CN107118500A - A kind of high oil resistant, acidproof accumulator housing material and preparation method - Google Patents
A kind of high oil resistant, acidproof accumulator housing material and preparation method Download PDFInfo
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- CN107118500A CN107118500A CN201710354521.0A CN201710354521A CN107118500A CN 107118500 A CN107118500 A CN 107118500A CN 201710354521 A CN201710354521 A CN 201710354521A CN 107118500 A CN107118500 A CN 107118500A
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L55/00—Compositions of homopolymers or copolymers, obtained by polymerisation reactions only involving carbon-to-carbon unsaturated bonds, not provided for in groups C08L23/00 - C08L53/00
- C08L55/02—ABS [Acrylonitrile-Butadiene-Styrene] polymers
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/02—Elements
- C08K3/08—Metals
- C08K2003/0812—Aluminium
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2296—Oxides; Hydroxides of metals of zinc
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/24—Acids; Salts thereof
- C08K3/26—Carbonates; Bicarbonates
- C08K2003/267—Magnesium carbonate
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- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/30—Sulfur-, selenium- or tellurium-containing compounds
- C08K2003/3045—Sulfates
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/38—Boron-containing compounds
- C08K2003/387—Borates
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/014—Additives containing two or more different additives of the same subgroup in C08K
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- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/02—Flame or fire retardant/resistant
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/22—Halogen free composition
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2203/00—Applications
- C08L2203/20—Applications use in electrical or conductive gadgets
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
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Abstract
The invention belongs to lead accumulator field of material technology there is provided a kind of high oil resistant, acidproof accumulator housing material and preparation method, the high oil resistant, acidproof accumulator housing material include the raw material of following parts by weight：50 70 parts of ABS resins, 20 25 parts of polyvinyl chloride, 0.5 5 parts of halogen-free flame retardants, 0.8 2.0 parts of antioxidant, 6 10 parts of glass microballoon, 36 parts of toughener, 13 parts of magnesium carbonate, 29 parts of resistance to fluid composition, 37 parts of line borate, 10 14 parts of ethene chlorotrifluoroethylene, 6 11 parts of calcium metasilicate, 59 parts of aluminium powder, 5 10 parts of calcium sulfate, 24 parts of NC Nitroncellulose.The present invention provides a kind of high oil resistant, acidproof accumulator housing material and preparation method, by adjusting the formula of existing accumulator housing material, improves oil resistivity, the acid resistance of battery.
Description
Technical field
The invention belongs to lead accumulator field of material technology, in particular it relates to a kind of high oil resistant, acidproof accumulator housing material
Material and preparation method.
Background technology
Chemical energy is converted into the device of electric energy chemical cell, commonly abbreviated as battery.After electric discharge, the side charged can be used
Formula regenerates internal active material -- and electrical power storage it is chemical energy；Need that chemical energy is converted to electric energy again during electric discharge.Will
This kind of battery is referred to as battery, also referred to as secondary cell.Acid accumulator is widely used in traffic, communication, electric power, military affairs, navigation, boat
Numerous economic fields such as sky, become a kind of indispensable important electrochmical power source.
Battery case is as one of lead-acid accumulator three-major-items, and it is used to carry all constituents such as pole plate, dividing plate, electrolyte
Matter, it is desirable to preferable resistance to acids and bases, high intensity and good processability.ABS resin is exactly the most frequently used one kind of battery case
Raw material, cheap, attractive in appearance, intensity is good.But conventional ABS resin, but to machine oil class material sensitive, battery casing surface is stained with
It is perishable after machine oil, ftractureed in the presence of internal stress.Battery is under its use environment, especially automobile environment, unavoidable meeting
Machine oil is stained with, and causes battery cracking, failure, leakage acid, corrosion other equipment.
Therefore need to be improved battery case materials, strengthen its oil resistivity, acid resistance.
The content of the invention
For defect of the prior art, the present invention provides a kind of high oil resistant, acidproof accumulator housing material and preparation side
Method, by adjusting the formula of existing accumulator housing material, improves oil resistivity, the acid resistance of battery.
