CN107117924A - Plugging agent for building and preparation method thereof - Google Patents

Plugging agent for building and preparation method thereof Download PDF

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Publication number
CN107117924A
CN107117924A CN201710540741.2A CN201710540741A CN107117924A CN 107117924 A CN107117924 A CN 107117924A CN 201710540741 A CN201710540741 A CN 201710540741A CN 107117924 A CN107117924 A CN 107117924A
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CN
China
Prior art keywords
parts
sealing agent
building
surfactant
filler
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
CN201710540741.2A
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Chinese (zh)
Inventor
郭建
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Hefei Yipianye Decoration Engineering Co ltd
Original Assignee
Hefei Yipianye Decoration Engineering Co ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Hefei Yipianye Decoration Engineering Co ltd filed Critical Hefei Yipianye Decoration Engineering Co ltd
Priority to CN201710540741.2A priority Critical patent/CN107117924A/en
Publication of CN107117924A publication Critical patent/CN107117924A/en
Withdrawn legal-status Critical Current

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Classifications

    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B28/00Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
    • C04B28/24Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing alkyl, ammonium or metal silicates; containing silica sols
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2111/00Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
    • C04B2111/00241Physical properties of the materials not provided for elsewhere in C04B2111/00
    • C04B2111/00293Materials impermeable to liquids
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2111/00Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
    • C04B2111/72Repairing or restoring existing buildings or building materials

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Ceramic Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Inorganic Chemistry (AREA)
  • Materials Engineering (AREA)
  • Structural Engineering (AREA)
  • Organic Chemistry (AREA)
  • Sealing Material Composition (AREA)

Abstract

The invention discloses a plugging agent for buildings and a preparation method thereof, wherein the plugging agent comprises the following raw materials: silica sol, polyacrylamide, polyvinyl alcohol, a filler, sepiolite, a surfactant, a high-efficiency accelerator and ethanol. The preparation method comprises the following steps: mixing polyacrylamide, polyvinyl alcohol and a proper amount of water, heating and stirring until the mixture is dissolved, adding a filler and a surfactant, stirring uniformly, and cooling for later use; and adding ethanol into another stirring reactor, slowly adding the prepared mixture while stirring, adding silica sol, sepiolite and a high-efficiency accelerator, and mixing and ultrasonically dispersing for 10-20 min to obtain the plugging agent. The plugging agent not only has good fluidity and can permeate into building cracks of different gaps, thereby greatly improving the building plugging effect, but also has good bonding strength and waterproof performance, effectively improving the connection between the plugging agent and a building and preventing secondary leakage.

