CN107100006A - A kind of sea farming fishing net anti-fouling agent and its application method - Google Patents
A kind of sea farming fishing net anti-fouling agent and its application method Download PDFInfo
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- CN107100006A CN107100006A CN201710336271.8A CN201710336271A CN107100006A CN 107100006 A CN107100006 A CN 107100006A CN 201710336271 A CN201710336271 A CN 201710336271A CN 107100006 A CN107100006 A CN 107100006A
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Abstract
The invention belongs to fishing net processing technique field, and in particular to a kind of sea farming fishing net anti-fouling agent and its application method, and anti-fouling agent is without copper class anti-fouling agent, including antifouling preparation, film preparation and additive, for brand-new fishing net.The present invention has advantages below compared with prior art：Anti-fouling agent used not copper ions in the present invention, it is prevented effectively from the pollution to marine environment, fishing net surface is retained in using what film preparation can make the antifouling preparation energy of attachment long period, prevent the aufwuch in seawater from adhering on fishing net, growing, so as to keep the relative clean of fishing net, additive can strengthen the antifouling efficacy of antifouling preparation, and performance is stable in the seawater；Anti-fouling agent preparation method is simple, and raw material configuration is reasonable, and advantage of lower cost is adapted to promote the use of.
Description
Technical field
The invention belongs to fishing net processing technique field, and in particular to a kind of sea farming fishing net anti-fouling agent and its user
Method.
Background technology
Part fishing net is needed, it is necessary to be located at for a long time in ocean, therefore, if without the fishing net of antifouling process due to using
The erosion of aufwuch, overgrows on the net, influences in a large amount of oceans such as meeting periphtic algae, fungi, barnacle, shell, amphipoda
Seawater circulation, the use to fishing net is affected greatly, and in order to prevent fishing net from being polluted by aufwuch in seawater, fishing net is entered
Row antifouling process turns into one of existing maximally effective approach, but existing anti-fouling agent has certain influence on waters, and raw in seawater
Species are various, depend a kind of medicine alone and also are difficult to reach antifouling effect, it is therefore desirable to which existing anti-fouling agent is further ground
Study carefully.
The content of the invention
The purpose of the present invention is that there is provided a kind of sea farming fishing net anti-fouling agent and its user the problem of being directed to existing
Method.
The present invention is achieved by the following technical solutions：A kind of sea farming fishing net anti-fouling agent, is that no copper class is antifouling
Agent, including antifouling preparation, film preparation and additive, its preparation method comprise the following steps：
（1）Raw material prepares, by weight, including：Silica nanosphere 16-18, the pipering 3-5 of fluoroalkyl；It is super
Branched polyurethanes emulsion 22-26, fluorine carbon emulsion 7-10, nano titanium oxide 4-7, aqueous alkide resin 5-10, Acrylates
Dispersant 16-20, rcumenol 2-3, water 4-8；Sodium alkyl sulfonate 8-14, Tissuemat E 2-5, organobentonite 2-5, polysiloxanes
The double hardness acid amides 2-5 of 4-7, vinyl；
（2）It is prepared by antifouling preparation：The silica nanosphere of fluoroalkyl and pipering are added refinement are ground in grinder,
Add equivalent to its mass percent as in 6% pyrosulfurous acid, stirring reaction 35-40 divides under conditions of temperature is 65-70 DEG C
Clock, filtering, is washed to neutrality with saturated sodium bicarbonate and deionized water, uses a small amount of anhydrous sodium sulfate drying, produce successively；
（3）It is prepared by film preparation：Acrylates dispersant and rcumenol are added to the water, in 3000-3300 revs/min of speed
Lower stirring 5-8 minutes, obtains dispersant standby；Super branched polyurethane emulsion, nano titanium oxide, aqueous alkide resin are mixed
Afterwards, irradiated 3-5 minutes with the far infrared that wavelength is 10-14 μm, temperature is no more than 80 DEG C, then add fluorine carbon emulsion and scattered
Agent, is stirred 10-15 minutes, discharging obtains film preparation under conditions of rotating speed is 2600-3000 rev/min；
（4）It is prepared by additive：Under conditions of temperature is 85-90 DEG C, with mixing speed, 200-300 revs/min is stirred raw material
Stirring mixing, near normal temperature is produced；
（5）It is prepared by anti-fouling agent：By antifouling preparation and additive temperature be sufficiently mixed under conditions of 65-70 DEG C it is scattered, in temperature
Spend under the oxygen free condition for 0-2 DEG C and preserve 4-6 hours, stir and produce with film preparation after taking-up.
