CN107120523A - A kind of hydrogen storage aqueous hydrogenation machine and its method of hydrotreating - Google Patents
A kind of hydrogen storage aqueous hydrogenation machine and its method of hydrotreating Download PDFInfo
- Publication number
- CN107120523A CN107120523A CN201710293894.1A CN201710293894A CN107120523A CN 107120523 A CN107120523 A CN 107120523A CN 201710293894 A CN201710293894 A CN 201710293894A CN 107120523 A CN107120523 A CN 107120523A
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- China
- Prior art keywords
- hydrogen storage
- fluid reservoir
- gas
- storage aqueous
- hydrogenation machine
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Classifications
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F17—STORING OR DISTRIBUTING GASES OR LIQUIDS
- F17C—VESSELS FOR CONTAINING OR STORING COMPRESSED, LIQUEFIED OR SOLIDIFIED GASES; FIXED-CAPACITY GAS-HOLDERS; FILLING VESSELS WITH, OR DISCHARGING FROM VESSELS, COMPRESSED, LIQUEFIED, OR SOLIDIFIED GASES
- F17C7/00—Methods or apparatus for discharging liquefied, solidified, or compressed gases from pressure vessels, not covered by another subclass
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F17—STORING OR DISTRIBUTING GASES OR LIQUIDS
- F17C—VESSELS FOR CONTAINING OR STORING COMPRESSED, LIQUEFIED OR SOLIDIFIED GASES; FIXED-CAPACITY GAS-HOLDERS; FILLING VESSELS WITH, OR DISCHARGING FROM VESSELS, COMPRESSED, LIQUEFIED, OR SOLIDIFIED GASES
- F17C11/00—Use of gas-solvents or gas-sorbents in vessels
- F17C11/005—Use of gas-solvents or gas-sorbents in vessels for hydrogen
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F17—STORING OR DISTRIBUTING GASES OR LIQUIDS
- F17C—VESSELS FOR CONTAINING OR STORING COMPRESSED, LIQUEFIED OR SOLIDIFIED GASES; FIXED-CAPACITY GAS-HOLDERS; FILLING VESSELS WITH, OR DISCHARGING FROM VESSELS, COMPRESSED, LIQUEFIED, OR SOLIDIFIED GASES
- F17C13/00—Details of vessels or of the filling or discharging of vessels
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F17—STORING OR DISTRIBUTING GASES OR LIQUIDS
- F17C—VESSELS FOR CONTAINING OR STORING COMPRESSED, LIQUEFIED OR SOLIDIFIED GASES; FIXED-CAPACITY GAS-HOLDERS; FILLING VESSELS WITH, OR DISCHARGING FROM VESSELS, COMPRESSED, LIQUEFIED, OR SOLIDIFIED GASES
- F17C13/00—Details of vessels or of the filling or discharging of vessels
- F17C13/12—Arrangements or mounting of devices for preventing or minimising the effect of explosion ; Other safety measures
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F17—STORING OR DISTRIBUTING GASES OR LIQUIDS
- F17C—VESSELS FOR CONTAINING OR STORING COMPRESSED, LIQUEFIED OR SOLIDIFIED GASES; FIXED-CAPACITY GAS-HOLDERS; FILLING VESSELS WITH, OR DISCHARGING FROM VESSELS, COMPRESSED, LIQUEFIED, OR SOLIDIFIED GASES
- F17C2227/00—Transfer of fluids, i.e. method or means for transferring the fluid; Heat exchange with the fluid
- F17C2227/01—Propulsion of the fluid
- F17C2227/0192—Propulsion of the fluid by using a working fluid
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F17—STORING OR DISTRIBUTING GASES OR LIQUIDS
- F17C—VESSELS FOR CONTAINING OR STORING COMPRESSED, LIQUEFIED OR SOLIDIFIED GASES; FIXED-CAPACITY GAS-HOLDERS; FILLING VESSELS WITH, OR DISCHARGING FROM VESSELS, COMPRESSED, LIQUEFIED, OR SOLIDIFIED GASES
- F17C2260/00—Purposes of gas storage and gas handling
- F17C2260/04—Reducing risks and environmental impact
- F17C2260/042—Reducing risk of explosion
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F17—STORING OR DISTRIBUTING GASES OR LIQUIDS
- F17C—VESSELS FOR CONTAINING OR STORING COMPRESSED, LIQUEFIED OR SOLIDIFIED GASES; FIXED-CAPACITY GAS-HOLDERS; FILLING VESSELS WITH, OR DISCHARGING FROM VESSELS, COMPRESSED, LIQUEFIED, OR SOLIDIFIED GASES
- F17C2260/00—Purposes of gas storage and gas handling
- F17C2260/04—Reducing risks and environmental impact
- F17C2260/044—Avoiding pollution or contamination
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/30—Hydrogen technology
