CN111019038A - Water-based acrylic resin with high acid and alkali resistance and preparation method thereof - Google Patents
Water-based acrylic resin with high acid and alkali resistance and preparation method thereof Download PDFInfo
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- CN111019038A CN111019038A CN201911268723.9A CN201911268723A CN111019038A CN 111019038 A CN111019038 A CN 111019038A CN 201911268723 A CN201911268723 A CN 201911268723A CN 111019038 A CN111019038 A CN 111019038A
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
- C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
- C08F220/10—Esters
- C08F220/12—Esters of monohydric alcohols or phenols
- C08F220/14—Methyl esters, e.g. methyl (meth)acrylate
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
- C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
- C08F220/10—Esters
- C08F220/12—Esters of monohydric alcohols or phenols
- C08F220/16—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms
- C08F220/18—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms with acrylic or methacrylic acids
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- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/10—Printing inks based on artificial resins
- C09D11/102—Printing inks based on artificial resins containing macromolecular compounds obtained by reactions other than those only involving unsaturated carbon-to-carbon bonds
- C09D11/103—Printing inks based on artificial resins containing macromolecular compounds obtained by reactions other than those only involving unsaturated carbon-to-carbon bonds of aldehydes, e.g. phenol-formaldehyde resins
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/10—Printing inks based on artificial resins
- C09D11/106—Printing inks based on artificial resins containing macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- C09D11/107—Printing inks based on artificial resins containing macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds from unsaturated acids or derivatives thereof
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Abstract
The invention discloses a water-based acrylic resin with high acid and alkali resistance and a preparation method thereof, wherein the water-based acrylic resin comprises the following components: the acrylic monomer containing carboxyl, vinyl monomer, acrylate monomer, acrylic monomer containing hydroxyl, functional acrylic monomer, epoxy reactive diluent, initiator, chain transfer agent, mixed solvent, neutralizer and deionized water. The water-based acrylic resin with high acid and alkali resistance and the preparation method thereof have excellent film forming property and storage stability; the prepared coating has excellent acid and alkali resistance, excellent water resistance and excellent adhesive force, and is suitable for preparing glass printing ink.
Description
Technical Field
The invention relates to a water-based acrylic resin and a preparation method thereof, in particular to a water-based acrylic resin with high acid and alkali resistance and a preparation method thereof.
Background
With the development of economy, the development of the printing industry gradually becomes one of the modernized marks, and the printing and decoration application of the glass and the products thereof is more and more extensive. China is the biggest glass producing country in the world, and glass products such as cosmetic bottles, wine bottles, colored crystals and the like in daily life all need to be protected and decorated with coatings to achieve the best effect, and naturally, the requirements on the performance of various aspects of glass ink printing products are higher and higher.
At present, with the continuous strengthening of environmental protection laws and regulations, the printing ink is promoted to develop towards sustainable and low-carbon concepts year by year, and the water-based paint taking water as a dispersion medium and a diluent is an important direction for the development of the ink, so that the discharge of VOC content can be greatly reduced. The aqueous hydroxyl acrylic acid dispersoid is a common binder resin of the cross-linking type ink, but a plurality of properties of the dispersoid are difficult to meet the application requirements at present, and the water-based development of the ink is restricted by low solid content, high viscosity, non-compact film formation, poor acid and alkali resistance and the like of the resin.
In order to improve the performance of glass printing inks, isocyanate curing agents are generally used to achieve a dense coating film, but this increases the cost and limits the time of use of the printing ink. On the other hand, the use of a high molecular weight aqueous propionic acid resin can meet the requirement of high acid and alkali resistance of the coating film, but this also reduces the adhesion of the remaining glass substrate surface.
Disclosure of Invention
The invention aims to solve the technical problem of providing the water-based acrylic resin with high acid and alkali resistance and the preparation method thereof, which have excellent film forming property and storage stability; the prepared coating has excellent acid and alkali resistance, excellent water resistance and excellent adhesive force, and is suitable for preparing glass printing ink.
