CN107114367A - The preparation method and product of a kind of PET bottle disinfectant - Google Patents
The preparation method and product of a kind of PET bottle disinfectant Download PDFInfo
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- CN107114367A CN107114367A CN201710396383.2A CN201710396383A CN107114367A CN 107114367 A CN107114367 A CN 107114367A CN 201710396383 A CN201710396383 A CN 201710396383A CN 107114367 A CN107114367 A CN 107114367A
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N37/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids
- A01N37/16—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing the group; Thio analogues thereof
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N25/00—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
- A01N25/22—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests containing ingredients stabilising the active ingredients
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N25/00—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
- A01N25/30—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests characterised by the surfactants
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N59/00—Biocides, pest repellants or attractants, or plant growth regulators containing elements or inorganic compounds
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- Life Sciences & Earth Sciences (AREA)
- Health & Medical Sciences (AREA)
- General Health & Medical Sciences (AREA)
- Dentistry (AREA)
- Plant Pathology (AREA)
- Engineering & Computer Science (AREA)
- Pest Control & Pesticides (AREA)
- Agronomy & Crop Science (AREA)
- Wood Science & Technology (AREA)
- Zoology (AREA)
- Environmental Sciences (AREA)
- Toxicology (AREA)
- Chemical & Material Sciences (AREA)
- Inorganic Chemistry (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
The invention discloses a kind of preparation method of PET bottle disinfectant and product.Including step 1, benzenetricarboxylic acid, organic phosphorus compound, tungstates or/and molybdate are mixed, mixture is obtained；A reactor is taken, water and the mixture obtained by step 1 are added into reactor；Surfactant is added into reactor；Hydrogen peroxide is added into reactor；Acetic acid is added into reactor, finished product is obtained.The product, is made up of hydrogen peroxide, acetic acid, tungstates and/or molybdate, organic phosphorus compound, benzenetricarboxylic acid, surfactant and distilled water.The preparation method of the present invention has the advantages that with low cost, technique is simple, production safety, product stability are good.The product of the present invention has that peroxyacetic acid concentration is high, stability is good, the good feature of sterilization effect.
Description
Technical field
The invention belongs to beverage bottle disinfection technology field, the preparation method of more particularly to a kind of PET bottle disinfectant and production
Thing.
Background technology
Although Peracetic acid (C2H4O3) is as beverage bottle disinfectant, possess wide spectrum, efficient, quick-acting, catabolite nontoxic
The advantages of noresidue, but because it is very unstable under normal conditions, the factor such as temperature, illumination, alkali, organic matter, metal ion
Its concentration can be caused to decline rapidly.Peracetic acid is caused to be restricted all the time in the popularization that beverage bottle sterilizes field.
Existing Peracetic acid technique and product have two kinds, and the problem of being respectively present is as follows：
One kind is binary form, and its product is divided into the component of A, B two, usually separately deposited, and is pressed A, B component necessarily using preceding
Ratio is mixed.Mixed peroxyacetic acid concentration declines comparatively fast, and this downward trend is with the raising of peroxyacetic acid concentration
Accelerate.
Another is unary form, and unary form Peracetic acid overcomes some defects of binary form Peracetic acid, but its is steady
Qualitative is still a big technical barrier.
In order to solve the above problems, main former material is used as using hydrogen peroxide, glacial acetic acid more than industrialized production Peracetic acid
Material.But, there is complex manufacturing in these improved technology techniques, manufacturing cost is high, and safety and stablization can not still meet life
Production and use requirement.
The content of the invention
It is an object of the invention to provide a kind of preparation method of PET bottle disinfectant and product, for currently used for beverage
The above mentioned problem that the peroxyacetic acid disinfectant of bottle sterilization is present, the present invention provides the preparation method and product of beverage bottle disinfectant,
With simple production process, safety, the advantages of concentration of product is high, stability is good, sterilization effect is good.
In order to solve the above technical problems, the present invention is achieved by the following technical solutions：
The present invention is a kind of preparation method of PET bottle disinfectant, is carried out as follows；
Step 1. mixes benzenetricarboxylic acid, organic phosphorus compound, tungstates or/and molybdate, obtains mixture；
Step 2. takes a reactor, and water is added into reactor, and the mixture that step 1 is obtained then is poured into the addition
Have in the reactor of water, stirring and dissolving；
Step 3. adds surfactant into reactor, is subsequently agitated for dissolving；
Step 4. adds hydrogen peroxide into reactor, is subsequently agitated for dissolving；
Step 5. adds acetic acid into reactor, is subsequently agitated for 30 to 60 minutes, obtains finished product.
Further, in the step 1, benzenetricarboxylic acid, organic phosphorus compound, the mass ratio of tungstates or/and molybdate are
(2~4)：1：(0.5~2).
Further, the mass ratio of the hydrogen peroxide, acetic acid, mixture, surfactant and water for (27.00~
39.00)：(22.00~36.00)：(0.01~2.00)：(0.01~2.00)：(21.00~50.98).