- Y02E60/32—Hydrogen storage
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- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- General Engineering & Computer Science (AREA)
- Output Control And Ontrol Of Special Type Engine (AREA)
Abstract
The present invention discloses a kind of hydrogen storage aqueous hydrogenation machine, including the fluid reservoir equipped with hydrogeneous liquid water, the top of the fluid reservoir is provided with air inlet and gas outlet, the air inlet is connected with aerator by pipeline, the gas outlet is connected with the inlet end of combustion apparatus by pipeline, it is provided with the fluid reservoir at the top of bubble generator, the fluid reservoir and gas-liquid separation device is provided with the position of gas outlet.The invention also discloses a kind of hydrogen storage aqueous method of hydrotreating.Compared with existing hydrogenation machine, this hydrogenation machine is easier, safety, and economically feasible, effects of energy conservation and environmental protection becomes apparent from, without explosion danger, nontoxic, pollution-free noresidue, and the extensive application value of application surface.Combustion apparatus such as internal combustion engine etc. can greatly reduce the usage amount of air cleaner using the present apparatus, economic and environment-friendly.
Description
Technical field
The invention belongs to renewable, clean environment firendly new energy field, and in particular to a kind of hydrogen storage aqueous hydrogenation machine and its
Method of hydrotreating.
Background technology
Hydrogen is that a kind of combustion heat value is high, the secondary energy sources of CO2 zero-emissions, the heat that every kilogram of combustion of hydrogen is produced, greatly
It is approximately 3 times of gasoline, 3 .9 times of alcohol, 4 .5 times of coke.Due to hydrogen be it is unique can provide both do not had " greenhouse effects ",
Energy again without any pollution, inexhaustible, people gradually recognize：Hydrogen Technology will be before most having 21 century
Scape, most can fundamentally solve the Last Resort of human environment crisis and energy crisis.
Hydrogen gas storage vessel in the hydrogen charging system used at present is typically designed to hydrogen and entered from storage container lower end
Gas, from storage container upper end outlet, this design can give enterprise's increase cost in actual applications because system using preceding and
, it is necessary to use nitrogen purging container and system after periodic maintenance, once being purged with nitrogen in the tun of gas station
After the completion of, it is difficult to hydrogen that nitrogen displacement is clean again.And hydrogen charging system is filled in the hydrogen tank to industrial use
When, because pressure difference is larger, the general method using decompression is filled, but because the working flow of decompressor is small, therefore fill
ETL estimated time of loading can be lengthened.
The content of the invention
The purpose of the present invention be in view of the shortcomings of the prior art there is provided a kind of simple in construction, cost is low and production hydrogen process not
Machine need to be hydrogenated with the hydrogen storage aqueous of electric energy.
The purpose of the present invention is achieved through the following technical solutions：
A kind of hydrogen storage aqueous is hydrogenated with machine, including the fluid reservoir equipped with hydrogeneous liquid water, and the top of the fluid reservoir is provided with air inlet
Mouth and gas outlet, the air inlet are connected with aerator by pipeline, and the gas outlet is connected with combustion apparatus by pipeline
Inlet end, be provided with the fluid reservoir at the top of bubble generator, the fluid reservoir and gas-liquid separation be provided with the position of gas outlet
Device.