The invention adopts a technical scheme to solve the technical problems and provides a water-based acrylic resin with high acid and alkali resistance, which comprises the following components: the acrylic monomer containing carboxyl, vinyl monomer, acrylate monomer, acrylic monomer containing hydroxyl, functional acrylic monomer, epoxy reactive diluent, initiator, chain transfer agent, mixed solvent, neutralizer and deionized water.
Further, the weight percentage of each component is as follows: 3-7% of acrylic monomer containing carboxyl, 5-8% of vinyl monomer, 8-13% of acrylate monomer, 4.2-8% of acrylic monomer containing hydroxyl, 4-8% of functional acrylic monomer, 5-10% of epoxy active diluent, 0.1-3% of initiator, 0.3-0.8% of chain transfer agent, 8-18% of mixed solvent, 0.5-3% of neutralizer and 34-46.5% of deionized water.
Further, the acrylic monomer containing carboxyl is acrylic acid or methacrylic acid; the vinyl monomer is vinyl acetate or styrene; the acrylic monomer containing hydroxyl is hydroxyethyl acrylate or hydroxypropyl acrylate; the acrylic ester monomer is one or more of methyl methacrylate, isooctyl methacrylate and butyl acrylate; the functional acrylic monomer is isobornyl methacrylate; the epoxy reactive diluent is tetradecyl glycidyl ether.
Further, the mixed solvent is one or two of propylene glycol butyl ether and n-butanol.
Further, the neutralizing agent is N, N-dimethylethanolamine or triethylamine.
Further, the initiator is azobisisobutyronitrile, azobisisovaleronitrile or tert-butyl peroxybenzoate.
Further, the chain transfer agent is mercaptoethanol, mercaptopropanol or mercaptoacetic acid.
The invention also provides a preparation method of the water-based acrylic resin with high acid and alkali resistance, which aims to solve the technical problems, and the preparation method comprises the following steps:
s1) uniformly stirring the epoxy active diluent and the mixed solvent, and adding the mixture into a multi-mouth flask provided with an electric stirrer, a condensation reflux device, a constant pressure titration funnel and a thermometer;
s2) uniformly mixing the monomer, the initiator and the chain transfer agent, equally dividing into 3 parts, adding the 1 st part of the monomer at 110 ℃, stirring for pre-reaction for 1h, and heating to 140 ℃;
s3) uniformly dripping the rest 2 parts of mixed monomers into the flask within 4h, and continuing to keep the temperature for 2 h;
s4), cooling to 70 ℃, adding a neutralizing agent, adjusting the pH value to 7-8, keeping the temperature for 1h, adding deionized water, and stirring at a high speed to obtain the water-based acrylic resin.
The invention also provides glass ink which comprises the following components: the water-based acrylic resin comprises water-based acrylic resin, amino resin, water-based white slurry, a wetting agent, a leveling agent, a defoaming agent and N, N-dimethylethanolamine, wherein the water-based acrylic resin is the water-based acrylic resin with high acid and alkali resistance.
Further, the weight percentage of each component is as follows: 51% of water-based acrylic resin, 7.5% of amino resin, 40.5% of water-based white slurry, 0.2% of wetting agent, 0.3% of flatting agent, 0.3% of defoaming agent and 0.2% of N, N-dimethylethanolamine.
Compared with the prior art, the invention has the following beneficial effects: the water-based acrylic resin with high acid and alkali resistance and the preparation method thereof have excellent film forming property and storage stability; the prepared coating has excellent acid and alkali resistance, excellent water resistance and excellent adhesive force, and is suitable for preparing glass printing ink.
Drawings
FIG. 1 is a diagram showing the particle size and distribution of the waterborne acrylic resin prepared by the example of the present invention;
FIG. 2 is an infrared spectrum of a waterborne acrylic resin prepared according to an embodiment of the present invention.
FIG. 3 is a graph showing the viscosity change of the aqueous acrylic resin prepared according to the example of the present invention.
Detailed Description
The invention is further described below with reference to the figures and examples.
