CN107118299A - A kind of environmental protection acrylic elastomer resin and preparation method thereof - Google Patents
A kind of environmental protection acrylic elastomer resin and preparation method thereof Download PDFInfo
- Publication number
- CN107118299A CN107118299A CN201710496846.2A CN201710496846A CN107118299A CN 107118299 A CN107118299 A CN 107118299A CN 201710496846 A CN201710496846 A CN 201710496846A CN 107118299 A CN107118299 A CN 107118299A
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- CN
- China
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- parts
- reaction temperature
- environmental protection
- acrylic elastomer
- elastomer resin
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Classifications
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
- C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
- C08F220/10—Esters
- C08F220/12—Esters of monohydric alcohols or phenols
- C08F220/16—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms
- C08F220/18—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms with acrylic or methacrylic acids
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2/00—Processes of polymerisation
- C08F2/12—Polymerisation in non-solvents
- C08F2/16—Aqueous medium
- C08F2/22—Emulsion polymerisation
- C08F2/24—Emulsion polymerisation with the aid of emulsifying agents
- C08F2/30—Emulsion polymerisation with the aid of emulsifying agents non-ionic
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
- C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
- C08F220/10—Esters
- C08F220/12—Esters of monohydric alcohols or phenols
- C08F220/16—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms
- C08F220/18—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms with acrylic or methacrylic acids
- C08F220/1818—C13or longer chain (meth)acrylate, e.g. stearyl (meth)acrylate
Abstract
The present invention relates to a kind of environmental protection acrylic elastomer resin and preparation method thereof, belong to resin technology field.Including following raw materials by weight：10 15 parts of n-BMA, 55 60 parts of hexadecyl metrhacrylate, 5 10 parts of hydroxyethyl methacrylate, 35 parts of NMA, 0.1 0.3 parts of ethyleneglycol dimethyacrylate, 5 10 parts of 10 emulsifying agents of OP, 0.2 0.5 parts of sodium acid carbonate, 0.2 0.5 parts of ammonium persulfate, 50 100 parts of deionized water.Present invention uses the monomer and crosslinking agent that can overcome prior art shortcoming to a certain extent, under conditions of ensureing that product combination property is constant, environment-friendly type polypropylene olefin(e) acid elastomer is prepared for using emulsion polymerization technique.
Description
Technical field
The present invention relates to a kind of resin and preparation method thereof, it is more particularly related to a kind of environmental protection acrylic
Elastomer resin and preparation method thereof, belongs to resin technology field.
Background technology
Acrylic elastomer resin is main as raw material and the water-proof acrylic acid paint preparation of acrylic rubber
Composition has highly important application.But due to production and application toxicity and the larger polymerization of excitant of current Related product
Monomer, makes remaining waste water after production post processing be difficult to handle.
State Intellectual Property Office discloses a Publication No. CN101899127A in 2010.12.1, and entitled " one kind is poly-
The invention of urethane modified acrylic resin and preparation method thereof ", the invention provides a kind of polyurethane modified acrylic resin and
Its preparation method.First using isocyanates, hydroxyalkyl acrylate and aliphatic alcohol reaction, unsaturated ammonia of the synthesis with double bond
The monomer of carbamate, is proved using examination of infrared spectrum, and the monomer contains C=C double bonds and-NHCOO- groups；The list is used again
Body is formed with acrylate monomer copolymerization, it is characterised in that resin of the present invention contains the structure of alkyl carbamate, is had concurrently poly-
The characteristics of both urethane and acrylic resin, excellent performance is presented, wide, the compound fastness of its applicable base materials strengthens and with ring
Simple, the cheap advantage of guarantor, technique, can dissolve in alcohol or esters solvent.Present invention also offers standby with the resin-made
Ink, composite adhesive, metal surface protection paint, woodenware polishing paint and preparation method thereof.Product prepared by the above method
And process is not very environmentally friendly, and the combination property of product can not be ensured.