A kind of high oil resistant, the acidproof accumulator housing material provided according to an aspect of the present invention, the high oil resistant, acidproof storage
Battery case materials include the raw material of following parts by weight：50-70 parts of ABS resins, 20-25 parts of polyvinyl chloride, halogen-free flame retardants
0.5-5 parts, 0.8-2.0 parts of antioxidant, 6-10 parts of glass microballoon, 3-6 parts of toughener, 1-3 parts of magnesium carbonate, the 2- of resistance to fluid composition
9 parts, 3-7 parts of line borate, 10-14 parts of ethylene-chlorotrifluoro-ethylene copolymer, 6-11 parts of calcium metasilicate, 5-9 parts of aluminium powder, calcium sulfate
5-10 parts, 2-4 parts of NC Nitroncellulose.
Preferably, the high oil resistant, acidproof accumulator housing material include the raw material of following parts by weight：ABS resins
60-70 parts, 20-23 parts of polyvinyl chloride, 0.5-4 parts of halogen-free flame retardants, 1.8-2.0 parts of antioxidant, 8-10 parts of glass microballoon, increase
Tough dose 3-4 parts, 1-2 parts of magnesium carbonate, the 2-6 of resistance to fluid composition parts, 3-5 parts of line borate, ethylene-chlorotrifluoro-ethylene copolymer 10-13
Part, 6-10 parts of calcium metasilicate, 5-7 parts of aluminium powder, 5-9 parts of calcium sulfate, 2-3 parts of NC Nitroncellulose.
Preferably, the high oil resistant, acidproof accumulator housing material include the raw material of following parts by weight：ABS resins 65
Part, 22 parts of polyvinyl chloride, 3.5 parts of halogen-free flame retardants, 1.9 parts of antioxidant, 9 parts of glass microballoon, 3 parts of toughener, magnesium carbonate 1
Part, 4 parts of resistance to fluid composition, 4 parts of line borate, 12 parts of ethylene-chlorotrifluoro-ethylene copolymer, 8 parts of calcium metasilicate, 6 parts of aluminium powder, sulfuric acid
8 parts of calcium, 2 parts of NC Nitroncellulose.
Preferably, the toughener includes the raw material of following parts by weight：10-50 parts of benzene tetracarboxylic acid, 1,5-PD 10-
40 parts.
Preferably, the resistance to fluid composition includes the raw material of following parts by weight：
40-60 parts of EVA7350；
5-12 parts of EPDM4725；
1-5 parts of oil-proof composition；
8-11 parts of butadiene acrylonitrile rubber；
1-4 parts of sodium metasilicate；
0.3-0.6 parts of silane coupler；
0.5-1.3 parts of Zinc Oxide；
0.1-0.4 parts of stearic acid.
Preferably, the halogen-free flame retardants is made up of the raw material of following weight parts, 4-7 parts of melamine cyanurate sodium, into
0.5-5.0 parts of charcoal accelerator, fire-retardant accelerator 0.5-4.0 parts.
Preferably, it is described into charcoal accelerator be nano imvite, dolomite dust or sepiolite in one or more, it is described
Fire-retardant accelerator is one or both of Firebrake ZB or calcium carbonate.
On the one hand high oil resistant, the acidproof accumulator housing material preparation method, the high oil resistant, acidproof battery jar provided
Body material preparation method comprises the following steps：
（1）Mixed in proportion by melamine cyanurate sodium, into charcoal accelerator, fire-retardant accelerator, be prepared into halogen-free flame retardants；
（2）By ABS resins, polyvinyl chloride, antioxidant, glass microballoon, toughener, magnesium carbonate, resistance to fluid composition, line borate,
Ethylene-chlorotrifluoro-ethylene copolymer, calcium metasilicate, aluminium powder, calcium sulfate, NC Nitroncellulose are mixed in proportion, prepared by extruding pelletization
Obtain plastic particles；
（3）Accumulator housing material is made in plastic particles injection molding.