The raw materials used in the embodiment of the invention are all commercial industrial products except for other descriptions, and can be purchased through commercial channels; the raw materials involved include:
acrylic acid, methacrylic acid, vinyl acetate, styrene, hydroxyethyl acrylate, hydroxypropyl acrylate, methyl methacrylate, isooctyl methacrylate, butyl acrylate, isobornyl methacrylate: industrial grade, korea SK chemistry;
tetradecyl glycidyl ether: industrial grade, guangzhou yuebao science & technology ltd;
propylene glycol methyl ether, n-butanol: industrial grade, dow chemistry;
n, N-dimethylethanolamine, triethylamine: analytically pure, basf;
azobisisobutyronitrile, azobisisovaleronitrile: analytically pure, national medicine group;
mercaptoethanol, mercaptopropanol: analytically pure, normal-cooked arkema;
defoaming agent Tego-901W: industrial grade, degusside height;
wetting agent BYK-346 and leveling agent BYK-333: technical grade, beck chemistry;
water white slurry: YoCH-110, Industrial grade, Shanghai you cai New Material science and technology Co., Ltd;
resimene 747 amino resin: technical grade, english.
Example 1
The water-based acrylic resin with high acid and alkali resistance of the embodiment is prepared from the following raw materials in mass:
7g of methacrylic acid, 8g of vinyl acetate, 13g of methyl methacrylate, 4.2g of hydroxypropyl acrylate, 4g of isobornyl methacrylate, 5g of tetradecyl glycidyl ether, 3g of azodiisovaleronitrile, 0.8g of thinning propanol, 18g of propylene glycol methyl ether, 3g of triethylamine and 34g of deionized water.
The preparation method of the water-based acrylic resin with high acid and alkali resistance of the embodiment comprises the following steps:
1) 5g of tetradecyl glycidyl ether and 18g of propylene glycol methyl ether were stirred well and charged with a motor stirrer. Condensing the solution back into a multi-mouth flask with a constant pressure titration funnel and a thermometer;
2) uniformly mixing 7g of acrylic acid, 8g of styrene, 13g of methyl methacrylate, 4.2g of hydroxyethyl acrylate, 4g of isobornyl methacrylate, 3g of azobisisovaleronitrile and 0.8g of mercaptopropanol, equally dividing into 3 parts, adding the 1 st part of mixture at 110 ℃, stirring for pre-reaction for 1 hour, and heating to 140 ℃;
3) after the remaining 2 parts of the mixture were added dropwise to the flask uniformly over 4h, the temperature was kept for 2 h.
4) And (3) cooling to 70 ℃, adding 3g of triethylamine, adjusting the pH value to 7, keeping the temperature for 1h, adding 34g of deionized water, and stirring at a high speed to obtain the water-based acrylic resin.
Example 2
The water-based acrylic resin with high acid and alkali resistance of the embodiment is prepared from the following raw materials in mass:
5g of acrylic acid, 6g of styrene, 13g of isooctyl methacrylate, 7.4g of hydroxyethyl acrylate, 6g of isobornyl methacrylate, 7g of tetradecyl glycidyl ether, 0.1g of tert-butyl peroxybenzoate, 0.5g of mercaptoacetic acid, 8g of propylene glycol methyl ether, 0.5g of N, N-dimethylethanolamine and 46.5g of deionized water.
The preparation method of the water-based acrylic resin with high acid and alkali resistance of the embodiment comprises the following steps:
1) 7g of tetradecyl glycidyl ether and 8g of propylene glycol methyl ether were stirred well and charged with a motor stirrer. Condensing the solution back into a multi-mouth flask with a constant pressure titration funnel and a thermometer;
2) uniformly mixing 5g of acrylic acid, 6g of styrene, 13g of methyl methacrylate, 7.4g of hydroxyethyl acrylate, 6g of isobornyl methacrylate, 0.1g of tert-butyl peroxybenzoate and 0.5g of mercaptoacetic acid, equally dividing into 3 parts, adding the 1 st part of mixture at 110 ℃, stirring for pre-reaction for 1 hour, and heating to 140 ℃;
3) after the remaining 2 parts of the mixture were added dropwise to the flask uniformly over 4h, the temperature was kept for 2 h.
