CN107100013A - A kind of mould proof PVC artificial leather and preparation method thereof - Google Patents
A kind of mould proof PVC artificial leather and preparation method thereof Download PDFInfo
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- CN107100013A CN107100013A CN201710335219.0A CN201710335219A CN107100013A CN 107100013 A CN107100013 A CN 107100013A CN 201710335219 A CN201710335219 A CN 201710335219A CN 107100013 A CN107100013 A CN 107100013A
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- layer slurry
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
- D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
- D06N3/04—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- D06N3/06—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds with polyvinylchloride or its copolymerisation products
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
- D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
- D06N3/0043—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by their foraminous structure; Characteristics of the foamed layer or of cellular layers
- D06N3/005—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by their foraminous structure; Characteristics of the foamed layer or of cellular layers obtained by blowing or swelling agent
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
- D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
- D06N3/0056—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by the compounding ingredients of the macro-molecular coating
- D06N3/0059—Organic ingredients with special effects, e.g. oil- or water-repellent, antimicrobial, flame-resistant, magnetic, bactericidal, odour-influencing agents; perfumes
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
- D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
- D06N3/0056—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by the compounding ingredients of the macro-molecular coating
- D06N3/0061—Organic fillers or organic fibrous fillers, e.g. ground leather waste, wood bark, cork powder, vegetable flour; Other organic compounding ingredients; Post-treatment with organic compounds
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
- D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
- D06N3/0056—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by the compounding ingredients of the macro-molecular coating
- D06N3/0063—Inorganic compounding ingredients, e.g. metals, carbon fibres, Na2CO3, metal layers; Post-treatment with inorganic compounds
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
- D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
- D06N3/0086—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by the application technique
- D06N3/0095—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by the application technique by inversion technique; by transfer processes
- D06N3/0097—Release surface, e.g. separation sheets; Silicone papers
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
- D06N2209/00—Properties of the materials
- D06N2209/16—Properties of the materials having other properties
- D06N2209/1671—Resistance to bacteria, mildew, mould, fungi
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
- D06N2211/00—Specially adapted uses
- D06N2211/12—Decorative or sun protection articles
- D06N2211/28—Artificial leather
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- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Life Sciences & Earth Sciences (AREA)
- Wood Science & Technology (AREA)
- Inorganic Chemistry (AREA)
- Synthetic Leather, Interior Materials Or Flexible Sheet Materials (AREA)
Abstract
A kind of mould proof PVC artificial leather of the present invention and preparation method thereof, the parts by weight of each component are：100 parts of PVC resin powder, 40~80 parts of plasticizer, the powder of stabilizer 1~10,1~5 part of foaming agent, 1~10 part of antioxidant, 20 40 parts of mould inhibitor, the preparing raw material of surface layer is mixed in the ratio, form surface layer slurry, the surface layer slurry is coated in release liners, 50 60S are dried under the conditions of 140 160 DEG C；The preparing raw material of foaming layer is mixed in the ratio, form foaming layer slurry, then foaming layer slurry is coated on the photochromic layer slurry after drying, foamable reaction is carried out under the conditions of 170 180 DEG C, the time of the foamable reaction is 70 80S, then in coating polyurethane binder on foaming layer slurry, foaming layer slurry is bonded by adhesive and base fabric, in drying 80 90S at 130 150 DEG C, release liners are detached, the mould proof PVC artificial leather is made.With excellent anti-mold effect, the service life of PVC artificial leather is effectively extended.
Description
Technical field
The invention belongs to PVC artificial leather technical field, specifically, it is related to a kind of mould proof PVC artificial leather and its preparation side
Method.
Background technology
In the market is sold natural leather and widely not used due to expensive for client, a kind of artificial leather occurs and replaces original
Natural leather.
Artificial leather, a class outward appearance, feel are like leather and can replace its plastic products that use.Generally using fabric as base,
Coat and the mixing material that various plastic additives are made is added by synthetic resin be made, now, designs and varieties are various in daily life
Leather goods be seen everywhere, such as interior decoration, sofa fabric, automotive trim, clothes, footwear and case and bag, people often recognize
It is that natural leather makes for these products, actually this is not so, and the sizable share of these leather goods is shared by artificial leather, synthetic leather
According to.
