CN107109310A

CN107109310A - Transparent liquid soap

Info

Publication number: CN107109310A
Application number: CN201580059372.4A
Authority: CN
Inventors: 肖巴尔·帕塔奈克; 塔努·阿格拉沃尔
Original assignee: LOreal SA
Current assignee: LOreal SA
Priority date: 2014-10-31
Filing date: 2015-10-30
Publication date: 2017-08-29
Also published as: WO2016066812A1

Abstract

Fluid composition is cleaned the present invention relates to one kind, it is included in the following material of physiologically acceptable aqueous medium：At least soap, at least one foaming surfactant, at least organic neutralizer, its using the mol ratio between soap and the organic neutralizer be at least 1:1.75 are present, and at least Tackified polymeric, and it comprises at least hydroxyl (C₁‑C₆) alkyl (C₁‑C₆) alkylcellulose, wherein, organic neutralizer makes said composition have from 8 to 9, preferably from 8 to 8.5 pH.The invention further relates to the method for cleaning keratin material, it includes applying the composition according to the present invention to the keratin material.

Description

Transparent liquid soap

Technical field

The present invention relates to a kind of personal nursing based on transparent liquid soap and/or cleaning composition, foam, it provides whole day Skin freshness, moisturizing, deposition the moment and whole day skin smooth and skin emolliency.The product also provides quick abundant Foam.

Background technology

A kind of our known limpid Cleasing compositions from document WO 2007/112852, its provide moisturizing and comprising Anion surfactant and another surface in amphoteric surfactant, nonionic surfactant or its mixture Activating agent, comprises in addition wetting agent.

Document WO2004/058212 and WO2004/100862 are disclosed comprising in the silicone component and aqueous phase in oil phase The oil-in-water emulsion formulations of polyalcohol or carboxylic acid.

The B1 of document EP 1 100 459 are disclosed comprising at least one nonionic surfactant, anion surface active Agent or the single-phase foaming oil formulation of zwitterionic surfactant, oil ingredient and at least one alkylphosphonate component.

Document US 5,030,374 discloses a kind of as clear as crystal gel facial cleansing agent formulation with neutral pH, its Do not foam, and be characterized in that the property got express developed, its substantially by gentle nonionic detergent and wound clean agent, NMF/wetting agent, gelling agent, viscosity stabiliser, directly pH adjusting agent, (substantive) emollient, preservative/bacterium Inhibitor, solubilizer, screening agent and deionized water composition.

In addition, JP 2008-137904 describe a kind of liquid skin detergent composition, it includes (A) 2 mass % extremely 30 mass % soap, (B) 0.1 mass % to 3 mass % non-ionic water-soluble polymer compound or anionic water The water-soluble silicone compounds of soluble polymeric compounds and (C) 0.3 mass % to 5 mass %.

Disclosed transparent composition does not have one to realize the excellent foam properties being entirely satisfactory, while making skin With mildness and moisture retention.

In addition, the visual appearance of product influences the impression of consumer.For example, limpid and transparent facial cleansing agent mainly with Freshness, mildness, purity, cooling feeling, the cleannes of consumer etc. are relevant.Therefore, opaque products are used for various personal nursings Using.Also, when opaque products are packaged in transparent wrapper, make consumer is organic to can be appreciated that whole product.

The content of the invention

Accordingly, it would be desirable to transparent and stable liquid cleansing composition.Advantageously, this transparent and stable cleaning liquid group Compound has the good foaming for being suitable for face washing and/or body wash and using, oil-control performance, and includes minimal amount of surface Activating agent.Advantageously, required composition is also gentle, moisturizing, skin care and is environment-friendly and can be biological Degraded.

In the present invention, it is stable at 4 DEG C during stable composition refers in 1 month period, preferably at 2 months.

The combination of the verified following material of inventor makes it possible to provide transparent and stable Cleasing compositions, and its is favourable Real estate lactogenesis smectic foam, moistening skin sensation and be gentle：

- at least soap,

- at least one foaming surfactant,

- at least organic neutralizer, the organic neutralizer is between soap and the organic neutralizer at least 1:1.75th, preferably extremely Few 1:1.8 mol ratio is present, and

- at least Tackified polymeric, the Tackified polymeric comprises at least hydroxyl (C₁-C₆) alkyl (C₁-C₆) alkylcellulose.

Therefore, the transparent of following material is contained it is an object of the invention to acceptable aqueous medium in a physiologically Cleaning fluid composition：

- at least soap,

- at least one foaming surfactant,

- at least Tackified polymeric, the Tackified polymeric comprises at least hydroxyl (C₁-C₆) alkyl (C₁-C₆) alkylcellulose,

Wherein, the pH of the composition is from 8 to 9, preferably from 8 to 8.5.

Facial cleansing agent is may be used as according to the Cleasing compositions of the present invention, such as makeup removing agent and hand cleaning agent With clean body agent.

According on the other hand, a theme of the invention is also a kind of method for cleaning keratin material, and it is included to institute State keratin material to apply according to composition of the invention, finally using water, then rinse to eliminate foam and dirt with water.Group Compound can be directly applied on wet keratin material, or be mixed with water, then be applied on keratin material.

For purposes of the present invention, statement " physiologically acceptable medium " refers to be applied in keratin material (such as skin Skin) on apply according to the present invention composition medium.

Physiologically acceptable medium is preferably the acceptable medium of beauty or the acceptable medium of dermatology, also It is to say, without unhappy smell or outward appearance and the medium fully compatible with topical routes of administration.

When this medium will not cause any unacceptable shouting pain of user, tighten or be rubescent, it is especially considered as It is physiologically acceptable.

For purposes of the present invention, term " liquid " refers in liquid form, and such as composition is at environment temperature (25 DEG C) With the flowing under its own weight in less than 5 seconds under atmospheric pressure.

Viscosity measurement

Under the framework of the present invention, Rheomat is usedDevice carries out viscosity survey under 25 DEG C and atmospheric pressure Amount.

Sample is placed at a temperature of 25 DEG C ± 0.5 DEG C.Rheomat is attached to using rotor 3With 200 The rotary speed of (fixation), 10 minutes measurement viscosity later is rotated in measuring instrument.With UD (unit offset) represent it is corresponding Value is converted into Pas.

Transparency

It is transparent according to the composition of the present invention.Using Shimadzu UV-1800 spectrometers, pass through 3.5mL quartz The light path of cuvette and 10mm, group is evaluated by the Transmissivity measurement under 25 DEG C and atmospheric pressure between 620nm and 750nm The transparency of compound.According to the present invention, when transmitance value is better than 90% in the wave-length coverage, composition is transparent.

Contain the surfactant and soap for assigning its foam properties of composition according to the composition of the present invention.

At least soap and at least one foaming surfactant are contained according to the frothing cleaning composition of the present invention.

According to another embodiment, relative to the gross weight of composition, foaming surfactant is with 0.5 weight % Amount to 10 weight %, particularly 2 weight % to 8 weight %, more particularly 3 weight % to 6 weight % is present in composition.

Foaming surfactant is detergent, and different from emulsifying agent in terms of its HLB (hydrophilic-lipophilic balance (HLB)) value, HLB is the ratio of hydrophilic segment and oleophilic moiety in molecule.Term " HLB " is that well known to a person skilled in the art and describe In such as " The HLB system.A time-saving guide to Emulsifier Selection " (ICI Americas Inc. are published, 1984) in.For emulsifying agent, the HLB for preparing W/O emulsions is usually 3 to 8, prepares O/W emulsions HLB be usually 8 to 18, and the HLB of foaming surfactant is typically larger than 20.

According to another embodiment, foaming surfactant at least contains anion surfactant.

According to another embodiment, foaming surfactant also contains cationic surfactant.It is described sun from Sub- surfactant can be present in composition relative to the gross weight of composition with the amount less than 2 weight %.More specifically, This cationic surfactant can relative to composition gross weight with 0.001 weight % to 0.5 weight %, more preferably 0.01 weight % to 0.1 weight % amount is present.

For soap, it is considered to the amount of calculating soap amount be free from the total fatty acid content of nertralizer.

Soap

The soap used within the framework of the invention is that have 10 to 22 carbon atoms, more preferably 12 to 18 carbon originals Son, organic soap of most preferably 12 aliphatic acid to 14 carbon atoms.

Aliphatic acid can in particular selected from caproic acid, capric acid, octanoic acid, oleic acid, linoleic acid, laurate, myristic acid, stearic acid, Palmitic acid and its mixture.

Nertralizer can be selected from amino alcohol, such as monoethanolamine, amino sugar, amino acid and its basic salt.Most preferably neutralize Agent is triethanolamine.

The neutralization of soap can be at least 1 by the mol ratio between aliphatic acid and nertralizer:1.75th, preferably at least 1:1.8 To realize.

According to another embodiment, the mol ratio between aliphatic acid and nertralizer is 1:1.75 to 1:3, particularly 1: 1.8 to 1:2.5.

Relative to the gross weight of composition, the soap content in composition may, for example, be 2 weight % to 7 weight %, more excellent Select 3 weight % to 6 weight %, most preferably 4 weight % to 5 weight %.