4) And (3) cooling to 70 ℃, adding 0.5g N N-dimethylethanolamine, adjusting the pH value to 7, keeping the temperature for 1h, adding 46.5g of deionized water, and stirring at a high speed to obtain the water-based acrylic resin.
Example 3
The water-based acrylic resin with high acid and alkali resistance of the embodiment is prepared from the following raw materials in mass:
6g of acrylic acid, 7g of styrene, 10g of methyl methacrylate, 6g of hydroxyethyl acrylate, 7g of isobornyl methacrylate, 8g of tetradecyl glycidyl ether, 0.7g of azobisisobutyronitrile, 0.3g of mercaptoethanol, 13g of propylene glycol methyl ether, 1.7g of N, N-dimethylethanolamine and 40.3g of deionized water.
The preparation method of the water-based acrylic resin with high acid and alkali resistance of the embodiment comprises the following steps:
1) 9g of tetradecyl glycidyl ether and 13g of propylene glycol methyl ether were stirred well and charged with a motor stirrer. Condensing the solution back into a multi-mouth flask with a constant pressure titration funnel and a thermometer;
2) uniformly mixing 6g of acrylic acid, 7g of styrene, 10g of methyl methacrylate, 6g of hydroxyethyl acrylate, 6g of isobornyl methacrylate, 0.7g of azobisisobutyronitrile and 0.3g of mercaptoethanol, equally dividing into 3 parts, adding the 1 st part of mixture at 110 ℃, stirring for pre-reaction for 1 hour, and heating to 140 ℃;
3) after the remaining 2 parts of the mixture were added dropwise to the flask uniformly over 4h, the temperature was kept for 2 h.
4) And cooling to 70 ℃, adding 1.7g N N-dimethylethanolamine, adjusting the pH value to 7, keeping the temperature for 1h, adding 40.3g deionized water, and stirring at a high speed to obtain the water-based acrylic resin.
The emulsion prepared by the embodiment has uniform particle size distribution, and please refer to fig. 1, the particle size and the distribution of the aqueous acrylic resin prepared by the embodiment are tested by a laser particle size analyzer, from which it can be found that the particle size of the aqueous acrylic resin has a monomodal distribution and the particle size distribution is more concentrated.
With continued reference to fig. 2, the infrared spectrum of the aqueous acrylic resin prepared in this example was tested by fourier infrared spectroscopy. As seen in FIG. 2, 3446cm-1is-OH vibration absorption peak, 2920cm-1Is the C-H stretching vibration peak, 1723cm-1C is the symmetric expansion characteristic peak of O. 1160cm-1And 1450cm-1Respectively represents an inner face vibration peak and a C-O vibration peak of-OH in primary alcohol hydroxyl, and is 698cm-1And 759cm-1Is benzene ring but the characteristic peak of substitution in styrene. 1640cm-1No expansion and contraction vibration absorption peak of olefin C ═ C appears nearby, which indicates that the monomer reaction is relatively complete and no residue exists.
The aqueous acrylic resin prepared in the example was prepared into an aqueous glass printing ink according to the following ratio:
| raw materials | w％ |
| Water-based acrylic resin | 51 |
| Resimene 747 | 7.5 |
| YOCH-110 | 40.5 |
| BYK-346 | 0.2 |
| BYK-333 | 0.3 |
| Tego-901W | 0.3 |
| N, N-dimethylethanolamine | 0.2 |
The performance of the water-based glass printing ink coating film is tested according to the relevant national standard, and the results are shown in the table below.
Example 4
The water-based acrylic resin with high acid and alkali resistance of the embodiment is prepared from the following raw materials in mass:
3g of acrylic acid, 5g of styrene, 5g of methyl methacrylate, 3g of butyl acrylate, 8g of hydroxyethyl acrylate, 8g of isobornyl methacrylate, 10g of tetradecyl glycidyl ether, 2.7g of azobisisobutyronitrile, 0.3g of mercaptoethanol, 7g of propylene glycol methyl ether, 3g of N-butanol, 0.8g of N, N-dimethylethanolamine and 44.2g of deionized water.