Compared with prior art, the present invention has following beneficial effect：
（1）Formula of the invention by adjusting existing accumulator housing material, on the basis of ABS, adds polyvinyl chloride, Halogen
Fire retardant antioxidant, glass microballoon, toughener, magnesium carbonate, resistance to fluid composition, line borate, ethylene-chlorinated copolymerization
Thing, calcium metasilicate, aluminium powder, calcium sulfate, NC Nitroncellulose improves oil resistivity, the acid resistance of battery；
（2）The present invention adds resistance to fluid composition in accumulator housing material prescription, resistance to fluid composition by EVA7350,
EPDM4725, oil-proof composition, butadiene acrylonitrile rubber, sodium metasilicate, silane coupler, Zinc Oxide, stearic acid composition, make existing case material
Phase oil resistant is increased substantially；
（3）The present invention is added after ethylene-chlorotrifluoro-ethylene copolymer, greatly improves the resistance to acids and bases of accumulator housing material.
Draw there is no exception in 20-30 days under 2mol/L sodium hydroxide solution and 2mol/L sulfuric acid respectively through experimental test
Foaming phenomena, with good acid and alkali-resistance effect.
Embodiment
With reference to specific embodiment, the present invention is expanded on further.It should be understood that these embodiments are merely to illustrate the present invention
Rather than limitation the scope of the present invention.
The present invention provides a kind of high oil resistant, acidproof accumulator housing material and preparation method, by adjusting existing battery
The formula of case material, improves oil resistivity, the acid resistance of battery.
A kind of high oil resistant, the acidproof accumulator housing material provided according to an aspect of the present invention, the high oil resistant, acidproof storage
Battery case materials include the raw material of following parts by weight：50-70 parts of ABS resins, 20-25 parts of polyvinyl chloride, halogen-free flame retardants
0.5-5 parts, 0.8-2.0 parts of antioxidant, 6-10 parts of glass microballoon, 3-6 parts of toughener, 1-3 parts of magnesium carbonate, the 2- of resistance to fluid composition
9 parts, 3-7 parts of line borate, 10-14 parts of ethylene-chlorotrifluoro-ethylene copolymer, 6-11 parts of calcium metasilicate, 5-9 parts of aluminium powder, calcium sulfate
5-10 parts, 2-4 parts of NC Nitroncellulose.
Preferably, the high oil resistant, acidproof accumulator housing material include the raw material of following parts by weight：ABS resins
60-70 parts, 20-23 parts of polyvinyl chloride, 0.5-4 parts of halogen-free flame retardants, 1.8-2.0 parts of antioxidant, 8-10 parts of glass microballoon, increase
Tough dose 3-4 parts, 1-2 parts of magnesium carbonate, the 2-6 of resistance to fluid composition parts, 3-5 parts of line borate, ethylene-chlorotrifluoro-ethylene copolymer 10-13
Part, 6-10 parts of calcium metasilicate, 5-7 parts of aluminium powder, 5-9 parts of calcium sulfate, 2-3 parts of NC Nitroncellulose.
Preferably, the high oil resistant, acidproof accumulator housing material include the raw material of following parts by weight：ABS resins 65
Part, 22 parts of polyvinyl chloride, 3.5 parts of halogen-free flame retardants, 1.9 parts of antioxidant, 9 parts of glass microballoon, 3 parts of toughener, magnesium carbonate 1
Part, 4 parts of resistance to fluid composition, 4 parts of line borate, 12 parts of ethylene-chlorotrifluoro-ethylene copolymer, 8 parts of calcium metasilicate, 6 parts of aluminium powder, sulfuric acid
8 parts of calcium, 2 parts of NC Nitroncellulose.
Preferably, the toughener includes the raw material of following parts by weight：10-50 parts of benzene tetracarboxylic acid, 1,5-PD 10-
40 parts.
Preferably, the resistance to fluid composition includes the raw material of following parts by weight：
40-60 parts of EVA7350；
5-12 parts of EPDM4725；
1-5 parts of oil-proof composition；
8-11 parts of butadiene acrylonitrile rubber；
1-4 parts of sodium metasilicate；
0.3-0.6 parts of silane coupler；
0.5-1.3 parts of Zinc Oxide；
0.1-0.4 parts of stearic acid.
