CN107116084A - A kind of steroidal compounds fermentation bacteria residue solidification and the method for dewater treatment - Google Patents
A kind of steroidal compounds fermentation bacteria residue solidification and the method for dewater treatment Download PDFInfo
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- CN107116084A CN107116084A CN201610101238.2A CN201610101238A CN107116084A CN 107116084 A CN107116084 A CN 107116084A CN 201610101238 A CN201610101238 A CN 201610101238A CN 107116084 A CN107116084 A CN 107116084A
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- Prior art keywords
- bacteria residue
- steroidal compounds
- curing agent
- fermentation
- solidfied material
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- 241000894006 Bacteria Species 0.000 title claims abstract description 117
- 238000000855 fermentation Methods 0.000 title claims abstract description 75
- 230000004151 fermentation Effects 0.000 title claims abstract description 75
- 150000001875 compounds Chemical class 0.000 title claims abstract description 73
- 230000003637 steroidlike Effects 0.000 title claims abstract description 67
- 238000000034 method Methods 0.000 title claims abstract description 38
- 238000007711 solidification Methods 0.000 title claims abstract description 25
- 230000008023 solidification Effects 0.000 title claims abstract description 25
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 57
- 239000000463 material Substances 0.000 claims abstract description 39
- 239000002893 slag Substances 0.000 claims abstract description 26
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 25
- 238000006243 chemical reaction Methods 0.000 claims abstract description 13
- 239000005416 organic matter Substances 0.000 claims abstract description 13
- 238000004064 recycling Methods 0.000 claims abstract description 12
- 239000003814 drug Substances 0.000 claims description 42
- 150000003839 salts Chemical class 0.000 claims description 24
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 claims description 16
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 claims description 14
- 206010002091 Anaesthesia Diseases 0.000 claims description 12
- 241000218631 Coniferophyta Species 0.000 claims description 12
- 230000037005 anaesthesia Effects 0.000 claims description 12
- 239000003163 gonadal steroid hormone Substances 0.000 claims description 11
- TWRXJAOTZQYOKJ-UHFFFAOYSA-L Magnesium chloride Chemical compound [Mg+2].[Cl-].[Cl-] TWRXJAOTZQYOKJ-UHFFFAOYSA-L 0.000 claims description 10
- CSNNHWWHGAXBCP-UHFFFAOYSA-L Magnesium sulfate Chemical compound [Mg+2].[O-][S+2]([O-])([O-])[O-] CSNNHWWHGAXBCP-UHFFFAOYSA-L 0.000 claims description 10
- 238000002156 mixing Methods 0.000 claims description 10
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 claims description 9
- 239000003470 adrenal cortex hormone Substances 0.000 claims description 8
- OSGAYBCDTDRGGQ-UHFFFAOYSA-L calcium sulfate Chemical compound [Ca+2].[O-]S([O-])(=O)=O OSGAYBCDTDRGGQ-UHFFFAOYSA-L 0.000 claims description 8
- RKHQGWMMUURILY-UHRZLXHJSA-N cortivazol Chemical compound C([C@H]1[C@@H]2C[C@H]([C@]([C@@]2(C)C[C@H](O)[C@@H]1[C@@]1(C)C2)(O)C(=O)COC(C)=O)C)=C(C)C1=CC1=C2C=NN1C1=CC=CC=C1 RKHQGWMMUURILY-UHRZLXHJSA-N 0.000 claims description 8
- 229910052938 sodium sulfate Inorganic materials 0.000 claims description 8
- 235000011152 sodium sulphate Nutrition 0.000 claims description 8
- 229910000029 sodium carbonate Inorganic materials 0.000 claims description 7
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 claims description 6
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 claims description 6
- 229910019142 PO4 Inorganic materials 0.000 claims description 6
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 claims description 6
- 239000010452 phosphate Substances 0.000 claims description 6
- BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 claims description 5
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 5
- 238000013019 agitation Methods 0.000 claims description 5
- 229910000019 calcium carbonate Inorganic materials 0.000 claims description 5
- BRPQOXSCLDDYGP-UHFFFAOYSA-N calcium oxide Chemical compound [O-2].[Ca+2] BRPQOXSCLDDYGP-UHFFFAOYSA-N 0.000 claims description 5
- 239000000292 calcium oxide Substances 0.000 claims description 5
- ODINCKMPIJJUCX-UHFFFAOYSA-N calcium oxide Inorganic materials [Ca]=O ODINCKMPIJJUCX-UHFFFAOYSA-N 0.000 claims description 5
- 238000001704 evaporation Methods 0.000 claims description 5
- 230000008020 evaporation Effects 0.000 claims description 5
- 238000010438 heat treatment Methods 0.000 claims description 5
- 229910001629 magnesium chloride Inorganic materials 0.000 claims description 5
- 229910052943 magnesium sulfate Inorganic materials 0.000 claims description 5
- 235000019341 magnesium sulphate Nutrition 0.000 claims description 5
- 239000000741 silica gel Substances 0.000 claims description 5
- 229910002027 silica gel Inorganic materials 0.000 claims description 5
- QTBSBXVTEAMEQO-UHFFFAOYSA-M Acetate Chemical compound CC([O-])=O QTBSBXVTEAMEQO-UHFFFAOYSA-M 0.000 claims description 4
- UXVMQQNJUSDDNG-UHFFFAOYSA-L Calcium chloride Chemical compound [Cl-].[Cl-].[Ca+2] UXVMQQNJUSDDNG-UHFFFAOYSA-L 0.000 claims description 4
