CN107090741B - Transfevent tipping paper and preparation method thereof - Google Patents
Transfevent tipping paper and preparation method thereof Download PDFInfo
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- CN107090741B CN107090741B CN201710228740.4A CN201710228740A CN107090741B CN 107090741 B CN107090741 B CN 107090741B CN 201710228740 A CN201710228740 A CN 201710228740A CN 107090741 B CN107090741 B CN 107090741B
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- China
- Prior art keywords
- transfevent
- tipping paper
- paper
- ink
- priming coat
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Classifications
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- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H19/00—Coated paper; Coating material
- D21H19/80—Paper comprising more than one coating
- D21H19/82—Paper comprising more than one coating superposed
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H19/00—Coated paper; Coating material
- D21H19/10—Coatings without pigments
- D21H19/12—Coatings without pigments applied as a solution using water as the only solvent, e.g. in the presence of acid or alkaline compounds
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H19/00—Coated paper; Coating material
- D21H19/36—Coatings with pigments
- D21H19/44—Coatings with pigments characterised by the other ingredients, e.g. the binder or dispersing agent
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H19/00—Coated paper; Coating material
- D21H19/80—Paper comprising more than one coating
- D21H19/82—Paper comprising more than one coating superposed
- D21H19/828—Paper comprising more than one coating superposed two superposed coatings, the first applied being non-pigmented and the second applied being pigmented
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H25/00—After-treatment of paper not provided for in groups D21H17/00 - D21H23/00
- D21H25/04—Physical treatment, e.g. heating, irradiating
- D21H25/06—Physical treatment, e.g. heating, irradiating of impregnated or coated paper
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H27/00—Special paper not otherwise provided for, e.g. made by multi-step processes
- D21H27/18—Paper- or board-based structures for surface covering
Landscapes
- Application Of Or Painting With Fluid Materials (AREA)
- Laminated Bodies (AREA)
Abstract
The material of a kind of transfevent tipping paper, including the transfevent base paper for tipping paper, priming coat and the ink layer that are cascading, the priming coat includes at least one of acrylic resin, polyurethane and modified nitrocotton；The material of the ink layer includes at least one of polyethylene glycol butyral, rosin resin, polyvinyl alcohol and phenolic resin.The present invention also provides a kind of preparation methods of transfevent tipping paper.Transfevent tipping paper provided by the present invention, VOC content is low and has excellent aesthetic quality.
Description
Technical field
The present invention relates to cigarette fields, more particularly to a kind of transfevent tipping paper and preparation method thereof.
Background technology
Transfevent tipping paper be by by cork paper body paper and aluminizing a kind of compound obtained tipping paper of transfer membrane, it is this to connect
Paper is filled due to there is aluminium coated, appearance metal sense is strong, and appearance is more bright and new beautiful, to be liked by consumers in general.
The ink for being currently used for plain edition tipping paper mostly uses the low alcohol-soluble polyethylene glycol butyral of VOC content as resin
Binder, however, such ink but cannot be well attached on transfevent tipping paper, this is because transfevent tipping paper surface
Aluminium molecular metal layer it is very poor to above-mentioned ink absorption.Therefore, for transfevent tipping paper, ester soluble ink is mostly used at present
As resin binder, to ensure adhesion-tight of the ink layer on transfevent tipping paper, not easily to fall off, this just causes transfevent
Requirement cannot be met by being hinged with the safety and sanitation indexs such as VOC content, the content of formaldehyde of paper product.
Invention content
Based on this, it is necessary to provide a kind of transfevent tipping paper and preparation method thereof that VOC content is low.
A kind of transfevent tipping paper, including the transfevent base paper for tipping paper, priming coat and the ink layer that are cascading, institute
The material for stating priming coat includes at least one of acrylic resin, polyurethane and modified nitrocotton；The material of the ink layer
Including at least one of polyethylene glycol butyral, rosin resin, polyvinyl alcohol and phenolic resin.
The transfevent base paper for tipping paper includes cork paper body paper and transfer membrane of aluminizing, institute in one of the embodiments,
It states priming coat and is directly arranged at described aluminize on transfer membrane.
The ink layer is directly arranged on the priming coat in one of the embodiments,.