Preferably, the halogen-free flame retardants is made up of the raw material of following weight parts, 4-7 parts of melamine cyanurate sodium, into
0.5-5.0 parts of charcoal accelerator, fire-retardant accelerator 0.5-4.0 parts.
Preferably, it is described into charcoal accelerator be nano imvite, dolomite dust or sepiolite in one or more, it is described
Fire-retardant accelerator is one or both of Firebrake ZB or calcium carbonate.
On the one hand high oil resistant, the acidproof accumulator housing material preparation method, the high oil resistant, acidproof battery jar provided
Body material preparation method comprises the following steps：
（1）Mixed in proportion by melamine cyanurate sodium, into charcoal accelerator, fire-retardant accelerator, be prepared into halogen-free flame retardants；
（2）By ABS resins, polyvinyl chloride, antioxidant, glass microballoon, toughener, magnesium carbonate, resistance to fluid composition, line borate,
Ethylene-chlorotrifluoro-ethylene copolymer, calcium metasilicate, aluminium powder, calcium sulfate, NC Nitroncellulose are mixed in proportion, prepared by extruding pelletization
Obtain plastic particles；
（3）Accumulator housing material is made in plastic particles injection molding.
Compared with prior art, the present invention has following beneficial effect：
（1）Formula of the invention by adjusting existing accumulator housing material, on the basis of ABS, adds polyvinyl chloride, Halogen
Fire retardant antioxidant, glass microballoon, toughener, magnesium carbonate, resistance to fluid composition, line borate, ethylene-chlorinated copolymerization
Thing, calcium metasilicate, aluminium powder, calcium sulfate, NC Nitroncellulose improves oil resistivity, the acid resistance of battery；
（2）The present invention adds resistance to fluid composition in accumulator housing material prescription, resistance to fluid composition by EVA7350,
EPDM4725, oil-proof composition, butadiene acrylonitrile rubber, sodium metasilicate, silane coupler, Zinc Oxide, stearic acid composition, make existing case material
Phase oil resistant is increased substantially；
（3）The present invention is added after ethylene-chlorotrifluoro-ethylene copolymer, greatly improves the resistance to acids and bases of accumulator housing material.
Draw there is no exception in 20-30 days under 2mol/L sodium hydroxide solution and 2mol/L sulfuric acid respectively through experimental test
Foaming phenomena, with good acid and alkali-resistance effect.
Embodiment 1
A kind of high oil resistant, acidproof accumulator housing material, the high oil resistant, acidproof battery jar that the present embodiment one side is provided
Body material includes the raw material of following parts by weight：70 parts of ABS resins, 20 parts of polyvinyl chloride, 5 parts of halogen-free flame retardants, antioxidant
0.8 part, 10 parts of glass microballoon, 3 parts of toughener, 3 parts of magnesium carbonate, 2 parts of resistance to fluid composition, 7 parts of line borate, ethene-trifluoro chloroethene
10 parts of alkene copolymer, 11 parts of calcium metasilicate, 5 parts of aluminium powder, 10 parts of calcium sulfate, 2 parts of NC Nitroncellulose.
Preferably, the toughener includes the raw material of following parts by weight：50 parts of benzene tetracarboxylic acid, 40 parts of 1,5-PD.
Preferably, the resistance to fluid composition includes the raw material of following parts by weight：
60 parts of EVA7350；
5 parts of EPDM4725；
5 parts of oil-proof composition；
8 parts of butadiene acrylonitrile rubber；
4 parts of sodium metasilicate；
0.3 part of silane coupler；
1.3 parts of Zinc Oxide；
0.1 part of stearic acid.
Preferably, the halogen-free flame retardants is made up of the raw material of following weight parts, 7 parts of melamine cyanurate sodium, into charcoal
0.5 part of accelerator, 4.0 parts of fire-retardant accelerator.
