CN107106460A - Waterborne compositions for making rhacoma - Google Patents

Waterborne compositions for making rhacoma Download PDF

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Publication number
CN107106460A
CN107106460A CN201480084378.2A CN201480084378A CN107106460A CN 107106460 A CN107106460 A CN 107106460A CN 201480084378 A CN201480084378 A CN 201480084378A CN 107106460 A CN107106460 A CN 107106460A
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CN
China
Prior art keywords
weight
composition
cellulose gum
aqueous solution
cps
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Pending
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CN201480084378.2A
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Chinese (zh)
Inventor
邓毅
L.柯
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
LOreal SA
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LOreal SA
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Publication of CN107106460A publication Critical patent/CN107106460A/en
Pending legal-status Critical Current

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Classifications

    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61QSPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q19/00Preparations for care of the skin
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/73Polysaccharides
    • A61K8/731Cellulose; Quaternized cellulose derivatives
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K2800/00Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
    • A61K2800/20Chemical, physico-chemical or functional or structural properties of the composition as a whole
    • A61K2800/28Rubbing or scrubbing compositions; Peeling or abrasive compositions; Containing exfoliants
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K2800/00Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
    • A61K2800/40Chemical, physico-chemical or functional or structural properties of particular ingredients
    • A61K2800/59Mixtures
    • A61K2800/592Mixtures of compounds complementing their respective functions
    • A61K2800/5922At least two compounds being classified in the same subclass of A61K8/18

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  • Health & Medical Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Animal Behavior & Ethology (AREA)
  • General Health & Medical Sciences (AREA)
  • Public Health (AREA)
  • Veterinary Medicine (AREA)
  • Birds (AREA)
  • Epidemiology (AREA)
  • Dermatology (AREA)
  • Cosmetics (AREA)

Abstract

There is provided waterborne compositions and application thereof.The waterborne compositions include a) at least one cellulose gum, when it is dissolved in the 1% w/w aqueous solution, the viscosity with 1,000 ~ 2,800 cps;B) at least one cellulose gum, when it is dissolved in the 2% w/w aqueous solution, the viscosity with 200 ~ 800 cps;And c) at least one cellulose gum, when it is dissolved in the 2% w/w aqueous solution, the viscosity with 25 ~ 50 cps.