The dry film grammes per square metre of the priming coat is 0.5g/m in one of the embodiments,2To 1.5g/m2, the priming coat
Thickness is 0.5 μm to 3 μm.
In one of the embodiments, the molecular weight of the acrylic resin, polyurethane or modified nitrocotton be 10000~
200000。
A kind of preparation method of transfevent tipping paper, which is characterized in that including：
Transfevent base paper for tipping paper is provided；
Primary coat liquid is provided, the primary coat liquid is coated on the transfevent base paper for tipping paper, forms priming coat, the bottom
Masking liquid is water-based acrylic resin lotion, aqueous polyurethane emulsion, alcohol-soluble polyurethane solution and watersoluble modified nitrocotton lotion
At least one of；And
The coating printing ink on the priming coat forms ink layer, to obtain the transfevent tipping paper, the ink packet
Include alcohol-soluble polyethylene glycol butyral ink, alcohol-soluble rosin resin ink, alcohol-soluble phenolic resin ink and aqueous polyethylene
At least one of alcohol ink.
The transfevent base paper for tipping paper includes cork paper body paper and transfer membrane of aluminizing, institute in one of the embodiments,
It states primary coat liquid and is directly coated on described aluminize on transfer membrane.
The solid content of the primary coat liquid is 10%~35% in one of the embodiments, and the viscosity of the primary coat liquid is
14s~22s (2# glasss English).
The dry film grammes per square metre of the priming coat is 0.5g/m in one of the embodiments,2To 1.5g/m2, the priming coat
Thickness is 0.5 μm to 3 μm.
Acrylic resin, polyurethane and/or the molecule for being modified nitrocotton in the primary coat liquid in one of the embodiments,
Amount is 10000~200000.
In the present invention, it by being initially formed priming coat on transfevent base paper for tipping paper, is then formed on priming coat poly-
Ethylene glycol butyral, rosin resin, polyvinyl alcohol and/or phenolic resin ink layer, cannot direct shape to solve above-mentioned ink layer
Problem on transfevent base paper for tipping paper described in Cheng Yu.In addition, the priming coat also has blast hyperchromic above-mentioned ink layer
Effect, so that the appearance glossiness higher of the transfevent tipping paper, ink layer hierarchical structure be clearly more demarcated and aesthetic quality
It is more excellent.
Description of the drawings
Fig. 1 is the preparation method flow chart of transfevent tipping paper provided by the invention；
Fig. 2 is the structural schematic diagram of transfevent tipping paper provided by the invention.
Specific implementation mode
In order to make the purpose , technical scheme and advantage of the present invention be clearer, by the following examples, it and combines attached
Figure, the present invention will be described in further detail.
It please refers to Fig.1 to Fig. 2, first embodiment of the invention provides a kind of preparation method of transfevent tipping paper 1, packet
It includes：
S1 provides transfevent base paper for tipping paper 10；
S2 provides primary coat liquid, and the primary coat liquid is coated on the transfevent base paper for tipping paper 10, forms priming coat
20, the primary coat liquid includes water-based acrylic resin lotion, aqueous polyurethane emulsion, alcohol-soluble polyurethane solution and watersoluble modified
At least one of nitrocotton lotion；And
S3, the coating printing ink on the priming coat 20 form ink layer 30, to obtain the transfevent tipping paper 1, institute
It includes alcohol-soluble polyethylene glycol butyral ink, alcohol-soluble rosin resin ink, alcohol-soluble phenolic resin ink and water to state ink
At least one of property polyvinyl alcohol ink.
In step sl, the transfevent base paper for tipping paper 10 can be silver color transfevent base paper for tipping paper, golden transfer
Type base paper for tipping paper or radium-shine transfevent base paper for tipping paper.The transfevent base paper for tipping paper 10 may include cork paper body paper 110
Be set on cork paper body paper 110 described in aluminize transfer membrane 120.The grammes per square metre of the transfevent base paper for tipping paper 10 can be
30g/m2To 45g/m2, the transfevent tipping paper 1 prepared by the transfevent base paper for tipping paper 10 by the grammes per square metre scope is right
Cigarette has best cigarette performance.