Preferably, it is described into charcoal accelerator be nano imvite, dolomite dust or sepiolite in one or more, it is described
Fire-retardant accelerator is one or both of Firebrake ZB or calcium carbonate.
On the one hand high oil resistant, the acidproof accumulator housing material preparation method, the high oil resistant, acidproof battery jar provided
Body material preparation method comprises the following steps：
（1）Mixed in proportion by melamine cyanurate sodium, into charcoal accelerator, fire-retardant accelerator, be prepared into halogen-free flame retardants；
（2）By ABS resins, polyvinyl chloride, antioxidant, glass microballoon, toughener, magnesium carbonate, resistance to fluid composition, line borate,
Ethylene-chlorotrifluoro-ethylene copolymer, calcium metasilicate, aluminium powder, calcium sulfate, NC Nitroncellulose are mixed in proportion, prepared by extruding pelletization
Obtain plastic particles；
（3）Accumulator housing material is made in plastic particles injection molding.
Embodiment 2
A kind of high oil resistant, acidproof accumulator housing material, the high oil resistant, acidproof battery jar that the present embodiment one side is provided
Body material includes the raw material of following parts by weight：It is 50 parts of ABS resins, 25 parts of polyvinyl chloride, 0.5 part of halogen-free flame retardants, anti-oxidant
2.0 parts of agent, 6 parts of glass microballoon, 6 parts of toughener, 1 part of magnesium carbonate, 9 parts of resistance to fluid composition, 3 parts of line borate, ethene-trifluoro chloroethene
14 parts of alkene copolymer, 6 parts of calcium metasilicate, 9 parts of aluminium powder, 5 parts of calcium sulfate, 4 parts of NC Nitroncellulose.
Preferably, the toughener includes the raw material of following parts by weight：10 parts of benzene tetracarboxylic acid, 40 parts of 1,5-PD.
Preferably, the resistance to fluid composition includes the raw material of following parts by weight：
40 parts of EVA7350；
12 parts of EPDM4725；
1 part of oil-proof composition；
11 parts of butadiene acrylonitrile rubber；
1 part of sodium metasilicate；
0.6 part of silane coupler；
0.5 part of Zinc Oxide；
0.4 part of stearic acid.
Preferably, the halogen-free flame retardants is made up of the raw material of following weight parts, 4 parts of melamine cyanurate sodium, into charcoal
5.0 parts of accelerator, 0.5 part of fire-retardant accelerator.
Preferably, it is described into charcoal accelerator be nano imvite, dolomite dust or sepiolite in one or more, it is described
Fire-retardant accelerator is one or both of Firebrake ZB or calcium carbonate.
On the one hand high oil resistant, the acidproof accumulator housing material preparation method, the high oil resistant, acidproof battery jar provided
Body material preparation method comprises the following steps：
（1）Mixed in proportion by melamine cyanurate sodium, into charcoal accelerator, fire-retardant accelerator, be prepared into halogen-free flame retardants；
（2）By ABS resins, polyvinyl chloride, antioxidant, glass microballoon, toughener, magnesium carbonate, resistance to fluid composition, line borate,
Ethylene-chlorotrifluoro-ethylene copolymer, calcium metasilicate, aluminium powder, calcium sulfate, NC Nitroncellulose are mixed in proportion, prepared by extruding pelletization
Obtain plastic particles；
（3）Accumulator housing material is made in plastic particles injection molding.
Embodiment 3
A kind of high oil resistant, acidproof accumulator housing material, the high oil resistant, acidproof battery jar that the present embodiment one side is provided
Body material includes the raw material of following parts by weight：The high oil resistant, acidproof accumulator housing material include following parts by weight
Raw material：70 parts of ABS resins, 20 parts of polyvinyl chloride, 4 parts of halogen-free flame retardants, 1.8 parts of antioxidant, 10 parts of glass microballoon, toughness reinforcing
3 parts of agent, 2 parts of magnesium carbonate, 2 parts of resistance to fluid composition, 5 parts of line borate, 10 parts of ethylene-chlorotrifluoro-ethylene copolymer, calcium metasilicate 10
Part, 5 parts of aluminium powder, 9 parts of calcium sulfate, 2 parts of NC Nitroncellulose.