Foaming surfactant

One or more surfactants are included according to the frothing cleaning composition of the present invention.

Surfactant can be selected from anionic lathering surfactant agent, both sexes (or amphion) lathering surfactant Agent, nonionic lather surfactants and/or cation foaming surfactant and its mixture.

Anion surfactant

One or more anion surfactants can also be included according to the composition of the present invention.

Term anion surfactant refers to only have anionic group as ionic group or ionogen Surfactant.

In this manual, using the present composition and the condition (such as medium, pH) of cationic charge is not being contained Under, when an entity has at least one permanent negative electrical charge or when it can be ionized to negative electrical charge entity, the entity quilt It is considered " anion ".

Anion surfactant can have at least one sulfate groups (- OSO₃H or-OSO₃ ^-) and/or sulfonic acid Foundation group (- SO₃H or-SO₃) sulfate or sulfonate, or with least one hydroxy-acid group (- COOH or-COO^-) Carboxylic acid surfactant or carboxylate surface active agent.

It should be appreciated that anionic carboxylic acid salt surfactant can include one or more sulfate groups or sulphonate-base Group；Sulfonate anionic surfactant optionally can further include one or more sulfate groups or carboxylate groups (carboxylate group)；And, sulphate anion surface active agent can be optionally further comprising one or more Carboxylate groups or sulfonate groups.

The anion surfactant that can be used includes alkyl sulfate, alkyl ether sulfate, alkylamidoalkyl ether sulphur Hydrochlorate, alkyl aryl polyether sulfate, single glycerine sulfate, alkylsulfonate or alpha-alkene sulfonate, alkylamide sulfonates, Alkylaryl sulfonates, alkane sulfonate, alkyl sulfosuccinates, alkyl ether sulfosuccinates, alkylamide sulfo group Succinate, alkyl sulfoacetate, acyl sarcosinates, acyl glutamate, alkyl sulfo succinate, acyl group hydroxyl second sulphur Hydrochlorate and N- acyl taurine salts, alkyl monoester and the polycarboxylic salt of many glucosides, acyl lactate, N- acylglycines Salt, the salt of D- galactosides-uronic acid, the salt of alkyl ether carboxylic acid, alkylaryl ether carboxylate, alkylamidoalkyl ether carboxylic acid Salt, sulfosalicylic acetate, the corresponding salt-independent shape of sulfolauric acid salt and all these compounds, the alkane of all these compounds Base group and carboxyl groups contain 6 to 40 carbon atoms, particularly 14 to 30 carbon atoms, more preferably 16 to 22 carbon Atom；And aryl refers to phenyl group.These compounds can be ethoxylation, then preferably comprise 1 to 50 ring Oxirane unit.

Polyoxyalkylenated (the C of ethene can also be enumerated₆-C₂₄) (amide groups) ether carboxylic acid and its salt, particularly comprising 2 extremely Those of 50 alkylen groups, those particularly for example sold by flower king (KAO) company with title AKYPO.

Preferred alkyl (C₆-C₂₄) (amide groups) ether carboxylic acid correspond to following formula：

R₁-(OC₂H₄)_n-OCH₂COOA (1)

Wherein：

-R₁Represent C₈To C₂₂Straight or branched alkyl or alkenyl, alkyl (C₈-C₉) phenyl group, R₂CONH-CH₂-CH₂- The group or mixture of group, wherein R₂Represent alkyl group, C₉To C₂₁Straight or branched alkenyl；Preferably, R₁For with 8 Individual to 20 carbon atoms, preferably 8 alkyl groups to 18 carbon atoms, and aryl preferably represents phenyl,

- n is integer or decimal number (average value), and it can change between 2 to 24 and preferably between 2 to 10,

- A represents H, ammonium, Na, K, Li, Mg or MEA or triethanolamine.

The mixture of formula (1) compound can also be used, the wherein different mixture of R1 groups is particularly.

It is preferably used in the polyoxyalkylenated (C in the present invention₆-C₂₄) those of (amide groups) ether carboxylic acid selected from formula (1), its In：

-R₁Represent (C₁₂-C₁₄) alkyl, cocoyl, oil base, the group or mixture of nonyl or octyl phenyl group,

- A represents hydrogen or sodium, and

- n is 2 to 20 and preferably 2 to 10.

Preferably use polyoxygenated (C₆-C₂₄) alkylene ether carboxylic acid and its salt, polyoxyalkylenated (C can also be used₆-C₂₄) Alkylamidoalkyl ether carboxylic acid and its salt；Particularly there are those of 2 to 15 alkylene oxide groups.

Even further preferably, wherein R can be used to be C₁₂Alkyl, A represent formula (1) chemical combination that hydrogen or sodium and n are 2 to 10 Thing.

Salt is in particular selected from alkali metal salt, particularly sodium, ammonium salt, amine salt, amino alcohol (such as triethanolamine or MEA) And magnesium salts.

Preferably, anion surfactant is selected from the following material individually or as mixture：

-(C₆-C₂₄) alkyl sulfate, particularly C₁₂-C₂₀Alkyl sulfate,

-(C₆-C₂₄) alkyl ether sulfate, particularly C₁₂-C₂₀Alkyl sulfate, preferably comprises 2 to 20 oxirane Unit,

-(C₆-C₂₄) alkyl sulfosuccinates, particularly C₁₂-C₂₀Alkyl sulfosuccinates, including lauryl sulfo group Succinate,

-(C₆-C₂₄) alkyl ether sulfosuccinates, particularly C₁₂-C₂₀Alkyl ether sulfosuccinates,

-(C₆-C₂₄) acyl sarcosinates, particularly C₁₂-C₂₀Acyl sarcosinates, including palmitoyl sarcosine salt,

-(C₆-C₂₄) alkyl ether carboxy acid salt, preferably (C₁₂-C₂₀) alkyl ether carboxy acid salt,

-(C₆-C₂₄) acyl isethinate, preferably (C₁₂-C₁₈) acyl isethinate,

- polyoxyalkylenated (C₆-C₂₄) alkyl (amide groups) ether carboxylic acid and its salt, particularly comprising 2 to 50 alkylene oxides Those of group, particularly oxirane,

-(C₆-C₂₄) acyl glutamate, particularly C₁₂-C₂₀Acyl glutamate,

-(C₆-C₂₄) acylglycine salt, particularly C₁₂-C₂₀Acylglycine salt,

Particularly in the form of alkali metal or alkaline-earth metal, ammonium, amine or amino alcohol.

It is highly preferred that anion surfactant is selected from (C₆-C₂₄) alkyl sulfate, (C₆-C₂₄) alkyl ether sulfate (example Such as sodium laureth sulfate), isethionate, amino acid, particularly glycinate (such as N- cocoyls Sodium Glycinate), it Basic salt and its mixture.

Both sexes and amphion foaming surfactant

One or more amphoteric surfactantes can also be included according to the composition of the present invention.

Amphoteric surfactant available for the present invention may optionally be quaternized secondary aliphatic amine derivative or tertiary fatty amine Derivative, wherein aliphatic group are that the amine derivative contains at least one comprising the straight or branched 8 to 22 carbon atoms Anionic group, such as carboxylate, sulfonate, sulfate, phosphate or phosphonate groups.

Can be with specifically mentioned (C₈-C₂₀) alkyl betaine, sulfobetaines, (C₈-C₂₀) alkyl sulfo betaines, (C₈- C₂₀) alkylamidoalkyl (C₁-C₆) alkyl betaine (such as Cocoamidopropyl betaine) and (C₈-C₂₀) alkylamidoalkyl (C₁- C₆) alkyl sulfo betaines and its mixture.

In the optional quaternized secondary aliphatic amine derivative that can be used or tertiary aliphatic amine derivative, it can also refer to The product of (A1) and (A2) each structure below：

(A1) Ra-CON(Z)CH₂-(CH₂)_m-N⁺(Rb)(Rc)(CH₂COO^-)

Wherein,

Ra represents the (C derived from the sour Ra-COOH being preferably in hydrolysis cocounut oil₁₀-C₃₀) alkyl group or (C₁₀- C₃₀) alkenyl group, heptyl groups, nonyl group or undecyl group,

Rb represents beta-hydroxyethyl group,

Rc represents carboxymethyl group,

M is equal to 0,1 or 2,

Z represents hydrogen atom or hydroxyethyl groups or carboxymethyl group；

(A2) R_a’-CON(Z)CH₂-(CH₂)_m’-N(B)(B')

Wherein：

B represents-CH₂CH₂OX', wherein X' represent-CH₂-COOH、CH₂-COOZ'、-CH₂CH₂-COOH、-CH₂CH₂-COOZ' Or hydrogen atom,

B' represents-(CH₂)_z- Y', wherein z=1 or 2, Y' represent-COOH ,-COOZ' ,-CH₂-CHOH-SO₃H or-CH₂- CHOH-SO₃Z',

M' is equal to 0,1 or 2,

Z represents hydrogen atom or hydroxyethyl groups or carboxymethyl group,

Z' represents the ion by alkali metal or alkaline-earth metal (such as sodium, potassium or magnesium) generation；Ammonium ion；Or produced by organic amine It is raw, particularly by amino alcohol (such as MEA, diethanol amine and triethanolamine, monoisopropanolamine, diisopropanolamine (DIPA) or three Isopropanolamine, 2-amino-2-methyl-1-propanol, 2- amino-2-methyl -1,3- propane diols and three (methylol) aminomethanes) production Raw ion.