In step s 2, the primary coat liquid is coatable in obtaining the priming coat 20 on the transfer membrane 120 of aluminizing.Institute
It states primary coat liquid and can be applied directly to and obtain the priming coat 20 on the transfer membrane 120 of aluminizing.The primary coat liquid is coated
Cheng Zhong, can be good at being attached to it is described aluminize on transfer membrane 120, so as to obtain being firmly attached to the transfer membrane of aluminizing
The priming coat 20 on 120.
Preferably, the solid content of the primary coat liquid is 10%~35%, so that the primary coat liquid has suitable viscosity, from
And make the primary coat liquid that not only there is good adhesion property on the transfer membrane 120 of aluminizing, but also there is good painting
Cover performance.It is further preferable that the solid content of the primary coat liquid is 20%~30%.Preferably, the viscosity of the primary coat liquid is 14
~22s (2# glasss English).It is further preferable that the viscosity of the primary coat liquid is 15~18s (2# glasss English).
Preferably, the molecular weight of the acrylic resin, polyurethane and/or modified nitrocotton is 10000~200000, should
Range not only makes the primary coat liquid have good paintability and adhesion property, but also can obtain continuous, uniform peace
Whole priming coat 20, so as to further increase the aesthetic quality of the transfevent tipping paper 1.It is further preferable that described third
The molecular weight of olefin(e) acid resin, polyurethane and/or modified nitrocotton is 10000~50000.
Preferably, the dry film grammes per square metre of the priming coat 20 is 0.5g/m2To 1.5g/m2, the priming coat of the range is with suitable
Thickness, preferably the ink layer 30 and the transfevent base paper for tipping paper 10 can not only be linked together, Er Qieneng
The transfevent tipping paper 1 is enough set to obtain better cigarette performance.It is further preferable that the dry film grammes per square metre of the priming coat 20 is
0.8g/m2To 1.2g/m2.Preferably, the thickness of the priming coat is 0.5 μm to 3 μm.It is further preferable that the thickness of the priming coat
Degree is 1 μm to 2 μm.
Further, the primary coat liquid is coated on after the transfevent base paper for tipping paper 10, can pass through the method for drying
Obtain the priming coat.Preferably, the drying temperature of the primary coat liquid can be 80 DEG C~125 DEG C, this temperature range both may be used
Quickly the primary coat liquid is dried, and transfevent base paper for tipping paper 10 will not be made to be deformed due to dehydration.Preferably, institute
The drying temperature for stating primary coat liquid can be 90 DEG C~110 DEG C.
In step s3, the ink can be directly coated on obtaining the ink layer 30 on the priming coat 20.Pass through
By the ink coated on the ink layer 30 is formed on the priming coat 20, it can not only make the ink layer well
It is attached on the priming coat 20 and the transfevent base paper for tipping paper 10, and the priming coat 20 goes back the ink layer 30
Have the function of that blast is hyperchromic, can obtain that appearance glossiness higher, ink layer hierarchical structure are clearly more demarcated and aesthetic quality is more excellent
The transfevent tipping paper 1.
Preferably, the thickness of the ink layer can be 0.5 μm to 15 μm, this range can not only make the transfer
Type tipping paper 1 has good cigarette performance, additionally it is possible to so that the transfevent tipping paper 1 has better organoleptic properties.More
For preferably, the thickness of the ink layer can be 5 μm to 10 μm.
Further, the ink is coated on after the priming coat 20, can obtain the ink by the method for drying
Layer 30.Preferably, the drying temperature of the ink layer can be 60 DEG C~100 DEG C.When coating the ink, the transfevent connects
The paper migration velocity for filling paper body paper 10 can be 80m/min~150m/min, this range is more advantageous to the ink in institute
State the coating on priming coat and film forming.
Referring to Fig. 2, second embodiment of the invention provides a kind of transfevent tipping paper 1, the transfevent tipping paper 1 wraps
Include the transfevent base paper for tipping paper 10, priming coat 20 and ink layer 30 being cascading.The material of the priming coat 20 includes
At least one of acrylic resin, polyurethane and modified nitrocotton.The material of the ink layer 30 includes polyethylene glycol contracting fourth
At least one of aldehyde, rosin resin, polyvinyl alcohol and phenolic resin.The ink layer 30 can be good by the priming coat 20
Ground is attached on the transfevent base paper for tipping paper 10, and the priming coat has the function of that blast is hyperchromic to the ink layer 30,
So that the appearance glossiness higher of the transfevent tipping paper 1, ink layer hierarchical structure are clearly more demarcated and aesthetic quality is more excellent.