The content of the invention
Present invention seek to address that the problems of the prior art are there is provided a kind of environmental protection acrylic elastomer resin, in environmental protection
On the premise of, the combination property of resin will not be changed.
In order to realize foregoing invention purpose, its specific technical scheme is as follows：
A kind of environmental protection acrylic elastomer resin, it is characterised in that：Including following raw materials by weight：
10-15 parts of n-BMA
55-60 parts of hexadecyl metrhacrylate
5-10 parts of hydroxyethyl methacrylate
3-5 parts of NMA
0.1-0.3 parts of ethyleneglycol dimethyacrylate
5-10 parts of OP-10 emulsifying agents
0.2-0.5 parts of sodium acid carbonate
0.2-0.5 parts of ammonium persulfate
50-100 parts of deionized water.
A kind of preparation method of environmental protection acrylic elastomer resin, it is characterised in that：Comprise the following steps that：
A, deionized water, OP-10 emulsifying agents are weighed by recipe requirements in a tool stirring there-necked flask, start stirring, fully dissolve；
B, accurately weigh other raw materials by recipe requirements and be sufficiently mixed in beaker uniformly；Said mixture is poured into described three mouthfuls
In bottle；Stirring is started to continue to make reactant mixture fully emulsified；
C, in 0.5-1h reaction temperature risen to 35-45 DEG C；The sodium acid carbonate prepared in advance, ammonium persulfate is added dropwise to trigger
Agent；Maintain above-mentioned reaction temperature 2h；Maintenance reaction temperature 70 C 2h；80 DEG C of 3h of maintenance reaction temperature；90 DEG C of maintenance reaction temperature
4h；
D, filtering reaction product, remove the caking produced in reaction；Demulsification operation is carried out to filtering out emulsion, the glue after demulsification is filtered out
Block；Blob of viscose is washed, product is drying to obtain.
The advantageous effects that the present invention is brought：
Present invention uses the monomer and crosslinking agent that can overcome prior art shortcoming to a certain extent, ensureing that product is comprehensive
Under conditions of energy is constant, environment-friendly type polypropylene olefin(e) acid elastomer is prepared for using emulsion polymerization technique.
Embodiment
Embodiment 1
A kind of environmental protection acrylic elastomer resin, including following raw materials by weight：
10 parts of n-BMA
55 parts of hexadecyl metrhacrylate
5 parts of hydroxyethyl methacrylate
3 parts of NMA
0.1 part of ethyleneglycol dimethyacrylate
5 parts of OP-10 emulsifying agents
0.2 part of sodium acid carbonate
0.2 part of ammonium persulfate
50 parts of deionized water.
Embodiment 2
A kind of environmental protection acrylic elastomer resin, including following raw materials by weight：
15 parts of n-BMA
60 parts of hexadecyl metrhacrylate
10 parts of hydroxyethyl methacrylate
5 parts of NMA
0.3 part of ethyleneglycol dimethyacrylate
10 parts of OP-10 emulsifying agents
0.5 part of sodium acid carbonate
0.5 part of ammonium persulfate
100 parts of deionized water.
Embodiment 3
A kind of environmental protection acrylic elastomer resin, including following raw materials by weight：
12.5 parts of n-BMA
57.5 parts of hexadecyl metrhacrylate
7.5 parts of hydroxyethyl methacrylate
4 parts of NMA
0.2 part of ethyleneglycol dimethyacrylate
7.5 parts of OP-10 emulsifying agents
0.35 part of sodium acid carbonate
0.35 part of ammonium persulfate
75 parts of deionized water.
Embodiment 4
A kind of environmental protection acrylic elastomer resin, including following raw materials by weight：
11 parts of n-BMA
59 parts of hexadecyl metrhacrylate
8 parts of hydroxyethyl methacrylate
3.5 parts of NMA
0.15 part of ethyleneglycol dimethyacrylate
6 parts of OP-10 emulsifying agents
0.3 part of sodium acid carbonate
0.3 part of ammonium persulfate
59 parts of deionized water.