- 229940037003 alum Drugs 0.000 claims description 4
- DIZPMCHEQGEION-UHFFFAOYSA-H aluminium sulfate (anhydrous) Chemical compound [Al+3].[Al+3].[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O DIZPMCHEQGEION-UHFFFAOYSA-H 0.000 claims description 4
- 150000003863 ammonium salts Chemical class 0.000 claims description 4
- 239000001110 calcium chloride Substances 0.000 claims description 4
- 229910001628 calcium chloride Inorganic materials 0.000 claims description 4
- ARUVKPQLZAKDPS-UHFFFAOYSA-L copper(II) sulfate Chemical compound [Cu+2].[O-][S+2]([O-])([O-])[O-] ARUVKPQLZAKDPS-UHFFFAOYSA-L 0.000 claims description 4
- 239000011790 ferrous sulphate Substances 0.000 claims description 4
- 235000003891 ferrous sulphate Nutrition 0.000 claims description 4
- BAUYGSIQEAFULO-UHFFFAOYSA-L iron(2+) sulfate (anhydrous) Chemical compound [Fe+2].[O-]S([O-])(=O)=O BAUYGSIQEAFULO-UHFFFAOYSA-L 0.000 claims description 4
- RUTXIHLAWFEWGM-UHFFFAOYSA-H iron(3+) sulfate Chemical compound [Fe+3].[Fe+3].[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O RUTXIHLAWFEWGM-UHFFFAOYSA-H 0.000 claims description 4
- 229910000359 iron(II) sulfate Inorganic materials 0.000 claims description 4
- 229910000360 iron(III) sulfate Inorganic materials 0.000 claims description 4
- ZLNQQNXFFQJAID-UHFFFAOYSA-L magnesium carbonate Chemical compound [Mg+2].[O-]C([O-])=O ZLNQQNXFFQJAID-UHFFFAOYSA-L 0.000 claims description 4
- 239000001095 magnesium carbonate Substances 0.000 claims description 4
- 229910000021 magnesium carbonate Inorganic materials 0.000 claims description 4
- 238000003756 stirring Methods 0.000 claims description 4
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims description 3
- 239000011734 sodium Substances 0.000 claims description 3
- 229910052708 sodium Inorganic materials 0.000 claims description 3
- QAOWNCQODCNURD-UHFFFAOYSA-L sulfate group Chemical group S(=O)(=O)([O-])[O-] QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 claims description 3
- LSNNMFCWUKXFEE-UHFFFAOYSA-L sulfite Chemical compound [O-]S([O-])=O LSNNMFCWUKXFEE-UHFFFAOYSA-L 0.000 claims description 3
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 claims description 2
- -1 alum Chemical compound 0.000 claims description 2
- 229910052710 silicon Inorganic materials 0.000 claims description 2
- 239000010703 silicon Substances 0.000 claims description 2
- 239000007787 solid Substances 0.000 claims description 2
- 230000018044 dehydration Effects 0.000 abstract description 41
- 238000006297 dehydration reaction Methods 0.000 abstract description 41
- 238000003860 storage Methods 0.000 abstract description 6
- 238000003912 environmental pollution Methods 0.000 abstract description 2
- 229940079593 drug Drugs 0.000 description 11
- 241000220317 Rosa Species 0.000 description 7
- 241000293029 Absidia caerulea Species 0.000 description 6
- 241000122824 Aspergillus ochraceus Species 0.000 description 6
- 229940088597 hormone Drugs 0.000 description 5
- 239000005556 hormone Substances 0.000 description 5
- 241000187747 Streptomyces Species 0.000 description 4
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 4
- JYGXADMDTFJGBT-VWUMJDOOSA-N hydrocortisone Chemical compound O=C1CC[C@]2(C)[C@H]3[C@@H](O)C[C@](C)([C@@](CC4)(O)C(=O)CO)[C@@H]4[C@@H]3CCC2=C1 JYGXADMDTFJGBT-VWUMJDOOSA-N 0.000 description 4
- 238000002360 preparation method Methods 0.000 description 4
- BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 description 3
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 3
- 241001655322 Streptomycetales Species 0.000 description 3
- 238000004519 manufacturing process Methods 0.000 description 3
- 150000003431 steroids Chemical class 0.000 description 3
- 235000008733 Citrus aurantifolia Nutrition 0.000 description 2
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
- 241000235527 Rhizopus Species 0.000 description 2
- VMHLLURERBWHNL-UHFFFAOYSA-M Sodium acetate Chemical compound [Na+].CC([O-])=O VMHLLURERBWHNL-UHFFFAOYSA-M 0.000 description 2
- 235000011941 Tilia x europaea Nutrition 0.000 description 2
- DKFCNIGGENJIJN-UHFFFAOYSA-L aluminum;iron(2+);sulfate Chemical compound [Al+3].[Fe+2].[O-]S([O-])(=O)=O DKFCNIGGENJIJN-UHFFFAOYSA-L 0.000 description 2
- 230000007812 deficiency Effects 0.000 description 2
- 238000010586 diagram Methods 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 229960000890 hydrocortisone Drugs 0.000 description 2
- 239000004571 lime Substances 0.000 description 2
- 238000011112 process operation Methods 0.000 description 2
- 239000001632 sodium acetate Substances 0.000 description 2
- 235000017281 sodium acetate Nutrition 0.000 description 2
- FUFLCEKSBBHCMO-UHFFFAOYSA-N 11-dehydrocorticosterone Natural products O=C1CCC2(C)C3C(=O)CC(C)(C(CC4)C(=O)CO)C4C3CCC2=C1 FUFLCEKSBBHCMO-UHFFFAOYSA-N 0.000 description 1
- HFVMLYAGWXSTQI-QYXZOKGRSA-N 5alpha-androst-16-en-3-one Chemical compound C1C(=O)CC[C@]2(C)[C@H]3CC[C@](C)(C=CC4)[C@@H]4[C@@H]3CC[C@H]21 HFVMLYAGWXSTQI-QYXZOKGRSA-N 0.000 description 1
- PQSUYGKTWSAVDQ-ZVIOFETBSA-N Aldosterone Chemical compound C([C@@]1([C@@H](C(=O)CO)CC[C@H]1[C@@H]1CC2)C=O)[C@H](O)[C@@H]1[C@]1(C)C2=CC(=O)CC1 PQSUYGKTWSAVDQ-ZVIOFETBSA-N 0.000 description 1