The product obtained using the preparation method of beverage bottle disinfectant, by hydrogen peroxide, acetic acid, tungstates and/or molybdic acid
Salt, organic phosphorus compound, benzenetricarboxylic acid, surfactant and distilled water composition；Wherein：
Hydrogen peroxide：27-39%；
Acetic acid：22-36%；
Tungstates and/or molybdate：0.01-2%；
Organic phosphorus compound：0.01-2%；
Benzenetricarboxylic acid：0.01-4%；
Surfactant：0.01-2%；
Remaining is water.
Further, the surfactant is nonionic surfactant.
The invention has the advantages that：
The preparation method of the present invention has the advantages that with low cost, technique is simple, production safety, product stability are good.
The product of the present invention has that peroxyacetic acid concentration is high, stability is good, the good feature of sterilization effect.
In addition, tungstates used in the present invention or molybdate, organic phosphorus compound, benzenetricarboxylic acid not only can be played stably
The effect of fluoroacetic acid reaction system, and can also be in complex solution trace metal ion, slow down the decomposition of Peracetic acid.So as to
So that peroxyacetic acid disinfectant more stability and security.
In surfactant used in the present invention, the wetability of peroxyacetic acid disinfectant can be improved, promote disinfectant
Contact with surface, improves Disinfection Effect.It is preferred that scheme be use isomery ether surfactants.
Certainly, any product for implementing the present invention it is not absolutely required to while reaching all the above advantage.
Brief description of the drawings
In order to illustrate the technical solution of the embodiments of the present invention more clearly, used required for being described below to embodiment
Accompanying drawing is briefly described, it should be apparent that, drawings in the following description are only some embodiments of the present invention, for ability
For the those of ordinary skill of domain, on the premise of not paying creative work, it can also be obtained according to these accompanying drawings other attached
Figure.
Fig. 1 is flow chart of the invention.
Embodiment
Below in conjunction with the accompanying drawing in the embodiment of the present invention, the technical scheme in the embodiment of the present invention is carried out clear, complete
Site preparation is described, it is clear that described embodiment is only a part of embodiment of the invention, rather than whole embodiments.It is based on
Embodiment in the present invention, it is all other that those of ordinary skill in the art are obtained under the premise of creative work is not made
Embodiment, belongs to the scope of protection of the invention.
Refer to shown in Fig. 1, the present invention is a kind of preparation method of PET bottle disinfectant, is carried out as follows；
Step 1. mixes benzenetricarboxylic acid, organic phosphorus compound, tungstates or/and molybdate, obtains mixture；
Step 2. takes a reactor, and water is added into reactor, and the mixture that step 1 is obtained then is poured into the addition
Have in the reactor of water, stirring and dissolving；
Step 3. adds surfactant into reactor, is subsequently agitated for dissolving；
Step 4. adds hydrogen peroxide into reactor, is subsequently agitated for dissolving；
Step 5. adds acetic acid into reactor, is subsequently agitated for 30 to 60 minutes, obtains finished product.
Wherein, in step 1, benzenetricarboxylic acid, organic phosphorus compound, the mass ratio of tungstates or/and molybdate are (2~4)：1：
(0.5~2).
Wherein, the mass ratio of hydrogen peroxide, acetic acid, mixture, surfactant and water is (27.00~39.00)：
(22.00~36.00)：(0.01~2.00)：(0.01~2.00)：(21.00~50.98).
The product obtained using the preparation method of beverage bottle disinfectant, by hydrogen peroxide, acetic acid, tungstates and/or molybdic acid
Salt, organic phosphorus compound, benzenetricarboxylic acid, surfactant and distilled water composition；Wherein：
Hydrogen peroxide：27-39%；
Acetic acid：22-36%；
Tungstates and/or molybdate：0.01-2%；
Organic phosphorus compound：0.01-2%；
Benzenetricarboxylic acid：0.01-4%；
Surfactant：0.01-2%；
Remaining is water.
Wherein, surfactant is nonionic surfactant.
Embodiment 1
1. by 0.5:1:4 mass ratio weighs sodium tungstate, ethylenediamine tetraacetic methyl acid phosphate, 1,3,5- 1,3,5-Benzenetricarboxylic acids respectively,
Mix and be sufficiently stirred for；
2 by sodium tungstate, ethylenediamine tetraacetic methyl acid phosphate and 1, mix reagent and the alcohol polyoxy of isomery ten of 3,5- 1,3,5-Benzenetricarboxylic acids
Ethene ether surface active agent, hydrogen peroxide, acetic acid input be equipped with and water reactor in, stirring and dissolving 60 minutes, that is, obtain stabilization
Property disinfectant.
Embodiment 2
1. by 2:1:4 mass ratio weighs potassium tungstate, hydroxy-methylbenzene fork diphosphonic acid, 1,2,3- benzene-1s, and mixing is simultaneously
It is sufficiently stirred for obtaining compound stabilizer.
