 3
Each raw material is weighed according to following proportioning：Polypropylene S2040 is 65 mass parts, and atactic copolymerized polypropene B4808 is 25
Mass parts, VistaMaxx 6202FL are 10 mass parts.By polypropylene S2040, atactic copolymerized polypropene B4808, acrylic bullet
Property body VistaMaxx 6202FL add high-speed mixer and be pre-mixed, mixing temperature is 25 DEG C, and rotating speed is 250 revs/min,
Incorporation time is 3.5 minutes.Then, the material this premix got togather adds three-screw extruder (screw diameter from feeding machine
35.2mm, draw ratio 28), melting extrusion granulation, process conditions are set as：200 revs/min of screw speed, feeding machine rotating speed 25
Rev/min, 160~200 DEG C of temperature of each section of extruder.Produce PP composite material.
At 200~250 DEG C with meltblown spinning-drawing machine prepared by dried PP composite material pellet into grammes per square metre to exist
80g/m2The composite polypropylene non-woven fabrics of left and right.The properties of test gained composite polypropylene non-woven fabrics, test result is shown in Table
1。
Polypropylene material and non-woven fabrics performance obtained by the embodiment of table 1 and comparative example
The non-woven fabrics prepared it can be seen from the result of table 1 using the PP composite material of the present invention has excellent parent
Aqueous and pliability, disclosure satisfy that the demand in the fields such as medical dressing and beauty mask.
Above-described embodiment is preferably embodiment, but embodiments of the present invention are not by above-described embodiment of the invention
Limitation, other any Spirit Essences without departing from the present invention and the change made under principle, modification, replacement, combine, simplification,
Equivalent substitute mode is should be, is included within protection scope of the present invention.
Claims (10)
1. a kind of PP composite material, it is characterised in that be made up of the component of following mass parts：
2. a kind of PP composite material according to claim 1, it is characterised in that：The HOPP 230 DEG C,
Melt flow rate (MFR) under the conditions of 2.16kg is 30~100g/10min.
3. a kind of PP composite material according to claim 1, it is characterised in that：The atactic copolymerized polypropene exists
230 DEG C, the melt flow rate (MFR) under the conditions of 2.16kg be 8~50g/10min.
4. a kind of PP composite material according to claim 1, it is characterised in that：Ethene in the propylene-based elastomeric
Content is 8.5~16%, 230 DEG C, the melt flow rate (MFR) under the conditions of 2.16kg is 2.2~18g/10min.
5. a kind of PP composite material according to claim 1, it is characterised in that：The ethylene-methyl methacrylate is total to
Methacrylic acid content is 9~15wt% in polymers, and density is 0.93~0.94g/cm3, 190 DEG C, molten under the conditions of 2.16kg
Body flow rate is 2.5~25g/10min.
6. a kind of PP composite material according to claim 1, it is characterised in that：The ethylene-methyl methacrylate salt
The molar content of methacrylic acid is 3.6 ± 0.5% in copolymer, and the degree of neutralization of methacrylic acid is 45%, neutralizes into salt
Metal ion is sodium, potassium, magnesium or zinc ion；The density of ethylene-methacrylic acid copolymer is 0.93~0.96g/cm3。
7. a kind of PP composite material according to claim 1, it is characterised in that：The hydrophilic lubrication agent is erucic acid acyl
Amine, purity is weight/mass percentage composition more than 99%.
8. the preparation method of a kind of PP composite material described in any one of claim 1~7, it is characterised in that including following
Preparation process：
By HOPP, atactic copolymerized polypropene, propylene-based elastomeric, ethylene-methacrylic acid copolymer, ethene-methyl
Acrylate copolymer and hydrophilic lubrication agent are pre-mixed, and are then added to melting extrusion in extruder and are granulated, obtain institute
State PP composite material.
9. a kind of preparation method of PP composite material according to claim 8, it is characterised in that：Described premixing
Carried out in high-speed mixer, mixing temperature is 20~30 DEG C, rotating speed is 200~300 revs/min, incorporation time is 3~8 minutes；
The melting extrusion granulation is carried out in three-screw extruder, 100~300 revs/min of screw speed, feeding machine rotating speed 10~50
Rev/min, 160~200 DEG C of temperature of each section of extruder.