PVC artificial leather in humid environment, exist under dirt and hot conditions, often due to the taste of yeast and mold
It is raw, its quality is severely impacted, shortens its service life, therefore PVC artificial leather needs mould proof processing.
The content of the invention
Instant invention overcomes shortcoming of the prior art, there is provided a kind of mould proof PVC artificial leather and preparation method thereof.
In order to solve the above-mentioned technical problem, the present invention is achieved by the following technical solutions：
A kind of mould proof PVC artificial leather, the parts by weight of each component are：100 parts of PVC resin powder, 40~80 parts of plasticizer, stably
The powder of agent 1~10,1~5 part of foaming agent, 1~10 part of antioxidant, 20-40 parts of mould inhibitor.
Further, the mould inhibitor is 30-40 parts of lignin, 10-20 parts of plant ash, 5-10 parts of molybdenum disulfide, nipalgin
10-20 parts of propyl ester, 5-10 parts of vermiculite power, pentachlorophenol part 10-15 parts, 5-10 parts of phenyl mercury oleate.
Further, the plasticizer is polypropylene glycol adipate.
Further, the stabilizer is benzoic acid or salicylic acid.
Further, the foaming agent is sulfonyl hydrazines compound.
Further, the antioxidant is phenols oxidant.
A kind of preparation method of mould proof PVC artificial leather, in proportion mixes the preparing raw material of surface layer, forms surface layer slurry,
The surface layer slurry is coated in release liners, 50-60S is dried under the conditions of 140-160 DEG C；In the ratio by foaming layer
Preparing raw material is mixed, and forms foaming layer slurry, then foaming layer slurry is coated on the photochromic layer slurry after drying, in 170-
Foamable reaction is carried out under the conditions of 180 DEG C, the time of the foamable reaction is 70-80S, then in coating poly- ammonia on foaming layer slurry
Ester adhesive, foaming layer slurry is bonded by adhesive and base fabric, in drying 80-90S at 130-150 DEG C, release liners taken out
From the obtained mould proof PVC artificial leather.
Further, the surface layer slurry raw material includes：The parts by weight of each component are：100 parts of PVC resin powder, plasticizer 50
Part, the powder of stabilizer 5,1 part of foaming agent, 3 parts of antioxidant, 30 parts of mould inhibitor.
Further, the foaming layer slurry feedstock includes：The parts by weight of each component are：100 parts of PVC resin powder, plasticizer
40 parts, the powder of stabilizer 7,4 parts of foaming agent, 6 parts of antioxidant, 35 parts of mould inhibitor.
Compared with prior art, the beneficial effects of the invention are as follows：
A kind of mould proof PVC artificial leather of the present invention and preparation method thereof, the parts by weight of each component are：PVC resin powder 100
Part, 40~80 parts of plasticizer, the powder of stabilizer 1~10,1~5 part of foaming agent, 1~10 part of antioxidant, 20-40 parts of mould inhibitor,
With excellent anti-mold effect, the service life of PVC artificial leather is effectively extended.
Embodiment
The preferred embodiments of the present invention are illustrated below, it will be appreciated that preferred embodiment described herein is only used
In the description and interpretation present invention, it is not intended to limit the present invention.
A kind of mould proof PVC artificial leather, the parts by weight of each component are：100 parts of PVC resin powder, 40~80 parts of plasticizer, stably
The powder of agent 1~10,1~5 part of foaming agent, 1~10 part of antioxidant, 20-40 parts of mould inhibitor.
Wherein, mould inhibitor is 35 parts of lignin, 15 parts of plant ash, 6 parts of molybdenum disulfide, 16 parts of propylben, vermiculite power 8
Part, pentachlorophenol part 12 parts, 8 parts of phenyl mercury oleate.
Surface layer slurry raw material includes：The parts by weight of each component are：100 parts of PVC resin powder, 50 parts of plasticizer, the powder of stabilizer 5
End, 1 part of foaming agent, 3 parts of antioxidant, 30 parts of mould inhibitor.