Preferred as one kind of such scheme, the hydrogen storage aqueous hydrogenation machine also includes booster pump, and the booster pump passes through
Pipeline is connected between aerator and air inlet.
As a kind of optional of such scheme, the hydrogen storage aqueous hydrogenation machine also includes negative pressure air-suction device, the negative pressure
Getter device is connected between gas outlet and combustion apparatus by pipeline.
It is preferred that, the fluid reservoir is also associated with automatic liquid feeder.
As such scheme one kind preferably, the bubble generator is that provided with multiple, and multiple bubble generators are successively
It is stacked, the air inlet accesses to the least significant end of the multiple bubble generator by pipeline.
Based on same design, the present invention also provides a kind of hydrogen storage aqueous method of hydrotreating, comprised the following steps：
S1, injects hydrogen storage aqueous in the fluid reservoir for having entrance point, the port of export；
S2, gas is accessed from the entrance point of fluid reservoir, out of, the outlet pipe nipple access combustion apparatus of fluid reservoir air inlet；
S3, gas switchs to tiny constant flow, and hydrogen molecule in hydrogen storage aqueous is sent into combustion apparatus and burnt.
Specifically, the gas is conveyed using positive pressure pump.
Specifically, the gas realizes that gas flows using port of export negative inspiratory pressure.
Specifically, being provided with bubble generator in the fluid reservoir.
Specifically, the air is air or combustion gas.
Compared with prior art, the advantage of the invention is that：
Compared with existing hydrogenation machine, this hydrogenation machine is easier, and safety, economically feasible, effects of energy conservation and environmental protection becomes apparent from, do not had
Explosion danger, nontoxic, pollution-free noresidue, and the extensive application value of application surface.Combustion apparatus such as internal combustion engine etc.
The usage amount of air cleaner can be greatly reduced using the present apparatus, it is economic and environment-friendly.
Brief description of the drawings
Fig. 1 is three-dimensional structure diagram of the invention.
Embodiment
With reference to embodiment and accompanying drawing, the present invention is described in further detail, but embodiments of the present invention are not limited
In this.
Embodiment
As shown in figure 1, a kind of hydrogen storage aqueous hydrogenation machine that the present invention is provided, including the fluid reservoir 1 equipped with hydrogeneous liquid water,
The top of the fluid reservoir 1 is provided with air inlet 2 and gas outlet 3, and the air inlet 2 is connected with aerator 4, institute by pipeline
State and bubble generator 6, the storage are provided with the inlet end that gas outlet 3 is connected with combustion apparatus 5 by pipeline, the fluid reservoir 1
The top of flow container 1 is provided with gas-liquid separation device 7 at the position of gas outlet.
Preferred as one kind of such scheme, the fluid reservoir 1 is also associated with automatic liquid feeder（Not shown in figure）.It is logical
Crossing above-mentioned automatic liquid feeder need to can carry out being automatically replenished addition in hydrogen storage aqueous after continuous consumption.
As a kind of embodiment, the hydrogen storage aqueous hydrogenation machine also includes booster pump 8, and the booster pump 8 is connected by pipeline
It is connected between aerator 4 and air inlet 2.Said structure passes through the pressurized feed of booster pump 8, it is ensured that whole hydrogen storage aqueous hydrogenation machine
Continuous service.
As another embodiment, the hydrogen storage aqueous hydrogenation machine also includes negative pressure air-suction device 9, the negative inspiratory pressure dress
9 are put to be connected between gas outlet 3 and combustion apparatus 5 by pipeline.Said structure by negative pressure air-suction device 9 can easily by
Hydrogen discharge in fluid reservoir 1, simple and fast, operating efficiency are high.
As such scheme one kind preferably, the bubble generator 6 be provided with multiple, and multiple bubble generators 6 according to
Secondary to be stacked, the air inlet 2 accesses to the least significant end of the multiple bubble generator 6 by pipeline.Using aforesaid way,
The gas entered from air inlet fully can mix with hydrogeneous liquid water with concussion, can more effective quick hydrogen in hydrogeneous liquid water
Melt and taken away.