The preparation method of the water-based acrylic resin with high acid and alkali resistance provided by the embodiment of the invention comprises the following steps:
1) 10g of tetradecyl glycidyl ether, 7g of propylene glycol methyl ether and 3g of n-butanol were uniformly stirred, and the mixture was charged into a motor-driven stirrer. Condensing the solution back into a multi-mouth flask with a constant pressure titration funnel and a thermometer;
2) uniformly mixing 3g of acrylic acid, 5g of styrene, 5g of methyl methacrylate, 3g of butyl acrylate, 8g of hydroxyethyl acrylate, 8g of isobornyl methacrylate, 2.7g of azobisisobutyronitrile and 0.3g of mercaptoethanol, equally dividing into 3 parts, adding the 1 st part of mixture at 110 ℃, stirring for pre-reaction for 1 hour, and heating to 140 ℃;
3) after the remaining 2 parts of the mixture were added dropwise to the flask uniformly over 4h, the temperature was kept for 2 h.
4) And cooling to 70 ℃, adding 1g N, N-dimethylethanolamine, adjusting the pH value to 7, keeping the temperature for 1h, adding 44.2g of deionized water, and stirring at a high speed to obtain the water-based acrylic resin.
FIG. 3 shows the effect of the amount of isobornyl methacrylate on the viscosity of the aqueous acrylic resin, and it can be seen from the graph that the viscosity of the resin gradually decreases as the amount of isobornyl methacrylate increases, and when the amount is 7%, the viscosity of the aqueous acrylic resin reaches the lowest value, and when the amount of isobornyl methacrylate is further increased, the viscosity increases. The isobornyl methacrylate has a large molecular weight, a side chain ester group of the isobornyl methacrylate is a huge and hydrophobic tertiary carbon structure, the acting force among molecular chains can be effectively weakened, a formed polymer macromolecular chain has good regularity, and therefore the viscosity of resin can be reduced.
The amount of epoxy reactive diluent used not only affects the water solubility of the waterborne hydroxyl acrylic resin, but also greatly affects the performance of the resin after film formation, and the tetradecyl glycidyl ether used in this example is used as epoxy reactive diluent for ring-opening graft modification with acrylic monomer, and the effect on the resin performance is shown in the following table:
as is apparent from the table, the viscosity of the synthetic resin is gradually reduced with the increasing amount of the epoxy reactive diluent, which further proves that the reactive diluent acts as a diluent in the early stage of the reaction and plays an important role in reducing viscosity, but the resistance of the synthetic resin is influenced with the further increasing amount of the reactive diluent, so that the resistance of the resin is ensured by selecting the proper amount on the premise of ensuring the water solubility of the resin.
Although the present invention has been described with respect to the preferred embodiments, it will be understood by those skilled in the art that various changes in form and details may be made therein without departing from the spirit and scope of the invention as defined by the appended claims.
Claims (10)
1. A water-based acrylic resin with high acid and alkali resistance is characterized by comprising the following components: the acrylic monomer containing carboxyl, vinyl monomer, acrylate monomer, acrylic monomer containing hydroxyl, functional acrylic monomer, epoxy reactive diluent, initiator, chain transfer agent, mixed solvent, neutralizer and deionized water.
2. The water-based acrylic resin with high acid and alkali resistance as claimed in claim 1, wherein the mass percentage of each component is as follows: 3-7% of acrylic monomer containing carboxyl, 5-8% of vinyl monomer, 8-13% of acrylate monomer, 4.2-8% of acrylic monomer containing hydroxyl, 4-8% of functional acrylic monomer, 5-10% of epoxy active diluent, 0.1-3% of initiator, 0.3-0.8% of chain transfer agent, 8-18% of mixed solvent, 0.5-3% of neutralizer and 34-46.5% of deionized water.
3. The aqueous acrylic resin having high acid and alkali resistance according to claim 1, wherein the carboxyl group-containing acrylic monomer is acrylic acid or methacrylic acid; the vinyl monomer is vinyl acetate or styrene; the acrylic monomer containing hydroxyl is hydroxyethyl acrylate or hydroxypropyl acrylate; the acrylic ester monomer is one or more of methyl methacrylate, isooctyl methacrylate and butyl acrylate; the functional acrylic monomer is isobornyl methacrylate; the epoxy reactive diluent is tetradecyl glycidyl ether.