Description

A kind of sealing agent for building and preparation method
Technical field
The present invention relates to building material technical field, and in particular to a kind of sealing agent for building and preparation method.
Background technology
At present, continuing to develop with construction business, construction quality also turns into the important topic of people's care at all times. After many traditional architectures come into operation, it will soon find that water leakage phenomenon can occur for wall, especially after the impact of heavy rain, Drainage is more serious, largely have impact on the sound development of real estate.
The quality of waterproofing quality is directly connected to building and the service life of structures and living and working in peace and contentment for the people, In recent years, the incidence of the roof waterproof seepage of China's building is high, and part building is non-delivery in use, just being oozed Leakage, the percolation ratio that current roofing occurs in the waterproof guarantee time limit has exceeded more than 50%.The seepage occurred for building construction, The outer anti-partial failure typically built, causes waterproof layer seepage occur, and seeps water by the defect of concrete must can just enter Enter building interior, the tiny crack of such as inside concrete cause when infiltration, concrete construction due to vibrate it is unreal and occur it is anti- The poor position infiltration of oozing property is very general free and unfettered, and the conventional waterproof layer design of domestic building designers is most of to use coiled material class waterproof Material, wherein it is in the majority with SBS waterproof rolls, for this kind of waterproof material, due to being constructed by the way of being stained with using point, easily wear Water phenomenon, find waterproof material ooze vanish it is a little more difficult.In order to quickly and effectively administer infiltration, to building interior concrete defect Position is quickly repaired, and is the preferable method for solving leakage of building.The sealing agent wide variety used at present, it is such as unsaturated Polyesters, propylene ester-amine series, polyurethanes etc., it is many at present using polyurethane grouting material progress leak stopping for creepage concrete, Although can more rapid sealing, reach administer seepage requirement.But the technology also has more obvious shortcoming:(1) for The concrete surface seepage that concrete vibrating is unreal and causes, the mode of slip casting is helpless, because can not in filling process Obvious crack is found, therefore the passage of grouting can not be formed;(2) crack after grouting, if due to settlement of foundation etc. because Element, is likely to result in crack and continues to expand, it is possible to cause second of seepage.For this leakage problems, it is badly in need of a kind of peace of research and development Complete durable sealing agent, it is ensured that the security of building.
The content of the invention
For defect of the prior art, it is an object of the invention to provide a kind of sealing agent for building and preparation method, institute Stating sealing agent not only has in preferable mobility, the building cracks that can penetrate into different gaps, greatly improves building mending-leakage effect Really, the connection between sealing agent and building also is effectively improved with preferable adhesion strength and water resistance, prevents secondary ooze Leakage.
The present invention solves technical problem and adopted the following technical scheme that:
The present invention relates to each raw material of a kind of sealing agent for building, including following parts by weight:30 ~ 45 parts of Ludox, polyacrylamide 5 ~ 10 parts of amine, 12 ~ 20 parts of polyvinyl alcohol, 7 ~ 15 parts of filler, 1 ~ 3 part of sepiolite, 3 ~ 6 parts of surfactant, efficient accelerator 0.5 ~ 2.5 part, 10 ~ 20 parts of ethanol, and appropriate water.
Preferably, the sealing agent includes each raw material of following parts by weight:40 parts of Ludox, 8 parts of polyacrylamide, poly- second 15 parts of enol, 10 parts of filler, 2 parts of sepiolite, 4 parts of surfactant, 1.5 parts of efficient accelerator, 18 parts of ethanol, and appropriate Water.
Preferably, the filler is any of anhydrous calcium chloride, lime stone, precipitated calcium carbonate.
Preferably, the surfactant is lignosulfonates or naphthalene sulphonate formaldehyde polymer.
Preferably, the efficient accelerator is aluminate or alkali-free liquid accelerator.
The invention further relates to a kind of method for preparing sealing agent for building, comprise the following steps:
