CN107116675A - Dry method illusion-colour particle, Ceramic Tiles of micro mist composite decoration and preparation method thereof - Google Patents

Dry method illusion-colour particle, Ceramic Tiles of micro mist composite decoration and preparation method thereof Download PDF

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Publication number
CN107116675A
CN107116675A CN201710496390.XA CN201710496390A CN107116675A CN 107116675 A CN107116675 A CN 107116675A CN 201710496390 A CN201710496390 A CN 201710496390A CN 107116675 A CN107116675 A CN 107116675A
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CN
China
Prior art keywords
powder
particle
toner
blanking
preparation
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Granted
Application number
CN201710496390.XA
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Chinese (zh)
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CN107116675B (en
Inventor
邓啟棠
吴文武
周勇
黄玲艳
朱晨华
邓爱忠
文卫国
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Guangdong Qingyuan Monalisa Ceramics Co Ltd
Monalisa Group Co Ltd
Original Assignee
Guangdong Qingyuan Monalisa Ceramics Co Ltd
Monalisa Group Co Ltd
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Application filed by Guangdong Qingyuan Monalisa Ceramics Co Ltd, Monalisa Group Co Ltd filed Critical Guangdong Qingyuan Monalisa Ceramics Co Ltd
Priority to CN201710496390.XA priority Critical patent/CN107116675B/en
Publication of CN107116675A publication Critical patent/CN107116675A/en
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Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B28WORKING CEMENT, CLAY, OR STONE
    • B28BSHAPING CLAY OR OTHER CERAMIC COMPOSITIONS; SHAPING SLAG; SHAPING MIXTURES CONTAINING CEMENTITIOUS MATERIAL, e.g. PLASTER
    • B28B15/00General arrangement or layout of plant ; Industrial outlines or plant installations
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B28WORKING CEMENT, CLAY, OR STONE
    • B28BSHAPING CLAY OR OTHER CERAMIC COMPOSITIONS; SHAPING SLAG; SHAPING MIXTURES CONTAINING CEMENTITIOUS MATERIAL, e.g. PLASTER
    • B28B13/00Feeding the unshaped material to moulds or apparatus for producing shaped articles; Discharging shaped articles from such moulds or apparatus
    • B28B13/02Feeding the unshaped material to moulds or apparatus for producing shaped articles
    • B28B13/0215Feeding the moulding material in measured quantities from a container or silo
    • B28B13/027Feeding the moulding material in measured quantities from a container or silo by using a removable belt or conveyor transferring the moulding material to the moulding cavities
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B28WORKING CEMENT, CLAY, OR STONE
    • B28BSHAPING CLAY OR OTHER CERAMIC COMPOSITIONS; SHAPING SLAG; SHAPING MIXTURES CONTAINING CEMENTITIOUS MATERIAL, e.g. PLASTER
    • B28B3/00Producing shaped articles from the material by using presses; Presses specially adapted therefor
    • B28B3/02Producing shaped articles from the material by using presses; Presses specially adapted therefor wherein a ram exerts pressure on the material in a moulding space; Ram heads of special form
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B28WORKING CEMENT, CLAY, OR STONE
    • B28BSHAPING CLAY OR OTHER CERAMIC COMPOSITIONS; SHAPING SLAG; SHAPING MIXTURES CONTAINING CEMENTITIOUS MATERIAL, e.g. PLASTER
    • B28B3/00Producing shaped articles from the material by using presses; Presses specially adapted therefor
    • B28B3/12Producing shaped articles from the material by using presses; Presses specially adapted therefor wherein one or more rollers exert pressure on the material
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B28WORKING CEMENT, CLAY, OR STONE
    • B28CPREPARING CLAY; PRODUCING MIXTURES CONTAINING CLAY OR CEMENTITIOUS MATERIAL, e.g. PLASTER
    • B28C3/00Apparatus or methods for mixing clay with other substances
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B28WORKING CEMENT, CLAY, OR STONE
    • B28CPREPARING CLAY; PRODUCING MIXTURES CONTAINING CLAY OR CEMENTITIOUS MATERIAL, e.g. PLASTER
    • B28C5/00Apparatus or methods for producing mixtures of cement with other substances, e.g. slurries, mortars, porous or fibrous compositions
    • B28C5/08Apparatus or methods for producing mixtures of cement with other substances, e.g. slurries, mortars, porous or fibrous compositions using driven mechanical means affecting the mixing
    • B28C5/18Mixing in containers to which motion is imparted to effect the mixing
    • B28C5/20Mixing in containers to which motion is imparted to effect the mixing rotating about a horizontal or substantially horizontal axis during mixing, e.g. without independent stirrers
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B28WORKING CEMENT, CLAY, OR STONE
    • B28CPREPARING CLAY; PRODUCING MIXTURES CONTAINING CLAY OR CEMENTITIOUS MATERIAL, e.g. PLASTER
    • B28C7/00Controlling the operation of apparatus for producing mixtures of clay or cement with other substances; Supplying or proportioning the ingredients for mixing clay or cement with other substances; Discharging the mixture
    • B28C7/02Controlling the operation of the mixing
    • B28C7/028Controlling the operation of the mixing by counting the number of revolutions performed, or by measuring the mixing time
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B28WORKING CEMENT, CLAY, OR STONE
    • B28CPREPARING CLAY; PRODUCING MIXTURES CONTAINING CLAY OR CEMENTITIOUS MATERIAL, e.g. PLASTER
    • B28C7/00Controlling the operation of apparatus for producing mixtures of clay or cement with other substances; Supplying or proportioning the ingredients for mixing clay or cement with other substances; Discharging the mixture
    • B28C7/04Supplying or proportioning the ingredients
    • B28C7/0404Proportioning
    • B28C7/0413Proportioning two or more flows in predetermined ratio
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B28WORKING CEMENT, CLAY, OR STONE
    • B28CPREPARING CLAY; PRODUCING MIXTURES CONTAINING CLAY OR CEMENTITIOUS MATERIAL, e.g. PLASTER
    • B28C9/00General arrangement or layout of plant
    • B28C9/02General arrangement or layout of plant for producing mixtures of clay or cement with other materials

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Dispersion Chemistry (AREA)
  • Ceramic Engineering (AREA)
  • Manufacturing & Machinery (AREA)
  • Structural Engineering (AREA)
  • Finishing Walls (AREA)
  • Preparation Of Clay, And Manufacture Of Mixtures Containing Clay Or Cement (AREA)

Abstract

A kind of all improved the invention provides floral designs, tone and production technology dry method illusion-colour particle, Ceramic Tiles of micro mist composite decoration and preparation method thereof, this method includes:Basic powder and colorant are subjected to dry mixed, toner is fabricated to;Toner is granulated and coloured particle of different shapes is formed;The toner of coloured particle and different colours is delivered in multiple agitators respectively in the ratio of setting and stirred;By the powder after being stirred in each agitator respectively through each feeding belt according in default material loading procedure blanking to vertical material-distributing device, natural packing forms flower pattern;By the flower pattern powder of formation deliver to press it is framed in and it is compressing.