Ra' represents to be preferably in hydrolysis linseed oil or the (C of the sour Ra'COOH in cocounut oil₁₀-C₃₀) alkyl group or Alkenyl group, alkyl group, particularly C17 alkyl groups and its isomers, or unsaturation C17 groups.

Compound corresponding to formula (A2) is preferred.

In the compound of formula (A2) of hydrogen atom is represented corresponding to wherein X', it can be mentioned that classify in CTFA dictionaries Compound, its title is sodium cocoamphoacetate, LAA, caprinoyl sodium acetate and decoyl both sexes base second Sour sodium.

Compound corresponding to formula (A2) can be (C₈-C₂₀) alkylamphoacetate and (C₈-C₂₀) alkyl both sexes base Diacetin and its mixture.

Other compounds corresponding to formula (A2) are cocounut oil acyl both sexes base diethyl acid disodium, lauroyl both sexes base oxalic acid two Sodium, caprinoyl both sexes base diethyl acid disodium, decoyl both sexes base diethyl acid disodium, cocounut oil acyl both sexes base disodium beclomethasone, lauroyl two Property base disodium beclomethasone, caprinoyl both sexes base disodium beclomethasone, decoyl both sexes base disodium beclomethasone, lauroyl both sexes base dipropionic acid and Cocounut oil both sexes base dipropionic acid.

It can be mentioned that example include by Rhodia companies with trade nameWhat C2M Concentrate were sold Cocounut oil acyl both sexes base diacetin, the cocounut oil acyl both sexes base sodium diacelate sold with trade name Miranol Ultra C 32, with And the product sold by Chimex companies with trade name Chimexane HA.

Formula (A3) compound can also be used：

(A3) R_a”-NH-CH(Y”)-(CH₂)n-C(O)-NH-(CH₂)n’-N(R_d)(R_e)

Wherein：

-R_a" represent to be preferably in hydrolysis linseed oil or hydrolyze the (C of sour Ra'-C (O) OH in coconut oil₁₀-C₃₀) alkane Base group or alkenyl group；

- Y " represents group-C (O) OH ,-C (O) OZ " ,-CH₂-CH(OH)-SO₃H or group-CH₂-CH(OH)-SO₃- Z ", Wherein Z " represents the cation counterbalancing ion produced by alkali metal or alkaline-earth metal (such as sodium), ammonium ion or produced by organic amine Ion；

-R_dAnd R_e(C is represented independently of one another₁-C₄) alkyl group or hydroxyalkyl group；And

- n and n' represent 1 to 3 integer independently of one another.

, can be with the specifically mentioned compound being included into CTFA dictionaries, its title in the compound corresponding to formula (A3) For lignocaine propyl group cocoyl asparagine, the product for example sold by Chimex companies with title Chimexane HB.

Preferably, amphoteric surfactant is selected from (C₈-C₂₀) alkyl betaine, (C₈-C₂₀) alkylamidoalkyl (C₁-C₆) alkane Base glycine betaine, (C₈-C₂₀) alkylamphoacetate and (C₈-C₂₀) alkyl both sexes base diacetin and its mixture.

Nonionic lather surfactants

Composition can particularly be represented comprising one or more nonionic alkyl polyglucoside surfactants by formula (I) Nonionic alkyl polyglucoside surfactant：

R₁O-(R₂O)_t-(G)_v

Wherein：

-R₁Represent the straight or branched alkyl group with 6 to 24 carbon atoms, particularly 8 to 18 carbon atoms Or alkenyl group, or its straight or branched alkyl includes 6 to 24 carbon atoms, particularly 8 alkyl to 18 carbon atoms Phenyl group,

-R₂The alkylene group with 2 to 4 carbon atoms is represented,

- G be containing 5 sugar units to 6 carbon atoms,

- t is 0 to 10 value, preferably 0 to 4 value,

- v is 1 to 15 value, preferably 1 to 4 value.

Preferably, alkyl polyglucoside surfactant is formula as described above (I) compound, wherein：

-R₁Straight or branched, saturation or undersaturated alkyl group with 8 to 18 carbon atoms are represented,

-R₂The alkylene group with 2 to 4 carbon atoms is represented,

- t is 0 to 3 value, preferably equal to 0,

- G represents glucose, fructose or galactolipin, preferably glucose,

The value of-the degree of polymerization, i.e. v can be 1 to 15, preferably 1 to 4；Average degree of polymerization is more specifically between 1 and 2.

Glycosidic bond between sugar unit is usually 1 to 6 or 1 to 4, preferably 1 to 4.

Preferably, alkyl polyglucoside surfactant is alkyl polyglucoside surfactant, even more preferably C8-C16 Alkyl polyglucoside, particularly preferably selected from Plantacare 818, caprylyl/capryl glucoside, lauryl glucoside, cocoyl Portugal Glucosides, caprylyl glucoside and its mixture.

In commercially available prod, following product can be enumerated：By section peaceful (COGNIS) with title (600CS/U, 1200 and 2000) or(818,1200 and 2000) sell product；By match Bick (SEPPIC) withThe Hes of CG 110The product that NS 10 is sold；By BASF (BASF) with title The product of the sales of LUTENSOL GD 70 or the product sold by CHEM Y companies with title AG10LK.

Preferably, using C8-C16 alkyl polyglucosides, Plantacare 818, caprylyl/capryl glucose are especially selected from Glycosides, lauryl glucoside, cocoyl glucoside, caprylyl glucoside and its mixture.

Cationic surfactant

One or more cationic surfactants can also be included according to the cosmetic composition of the present invention.They are favourable Ground is selected from optionally polyoxyalkylenated primary aliphatic amine salt, secondary fatty amine salt or tertiary fatty amine salt, quaternary ammonium salt and its mixture.

Can be with specifically mentioned：

- the quaternary ammonium salt with formula (Ia)：

Wherein：

Group R₈To R₁₁(can be same or different) represents the straight or branched fat containing 1 to 30 carbon atom Race's group, or aromatic group, such as aryl or alkaryl, group R₈To R₁₁At least one of contain 8 to 30 carbon atoms And it is preferred that 12 to 24 carbon atoms；Aliphatic group can include hetero atom, for example, particularly oxygen, nitrogen, sulphur or halogen；With And

X^-It is to be selected from by halide, phosphate, acetate, lactate, (C₁-C₄) alkyl sulfate, (C₁-C₄) alkyl Sulfonate and (C₁-C₄) alkylaryl sulfonates constitute group anion.

Aliphatic group is selected from such as (C₁-C₃₀) alkyl, (C₁-C₃₀) alkoxy, (C₂-C₆) polyoxyalkylene, (C₁-C₃₀) alkyl Acid amides, (C₁₂-C₂₂) alkyl (C₂-C₆) alkylamidoalkyl, (C₁₂-C₂₂) acetate alkyl salt and hydroxyl (C₁-C₃₀) alkyl group.

It can be mentioned that tetraalkylammonium halide, preferably chloride (such as dialkyl dimethyl ammonium chloride or alkyl trimethyl Ammonium chloride), wherein alkyl group includes 12 to 22 carbon atoms, particularly behenyl base trimethyl ammonium chloride, distearyl two Ammonio methacrylate, hexadecyltrimethylammonium chloride and benzyl dimethoylstearyl ammonium chloride.

Palmityl amido oxypropyl trimethyl ammonium halide, preferably palmityl amidopropyl trimethyl ammonium chlorine can also be referred to Compound, or bisisostearamidopropyldimonium (myristyl alcohol acetic acid esters)-ammonium halide, preferably bisisostearamidopropyldimonium (myristyl alcohol acetic acid esters)-ammonium chloride, such as by VAN DYK companies with title70 products sold.

- the imidazoline quaternary ammonium salt with formula (IIa)：

Wherein：

R₁₂Represent alkenyl group or alkyl group containing 8 to 30 carbon atoms, the derivative of fatty acid of such as tallow；

R₁₃Represent hydrogen atom, (C₁-C₄) alkyl group or alkenyl group or alkyl base containing 8 to 30 carbon atoms Group；

R₁₄Represent (C₁-C₄) alkyl group；

R₁₅Represent hydrogen atom or (C₁-C₄) alkyl group；

X is anion, is preferably chosen from by halide, phosphate, acetate, lactate, (C₁-C₄) alkyl sulfate, (C₁-C₄) alkylsulfonate and (C₁-C₄) alkylaryl sulfonates constitute group anion；

R₁₂And R₁₃Preferably represent the mixture of the alkenyl group containing 12 to 21 carbon atoms or alkyl group, example Such as the derivative of fatty acid of butter, R₁₄Represent methyl group, and R₁₅Represent hydrogen atom.This product for example by Rewo companies with TitleW 75 is sold.