Preferably, the toughener includes the raw material of following parts by weight：40 parts of benzene tetracarboxylic acid, 40 parts of 1,5-PD.
Preferably, the resistance to fluid composition includes the raw material of following parts by weight：
50 parts of EVA7350；
9 parts of EPDM4725；
4 parts of oil-proof composition；
9 parts of butadiene acrylonitrile rubber；
3 parts of sodium metasilicate；
0.4 part of silane coupler；
0.9 part of Zinc Oxide；
0.3 part of stearic acid.
Preferably, the halogen-free flame retardants is made up of the raw material of following weight parts, 5 parts of melamine cyanurate sodium, into charcoal
3.0 parts of accelerator, 3.0 parts of fire-retardant accelerator.
Preferably, it is described into charcoal accelerator be nano imvite, dolomite dust or sepiolite in one or more, it is described
Fire-retardant accelerator is one or both of Firebrake ZB or calcium carbonate.
On the one hand high oil resistant, the acidproof accumulator housing material preparation method, the high oil resistant, acidproof battery jar provided
Body material preparation method comprises the following steps：
（1）Mixed in proportion by melamine cyanurate sodium, into charcoal accelerator, fire-retardant accelerator, be prepared into halogen-free flame retardants；
（2）By ABS resins, polyvinyl chloride, antioxidant, glass microballoon, toughener, magnesium carbonate, resistance to fluid composition, line borate,
Ethylene-chlorotrifluoro-ethylene copolymer, calcium metasilicate, aluminium powder, calcium sulfate, NC Nitroncellulose are mixed in proportion, prepared by extruding pelletization
Obtain plastic particles；
（3）Accumulator housing material is made in plastic particles injection molding.
Embodiment 4
A kind of high oil resistant, acidproof accumulator housing material, the high oil resistant, acidproof battery jar that the present embodiment one side is provided
Body material includes the raw material of following parts by weight：The high oil resistant, acidproof accumulator housing material include following parts by weight
Raw material：60 parts of ABS resins, 23 parts of polyvinyl chloride, 0.5 part of halogen-free flame retardants, 2.0 parts of antioxidant, 8 parts of glass microballoon, toughness reinforcing
4 parts of agent, 1 part of magnesium carbonate, 6 parts of resistance to fluid composition, 3 parts of line borate, 13 parts of ethylene-chlorotrifluoro-ethylene copolymer, calcium metasilicate 6
Part, 7 parts of aluminium powder, 5 parts of calcium sulfate, 3 parts of NC Nitroncellulose.
Preferably, the toughener includes the raw material of following parts by weight：30 parts of benzene tetracarboxylic acid, 40 parts of 1,5-PD.
Preferably, the resistance to fluid composition includes the raw material of following parts by weight：
55 parts of EVA7350；
7 parts of EPDM4725；
3 parts of oil-proof composition；
11 parts of butadiene acrylonitrile rubber；
4 parts of sodium metasilicate；
0.4 part of silane coupler；
0.9 part of Zinc Oxide；
0.2 part of stearic acid.
Preferably, the halogen-free flame retardants is made up of the raw material of following weight parts, 5 parts of melamine cyanurate sodium, into charcoal
4.0 parts of accelerator, 3.0 parts of fire-retardant accelerator.
Preferably, it is described into charcoal accelerator be nano imvite, dolomite dust or sepiolite in one or more, it is described
Fire-retardant accelerator is one or both of Firebrake ZB or calcium carbonate.
On the one hand high oil resistant, the acidproof accumulator housing material preparation method, the high oil resistant, acidproof battery jar provided
Body material preparation method comprises the following steps：
（1）Mixed in proportion by melamine cyanurate sodium, into charcoal accelerator, fire-retardant accelerator, be prepared into halogen-free flame retardants；
（2）By ABS resins, polyvinyl chloride, antioxidant, glass microballoon, toughener, magnesium carbonate, resistance to fluid composition, line borate,
Ethylene-chlorotrifluoro-ethylene copolymer, calcium metasilicate, aluminium powder, calcium sulfate, NC Nitroncellulose are mixed in proportion, prepared by extruding pelletization
Obtain plastic particles；
（3）Accumulator housing material is made in plastic particles injection molding.