4. The aqueous acrylic resin having high acid and alkali resistance according to claim 1, wherein the mixed solvent is one or both of propylene glycol butyl ether and n-butanol.
5. The aqueous acrylic resin having high acid and alkali resistance according to claim 1, wherein the neutralizing agent is N, N-dimethylethanolamine or triethylamine.
6. The aqueous acrylic resin having high acid and alkali resistance according to claim 1, wherein the initiator is azobisisobutyronitrile, azobisisovaleronitrile or tert-butyl peroxybenzoate.
7. The aqueous acrylic resin having high acid and alkali resistance according to claim 1, wherein the chain transfer agent is mercaptoethanol, mercaptopropanol or mercaptoacetic acid.
8. A method for preparing the aqueous acrylic resin having high acid-base resistance as set forth in any one of claims 1 to 7, comprising the steps of:
s1) uniformly stirring the epoxy active diluent and the mixed solvent, and adding the mixture into a multi-mouth flask provided with an electric stirrer, a condensation reflux device, a constant pressure titration funnel and a thermometer;
s2) uniformly mixing the monomer, the initiator and the chain transfer agent, equally dividing into 3 parts, adding the 1 st part of the monomer at 110 ℃, stirring for pre-reaction for 1h, and heating to 140 ℃;
s3) uniformly dripping the rest 2 parts of mixed monomers into the flask within 4h, and continuing to keep the temperature for 2 h;
s4), cooling to 70 ℃, adding a neutralizing agent, adjusting the pH value to 7-8, keeping the temperature for 1h, adding deionized water, and stirring at a high speed to obtain the water-based acrylic resin.
9. Glass ink, characterized by comprising the following components: the water-based acrylic resin, amino resin, water-based white slurry, a wetting agent, a leveling agent, a defoaming agent and N, N-dimethylethanolamine, wherein the water-based acrylic resin with high acid and alkali resistance is defined in any one of claims 1 to 7.
10. The glass ink according to claim 9, wherein the components are in the following mass percent: 51% of water-based acrylic resin, 7.5% of amino resin, 40.5% of water-based white slurry, 0.2% of wetting agent, 0.3% of flatting agent, 0.3% of defoaming agent and 0.2% of N, N-dimethylethanolamine.
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Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN112080182A (en) * | 2020-09-24 | 2020-12-15 | 西北永新涂料有限公司 | Cold-coating zinc coating with high compactness and preparation method thereof |
| CN113185634A (en) * | 2021-06-10 | 2021-07-30 | 安徽强邦印刷材料有限公司 | Solvent-resistant resin and application thereof in printing plate coating |
| CN115073894A (en) * | 2022-07-05 | 2022-09-20 | 威海市铎豪碳纳米科技有限公司 | Filling master batch for high-compatibility degradable material and preparation method thereof |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105601785A (en) * | 2015-11-06 | 2016-05-25 | 武汉工程大学 | Epoxy active diluent modified acrylic acid resin aqueous dispersion |
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2019
- 2019-12-11 CN CN201911268723.9A patent/CN111019038A/en active Pending
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105601785A (en) * | 2015-11-06 | 2016-05-25 | 武汉工程大学 | Epoxy active diluent modified acrylic acid resin aqueous dispersion |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN112080182A (en) * | 2020-09-24 | 2020-12-15 | 西北永新涂料有限公司 | Cold-coating zinc coating with high compactness and preparation method thereof |
| CN112080182B (en) * | 2020-09-24 | 2022-02-08 | 西北永新涂料有限公司 | Cold-coating zinc coating with high compactness and preparation method thereof |
| CN113185634A (en) * | 2021-06-10 | 2021-07-30 | 安徽强邦印刷材料有限公司 | Solvent-resistant resin and application thereof in printing plate coating |
| CN115073894A (en) * | 2022-07-05 | 2022-09-20 | 威海市铎豪碳纳米科技有限公司 | Filling master batch for high-compatibility degradable material and preparation method thereof |
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