CN107128110A - Novel ink stone - Google Patents
Novel ink stone Download PDFInfo
- Publication number
- CN107128110A CN107128110A CN201710270934.0A CN201710270934A CN107128110A CN 107128110 A CN107128110 A CN 107128110A CN 201710270934 A CN201710270934 A CN 201710270934A CN 107128110 A CN107128110 A CN 107128110A
- Authority
- CN
- China
- Prior art keywords
- weight
- parts
- parent
- raw material
- inkstone
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B43—WRITING OR DRAWING IMPLEMENTS; BUREAU ACCESSORIES
- B43L—ARTICLES FOR WRITING OR DRAWING UPON; WRITING OR DRAWING AIDS; ACCESSORIES FOR WRITING OR DRAWING
- B43L27/00—Ink stands
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B26/00—Compositions of mortars, concrete or artificial stone, containing only organic binders, e.g. polymer or resin concrete
- C04B26/02—Macromolecular compounds
- C04B26/10—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- C04B26/18—Polyesters; Polycarbonates
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
- C08G63/02—Polyesters derived from hydroxycarboxylic acids or from polycarboxylic acids and polyhydroxy compounds
- C08G63/12—Polyesters derived from hydroxycarboxylic acids or from polycarboxylic acids and polyhydroxy compounds derived from polycarboxylic acids and polyhydroxy compounds
- C08G63/52—Polycarboxylic acids or polyhydroxy compounds in which at least one of the two components contains aliphatic unsaturation
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
- C08G63/78—Preparation processes
- C08G63/82—Preparation processes characterised by the catalyst used
- C08G63/85—Germanium, tin, lead, arsenic, antimony, bismuth, titanium, zirconium, hafnium, vanadium, niobium, tantalum, or compounds thereof
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D161/00—Coating compositions based on condensation polymers of aldehydes or ketones; Coating compositions based on derivatives of such polymers
- C09D161/04—Condensation polymers of aldehydes or ketones with phenols only
- C09D161/06—Condensation polymers of aldehydes or ketones with phenols only of aldehydes with phenols
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D4/00—Coating compositions, e.g. paints, varnishes or lacquers, based on organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond ; Coating compositions, based on monomers of macromolecular compounds of groups C09D183/00 - C09D183/16
- C09D4/06—Organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond in combination with a macromolecular compound other than an unsaturated polymer of groups C09D159/00 - C09D187/00
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/011—Nanostructured additives
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/34—Silicon-containing compounds
- C08K3/36—Silica
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K7/00—Use of ingredients characterised by shape
- C08K7/22—Expanded, porous or hollow particles
- C08K7/24—Expanded, porous or hollow particles inorganic
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K9/00—Use of pretreated ingredients
- C08K9/04—Ingredients treated with organic substances
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Materials Engineering (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Ceramic Engineering (AREA)
- Health & Medical Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Wood Science & Technology (AREA)
- Structural Engineering (AREA)
- Paints Or Removers (AREA)
Abstract
The invention provides a kind of novel ink stone, it includes inkstone parent and the anticorrosion layer positioned at rub-down ink area and the light-absorption layer positioned at the female body sidewall of inkstone.The inkstone is not susceptible to corrosion phenomenon, and intensity is high, will not cause reduction in performance of ink, also, the novel ink stone can prevent prepared Chinese ink from solidifying.
Description
Technical field
The present invention relates to inkstone technical field, more particularly to a kind of novel ink stone for storing ink and heating function.
Background technology
Inkstone is one of important class of the traditional divine force that created the universe of ancient Chinese, the hat of the writing brush, ink stick, ink slab and paper, be collection it is aesthetic with it is practical be one
The ancient Chinese art design of body.The need for inkstone is born in use, from with the art work that combination of appreciation and practicality is gradually evolved into for ancestor.In
Among one inkstone, we, which can not only sample, enjoys the beautiful of material texture, carves intention, and the Seiko of artistic technique is exquisite, meanwhile,
Inkstone is undoubtedly a posting of traditional Chinese culture, accumulation and epitome.
Traditional inkstone passes through under the use of long period, the corrosion that prepared Chinese ink is produced, and crack, shape easily occurs in inkstone
Into tiny hole, make inkstone intensity decreases, crack makes ink permeation, cause storage performance of ink reduction.In addition, existing inkstone exists
In the case that weather is colder, the prepared Chinese ink of grinding can turn cold, and solidification, influence is used.
The invention provides novel ink stone, the inkstone is not susceptible to corrosion phenomenon, and intensity is high, will not cause drop in performance of ink
It is low, also, the novel ink stone can prevent prepared Chinese ink from solidifying.
The content of the invention
The technical problems to be solved by the invention are to provide a kind of novel ink stone, and the inkstone is not susceptible to corrosion phenomenon, by force
Degree is high, will not cause reduction in performance of ink, also, the novel ink stone can prevent prepared Chinese ink from solidifying.