Embodiment 5
A kind of high oil resistant, acidproof accumulator housing material, the high oil resistant, acidproof battery jar that the present embodiment one side is provided
Body material includes the raw material of following parts by weight：The high oil resistant, acidproof accumulator housing material include following parts by weight
Raw material：65 parts of ABS resins, 22 parts of polyvinyl chloride, 3.5 parts of halogen-free flame retardants, 1.9 parts of antioxidant, 9 parts of glass microballoon, toughness reinforcing
3 parts of agent, 1 part of magnesium carbonate, 4 parts of resistance to fluid composition, 4 parts of line borate, 12 parts of ethylene-chlorotrifluoro-ethylene copolymer, calcium metasilicate 8
Part, 6 parts of aluminium powder, 8 parts of calcium sulfate, 2 parts of NC Nitroncellulose.
Preferably, the toughener includes the raw material of following parts by weight：50 parts of benzene tetracarboxylic acid, 40 parts of 1,5-PD.
Preferably, the resistance to fluid composition includes the raw material of following parts by weight：
45 parts of EVA7350；
11 parts of EPDM4725；
3 parts of oil-proof composition；
9 parts of butadiene acrylonitrile rubber；
3 parts of sodium metasilicate；
0.4 part of silane coupler；
0.8 part of Zinc Oxide；
0.3 part of stearic acid.
Preferably, the halogen-free flame retardants is made up of the raw material of following weight parts, 6 parts of melamine cyanurate sodium, into charcoal
2.5 parts of accelerator, 2.5 parts of fire-retardant accelerator.
Preferably, it is described into charcoal accelerator be nano imvite, dolomite dust or sepiolite in one or more, it is described
Fire-retardant accelerator is one or both of Firebrake ZB or calcium carbonate.
On the one hand high oil resistant, the acidproof accumulator housing material preparation method, the high oil resistant, acidproof battery jar provided
Body material preparation method comprises the following steps：
（1）Mixed in proportion by melamine cyanurate sodium, into charcoal accelerator, fire-retardant accelerator, be prepared into halogen-free flame retardants；
（2）By ABS resins, polyvinyl chloride, antioxidant, glass microballoon, toughener, magnesium carbonate, resistance to fluid composition, line borate,
Ethylene-chlorotrifluoro-ethylene copolymer, calcium metasilicate, aluminium powder, calcium sulfate, NC Nitroncellulose are mixed in proportion, prepared by extruding pelletization
Obtain plastic particles；
（3）Accumulator housing material is made in plastic particles injection molding.
The specific embodiment of the present invention is described above.It is to be appreciated that the invention is not limited in above-mentioned specific
Embodiment, those skilled in the art can make various deformations or amendments within the scope of the claims, and this has no effect on this
The substantive content of invention.
Claims (8)
1. a kind of high oil resistant, acidproof accumulator housing material, it is characterised in that the high oil resistant, acidproof accumulator housing material
Include the raw material of following parts by weight：50-70 parts of ABS resins, 20-25 parts of polyvinyl chloride, 0.5-5 parts of halogen-free flame retardants, antioxygen
0.8-2.0 parts of agent, 6-10 parts of glass microballoon, 3-6 parts of toughener, 1-3 parts of magnesium carbonate, the 2-9 of resistance to fluid composition parts, line borate 3-
7 parts, 10-14 parts of ethylene-chlorotrifluoro-ethylene copolymer, 6-11 parts of calcium metasilicate, 5-9 parts of aluminium powder, 5-10 parts of calcium sulfate, nitro it is fine
Tie up 2-4 parts of element.
