CN107129147A - A kind of glass used for building exterior wall - Google Patents
A kind of glass used for building exterior wall Download PDFInfo
- Publication number
- CN107129147A CN107129147A CN201710334992.5A CN201710334992A CN107129147A CN 107129147 A CN107129147 A CN 107129147A CN 201710334992 A CN201710334992 A CN 201710334992A CN 107129147 A CN107129147 A CN 107129147A
- Authority
- CN
- China
- Prior art keywords
- parts
- glass
- oxide
- colouring agent
- exterior wall
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
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Classifications
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C1/00—Ingredients generally applicable to manufacture of glasses, glazes, or vitreous enamels
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03B—MANUFACTURE, SHAPING, OR SUPPLEMENTARY PROCESSES
- C03B25/00—Annealing glass products
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03B—MANUFACTURE, SHAPING, OR SUPPLEMENTARY PROCESSES
- C03B5/00—Melting in furnaces; Furnaces so far as specially adapted for glass manufacture
- C03B5/16—Special features of the melting process; Auxiliary means specially adapted for glass-melting furnaces
- C03B5/235—Heating the glass
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C1/00—Ingredients generally applicable to manufacture of glasses, glazes, or vitreous enamels
- C03C1/02—Pretreated ingredients
Abstract
A kind of glass used for building exterior wall, the glass is made up of the raw material of following parts by weight：20 30 parts of silica, 58 parts of sodium carbonate, 47 parts of calcium silicates, 0.2 0.8 parts of silver chlorate, 1.3 1.5 parts of manganese dioxide, 0.5 0.8 parts of titanium dioxide, 1.2 1.6 parts of pearl essence, 0.1 0.3 parts of zirconium oxide, 0.2 0.6 parts of reflective powder, 0.3 0.5 parts of colouring agent.The present invention by adding silver chlorate, manganese dioxide, titanium dioxide, pearl essence, zirconium oxide, reflective powder, colouring agent in silica, so that obtained glass can absorb less than 70% infrared energy, good light transmittance is kept again and absorbs some visible light, the ability of ultraviolet, with the effect such as anti-dazzle, antiultraviolet, while having preferable effect of heat insulation.
Description
Technical field
The present invention relates to technical field of glass materials, and in particular to a kind of glass used for building exterior wall.
Background technology
Glass be fused together by silica and other chemical substances formed (main production raw material is：Soda ash, stone
Lime stone, quartz).Contiguous network structure is formed in melting, viscosity, which gradually increases and hardened, in cooling procedure causes what it was crystallized
Silicates nonmetallic materials.The chemical composition of simple glass is Na2SiO3, CaSiO3, SiO2 or Na2OCaO6SiO2
Deng main component is silicate double salt, is a kind of non-crystalline solids of random structure.Be widely used in building, for every
Wind printing opacity, belongs to mixture.It is another to have the oxide or salt that have been mixed into some metals and the coloured glass for showing color, and
Pass through safety glass etc. made from the method for physics or chemistry.
Human asm's manufacture but 1000 for many years, is used as building glass material using the history of the existing more than one thousand years of glass
The development of material is that comparison is slow.With the development and the raising of living standards of the people of modern science and technology and glass technology, build
The function of building glass is no longer only to meet daylighting requirement, but to have energy light regulating, insulation, safety (shellproof, anti-
Robber, fire prevention, radiation proof, anti electromagnetic wave interference), the characteristic such as artistic decoration.
The content of the invention
The present invention is to solve the above problems, provide a kind of with heat absorption function, the glass used for building exterior wall of stable chemical performance
Glass.
The technical problems to be solved by the invention are realized using following technical scheme：
A kind of glass used for building exterior wall, the glass is made up of the raw material of following parts by weight：
20-30 parts of silica, 5-8 parts of sodium carbonate, 4-7 parts of calcium silicates, 0.2-0.8 parts of silver chlorate, manganese dioxide 1.3-
1.5 parts, 0.5-0.8 parts of titanium dioxide, 1.2-1.6 parts of pearl essence, 0.1-0.3 parts of zirconium oxide, 0.2-0.6 parts of reflective powder, coloring
0.3-0.5 parts of agent.