In order to solve the above technical problems, the invention provides a kind of novel ink stone, it includes inkstone parent and positioned at rub-down ink
The anticorrosion layer in area and the light-absorption layer positioned at the female body sidewall of inkstone.
Preparing the raw material of the parent includes calcite, clay, quartz, silica modified unsaturated polyester (UP) and solidification
Agent.
The percentage by weight of each raw material is respectively calcite 3%~8%, clay 35%~40%, quartz 35% in the parent
~45%, silica modified unsaturated polyester (UP) 15%~20% and curing agent 1%~2%, the quality sum of each raw material is 100%.
The preparation method of the silica modified polyester includes：
The first step, silica is crushed, and is dried at high temperature, crosses 100 mesh sieves, often takes the silicon dioxide powder after 300g sievings
End, adds the aqueous solution 200ml (content of stearic acid sodium is 3g in 100ml solution) of surface modifier stearic acid sodium, in room temperature
Lower high-speed stirred 30 minutes, filtering, filter cake is washed 3 times with absolute ethyl alcohol, and each ethanol consumption is 30ml, filtration cakes torrefaction, grinding
Into powder；
Second step, using 5g rutgerses as measurement basis, often added in reaction vessel 5g dimethyl terephthalate (DMT)s,
1,2-PD 10g, tetra-n-butyl titanate 1g are added, nitrogen is passed through in reaction vessel, heat temperature raising, after being opened after material melts
Begin to stir, controlling reaction temperature is in 180 degree, when acid number drops to 8mgKOH/g, reduce temperature, further add 30g maleics
Dicarboxylic anhydride, 1,2-PD 30g30g (based on 5g dimethyl terephthalate (DMT)s), proceed esterification, control reaction
Temperature stirs 2 hours~3 hours at 200 DEG C or so, is cooled to 90 DEG C, insulated and stirred is uniformly produced.
3rd step, the powder for often taking the 5g first steps to prepare is added in the product of second step preparation and is sufficiently stirred for, and adds and promotees
Enter agent benzoyl peroxide 0.05g to be mixed evenly, be put into after vacuum defoamation in vacuum drying chamber, normal temperature cure 24h, then rise
Temperature is ground into powder to 90 DEG C of solidification 2h.
For formed the anticorrosion layer the corrosion resistance coating raw material include alkamine modified epoxy resin, silica,
Water, pyrrolidones, acrylate and KH-560.
The weight of each raw material is respectively in the corrosion resistance coating, relative to the alkamine modified epoxy resin of 100 parts by weight, institute
It is the parts by weight of 40 parts by weight~50 to state the consumption of silica, and the parts by weight of the pyrrolidones are the parts by weight of 5 parts by weight~8,
The parts by weight of parts by weight of acrylate 20~30, KH-560 is the parts by weight of 3 parts by weight~5, and in terms of solid, the consumption of the water is
The parts by weight of 100 parts by weight~150.
The preparation method of the alkamine modified epoxy resin is that solvent absolute ethyl alcohol and bisphenol A-type are added in reaction vessel
The mol ratio of epoxy resin, stirring preheating 50 minutes at 60 DEG C, solvent absolute ethyl alcohol and bisphenol A type epoxy resin is 4:1, with
After be slowly added to diglycolamine, the mol ratio of diglycolamine and bisphenol A type epoxy resin is 0.3:1, it is warming up to 85 DEG C of reactions 3 small
When, then it is cooled in 60 DEG C of addition glacial acetic acid and neutralizes into salt, the mol ratio of bisphenol A type epoxy resin and glacial acetic acid is 1:0.3
~0.4, react 40 minutes, add deionized water, obtain alkamine modified epoxy resin, bisphenol A type epoxy resin and deionized water
Ratio be 1mol resins correspondence 10ml deionized waters.
The raw material of light absorption paint for forming the light-absorption layer includes sulfonate modified CNT, diazo naphthoquinone chemical combination
Thing, novolac resin and ethyl lactate solvent.
The parts by weight of each raw material are respectively the weight of sulfonate modified parts by weight of CNT 5~10 in the light absorption paint
Part, the parts by weight of the parts by weight of parts by weight of diazo naphthoquinone compound 8~12, the parts by weight of novolac resin 50~60 and ethyl lactate it is molten
The parts by weight of parts by weight of agent 30~40.
The preparation method of the diazo naphthoquinone compound is in terms of 5g diazo naphthoquinone sulfonic acid chloride weight, by diazo naphthoquinone sulphonyl
Chlorine 5g and trihydroxybenzophenone 2g is put into reaction vessel, is added 50ml acetone stirring and dissolvings, is subsequently added 5ml water, slowly
The triethylamine with trihydroxybenzophenone equimolar amounts is added dropwise, triethylamine is dissolved in acetone soln and is added dropwise, after completion of dropping extremely
Reaction is completed, and reaction solution is stirred down and poured into 300ml distilled water, is added chloride solid and is dissolved, promotes reaction product
Separate out, filtering is washed three times, is dried into perseverance, is obtained solid.