Description

Waterborne compositions for making rhacoma
The present invention relates to composition, especially cosmetic composition is preferably used as the cosmetic skin of excoriation facial mask Care composition.Make the beauty method that skin surface comes off the invention further relates to the cosmetic composition using the present invention.
Numerous cosmetic products for making rhacoma are commercially available.These products are usually contained Excoriation particle, the particle is scattered in the medium for allowing them to keep suspension, such as gel, emulsion, anhydrous gel Oil or cream.
These products make it possible to perform the cosmetic treatments to skin, including peeling(peeling).However, they are not It is entirely satisfactory.
Especially, scattered in cosmetic product of excoriation particle need not be uniform, long period of storage it It is especially true afterwards.Therefore cosmetic product may include the region without particle, and this significantly limit its effect.On the contrary, cosmetics Some regions of product can include too many excoriation particle, and this causes obvious stimulation after being contacted with skin.
In addition, the excoriation effect of cosmetic product may be unsatisfactory.Consumer has found, is difficult to after scrubbing Discover excoriation object, i.e. occur without excoriation object after scrubbing or small excoriation object occur.Also It is possible that making the rhacoma needs relatively long scouring time, such as more than 5 minutes.
For " excoriation object ", it represents solid filament, such as " noodles(noodles)", by its When cleaning on skin, it can provide excoriation and/or cleaning effect(Such as peeling and/or cleaning skin), so that going Cosmetics nursing is provided except dead skin and/or for skin.
Preferably, the dirt on dead skin and/or skin can be mixed with cosmetic composition, to form excoriation object.
Therefore it there is demand for the composition with improved excoriation performance.
It is an object of the invention to obtain composition, the especially cosmetic composition with improved excoriation performance, The formation speed of the excoriation performance such as excoriation object, it is easy to rinse.
It is a further object to provide the improved cosmetic treatments to skin, such as cleaning, comfortable and hydration.
According to an aspect of the present invention, the present composition is waterborne compositions, and it is included:
A) at least one cellulose gum, it is viscous with 1,000 ~ 2,800 cps when it is dissolved in the 1% w/w aqueous solution Degree;
B) at least one cellulose gum, when it is dissolved in the 2% w/w aqueous solution, the viscosity with 200 ~ 800 cps;With
C) at least one cellulose gum, when it is dissolved in the 2% w/w aqueous solution, the viscosity with 25 ~ 50 cps.
For " waterborne compositions ", it refers to the main composition for including water.It can be the aqueous solution, water-in-oil emulsion, Aqueous dispersion, frost, washing lotion or the gel of oil-in-water emulsion, solid particle in aqueous phase.
Preferably, the present composition is the aqueous solution.
Cellulose gum
Cellulose gum (also referred to as carboxymethyl cellulose (CMC)) is cellulose derivative, and it has with constituting cellulosic backbone The carboxymethyl group (- CH of some hydroxy combinings of glucopyra sugar monomer2-COOH)。
Preferably, cellulose gum is carboxymethyl cellulose, more preferably sodium carboxymethylcellulose.
Sodium carboxymethylcellulose is the sodium salt of the poly- carboxymethyl ester of cellulose.
According to the present invention, have is for the cellulose gum of the present composition:
A) when it is dissolved in the 1% w/w aqueous solution, viscosity is 1,000 ~ 2,800 cps cellulose gum;
B) when it is dissolved in the 2% w/w aqueous solution, viscosity is 200 ~ 800 cps cellulose gum;With
C) when it is dissolved in the 2% w/w aqueous solution, viscosity is 25 ~ 50 cps cellulose gum.
At 25 DEG C, the viscosity of cellulose gum is measured with the rotation viscometer provided by Brookfield companies.
First, determined using " determination of moisture " method provided by Ashland companies for measuring the viscous of cellulose gum The debita spissitudo of degree.Then the aqueous solution of cellulose gum is prepared according to the debita spissitudo.Then the aqueous solution is placed on viscosity On meter.Viscosity is reported by viscosimeter within 3 minutes after rotation.
Measure the viscosity of cellulose gum in form of an aqueous solutions.It means that the molecule of cellulose gum turns into water Solvate.Just " the X% w/w cellulose gum aqueous solution ", it represents the gross weight meter relative to the solution, includes X weight % The aqueous solution of cellulose gum (dry).
According to a kind of embodiment, the cellulose gum used in the present invention exists or with the aqueous solution in the form of dry Form is present.
On cellulose gum a), the AQUALON from ASHLAND can be used CMC 7H3SXF。
On cellulose gum b), the BLANOSE CMC 7M8SF from ASHLAND can be used.
On cellulose gum c), the BLANOSE CMC 7LF from ASHLAND can be used.
According to preferred embodiment, relative to the gross weight meter of composition, the presence of cellulose gum a) in the composition Measure as the weight % of 0.1 weight % ~ 5.0, the weight % of preferably 0.1 weight % ~ 2.0 weight %, more preferably 0.1 weight % ~ 1.0.
According to preferred embodiment, relative to the gross weight meter of composition, the presence of cellulose gum b) in the composition Measure as the weight % of 0.5 weight % ~ 5.0, the weight % of preferably 0.5 weight % ~ 2.5.
According to preferred embodiment, relative to the gross weight meter of composition, the presence of cellulose gum c) in the composition Measure as the weight % of 0.5 weight % ~ 5.0, the weight % of preferably 1.0 weight % ~ 3.0.
According to particularly preferred embodiment, by based on the weight of the gross weight of composition, of the invention aqueous group Compound is included:
A) 0.1% ~ 2.0% cellulose gum, it is viscous with 1,000 ~ 2,800 cps when it is dissolved in the 1% w/w aqueous solution Degree;
B) 0.5% ~ 2.5% cellulose gum, when it is dissolved in the 2% w/w aqueous solution, the viscosity with 200 ~ 800 cps;With