It is preferred that, the glass is made up of the raw material of following parts by weight：
25 parts of silica, 7 parts of sodium carbonate, 5 parts of calcium silicates, 0.5 part of silver chlorate, 1.4 parts of manganese dioxide, titanium dioxide
0.6 part, 1.4 parts of pearl essence, 0.2 part of zirconium oxide, 0.4 part of reflective powder, 0.4 part of colouring agent.
The colouring agent is selected from the one or more in iron oxide, nickel oxide, tin oxide, antimony oxide.
It is preferred that, the colouring agent is made up of the raw material of following parts by weight：
1.0-1.2 parts of iron oxide, 0.2-0.5 parts of antimony oxide, 0.5-2.5 parts of tin oxide, 0.3-0.7 parts of nickel oxide.
A kind of method for glass preparation used for building exterior wall, comprises the following steps：
(1) each raw material of composition glass is weighed respectively and is ground after being well mixed, and obtains compound；
(2) gained compound in step (1) is subjected to Nanosurface processing；
(3) compound handled in step (2) by Nanosurfaceization is subjected to ionization and is heat-treated to obtain molten glass
Liquid；
(4) molten glass liquid is shaped into obtain glass substrate；
(5) glass substrate is annealed in the lehr.
It is 200-300 mesh that mixing material granularity is controlled after being ground in the step (1).
Carrying out Nanosurfaceization processing in the step (2) to compound is entered by adding surfactant and dispersant
Capable.
The surfactant is alkyl phosphorus carboxylate.
The dispersant is stearate.
The ionized Heat Treatment Control temperature of step (3) is at 1550~1600 DEG C.
Annealing is in nitrogen atmosphere in shaping, step (5) in the ionized heat treatment of step (3), step (4)
Carry out.
Annealing is divided into three phases in the step (5), and the respectively first stage anneals slowly, second stage short annealing and
Phase III normal temperature is annealed, and wherein first stage slow annealing regulation annealing rate is in 50~80 degree/hour, until temperature is reduced to
550~600 degree, subsequently into second stage short annealing, control annealing rate is in 100~120 degree/hour, until temperature drop
As little as 100~120 degree, the annealing of phase III normal temperature is finally entered, from moving back when glass baseplate surface temperature is down to 20~25 degree
Taken out in stove.
Beneficial effects of the present invention are：
(1) by add in silica silver chlorate, manganese dioxide, titanium dioxide, pearl essence, zirconium oxide, reflective powder,
Colouring agent so that obtained glass can absorb less than 70% infrared energy, keeps good light transmittance and absorption portion again
Divide visible ray, the ability of ultraviolet, with the effect such as anti-dazzle, antiultraviolet, while having preferable effect of heat insulation；Silver chlorate
Under light illumination so that glass colour is dimmed, endothermic effect is improved, while silver ion, which has, absorbs ultraviolet effect；Manganese dioxide,
Titanium dioxide, pearl essence are scattered in glass, change glass basis refractive index, and incident ray can be inhaled by multiple refraction
Receive；Zirconium oxide reduction glass expansion coefficient is mixed, extends glass service life.
(2) frit carries out Nanosurface processing, and ionization heat treatment is then carried out again, surface-active is improved
Can, reunions is produced due to intermolecular active force, chemical bond, eliminate inside glass a large amount of defects (including satiate
Room, dislocation and the Non-equilibrium Grain Boundary of sum) and improve its stress distribution situation, obtained glass transmission rate can reach 90% with
On, moreover it is possible to the ultraviolet and more than 70% infrared ray in the external world more than 96% are blocked, mosquito and moth will not be gathered in glass
Surface.