Based on same design, the present invention also provides a kind of hydrogen storage aqueous method of hydrotreating, comprised the following steps：
S1, the injection hydrogen storage aqueous in the fluid reservoir 1 for having entrance point, the port of export；
S2, gas is accessed from the entrance point of fluid reservoir 1, and the air inlet of combustion apparatus 5 is accessed from the outlet pipe nipple of fluid reservoir 1
It is interior；
S3, gas switchs to tiny constant flow, and hydrogen molecule in hydrogen storage aqueous is sent into combustion apparatus 5 and burnt.
Specifically, the gas is conveyed using positive pressure pump.
Specifically, the gas realizes that gas flows using port of export negative inspiratory pressure.
Specifically, being provided with bubble generator in the fluid reservoir 1.
Specifically, the air is air or combustion gas.
The operation principle of the present invention is as follows：
During work, hydrogen storage aqueous is injected in the sealing container for have import and export（I.e. hydrogeneous liquid）, gas is accessed from entrance point（Can
To be air, combustion gas etc.）, from outlet pipe nipple access combustion apparatus（Including internal combustion engine, boiler, combustor etc.）Air inlet
It is interior；Gas constant flow enters in fluid reservoir, and the hydrogen molecule in hydrogeneous liquid water is sent into combustion apparatus and burnt, hydrogen storage aqueous
Supplement addition need to be carried out after continuous consumption, gas can be using malleation pumping, i.e., from inlet end pressurized feed, it would however also be possible to employ
Port of export negative inspiratory pressure realizes that gas flows, and fluid reservoir can be that single tank can also be multiple tank, gas-liquid separation device（Such as air water point
From device）Can also be in built-in tank it is external with outside fluid reservoir, when using can with it is multiple it is in series or in parallel use, work as liquid storage
When precipitated powder trifle in the world thing is excessive in tank, the cleaning of liquid storage pot bottom can be opened and carry out blowdown cleaning.
It is not intended to limit the scope of the present invention above, all implementation according to the technology of the present invention essence to more than
Example any modification, equivalent variations and the modification made, in the range of still falling within technical scheme.
Claims (10)
1. a kind of hydrogen storage aqueous is hydrogenated with machine, it is characterised in that：Including the fluid reservoir equipped with hydrogeneous liquid water, the fluid reservoir
Top is provided with air inlet and gas outlet, and the air inlet is connected with aerator by pipeline, and the gas outlet is connected by pipeline
It is connected in the inlet end of combustion apparatus, the fluid reservoir and is provided with bubble generator, at the top of the fluid reservoir at the position of gas outlet
Provided with gas-liquid separation device.
2. a kind of hydrogen storage aqueous hydrogenation machine according to claim 1, it is characterised in that：The hydrogen storage aqueous hydrogenation machine is also wrapped
Booster pump is included, the booster pump is connected between aerator and air inlet by pipeline.
3. a kind of hydrogen storage aqueous hydrogenation machine according to claim 1, it is characterised in that：The hydrogen storage aqueous hydrogenation machine is also wrapped
Negative pressure air-suction device is included, the negative pressure air-suction device is connected between gas outlet and combustion apparatus by pipeline.
4. a kind of hydrogen storage aqueous hydrogenation machine according to Claims 2 or 3, it is characterised in that：The fluid reservoir is also associated with
Automatic liquid feeder.
5. a kind of hydrogen storage aqueous hydrogenation machine according to claim 4, it is characterised in that：The bubble generator is provided with many
It is individual, and multiple bubble generators are cascading, the air inlet accesses to the multiple bubble generator by pipeline
Least significant end.
6. a kind of hydrogen storage aqueous method of hydrotreating, comprises the following steps：
S1, injects hydrogen storage aqueous in the fluid reservoir for having entrance point, the port of export；
S2, gas is accessed from the entrance point of fluid reservoir, out of, the outlet pipe nipple access combustion apparatus of fluid reservoir air inlet；
S3, gas switchs to tiny constant flow, and hydrogen molecule in hydrogen storage aqueous is sent into combustion apparatus and burnt.