Description

Dry method illusion-colour particle, Ceramic Tiles of micro mist composite decoration and preparation method thereof
Technical field
The present invention relates to architectural pottery technical field, more particularly to a kind of dry method illusion-colour particle, micro mist composite decoration Ceramic Tiles and preparation method thereof.
Background technology
With the continuous development and progress of ceramic industry, Ceramic Tiles have many in each technological process and preparation method Improvement and innovation.Wherein in flow of the base powder to color, although existing dry method colour mixture occurs, but fresh rare, especially pole It is used in less among conventional ceramic brick product, its main cause is that dry method colour mixture contrasts traditional wet method to color, in the mistake of production It is easier to color group occur in journey, and is difficult to solve, therefore is seldom used among polished bricks fabric.And conventional wet is to color base The granulation of powder, its granularity is small, thickness is single, color is dull, difficult with matching present colourful layout style, and granulation is received Very low into rate, powder wastes very serious.
Ink-jet products such as glazed tile, Antique Imitation Tiles, vertical infiltration in the market, its texture-rich, tone dazzle it is beautiful, close to day Right stone material, occupies the half of the country of inner wall of building brick, but its surface can not copy the stereo concave-convex sense of lithotome all the time, It is caused positive decorative effect is stiff, dullness.Its granularity of traditional granulation is small, thickness is single, color is single, it is impossible to incorporate rich In rich colorful ceramic surface, hardly possible matches with layout style, and granulation harvest rate is very low, and powder wastes very serious.Such as The diversity and the advantage of the stereo concave-convex sense of space of a whole page stone material what granulates dry method colour mixture are embodied among product, and solve color group The problems such as, it is the problem of being currently needed for solving.
The content of the invention
The problem of existing for prior art, it is an object of the invention to provide a kind of floral designs, tone and production work Dry method illusion-colour particle that skill is all improved, Ceramic Tiles of micro mist composite decoration and preparation method thereof.
The invention provides a kind of dry method illusion-colour particle, the preparation method of the Ceramic Tiles of micro mist composite decoration, including:
Basic powder and colorant are subjected to dry mixed, toner is fabricated to;
Toner is granulated and coloured particle of different shapes is formed;
The toner of coloured particle and different colours is delivered in multiple agitators respectively in the ratio of setting and stirred;
By the powder after being stirred in each agitator respectively through each feeding belt according to default material loading procedure blanking to vertical material-distributing In device, natural packing formation flower pattern;
By the flower pattern powder of formation deliver to press it is framed in and it is compressing.
According to above-mentioned preparation method, simple vertical material-distributing device is seemed by one, is controlled according to default material loading procedure Blanking, using the distributing method of natural principle, but form is changeable for the effect that cloth comes out, and contrasts the stiff and single of traditional cloths It is constant, not discoordination and it is unified while, can subregion it is obvious, well arranged, can also get along swimmingly with each other, one integrated mass, through process Writing for sequence, more masterly in the processing of variations in detail, the textural characteristics distinctness of flower pattern, conversion are various, natural, rich It is rich, full, it can effectively prepare the porcelain unglazed tile of such as such effect of the ecological stone in Rome.Contrast is now relatively stiff general Logical micro mist cloth and multitube cloth polished bricks, can be realized on same tablecloth truck need to only be made not by converting various programs Same flower pattern, the effect of the space of a whole page.Such product is not restricted to one pattern, flexible and changeable, stereovision is strong.In process of production because each material exists Only pass through agitator blanking on charge car, and enter vertical material-distributing device, relative dust is small, turn to clear up charge car during numbering also more Plus conveniently, write computer automation operation after program relatively easy.Also, dry method colour mixture contrasts conventional wet to color, cuts Colorant goal, ball milling, blowing, heavy colour slurry, the production link with mill base are taken out, simplify the preparation technology flow of toner.Save A large amount of human and material resources and time, manually-operated error is reduced, improve operating efficiency, save energy consumption.By using dry method colour mixture To color, color matching pattern, thoroughly solve conventional wet it is complicated to color to color pattern, reduce to greatest extent to during color The problem of equipment, energy consumption, personnel, environmental pollution, colorant are lost.
It is preferred that when carrying out dry mixed, to adding spray teflon coatings at the direct contact surface of dry powder conveying equipment, and Increased sieve apparatus.Be conducive to further solving the color clique problem for producing such product using dry method colour mixture mode.
It is preferred that the coloured particle includes bulky grain and little particle, the little particle refers to can be by 4 mesh sub-sieves Particle, bulky grain refers to the particle that particle diameter is 2~4cm.
It is preferred that the bulky grain is made by the following method:After the agitated device stirring of the toner of different colours, fall into Granulate in the hopper on belt, delivering to briquetting roller by the granulation belt is pressed into certain thickness (such as 2.5~3.0mm) and hard The powder block of degree (such as compression ratio is 3.0~3.5%), into particle after material cutting device is cut.
It is preferred that the little particle is made by the following method:After the toner of different colours is crushed through polishing, through roller Feeding is superimposed upon on feeding belt, then the toner after superposition is sent in the hopper on granulation belt by the feeding belt together, Granulation is suppressed on the granulation belt.