(1)Polyacrylamide, polyvinyl alcohol and appropriate water are weighed respectively according to proportioning to add in stirred reactor, are warming up to 70 ~ 80 DEG C, stirring adds filler and surfactant, stirred to dissolving, and cools down standby;
(2)Ethanol is added in another stirred reactor, step is slowly added to while stirring(1)Obtained mixture, mixing is equal After even, Ludox is added, sepiolite and efficient accelerator are added after stirring, be well mixed, then by mixture 10 ~ 20min of ultrasonic disperse in ultrasonic wave is placed in, the sealing agent is produced.
Preferably, the step(1)The quality of middle addition water is 15 ~ 25 times of polymer quality.
Preferably, the step(2)Middle addition step(1)The speed control of middle mixture is in 60 ~ 90min completion of dropping.
Compared with prior art, the present invention has following beneficial effect:
(1)Sealing agent for building of the present invention, not only with preferable mobility, the building that can penetrate into different gaps is split In seam, building mending-leakage effect is greatly improved, also with preferable adhesion strength and water resistance, sealing agent and building is effectively improved Connection between thing, prevents secondary seepage, with preferable application value.
(2)Sepiolite is added with sealing agent for building of the present invention, is limbered up with water is met, dries the property being hardened Can, good fluidity and dried connectivity robustness for sealing agent provide guarantee.
(3)Polyacrylamide is added with sealing agent for building of the present invention, with preferable adsorption function, energy Enough absorption suspended particle agglomeration fills the dispersing uniformity that each component is on the one hand improved with building in gap into macromolecular mass, separately On the one hand suspended particles are prevented to be layered.
(4)Polyvinyl alcohol is also added with sealing agent for building of the present invention, with preferable thickening, thickening, Scattered, emulsification and the effect of protecting colloid, can not only improve the dispersing uniformity between each component, also substantially increase leak stopping The viscosity of agent, enhances the being firmly bonded property between sealing agent and building.
(5)The preparation technology of sealing agent for building of the present invention is simple, mild condition, equipment investment are few, and produces Journey is safe and pollution-free, is adapted to industrialization promotion production, with preferable application prospect.
Embodiment
With reference to specific embodiment, the present invention is expanded on further.These embodiments be merely to illustrate the present invention and without In limitation the scope of the present invention.The experimental method of unreceipted actual conditions in the following example, generally according to normal condition, for example Sambrook equimoleculars are cloned:Laboratory manual(New York:Cold Spring Harbor Laboratory Press, 1989)Described in condition, or according to the condition proposed by manufacturer.
Embodiment 1:
A kind of sealing agent for building and preparation method of the preferred embodiment of the present invention;
The sealing agent for building, is prepared from by each raw material of following parts by weight:
40 parts of Ludox;
8 parts of polyacrylamide;
15 parts of polyvinyl alcohol;
10 parts of filler;
2 parts of sepiolite;
4 parts of surfactant;
Efficient 1.5 parts of accelerator;
18 parts of ethanol;
And appropriate water.
The filler is anhydrous calcium chloride.
The surfactant is lignosulfonates.
The efficient accelerator is aluminate.
The method that the present invention prepares sealing agent for building, comprises the following steps:
(1)Polyacrylamide, polyvinyl alcohol and appropriate water are weighed respectively according to proportioning to add in stirred reactor, are warming up to 80 DEG C, stirring adds filler and surfactant, stirred to dissolving, and cools down standby;
(2)Ethanol is added in another stirred reactor, step is slowly added to while stirring(1)Obtained mixture, mixing is equal After even, Ludox is added, sepiolite and efficient accelerator are added after stirring, be well mixed, then by mixture Ultrasonic disperse 15min in ultrasonic wave is placed in, the sealing agent is produced.
Step(1)The quality of middle addition water is 20 times of polymer quality.
Step(2)Middle addition step(1)The speed control of middle mixture is in 80min completion of dropping.
Embodiment 2:
A kind of sealing agent for building and preparation method of the preferred embodiment of the present invention;
The sealing agent for building, is prepared from by each raw material of following parts by weight:
30 parts of Ludox;
5 parts of polyacrylamide;
12 parts of polyvinyl alcohol;
7 parts of filler;
1 part of sepiolite;
3 parts of surfactant;
Efficient 0.5 part of accelerator;
10 parts of ethanol;