The preparation method of the sulfonate modified CNT includes：
The first step, by CNT immersion in concentrated sulfuric acid, ultrasonic disperse, the reflow treatment 1h at 90 DEG C, suction filtration and spend from
Son is washed to neutrality, freezes；
Second step, the product of the first step is dissolved in water, and is added drop-wise in aminobenzenesulfonic acid diazonium salt solution, CNT and ammonia
The mass ratio of base benzene sulfonic acid diazol is 1:2, react in a water bath 5 hours, then continue to react 3 hours at normal temperatures, reaction
Suction filtration, and use deionized water rinsing afterwards, it is lyophilized to obtain product.
Present invention also offers the preparation method of above-mentioned inkstone, it includes：
The first step, each raw material is added and stirred in mixer, is packed into mould, and uniform compaction solidifies 3 at 30 DEG C~40 DEG C
Hour, obtain parent；
Second step, engraving, parent is engraved as needed the pattern of various needs；
3rd step, polishing carries out black system to the parent after engraving, makes its smooth, smooth, remove unnecessary tool marks；
4th step, coating, in the rub-down ink area coating corrosion resistance coating formation anticorrosion layer of parent, in side, wall coating light absorption paint formation is inhaled
Photosphere.
Beneficial effects of the present invention:
The inkstone that the present invention is provided is not susceptible to corrosion phenomenon, and intensity is high, will not cause reduction in performance of ink, also, this is new
Inkstone can prevent prepared Chinese ink from solidifying.
Brief description of the drawings
The infrared spectrum of the alkamine modified epoxy resin of Fig. 1；
The infrared spectrum of the silica modified polyester of Fig. 2；
The infrared spectrum of the sulfonate modified CNTs of Fig. 3.
Embodiment
The invention provides a kind of novel ink stone, it includes inkstone parent and anticorrosion layer positioned at rub-down ink area and positioned at inkstone
The light-absorption layer of female body sidewall.
Preparing the raw material of the parent includes calcite, clay, quartz, silica modified unsaturated polyester (UP) and solidification
Agent.
Further preferably, the parent is only prepared from by above-mentioned raw materials.
The percentage by weight of each raw material is respectively calcite 3%~8%, clay 35%~40%, quartz 35% in the parent
~45%, silica modified unsaturated polyester (UP) 15%~20% and curing agent 1%~2%, the quality sum of each raw material is 100%.
The weight of each raw material is further preferably respectively calcite 6%, clay 35%, quartz 40%, dioxy in the parent
SiClx modified unsaturated polyester 18% and curing agent 1%.
The curing agent is methyl ethyl ketone peroxide.
The addition of silica modified polyester can strengthen its toughness while inkstone hardness is kept, and reduce due to corrosion
Inkstone hardness is reduced caused by the crack that phenomenon is produced, and reduces the broken possibility of inkstone.The silica modified polyester
Preparation method includes：
The first step, silica is crushed, and is dried at high temperature, crosses 100 mesh sieves, often takes the silicon dioxide powder after 300g sievings
End, adds the aqueous solution 200ml (content of stearic acid sodium is 3g in 100ml solution) of surface modifier stearic acid sodium, in room temperature
Lower high-speed stirred 30 minutes, filtering, filter cake is washed 3 times with absolute ethyl alcohol, and each ethanol consumption is 30ml, filtration cakes torrefaction, grinding
Into powder；
Second step, using 5g rutgerses as measurement basis, often added in reaction vessel 5g dimethyl terephthalate (DMT)s,
1,2-PD 10g, tetra-n-butyl titanate 1g are added, nitrogen is passed through in reaction vessel, heat temperature raising, after being opened after material melts
Begin to stir, controlling reaction temperature is in 180 degree, when acid number drops to 8mgKOH/g, reduce temperature, further add 30g maleics
Dicarboxylic anhydride, 1,2-PD 30g30g (based on 5g dimethyl terephthalate (DMT)s), proceed esterification, control reaction
Temperature stirs 2 hours~3 hours at 200 DEG C or so, is cooled to 90 DEG C, insulated and stirred is uniformly produced.
3rd step, the powder for often taking the 5g first steps to prepare is added in the product of second step preparation and is sufficiently stirred for, and adds and promotees
Enter agent benzoyl peroxide 0.05g to be mixed evenly, be put into after vacuum defoamation in vacuum drying chamber, normal temperature cure 24h, then rise
Temperature is ground into powder to 90 DEG C of solidification 2h.
Present invention also offers the preparation method of above-mentioned inkstone, it includes：
The first step, each raw material is added and stirred in mixer, is packed into mould, and uniform compaction solidifies 3 at 30 DEG C~40 DEG C
Hour, obtain parent；
Second step, engraving, parent is engraved as needed the pattern of various needs；
3rd step, polishing carries out black system to the parent after engraving, makes its smooth, smooth, remove unnecessary tool marks；
4th step, coating, in the rub-down ink area coating corrosion resistance coating formation anticorrosion layer of parent, in side, wall coating light absorption paint formation is inhaled
Photosphere.