2. by water, compound stabilizer, isomery undecyl alcohol polyoxyethylene ether surface active agent, hydrogen peroxide and acetic acid successively pump
Enter in reactor, fully dissolve and stir 45 minutes, that is, obtain disinfectant of the present invention.
The present invention reached peak concentration (Peracetic acid content 20.6%) in 10 days, and through room temperature stored protected from light 6 from
After the right moon, clear appearance is transparent, no color change and without precipitation and suspension.The stability of Peracetic acid very well, is always maintained at
Between 19.0%-20.1%, the rate of descent of Peracetic acid content is no more than 10%.
In the description of this specification, the description of reference term " one embodiment ", " example ", " specific example " etc. means
At least one implementation of the present invention is contained in reference to specific features, structure, material or the feature that the embodiment or example are described
In example or example.In this manual, identical embodiment or example are not necessarily referring to the schematic representation of above-mentioned term.
Moreover, specific features, structure, material or the feature of description can be closed in any one or more embodiments or example
Suitable mode is combined.
Present invention disclosed above preferred embodiment is only intended to help and illustrates the present invention.Preferred embodiment is not detailed
All details of narration, it is only described embodiment that the invention is not limited yet.Obviously, according to the content of this specification,
It can make many modifications and variations.This specification is chosen and specifically describes these embodiments, is to preferably explain the present invention
Principle and practical application so that skilled artisan can be best understood by and utilize the present invention.The present invention is only
Limited by claims and its four corner and equivalent.
Claims (5)
1. a kind of preparation method of PET bottle disinfectant, it is characterised in that carry out as follows：
Step 1. mixes benzenetricarboxylic acid, organic phosphorus compound, tungstates or/and molybdate, obtains mixture；
Step 2. takes a reactor, and water is added into reactor, and the mixture that step 1 is obtained then is poured into this added with water
Reactor in, stirring and dissolving；
Step 3. adds surfactant into reactor, is subsequently agitated for dissolving；
Step 4. adds hydrogen peroxide into reactor, is subsequently agitated for dissolving；
Step 5. adds acetic acid into reactor, is subsequently agitated for 30 to 60 minutes, obtains finished product.
2. the preparation method of a kind of PET bottle disinfectant according to claim 1, it is characterised in that in the step 1, benzene
Tricarboxylic acid, organic phosphorus compound, the mass ratio of tungstates or/and molybdate are (2~4)：1：(0.5~2).
3. the preparation method of a kind of PET bottle disinfectant according to claim 1, it is characterised in that the hydrogen peroxide, second
Acid, mixture, the mass ratio of surfactant and water are (27.00~39.00)：(22.00~36.00)：(0.01~2.00)：
(0.01~2.00)：(21.00~50.98).
4. the product obtained using the preparation method of beverage bottle disinfectant, it is characterised in that：By hydrogen peroxide, acetic acid, tungstates
And/or molybdate, organic phosphorus compound, benzenetricarboxylic acid, surfactant and distilled water composition；Wherein：
Hydrogen peroxide：27-39%；
Acetic acid：22-36%；
Tungstates and/or molybdate：0.01-2%；
Organic phosphorus compound：0.01-2%；
Benzenetricarboxylic acid：0.01-4%；
Surfactant：0.01-2%；
Remaining is water.
5. the product that the preparation method of use beverage bottle disinfectant according to claim 4 is obtained, it is characterised in that described
Surfactant is nonionic surfactant.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710396383.2A CN107114367A (en) | 2017-05-31 | 2017-05-31 | The preparation method and product of a kind of PET bottle disinfectant |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710396383.2A CN107114367A (en) | 2017-05-31 | 2017-05-31 | The preparation method and product of a kind of PET bottle disinfectant |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN107114367A true CN107114367A (en) | 2017-09-01 |
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201710396383.2A Pending CN107114367A (en) | 2017-05-31 | 2017-05-31 | The preparation method and product of a kind of PET bottle disinfectant |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN113785829A (en) * | 2021-10-19 | 2021-12-14 | 乐威医药(天津)有限公司 | Peroxyacetic acid solution and preparation method and application thereof |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102037959A (en) * | 2010-12-29 | 2011-05-04 | 广东环凯微生物科技有限公司 | Method for preparing stable peracetic acid disinfectant |
| CN102090393A (en) * | 2010-12-29 | 2011-06-15 | 广东环凯微生物科技有限公司 | Stable peroxyacetic acid disinfectant |
-
2017
- 2017-05-31 CN CN201710396383.2A patent/CN107114367A/en active Pending
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102037959A (en) * | 2010-12-29 | 2011-05-04 | 广东环凯微生物科技有限公司 | Method for preparing stable peracetic acid disinfectant |
| CN102090393A (en) * | 2010-12-29 | 2011-06-15 | 广东环凯微生物科技有限公司 | Stable peroxyacetic acid disinfectant |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN113785829A (en) * | 2021-10-19 | 2021-12-14 | 乐威医药(天津)有限公司 | Peroxyacetic acid solution and preparation method and application thereof |
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Application publication date: 20170901 |