10. a kind of the answering in hydrophilic flexible non-woven fabrics is prepared of PP composite material described in any one of claim 1~7
With.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710285391.XA CN107141584B (en) | 2017-04-27 | 2017-04-27 | A kind of PP composite material and its preparing the application in hydrophilic flexible non-woven fabrics |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710285391.XA CN107141584B (en) | 2017-04-27 | 2017-04-27 | A kind of PP composite material and its preparing the application in hydrophilic flexible non-woven fabrics |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN107141584A true CN107141584A (en) | 2017-09-08 |
| CN107141584B CN107141584B (en) | 2019-10-18 |
Family
ID=59774831
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201710285391.XA Active CN107141584B (en) | 2017-04-27 | 2017-04-27 | A kind of PP composite material and its preparing the application in hydrophilic flexible non-woven fabrics |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN107141584B (en) |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN111005159A (en) * | 2019-12-30 | 2020-04-14 | 山东恒鹏卫生用品有限公司 | Non-woven fabric applied to paper diaper core wrapping and production method thereof |
| EP3722095A1 (en) * | 2019-04-12 | 2020-10-14 | Thai Polyethylene Co., Ltd. | A polypropylene composition for retort packaging application |
| CN113717460A (en) * | 2021-07-22 | 2021-11-30 | 广东金发科技有限公司 | High-surface-hydrophilicity polypropylene composite material and preparation method and application thereof |
| CN113881134A (en) * | 2020-07-01 | 2022-01-04 | 中国石油天然气股份有限公司 | Composition for hydrophilic non-woven fabric and application thereof |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1383442A (en) * | 2000-06-07 | 2002-12-04 | 巴赛尔技术有限公司 | Polyolefin compsn. contg. low viscosity propylene homopolymers, fiber and extensible non-woven fabric prepared therefrom |
| CN1420952A (en) * | 2000-02-10 | 2003-05-28 | 出光统一科技株式会社 | Nonwoven fabric, process for producing same, sanitary material, and sanitary supply |
| CN102336960A (en) * | 2011-07-20 | 2012-02-01 | 江苏兆鋆新材料科技有限公司 | Method for improving hydrophilicity of polypropylene and application of obtained product |
-
2017
- 2017-04-27 CN CN201710285391.XA patent/CN107141584B/en active Active
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1420952A (en) * | 2000-02-10 | 2003-05-28 | 出光统一科技株式会社 | Nonwoven fabric, process for producing same, sanitary material, and sanitary supply |
| CN1383442A (en) * | 2000-06-07 | 2002-12-04 | 巴赛尔技术有限公司 | Polyolefin compsn. contg. low viscosity propylene homopolymers, fiber and extensible non-woven fabric prepared therefrom |
| CN102336960A (en) * | 2011-07-20 | 2012-02-01 | 江苏兆鋆新材料科技有限公司 | Method for improving hydrophilicity of polypropylene and application of obtained product |
Non-Patent Citations (3)
| Title |
|---|
| LONGSHENG LU, ET AL: "Electrical conduction investigation of a nonwoven fabric composed of carbon fibers and polypropylene/polyethylene core/sheath bicomponent fibers", 《MATERIALS AND DESIGN》 * |
| RONG LI,ET AL: "Immobilization of Heparin on the Surface of Polypropylene Non-Woven Fabric for Improvement of the Hydrophilicity and Blood Compatibility", 《JOURNAL OF BIOMATERIALS SCIENCE, POLYMER EDITION》 * |
| 张雪婷 等: "细菌纤维素改性无纺布复合材料的制备及性能", 《功能材料》 * |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP3722095A1 (en) * | 2019-04-12 | 2020-10-14 | Thai Polyethylene Co., Ltd. | A polypropylene composition for retort packaging application |
| CN111005159A (en) * | 2019-12-30 | 2020-04-14 | 山东恒鹏卫生用品有限公司 | Non-woven fabric applied to paper diaper core wrapping and production method thereof |
| CN113881134A (en) * | 2020-07-01 | 2022-01-04 | 中国石油天然气股份有限公司 | Composition for hydrophilic non-woven fabric and application thereof |
| CN113881134B (en) * | 2020-07-01 | 2023-07-25 | 中国石油天然气股份有限公司 | Composition for hydrophilic non-woven fabric and application thereof |
| CN113717460A (en) * | 2021-07-22 | 2021-11-30 | 广东金发科技有限公司 | High-surface-hydrophilicity polypropylene composite material and preparation method and application thereof |
Also Published As
| Publication number | Publication date |
|---|---|
| CN107141584B (en) | 2019-10-18 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN110093681B (en) | Antibacterial ES composite short fiber for hot-air non-woven fabric surface layer and preparation method thereof | |
| CN107141584B (en) | A kind of PP composite material and its preparing the application in hydrophilic flexible non-woven fabrics | |
| CN105263996B (en) | Hole elicitation technique | |
| CN100344807C (en) | Elastic bicomponent and biconstituent fibers, and methods of making cellulosic structures from the same | |
| CN103069058B (en) | The acid fiber by polylactic of modification | |
| DE602006000082T2 (en) | Fiber with antimicrobial composition | |
| CN105492513B (en) | Anisotropic polymer material | |
| CN105247119A (en) | Porous polyolefin fibers | |
| CN104093891A (en) | Renewable polyester fibers having a low density | |
| CN106222789B (en) | A kind of manufacturing method of biomass graphene fire-retardant polyester fibre | |
| KR20070045220A (en) | Fabric and clothes for atopic dermatitis patients | |
| JP2015510555A (en) | Modified polylactic acid fiber | |
| JP2008266812A (en) | Functional modified cross-section type regenerated polyethylene terephthalate fiber, and method for producing the same | |
| TWI529271B (en) | Cooling fabric based on hydrophobic peba | |
| CN103502517A (en) | Fiber, non-woven fabric and use thereof | |
| CN112921449A (en) | Chitosan quaternary ammonium salt/seaweed composite antibacterial fiber, preparation method thereof and application thereof in home textile products for children | |
| US9243349B2 (en) | Functional cellulosic moldings | |
| TW585889B (en) | An extruded and drawn fiber and an extruded and drawn multicomponent fiber | |
| CN113089321A (en) | Vinyl monomer graft modified antibacterial fiber, preparation method thereof and application thereof in antibacterial socks | |
| CN113089151B (en) | Three-dimensional antibacterial yarn containing cotton fibers, preparation method of three-dimensional antibacterial yarn and towel product | |
| CN113152098A (en) | Antibacterial finishing agent, finishing method and fabric product | |
| CN107189223A (en) | A kind of special ultra-dispersed Masterbatch of polypropylene melt spraying and preparation method thereof | |
| CN111733475A (en) | Biodegradable spinning material and preparation method and application thereof | |
| CN111605098A (en) | Color master batch with antibacterial hydrophilic softening function, non-woven fabric and preparation method thereof | |
| JP2008075194A (en) | Knitted fabric containing nanofiber fiber |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| GR01 | Patent grant | ||
| GR01 | Patent grant |