2. high oil resistant according to claim 1, acidproof accumulator housing material, it is characterised in that the high oil resistant, acidproof
Accumulator housing material includes the raw material of following parts by weight：60-70 parts of ABS resins, 20-23 parts of polyvinyl chloride, halogen-free flameproof
0.5-4 parts of agent, 1.8-2.0 parts of antioxidant, 8-10 parts of glass microballoon, 3-4 parts of toughener, 1-2 parts of magnesium carbonate, resistance to fluid composition
2-6 parts, 3-5 parts of line borate, 10-13 parts of ethylene-chlorotrifluoro-ethylene copolymer, 6-10 parts of calcium metasilicate, 5-7 parts of aluminium powder, sulfuric acid
5-9 parts of calcium, 2-3 parts of NC Nitroncellulose.
3. high oil resistant according to claim 1, acidproof accumulator housing material, it is characterised in that the high oil resistant, acidproof
Accumulator housing material includes the raw material of following parts by weight：65 parts of ABS resins, 22 parts of polyvinyl chloride, halogen-free flame retardants 3.5
Part, 1.9 parts of antioxidant, 9 parts of glass microballoon, 3 parts of toughener, 1 part of magnesium carbonate, 4 parts of resistance to fluid composition, 4 parts of line borate, second
12 parts of alkene-chlorotrifluoroethylene, 8 parts of calcium metasilicate, 6 parts of aluminium powder, 8 parts of calcium sulfate, 2 parts of NC Nitroncellulose.
4. high oil resistant according to claim 1, acidproof accumulator housing material, it is characterised in that the toughener includes
The raw material of following parts by weight：10-50 parts of benzene tetracarboxylic acid, 10-40 parts of 1,5-PD.
5. high oil resistant according to claim 1, acidproof accumulator housing material, it is characterised in that：The resistance to fluid composition
Include the raw material of following parts by weight：
40-60 parts of EVA7350；
5-12 parts of EPDM4725；
1-5 parts of oil-proof composition；
8-11 parts of butadiene acrylonitrile rubber；
1-4 parts of sodium metasilicate；
0.3-0.6 parts of silane coupler；
0.5-1.3 parts of Zinc Oxide；
0.1-0.4 parts of stearic acid.
6. high oil resistant according to claim 1, acidproof accumulator housing material, it is characterised in that：The halogen-free flame retardants
It is made up of the raw material of following weight parts, 4-7 parts of melamine cyanurate sodium, into 0.5-5.0 parts of charcoal accelerator, fire-retardant accelerator
0.5-4.0 parts.
7. high oil resistant according to claim 6, acidproof accumulator housing material, it is characterised in that：It is described into charcoal accelerator
For the one or more in nano imvite, dolomite dust or sepiolite, the fire-retardant accelerator is in Firebrake ZB or calcium carbonate
One or two.
8. high oil resistant, acidproof accumulator housing material preparation method as described in claim any one of 1-7, it is characterised in that：Bag
Include following steps：
（1）Mixed in proportion by melamine cyanurate sodium, into charcoal accelerator, fire-retardant accelerator, be prepared into halogen-free flame retardants；
（2）By ABS resins, polyvinyl chloride, antioxidant, glass microballoon, toughener, magnesium carbonate, resistance to fluid composition, line borate,
Ethylene-chlorotrifluoro-ethylene copolymer, calcium metasilicate, aluminium powder, calcium sulfate, NC Nitroncellulose are mixed in proportion, prepared by extruding pelletization
Obtain plastic particles；
（3）Accumulator housing material is made in plastic particles injection molding.
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| CN102010562A (en) * | 2010-11-15 | 2011-04-13 | 江苏双登集团有限公司 | Environmentally-friendly flame-retardant ABS shell material for valve-controlled sealed lead acid battery |
| CN102070898A (en) * | 2010-12-30 | 2011-05-25 | 金发科技股份有限公司 | Red phosphorus and fire-retarding polyamide composite and preparation method thereof |
| CN103146127A (en) * | 2013-04-04 | 2013-06-12 | 青岛文晟汽车零部件有限公司 | Corrosion-resistant ABS (acrylonitrile butadiene styrene) alloy material for automobile oil delivery pipes |
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Application publication date: 20170901 |