C) 1.0% ~ 3.0% cellulose gum, when it is dissolved in the 2% w/w aqueous solution, the viscosity with 25 ~ 50 cps.
Inventor have observed that, the combinations of three kinds of cellulose gums of the invention on skin is applied the composition to it Afterwards, excoriation object can be formed.
More specifically, inventor have observed that, the cosmetic composition of the combination comprising three kinds of cellulose gums allows Excoriation object needed for being formed, that is to say, that a certain amount of excoriation object, it holds when being swabbed on skin Easily perceived by user or consumer, and the excoriation object is easily from the surface separation or removal of skin, and be not adhere to On skin.
More specifically, the inventors discovered that, such cosmetic composition allows after said composition is applied, and skin is arrived when cleaning When on skin, excoriation object is formed in the rational period.More preferably after the cosmetic composition of the present invention is applied, Occurs excoriation object immediately after cleaning onto skin.
When the present inventor has also been observed that the combination according to above-mentioned preferred amounts use cellulose gum of the present invention, Within the appropriate time, excoriation object is obtained with appropriate form and appropriate amount, so that can be by cleaning on skin To carry out optimizing excoriation cosmetic treatments.
Preferably, after applying the composition on skin, when cleaning onto skin, within 3 minutes(It is preferred that 1 Within minute, more preferably immediately)Form excoriation object.
Preferably, excoriation object is in the shape of noodles.For " noodles ", it is represented by using observing Examine the solid filament easily discovered.In addition, the filament is easily separated or removed from skin, without any tacky sensation.
Aqueous phase
The waterborne compositions of the present invention include aqueous phase, and the aqueous phase includes water.
According to a kind of embodiment, relative to the gross weight meter of the composition, according to the composition of the present invention comprising extremely Few 50 weight % water.The total amount for the water that this amount of water corresponds in composition.
According to a kind of embodiment, relative to the gross weight meter of the composition, according to the composition of the present invention comprising extremely Few 50 weight %, preferably at least 60 weight % water, especially comprising 60 weight % ~ 90 weight %, more specifically 60 weight % ~ 85 weight % Water.
More specifically, waterborne compositions of the invention are the aqueous solution.
For " aqueous solution ", it represents that dry ingredients present in composition turn into solvate in the composition.
According to the composition of the present invention can also comprising one or more of miscible organic solvents (environment temperature- At 25 DEG C), for example:
- the monohydric alcohol with 2 ~ 6 carbon atoms, such as ethanol and isopropanol;
- there are 2 ~ 20 carbon atoms(It is preferred that with 2 ~ 10 carbon atoms, preferably with 2 ~ 6 carbon atoms)Polyalcohol, for example Glycerine, propane diols, butanediol, pentanediol, hexylene glycol, pungent ethylene glycol(caprylylglycol), dipropylene glycol and two sweet Alcohol;
- the glycol ethers especially with 3 ~ 24 carbon atoms, such as propylene glycol alkyl (C1-C4) ether, dipropylene glycol alkyl (C1-C4) ether or tripropylene glycol alkyl (C1-C4) ether, ethylene glycol alkyl (C1-C4) ether, diethylene glycol (DEG) alkyl (C1-C4) ether or three Glycol alkyl (C1-C4) ether and with 2 ~ 12 ethylene oxide units(Such as 8 ethylene oxide units)Polyethylene glycol; And
- its mixture.
According to preferred embodiment, according to the composition of the present invention is comprising water, glycerine, ethanol, polyethylene glycol or it is mixed Compound.
Relative to the gross weight meter of composition, the present composition preferably comprises the weight % of 0.1 weight % ~ 20.0, more preferably The weight % of 1.0 weight % ~ 15.0 weight %, especially 5.0 weight % ~ 10.0 one or more of miscible organic solvents.
Active material
According to a kind of embodiment, according to the composition of the present invention further comprising at least one active component, it is preferably selected from protecting Humectant, consolidant, cleaning agent and/or antidotal agent.
The active component for being suitable for the present composition is preferably water miscible or hydrophilic.
For " water solubility ", it is represented at room temperature, active by based on the weight of the gross weight of the aqueous solution The solubility of composition in aqueous is more than or equal to 1%, preferably greater than or equal to 5%.
It is highly preferred that using NMF in the compositions of the present invention.
Preferably, using NMF (also referred to as wetting agent).
This active component is such as royal jelly, and it is the pharyngeal secretion thing of worker bee, is had by Chinese Medicine health industry share Limit company(China Meheco Corporation), sold with title royal jelly freeze-dried powder;Or the polysaccharide fractions derived from mushroom, For example from white fungus(Tremella fuciformis), it is miscellaneous with title white fungus by Shanghai Huwen Biotech companies Polysaccharide(Tremella Heteropolysaccharide)WSK is sold.
Those skilled in the art can by routine operation come adjust be present according to the present invention composition in activity into Point type and amount so that the influence of cosmetics performance and performance for stability sought by these compositions not receptor 1 activity composition.
Inventor have observed that, effective excoriation effect is attributed to, the present composition advantageouslys allow for living Property composition(When there are these active materials)More effectively penetrate into skin.
According to a kind of embodiment, these active components are cosmetic active substances, and without therapeutic effect.
Additive
According to the composition of the present invention also can further include generally in discussion field(Especially in the cosmetics for skin In composition)Any additive used, is selected from other natural gum, resin, dispersant, polymer in addition, anti-oxidant Agent, preservative, aromatic, chelating agent, nertralizer, antiseptic(antiseptic agents), anti-UV protective agents and its mixing Thing.