The anticorrosion layer is to coat a floor corrosion resistance coating in rub-down ink area on the basis of inkstone parent to form, and anticorrosion layer is deposited
Do not contacted easily with parent making prepared Chinese ink, thus prevent corrosion produce crack caused by inkstone hardness reduce.
The raw material of the corrosion resistance coating includes alkamine modified epoxy resin, silica, water, pyrrolidones, acrylate
And KH-560.
Further, the corrosion resistance coating is only prepared from by above-mentioned raw materials.
The weight of each raw material is respectively in the corrosion resistance coating, relative to the alkamine modified epoxy resin of 100 parts by weight, institute
It is the parts by weight of 40 parts by weight~50 to state the consumption of silica, and the parts by weight of the pyrrolidones are the parts by weight of 5 parts by weight~8,
The parts by weight of parts by weight of acrylate 20~30, KH-560 is the parts by weight of 3 parts by weight~5, and in terms of solid, the consumption of the water is
The parts by weight of 100 parts by weight~150.
Further preferably, the weight of each raw material is respectively in the corrosion resistance coating, alkamine modified relative to 100 parts by weight
Epoxy resin, the consumption of the silica is 50 parts by weight, and the parts by weight of the pyrrolidones are 6 parts by weight, acrylate
25 parts by weight, KH-560 is 4 parts by weight, in terms of solid, and the consumption of the water is 120 parts by weight.
The preparation method of the alkamine modified epoxy resin is that solvent absolute ethyl alcohol and bisphenol A-type are added in reaction vessel
The mol ratio of epoxy resin, stirring preheating 50 minutes at 60 DEG C, solvent absolute ethyl alcohol and bisphenol A type epoxy resin is 4:1, with
After be slowly added to diglycolamine, the mol ratio of diglycolamine and bisphenol A type epoxy resin is 0.3:1, it is warming up to 85 DEG C of reactions 3 small
When, then it is cooled in 60 DEG C of addition glacial acetic acid and neutralizes into salt, the mol ratio of bisphenol A type epoxy resin and glacial acetic acid is 1:0.3
~0.4, react 40 minutes, add deionized water, obtain alkamine modified epoxy resin, bisphenol A type epoxy resin and deionized water
Ratio be 1mol resins correspondence 10ml deionized waters.
The bisphenol A type epoxy resin is epoxy resin E51.
It is specially to be blended in above-mentioned each raw material by weight present invention also offers the preparation method of above-mentioned corrosion resistance coating
Together, 30 DEG C~40 DEG C are heated to, is stirred 2~3 hours, room temperature is down to, coating is obtained.
The light-absorption layer is to coat one layer of light absorption paint in side wall on the basis of inkstone parent to form, and the light-absorption layer leads to
Cross and luminous energy is changed into heat energy, inkstone bulk temperature can be made higher, it is ensured that prepared Chinese ink is difficult to condense into solid, convenient use.
The raw material of the light absorption paint includes sulfonate modified CNT, diazo naphthoquinone compound, novolac resin
With ethyl lactate solvent.
Further preferably, the light absorption paint is only prepared from by above-mentioned raw materials.
The parts by weight of each raw material are respectively the weight of sulfonate modified parts by weight of CNT 5~10 in the light absorption paint
Part, the parts by weight of the parts by weight of parts by weight of diazo naphthoquinone compound 8~12, the parts by weight of novolac resin 50~60 and ethyl lactate it is molten
The parts by weight of parts by weight of agent 30~40.
Further preferably, the parts by weight of each raw material are respectively the sulfonate modified weight of CNT 8 in the light absorption paint
Part, the parts by weight of diazo naphthoquinone compound 10, the parts by weight of novolac resin 55 and the parts by weight of ethyl lactate solvent 35.
The preparation method of the diazo naphthoquinone compound is in terms of 5g diazo naphthoquinone sulfonic acid chloride weight, by diazo naphthoquinone sulphonyl
Chlorine 5g and trihydroxybenzophenone 2g is put into reaction vessel, is added 50ml acetone stirring and dissolvings, is subsequently added 5ml water, slowly
The triethylamine with trihydroxybenzophenone equimolar amounts is added dropwise, triethylamine is dissolved in acetone soln and is added dropwise, after completion of dropping extremely
Reaction is completed, and reaction solution is stirred down and poured into 300ml distilled water, is added chloride solid and is dissolved, promotes reaction product
Separate out, filtering is washed three times, is dried into perseverance, is obtained solid.
The preparation method of the sulfonate modified CNT includes：
The first step, by CNT immersion in concentrated sulfuric acid, ultrasonic disperse, the reflow treatment 1h at 90 DEG C, suction filtration and spend from
Son is washed to neutrality, freezes；
Second step, the product of the first step is dissolved in water, and is added drop-wise in aminobenzenesulfonic acid diazonium salt solution, CNT and ammonia
The mass ratio of base benzene sulfonic acid diazol is 1:2, react in a water bath 5 hours, then continue to react 3 hours at normal temperatures, reaction
Suction filtration, and use deionized water rinsing afterwards, it is lyophilized to obtain product.