Thus, the granulation pattern of the invention by improving the large and small particle of micro mist, is changed to not by traditional monochromatic single roller granulation With being granulated again after the agitated device premix of toner, its granular size, thickness are handled by special equipment, the particle of making is existed Traditional granulation mode is superior in terms of shape, colorfulness, harvest rate.Colourful micro mist bulky grain, little particle are added, Make the third dimension of product stronger, the unordered change of size, the color of particle, particle and micro mist are perfectly combined completely close to natural The floral designs of stone material, its natural-surface, the imitation stone effect of die face have even surmounted the decorative effect of lithotome.
It is preferred that regulating and controlling the collocation colour mixture degree of powder by regulating and controlling the stirring frequency of the agitator.So can be with Form the decorative pattern and tone of more horn of plenty.
It is preferred that when being delivered to the blanking of agitator by the toner of default programme-control coloured particle and different colours Between and discharge quantity.The color and pattern that so can be more enriched.
It is preferred that the default material loading procedure control the lower discharge position of each feeding belt, each feeding belt from certain once Translational speed, each feeding belt when discharge position is moved to next lower discharge position when a certain lower discharge position is stopped blanking it is total when Between and powder at least one of from each feeding belt blanking to the speed of vertical material-distributing device.Thus, it is possible to which cloth goes out texture change Change abundant precoat.
It is preferred that by the powder after the stirring in each agitator, communicated band delivers to vertical material-distributing according to material loading procedure respectively , can be using mobile or positioned ways blanking during device;Also optional subregion blanking pattern, optional while blanking, fixed point blanking, movement Blanking or movement and fixed point both of which collocation blanking.So the whole structure of cloth can make curved line, two kinds of twill greatly The flower pattern of body effect, curved area's degree and inclined degree can also be adjusted by the lower discharge position of speed, fixed point and time of mobile blanking It is whole, the change in details can be also made while making different-style by these.
It is preferred that the accumulating amount for changing blank by regulating and controlling the feeding speed of the feeding belt is (i.e. foregoing " from respectively sending Expect belt blanking to the speed of vertical material-distributing device ").The size in each cloth area can be so controlled, and then forms more horn of plenty Level.
It is preferred that the vertical material-distributing device wide 20~35mm more framed than the press.So, when using flat throwing mode by heap Long-pending flower pattern from truck transfer belt be sent into press it is framed when, flat throw into the framed shaping powder of press can be caused to fill up enough Press is framed, it is to avoid easily occur after press is compressing it is more while layering and while it is show-through the problem of.
The invention provides the Ceramic Tiles of the dry method illusion-colour particle prepared by above-mentioned preparation method, micro mist composite decoration.Should Ceramic Tiles not discoordination and it is unified while, can subregion it is obvious, well arranged, can also get along swimmingly with each other, one integrated mass, in details More masterly in the processing of change, the textural characteristics distinctness of flower pattern, conversion are various, natural, abundant, full.
Brief description of the drawings
Fig. 1 shows breakage rate of the powder under different chemical industry material;
Fig. 2 shows influence of the chemical industry material addition to flow velocity;
Fig. 3 shows influence of the dry-mixed time to percentage of damage under same rotational speed;
Fig. 4 shows influence of the dry-mixed rotating speed to percentage of damage under same time;
Fig. 5 shows influence of the granulation compression ratio to Particle attrition rate;
Fig. 6 is the process chart of an example of the present invention;
Fig. 7 is the structural representation of the basic colorant bucket of the dry method additive colo(u)r system of an example of the present invention;
Fig. 8 is the electronic proportioning structural representation of the dry method additive colo(u)r system of an example of the present invention;
Fig. 9 is the structural representation of the colour mixture tank of the dry method additive colo(u)r system of an example of the present invention;
Figure 10 is the toner discharging schematic diagram of the dry method additive colo(u)r system of an example of the present invention;
Figure 11 is the structural representation of the powder feeding equipment of the bulky grain comminutor of an example of the present invention;
Figure 12 is the structural representation of the bulky grain comminutor of an example of the present invention;
Figure 13 shows the dry method colour mixture technological process of an example of the present invention;
Figure 14 is the structural representation of the distribution device of an example of the present invention;
Figure 15 shows the distributing technique flow of an example of the present invention;
Figure 16 shows the cloth design sketch of an example of the present invention;
Figure 17 shows the cloth design sketch of another example of the invention
Figure 18 shows the sintering curve figure of an example of the present invention;
Symbol description:
1st, basic colorant bucket;
2nd, color matching colorant cylinder;
3rd, electronic batching scale;
4th, spiral propeller;
5th, base-material storehouse;
6th, base-material electronic scale;
7th, feeding belt;
8th, colo(u)r mixer;
9th, transfer powder cabin;
10th, discharge guide groove;
11st, vibration screen;
12nd, feeding belt;
13rd, toner hopper;
14th, discharge bucket;
15th, powder feeding belt;
16th, hopper;
17th, agitator;
18th, briquetting roller;
19th, material cutting device;
20th, belt is granulated;
21st, agitator;
22nd, feeding belt lace;
23rd, vertical material-distributing device;
24th, the big belt of truck;
25th, truck transfer belt.
Embodiment
The present invention is further illustrated below in conjunction with accompanying drawing and following embodiments, it should be appreciated that accompanying drawing and following embodiments The present invention is merely to illustrate, is not intended to limit the present invention.
The technical process of existing Ceramic Tiles, such as polished bricks includes:Raw material-ball milling-mistake screens out iron-right Color-spray drying-bin stock-dispensing-granulation-cloth-compacting-drying-glazing-burn till-polish-is classified bag Dress-storage etc..And the flower pattern caused by the present invention is directed to roller grid distributing technique used in the prior art is simply given birth to Firmly, the defect such as decorative effect is poor, to the preparation method of Ceramic Tiles, especially to being related to the colour mixture of pattern forming, granulation, cloth Link is improved.Therefore, the invention provides a kind of dry method illusion-colour particle, the preparation side of the Ceramic Tiles of micro mist composite decoration Method, including:Basic powder and colorant are subjected to dry mixed, toner is fabricated to;Toner is granulated and different shape is formed Coloured particle;The toner of coloured particle and different colours is delivered in multiple agitators respectively in the ratio of setting and stirred; By the powder after being stirred in each agitator respectively through each feeding belt according in default material loading procedure blanking to vertical material-distributing device, Natural packing formation flower pattern;By the flower pattern powder of formation deliver to press it is framed in and it is compressing.