And appropriate water.
The filler is lime stone.
The surfactant is naphthalene sulphonate formaldehyde polymer.
The efficient accelerator is alkali-free liquid accelerator.
The method that the present invention prepares sealing agent for building, comprises the following steps:
(1)Polyacrylamide, polyvinyl alcohol and appropriate water are weighed respectively according to proportioning to add in stirred reactor, are warming up to 70 DEG C, stirring adds filler and surfactant, stirred to dissolving, and cools down standby;
(2)Ethanol is added in another stirred reactor, step is slowly added to while stirring(1)Obtained mixture, mixing is equal After even, Ludox is added, sepiolite and efficient accelerator are added after stirring, be well mixed, then by mixture Ultrasonic disperse 10min in ultrasonic wave is placed in, the sealing agent is produced.
Step(1)The quality of middle addition water is 15 times of polymer quality.
Step(2)Middle addition step(1)The speed control of middle mixture is in 60min completion of dropping.
Embodiment 3:
A kind of sealing agent for building and preparation method of the preferred embodiment of the present invention;
The sealing agent for building, is prepared from by each raw material of following parts by weight:
45 parts of Ludox;
10 parts of polyacrylamide;
20 parts of polyvinyl alcohol;
15 parts of filler;
3 parts of sepiolite;
6 parts of surfactant;
Efficient 2.5 parts of accelerator;
20 parts of ethanol;
And appropriate water.
The filler is precipitated calcium carbonate.
The surfactant is lignosulfonates.
The efficient accelerator is aluminate.
The method that the present invention prepares sealing agent for building, comprises the following steps:
(1)Polyacrylamide, polyvinyl alcohol and appropriate water are weighed respectively according to proportioning to add in stirred reactor, are warming up to 80 DEG C, stirring adds filler and surfactant, stirred to dissolving, and cools down standby;
(2)Ethanol is added in another stirred reactor, step is slowly added to while stirring(1)Obtained mixture, mixing is equal After even, Ludox is added, sepiolite and efficient accelerator are added after stirring, be well mixed, then by mixture Ultrasonic disperse 20min in ultrasonic wave is placed in, the sealing agent is produced.
Step(1)The quality of middle addition water is 25 times of polymer quality.
Step(2)Middle addition step(1)The speed control of middle mixture is in 90min completion of dropping.
Performance test:
The sealing agent for building that embodiment 1 ~ 3 is prepared is subjected to performance test respectively respectively, comprised the following steps that:
(1)Make test glass
Use cement:It is husky:Water=2:3:1 mixture is raw material, and internal diameter is made for 50mm, high 40mm, thick 10mm concrete cups, This cup is slit longitudinally into two halves, then where together, is fastened in its periphery with vinyl strap.
Three groups of sample cups are made according to this step, it is every group 5, standby.
(2)Waterproof Drain Resistance performance test
In being injected separately into the sealing agent 20ml that the embodiment of the present invention 1 ~ 3 is prepared in every group of sample cup under water wet condition, and it is quiet Put and poured out after 1h, each injection 20ml clear water, places 1 round the clock, observe water leakage situation after then being rinsed well respectively with water;Then again 5 observation water leakage situations of water are filled repeatedly.
(3)Test result
Leak stopping performance test is carried out according to the method described above, learns that the sealing agent that the embodiment of the present invention 1 ~ 3 is prepared places 1 round the clock Cup is without drainage afterwards, and fills water test repeatedly 5 times also without drainage.
In summary, sealing agent for building of the present invention, not only with preferable mobility, can penetrate into different seams In the building cracks of gap, building mending-leakage effect is greatly improved, also with preferable adhesion strength and water resistance, is effectively improved stifled The connection between agent and building is leaked, secondary seepage is prevented, with preferable application value.
The preparation technology of sealing agent for building of the present invention is simple, mild condition, equipment investment are few, and production process is pacified Entirely, it is pollution-free, it is adapted to industrialization promotion production, with preferable application prospect.
The specific embodiment of the present invention is described above.It is to be appreciated that the invention is not limited in above-mentioned Particular implementation, those skilled in the art can make various deformations or amendments within the scope of the claims, this not shadow Ring the substantive content of the present invention.