- PQSUYGKTWSAVDQ-UHFFFAOYSA-N Aldosterone Natural products C1CC2C3CCC(C(=O)CO)C3(C=O)CC(O)C2C2(C)C1=CC(=O)CC2 PQSUYGKTWSAVDQ-UHFFFAOYSA-N 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical group [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- QCDFBFJGMNKBDO-UHFFFAOYSA-N Clioquinol Chemical compound C1=CN=C2C(O)=C(I)C=C(Cl)C2=C1 QCDFBFJGMNKBDO-UHFFFAOYSA-N 0.000 description 1
- MFYSYFVPBJMHGN-ZPOLXVRWSA-N Cortisone Chemical compound O=C1CC[C@]2(C)[C@H]3C(=O)C[C@](C)([C@@](CC4)(O)C(=O)CO)[C@@H]4[C@@H]3CCC2=C1 MFYSYFVPBJMHGN-ZPOLXVRWSA-N 0.000 description 1
- MFYSYFVPBJMHGN-UHFFFAOYSA-N Cortisone Natural products O=C1CCC2(C)C3C(=O)CC(C)(C(CC4)(O)C(=O)CO)C4C3CCC2=C1 MFYSYFVPBJMHGN-UHFFFAOYSA-N 0.000 description 1
- 239000004593 Epoxy Substances 0.000 description 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
- 238000007605 air drying Methods 0.000 description 1
- 229960002478 aldosterone Drugs 0.000 description 1
- 239000003098 androgen Substances 0.000 description 1
- 229940030486 androgens Drugs 0.000 description 1
- 241001609914 bacterium 150 Species 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000003115 biocidal effect Effects 0.000 description 1
- 235000008429 bread Nutrition 0.000 description 1
- GJYLKIZKRHDRER-UHFFFAOYSA-N calcium;sulfuric acid Chemical compound [Ca].OS(O)(=O)=O GJYLKIZKRHDRER-UHFFFAOYSA-N 0.000 description 1
- 238000005119 centrifugation Methods 0.000 description 1
- 238000002485 combustion reaction Methods 0.000 description 1
- 229960004544 cortisone Drugs 0.000 description 1
- 239000012024 dehydrating agents Substances 0.000 description 1
- 229960003957 dexamethasone Drugs 0.000 description 1
- UREBDLICKHMUKA-CXSFZGCWSA-N dexamethasone Chemical compound C1CC2=CC(=O)C=C[C@]2(C)[C@]2(F)[C@@H]1[C@@H]1C[C@@H](C)[C@@](C(=O)CO)(O)[C@@]1(C)C[C@@H]2O UREBDLICKHMUKA-CXSFZGCWSA-N 0.000 description 1
- 239000000262 estrogen Substances 0.000 description 1
- 229940011871 estrogen Drugs 0.000 description 1
- DNJIEGIFACGWOD-UHFFFAOYSA-N ethanethiol Chemical compound CCS DNJIEGIFACGWOD-UHFFFAOYSA-N 0.000 description 1
- 238000001914 filtration Methods 0.000 description 1
- 239000003205 fragrance Substances 0.000 description 1
- 239000003862 glucocorticoid Substances 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 239000003158 myorelaxant agent Substances 0.000 description 1
- RGSFGYAAUTVSQA-UHFFFAOYSA-N pentamethylene Natural products C1CCCC1 RGSFGYAAUTVSQA-UHFFFAOYSA-N 0.000 description 1
- 125000004817 pentamethylene group Chemical group [H]C([H])([*:2])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[*:1] 0.000 description 1
- 238000003672 processing method Methods 0.000 description 1
- 239000000583 progesterone congener Substances 0.000 description 1
- 229940095055 progestogen systemic hormonal contraceptives Drugs 0.000 description 1
- 102000004169 proteins and genes Human genes 0.000 description 1
- 108090000623 proteins and genes Proteins 0.000 description 1
- 239000004449 solid propellant Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 239000013589 supplement Substances 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B09—DISPOSAL OF SOLID WASTE; RECLAMATION OF CONTAMINATED SOIL
- B09B—DISPOSAL OF SOLID WASTE NOT OTHERWISE PROVIDED FOR
- B09B3/00—Destroying solid waste or transforming solid waste into something useful or harmless
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B09—DISPOSAL OF SOLID WASTE; RECLAMATION OF CONTAMINATED SOIL
- B09B—DISPOSAL OF SOLID WASTE NOT OTHERWISE PROVIDED FOR
- B09B5/00—Operations not covered by a single other subclass or by a single other group in this subclass
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B09—DISPOSAL OF SOLID WASTE; RECLAMATION OF CONTAMINATED SOIL
- B09B—DISPOSAL OF SOLID WASTE NOT OTHERWISE PROVIDED FOR
- B09B2101/00—Type of solid waste
- B09B2101/02—Gases or liquids enclosed in discarded articles, e.g. aerosol cans or cooling systems of refrigerators
Landscapes
- Engineering & Computer Science (AREA)
- Environmental & Geological Engineering (AREA)
- Medicines Containing Material From Animals Or Micro-Organisms (AREA)
Abstract
The invention provides a kind of fermentation bacteria residue solidification of steroidal compounds and the method for dewater treatment, this method is：Steroidal compounds fermentation bacteria residue and curing agent are subjected to curing reaction, dry and comfortable solidfied material is obtained；The curing agent is：Can be formed in hydrate, absorbable moisture or the inorganic matter and/or organic matter that can be reacted with water any one or at least two combination；Further dehydration obtains dried object to solidfied material.Solidfied material and/or dried object carry out recycling or burning disposal.The present invention can realize the dry and comfortable solidification of wet bacteria slag at normal temperatures, reduce the dehydration cost of wet bacteria slag, avoid the environmental pollution of wet bacteria slag secondary fermentation generation, it is easy to the storage and transport of fermentation bacteria residue, the problem of solving steroidal compounds fermentation bacteria residue recycling and high harmless treatment cost, cost-effectively solidifies dehydration for steroidal compounds fermentation bacteria residue and provides a kind of new method with further recycling.