- quaternized di-ammonium salts or quaternized three ammonium salt with formula (IIIa)：

Wherein：

R₁₆Represent containing 16 alkyl groups to 30 carbon atoms, it is optionally by hydroxylating and/or by one or many Individual oxygen atom is interrupted,

R₁₇Represent hydrogen atom or alkyl group or group-(CH containing 1 to 4 carbon atom₂)₃-N⁺(R_16a)(R_17a) (R_18a)；Wherein R_16a、R_17a、R_18a(can be same or different) be selected from hydrogen and includes the alkyl base of 1 to 4 carbon atom Group,

R₁₈、R₁₉、R₂₀And R₂₁(can be same or different) be selected from hydrogen and includes the alkyl base of 1 to 4 carbon atom Group；And

X^-It is to be preferably chosen from by halide, acetate, phosphate, nitrate, (C₁-C₄) alkyl sulfate, (C₁-C₄) alkane Base sulfonate and (C₁-C₄) anion in the group that constitutes of alkylaryl sulfonates, particularly Methylsulfate and ethyl sulfuric acid Salt.

These compounds be the Finquat CT-P (Quaternium 89) that are for example sold by Finetex companies and by The Finquat CT (Quaternium 75) that Finetex companies sell.

- the quaternary ammonium salt with following formula (IV a) containing one or more ester functional groups：

Wherein：

R₂₂Selected from (C₁-C₆) alkyl group and hydroxyl (C₁-C₆) alkyl group or dihydroxy (C₁-C₆) alkyl group；

R₂₃Selected from group R₂₆- C (=O)-；Straight or branched, saturation or undersaturated C based on hydrocarbon₁-C₂₂Group R₂₇； And hydrogen atom；

R₂₅Selected from group R₂₈- C (=O)-；Straight or branched, saturation or undersaturated C based on hydrocarbon₁-C₆Group R₂₉； And hydrogen atom；

R₂₄、R₂₆And R₂₈(can be same or different) be selected from straight or branched, saturation or undersaturated C₇-C₂₁ Hydrocarbyl group；

R, s and t (can be same or different) be 2 to 6 integer；

R1 and t1 (can be same or different) is equal to 0 or 1；

R2+r1=2r and t1+t2=2t；

Y is 1 to 10 integer；

X and z (can be same or different) is 0 to 10 integer；

X+y+z's and for 1 to 15；

X^-It is anion；

Condition is the then R when x is 0₂₃Represent R₂₇, when z is 0, then R₂₅Represent R₂₉。

Alkyl group R₂₂Can be straight or branched, more specifically straight chain.Preferably, R₂₂Represent methyl, second Base, ethoxy or dihydroxypropyl group, more specifically methyl group or ethyl group.

Work as R₂₃For R₂₇During hydrocarbyl group, it can have 12 to 22 carbon atoms, or can have 1 to 3 carbon Atom.

Work as R₂₅For R₂₉During hydrocarbyl group, it preferably has 1 to 3 carbon atom.

Advantageously, R₂₄、R₂₆And R₂₈(same or different) selected from straight or branched, saturation or undersaturated C₁₁- C₂₁Hydrocarbyl group, more specifically selected from straight or branched C₁₁-C₂₁Alkyl and alkenyl group.

Preferably, x and z (can be same or different) is equal to 0 or 1.

Advantageously, y is equal to 1.

Advantageously, x+y+z's and for 1 to 10.

Preferably, r, s and t (can be same or different) be equal to 2 or 3, or even are more specifically equal to 2.

Anion X^-Preferably halide (preferably chloride, bromide or iodide), (C₁-C₄) alkyl sulfate, (C₁-C₄) alkylsulfonate or (C₁-C₄) alkylaryl sulfonates, mesylate, phosphate, nitrate, toluene fulfonate, spread out Be born from organic acid anion (such as acetate or lactate) or it is compatible with the ammonium comprising ester functional group it is any other it is cloudy from Son.Anion X^-More specifically chloride, Methylsulfate or sulfovinate.

In the composition according to the present invention, more specifically using the ammonium salt with formula (IV a), wherein：

-R₂₂Methyl group or ethyl group are represented,

- x and y is equal to 1,

- z is equal to 0 or 1,

- r, s and t are equal to 2,

-R₂₃Selected from group R₂₆- C (=O)；Methyl group, ethyl group or the C based on hydrocarbon₁₄-C₂₂Group；And hydrogen atom,

-R₂₅Selected from R₂₈- C (=O)-；And hydrogen atom,

-R₂₄、R₂₆And R₂₈(can be same or different) be selected from straight or branched, saturation or undersaturated C₁₃- C₁₇Hydrocarbyl group, preferably straight or branched, saturation or undersaturated C₁₃-C₁₇Alkyl group and alkenyl group.

Group based on hydrocarbon advantageously straight chain.

In formula (IV a) compound, the example that can be mentioned that includes two dimethylbenzylammonium ammoniums, two trimethylammoniums Hydroxyethyl methyl ammonium, mono-acyloxy ethyl dihydroxy ethyl ammonium methyl, three acyloxy ethyl-methyl ammoniums or mono-acyloxy ethyl hydroxyl second The salt of base Dimethyl Ammonium and its mixture, especially their chloride or Methylsulfate.Carboxyl groups preferably comprises 14 To 18 carbon atoms, and more particularly from vegetable oil, such as palm oil or sunflower oil.When compound contains some acyl groups During group, these groups can be same or different.

These products for example pass through optional oxyalkylenated triethanolamine, triisopropanolamine, alkyldiethanolamine or alkane Aliphatic acid or the fatty acid mixt direct esterification of base diisopropanolamine (DIPA) and plant or animal origin, or the ester for passing through its methyl ester Exchange to obtain.It is such as alkyl halide (the preferably methyl halide or ethyl halogenation by alkylating agent after the esterification Thing), dialkyl sulfate (preferably Methylsulfate or sulfovinate), methyl methylsulfonate, methyl tosylate, chloroethene Glycol or propylene glycol of chlorine carry out quaternized.These compounds are, for example, with title by Henkel (Henkel) company Sell, by Stepan companies with titleSell, by Ceca companies with titleSell or By Rewo-Witco companies withWE 18 is sold.

The mixing of such as quaternary ammonium monoester salt, quaternary ammonium diester salt and the ester salt of quaternary ammonium three can be included according to the composition of the present invention Thing, wherein with the diester salt for accounting for most of weight.It can also use in patent US-A-4 874 554 and US-A-4 137 The ammonium salt containing at least one ester functional group described in 180.Behenyl acyloxy hydroxypropyl trimethyl chlorination can also be used Ammonium, the product for example sold by Kao companies with title Quartamin BTC 131.

Preferably, the ammonium salt containing at least one ester functional group contains Liang Ge esters functional group.

Preferably, cationic surfactant is selected from formula (Ia) compound and formula (IVa) compound, is preferably chosen from 16 Alkyl trimethyl ammonium salt, behenyl base leptodactyline and two paimcarboxyethyl hydroxyethyl methyl ammonium salts and its mixture, more specifically Ground be selected from Varisoft BT 85 or behenyl base trimethylammoniumethyl sulfate, hexadecyltrimethylammonium chloride or Cetyltrimethyl ammonium Methylsulfate and two paimcarboxyethyl hydroxyethyl ammonium chlorides or two paimcarboxyethyl hydroxyethyl ammoniums Methylsulfate and its mixture.Even further preferably, cationic surfactant is behenyl base leptodactyline.

According to preferred embodiment, composition includes at least one anion surfactant, is preferably chosen from containing 6 Individual to 24 carbon atoms, preferably 2 alkyl ether sulfates to 20 carbon atoms；Amino acid, particularly glycinate；And its it is mixed Compound.

In a specific embodiment, composition includes at least one anion surfactant, is preferably chosen from Sodium laureth sulfate (SLES), particularly SLES 1EO, such as by Galaxy Surfactants with title Galaxy LES 170 those sold；Glycinate, such as cocoyl Sodium Glycinate.

Tackified polymeric

At least one Tackified polymeric is included according to the Cleasing compositions of the present invention, it includes at least one hydroxyl (C₁-C₆) Alkyl (C₁-C₆) alkylcellulose.According to specific embodiment, Tackified polymeric comprises at least hydroxyl (C₁-C₄) alkyl (C₁- C₄) alkylcellulose.

The viscosity of Tackified polymeric can be according to described above for the water-soluble of the polymer comprising 2 weight % The scheme measurement of liquid.

According to specific embodiment, when Tackified polymeric is present in the aqueous solution with 2% weight concentration, thickening is poly- The viscosity of compound changes between 75 000mPas and 140 000mPas.

Can be in particular selected from methylol-butyl cellulose, hydroxyethyl methyl with cellulose ether used according to the invention Cellulose, ethoxy butyl cellulose and hydroxypropyl methyl cellulose (also referred to as HPMC) and its mixture.

It is highly preferred that suitable for the hydroxyl (C used in the present invention₁-C₆) alkyl (C₁-C₆) alkylcellulose is hydroxypropyl Methylcellulose.