Foaming layer slurry feedstock includes：The parts by weight of each component are：100 parts of PVC resin powder, 40 parts of plasticizer, stabilizer 7
Powder, 4 parts of foaming agent, 6 parts of antioxidant, 35 parts of mould inhibitor.
Wherein, plasticizer is polypropylene glycol adipate, and stabilizer is benzoic acid or salicylic acid, and foaming agent is sulfonyl hydrazines
Compound, antioxidant is phenols oxidant.
A kind of preparation method of mould proof PVC artificial leather, in proportion mixes the preparing raw material of surface layer, forms surface layer slurry,
The surface layer slurry is coated in release liners, 50-60S is dried under the conditions of 140-160 DEG C；In the ratio by foaming layer
Preparing raw material is mixed, and forms foaming layer slurry, then foaming layer slurry is coated on the photochromic layer slurry after drying, in 170-
Foamable reaction is carried out under the conditions of 180 DEG C, the time of the foamable reaction is 70-80S, then in coating poly- ammonia on foaming layer slurry
Ester adhesive, foaming layer slurry is bonded by adhesive and base fabric, in drying 80-90S at 130-150 DEG C, release liners taken out
From the obtained mould proof PVC artificial leather.
Finally it should be noted that：The preferred embodiments of the present invention are these are only, are not intended to limit the invention, although
The present invention is described in detail with reference to embodiment, for those skilled in the art, it still can be to foregoing
Technical scheme described in each embodiment is modified, or to which part technical characteristic carry out equivalent substitution, but it is all
Within the spirit and principles in the present invention, any modification, equivalent substitution and improvements made etc. should be included in the protection of the present invention
Within the scope of.
Claims (9)
1. a kind of mould proof PVC artificial leather, it is characterised in that the parts by weight of each component are：100 parts of PVC resin powder, plasticizer 40~
80 parts, the powder of stabilizer 1~10,1~5 part of foaming agent, 1~10 part of antioxidant, 20-40 parts of mould inhibitor.
2. a kind of mould proof PVC artificial leather according to claim 1, it is characterised in that the mould inhibitor is lignin 30-40
Part, 10-20 parts of plant ash, 5-10 parts of molybdenum disulfide, 10-20 parts of propylben, 5-10 parts of vermiculite power, pentachlorophenol part 10-15
Part, 5-10 parts of phenyl mercury oleate.
3. a kind of mould proof PVC artificial leather according to claim 1, it is characterised in that the plasticizer is polyadipate the third two
Alcohol ester.
4. a kind of mould proof PVC artificial leather according to claim 1, it is characterised in that the stabilizer is benzoic acid or bigcatkin willow
Acid.
5. a kind of mould proof PVC artificial leather according to claim 1, it is characterised in that the foaming agent is sulfonyl hydrazines chemical combination
Thing.
6. a kind of mould proof PVC artificial leather according to claim 1, it is characterised in that the antioxidant is phenols oxidant.
7. a kind of preparation method of mould proof PVC artificial leather according to claim 1, it is characterised in that as described in claim 1
Ratio mixes the preparing raw material of surface layer, forms surface layer slurry, the surface layer slurry is coated in release liners, in 140-160
50-60S is dried under the conditions of DEG C；The preparing raw material of foaming layer is mixed in ratio described in claim 1, foaming layer slurry is formed,
Then foaming layer slurry is coated on the photochromic layer slurry after drying, foamable reaction is carried out under the conditions of 170-180 DEG C, it is described
The time of foamable reaction is 70-80S, then in coating polyurethane binder on foaming layer slurry, foaming layer slurry is passed through viscous
Mixture is bonded with base fabric, and in drying 80-90S at 130-150 DEG C, release liners are detached, and the mould proof PVC artificial leather is made.
8. a kind of preparation method of mould proof PVC artificial leather according to claim 7, it is characterised in that the surface layer slurry is former
Material includes：The parts by weight of each component are：100 parts of PVC resin powder, 50 parts of plasticizer, the powder of stabilizer 5,1 part of foaming agent, antioxygen
3 parts of agent, 30 parts of mould inhibitor.