Description
Technical field
The invention belongs to steroidal compounds zymophyte Slag treatment and its application technology as the second resource field, it is related to one kind
Steroidal compounds fermentation bacteria residue solidification and the method for dewater treatment.
Background technology
Steroid drugs is the second major class medicine that yield is only second to antibiotic, and China's steroid drugs annual production accounts for generation
1/3 or so of boundary's total output, cortin production of raw medicine ability and actual production rank first in the world.
A large amount of bacteria residues are produced in steroidal compounds fermentation process, bacteria residue moisture content height (70~93%), and it is rich
Containing organic matter.Undressed steroidal compounds fermentation bacteria residue places a period of time meeting secondary fermentation, causes bacterium
Slag become it is glutinous, thinning, distribute stench, to surrounding environment cause seriously endanger, while also make bacteria residue storage and
Transport turns into problem.The moisture overwhelming majority in steroidal compounds fermentation bacteria residue is present in inside mycelium or inhaled
Mycelium surface is attached to, substantial amounts of moisture exists in colloidal state water form, and free water content is seldom, therefore with often
The press filtration and centrifugation of rule can not effectively remove the moisture in bacteria residue.Although can be made using the method for thermal dehydration
Bacteria residue is thoroughly dried, but processing procedure power consumption is big, and processing cost is very high.Fermentation bacteria residue is directly burned
It is a kind of method for handling steroidal compounds fermentation bacteria residue, but because the bacteria residue moisture content is high, it is necessary to additional combustion
The deficiency of material supplement calorific value, therefore directly burning disposal cost is too high (about 2000 yuan/ton of wet bacteria slags), it is difficult to
Extensive industrialization.
The method for studying steroidal compounds fermentation bacteria residue low-cost solidification and dewater treatment, for solving steroidal
Compound fermentation bacteria residue secondary fermentation, storage transport difficult, high dehydration cost, recycling and innoxious place
Manage the problem of cost is high significant.
The content of the invention
In view of the deficienciess of the prior art, it is an object of the invention to provide a kind of steroidal compounds zymophyte
Steroidal compounds fermentation can be achieved in the method for slag low-cost solidification and dewater treatment, methods described at normal temperatures
The dry and comfortable solidification of bacteria residue, reduces the cost of wet bacteria slag dehydration, it is to avoid the environment that bacteria residue secondary fermentation is produced
Pollution, be easy to ferment bacteria residue storage and transport, solve steroidal compounds fermentation bacteria residue recycling and
The problem of harmless treatment cost is high, is steroidal compounds fermentation bacteria residue solidification dehydration and further recycling profit
With there is provided a kind of new method.
For up to this purpose, the present invention uses following technical scheme：
A kind of fermentation bacteria residue solidification of steroidal compounds and the method for dewater treatment, methods described is：By steroidal
Compound fermentation bacteria residue is mixed with curing agent, carries out the water in curing reaction, removing steroidal compounds fermentation bacteria residue
Point, obtain dry and comfortable solidfied material；Wherein, the curing agent is：Can be formed hydrate, absorbable moisture or
Can be with any one in the inorganic matter and/or organic matter of water reaction or at least two combination.
The curing agent can be：Organic matter that hydrate can be formed, the inorganic matter that hydrate can be formed, it can inhale
Receive the organic matter of moisture, the inorganic matter of absorbable moisture, the inorganic matter that can be reacted with water or can be reacted with water
In organic matter any one or at least two combination.Typical but non-limiting solidification dehydrating agent combination
For：The inorganic matter of hydrate and the inorganic matter that can be reacted with water can be formed, can be formed the organic matter of hydrate with
The inorganic matter of absorbable moisture, the organic matter that can be reacted with water, the organic matter of absorbable moisture are with that can form water
The organic matter of compound, can be formed hydrate organic matter, can with water react inorganic matter, hydrate can be formed
Inorganic matter and the organic matter etc. that can be reacted with water.
The processing method for the steroidal compounds fermentation bacteria residue that the present invention is provided, utilizes curing agent to absorb sterides compound
Moisture in thing fermentation bacteria residue, it is to avoid the dirt that the secondary fermentation of steroidal compounds fermentation bacteria residues is caused to environment
Dye, solves storage and transport difficult, dehydration cost height, recycling under steroidal compounds fermentation bacteria residue normal temperature
The problem of using cost height and high harmless treatment cost.
The steroidal compounds fermentation bacteria residue is to prepare the fermentation bacteria residue produced during steroidal compounds.