Specifically, the present invention is from the angles of the floral designs of the traditional polished bricks of lifting, with reference in the market most The gorgeous colourful floral designs effect of glazed tile, Polished crystal tile made a pet of by people, changes polished bricks traditional cloths pattern, and Its single dull floral designs, reaches the purpose of the various color of surface change and pattern, finally not only retains and lift throwing The various physicochemical properties of light brick, and its surface decoration effect is closer to lithotome, better than glazed tile, the effect of Polished crystal tile.
An embodiment of the invention provides a kind of preparation method of Ceramic Tiles, and the preparation method can be found in Fig. 6, its Technological process is roughly the same with the common micro powder product technological process of production, and its main points is micro- in colour mixture, granulation, cloth flow and tradition Powder cloth is different.In one example, the preparation method of Ceramic Tiles mainly includes:Base substrate is to color, granulation, cloth etc..
In the present invention, toner is formed by basic base substrate powder and colorant dry mixed.Required raw material is carried out first below Describe in detail.
It is preferred that the basic components of the base substrate powder are:Ball clay:10~15%, raw ore mud:3~6%, talcum:1.5 ~4.0%, soil is strengthened:2~4%, smart sodium sand:10~37%, albarium:35~41%.According to the formula, ideal can be obtained Sintering degree, whiteness, unit weight, and powder breakage rate can be reduced.
It is preferred that the base substrate powder also containing relative to 0.1~0.3wt% of basic components reinforcing agent (i.e. relative to The mass percent being entirely formulated, additional 0.1~0.3wt% reinforcing agent).Thus, it is possible to increase the intensity of powder, powder is reduced Expect breakage rate, and be that powder has good mobility.
Preferably, the reinforcing agent is selected from sodium carboxymethylcellulose, special efficacy reinforcing agent (inorganic, such as ultra-fine selected swelling Soil etc.), at least one of macromolecule reinforcing agent (organic, such as modified starch), preferably macromolecule reinforcing agent.
It is preferred that the unit weight of the toner is 92~95g/100mL, the grain composition of toner is:On 30 mesh:≤ 15%, 30~60 mesh:70~80%, 60~80 mesh:5~8%.Thus, it is possible to make toner that there is good mobility.
< base substrates are to color >
(base substrate powder formulation)
In the present invention, preferably powder has preferable intensity and mobility, to be more suitable for the distributing mode in the present invention.It is stable Powder mobility directly affect the load of toner and the mixability of different toners, and directly contribute the change of decorative pattern, pattern Change.
1. powder strength study
Powder intensity is influenceed by mud kind, sand material, chemical industry material.Hereinafter, mud kind, sand material, the selection of chemical industry material are described in detail.
The selection of 1.1 mud kinds
Table 1 is influence of the different mud kinds to powder intensity under identical sand material proportioning, as can be seen from the table, uses raw ore mud Powder can be made to have more preferable intensity, breakage rate of the powder in transportation is smaller.Therefore, in powder formulation of the invention, It is used as pug, preferably raw ore mud;
Influence of the different pugs of table 1 to powder intensity
The selection of 1.2 sand materials
Table 2 is influence of the different sandstone class raw material under same pug proportioning to powder intensity, as can be seen from the table, Sand class raw material dosage is bigger in formula, and powder intensity is better, and powder breakage rate is smaller, and water mill class raw material dosage is bigger, and powder is strong Degree is poorer, and powder breakage rate is bigger.Therefore, in powder formulation of the invention, sand material, preferably sand class are used as.The sand class Preferably Gao Bai, low iron, raw ore sand class potassium, albite etc., including but not limited to high white sand, albarium, white sand, Fujian sand, heat Water sand, mountain white sand, smart sodium sand;
Influence of the different sand materials of table 2 to powder intensity
The selection of 1.3 chemical industry material
Here, " chemical industry material " refers in addition to base substrate basic ingredient, added in base substrate to improve the raw material of body crack defects.Fig. 1 Show damaged to powder using sodium carboxymethylcellulose (abbreviation methyl), base substrate reinforcing agent, macromolecule reinforcing agent in same formula The influence of rate.As seen from the figure, powder breakage rate is with reinforcing agent after methyl, base substrate reinforcing agent, the addition of macromolecule reinforcing agent are formulated Content increases and reduced.Fig. 2 shows influence of the chemical industry material addition to flow velocity.As can be seen that the best macromolecule of enhancing effect Use ratio of the reinforcing agent in formula, when addition reaches more than 0.3%, it starts to become big on flow rate of slurry influence.Knot Close Fig. 1 and Fig. 2 to understand, in the present invention, therefore, in powder formulation of the invention, preferably it is possible to additionally incorporate sodium carboxymethylcellulose, base At least one of body reinforcing agent, macromolecule reinforcing agent, preferably it is possible to additionally incorporate macromolecule reinforcing agent.The base substrate reinforcing agent is Refer to inorganic raw material, such as ultra-fine selected bentonite.The macromolecule reinforcing agent for example may be selected from methyl, special efficacy reinforcing agent (nothing Machine class raw material, such as ultra-fine selected bentonite), at least one in macromolecule reinforcing agent (organic raw material, such as modified starch) Kind.The addition of the base substrate reinforcing agent can be 0.1~0.5wt%.The addition of the macromolecule reinforcing agent can for 0.1~ 0.3wt%.If its addition is very few, the improvement to powder breakage rate is not enough;If its addition is excessive, cause slurry Flow velocity is excessively slow.