It is used as further improvement of these options, the preparation method of the silica nanosphere of the fluoroalkyl
For：Lupeol is dissolved in the ethanol solution that mass concentration of 15-18 times equivalent to its weight is 75%, in 0 DEG C of condition
Lower stirring 30 minutes, then heats to normal temperature, adds the silica nanosphere equivalent to ethanol solution weight 30%, using super
Sound disperses, and adds the fluoroalkyl equivalent to ethanol solution weight 2%, stirring reaction 6 hours, filtration drying obtains fluoroalkyl and changed
The silica nanosphere of property.
As further improvement of these options, the particle diameter of the silica nanosphere of the fluoroalkyl is 20-
40nm。
As further improvement of these options, the anti-fouling agent is used for brand-new fishing net.
A kind of application method of sea farming fishing net anti-fouling agent, the brand-new fishing net is with anti-fouling agent before processing temperature
After the sodium hydroxide solution for being 6% for 55-60 DEG C, mass concentration soaks 15-20 minutes, cleaned, dried with deionized water；Will be anti-
Dirty agent temperature is diluted after 8 times for 60 DEG C of water, pretreated fishing net is immersed, nitrogen charging hermetic seal 10 minutes, is taken out
Afterwards with distilled water flushing, drying.
The present invention has advantages below compared with prior art：Anti-fouling agent used not copper ions, are prevented effectively from the present invention
Pollution to marine environment, is retained in fishing net surface using what film preparation can make the antifouling preparation energy of attachment long period, makes seawater
In aufwuch can not adhere on fishing net, grow, so as to keep the relative clean of fishing net, additive can strengthen antifouling preparation
Antifouling efficacy, performance is stable in the seawater；Anti-fouling agent preparation method is simple, and raw material configuration is reasonable, and advantage of lower cost is adapted to
Promote the use of.
Embodiment
Embodiment 1
A kind of sea farming fishing net anti-fouling agent, is no copper class anti-fouling agent, including antifouling preparation, film preparation and additive, and it is made
Preparation Method comprises the following steps：
（1）Raw material prepares, by weight, including：Silica nanosphere 17, the pipering 4 of fluoroalkyl；Hyperbranched poly
Urethane emulsion 26, fluorine carbon emulsion 7, nano titanium oxide 7, aqueous alkide resin 5, Acrylates dispersant 20, rcumenol 3,
Water 8；The double hardness acid amides 2 of sodium alkyl sulfonate 8, Tissuemat E 5, organobentonite 2, polysiloxanes 7, vinyl；
（2）It is prepared by antifouling preparation：The silica nanosphere of fluoroalkyl and pipering are added refinement are ground in grinder,
Add equivalent to its mass percent as in 6% pyrosulfurous acid, stirring reaction 35-40 divides under conditions of temperature is 65-70 DEG C
Clock, filtering, is washed to neutrality with saturated sodium bicarbonate and deionized water, uses a small amount of anhydrous sodium sulfate drying, produce successively；
（3）It is prepared by film preparation：Acrylates dispersant and rcumenol are added to the water, in 3000-3300 revs/min of speed
Lower stirring 5-8 minutes, obtains dispersant standby；Super branched polyurethane emulsion, nano titanium oxide, aqueous alkide resin are mixed
Afterwards, irradiated 3-5 minutes with the far infrared that wavelength is 10-14 μm, temperature is no more than 80 DEG C, then add fluorine carbon emulsion and scattered
Agent, is stirred 10-15 minutes, discharging obtains film preparation under conditions of rotating speed is 2600-3000 rev/min；
（4）It is prepared by additive：Under conditions of temperature is 85-90 DEG C, with mixing speed, 200-300 revs/min is stirred raw material
Stirring mixing, near normal temperature is produced；
（5）It is prepared by anti-fouling agent：By antifouling preparation and additive temperature be sufficiently mixed under conditions of 65-70 DEG C it is scattered, in temperature
Spend under the oxygen free condition for 0-2 DEG C and preserve 4-6 hours, stir and produce with film preparation after taking-up.
Wherein, the preparation method of the silica nanosphere of the fluoroalkyl is：Lupeol is dissolved in quite
In 15-18 times of mass concentration of its weight is 75% ethanol solution, stirs 30 minutes, then heat under conditions of 0 DEG C
Normal temperature, adds the silica nanosphere equivalent to ethanol solution weight 30%, using ultrasonic disperse, adds equivalent to ethanol
The fluoroalkyl of solution weight 2%, stirring reaction 6 hours, filtration drying obtains the silica nanosphere of fluoroalkyl；It is described
The particle diameter of the silica nanosphere of fluoroalkyl is 20-40nm.