The steroidal compounds are to have steroidal parent nucleus, i.e. its basic carbon skeleton with one in chemical constitution
The parent nucleus of " pentamethylene and many hydrogen are luxuriant and rich with fragrance " and the compound of three side chains.Preferably, the steroidal compounds are skin
Matter hormone medicine and its prepare intermediate, sex hormone drug and its prepare intermediate or anesthesia and flesh conifer
Medicine and its prepare in intermediate any one or at least two combination.
The corticoid medicine is artificial synthesized cortex hormone of aadrenaline extremely derivative, including salted hide
Matter hormone medicine and glucocorticoid medicine, such as aldosterone, cortisone and dexamethasone；The property
Hormone medicine includes estrogen drugs, progestogens medicine, androgens medicine, protein and assimilates sharp
Plain class medicine and gonadotrophins medicine etc.；The anesthesia is arcotic and muscle relaxant with flesh conifer medicine.
The steroidal compounds can be corticoid medicine, the intermediate for preparing corticoid, sex hormone
Class medicine, the intermediate for preparing sex hormone drug, anesthesia and flesh conifer medicine prepare anesthesia and flesh conifer
In the intermediate of medicine any one or at least two combination.It is typical but non-limiting to be combined as：Skin
Matter hormone medicine and sex hormone drug, prepare the intermediate of sex hormone drug and prepare corticoid
Intermediate, corticoid medicine, sex hormone drug and anesthesia and flesh conifer medicine prepare sex hormone
The intermediate of class medicine, the intermediate for preparing corticoid are with preparing anesthesia and the centre of flesh conifer medicine
Body, intermediate and the anesthesia and flesh conifer medicine, sex hormone of corticoid medicine preparation sex hormone drug
Class medicine, the intermediate for preparing sex hormone drug, anesthesia and flesh conifer medicine prepare anesthesia and flesh conifer
The intermediate of medicine.
The curing agent is that can form hydrate, absorbable moisture or the inorganic salts that can be reacted with water and/or organic
In salt any one or at least two combination.The curing agent can be：The inorganic of hydrate can be formed
Salt, the organic salt that hydrate can be formed, the organic salt of absorbable moisture, the inorganic salts of absorbable moisture, can
With water react organic salt or can with water react inorganic salts in any one or at least two combination.Allusion quotation
Type but nonrestrictive it is combined as：The inorganic salts of hydrate and the inorganic salts of absorbable moisture can be formed, can shape
Into the organic salt of the organic salt and absorbable moisture of hydrate, it can absorb the inorganic salts of moisture, can be reacted with water
Organic salt and the inorganic salts that can be reacted with water, can absorb organic salt, the inorganic salts of absorbable moisture of moisture
With can with water react organic salt, the inorganic salts that hydrate can be formed, the organic salt that hydrate can be formed, can
Absorb the organic salt of moisture and the inorganic salts of absorbable moisture.
Preferably, the curing agent is sulfate, sulphite, carbonate, hydrochloride, phosphate, silicon
In hydrochlorate, ammonium salt or acetate any one or at least two combination.Typical but non-limiting combination
For：Sulfate and carbonate, sulphite and hydrochloride, hydrochloride and phosphate, silicate, acetate
With ammonium salt, carbonate, hydrochloride and phosphate, phosphate, ammonium salt and silicate, carbonate, hydrochloric acid
Salt, phosphate, silicate and acetate.
Preferably, the curing agent be sodium sulphate, magnesium sulfate, aluminum sulfate, alum, ferrous sulfate,
Ferric sulfate, copper sulphate, calcium sulfate, sodium carbonate, magnesium carbonate, calcium carbonate, magnesium chloride, calcium chloride, acetic acid
In sodium, calcium oxide or anhydrous silica gel any one or at least two combination, preferably calcium oxide and/or nothing
Water silica gel.Typical but non-limiting combined optional is certainly：Sodium sulphate and magnesium sulfate, sodium sulphate, ferric sulfate with
Magnesium chloride, aluminum sulfate, aluminium iron sulfate, copper sulphate and calcium sulfate, magnesium chloride, ferrous sulfate, calcium chloride with
Sodium acetate, magnesium carbonate, aluminium iron sulfate, calcium carbonate and magnesium chloride, sodium acetate, ferric sulfate, calcium oxide and nothing
Water silica gel, calcium sulfate, sodium carbonate, magnesium carbonate and calcium carbonate, magnesium sulfate, aluminum sulfate, copper sulphate and sulfuric acid
Calcium.
The addition of the curing agent is the 5-150% of steroidal compounds zymophyte slag amount, such as 10%,
20%th, 30%, 40%, 60%, 80%, 100%, 110%, 120%, 130% or 140% etc., preferably
For 50-120%.
The hybrid mode of steroidal compounds fermentation bacteria residue and curing agent is：One-component curing agent and steroidal
Mixed after the mixing of compound fermentation bacteria residue one step, the mixing of multicomponent curing agent with steroidal compounds fermentation bacteria residue one step
Close or multicomponent curing agent each component is mixed with steroidal compounds fermentation bacteria residue substep.
The mode that steroidal compounds fermentation bacteria residue is mixed with curing agent is mechanical agitation, stirs or extrudes
Any one or at least two combination.It is typical but non-limiting to be combined as：Mechanical agitation with stirring,
Stir and extrude, mechanical agitation and extruding, are stirred and extruded at mechanical agitation.The purpose of the mixing is will
Steroidal compounds fermentation bacteria residue is well mixed with curing agent.