2. powder Study of Liquidity
Table 3 is that each ultrawhite formula is contrasted in different powder particle-levels with lower mobility.Wherein, the assay method of flow velocity is using appearance Measure as 65ml, the flow velocity cup that discharging opening is 15.5mm, during detecting that brimmer powder has flowed used completely in flow velocity cup Between.As can be seen from the table, under identical powder particle-level is matched somebody with somebody, the unit weight of powder is bigger, and powder mobility is better;Same recipe It is more than powder, the mesh of powder particle 30 and 60 mesh below it is fewer, powder mobility is better.In the present invention, the unit weight of powder is preferably 91~95g/100mL.The grain composition of powder is preferably:On 30 mesh:≤ 15%, 30~60 mesh:70~80%, 60~80 mesh:5 ~8%;
Mobility result statistics of the powder of table 3 in different particle-levels with
3. formula system is designed
In the present invention, base substrate powder formulation is preferably the maximum under stable whiteness (preferably more than 60 degree of basic components whiteness) Limit increases powder intensity, so as to ensure that the mobility of powder is stable.For example, the breakage rate of powder is preferably less than 2.2%.Separately Outside, the flow velocity of powder is preferably 1.35~1.46 seconds.
Table 4 shows the raw material chemical composition of more than 60 degree of optional whiteness in the present invention;
The formula of table 4 chooses raw material chemical composition (wt%)
In one embodiment, in powder basic components of the invention, ball clay (clay), talcum, raw ore mud, increasing can be contained Strong soil and sand class.In one preferred example, powder basic components are:By weight, ball clay:10~15%, raw ore mud:3 ~6%, talcum:1.5~2.5%, soil is strengthened:2~4%, smart sodium sand:18~37%, albarium:35~41%.In addition, may be used also Add the macromolecule reinforcing agent relative to 0.1~0.3wt% of basic components (such as 0.3wt%).Table 5 shows multiple exemplary Formula.Table 6 shows the performance of each formula.Wherein, synthesis is examined in terms of the sintering degree of product, whiteness, unit weight, powder breakage rate Consider, preferably 5# formulas;
Table 5 is respectively formulated example
Each performance formula result of table 6
Formula number Whiteness (dry) Water absorption rate (%) Unit weight (g/100ml) Powder breakage rate (%)
0# 61.8/62.0 0.057/0.041 93.8 2.2
1# 60.8/60.8 0.039/0.042 93.5 2.5
2# 63.6/63.9 0.261/0.193 94.2 1.9
3# 64.9/64.9 0.309/0.117 95 1.3
4# 56.7/56.8 0.074/0.041 93.8 2.4
5# 59.6/59.8 0.024/0.016 92.0 2.0
6# 57.0/57.1 0.013/0.018 91.8 4.2
7# 58.2/58.6 0.036/0.040 94.2 2.0
(note:Whiteness and water absorption rate have two values in table 6, and its implication is while two coupon results done).
By the coloring material for mixing after base substrate slurry and ball milling, toner is prepared by spray drying.
In the present invention, basic components slurry fineness can be 0.5~0.8% (250 mesh screen residue).Flow rate of slurry can for 40~ 70S.Slurry proportion can be 1.68~1.71g/cm3.Grain composition can be:On 30 mesh:≤ 15%;30~60 mesh:70~80%; 60~80 mesh:5~8%.Powder moisture can be 5.0~5.5%.
< dry method colour mixtures >
Then, the dry method colour mixture mode that the present invention is used is described in detail, shown in its technological process Figure 13, and Fig. 7 to Figure 10 is shown The structural representation of the dry method additive colo(u)r system of an example of the present invention.Specifically, Fig. 7 be an example of the present invention dry method mix The structural representation of the basic colorant bucket of colour system system;Fig. 8 is the electronic proportioning knot of the dry method additive colo(u)r system of an example of the present invention Structure schematic diagram;Fig. 9 is the structural representation of the colour mixture tank of the dry method additive colo(u)r system of an example of the present invention;Figure 10 is the present invention one The toner discharging schematic diagram of the dry method additive colo(u)r system of individual example.
Referring to Fig. 7 to Figure 10, Figure 13, dry method colour mixture technique mainly comprises the following steps:
Basic powder is sent to the base-material storehouse of additive colo(u)r system by raw material workshop;
Will dry-mixed colorant pour into multiple basic colorant buckets 1 of additive colo(u)r system, as shown in fig. 7, in one embodiment may be used Using six basic colorant buckets;
Various colorant titles, various toner titles and proportioning data needed for being inputted in the operating computer of additive colo(u)r system;
Control the colorant in basic colorant bucket being drawn into six color matching colorant cylinders 2 of additive colo(u)r system by computer, and adjust, The lustful stream amount of check and correction;
Additive colo(u)r system controls the speed of feeding belt 7 according to the base-material flow of the toner of the setting in computer;
Additive colo(u)r system carries out dispensing according to the proportioning data of the toner of the setting in computer;
In the colour mixture tank 8 that the toner prepared is delivered to additive colo(u)r system, and according to the rotating speed and/or time set in computer (for example Dry-mixed rotating speed:40 revs/min;The dry-mixed time:2.5 minutes) carry out it is dry-mixed, it is mixed after toner by belt is delivered into transfer powder cabin 9.
Fig. 3 shows influence of the dry-mixed time to percentage of damage under same rotational speed;Fig. 4 shows dry-mixed rotating speed under same time Influence to percentage of damage.As shown in Figure 3 and Figure 4, dry method colour mixture is with dry-mixed time, the increase of dry-mixed rotating speed, the breakage of powder Rate is also with rising.
Preferably, the present invention is when carrying out dry mixed, to adding spray Teflon at the direct contact surface of dry powder conveying equipment Coating, and increased sieve apparatus.Be conducive to further solving the color clique problem for producing such product using dry method colour mixture mode.
More specifically, basic powder is sent to the base-material storehouse 5 of dry-mixed system by raw material workshop, can be in each belt in transportation Interface increases Special screen, crosses the fine powder under certain size.
Colorant title is write to control computer to the position of corresponding basic colorant bucket 1 and corresponding color matching colorant cylinder 2, The proportioning for respectively having base-material and colorant in toner material is inputted into computer.