Embodiment
In order that the technical means, the inventive features, the objects and the advantages of the present invention are easy to understand, tie below
Embodiment is closed, the present invention is expanded on further.
Embodiment 1
A kind of glass used for building exterior wall, the glass is made up of the raw material of following parts by weight：
20 parts of silica, 5 parts of sodium carbonate, 4 parts of calcium silicates, 0.2 part of silver chlorate, 1.3 parts of manganese dioxide, titanium dioxide
0.5 part, 1.2 parts of pearl essence, 0.1 part of zirconium oxide, 0.2 part of reflective powder, 0.3 part of colouring agent.
The colouring agent is selected from the one or more in iron oxide, nickel oxide, tin oxide, antimony oxide.
The colouring agent is made up of the raw material of following parts by weight：
Iron oxide 1.0, antimony oxide 0.2, tin oxide 0.5, nickel oxide 0.3.
Embodiment 2
A kind of glass used for building exterior wall, the glass is made up of the raw material of following parts by weight：
25 parts of silica, 7 parts of sodium carbonate, 5 parts of calcium silicates, 0.5 part of silver chlorate, 1.4 parts of manganese dioxide, titanium dioxide
0.6 part, 1.4 parts of pearl essence, 0.2 part of zirconium oxide, 0.4 part of reflective powder, 0.4 part of colouring agent.
The colouring agent is selected from the one or more in iron oxide, nickel oxide, tin oxide, antimony oxide.
The colouring agent is made up of the raw material of following parts by weight：
Iron oxide 1.0, antimony oxide 0.2, tin oxide 0.5, nickel oxide 0.3.
Embodiment 3
A kind of glass used for building exterior wall, the glass is made up of the raw material of following parts by weight：
30 parts of silica, 8 parts of sodium carbonate, 7 parts of calcium silicates, 0.8 part of silver chlorate, 1.5 parts of manganese dioxide, titanium dioxide
0.8 part, 1.6 parts of pearl essence, 0.3 part of zirconium oxide, 0.6 part of reflective powder, 0.5 part of colouring agent.
The colouring agent is selected from the one or more in iron oxide, nickel oxide, tin oxide, antimony oxide.
The colouring agent is made up of the raw material of following parts by weight：
Iron oxide 1.0, antimony oxide 0.2, tin oxide 0.5, nickel oxide 0.3.
Embodiment 4
A kind of glass used for building exterior wall, the glass is made up of the raw material of following parts by weight：
25 parts of silica, 7 parts of sodium carbonate, 5 parts of calcium silicates, 0.5 part of silver chlorate, 1.4 parts of manganese dioxide, titanium dioxide
0.6 part, 1.4 parts of pearl essence, 0.2 part of zirconium oxide, 0.4 part of reflective powder, 0.4 part of colouring agent.
The colouring agent is selected from the one or more in iron oxide, nickel oxide, tin oxide, antimony oxide.
The colouring agent is made up of the raw material of following parts by weight：
1.1 parts of iron oxide, 0.3 part of antimony oxide, 1.5 parts of tin oxide, 0.5 part of nickel oxide.
Embodiment 5
A kind of glass used for building exterior wall, the glass is made up of the raw material of following parts by weight：
25 parts of silica, 7 parts of sodium carbonate, 5 parts of calcium silicates, 0.5 part of silver chlorate, 1.4 parts of manganese dioxide, titanium dioxide
0.6 part, 1.4 parts of pearl essence, 0.2 part of zirconium oxide, 0.4 part of reflective powder, 0.4 part of colouring agent.
The colouring agent is selected from the one or more in iron oxide, nickel oxide, tin oxide, antimony oxide.
The colouring agent is made up of the raw material of following parts by weight：
1.2 parts of iron oxide, 0.5 part of antimony oxide, 2.5 parts of tin oxide, 0.7 part of nickel oxide.