Those skilled in the art can adjust the additive being present in the composition according to the present invention by routine operation Type and amount so that the cosmetics performance and performance for stability sought by these compositions are not influenceed by additive.
Using
According to another aspect of the present invention, the invention further relates to cosmetic composition, it is in a physiologically in acceptable medium Include the combination of three kinds of cellulose gums defined above.
Term " physiologically acceptable medium " is intended to expression and is especially suitable for the present composition being applied to skin The medium of skin or lip.
Physiologically acceptable medium, which is generally suitable for use in, should apply composition the property of carrier thereon, and also fit Share in the mode for wherein packing composition.
Preferably, cosmetic composition of the invention is intended to nursing skin, especially cleaning skin and/or takes off epiderm skin Fall, for example, be applied on skin, and be swabbed after few minutes.
The cosmetic composition of the present invention is especially intended to remove the peel and/or clean the skin of user, thus remove dead skin with/ Or offer is nursed to the cosmetics of skin.
The cosmetic composition of the present invention can face or body processing.
In one embodiment, cosmetic composition is that facial mask applies some make up composition, and the facial mask is, for example, to be used for The facial mask of cleaning skin and/or the facial mask for making rhacoma, are preferred for making the facial mask of rhacoma, i.e. It is intended to be applied to face, in order to make rhacoma and/or cleaning skin, preferably makes the composition of rhacoma.
Preferably, it is the form of frost, washing lotion or gel, more particularly gel according to the composition of the present invention.
At 25 DEG C, the M3 axles with the viscosity for being adapted to gel to be tested are used(spindle M3)ProRheo R180 machines (by PRORHEO is sold) come measure according to the present invention gel viscosity.
Rotor selection for 20 UD ~ 80 UD (UD=unit deviation) measure, revolved inside gel making rotor Measured after turning 10 minutes, wherein shear rate is from 200 s-1Rise.Then it can be used corresponding table that UD values are scaled into pool (1 Moor=0.1 Pa.s).
Preferably, as according to measured by methods defined above, it is less than or waits according to the viscosity of the gel of the present invention In 80 UD.
It is highly preferred that according to a kind of embodiment, as according to measured by methods defined above, being coagulated according to of the invention The viscosity of glue is the UD of 40 UD ~ 50.
The invention further relates to non-therapeutic method, it includes the composition application to skin according to the present invention by least one layer On.
According to another aspect of the present invention, the present invention relates to for cleaning skin and/or control the non-of rhacoma The property treated method, it comprises the following steps:
- will be applied to according to the waterborne compositions of the present invention at least one region of skin,
- cosmetic composition is retained on skin at least 1 minute, the period of preferably 3 minutes ~ 15 minutes,
- cosmetic composition is cleaned from skin, and
- optionally, rinse out cosmetic composition.
According on the other hand, the invention further relates to combination of the following material in waterborne compositions for taking off epiderm skin The purposes fallen:
A) at least one cellulose gum, it is viscous with 1,000 ~ 2,800 cps when it is dissolved in the 1% w/w aqueous solution Degree;
B) at least one cellulose gum, when it is dissolved in the 2% w/w aqueous solution, the viscosity with 200 ~ 800 cps;With
C) at least one cellulose gum, when it is dissolved in the 2% w/w aqueous solution, the viscosity with 25 ~ 50 cps.
Embodiment
1. according to the preparation of the composition of the present invention
The composition (composition A and composition B) according to the present invention is prepared according to consisting of:
Composition A and B are the gel masks for face.
Them are prepared according to following steps:At 70 DEG C, cellulose gum is mixed into water one by one, then to mixing Tremella polysaccharides is added in thing;Then dihydric alcohol (polyethylene glycol, 1,3-BDO and glycerine) is added into mixture, then will be mixed Compound is cooled to 40 DEG C, adds ethanol and royal jelly.
2. with making the method for rhacoma according to the composition of embodiment 1
The composition of embodiment 1 is applied to the face of user with the thick layers of 1mm respectively.
Composition layer is set to be retained in respectively on skin 10 minutes, without touching.
After 10 minutes, the excoriation object about 1 minute formed on skin is wiped, excoriation is provided for skin Cosmetic result.
Then excoriation object is rinsed out with water.
3. according to the evaluation of the excoriation performance of the composition of embodiment 1
Evaluate the excoriation performance of the composition in embodiment 1.According to the method in embodiment 2, carried out in 5 consumers Evaluate.
Evaluated by consumer epidermis cast body formed speed and apply after sensation (provide 1 ~ 5 scoring:When When scoring is less than 3, it is regarded as unacceptable;And when scoring is greater than or equal to 3, it is regarded as acceptable).
As a result it is as follows:
Attribute Composition A Composition B
The formation speed of excoriation object Occur after cleaning 5 minutes Occur immediately during scouring
Rinse easness 3.5 3.6
Skin cleannes 4.0 4.4
Skin comfort degree 3.5 3.8
Skin hydration 3.0 3.4
It was observed that, according to the present invention composition A and B be excoriation facial mask, its 4 DEG C, room temperature (20 DEG C -25 DEG C) and Stablize at 45 DEG C 2 months.
The inventors discovered that, according to the evaluation made by consumer, comparing A and B has improved exfoliative Can, the formation speed of such as excoriation object rinses easness.
Composition A and B allow the improved cosmetic treatments to skin, such as cleaning, comfortable and hydration.