The temperature of the curing reaction be 0-80 DEG C, such as 2 DEG C, 5 DEG C, 8 DEG C, 10 DEG C, 15 DEG C, 20 DEG C,
30 DEG C, 40 DEG C, 45 DEG C, 50 DEG C, 55 DEG C, 60 DEG C, 65 DEG C, 70 DEG C or 75 DEG C etc., it is preferably
10-60℃。
The different curing agent of selection, the time of curing reaction is different.Preferably, the curing reaction proceeds to
Untill the solidfied material for obtaining dry condition.The solidfied material of dry condition, is readily transported and stores, also prevent
The secondary fermentation of steroidal compounds fermentation bacteria residue.
After the cured reaction of steroidal compounds, the solidfied material of dry condition is obtained.The solidfied material can be with
Further dehydration, obtains dried object.
Preferably, the temperature being further dehydrated be 20-150 DEG C, such as 25 DEG C, 35 DEG C, 40 DEG C,
50 DEG C, 70 DEG C, 80 DEG C, 90 DEG C, 95 DEG C, 110 DEG C, 120 DEG C, 130 DEG C or 140 DEG C etc., it is preferably
30-100℃.After curing reaction, the temperature reduction by more than 10% that solidfied material is further dehydrated, highest
50% is reached, the reduction of bacteria residue dehydration cost is realized.
Preferably, using any one in heating, air-dried or evaporation or at least two combination to solid
Compound is further dehydrated.It is typical but non-limiting to be combined as：Heating is with air-drying, and heating and evaporation are air-dried
With evaporation, heating, air-dried and evaporation.As can be seen here, after cured reaction, steroidal compounds zymophyte
Slag is easier dehydration, and dewatering type is simpler.
The solidfied material and/or dried object carry out recycling or burning disposal.The recycling refers to
Solidfied material and/or dried object are used as solid fuel or utilized in other forms.
As preferred technical scheme, the invention provides a kind of fermentation bacteria residue solidification of steroidal compounds and dehydration
The method of processing, methods described comprises the following steps：
(1) carry out solidifying instead under the conditions of 0-80 DEG C after steroidal compounds fermentation wet bacteria slag is mixed with curing agent
Should, dry and comfortable solidfied material is obtained, wherein, the quality of curing agent is steroidal compounds zymophyte slag amount
5-150%；
(2) solidfied material is further dehydrated under the conditions of 20-150 DEG C, obtains dried object；
(3) solidfied material and/or dried object are subjected to recycling or burning disposal.
Compared with prior art, beneficial effects of the present invention are：
(1) present invention realizes the normal temperature cure of steroidal compounds fermentation bacteria residue by the curing agent of low cost,
The environmental pollution of bacteria residue secondary fermentation generation is avoided, while solving bacteria residue storage hardly possible and transporting difficult ask
Topic.
(2) present invention solidifies steroidal compounds fermentation bacteria residue by curing agent, the steroidal after curing process
Compound fermentation bacteria residue dehydration temperaturre reduction by more than 10%, up to 50%, realizes bacteria residue dehydration cost
Reduction.
Brief description of the drawings
Fig. 1 is the bacteria residue pattern comparison diagram before and after the steroidal compounds zymophyte Slag treatment that embodiment 1 is provided,
Wherein, A figures are bacteria residue before processing shape appearance figure, and B figures are shape appearance figure after bacteria residue processing.
Fig. 2 is the bacteria residue pattern comparison diagram before and after the steroidal compounds fermentation bacteria residue solidification that embodiment 2 is provided,
Wherein, A figures are bacteria residue before processing shape appearance figure, and B figures are shape appearance figure after bacteria residue processing.
Embodiment
Technical scheme is further illustrated below by embodiment, listed embodiment is not right
The present invention constitutes any limitation.
Embodiment 1
Weigh the Aspergillus ochraceus bacterium fermentation bacteria residue 10g of 11 Alpha-hydroxy -18- methyl female steroid -4- alkene -3,17- diketone of preparation (such as
Shown in Figure 1A), add 0.5g curing agent (main component sulfuric acid by the 5% of Aspergillus ochraceus bacterium zymophyte slag amount
Sodium), addition manner is：One step is added, and at 10 DEG C, bacteria residue is well mixed into progress with curing agent anti-
Should, until forming dry and comfortable solidfied material (as shown in Figure 1B).Solidfied material dehydration operating temperature range is
80-150 DEG C, optimal dehydration temperaturre scope is 90-140 DEG C.
Aspergillus ochraceus bacterium prepares other steroidal compounds, such as 11 Alpha-hydroxy -16 α, 17 α-epoxy progesterone, 11 Alpha-hydroxies
The zymophyte produced when-13 β-ethyl-4- alkene-3,17- diketone or 15-13 β of Alpha-hydroxy-ethyl-4- alkene-3,17- diketone
Slag also can carry out solidification dehydration with methods described.
Embodiment 2
16 beta-hydroxy androstane-4-alkene-3s of preparation are weighed, the black-koji mould of 17- diketone ferments bacteria residue 10g (such as Fig. 2A institutes
Show), by 30% addition 3g curing agent (main component sodium sulphate) of black-koji mould zymophyte slag amount, addition
Mode is：One step is added, and at 40 DEG C, bacteria residue is well mixed with curing agent and reacted, until being formed
Dry and comfortable solidfied material (as shown in Figure 2 B).Solidfied material dehydration operating temperature range is 20-150 DEG C, most preferably
Dehydration temperaturre scope is 80-130 DEG C.
Embodiment 3
The Absidia coerulea bacterium fermentation bacteria residue 10g for preparing hydrocortisone is weighed, is fermented by Absidia coerulea bacterium
The addition 4g curing agent of bacteria residue quality 40% (main component ferrous sulfate), addition manner is：One step is added,
In at 25 DEG C, bacteria residue is well mixed with curing agent and reacted, until forming dry and comfortable solidfied material.Solidification
Thing dehydration operating temperature range is 20-150 DEG C, and optimal dehydration temperaturre scope is 50-120 DEG C.