A kind of application method of sea farming fishing net anti-fouling agent, the brand-new fishing net is with anti-fouling agent before processing temperature
After the sodium hydroxide solution for being 6% for 55-60 DEG C, mass concentration soaks 15-20 minutes, cleaned, dried with deionized water；Will be anti-
Dirty agent temperature is diluted after 8 times for 60 DEG C of water, pretreated fishing net is immersed, nitrogen charging hermetic seal 10 minutes, is taken out
Afterwards with distilled water flushing, drying.
Embodiment 2
The anti-fouling agent, raw material prepares, by weight, including：Silica nanosphere 16, the pipering 3 of fluoroalkyl；
Super branched polyurethane emulsion 26, fluorine carbon emulsion 10, nano titanium oxide 7, aqueous alkide resin 10, Acrylates dispersant
16th, rcumenol 2, water 8；The double hardness acid amides of sodium alkyl sulfonate 14, Tissuemat E 2, organobentonite 2, polysiloxanes 7, vinyl
2；Remaining content is in the same manner as in Example 1.
Embodiment 3
The anti-fouling agent, raw material prepares, by weight, including：Silica nanosphere 18, the pipering 5 of fluoroalkyl；
Super branched polyurethane emulsion 22, fluorine carbon emulsion 7, nano titanium oxide 4, aqueous alkide resin 5, Acrylates dispersant 20,
Rcumenol 3, water 4；The double hardness acid amides 4 of sodium alkyl sulfonate 8, Tissuemat E 5, organobentonite 5, polysiloxanes 4, vinyl；Its
Remaining content is in the same manner as in Example 1.
Control group 1 is set, with chlorine partial emulsion and pitch by weight 2:Film forming agent is made in 1 mixing, with pyrithione A, sulphur cyanogen
Hydrochlorate, pyridine sulfuric acid ketone B are anti-fouling agent raw material, from polythene fishing net as experiment matrix, respectively to the film forming of anti-fouling agent
Detected with antifouling capacity；
Wherein, 6g salt is added in 1L water and prepares saline solution, after polyethylene is coated with by anti-fouling agent for the fishing net of raw material, dried in the air
Dry, rubbing, folding repeatedly, has seen whether leachable and film forming obscission, wherein embodiment 1-3 is rolling over repeatedly in salt solution
After folded 30 times, observation does not occur leachable or film forming obscission；There is leachable after folding 14 times in control group 1, after
Continuing after folding 5 times has film forming obscission；Therefore, film forming agent can more be protected compared to existing chlorine partial emulsion and pitch mixing in the present invention
Hold the stability and tack of anti-fouling agent.
Anti-fouling agent is coated on after fishing net in control group 1, and its tensile strength improves 8.6% or so, and elongation at break is added
12.7%, anti-fouling agent is coated on after fishing net in embodiment 1, and tensile strength and elongation at break increase be not obvious.
Control group 1 and embodiment 1 carry out anti-fouling agent in toxicity detection, control group 1 to it respectively has certain thorn to lagophthalmos eyeball
Swash, to no skin irritation；Embodiment 1 is nonirritant to lagophthalmos eyeball and skin；
Setting control group 2 is blank group, it is handled without anti-fouling agent, in great Chen islands marine site, lacing film is tested, and is being worked as
July in year plunges into the commercial sea, and detects biological attachment area respectively in September and November, obtains following result：
Table 1
| Group | September bond area（%） | November bond area（%） |
| Embodiment 1 | 18 | 5 |
| Embodiment 2 | 20 | 6 |
| Embodiment 3 | 18 | 4 |
| Control group 1 | 15 | 11 |
| Control group 2 | 84 | 100 |
Can be seen that anti-fouling agent in the present invention by data in table 1, anti-fouling effect is poor compared to control group 1 in the early stage, but rear
Phase is antifouling to be want to significantly improve compared to control group 1, it is seen that anti-fouling agent stability is good in the present invention, can be effectively antifouling.