9. a kind of preparation method of mould proof PVC artificial leather according to claim 7, it is characterised in that the foaming layer slurry
Raw material includes：The parts by weight of each component are：It is 100 parts of PVC resin powder, 40 parts of plasticizer, the powder of stabilizer 7,4 parts of foaming agent, anti-
6 parts of oxidant, 35 parts of mould inhibitor.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710335219.0A CN107100013A (en) | 2017-05-12 | 2017-05-12 | A kind of mould proof PVC artificial leather and preparation method thereof |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710335219.0A CN107100013A (en) | 2017-05-12 | 2017-05-12 | A kind of mould proof PVC artificial leather and preparation method thereof |
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| Publication Number | Publication Date |
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| CN107100013A true CN107100013A (en) | 2017-08-29 |
Family
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| CN201710335219.0A Pending CN107100013A (en) | 2017-05-12 | 2017-05-12 | A kind of mould proof PVC artificial leather and preparation method thereof |
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Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108085980A (en) * | 2017-11-23 | 2018-05-29 | 苏州梅香雅筑工艺品有限公司 | A kind of mildew-proof treatment method of circular fan covering of the fan |
| CN108660782A (en) * | 2018-05-15 | 2018-10-16 | 佛山市高明威仕达塑料有限公司 | A kind of new-energy automobile interior decoration leather and preparation method thereof |
| CN108677546A (en) * | 2018-06-05 | 2018-10-19 | 广州益合康科技材料有限公司 | A kind of mould proof artificial leather and preparation method thereof |
| CN108823992A (en) * | 2018-05-15 | 2018-11-16 | 佛山市高明威仕达塑料有限公司 | A kind of yacht leather and preparation method thereof |
| CN109112846A (en) * | 2018-07-23 | 2019-01-01 | 南通中奥车用新材料有限公司 | A kind of high-strength abrasion-proof plated film PVC artificial leather |
| CN112323507A (en) * | 2020-09-30 | 2021-02-05 | 广东远华新材料股份有限公司 | Mildew-proof antibacterial crawling pad and preparation method thereof |
| CN112721364A (en) * | 2021-01-20 | 2021-04-30 | 嘉兴市博尔新材料有限公司 | Mildew-proof wear-resistant environment-friendly PVC artificial leather and preparation method thereof |
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| CN106087438A (en) * | 2016-06-23 | 2016-11-09 | 福建宝利特科技股份有限公司 | A kind of environment-friendlyfoamed foamed artificial leather and preparation method thereof |
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Cited By (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108085980A (en) * | 2017-11-23 | 2018-05-29 | 苏州梅香雅筑工艺品有限公司 | A kind of mildew-proof treatment method of circular fan covering of the fan |
| CN108660782A (en) * | 2018-05-15 | 2018-10-16 | 佛山市高明威仕达塑料有限公司 | A kind of new-energy automobile interior decoration leather and preparation method thereof |
| CN108823992A (en) * | 2018-05-15 | 2018-11-16 | 佛山市高明威仕达塑料有限公司 | A kind of yacht leather and preparation method thereof |
| CN108677546A (en) * | 2018-06-05 | 2018-10-19 | 广州益合康科技材料有限公司 | A kind of mould proof artificial leather and preparation method thereof |
| CN109112846A (en) * | 2018-07-23 | 2019-01-01 | 南通中奥车用新材料有限公司 | A kind of high-strength abrasion-proof plated film PVC artificial leather |
| CN109112846B (en) * | 2018-07-23 | 2021-03-02 | 南通中奥车用新材料有限公司 | High-strength wear-resistant coated PVC artificial leather |
| CN112323507A (en) * | 2020-09-30 | 2021-02-05 | 广东远华新材料股份有限公司 | Mildew-proof antibacterial crawling pad and preparation method thereof |
| CN112721364A (en) * | 2021-01-20 | 2021-04-30 | 嘉兴市博尔新材料有限公司 | Mildew-proof wear-resistant environment-friendly PVC artificial leather and preparation method thereof |
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Application publication date: 20170829 |