7. a kind of hydrogen storage aqueous method of hydrotreating according to claim 6, it is characterised in that：The gas is defeated using positive pressure pump
Send.
8. a kind of hydrogen storage aqueous method of hydrotreating according to claim 6, it is characterised in that：The gas is negative using the port of export
Pressure air-breathing realizes that gas flows.
9. a kind of hydrogen storage aqueous method of hydrotreating according to claim any one of 6-8, it is characterised in that：In the fluid reservoir
Provided with bubble generator.
10. a kind of hydrogen storage aqueous method of hydrotreating according to claim any one of 6-8, it is characterised in that：The air is
Air or combustion gas.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710293894.1A CN107120523A (en) | 2017-04-28 | 2017-04-28 | A kind of hydrogen storage aqueous hydrogenation machine and its method of hydrotreating |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710293894.1A CN107120523A (en) | 2017-04-28 | 2017-04-28 | A kind of hydrogen storage aqueous hydrogenation machine and its method of hydrotreating |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN107120523A true CN107120523A (en) | 2017-09-01 |
Family
ID=59726188
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201710293894.1A Pending CN107120523A (en) | 2017-04-28 | 2017-04-28 | A kind of hydrogen storage aqueous hydrogenation machine and its method of hydrotreating |
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Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1789783A (en) * | 2004-09-23 | 2006-06-21 | 气体产品与化学公司 | Ionic liquid based mixtures for gas storage and delivery |
| CN103232382A (en) * | 2013-04-19 | 2013-08-07 | 西安交通大学 | Hydrogenation method of ethylcarbazole and dehydrogenation method of product thereof |
| DE102012004444A1 (en) * | 2012-03-04 | 2013-09-05 | Friedrich-Alexander-Universität Erlangen-Nürnberg | Method for operating hydrogen gas station for e.g. passenger car, involves conveying partly hydrogenated liquid organic hydrogen carrier into chemical reactor, where hydrogen is not chemically bound as substance in carrier in gas station |
| CN104791603A (en) * | 2014-01-20 | 2015-07-22 | 上海华捷视医疗设备有限公司 | Hydrogen energy storage and supply system, and hydrogen energy storage and supply method |
| CN106148990A (en) * | 2015-04-15 | 2016-11-23 | 高·哈里·凡 | Electrochemistry high-pressure hydrogenation and organic liquid hydrogen-storing device and hydrogen storage method |
| CN106252691A (en) * | 2016-08-27 | 2016-12-21 | 温州集智科技有限公司 | A kind of liquid state organics is as the hydrogen storage electricity generation system of hydrogen storage material |
-
2017
- 2017-04-28 CN CN201710293894.1A patent/CN107120523A/en active Pending
Patent Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1789783A (en) * | 2004-09-23 | 2006-06-21 | 气体产品与化学公司 | Ionic liquid based mixtures for gas storage and delivery |
| DE102012004444A1 (en) * | 2012-03-04 | 2013-09-05 | Friedrich-Alexander-Universität Erlangen-Nürnberg | Method for operating hydrogen gas station for e.g. passenger car, involves conveying partly hydrogenated liquid organic hydrogen carrier into chemical reactor, where hydrogen is not chemically bound as substance in carrier in gas station |
| CN103232382A (en) * | 2013-04-19 | 2013-08-07 | 西安交通大学 | Hydrogenation method of ethylcarbazole and dehydrogenation method of product thereof |
| CN104791603A (en) * | 2014-01-20 | 2015-07-22 | 上海华捷视医疗设备有限公司 | Hydrogen energy storage and supply system, and hydrogen energy storage and supply method |
| CN106148990A (en) * | 2015-04-15 | 2016-11-23 | 高·哈里·凡 | Electrochemistry high-pressure hydrogenation and organic liquid hydrogen-storing device and hydrogen storage method |
| CN106252691A (en) * | 2016-08-27 | 2016-12-21 | 温州集智科技有限公司 | A kind of liquid state organics is as the hydrogen storage electricity generation system of hydrogen storage material |
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Application publication date: 20170901 |
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