The concentrated sulfuric acid is commercially available prod, and concentration is 98%.
It is specially to be blended in above-mentioned each raw material by weight present invention also offers the preparation method of above-mentioned light absorption paint
Together, 45 DEG C~60 DEG C are heated to, is stirred 1~2 hour, room temperature is down to, coating is obtained.
Describe embodiments of the present invention in detail using embodiment below, whereby to the present invention how application technology means
To solve technical problem, and reach the implementation process of technique effect and can fully understand and implement according to this.
The alkamine modified epoxy resin of embodiment 1
Solvent absolute ethyl alcohol and bisphenol A type epoxy resin E51 are added in reaction vessel, both mol ratios are 4:1, at 60 DEG C
Lower stirring preheating 50 minutes, is then slowly added to diglycolamine, and diglycolamine and bisphenol A type epoxy resin E51 mol ratio are
0.3:1, it is warming up to 85 DEG C and reacts 3 hours, is then cooled in 60 DEG C of addition glacial acetic acid and neutralizes into salt, bisphenol A type epoxy resin
The mol ratio of E51 and glacial acetic acid is 1:0.3, react 40 minutes, add deionized water, obtain alkamine modified epoxy resin, bisphenol-A
The ratio of type epoxy resin and deionized water is the corresponding 10ml deionized waters of 1mol resins, obtains alkamine modified epoxy resin.
The infrared spectrum of product is shown in that Fig. 1, a are epoxy resin spectrogram before modified, and b is modified epoxy resin spectrogram.
The silica modified polyester of embodiment 2
Silica is crushed, dried at high temperature, 100 mesh sieves are crossed, the SiO 2 powder after 300g sievings is often taken, adds table
The aqueous solution 200ml (in 100ml solution the content of stearic acid sodium be 3g) of face modifying agent stearic acid sodium, at room temperature high-speed stirred
30 minutes, filtering, filter cake was washed 3 times with absolute ethyl alcohol, and each ethanol consumption is 30ml, filtration cakes torrefaction, grind into powder, with 5g
Rutgers is measurement basis, and 5g dimethyl terephthalate (DMT)s, addition 1,2-PD are often added in reaction vessel
10g, tetra-n-butyl titanate 1g, are passed through nitrogen in reaction vessel, and heat temperature raising, after starting stirring after material melts, is controlled anti-
Temperature is answered in 180 degree, when acid number drops to 8mgKOH/g, temperature is reduced, further adds 30g maleic anhydrides, 1,2- third
Glycol 30g30g (based on 5g dimethyl terephthalate (DMT)s), proceeds esterification, controlling reaction temperature is on 200 DEG C of left sides
The right side, is stirred 2 hours~3 hours, is cooled to 90 DEG C, insulated and stirred is uniformly produced, and the powder for often taking the 5g first steps to prepare is added to
It is sufficiently stirred in product prepared by second step, adds accelerator benzoyl peroxide 0.05g and be mixed evenly, is put into vacuum and does
After vacuum defoamation in dry case, normal temperature cure 24h, then 90 DEG C of solidification 2h are warming up to, are ground into powder, obtain silica modified poly-
Ester.
The infrared spectrum of product is shown in that Fig. 2, a are silica modified spectrogram, and b is polyester infrared spectrum, and c is product spectrogram.
The diazo naphthoquinone compound of embodiment 3
In terms of 5g diazo naphthoquinone sulfonic acid chloride weight, diazo naphthoquinone sulfonic acid chloride 5g and trihydroxybenzophenone 2g are put into reaction vessel
In, 50ml acetone stirring and dissolvings are added, 5ml water is subsequently added, three second with trihydroxybenzophenone equimolar amounts is slowly added dropwise
Amine, triethylamine is dissolved in acetone soln and is added dropwise, and is completed after completion of dropping to reaction, reaction solution is stirred down and pours into 300ml
In distilled water, add chloride solid and dissolve, promote reaction product to separate out, filter, wash three times, dry into perseverance, obtain
Solid.
In terms of infrared spectrum, diazo naphthoquinone compound is in 3430cm-1 There is the broad peak of moderate strength at place, illustrates in product
There are hydroxyl, 2149 cm-1 The absorption at place, which illustrates to contain in product, is free of CC in cyano group or triple carbon-carbon bonds, but reactant
The three keys and reaction can not generate the keys of CC tri-, therefore contain cyano group in product, in 1602 cm-1 There is sharp absorption at place
Illustrate there is phenyl ring in product, the cm of diazonium naphthoquinone sulphonate 3433-1- OH characteristic absorption peaks weaken, illustrate there has been the hydroxyl of part three
With diazo naphthoquinone sulfonic acid chloride esterification occurs for base benzophenone.