According to the specific embodiment, relative to the gross weight of hydroxypropyl methyl cellulose, hydroxypropyl methyl fiber Element has such as 7 weight % to 12 weight % hydroxypropyl content, and relative to the gross weight of hydroxypropyl methyl cellulose, tool There is such as 20 weight % to 24 weight % methoxyl content.

Hydroxypropyl methyl cellulose is especially by Shin-Etsu companies with title Metolose^TMSell, more specifically, example Such as with title Metolose^TM 60SH 4000、Metolose^TM 60SH 50、Metolose^TM 90SH 100、Metolose^TM 90SH 4000、Metolose^TM 90SH 15000、Metolose^TM 65SH 50、Metolose^TM 65SH 4000、 Metolose^TM60SH 4000 and Metolose^TM60SH 5 is sold；By Dow Chemical (The Dow Chemical Company) with title Methocel^TMSell, more specifically, for example with title Methocel^TM E-3、Methocel^TM E-6、 Methocel^TM E-50、Methocel^TM E4M、Methocel^TM F50、Methocel^TM F4M、Methocel^TM K100、 Methocel^TMK4M and Methocel^TMK100M is sold；By conspicuous (Shandong Head) company that reaches in Shandong with title Headcel^TMSell, more specifically, for example with title Headcel^TM 60HD3、Headcel^TM 60HD15、 Headcel^TM60HD4000、Headcel^TM 65HD50、Headcel^TM 75HD100、Headcel^TM 75HD4000、 Headcel^TM75HD15000 and Headcel^TM75HD100000 is sold；And by Ya Shilan (Ashland) with title BENECEL K100M are sold.

In the hydroxypropyl methyl cellulose, the BENECEL K100M sold by Ya Shilan can be especially enumerated.

Relative to the gross weight of composition, Tackified polymeric can be with 0.2 weight % to 6 weight %, particularly 0.5 weight Amount % to 5 weight %, more specifically 0.8 weight % to 1.2 weight % amount are present in the Cleasing compositions according to the present invention.

Composition

The viscosity (being determined according to scheme described above) that can be presented according to the composition of the present invention is 0.1Pas To 3Pas, particularly 0.2Pas to 2Pas, more particularly 0.3Pas to 1.3Pa.s.

Aqueous medium or aqueous phase are included according to the composition of the present invention.

Composition can be at least 50 weight %, preferably 50 weight % to 95 weights comprising the gross weight relative to composition %, preferably 60 weight % is measured to the water of 90 weight % amount.According to specific embodiment, according to the composition bag of the present invention Gross weight containing relative to composition is less than 1 weight % oil ingredient.According to specific embodiment, composition not oil-containing.

A variety of water-soluble additives can be contained according to the Cleasing compositions of the present invention, it is selected from conventionally used for skin care or unloaded The water-soluble additives of adornment product, as long as these additives and its amount do not influence the transparency according to needed for the composition of the present invention And stability.

Therefore, following additive can be included according to the Cleasing compositions of the present invention：Preservative, chelating agent (EDTA and its Salt), antioxidant, aromatic, active component.

The amount of these various adjuvants be in the art it is under consideration it is conventional use of those, for example, composition gross weight The 0.01% to 20% of the active material of amount.Needed for these adjuvants and its consumption should make it that they do not change the present composition Property.

Amphiphilic polymers, cationic polymerization optionally can also be selected from comprising one or more according to the composition of the present invention The polymer of thing and its mixture.

Term " cationic polymer " refers to comprising cation group and/or can ionize group for cation group Any polymer.Preferably, cationic polymer is hydrophilic or amphipathic.It is preferred that cationic polymer be selected from containing bag The polymer of unit containing primary amine, secondary amine, tertiary amine and/or quaternary amines, the unit can form a part for host polymer chain Or can be carried by the side substituent directly connected.

The weight-average molar mass (Mw) for the cationic polymer that can be preferably used is about 500 to 5 × 10⁶, preferably about For 10³To 3 × 10⁶。

In cationic polymer, can more specifically it refer to：

(1) derived from propylene acid esters or methacrylate or acrylamide or Methacrylamide and at least one is included The homopolymer or copolymer of the unit of individual following formula：

Wherein:

-R₃It can be same or different, represent hydrogen atom or CH₃Base；

- A can be same or different, represent 1 to 6 carbon atom, the straight chain of preferably 2 or 3 carbon atoms or The divalent alkyl group of side chain or 1 hydroxyalkyl group to 4 carbon atoms；

-R₄、R₅And R₆, can be same or different, represent alkyl group or benzyl containing 1 to 18 carbon atom Base group, preferably comprises 1 alkyl group to 6 carbon atoms；

-R₁And R₂, it can be same or different, represent hydrogen atom or the alkyl group containing 1 to 6 carbon atoms, It is preferred that methyl or ethyl；

- X represents the anion derived from mineral acid or organic acid, and such as methyl sulfate anions or halide are (for example Chloride or bromide).

The copolymer of family (1) can also contain one or more units derived from comonomer, and the comonomer can With selected from acrylamide, Methacrylamide, DAAM, on nitrogen use (C₁-C₄) alkyl, acrylic acid or its ester or Methacryloxyethyl acid or the acrylamide and Methacrylamide, vinyl lactam (such as ethenyl pyrrolidone of the substitution of its ester Ketone or caprolactam) and vinyl esters family.

In these family (1) copolymers, it can be mentioned that：

- acrylamide and the dimethylaminoethyl second quaternized with Dimethylsulfate or with dimethyl halide The copolymer of ester, the product for example sold by Hercules companies with title Hercofloc,

The copolymer of-acrylamide and methacryloxyethyl trimethyl ammonium chloride, such as it is public by Ciba Geigy Those sold with title Bina Quat P 100 are taken charge of,

The copolymer of-acrylamide and methacryloxyethyl trimethyl methyl ammonium sulfate, such as by Hercules The product that company is sold with title Reten,

- quaternized or on-quaternised vinyl pyrrolidone/dialkyl aminoalkyl acrylates or methacrylic acid Ester copolymer, the product for example sold by ISP companies with title Gafquat, such as Gafquat 734 or Gafquat 755, or Person is referred to as the product of copolymer 845,958 and 937.This is described in detail in French Patent (FRP) 2 077 143 and 2 393 573 A little polymer,

- dimethylaminoethyl methacrylate/caprolactam/vinyl pyrrolidone terpolymer, for example The product sold by ISP companies with Gaffix VC 713,

- vinyl pyrrolidone/methacryiamidopropyl dimethyl amine copolymer, such as by ISP with title Those products that Styleze CC 10 are sold,

- quartenized vinyl base pyrrolidones/dimethylamino-propyl methacrylamide copolymer, for example by ISP companies with The product that title Gafquat HS 100 are sold,

- preferably methacryloxy (C₁-C₄) three (C of alkyl₁-C₄) alkylammonium salt cross-linked polymer, for example by with The polymer of lower acquisition：With the homopolymerization of the quaternized dimethylaminoethyl methacrylate of Methochloride, or pass through acryloyl The amine dimethylaminoethyl methacrylate copolymerization quaternized with using Methochloride, after the homopolymerization or copolymerization, with olefinic Unsaturated compound is crosslinked, and is more specifically crosslinked with methylene-bisacrylamide.Can be more specifically using the acryloyl of crosslinking Amine/methacryloxyethyl trimethyl ammonium chloride copolymer (20/80 weight ratio), to contain 50 weight % in mineral oil The copolymer dispersion form.The dispersion is by Ciba companies with titleSC 92 is sold.Can also Use the crosslinked methacrylic trimethylammonium trimethyl chlorine of the homopolymer containing about 50 weight % in mineral oil or liquid ester Change ammonium homopolymer.These dispersions are by Ciba companies with titleThe Hes of SC 95SC 96 is sold.

(2) cationic polysaccharide, particularly cationic cellulose and galactomannan gum., can be with cationic polysaccharide More specifically refer to the cellulose ether derivative comprising quaternary ammonium group, be grafted with water soluble quaternary ammonium monomer cationic cellulose be total to Polymers or cellulose derivative and cationic galactomannan glue.

The cellulose ether derivative comprising quaternary ammonium group is particularly described in French Patent (FRP) 1492597, and can be carried And by Amerchol companies with title Ucare Polymer " JR " (JR 400LT, JR 125 and JR 30M) or " LR " (LR 400 Or LR 30M) sell polymer.These polymer are also defined as in CTFA dictionaries and replaced with trimethyl ammonium group The quaternary ammonium of epoxide reactive hydroxyethyl cellulose.

The cationic cellulose copolymerization for being grafted with water soluble quaternary ammonium monomer is particularly described in United States Patent (USP) 4 131 576 Thing or cellulose derivative, and it can be mentioned that particularly it is grafted with methylacryloyl ethyl trimethyl ammonium, methacryl (such as hydroxymethyl cellulose, ethoxy are fine for the hydroxy alkyl cellulose of aminocarbonyl propyl trimethyl ammonium or dimethyldiallylammonium salt Dimension element or hydroxypropyl cellulose).The commodity corresponding with this definition are more specifically by National Starch companies with title The product that Celquat L 200 and Celquat H 100 are sold.