Claims (16)

1. waterborne compositions, it is included:
A) at least one cellulose gum, it is viscous with 1,000 ~ 2,800 cps when it is dissolved in the 1% w/w aqueous solution Degree;
B) at least one cellulose gum, when it is dissolved in the 2% w/w aqueous solution, the viscosity with 200 ~ 800 cps;With
C) at least one cellulose gum, when it is dissolved in the 2% w/w aqueous solution, the viscosity with 25 ~ 50 cps.
2. composition according to claim 1, wherein the cellulose gum is carboxymethyl cellulose, preferred carboxymethyl cellulose Plain sodium.
3. the composition according to any one of claim 1 or 2, wherein relative to the gross weight meter of the composition, institute It is the weight % of 0.1 weight % ~ 5.0 to state cellulose gum a) amount, the weight % of preferably 0.1 weight % ~ 2.0, more preferably 0.1 weight Measure the weight % of % ~ 1.0.
4. the composition according to any one of claim 1 ~ 3, wherein relative to the gross weight meter of the composition, it is described Cellulose gum b) amount is the weight % of 0.5 weight % ~ 5.0 weight %, preferably 5 weight % ~ 2.5.
5. the composition according to any one of claim 1 ~ 4, wherein relative to the gross weight meter of the composition, it is described Cellulose gum c) amount is the weight % of 0.5 weight % ~ 5.0 weight %, preferably 1 weight % ~ 3.
6. the composition according to any one of preceding claims 1 ~ 5, with the weight of the gross weight relative to the composition Gauge, it is included:
A) 0.1% ~ 2.0% at least one cellulose gum, when it is dissolved in the 1% w/w aqueous solution, with 1,000 ~ 2,800 Cps viscosity;
B) 0.5% ~ 2.5% at least one cellulose gum, when it is dissolved in the 2% w/w aqueous solution, with 200 ~ 800 cps' Viscosity;
C) 1.0% ~ 3.0% at least one cellulose gum, it is viscous with 25 ~ 50 cps when it is dissolved in the 2% w/w aqueous solution Degree.
7. the composition according to any one of preceding claims 1 ~ 6, wherein the composition is the aqueous solution.
8. the composition according to any one of claim 1 ~ 7, relative to the gross weight meter of the composition, it is included At least 50 weight %, preferably at least 60 weight % water.
9. the composition according to any one of claim 1 ~ 8, it is further organic molten comprising at least one water miscibility Agent.
10. composition according to claim 9, wherein the miscible organic solvents, which are selected from, has 2 ~ 6 carbon atoms Monohydric alcohol, the polyalcohol with 2 ~ 20 carbon atoms, the glycol ethers and its mixture especially with 3 ~ 24 carbon atoms.
11. the composition according to any one of claim 9 or 10, relative to the gross weight meter of the composition, it is wrapped Containing 0.1 weight % ~ 20.0 weight % one or more of miscible organic solvents.
12. cosmetic composition, it is included according to any one of claim 1 ~ 11 institute in acceptable medium in a physiologically The composition stated.
13. cosmetic composition according to claim 12, it is that facial mask applies some make up composition, the facial mask for example with In the facial mask of cleaning skin and/or facial mask for making rhacoma, it is preferred for making the facial mask of rhacoma.
14. the composition according to any one of claim 1 ~ 13, it is preferably gel.
15. for cleaning skin and/or making the beauty method of rhacoma, it comprises the following steps:
Waterborne compositions according to any one of claim 1 ~ 14 are applied at least one region of skin,
The cosmetic composition is set to be retained on the skin at least 1 minute, the period of preferably 3 minutes ~ 15 minutes,
The cosmetic composition is cleaned from the skin.
16. below material in waterborne compositions combination be used for make the purposes of rhacoma:
A) at least one cellulose gum, it is viscous with 1,000 ~ 2,800 cps when it is dissolved in the 1% w/w aqueous solution Degree;
B) at least one cellulose gum, when it is dissolved in the 2% w/w aqueous solution, the viscosity with 200 ~ 800 cps;With
C) at least one cellulose gum, when it is dissolved in the 2% w/w aqueous solution, the viscosity with 25 ~ 50 cps.
CN201480084378.2A 2014-12-26 2014-12-26 Waterborne compositions for making rhacoma Pending CN107106460A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
PCT/CN2014/095103 WO2016101253A1 (en) 2014-12-26 2014-12-26 Aqueous composition for exfoliating the skin