The sulfonate modified CNT of embodiment 4
CNT is immersed in the concentrated sulfuric acid that commercial concentration is 98%, ultrasonic disperse, reflow treatment 1h, suction filtration at 90 DEG C
And be washed with deionized water to neutrality, freeze, product is dissolved in water, is added drop-wise in aminobenzenesulfonic acid diazonium salt solution, carbon is received
The mass ratio of mitron and aminobenzenesulfonic acid diazol is 1:2, react in a water bath 5 hours, then continue reaction 3 at normal temperatures small
When, suction filtration after reaction, and deionized water rinsing is used, it is lyophilized to obtain product.
The infrared spectrum of sulfonate modified CNT is shown in that Fig. 3, a are the infrared spectrum of CNT, and b is sulfonated carbon
Nanotube spectrogram.
The corrosion resistance coating of embodiment 5
By 1kg alkamine modified epoxy resin, 0.5kg silica, 60g pyrrolidones, 0.25kg acrylate, 40gKH-
560, water 1.2kg is mixed, and is heated to 30 DEG C, is stirred 2.5 hours, is down to room temperature, obtains coating.
The light absorption paint of embodiment 6
Diazo naphthoquinone compound 100g, phenolic aldehyde prepared by sulfonate modified CNT 80g prepared by embodiment 4, embodiment 3
Varnish gum 5.5kg and ethyl lactate solvent 3.5kg are mixed, and are heated to 50 DEG C, are stirred 2 hours, are down to room temperature, are obtained
Coating.
The preparation of the inkstone of embodiment 7
By calcite 60g, clay 350g, quartz 400, silica modified unsaturated polyester (UP) 180g and curing agent peroxidating first
Ethyl ketone 10g is added to stir in mixer, is packed into mould, and uniform compaction solidifies 3 hours at 40 DEG C, parent obtained, by mother
Body is engraved as the pattern of various needs as needed, and black system is carried out to the parent after engraving, makes its smooth, smooth, should not removed
Some tool marks, the corrosion resistance coating formation anticorrosion layer prepared in the rub-down ink area coating embodiment 5 of parent, in side, wall coats embodiment 6
The light absorption paint formation light-absorption layer of preparation, so as to prepare inkstone.
The corrosion resisting property of the inkstone of embodiment 8
The inkstone of the preparation of embodiment 7, inkstone prepared by calcite, the inkstone of marble preparation is chosen to be compared.
Black duration is store to ink-stone in 4 DEG C, 20 DEG C or so respectively and carries out simulated experiment, 1 is the results are shown in Table.
The black duration simulated experiment of the ink-stone of table 1 storage
| Inkstone of the present invention | Calcite inkstone | Marble inkstone | |
| 4 ℃ | 43.0h | 5.8h | 7.3h |
| 20 ℃ | 60.0h | 8.6h | 11.5h |
As a result show, the time that ink retains in inkstone sample aperture prepared by the embodiment of the present invention 7 is longer, it is a length of during storage ink
43.0~60.0 h, retention time is appreciably shorter in calcite inkstone and marble inkstone, a length of 5.8~11.5h during storage ink.
Here, it can be seen that dissolution extent is lower, mineral arrangement is close under the microscope, and consistency is high, water penetration effect
Difference, storage performance of ink is good.
All above-mentioned this intellectual properties of primarily implementation, the not this new product of implementation of setting limitation other forms
And/or new method.Those skilled in the art will utilize this important information, the above modification, to realize similar execution feelings
Condition.But, all modifications or transformation belong to the right of reservation based on new product of the present invention.
The above described is only a preferred embodiment of the present invention, being not the limitation for making other forms to the present invention, appoint
What those skilled in the art changed or be modified as possibly also with the technology contents of the disclosure above equivalent variations etc.
Imitate embodiment.But it is every without departing from technical solution of the present invention content, the technical spirit according to the present invention is to above example institute
Any simple modification, equivalent variations and the remodeling made, still fall within the protection domain of technical solution of the present invention.
Claims (9)
1. a kind of novel ink stone, it is characterised in that：Including inkstone parent and positioned at rub-down ink area anticorrosion layer and positioned at inkstone parent
The light-absorption layer of side wall.
2. novel ink stone as claimed in claim 1, it is characterised in that：Prepare the parent raw material include calcite, clay,
Quartz, silica modified unsaturated polyester (UP) and curing agent.
3. novel ink stone as claimed in claim 1 or 2, it is characterised in that：The weight percent score of each raw material in the parent
Wei not calcite 3%~8%, clay 35%~40%, quartz 35%~45%, the and of silica modified unsaturated polyester (UP) 15%~20%
Curing agent 1%~2%, the quality sum of each raw material is 100%.