Cationic galactomannan glue is more particularly described in United States Patent (USP) 3 589 578 and 4 031 307, and And can be mentioned that the guar gum for including cation trialkyammonium group.It can use for example with 2,3- epoxy ammonium salts (such as chloride) modified guar gum.These products are especially by Rhodia companies with title Jaguar C13S, Jaguar C 15th, Jaguar C 17 or Jaguar C162 are sold.

(3) polymer that the divalent alkyl or hydroxy alkylidene by piperazinyl units and containing straight or branched are formed with And oxidation and/or the quaternized products of these polymer, the polymer optionally by oxygen atom, sulphur atom or nitrogen-atoms interrupt, Or interrupted by aromatic ring or heterocycle.

(4) water-soluble polyaminoamide prepared especially through the polycondensation of acid compound and polyamines；These poly- aminoacyls Amine can be with epihalohydrin, diepoxide, dianhydride, unsaturated dianhydride, double unsaturated derivatives, double halohydrins, dinitrogen heterocycle Butane, double halogenacyl diamines, the crosslinking of double alkyl halides, or with by reactive difunctional compound and pair halohydrins, double Azetidine, double halogenacyl diamines, double alkyl halides, epihalohydrin, diepoxide or double unsaturated derivatives The oligomer crosslinking that reaction is produced；The amount ranges of the crosslinking agent are the amido base of 0.025 to 0.35 mole/polyaminoamide Group；These polyaminoamides can be partially alkylated or alkylated, or if they include one or more tertiary amine functional groups, then they can be with It is quaternized.

(5) the poly- ammonia as obtained from polyalkylene polyamine and polycarboxylic acid are condensed and then be alkylated with bifunctional reagent Yl amide derivatives.It can be mentioned that such as adipic acid/amine polymer of dialkyl amido hydroxyalkyl dialkylene three, wherein alkyl group Comprising 1 to 4 carbon atom, and preferably represent methyl, ethyl or propyl group.In these derivatives, can more specifically it carry And the adipic acid sold by Sandoz companies with title Cartaretine F, F4 or F8/dimethylamino hydroxypropyl/divinyl Three amine polymers.

(6) by making the polyalkylene polyamine comprising two primary amine groups and at least one secondary amine group with being selected from diethylene glycol (DEG) The polymer that the dicarboxyl acid reaction of saturated fat dicarboxylic acids sour and containing 3 to 8 carbon atoms is obtained；Polyalkylene polyamine and Mol ratio between dicarboxylic acids is preferably 0.8:1 and 1.4:Between 1；Gained polyaminoamide and epichlorohydrin with epichlorohydrin relative to The mol ratio of the secondary amine group of polyaminoamide is preferably 0.5:1 to 1.8:1 reaction.For the sub- second of adipic acid/glycidyl/bis- For base triamine copolymer, such polymer is particularly by Hercules Inc. companies with title Hercosett 57 Sell, or sold by Hercules companies with title PD 170 or Delsette 101.

(7) cyclic polymer of cyclopolymers of alkyldiallylamine or dialkyl diallyl amine, such as containing being used as the main of chain The homopolymer or copolymer of the unit for corresponding to formula (I) or formula (II) of composition：

Wherein：

- k and t be equal to 0 or 1, k+t and equal to 1；

-R₁₂Represent hydrogen atom or methyl group；

-R₁₀And R₁₁C1-C6 alkyl groups, hydroxyl (C1-C5) alkyl group, C1-C4 amido alkyls are represented independently of one another Base group；Or R₁₀And R₁₁Can with heterocyclic radical, such as piperidyl or morpholine are represented together with the nitrogen-atoms attached by them Base；R₁₀And R₁₁It is preferred independently of one another to represent C1-C4 alkyl groups；

-Y^-It is anion, such as bromide, chloride, acetate, borate, citrate, tartrate, hydrogen sulfate Salt, bisulfites, sulfate or phosphate.

More specifically it can be mentioned that the dimethyl diallyl for example sold by Nalco companies with title Merquat 100 The homopolymer of ammonium salt (such as chloride), and two allyls especially sold with title Merquat 550 or Merquat 7SPR The copolymer of base dimethyl ammonium (such as chloride) and acrylamide.

(8) season two ammonium (quaternary diammonium) polymer of the repeat unit comprising following formula：

Wherein：

-R₁₃、R₁₄、R₁₅And R₁₆It can be same or different, represent comprising the fatty group 1 to 20 carbon atoms Group, alicyclic group or arylaliphatic moieties, or C1-C12 hydroxy alkyl fatties race group,

Or R₁₃、R₁₄、R₁₅And R₁₆Together or individually, and constitute and optionally wrap together with the nitrogen-atoms attached by them Containing the heteroatomic heterocycle of the second non-nitrogen,

Or R₁₃、R₁₄、R₁₅And R₁₆Represent by nitrile, ester, acyl group, acid amides or-CO-O-R17-D or-CO-NH-R17-D groups Substituted straight or branched C1-C6 alkyl groups, wherein R17 is alkylidene, and D is quaternary ammonium group；

-A₁And B₁Represent saturation or undersaturated divalence polymethylene comprising 2 straight or brancheds to 20 carbon atoms Group, and it can contain one or more aromatic rings or one or more oxygen atoms or sulphur atom or sulfoxide, sulfone, curing (these groups are connected or are inserted in master with main chain for thing, amino, alkyl amino, hydroxyl, quaternary ammonium, urea groups, acid amides or ester group In chain), and

- X- represents the anion derived from mineral acid or organic acid；

It should be appreciated that A₁、R₁₃And R₁₅Piperazine ring can be formed with two nitrogen-atoms attached by them；

If in addition, A₁Straight or branched, saturation or undersaturated alkylidene or hydroxyalkylene group are represented, then B₁ Group (CH can also be represented₂)n-CO-D-OC-(CH₂) n-, wherein D represents：

A) formula-O-Z-O- diol residue, wherein Z represents the hydrocarbyl group of straight or branched or corresponding to one of following formula Group：-(CH₂-CH₂-O)x-CH₂-CH₂- and-[CH₂-CH(CH₃)-O]y-CH₂-CH(CH₃)-, wherein x and y refer to expression definition and 1 to 4 integer of unique degree of polymerization or 1 to the 4 any numeral for representing average degree of polymerization；

B) double secondary diamine residues, such as bridged piperazine derivatives；

C) formula-NH-Y-NH- double primary diamines residues, wherein Y represent straight or branched hydrocarbyl group or divalent group- CH₂-CH₂-S-S-CH₂-CH₂-；

D) formula-NH-CO-NH- urylene (ureylene) group；

Preferably, X^-It is anion, such as chloride or bromide.The mumber average molar mass (Mn) of these polymer is generally For 1000 to 100000.

The polymer being made up of the repeat unit corresponding to following formula can more specifically be referred to：

Wherein, R₁、R₂、R₃And R₄It can be same or different, represent alkyl or hydroxyl containing 1 to 4 carbon atom Alkyl group, n and p are 2 to 20 integer, X^-It is the anion derived from organic acid or mineral acid.

The compound of particularly preferred formula (IV) is wherein R₁、R₂、R₃And R₄Represent methyl group and n=3, p=6 and X =Cl formula (IV) compound, is referred to as extra large U.S. oronain according to INCI (CTFA) nomenclature.

(9) polyquaternary polymers of formula (V) unit are included：

Wherein：

-R₁₈、R₁₉、R₂₀And R₂₁It can be same or different, represent hydrogen atom or methyl, ethyl, propyl group, β-hydroxyl second Base, β-hydroxypropyl or-CH₂CH₂(OCH₂CH₂)_pOH groups, wherein p be equal to 0 or equal to 1 to 6 between integer, condition is R₁₈、 R₁₉、R₂₀And R₂₁Hydrogen atom is asynchronously represented,

- r and s (can be same or different) is the integer between 1 and 6,

- q be equal to 0 or equal to 1 to 34 between integer,

-X^-Expression anion, such as halide,

- A represents dihalide group, or preferably expression-CH₂-CH₂-O-CH₂-CH₂-。

It can be mentioned that example include the product sold by Miranol companiesA15、AD1、AZ1 and175。

(10) quaternary ammonium polymer of vinyl pyrrolidone and vinyl imidazole, such as by BASF AG with titleThe product that FC 905, FC 550 and FC 370 are sold.

(11) polyamines, for example, sold by CognisH, with title polyethylene glycol in CTFA dictionaries (15) tallow polyamines is mentioned.

(12) included in its structure with the polymer of lower unit：

(a) one or more units corresponding to following formula (A)：

(b) optionally, one or more units corresponding to following formula (B)：

In other words, what these polymer can in particular selected from the unit comprising one or more derived from ethylene amine and optionally The homopolymer or copolymer of the unit of one or more derived from ethylene base formamides.

Preferably, these cationic polymers comprising 5 moles of % to 100 moles of % in its structure selected from corresponding to formula (A) unit and the polymer of 0 mole of % to the 95 moles of % unit corresponding to formula (B), preferably 10 moles % to 100 rub Your the % unit and 0 mole of % to the 90 moles of % unit corresponding to formula (B) corresponding to formula (A).