General principle, principal character and the advantages of the present invention of the present invention has been shown and described above.The technology of the industry
Personnel are it should be appreciated that the present invention is not limited to the above embodiments, and that described in above-described embodiment and specification is only the present invention
Preference, be not intended to limit the present invention, without departing from the spirit and scope of the present invention, the present invention also have it is various
Changes and improvements, these changes and improvements all fall within the protetion scope of the claimed invention.The claimed scope of the invention is by institute
Attached claims and its equivalent thereof.
Claims (4)
1. a kind of glass used for building exterior wall, it is characterised in that the glass is made up of the raw material of following parts by weight：
20-30 parts of silica, 5-8 parts of sodium carbonate, 4-7 parts of calcium silicates, 0.2-0.8 parts of silver chlorate, manganese dioxide 1.3-1.5
Part, 0.5-0.8 parts of titanium dioxide, 1.2-1.6 parts of pearl essence, 0.1-0.3 parts of zirconium oxide, 0.2-0.6 parts of reflective powder, colouring agent
0.3-0.5 parts.
2. a kind of glass used for building exterior wall as claimed in claim 1, it is characterised in that the glass by following parts by weight original
Material composition：
25 parts of silica, 7 parts of sodium carbonate, 5 parts of calcium silicates, 0.5 part of silver chlorate, 1.4 parts of manganese dioxide, 0.6 part of titanium dioxide,
1.4 parts of pearl essence, 0.2 part of zirconium oxide, 0.4 part of reflective powder, 0.4 part of colouring agent.
3. a kind of glass used for building exterior wall as claimed in claim 1, it is characterised in that the colouring agent is selected from iron oxide, oxygen
Change the one or more in nickel, tin oxide, antimony oxide.
4. a kind of glass used for building exterior wall as claimed in claim 1, it is characterised in that the colouring agent is by following parts by weight
Raw material is constituted：
1.0-1.2 parts of iron oxide, 0.2-0.5 parts of antimony oxide, 0.5-2.5 parts of tin oxide, 0.3-0.7 parts of nickel oxide.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710334992.5A CN107129147A (en) | 2017-05-12 | 2017-05-12 | A kind of glass used for building exterior wall |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710334992.5A CN107129147A (en) | 2017-05-12 | 2017-05-12 | A kind of glass used for building exterior wall |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN107129147A true CN107129147A (en) | 2017-09-05 |
Family
ID=59733134
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201710334992.5A Pending CN107129147A (en) | 2017-05-12 | 2017-05-12 | A kind of glass used for building exterior wall |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN107129147A (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110396953A (en) * | 2019-08-05 | 2019-11-01 | 河南新之源园林绿化设计有限公司 | A kind of town road Traffic alarm light |
| CN114262154A (en) * | 2021-12-10 | 2022-04-01 | 江苏神盾新材料科技有限公司 | Special radiation-proof glass for nuclear power station and preparation process thereof |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1086499A (en) * | 1992-10-30 | 1994-05-11 | 康宁股份有限公司 | Colored glass and colorize method thereof |
| CN106274389A (en) * | 2016-08-11 | 2017-01-04 | 蚌埠翼诚玻璃有限公司 | A kind of multi-functional front windshield |
-
2017
- 2017-05-12 CN CN201710334992.5A patent/CN107129147A/en active Pending
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1086499A (en) * | 1992-10-30 | 1994-05-11 | 康宁股份有限公司 | Colored glass and colorize method thereof |
| CN106274389A (en) * | 2016-08-11 | 2017-01-04 | 蚌埠翼诚玻璃有限公司 | A kind of multi-functional front windshield |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110396953A (en) * | 2019-08-05 | 2019-11-01 | 河南新之源园林绿化设计有限公司 | A kind of town road Traffic alarm light |
| CN114262154A (en) * | 2021-12-10 | 2022-04-01 | 江苏神盾新材料科技有限公司 | Special radiation-proof glass for nuclear power station and preparation process thereof |
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| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20170905 |