Computer is sent out colorant by spiral propeller 4, the size of spiral propeller 4 is determined by proportioning datamation dispensing Fixative maximum stream flow, the automatic control flow of electronic batching scale 3 by the lower section of color matching colorant cylinder 2, the flow of base-material is under belt The base-material electronic scale 6 of side is controlled.
Colorant is admitted in dry-mixed colour mixture tank 8 by proportioning with base-material and mixed.Furthermore, colour mixture tank 8 can be with shape Motor as its side drives the paddle in colour mixture tank 8, for colour mixture;The motor of opposite side drives whole colour mixture tank 8 to revolve Turn, improve the efficiency of colour mixture, save the time.
The toner respectively mixed is admitted in each transfer powder cabin 9.Toner in transfer powder cabin 9 is delivered to by discharging guide groove 10 Expect to supply production and application on belt 12.Vibration screen 11 can be provided with discharging guide groove 10, the sieve that shakes sifts out color group.
< granulates >
Then, the granulating working procedure that the present invention is used is described in detail.What the coloured particle of the present invention was obtained after foregoing dry method colour mixture Toner is granulated and obtained.
It is preferred that the coloured particle includes little particle and bulky grain, wherein, the little particle passes through following conventional side Method is made:Different colours there is into toner material after polishing and crushing, are superimposed upon through roller feeding on feeding belt, then by after superposition Have toner material together by the belt be sent to granulation belt on big powder bucket in, granulation belt on suppress granulation;
The bulky grain is made by following distinctive method:By the toner of different colours after the stirring of agitated device, fall into and make In hopper on grain belt, briquetting roller is delivered to by granulation belt and is pressed into certain thickness and the powder block of hardness, by blank Into particle after device cutting.
Fig. 5 shows influence of the granulation compression ratio to Particle attrition rate.As shown in figure 5, compression ratio during granulation is bigger, The breakage rate of grain transportation is smaller.
Figure 11 is the structural representation of the powder feeding equipment of the bulky grain comminutor of an example of the present invention;Figure 12 is the present invention The structural representation of the bulky grain comminutor of one example.
The various toners for preparing color turn the corresponding toner hopper 13 of powder cabin feeding from the foregoing, and toner passes through discharge bucket 14, Again by setting the powder feeding belt 15 of speed by the feeding of hopper 16 into agitator 17, then again by the feeding of granulation belt 20 Certain thickness and the powder block of hardness are pressed into briquetting roller 18, into particle after the cutting of material cutting device 19.In the kind of granulation Point little particle, bulky grain in class.Wherein, little particle refers to refer to that particle diameter is about 2 by the particles of 4 mesh sub-sieves, bulky grain ~4cm particle.
More specifically, little particle can adopt traditional granulation pattern:1. there is toner material broken through polishing different colours Afterwards, it is superimposed upon through roller by setting ratio feeding on feeding belt;2. toner material will is sent together by the belt after superposition again In big powder bucket on to granulation belt;3. certain thickness and the powder of hardness are pressed into by granulating ribbon feeding to briquetting roller Expect block, after material cutting device is cut into particle and by 4 mesh sieves be sent into hopper use.
And bulky grain can use new granulation pattern:As shown in FIG. 11 and 12,1. the various toners of color will be prepared (for example 4) by toner hopper 13 and it is sent in same agitator 17 and is stirred according to the powder feeding belt 15 for setting speed, agitator 17 drive constantly circulation transverse shifting batch mixing by motor, are then pressed into again by the feeding of granulation belt 20 to briquetting roller 18 The powder block of certain thickness and hardness, delivers into particle after the cutting of material cutting device 19 and production and application is supplied in the hopper specified.
< clothes >
Traditional cloths car by powder cabin through sander blanking to each hopper, then by roller, leather belt material distributing, finally by belt, lattice Grid send into press, and different flower pattern are formed by simple micro mist cloth and multitube cloth.In an embodiment of the invention, The cloth of fabric is carried out using the pattern different from traditional cloths.
Figure 14 shows the structural representation of the distribution device of an example of the present invention.As shown in figure 14, the distribution device Including:The multiple agitators 21 mixed to the toner of coloured particle and different colours;With the discharging opening of agitator 21 Multiple feeding belts 22 of connection;The vertical material-distributing device 23 being connected positioned at the lower section of feeding belt 22, with one end of feeding belt 22. Powder is delivered in vertical material-distributing device 23 from feeding belt 22, natural packing formation flower pattern.It can be provided with vertical material-distributing device 23 The big belt 24 of truck.The flower pattern powder of formation can be dropped down onto on the big belt 24 of truck by the vibration of distributing device 23.Can be with truck great Pi Band 24 is set up in parallel truck transfer belt 25, and the flat throwing of flower pattern powder on the big belt 24 of truck is framed (not shown) to press In be pressed.
The present invention can realize subregion cloth by multiple agitators 21 and its corresponding feeding belt 22.In an embodiment party In formula, as shown in figure 14, it is for instance possible to use the mode of Fen Liang areas cloth, i.e., including two agitators 21 and feeding belt 22. By setting blanking time in each area, discharge quantity, lower discharge position, abundant decorative pattern and tonal effect can be formed.
Figure 15 shows the distributing technique flow of an example of the present invention.As shown in figure 15, by it is foregoing prepare it is coloured The toner of particle and different colours is delivered to two in the ratio of setting by conveying mechanisms such as flow belts (not shown) and stirred respectively Mix in device 21, and be stirred according to the mixing speed of setting.Default programme-control coloured particle and different face can be passed through Blanking time and discharge quantity of the toner of color on flow belt, that is, realize that the toner of coloured particle and different colours is delivered to and stir Mix blanking time and the control of discharge quantity of device.The mixing speed of agitator is variable, for example, can be 0~60rpm, so each area can To control, adjust the collocation colour mixture degree of powder.
By the powder after being stirred in each agitator 21 respectively through in each blanking of feeding belt 22 to vertical material-distributing device 23.Feeding The fabric in Liang Ge areas is pinpointed under the drive of servomotor (not shown) or movement is sent by belt 22 according to default material loading procedure To vertical material-distributing device 23, using gravity principle by the powder natural packing in distributing device, flower pattern is formed.The present invention can be used Mobile or positioned ways blanking;Also optional subregion blanking pattern, optional while blanking, fixed point blanking, mobile blanking or shifting Dynamic and fixed point both of which collocation blanking.