Publications (1)

Publication Number Publication Date
CN107106460A true CN107106460A (en) 2017-08-29

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Application Number Title Priority Date Filing Date
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WO (1) WO2016101253A1 (en)

Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS60115507A (en) * 1983-11-28 1985-06-22 Sunstar Inc Cosmetic pack
KR100337193B1 (en) * 1999-06-16 2002-05-18 차동천 The keratotic plug remove composition in using sheet-like material
JP2007217299A (en) * 2006-02-14 2007-08-30 Kose Corp Gommerge cosmetic
JP2007262029A (en) * 2006-03-29 2007-10-11 Kose Corp Gommage cosmetic
US20100297191A1 (en) * 2007-10-17 2010-11-25 Georgia-Pacific France Method for manufacturing a cleansing and/or care article
CN102462641A (en) * 2010-11-08 2012-05-23 耿毅 Fruit juice mask
CN102764212A (en) * 2012-07-04 2012-11-07 江苏碧松照明电气有限公司 Exfoliating gel

Patent Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS60115507A (en) * 1983-11-28 1985-06-22 Sunstar Inc Cosmetic pack
KR100337193B1 (en) * 1999-06-16 2002-05-18 차동천 The keratotic plug remove composition in using sheet-like material
JP2007217299A (en) * 2006-02-14 2007-08-30 Kose Corp Gommerge cosmetic
JP2007262029A (en) * 2006-03-29 2007-10-11 Kose Corp Gommage cosmetic
US20100297191A1 (en) * 2007-10-17 2010-11-25 Georgia-Pacific France Method for manufacturing a cleansing and/or care article
CN102462641A (en) * 2010-11-08 2012-05-23 耿毅 Fruit juice mask
CN102764212A (en) * 2012-07-04 2012-11-07 江苏碧松照明电气有限公司 Exfoliating gel

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
吕百龄: "《实用工业助剂全书》", 31 August 2001, 化学工业出版社 *

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