4. the novel ink stone as described in claims 1 to 3, it is characterised in that：The preparation method of the silica modified polyester
Including,
The first step, silica is crushed, and is dried at high temperature, crosses 100 mesh sieves, often takes the silicon dioxide powder after 300g sievings
End, adds the aqueous solution 200ml (content of stearic acid sodium is 3g in 100ml solution) of surface modifier stearic acid sodium, in room temperature
Lower high-speed stirred 30 minutes, filtering, filter cake is washed 3 times with absolute ethyl alcohol, and each ethanol consumption is 30ml, filtration cakes torrefaction, grinding
Into powder；
Second step, using 5g rutgerses as measurement basis, often added in reaction vessel 5g dimethyl terephthalate (DMT)s,
1,2-PD 10g, tetra-n-butyl titanate 1g are added, nitrogen is passed through in reaction vessel, heat temperature raising, after being opened after material melts
Begin to stir, controlling reaction temperature is in 180 degree, when acid number drops to 8mgKOH/g, reduce temperature, further add 30g maleics
Dicarboxylic anhydride, 1,2-PD 30g30g (based on 5g dimethyl terephthalate (DMT)s), proceed esterification, control reaction
Temperature stirs 2 hours~3 hours at 200 DEG C or so, is cooled to 90 DEG C, insulated and stirred is uniformly produced；
3rd step, the powder for often taking the 5g first steps to prepare is added in the product of second step preparation and is sufficiently stirred for, and adds accelerator
Benzoyl peroxide 0.05g is mixed evenly, and is put into after vacuum defoamation in vacuum drying chamber, normal temperature cure 24h, then be warming up to
90 DEG C of solidification 2h, are ground into powder.
5. the novel ink stone as described in Claims 1-4, it is characterised in that：The anti-corrosion painting for forming the anticorrosion layer
The raw material of material includes alkamine modified epoxy resin, silica, water, pyrrolidones, acrylate and KH-560.
6. the novel ink stone as described in claim 1 to 5, it is characterised in that：The weight difference of each raw material in the corrosion resistance coating
For, relative to the alkamine modified epoxy resin of 100 parts by weight, the consumption of the silica is the parts by weight of 40 parts by weight~50,
The parts by weight of the pyrrolidones are the parts by weight of 5 parts by weight~8, the parts by weight of parts by weight of acrylate 20~30, and KH-560 is 3 weights
The parts by weight of part~5 are measured, in terms of solid, the consumption of the water is the parts by weight of 100 parts by weight~150.
7. the novel ink stone as described in claim 1 to 6, it is characterised in that：Light absorption paint for forming the light-absorption layer
Raw material includes sulfonate modified CNT, diazo naphthoquinone compound, novolac resin and ethyl lactate solvent.
8. the novel ink stone as described in claim 1 to 7, it is characterised in that：The parts by weight of each raw material point in the light absorption paint
Wei not the parts by weight of sulfonate modified parts by weight of CNT 5~10, the parts by weight of parts by weight of diazo naphthoquinone compound 8~12, phenolic aldehyde
The parts by weight of the parts by weight of parts by weight of varnish gum 50~60 and the parts by weight of ethyl lactate solvent 30~40.
9. the preparation method of inkstone described in claim 1 to 8, it is characterised in that including：
The first step, each raw material is added and stirred in mixer, is packed into mould, and uniform compaction solidifies 3 at 30 DEG C~40 DEG C
Hour, obtain parent；
Second step, engraving, parent is engraved as needed the pattern of various needs；
3rd step, polishing carries out black system to the parent after engraving, makes its smooth, smooth, remove unnecessary tool marks；
4th step, coating, in the rub-down ink area coating corrosion resistance coating formation anticorrosion layer of parent, in side, wall coating light absorption paint formation is inhaled
Photosphere.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710270934.0A CN107128110B (en) | 2017-04-24 | 2017-04-24 | Novel ink stone |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710270934.0A CN107128110B (en) | 2017-04-24 | 2017-04-24 | Novel ink stone |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN107128110A true CN107128110A (en) | 2017-09-05 |
| CN107128110B CN107128110B (en) | 2018-06-19 |
Family
ID=59715053
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201710270934.0A Active CN107128110B (en) | 2017-04-24 | 2017-04-24 | Novel ink stone |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN107128110B (en) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110757822A (en) * | 2018-07-26 | 2020-02-07 | 安徽省绩溪旭龙山庄四宝文化有限公司 | Method for manufacturing inkstone by utilizing inkstone leftover materials |
| CN110760250A (en) * | 2018-07-27 | 2020-02-07 | 安徽省绩溪旭龙山庄四宝文化有限公司 | Corrosion-resistant inkstone |
| CN110759709A (en) * | 2018-07-25 | 2020-02-07 | 安徽省绩溪旭龙山庄四宝文化有限公司 | Coal gangue-based artificial inkstone and preparation method thereof |