These polymer can be obtained for example by the partial hydrolysis of polyvinyl formamide.The hydrolysis can be in acidity Jie Carried out in matter or alkaline medium.

Weight average molecular weight by the polymer of light scattering measurement can be 1000g/mol to 3000000g/mol, Preferably 10000 to 1000000g/mol, more particularly 100000g/mol to 500000g/mol.

Polymer including formula (A) unit and optional formula (B) unit is especially gone out by BASF AG with title Lupamin Sell, for example, and in a non-limiting manner, with title Lupamin 9095, Lupamin 5095, Lupamin 1095, The product that Lupamin 9030 (or Luviquat 9030) and Lupamin 9010 is sold.

In the context of the present invention workable other cationic polymers be cationic protein or cationic protein hydrolysate, Polyalkyleneimine (particularly polyethyleneimine), polymer, polyamines comprising vinylpyridine or vinylpyridine salt unit Condensation product, quaternized poly- urylene (quaternary polyureylene) and chitin derivative with epichlorohydrin.

Preferably, cationic polymer is selected from the polymer of above-mentioned family (1), (2), (7) and (10).

In above-mentioned cationic polymer it is preferable to use cationic polymer be cationic polysaccharide, particularly sun Ion fiber element and galactomannan gum, particularly quaternized cellulose ethers derivative, such as by Amerchol companies with name The product for claiming " JR400 " to sell；Cation ring polymers, particularly by Nalco companies with title Merquat 100, Merquat The homopolymer or copolymer for the dimethyldiallylammonium salt (such as chloride) that 550 and Merquat S are sold；Vinyl pyrrole The quaternary ammonium polymer of alkanone and vinyl imidazole, optionally methacryloxy (C₁-C₄) three (C of alkyl₁-C₄) alkylammonium The homopolymer or copolymer of the crosslinking of salt, and its mixture.

Amphiphilic polymers can also be used, it can be preferably chosen from including the amphiphilic polymers of following repetition：

(i) one or more units for being derived from (methyl) acrylamide monomers,

(ii) one or more units for being derived from (methyl) acrylamido alkyl trialkyl ammonium type monomer,

(iii) one or more units for being derived from (methyl) acrylic type acid monomer.

Preferably, the unit (i) of the monomer derived from (methyl) acid/acrylic amide type is following structure (Ia) unit：

Wherein, R₁Represent H or CH₃, and R₂Selected from amino, dimethylamino, tert-butylamino, lauryl amino or-NH- CH₂OH groups.

Preferably, the amphiphilic polymers include the repetition of only one formula (Ia) unit.

Derived from wherein R₁Represent H and R₂It is amino group (NH₂) formula (Ia) (methyl) acrylamide monomers list Member is particularly preferred.It corresponds to acrylamide monomer in itself.

Preferably, the unit (ii) of the monomer derived from (methyl) acrylamido alkyl trialkyl ammonium type is following structure (IIa) unit：

Wherein：

-R₃Represent H or CH₃,

-R₄Represent group (CH₂) k, wherein k is 1 to 6, preferably 2 to 4 integer；

-R₅、R₆And R₇Can be same or different, expression contains 1 alkyl group to 4 carbon atoms；

Preferably, the amphiphilic polymers include the repetition of only one formula (IIa) unit.

In these units of (methyl) acrylamido alkyl trialkyl ammonium type monomer derived from formula (IIa), preferably Unit be those units derived from methacryiamidopropyl trimethyl ammonium chloride monomer, wherein R₃Represent methyl, k etc. In 3, R₅、R₆And R₇Represent methyl group, Y^-Represent chloride anion.

Preferably, the unit (iii) of the monomer derived from (methyl) acrylic type is formula (IIIa) unit：

Wherein, R₈Represent H or CH₃, R₉Represent oh group or-NH-C (CH₃)₂-CH₂-SO₃H groups.

It is preferred that formula (IIIa) unit correspond to acrylic acid, methacrylic acid and 2- acrylamide-2-methylpro panesulfonic acids Monomer.

Preferably, the unit of (methyl) acrylic monomer derived from formula (IIIa) is the unit of derived from propylene acid, Wherein R₈Represent hydrogen atom and R₉Represent oh group.

The acid monomer of (methyl) acrylic type can be unneutralized or partially or completely with organic base or mineral alkali The monomer of sum.

Preferably, the amphiphilic polymers include the repetition of only one formula (IIIa) unit.

According to the preferred embodiment of the present invention, such amphiphilic polymers being derived from comprising at least 30 moles % The unit (i) of (methyl) acrylamide monomers.Preferably, they rub comprising 30 moles of % to 70 moles of %, more preferably 40 Your % to the 60 moles of % unit derived from (methyl) acrylamide monomers.

The content of unit (ii) derived from (methyl) acrylamido alkyl trialkyl ammonium type monomer can be advantageously 10 moles of % to 60 moles of %, it is therefore preferable to 20 moles of % to 55 moles of %.

The content of the unit (iii) of acid monomer derived from (methyl) acrylic type can be advantageously 1 mole of % extremely 20 moles of % and preferably 5 moles % to 15 moles of %.

According to the particularly preferred embodiment of the present invention, such amphiphilic polymers include：

% to 60 moles of %'s of -30 moles of % to 70 moles of %, more preferably 40 moles is derived from (methyl) acrylamide The unit (i) of the monomer of type,

% to 55 moles of %'s of -10 moles of % to 60 moles of %, preferably 20 moles is derived from (methyl) acrylamido alkane The unit (ii) of the monomer of base trialkyl ammonium type, and

% to 15 moles of % of -1 mole of % to 20 moles of %, the preferably 5 moles monomer derived from (methyl) acrylic type Unit (iii).

Such amphiphilic polymers can also include except as described above derived from (methyl) acrylamide monomers, Other unit outside the unit of (methyl) acrylamido alkyl trialkyl ammonium type monomer and (methyl) acrylic monomer.

However, according to the preferred embodiment of the present invention, the amphiphilic polymers are only by derived from (methyl) acrylamide The unit (i) of type monomer, the unit (ii) derived from (methyl) acrylamido alkyl trialkyl ammonium type monomer and derived from (first Base) acrylic monomer unit (iii) constitute.

As the example of particularly preferred amphiphilic polymers, it can be mentioned that acrylamide/Methacrylamide propyl group front three Ammonium chloride/acrylic ternary copolymer.This polymer is listed in CTFA with title polyquaternium (Polyquaternium) 53 In dictionary (international cosmetic ingredient dictionary).Corresponding product is especially by Nalco companies with the Hes of title Merquat 2003 Merquat 2003PR are sold.

As the another type of amphiphilic polymers that can be used, it can also refer to and be based on (methyl) acrylic acid and dioxane The copolymer of the copolymer, such as (methyl) acrylic acid and dimethyl diallyl ammonium chloride of base diallyl ammonium salt.It may carry And an example be the Merquat 280 sold by Nalco companies.

Gross weight preferably relative to composition can be included with 0.01 weight % to 0.5 according to the composition of the present invention The cationic polymer and/or amphiphilic polymers of weight % amount.

Polyalcohol

For the purposes of the present invention, term " polyol " is understood to include any of at least two free hydroxyl radicals and had Machine molecule.

According to the present invention composition can include relative to composition gross weight for 0.1 weight % to 20 weight %, It is preferred that one or more polyalcohols of the 1 weight % to 15 weight %.

Suitable for the present invention polyalcohol can be such as on alkyl chain have at least two-OH functional groups, particularly The saturation or undersaturated, straight chain of at least three-OH functional groups, more particularly at least four-OH functional groups, side chain or ring-type The compound of alkyl.

The polyalcohol for being advantageously applied to the formula of the frothing cleaning composition according to the present invention is that especially have 2 to 16 Individual carbon atom, preferably 3 polyalcohols to 8 carbon atoms.

In polyalcohol, it can enumerate following：Glycerine, sorbierite, 1,3- propane diols, isoprene, pentanediol, hexylene glycol, Glycerine, glycols (such as ethylene glycol, propane diols, butanediol, pentanediol, diethylene glycol, decanediol, ethohexadiol), poly- second two Alcohol (such as PEG-8), polyglycereol (such as glycerin oligomer, such as diglycerol), erythrite, arabite, ribitol, sorb Alcohol, galactitol, glucose, fructose, xylose, trehalose, sucrose (sucrose), maltose, sucrose (saccharose) and breast Sugar, and its mixture.

According to preferred embodiment, following polyalcohol can be used：Glycerine, sorbierite, propane diols, decanediol, pungent two Alcohol, butanediol, pentanediol, polyethylene glycol and its mixture.

According to the embodiment of the present invention, polyalcohol is not the polymer with repeat unit.

According to particularly preferred embodiment, polyalcohol comprises at least sorbierite.

In entire disclosure, including claims, unless otherwise stated, should will statement " including one " be interpreted as With " including at least one " synonymous.

Unless otherwise stated, statement " ... and ... between " and " scope from ... to ... " be understood to refer to Include end value.

The following examples explanation is of the invention and does not limit its scope.

The Cleasing compositions described in following examples are prepared using following conventional method：

In primary tank situ formation soap at 1.75-80 DEG C, and start mixing under the low speed to be dissolved in the water.