The institute that the transfevent base paper for tipping paper 10 may include cork paper body paper 110 and be set on cork paper body paper 110
State transfer membrane 120 of aluminizing.The priming coat 20 can be directly arranged at described aluminize on transfer membrane 120.The ink layer 30 can be straight
It connects and is set on the priming coat 20.
Transfevent base paper for tipping paper 10, cork paper body paper 110, transfer membrane 120 of aluminizing in second embodiment of the invention,
Priming coat 20 and ink layer 30 are essentially identical with first embodiment of the invention, and details are not described herein.
Embodiment 1
Selection grammes per square metre is 32.5g/m2Silver color transfevent base paper for tipping paper, using water-based acrylic resin lotion as primary coat
Liquid carries out intaglio printing on the silver color transfevent base paper for tipping paper, and priming coat is formed after drying, and the consolidating for primary coat liquid contains
Amount is 20%, 115 DEG C of drying temperature, and the dry film grammes per square metre of the priming coat is 0.8g/m2；Use alcohol-soluble polyethylene glycol butyral
Ink system carries out intaglio printing on priming coat, and ink layer is formed after drying, obtains transfevent tipping paper.
Embodiment 2
Selection grammes per square metre is 34.5g/m2Golden transfevent base paper for tipping paper, is existed using aqueous polyurethane emulsion as primary coat liquid
Intaglio printing is carried out on the gold transfevent base paper for tipping paper, forms priming coat after drying, the solid content of the primary coat liquid is
24%, the dry film grammes per square metre of 125 DEG C of drying temperature, the priming coat is 1.0g/m2；Existed using alcohol-soluble rosin resin ink system
Intaglio printing is carried out on priming coat, ink layer is formed after drying, obtains transfevent tipping paper.
Comparative example 1
The present embodiment and comparative example 1 are essentially identical, the difference is that, use alcohol-soluble polyethylene glycol butyral ink
System directly carries out intaglio printing, the alcohol-soluble polyethylene glycol butyral ink on the silver color transfevent base paper for tipping paper
System can not be attached on the silver color transfevent base paper for tipping paper, to be unable to get ink layer.
Comparative example 2
The present embodiment and comparative example 1 are essentially identical, the difference is that, with ester soluble ink system directly in the silver
Intaglio printing is carried out on color transfevent base paper for tipping paper, ink layer is formed after drying, to obtain transfevent tipping paper.
Comparative example 3
The present embodiment and comparative example 1 are essentially identical, the difference is that, by water-based acrylic resin lotion and alcohol-soluble
After the mixing of polyethylene glycol butyral ink system, intaglio printing directly is carried out on the silver color transfevent base paper for tipping paper, by
It is unstable in mixed ink, there is demulsifying phenomenon, can not complete to print.
Comparative example 4
The present embodiment and comparative example 1 are essentially identical, the difference is that, by alcohol-soluble polyurethane solution and the poly- second of alcohol-soluble
After the mixing of two butyral ink systems, intaglio printing directly is carried out on the silver color transfevent base paper for tipping paper, after drying
Ink layer is formed, to obtain transfevent tipping paper.
1~4 experimental result contrast table of 1 Examples 1 to 2 of table and comparative example
In the present invention, it by being initially formed priming coat on transfevent base paper for tipping paper, is then formed on priming coat poly-
Ethylene glycol butyral, rosin resin, alcohol-soluble phenolic resin and/or polyvinyl alcohol ink layer, cannot to solve above-mentioned ink layer
The problem being formed directly on the transfevent base paper for tipping paper.In addition, the priming coat also has blast to above-mentioned ink layer
Hyperchromic effect, so that the appearance glossiness higher of the transfevent tipping paper, ink layer hierarchical structure are clearly more demarcated and feel
Official's mass is more excellent.