Claims (5)
1. a kind of sea farming fishing net anti-fouling agent, it is characterised in that be without copper class anti-fouling agent, including antifouling preparation, film preparation
And additive, its preparation method comprises the following steps：
（1）Raw material prepares, by weight, including：Silica nanosphere 16-18, the pipering 3-5 of fluoroalkyl；It is super
Branched polyurethanes emulsion 22-26, fluorine carbon emulsion 7-10, nano titanium oxide 4-7, aqueous alkide resin 5-10, Acrylates
Dispersant 16-20, rcumenol 2-3, water 4-8；Sodium alkyl sulfonate 8-14, Tissuemat E 2-5, organobentonite 2-5, polysiloxanes
The double hardness acid amides 2-5 of 4-7, vinyl；
（2）It is prepared by antifouling preparation：The silica nanosphere of fluoroalkyl and pipering are added refinement are ground in grinder,
Add equivalent to its mass percent as in 6% pyrosulfurous acid, stirring reaction 35-40 divides under conditions of temperature is 65-70 DEG C
Clock, filtering, is washed to neutrality with saturated sodium bicarbonate and deionized water, uses a small amount of anhydrous sodium sulfate drying, produce successively；
（3）It is prepared by film preparation：Acrylates dispersant and rcumenol are added to the water, in 3000-3300 revs/min of speed
Lower stirring 5-8 minutes, obtains dispersant standby；Super branched polyurethane emulsion, nano titanium oxide, aqueous alkide resin are mixed
Afterwards, irradiated 3-5 minutes with the far infrared that wavelength is 10-14 μm, temperature is no more than 80 DEG C, then add fluorine carbon emulsion and scattered
Agent, is stirred 10-15 minutes, discharging obtains film preparation under conditions of rotating speed is 2600-3000 rev/min；
（4）It is prepared by additive：Under conditions of temperature is 85-90 DEG C, with mixing speed, 200-300 revs/min is stirred raw material
Stirring mixing, near normal temperature is produced；
（5）It is prepared by anti-fouling agent：By antifouling preparation and additive temperature be sufficiently mixed under conditions of 65-70 DEG C it is scattered, in temperature
Spend under the oxygen free condition for 0-2 DEG C and preserve 4-6 hours, stir and produce with film preparation after taking-up.
2. a kind of sea farming fishing net anti-fouling agent as claimed in claim 1, it is characterised in that the dioxy of the fluoroalkyl
The preparation method of SiClx nanosphere is：The second that the mass concentration that lupeol is dissolved in into 15-18 times equivalent to its weight is 75%
In alcoholic solution, stirred 30 minutes under conditions of 0 DEG C, then heat to normal temperature, added equivalent to the two of ethanol solution weight 30%
Monox nanometer ball, using ultrasonic disperse, adds the fluoroalkyl equivalent to ethanol solution weight 2%, stirring reaction 6 hours, mistake
It is filtered dry dry, obtains the silica nanosphere of fluoroalkyl.
3. a kind of sea farming fishing net anti-fouling agent as claimed in claim 1, it is characterised in that the dioxy of the fluoroalkyl
The particle diameter of SiClx nanosphere is 20-40nm.
4. a kind of sea farming fishing net anti-fouling agent as claimed in claim 1, it is characterised in that the anti-fouling agent is used for brand-new fishing
Net.
5. a kind of application method of sea farming fishing net anti-fouling agent as claimed in claim 4, it is characterised in that the brand-new fishing
Net be 55-60 DEG C with temperature with anti-fouling agent before processing, after the sodium hydroxide solution that mass concentration is 6% soaks 15-20 minutes,
Cleaned, dried with deionized water；Anti-fouling agent temperature is diluted after 8 times for 60 DEG C of water, pretreated fishing net is immersed it
In, nitrogen charging hermetic seal 10 minutes, with distilled water flushing, drying after taking-up.
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| CN201710336271.8A CN107100006A (en) | 2017-05-13 | 2017-05-13 | A kind of sea farming fishing net anti-fouling agent and its application method |
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| CN201710336271.8A CN107100006A (en) | 2017-05-13 | 2017-05-13 | A kind of sea farming fishing net anti-fouling agent and its application method |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108914595A (en) * | 2018-04-11 | 2018-11-30 | 巢湖市瀚海渔具有限公司 | A kind of preparation method of high-strength composite netting twine |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101333348A (en) * | 2008-07-02 | 2008-12-31 | 大连海事大学 | Non-toxic anti-pollution paint for sea and method for preparing same |
| CN103374140A (en) * | 2012-04-25 | 2013-10-30 | 深圳富泰宏精密工业有限公司 | Shell and preparation method thereof |
| CN104762813A (en) * | 2015-03-30 | 2015-07-08 | 巢湖市强力渔业有限责任公司 | Natural fishing net antifouling compound |
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2017
- 2017-05-13 CN CN201710336271.8A patent/CN107100006A/en active Pending
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101333348A (en) * | 2008-07-02 | 2008-12-31 | 大连海事大学 | Non-toxic anti-pollution paint for sea and method for preparing same |
| CN103374140A (en) * | 2012-04-25 | 2013-10-30 | 深圳富泰宏精密工业有限公司 | Shell and preparation method thereof |
| CN104762813A (en) * | 2015-03-30 | 2015-07-08 | 巢湖市强力渔业有限责任公司 | Natural fishing net antifouling compound |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108914595A (en) * | 2018-04-11 | 2018-11-30 | 巢湖市瀚海渔具有限公司 | A kind of preparation method of high-strength composite netting twine |
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