Hereinafter, describe in detail and control cloth according to default material loading procedure.
The floral designs of the Ceramic Tiles of the present invention can be completely by computer program control, and its program is sent by setting 2 respectively Expect lower discharge position, blanking time, and/or the translational speed of belt 22 (being respectively A areas and B areas) on vertical material-distributing device 23 etc., To control accumulation effect of the micro mist in vertical material-distributing device, so as to control pattern effect.
In programme-control, following parameter can control:
Perform step (n):Refer to the execution step (n) of the program statement in a material loading procedure, when the last item sentence is performed After complete, first statement circulation execution can be returned to.When being combined into one group of composite material-feeding by multiple identical or different material loading procedures During program, next material loading procedure is jumped in the step of the last item sentence of each material loading procedure can be by setting after having performed First statement is performed, and such program statement circulation is performed;
Lower discharge position (mm):It is the stop place in the range of 0~780mm to refer to feeding belt width in vertical material-distributing device;
Translational speed (mm/s):Refer to that feeding belt is moved to the translational speed of step (n+1) position from the position of step (n);
Residence time (0.1s):Refer to the total time of feeding belt blanking when some lower discharge position is stopped;
Cloth speed (rpm):Refer to expect under feeding belt the rotating speed of the feeding belt motor in vertical material-distributing device;
Above step can drive cloth cuticle by the servomotor for controlling to be arranged on cloth belt lace (feeding belt) base Translational speed of the band on vertical material-distributing device, transfer point, residence time are realized.
Table 7 shows the control of each parameter in material loading procedure.According to the control, cloth effect as shown in figure 16 can be obtained Really.
The material loading procedure of table 7
Further, by adjustment lower discharge position, residence time and cloth speed finally determine the best program of effect and Pattern.Table 8 shows the control of each parameter in improved material loading procedure.According to the control, cloth as shown in figure 17 can be obtained Effect.
Program after the improvement of table 8
Then, the natural shaped monoblock flower pattern in vertical material-distributing device, the big ribbon feeding of truck are pulled out with the big belt of truck To truck transfer belt, monoblock flower pattern is sent into press by truck transfer belt by the flat pattern thrown again.Vertical material-distributing device 23 can Wide 20~35mm more framed than press.So, when using flat throwing mode by the flower pattern of accumulation from truck transfer belt be sent into press mould During frame, it can flat to throw that to fill up press enough into the framed shaping powder of press framed, it is to avoid after press is compressing hold Easily occur it is more while layering and while it is show-through the problem of.
The present invention passes through programme-control coloured particle and different face from the angle of the traditional polished bricks floral designs of lifting Blanking time and discharge quantity of the toner micro mist of color on flow belt, after the stirring of agitated device, then stirred by programme-control Device, each particle of feeding belt are with admixed finepowder to vertical framed interior blanking time and discharge quantity, and cloth goes out in distributing belt The abundant micro mist shell fabric of texture variations, the compacting of product is completed by just beating molding mode.By controlling particle and toner extremely Agitator, agitator to vertical framed program parameter are set, and make floral designs change various with this.In whole cloth process In, by traditional monochromatic powder by each roller blanking since initial blanking, become each powder subregion by stirring Discharged after device stirring, wherein agitator can change stirring frequency by computer, and so each area can control, adjust the collocation of powder Colour mixture degree.When by the powder after the stirring in each agitator, communicated band delivers to vertical material-distributing device according to material loading procedure respectively, Can be using mobile or positioned ways blanking;Also optional subregion blanking pattern, it is optional and meanwhile blanking, fixed point blanking, mobile blanking, Or the various patterns collocation blankings such as movement and fixed point.So the whole structure of cloth can make curved line, two kinds of twill substantially The flower pattern of effect, curved area's degree and inclined degree can also be adjusted by the lower discharge position of speed, fixed point and time of mobile blanking, Also the change in details can be made while making different-style by these.The speed of feeding belt lace can also be regulated and controled, Change the accumulating amount of each area's powder, twoth area and size are adjusted.Distinct program is also stackable to be used.
Simple vertical framed cloth so is seemed by one, by mobile and fixed point blanking pattern, nature is utilized The distributing method of principle, but form is changeable for the effect that cloth comes out, and contrasts the stiff and single constant of traditional cloths, is not losing association While reconciling unified, can subregion it is obvious, well arranged, can also get along swimmingly with each other, one integrated mass, by writing for program, thin More masterly in the processing of section change, the textural characteristics distinctness of flower pattern, conversion are various, natural, abundant, full.Contrast is existing In relatively stiff common micro mist cloth and multitube cloth polished bricks, being realized on same tablecloth truck only need to be each by conversion The program of kind makes different flower pattern, the effect of the space of a whole page.Such product is not restricted to one pattern, flexible and changeable, stereovision is strong.In production process In two portable agitato blankings are only passed through on charge car due to each material, and enter vertical framed, relative dust is small, turns numbering Shi Qingli charge cars also more facilitate, and write computer automation operation after program relatively easy.
The present invention also provides a kind of equipment for making Ceramic Tiles, and it may include the above-mentioned dry method additive colo(u)r system being sequentially connected Individual, comminutor, distribution device and by the compressing press of the flower pattern gone out through distribution device cloth.
When compressing in press, shaping frequency can be 6.0~6.5 beats/min.Molding thickness can for 12.2 ± 0.2mm.Briquetting pressure can be 310bar.Die size can be 890 × 890mm.
After shaping, adobe can be dried.For example, the brick bat drying cycle can be about 90min.Dry base moisture content Ke≤ 0.5%.
After being molded or drying, enter kiln and burn till.Calcining system can be according to the blank reasonable selection of selection.For example, burning till temperature Degree can be 1180~1200 DEG C.Firing period can be 60~70min.In one example, sintering curve is as shown in figure 18.