2. preservative, chelating agent and polyalcohol are added into primary tank.

3. Tackified polymeric disperses at high speeds, the temperature of primary tank is kept to be more than 80 DEG C.

4. add surfactant at 45 to 65 DEG C.

5. in the case of acrylate based polyalcohol and GHTC, polymer is dispersed in water and later at room temperature Stage neutralizes.

The amount of composition is represented with active material percetage by weight " wgt% " in the examples below.

Embodiment 1：The selection of Tackified polymeric

With following different polymer preparation of preparation.In following examples, the mol ratio of aliphatic acid and triethanolamine is 1:1.3。

Attempt following polymer：

1. the Methocel K15M sold by Dow Chemical：Hydroxypropyl methyl cellulose

2. the Natrosol 250HHR sold by Hashland：Hydroxyethyl cellulose

3. the Carbopol ultrez 20 sold by Lubrizol：Acrylate/C10-30 alkyl acrylates crosslinking Polymer

4. the Carbopol ETD 2020 sold by Lubrizol：Acrylate/C10-30 alkyl acrylates crosslinking is poly- Compound

5. the Keltrol CG-T sold by CP Kelco：Xanthans

6. the Jaguar C13-S sold by Solvay：Guar hydroxypropyltrimonium ammonium chloride (GHTC)

7. the Benecel K100M sold by Ashland：Hydroxypropyl content is 7%-12% and methoxyl content is 20%-24% hydroxypropyl methyl cellulose, viscosity is that 75,000mPas to 140,000mPas (such as passes through The viscosity of 2% aqueous solution of Brookfiled (rotation) viscosity meter)

In the following table, " comp " refers to composition outside the scope of the present invention, and " inv " refers to corresponding composition explanation Invention claimed.

Table 1：

Table 2:

Result is " to test 1 " and " composition of experiment 7 " all meets transparency requirement.For viscosity, result is " experiment 7 " show bigger viscosity number, therefore constitute the preferred embodiment of the present invention.

Embodiment 2：The implementation of a variety of polyalcohols

Table 3:

1% propane diols is kept to dissolve p-hydroxybenzoate in all experiments.

The composition of all tests is all transparent and stable.

Embodiment 3：A variety of mol ratios between aliphatic acid and nertralizer

The combination of C12 fatty acid soaps and C14 fatty acid soaps produces the required creaminess foam with enough foam volumes.

As described below, prepared and be formulated with the aliphatic acid and triethanolamine of different mol ratio.

Table 4:

Table 5:

In the formulation composition of the present invention, when the mol ratio between aliphatic acid and triethanolamine is 1:When 1.8 or higher, Gratifying result is given in terms of transparency.

Embodiment 4：Utilize the composition according to the present invention

It will be applied to according to the composition of embodiment 2 on the moistening skin of face.Then, foamed and rinsed with water.

After washing, skin is all clean and moistening in all cases.

Claims

1. a kind of transparent cleaning fluid composition, the following material containing acceptable aqueous medium in a physiologically：

- at least soap,

- at least one foaming surfactant,

- at least organic neutralizer, the organic neutralizer is with least 1:1.75th, preferably at least 1:1.8 soap with it is described it is organic in Mol ratio between agent and exist, and

Wherein, the composition has from 8 to 9, preferably from 8 to 8.5 pH.

2. composition according to claim 1, wherein, relative to the gross weight of the composition, the soap is with 2 weight % To 7 weight %, particularly 3 weight % to 6 weight %, most preferably 4 weight % to 5 weight % amount are present in the composition In.

3. composition according to claim 1 or 2, wherein, the soap is that have 10 to 22 carbon atoms, more preferably 12 Individual to 18 carbon atoms, organic soaps of most preferably 12 aliphatic acid to 14 carbon atoms.

4. composition according to any one of the preceding claims, wherein, the aliphatic acid be selected from caproic acid, capric acid, octanoic acid, Oleic acid, linoleic acid, laurate, myristic acid, stearic acid, palmitic acid and its mixture.

5. composition according to any one of the preceding claims, wherein, the mol ratio between aliphatic acid and nertralizer is 1:1.75 to 1:3, particularly 1:1.8 to 1:2.5.

6. composition according to any one of the preceding claims, wherein, the hydroxyl (C₁-C₆) alkyl (C₁-C₆) alkyl Cellulose is hydroxyl (C₁-C₄) alkyl (C₁-C₄) alkylcellulose, and more specifically it is selected from methylol-butyl cellulose, hydroxyl second Ylmethyl cellulose, ethoxy butyl cellulose and hydroxypropyl methyl cellulose and its mixture.

7. composition according to any one of the preceding claims, wherein, when the Tackified polymeric is dense with 2% weight When degree is present in the aqueous solution, the viscosity of the Tackified polymeric changes between 75000Pas and 140000Pas.

8. composition according to any one of the preceding claims, wherein, cellulose ether is hydroxypropyl methyl cellulose, and And especially, relative to the gross weight of hydroxypropyl methyl cellulose, the cellulose ether has 7 weight % to 12 weight % hydroxyl Propyl group content, and the methoxyl content with 20 weight % to 24 weight %.

9. composition according to any one of the preceding claims, wherein, it is described relative to the gross weight of the composition Tackified polymeric is with 0.2 weight % to 6 weight %, especially 0.5 weight % to 5 weight %, more particularly 0.8 weight % is extremely 1.2 weight % amount is present in the composition.

10. composition according to any one of the preceding claims, wherein, the composition is comprising at least one selected from the moon Ion foaming surfactant, both sexes (or amphion) foaming surfactant, nonionic lather surfactants and/or sun The foaming surfactant of ion foaming surfactant and its mixture, the anion surfactant is in particular selected from alkyl Sulfate, alkyl ether sulfate, alkyl amido ether sulfates, alkyl aryl polyether sulfate, single glycerine sulfate, alkyl sulphur Hydrochlorate or alpha-alkene sulfonate, alkylamide sulfonates, alkylaryl sulfonates, alkane sulfonate, alkyl sulfosuccinic Ester, alkyl ether sulfosuccinates, alkylamide sulfosuccinate, alkyl sulfoacetate, acyl sarcosinates, acyl group paddy Propylhomoserin salt, alkyl sulfo succinate, acyl isethinate and N- acyl taurine salts, alkyl monoester and many glucosides polycarboxylic acids Salt, acyl lactate, N- acylglycines salt, the salt of D- galactosides-uronic acid, the salt of alkyl ether carboxylic acid, alkyl Aryl ether carboxylate, the salt of alkylamidoalkyl ether carboxylic acid, sulfosalicylic acetate, pair of sulfolauric acid salt and all these compounds The salt-independent shape answered, the both sexes or zwitterionic surfactant are in particular selected from (C₈-C₂₀) alkyl betaine, sulfobetaines Alkali, (C₈-C₂₀) alkyl sulfo betaines, (C₈-C₂₀) alkylamidoalkyl (C₁-C₆) alkyl betaine, (C₈-C₂₀) alkylamidoalkyl (C₁-C₆) alkyl sulfo betaines, (C₈-C₂₀) alkylamphoacetate, (C₈-C₂₀) alkyl both sexes base diacetin and its mixed Compound, and the nonionic surfactant is in particular selected from alkyl polyglucoside, and the cationic surfactant is special Xuan Zi not optionally polyoxyalkylenated primary aliphatic amine salt, secondary fatty amine salt or tertiary fatty amine salt, quaternary ammonium salt, imidazoline quaternary ammonium Salt, season di-ammonium salts or the ammonium salt of season three, quaternary ammonium salt and its mixture containing one or more ester functional groups.

11. composition according to any one of the preceding claims, wherein, the foaming surfactant is at least containing the moon Ionic surface active agent, and in particular selected from (C₆-C₂₄) alkyl sulfate；(C₆-C₂₄) alkyl ether sulfate, such as lauryl ether sulphur Sour sodium；Isethionate；Amino acid, particularly glycinate, such as N- cocoyls Sodium Glycinate；Their basic salt；And Its mixture.

12. composition according to any one of the preceding claims, wherein, relative to the gross weight of the composition, institute Foaming surfactant is stated with 0.5 weight % to 10 weight %, particularly 2 weight % to 8 weight %, more particularly 3 weight % Amount to 6 weight % is present in the composition.

13. composition according to any one of the preceding claims, wherein, the organic neutralizer is selected from amino alcohol, example Such as monoethanolamine, amino sugar, amino acid and its basic salt.

14. composition according to any one of the preceding claims, wherein, the composition also includes polyalcohol, for example Glycerine, sorbierite, propane diols, decanediol, ethohexadiol, butanediol, pentanediol, polyethylene glycol and its mixture.

15. composition according to any one of the preceding claims, wherein, the viscosity that the composition is presented is 0.1Pas to 3Pas, especially 0.2Pas to 2Pas, more particularly 0.3Pas to 1.3Pas.

16. a kind of method for cleaning keratin material, methods described includes applying according to foregoing to the keratin material Composition any one of claim, finally using water, then rinses to eliminate foam and dirt with water.