Claims (8)

1. a kind of sealing agent for building, it is characterised in that:Each raw material including following parts by weight:30 ~ 45 parts of Ludox, polypropylene 5 ~ 10 parts of acid amides, 12 ~ 20 parts of polyvinyl alcohol, 7 ~ 15 parts of filler, 1 ~ 3 part of sepiolite, 3 ~ 6 parts of surfactant, efficient rapid hardening 0.5 ~ 2.5 part of agent, 10 ~ 20 parts of ethanol, and appropriate water.
2. sealing agent for building according to claim 1, it is characterised in that:The sealing agent includes each of following parts by weight Raw material:40 parts of Ludox, 8 parts of polyacrylamide, 15 parts of polyvinyl alcohol, 10 parts of filler, 2 parts of sepiolite, surfactant 4 Part, 1.5 parts of efficient accelerator, 18 parts of ethanol, and appropriate water.
3. sealing agent for building according to claim 1, it is characterised in that:The filler is anhydrous calcium chloride, lime Any of stone, precipitated calcium carbonate.
4. sealing agent for building according to claim 1, it is characterised in that:The surfactant is lignosulfonates Or naphthalene sulphonate formaldehyde polymer.
5. sealing agent for building according to claim 1, it is characterised in that:The efficient accelerator is aluminate or nothing Alkali liquid quick-setting agent.
6. the method that one kind prepares the sealing agent for building as described in any one of claim 1 ~ 5, it is characterised in that:Including as follows Step:
(1)Polyacrylamide, polyvinyl alcohol and appropriate water are weighed respectively according to proportioning to add in stirred reactor, are warming up to 70 ~ 80 DEG C, stirring adds filler and surfactant, stirred to dissolving, and cools down standby;
(2)Ethanol is added in another stirred reactor, step is slowly added to while stirring(1)Obtained mixture, mixing is equal After even, Ludox is added, sepiolite and efficient accelerator are added after stirring, be well mixed, then by mixture 10 ~ 20min of ultrasonic disperse in ultrasonic wave is placed in, the sealing agent is produced.
7. the preparation method of sealing agent for building according to claim 6, it is characterised in that:The step(1)It is middle to add The quality of water is 15 ~ 25 times of polymer quality.
8. the preparation method of sealing agent for building according to claim 6, it is characterised in that:The step(2)It is middle to add Step(1)The speed control of middle mixture is in 60 ~ 90min completion of dropping.
CN201710540741.2A 2017-07-05 2017-07-05 Plugging agent for building and preparation method thereof Withdrawn CN107117924A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201710540741.2A CN107117924A (en) 2017-07-05 2017-07-05 Plugging agent for building and preparation method thereof

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Application Number Priority Date Filing Date Title
CN201710540741.2A CN107117924A (en) 2017-07-05 2017-07-05 Plugging agent for building and preparation method thereof

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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108640582A (en) * 2018-06-20 2018-10-12 河南阳光防水科技有限公司 Microdilatancy low viscosity grouting for water plugging agent
CN109232819A (en) * 2018-09-19 2019-01-18 佛山市三水伯马絮凝剂厂 A kind of aqueous composite material and preparation method of linear polypropylene acid esters
CN113767082A (en) * 2019-05-29 2021-12-07 Sika技术股份公司 Non-invasive repair and modification of hardened cement-based materials

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101439944A (en) * 2008-10-17 2009-05-27 王功全 Plugging anti-seepage agent
CN105016651A (en) * 2015-07-14 2015-11-04 桂林市和鑫防水装饰材料有限公司 Expansion-controllable plugging agent
CN105523729A (en) * 2016-01-22 2016-04-27 广西科开成林科技有限公司 Efficient fast-setting bentonite-compounded waterproof plugging agent

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101439944A (en) * 2008-10-17 2009-05-27 王功全 Plugging anti-seepage agent
CN105016651A (en) * 2015-07-14 2015-11-04 桂林市和鑫防水装饰材料有限公司 Expansion-controllable plugging agent
CN105523729A (en) * 2016-01-22 2016-04-27 广西科开成林科技有限公司 Efficient fast-setting bentonite-compounded waterproof plugging agent

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108640582A (en) * 2018-06-20 2018-10-12 河南阳光防水科技有限公司 Microdilatancy low viscosity grouting for water plugging agent
CN109232819A (en) * 2018-09-19 2019-01-18 佛山市三水伯马絮凝剂厂 A kind of aqueous composite material and preparation method of linear polypropylene acid esters
CN113767082A (en) * 2019-05-29 2021-12-07 Sika技术股份公司 Non-invasive repair and modification of hardened cement-based materials

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