Absidia coerulea bacterium prepares other steroidal compounds, and such as 14 Alpha-hydroxy 4-ADs or 11 β-
Hydroxy-16 alpha, the fermentation bacteria residue produced during 17 α-epoxy progesterone also can carry out solidification dehydration with methods described.
Embodiment 4
The rhizopus niger fermentation bacteria residue 10g for preparing 11 Alpha-hydroxy 4-ADs is weighed, by bread mold
50% addition 5g curing agent (main component magnesium sulfate) of bacterium zymophyte slag amount, addition manner is：One step
Addition, at 25 DEG C, bacteria residue is well mixed with curing agent and reacted, until forming dry and comfortable solidification
Thing.Solidfied material dehydration operating temperature range is 20-150 DEG C, and optimal dehydration temperaturre scope is
50-100℃。
Rhizopus niger prepares other steroidal compounds, the fermentation bacteria residue produced during such as 11 Alpha-hydroxy epoxy progesterone
Also solidification dehydration can be carried out with methods described.
Embodiment 5
Weigh the preparation pregnant Gona-4-ene-3 of 11 beta-hydroxy -16 ɑ, l7 α-epoxy, the small-sized phosphor zymophyte of 20- diketone
Slag 10g, 8g curing agent (main component sulfuric acid is added by the 80% of small-sized phosphor zymophyte slag amount
Iron), addition manner is：One step is added, and at 20 DEG C, bacteria residue is well mixed into progress with curing agent anti-
Should, until forming dry and comfortable solidfied material.Solidfied material dehydration operating temperature range is 20-150 DEG C, most preferably
Dehydration temperaturre scope is 30-110 DEG C.
Small-sized phosphor prepares other steroidal compounds, and such as 7 Alpha-hydroxy -16 α, 17 α-epoxy progesterone or 9 α -
Hydroxy-16 alpha, the fermentation bacteria residue produced during 17 α-epoxy progesterone also can carry out solidification dehydration with methods described.
Embodiment 6
The rose streptomyces chromogenes fermentation bacteria residue 10g for preparing 16 alpha-hydroxy prednisonlones is weighed, it is chromogenic by rose
100% addition 10g curing agent (main component sodium carbonate) of streptomycete fermentation bacteria residue quality, addition manner is：
One step is added, and at 25 DEG C, bacteria residue is reacted with curing agent mixing, until forming dry and comfortable solidification
Thing.Solidfied material dehydration operating temperature range is 20-150 DEG C, and optimal dehydration temperaturre scope is
30-100℃。
Embodiment 7
Weigh and prepare the 11 female Gona-4-ene-3s 3 of Alpha-hydroxy -18- methyl, the Aspergillus ochraceus bacterium fermentation bacteria residue 10g of 17- diketone,
By 120% addition 12g curing agent (main composition-calcium carbonate) of Aspergillus ochraceus bacterium zymophyte slag amount, addition side
Formula is：One step is added, and at 35 DEG C, bacteria residue is reacted with curing agent mixing, until being formed dry and comfortable
Solidfied material.Solidfied material dehydration operating temperature range is 20-150 DEG C, and optimal dehydration temperaturre scope is
40-100℃。
Aspergillus ochraceus bacterium prepares other steroidal compounds, such as 11 Alpha-hydroxy -16 α, 17 α-epoxy progesterone, 11 Alpha-hydroxies
The zymophyte produced when-13 β-ethyl-4- alkene-3,17- diketone or 15-13 β of Alpha-hydroxy-ethyl-4- alkene-3,17- diketone
Slag also can carry out solidification dehydration with methods described.
Embodiment 8
The Absidia coerulea bacterium fermentation bacteria residue 10g for preparing hydrocortisone is weighed, is fermented by Absidia coerulea bacterium
150% addition 15g curing agent (main component calcium chloride) of bacteria residue quality, addition manner is：One step is added,
In at 60 DEG C, bacteria residue is reacted with curing agent mixing, until forming dry and comfortable solidfied material.Solidfied material takes off
Water process operation temperature range is 20-150 DEG C, and optimal dehydration temperaturre scope is 50-110 DEG C.
Absidia coerulea bacterium prepares other steroidal compounds, and such as 14 Alpha-hydroxy 4-ADs, 11 β-
Hydroxy-16 alpha, the fermentation bacteria residue produced during 17 α-epoxy progesterone also can carry out solidification dehydration with methods described.
Embodiment 9
The rose streptomyces chromogenes fermentation bacteria residue 10g for preparing 16 alpha-hydroxy prednisonlones is weighed, it is chromogenic by rose
150% addition 15g curing agent (main component sodium sulphate and sodium carbonate) of streptomycete fermentation bacteria residue quality, adds
Add mode is：First addition sodium sulphate adds sodium carbonate again, and at 0 DEG C, bacteria residue is mixed into progress with curing agent
Reaction, until forming dry and comfortable solidfied material.Solidfied material dehydration operating temperature range is 20-150 DEG C, most
Good dehydration temperaturre scope is 30-100 DEG C.
Embodiment 10
The rose streptomyces chromogenes fermentation bacteria residue 10g for preparing 16 alpha-hydroxy prednisonlones is weighed, it is chromogenic by rose
The 100% addition 10g curing agent (mixing of main component lime and alum of streptomycete fermentation bacteria residue quality
Thing), addition manner is：The mixture of lime and alum is added to rose streptomyces chromogenes zymophyte
In slag, in being reacted bacteria residue with curing agent mixing at 80 DEG C, until forming dry and comfortable solidfied material.Solidification
Thing dehydration operating temperature range is 20-150 DEG C, and optimal dehydration temperaturre scope is 30-100 DEG C.