Citations (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1156157A (en) * | 1996-01-31 | 1997-08-06 | 何信伟 | Plastic material and its use |
| CN103144477A (en) * | 2013-02-01 | 2013-06-12 | 上海维凯化学品有限公司 | Ink slab with grinding layer and preparing method thereof |
| CN203093554U (en) * | 2013-02-01 | 2013-07-31 | 上海维凯化学品有限公司 | Novel ink-stone |
| CN103640380A (en) * | 2013-11-22 | 2014-03-19 | 大连创达技术交易市场有限公司 | Traditional Chinese painting ink grinding device with heating function |
| CN103819134A (en) * | 2013-12-31 | 2014-05-28 | 北京仁创砂艺文化有限公司 | Silica sand inkstone and preparation method thereof |
| CN103864400A (en) * | 2014-01-20 | 2014-06-18 | 惠东存 | Method for manufacturing Chengni inkstone |
| CN204955821U (en) * | 2015-07-24 | 2016-01-13 | 张盈睿 | Cap of a pen generates heat |
| CN105415473A (en) * | 2015-10-29 | 2016-03-23 | 安徽省俞金海漆器工艺有限公司 | Paint-emery inkstone |
-
2017
- 2017-04-24 CN CN201710270934.0A patent/CN107128110B/en active Active
Patent Citations (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1156157A (en) * | 1996-01-31 | 1997-08-06 | 何信伟 | Plastic material and its use |
| CN103144477A (en) * | 2013-02-01 | 2013-06-12 | 上海维凯化学品有限公司 | Ink slab with grinding layer and preparing method thereof |
| CN203093554U (en) * | 2013-02-01 | 2013-07-31 | 上海维凯化学品有限公司 | Novel ink-stone |
| CN103640380A (en) * | 2013-11-22 | 2014-03-19 | 大连创达技术交易市场有限公司 | Traditional Chinese painting ink grinding device with heating function |
| CN103819134A (en) * | 2013-12-31 | 2014-05-28 | 北京仁创砂艺文化有限公司 | Silica sand inkstone and preparation method thereof |
| CN103864400A (en) * | 2014-01-20 | 2014-06-18 | 惠东存 | Method for manufacturing Chengni inkstone |
| CN204955821U (en) * | 2015-07-24 | 2016-01-13 | 张盈睿 | Cap of a pen generates heat |
| CN105415473A (en) * | 2015-10-29 | 2016-03-23 | 安徽省俞金海漆器工艺有限公司 | Paint-emery inkstone |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110759709A (en) * | 2018-07-25 | 2020-02-07 | 安徽省绩溪旭龙山庄四宝文化有限公司 | Coal gangue-based artificial inkstone and preparation method thereof |
| CN110757822A (en) * | 2018-07-26 | 2020-02-07 | 安徽省绩溪旭龙山庄四宝文化有限公司 | Method for manufacturing inkstone by utilizing inkstone leftover materials |
| CN110760250A (en) * | 2018-07-27 | 2020-02-07 | 安徽省绩溪旭龙山庄四宝文化有限公司 | Corrosion-resistant inkstone |
Also Published As
| Publication number | Publication date |
|---|---|
| CN107128110B (en) | 2018-06-19 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN107128110B (en) | Novel ink stone | |
| CN110041021B (en) | Environmentally friendly soil-solidified-agent and preparation method thereof | |
| CN105622161B (en) | Cement base foamed light composite material and preparation method | |
| CN104014728B (en) | A kind of blast-furnace cinder alcohol-base foundry coating and preparation method thereof | |
| CN104190858B (en) | Alcohol-base foundry coating that a kind of sillimanite/titanium dioxide is compound and preparation method thereof | |
| CN106270370A (en) | A kind of needle prick shape cylinder jacket and preparation method thereof | |
| CN104439045A (en) | Rice hull lost foam alcohol-based casting coating and preparation method thereof | |
| CN104014720A (en) | Quartz sand/fire clay composite alcohol group casting coating and preparation method thereof | |
| CN105368383A (en) | Foamed plastic binder for centrifugal pump lost foam casting | |
| CN110238931A (en) | A kind of high efficiency bronze ware manufacture craft | |
| CN100409973C (en) | Water base paint special for resin sand automobile mould full mold casting | |
| CN102417322A (en) | Raw material for sculpture and production method thereof | |
| CN102529556B (en) | Artificial exquisite crystal environmental-protection stone material craft calligraphy and painting plaque and preparing method thereof | |
| CN105837094B (en) | A kind of medium-sized fused cast refractories mo(u)ld blacking | |
| CN107400505A (en) | A kind of high-temp solid foam discharging agent and preparation method | |
| CN106379100A (en) | Egg carving based on art sculpture forming mud and preparation method thereof | |
| CN109081674A (en) | A kind of artificial stone and its production method | |
| CN102557573A (en) | Artificial sandstone and preparation method thereof | |
| KR100815315B1 (en) | A manufacturing process of an artificial basalt stone | |
| CN1864889A (en) | A method for cleaning core sand of cast piece by use of crumbling agent | |
| CN110102706A (en) | A kind of EPC disappears molding potassium steel coating and preparation method thereof | |
| CN104525452B (en) | A kind of cold nonirrigated farmland district historic building structure protection against the tide construction method | |
| CN106280585A (en) | A kind of for painting feed liquid preparing needle prick shape cylinder jacket and preparation method thereof | |
| CN107655344A (en) | A kind of porcelain agglomerating plant | |
| CN109836861A (en) | A kind of preparation method of casting magnesium aluminum alloy coating |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| GR01 | Patent grant | ||
| GR01 | Patent grant |