Embodiment 5
A kind of preparation method of environmental protection acrylic elastomer resin, is comprised the following steps that：
A, deionized water, OP-10 emulsifying agents are weighed by recipe requirements in a tool stirring there-necked flask, start stirring, fully dissolve；
B, accurately weigh other raw materials by recipe requirements and be sufficiently mixed in beaker uniformly；Said mixture is poured into described three mouthfuls
In bottle；Stirring is started to continue to make reactant mixture fully emulsified；
C, in 0.5h reaction temperature risen to 35 DEG C；The sodium acid carbonate prepared in advance, ammonium persulfate initiator is added dropwise；Maintain
Above-mentioned reaction temperature 2h；Maintenance reaction temperature 70 C 2h；80 DEG C of 3h of maintenance reaction temperature；90 DEG C of 4h of maintenance reaction temperature；
D, filtering reaction product, remove the caking produced in reaction；Demulsification operation is carried out to filtering out emulsion, the glue after demulsification is filtered out
Block；Blob of viscose is washed, product is drying to obtain.
Embodiment 6
A kind of preparation method of environmental protection acrylic elastomer resin, is comprised the following steps that：
A, deionized water, OP-10 emulsifying agents are weighed by recipe requirements in a tool stirring there-necked flask, start stirring, fully dissolve；
B, accurately weigh other raw materials by recipe requirements and be sufficiently mixed in beaker uniformly；Said mixture is poured into described three mouthfuls
In bottle；Stirring is started to continue to make reactant mixture fully emulsified；
C, in 1h reaction temperature risen to 45 DEG C；The sodium acid carbonate prepared in advance, ammonium persulfate initiator is added dropwise；In maintenance
State reaction temperature 2h；Maintenance reaction temperature 70 C 2h；80 DEG C of 3h of maintenance reaction temperature；90 DEG C of 4h of maintenance reaction temperature；
D, filtering reaction product, remove the caking produced in reaction；Demulsification operation is carried out to filtering out emulsion, the glue after demulsification is filtered out
Block；Blob of viscose is washed, product is drying to obtain.
Embodiment 7
A kind of preparation method of environmental protection acrylic elastomer resin, is comprised the following steps that：
A, deionized water, OP-10 emulsifying agents are weighed by recipe requirements in a tool stirring there-necked flask, start stirring, fully dissolve；
B, accurately weigh other raw materials by recipe requirements and be sufficiently mixed in beaker uniformly；Said mixture is poured into described three mouthfuls
In bottle；Stirring is started to continue to make reactant mixture fully emulsified；
C, in 0.75h reaction temperature risen to 40 DEG C；The sodium acid carbonate prepared in advance, ammonium persulfate initiator is added dropwise；Dimension
Hold above-mentioned reaction temperature 2h；Maintenance reaction temperature 70 C 2h；80 DEG C of 3h of maintenance reaction temperature；90 DEG C of 4h of maintenance reaction temperature；
D, filtering reaction product, remove the caking produced in reaction；Demulsification operation is carried out to filtering out emulsion, the glue after demulsification is filtered out
Block；Blob of viscose is washed, product is drying to obtain.
Embodiment 8
A kind of preparation method of environmental protection acrylic elastomer resin, is comprised the following steps that：
A, deionized water, OP-10 emulsifying agents are weighed by recipe requirements in a tool stirring there-necked flask, start stirring, fully dissolve；
B, accurately weigh other raw materials by recipe requirements and be sufficiently mixed in beaker uniformly；Said mixture is poured into described three mouthfuls
In bottle；Stirring is started to continue to make reactant mixture fully emulsified；
C, in 0.6h reaction temperature risen to 37 DEG C；The sodium acid carbonate prepared in advance, ammonium persulfate initiator is added dropwise；Maintain
Above-mentioned reaction temperature 2h；Maintenance reaction temperature 70 C 2h；80 DEG C of 3h of maintenance reaction temperature；90 DEG C of 4h of maintenance reaction temperature；
D, filtering reaction product, remove the caking produced in reaction；Demulsification operation is carried out to filtering out emulsion, the glue after demulsification is filtered out
Block；Blob of viscose is washed, product is drying to obtain.