After burning till, then by polishing waxing it can do polishing face brick.Because having the flower pattern feature of uniqueness and relatively naturally flowing Line style, the glaze spraying processing on surface after base substrate goes out dry kiln, can also be carried out on glaze line, then burns out and does natural-surface Brick, it is naturally pure and fresh.
After testing, the product quality meets GB/T4100-2006 standard annex L requirement, and radioactivity check figure index meets A classes ornament materials requirement in GB6566-2001 standards.The property indices of the Ceramic Tiles of the present invention are as shown in table 10:
The Ceramic Tiles property indices of table 10
Enriched using the product of technique its decorative pattern of the present invention, pattern, not only maintain the high-wearing feature of polishing brick product, Also make the product surface of production rich and varied, while the diversity of product surface decoration provides more preferable element for domestic applications Material product, while the technique more greatly simplifies the complicated production distributing mode of traditional micro-powder brick, so as to greatly reduce life Produce cost and save a much progress of the energy, actually ceramic production technology.
The invention has the advantages that:
(1), by optimizing and revising plastic material kind and materials ratio in formula, modified starch series reinforcing agent is chosen, is improved The intensity and mobility of powder.The harvest rate of stability and compacting for cloth is improved and laid a good foundation.
(2), using dry method colour mixture to color, color matching pattern, conventional wet is thoroughly solved to color complexity to color pattern, it is maximum Limit is reduced to the problem of equipment, energy consumption, personnel, environmental pollution, colorant are lost during color.
(3), by adding spray teflon coatings to the contact surface that dry powder conveying equipment is directly located, sieve apparatus was increased, in vertical cloth Propeller discharging before glassware is changed to conveyer belt discharging, solves the color group for producing such product using dry method colour mixture mode and asks Topic.
(4) colourful micro mist bulky grain, little particle, are added in the series of products, makes the third dimension of product stronger, particle The floral designs being perfectly combined completely close to lithotome of the unordered change of size, color, particle and micro mist, its natural-surface, The imitation stone effect of die face has even surmounted the decorative effect of lithotome.
(5), by using by mobile and fixed point blanking pattern, using the distributing method of the natural whereabouts principle of powder gravity, Using vertical framed cloth, material loading procedure is controlled by computer, the product floral designs form that cloth comes out is changeable.
(6), by the experiment and adjustment to material loading procedure, make the different coordinating and unifyings again of pattern of product, completely solve product Color problem, reduces production cost.
(7), simple production process, compared to traditional micro mist class product, its occupancy equipment is few, and site requirements is small, less energy consumption (gas shock number Amount be complicated micro mist 1/20), maintaining is convenient.
(8), technique is simple, and it is difficult that more traditional micro powder product dust generation point is less, centralized collection conveniently, significantly mitigates environment protection treating Degree.

Claims (10)

1. dry method illusion-colour particle, the preparation method of the Ceramic Tiles of micro mist composite decoration, it is characterised in that including:
Basic powder and colorant are subjected to dry mixed, toner is fabricated to;
Toner is granulated and coloured particle of different shapes is formed;
The toner of coloured particle and different colours is delivered in multiple agitators respectively in the ratio of setting and stirred;
By the powder after being stirred in each agitator respectively through each feeding belt according to default material loading procedure blanking to vertical material-distributing In device, natural packing formation flower pattern;
By the flower pattern powder of formation deliver to press it is framed in and it is compressing.
2. preparation method according to claim 1, it is characterised in that characterized in that,
When carrying out dry mixed, set to adding spray teflon coatings at the direct contact surface of dry powder conveying equipment, and increasing sieving It is standby.
3. preparation method according to claim 1, it is characterised in that the coloured particle includes bulky grain and little particle, The little particle refers to can be by the particles of 4 mesh sub-sieves, and bulky grain refers to the particle that particle diameter is 2 ~ 4cm.
4. preparation method according to claim 3, it is characterised in that the bulky grain is made by the following method:Will not After the agitated device stirring of toner of color, fall into the hopper on granulation belt, briquetting roller pressure is delivered to by the granulation belt Powder block is made, into particle after material cutting device is cut.
5. preparation method according to claim 3, it is characterised in that the little particle is made by the following method:Will not Toner with color is superimposed upon on feeding belt after polishing and crushing through roller feeding, then by the toner after superposition together by this Feeding belt is sent in the hopper on granulation belt, and granulation is suppressed on the granulation belt.
6. preparation method according to any one of claim 1 to 5, it is characterised in that pass through default feed program control The toner for being formed with coloured particles and different colours is delivered to blanking time and the discharge quantity of agitator.
7. preparation method according to any one of claim 1 to 6, it is characterised in that the default material loading procedure control Make the lower discharge position of each feeding belt, each feeding belt from a certain lower discharge position be moved to next lower discharge position when mobile speed Degree, each feeding belt when a certain lower discharge position is stopped the total time of blanking and powder from each feeding belt blanking to vertical At least one of speed of distributing device.
8. preparation method according to any one of claim 1 to 7, it is characterised in that
By the powder after the stirring in each agitator respectively through each feeding belt according to default material loading procedure blanking to vertical cloth During glassware, using subregion blanking, while under blanking and fixed point blanking, mobile blanking or movement and fixed point both of which collocation Material.
9. preparation method according to any one of claim 1 to 8, it is characterised in that the vertical material-distributing device is than described The framed wide 20~35mm of press.
10. the compound dress of dry method illusion-colour particle prepared by a kind of preparation method as any one of claim 1 to 9, micro mist The Ceramic Tiles of decorations.
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CN113664998A (en) * 2021-07-30 2021-11-19 安徽三朋建材集团有限公司 Mortar preparation system capable of simultaneously producing masonry mortar and surface mortar
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CN114474343A (en) * 2022-01-10 2022-05-13 蒙娜丽莎集团股份有限公司 Multicolor cloth equipment, multicolor whole-body ceramic plate obtained by using same and preparation method thereof
CN114474343B (en) * 2022-01-10 2024-01-09 蒙娜丽莎集团股份有限公司 Multicolor material distribution equipment, multicolor whole ceramic plate obtained by using same and preparation method thereof

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