Embodiment 11
The mycobacteria fermentation bacteria residue 10g for preparing androstenone is weighed, by mycobacteria zymophyte slag amount
100% addition 10g curing agent (main component sodium sulphate and sodium carbonate), addition manner is：One step is added,
In at 20 DEG C, bacteria residue is reacted with curing agent mixing, until forming dry and comfortable solidfied material.Solidfied material takes off
Water process operation temperature range is 20-150 DEG C, and optimal dehydration temperaturre scope is 30-100 DEG C.
The fermentation produced during the intermediate for preparing anesthesia and flesh conifer medicine or anesthesia and flesh conifer medicine
Bacteria residue is similar with the fermentation bacteria residue property in above-described embodiment, it is also possible to which the method described in above-described embodiment is carried out
Solidification dehydration.
Applicant states, the foregoing is only the embodiment of the present invention, but protection scope of the present invention
It is not limited thereto, person of ordinary skill in the field is it will be clearly understood that any skill for belonging to the art
Art personnel the invention discloses technical scope in, the change or replacement that can be readily occurred in all fall within the present invention
Protection domain and it is open within the scope of.
Claims (10)
1. a kind of steroidal compounds fermentation bacteria residue solidification and the method for dewater treatment, it is characterised in that described
Method is：Steroidal compounds fermentation bacteria residue is mixed with curing agent, curing reaction is carried out, obtains dry and comfortable consolidate
Compound；Wherein, the curing agent is：Hydrate, absorbable moisture can be formed or can be reacted with water it is inorganic
In thing and/or organic matter any one or at least two combination.
2. according to the method described in claim 1, it is characterised in that the steroidal compounds fermentation bacteria residue
To prepare the fermentation bacteria residue produced during steroidal compounds；
Preferably, the steroidal compounds are corticoid medicine and its prepare intermediate, sex hormones medicine
Thing and its prepare intermediate or anesthesia and flesh conifer medicine and its prepare any one in intermediate or at least two
The combination planted.
3. method according to claim 1 or 2, it is characterised in that the curing agent is that can form water
Any one in compound, absorbable moisture or the inorganic salts and/or organic salt that can be reacted with water or at least two
The combination planted；
Preferably, the curing agent is sulfate, sulphite, carbonate, hydrochloride, phosphate, silicon
In hydrochlorate, ammonium salt or acetate any one or at least two combination；
Preferably, the curing agent be sodium sulphate, magnesium sulfate, aluminum sulfate, alum, ferrous sulfate,
Ferric sulfate, copper sulphate, calcium sulfate, sodium carbonate, magnesium carbonate, calcium carbonate, magnesium chloride, calcium chloride, acetic acid
In sodium, calcium oxide or anhydrous silica gel any one or at least two combination, preferably calcium oxide and/or
Anhydrous silica gel.
4. the method according to one of claim 1-3, it is characterised in that the addition of the curing agent
For the 5-150% of steroidal compounds zymophyte slag amount, preferably 50-120%.
5. the method according to one of claim 1-4, it is characterised in that the steroidal compounds fermentation
The hybrid mode of bacteria residue and curing agent is：One-component curing agent is mixed with steroidal compounds fermentation bacteria residue one step
Close, multicomponent curing agent is mixed or multicomponent curing agent each group after mixing with the steroidal compounds fermentation step of bacteria residue one
Divide and mixed with steroidal compounds fermentation bacteria residue substep.
6. the method according to one of claim 1-5, it is characterised in that the steroidal compounds fermentation
The mode that bacteria residue is mixed with curing agent is mechanical agitation, stir or extrude in any one or at least two
Combination.
7. the method according to one of claim 1-6, it is characterised in that the temperature of the curing reaction
For 0-80 DEG C, preferably 10-60 DEG C；
Preferably, the solidfied material that the curing reaction is obtained is dry condition.
8. the method according to one of claim 1-7, it is characterised in that methods described also includes：Will
Solidfied material is further dehydrated, and obtains dried object；
Preferably, the temperature being further dehydrated is 20-150 DEG C, preferably 30-100 DEG C；
Preferably, using any one in heating, air-dried or evaporation or at least two combination to solid
Compound is further dehydrated.
9. the method according to one of claim 1-8, it is characterised in that the solidfied material and/or dry
Dry thing carries out recycling or burning disposal.
10. the method according to one of claim 1-9, it is characterised in that methods described includes as follows
Step：
(1) carry out solidifying instead under the conditions of 0-80 DEG C after steroidal compounds fermentation wet bacteria slag is mixed with curing agent
Should, dry and comfortable solidfied material is obtained, wherein, the quality of curing agent is steroidal compounds zymophyte slag amount
5-150%；
(2) solidfied material is further dehydrated under the conditions of 20-150 DEG C, obtains dried object；
(3) solidfied material and/or dried object are subjected to recycling or burning disposal.
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| Application Number | Priority Date | Filing Date | Title |
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| CN201610101238.2A CN107116084A (en) | 2016-02-24 | 2016-02-24 | A kind of steroidal compounds fermentation bacteria residue solidification and the method for dewater treatment |
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| CN201610101238.2A CN107116084A (en) | 2016-02-24 | 2016-02-24 | A kind of steroidal compounds fermentation bacteria residue solidification and the method for dewater treatment |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110813999A (en) * | 2019-11-27 | 2020-02-21 | 湖北共同生物科技有限公司 | Method for curing and dehydrating steroid compound fermentation fungus residues |
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| CN101624256A (en) * | 2008-07-09 | 2010-01-13 | 密西西比国际水务有限公司 | Method and device for processing sludge and/or waste residues |
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