Claims (2)
1. a kind of environmental protection acrylic elastomer resin, it is characterised in that：Including following raw materials by weight：
10-15 parts of n-BMA
55-60 parts of hexadecyl metrhacrylate
5-10 parts of hydroxyethyl methacrylate
3-5 parts of NMA
0.1-0.3 parts of ethyleneglycol dimethyacrylate
5-10 parts of OP-10 emulsifying agents
0.2-0.5 parts of sodium acid carbonate
0.2-0.5 parts of ammonium persulfate
50-100 parts of deionized water.
2. a kind of preparation method of environmental protection acrylic elastomer resin according to claim 1, it is characterised in that：Including
Following processing step：
A, deionized water, OP-10 emulsifying agents are weighed by recipe requirements in a tool stirring there-necked flask, start stirring, fully dissolve；
B, accurately weigh other raw materials by recipe requirements and be sufficiently mixed in beaker uniformly；Said mixture is poured into described three mouthfuls
In bottle；Stirring is started to continue to make reactant mixture fully emulsified；
C, in 0.5-1h reaction temperature risen to 35-45 DEG C；The sodium acid carbonate prepared in advance, ammonium persulfate is added dropwise to trigger
Agent；Maintain above-mentioned reaction temperature 2h；Maintenance reaction temperature 70 C 2h；80 DEG C of 3h of maintenance reaction temperature；90 DEG C of maintenance reaction temperature
4h；
D, filtering reaction product, remove the caking produced in reaction；Demulsification operation is carried out to filtering out emulsion, the glue after demulsification is filtered out
Block；Blob of viscose is washed, product is drying to obtain.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710496846.2A CN107118299A (en) | 2017-06-27 | 2017-06-27 | A kind of environmental protection acrylic elastomer resin and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710496846.2A CN107118299A (en) | 2017-06-27 | 2017-06-27 | A kind of environmental protection acrylic elastomer resin and preparation method thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN107118299A true CN107118299A (en) | 2017-09-01 |
Family
ID=59719422
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201710496846.2A Pending CN107118299A (en) | 2017-06-27 | 2017-06-27 | A kind of environmental protection acrylic elastomer resin and preparation method thereof |
Country Status (1)
| Country | Link |
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| CN (1) | CN107118299A (en) |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1267318A (en) * | 1997-06-19 | 2000-09-20 | 埃勒夫阿托化学有限公司 | Plastic composition |
| WO2006122414A1 (en) * | 2005-05-17 | 2006-11-23 | Matregen Corp. | Depot for sustained and controlled delivery of methotrexate |
| CN103772593A (en) * | 2013-12-09 | 2014-05-07 | 何小刚 | Crylic acid elastic latex and preparation method thereof |
| CN106117418A (en) * | 2016-07-22 | 2016-11-16 | 马晓均 | A kind of preparation method of magnetic steering super-hydrophobic acrylate rubber thin film |
-
2017
- 2017-06-27 CN CN201710496846.2A patent/CN107118299A/en active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1267318A (en) * | 1997-06-19 | 2000-09-20 | 埃勒夫阿托化学有限公司 | Plastic composition |
| WO2006122414A1 (en) * | 2005-05-17 | 2006-11-23 | Matregen Corp. | Depot for sustained and controlled delivery of methotrexate |
| CN103772593A (en) * | 2013-12-09 | 2014-05-07 | 何小刚 | Crylic acid elastic latex and preparation method thereof |
| CN106117418A (en) * | 2016-07-22 | 2016-11-16 | 马晓均 | A kind of preparation method of magnetic steering super-hydrophobic acrylate rubber thin film |
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Application publication date: 20170901 |
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