Each technical characteristic of embodiment described above can be combined arbitrarily, to keep description succinct, not to above-mentioned reality
It applies all possible combination of each technical characteristic in example to be all described, as long as however, the combination of these technical characteristics is not deposited
In contradiction, it is all considered to be the range of this specification record.
Several embodiments of the invention above described embodiment only expresses, the description thereof is more specific and detailed, but simultaneously
It cannot therefore be construed as limiting the scope of the patent.It should be pointed out that coming for those of ordinary skill in the art
It says, without departing from the inventive concept of the premise, various modifications and improvements can be made, these belong to the protection of the present invention
Range.Therefore, the protection domain of patent of the present invention should be determined by the appended claims.
Claims (8)
1. a kind of transfevent tipping paper, which is characterized in that including be cascading transfevent base paper for tipping paper, priming coat and
Ink layer, the transfevent base paper for tipping paper include cork paper body paper and transfer membrane of aluminizing, and the priming coat is directly arranged at institute
It states and aluminizes on transfer membrane, the material of the priming coat includes at least one of acrylic resin, polyurethane and modified nitrocotton；
The material of the ink layer includes at least one of polyethylene glycol butyral, rosin resin, polyvinyl alcohol and phenolic resin.
2. transfevent tipping paper according to claim 1, which is characterized in that the ink layer is directly arranged at the primary coat
On layer.
3. transfevent tipping paper according to claim 1, which is characterized in that the dry film grammes per square metre of the priming coat is 0.5g/m2
To 1.5g/m2, the thickness of the priming coat is 0.5 μm to 3 μm.
4. transfevent tipping paper according to claim 1, which is characterized in that the acrylic resin, polyurethane and modification
The molecular weight of nitrocotton is 10000 ~ 200000.
5. a kind of preparation method of transfevent tipping paper, which is characterized in that including：
Transfevent base paper for tipping paper is provided, the transfevent base paper for tipping paper includes cork paper body paper and transfer membrane of aluminizing；
Primary coat liquid is provided, the primary coat liquid is directly coated on described in the transfevent base paper for tipping paper and is aluminized on transfer membrane,
Formed priming coat, the primary coat liquid include water-based acrylic resin lotion, aqueous polyurethane emulsion, alcohol-soluble polyurethane solution and
At least one of watersoluble modified nitrocotton lotion；And
The coating printing ink on the priming coat forms ink layer, and to obtain the transfevent tipping paper, the ink includes alcohol
Dissolubility polyethylene glycol butyral ink, alcohol-soluble rosin resin ink, alcohol-soluble phenolic resin ink and watersoluble polyvinyl alcohol oil
At least one of ink.
6. the preparation method of transfevent tipping paper according to claim 5, which is characterized in that the solid content of the primary coat liquid
It is 10% ~ 35%, the viscosity of the primary coat liquid is 14s ~ 22s when being measured with English 2# glasss.
7. the preparation method of transfevent tipping paper according to claim 5, which is characterized in that the dry film gram of the priming coat
Weight is 0.5g/m2To 1.5g/m2, the thickness of the priming coat is 0.5 μm to 3 μm.
8. the preparation method of transfevent tipping paper according to claim 5, which is characterized in that the propylene in the primary coat liquid
The molecular weight of acid resin, polyurethane and modified nitrocotton is 10000 ~ 200000.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710228740.4A CN107090741B (en) | 2017-04-10 | 2017-04-10 | Transfevent tipping paper and preparation method thereof |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710228740.4A CN107090741B (en) | 2017-04-10 | 2017-04-10 | Transfevent tipping paper and preparation method thereof |
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| CN107090741A CN107090741A (en) | 2017-08-25 |
| CN107090741B true CN107090741B (en) | 2018-10-19 |
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Families Citing this family (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109294328A (en) * | 2018-10-10 | 2019-02-01 | 玉溪接装纸制造有限公司 | A kind of gravure ink binder and preparation method thereof suitable for tipping paper of aluminizing |
| CN110629591B (en) * | 2019-09-26 | 2022-04-12 | 安徽集友纸业包装有限公司 | Composite transfer paper, preparation method thereof and cigarette packet product |
| CN111501405B (en) * | 2020-04-28 | 2023-03-24 | 安徽集友纸业包装有限公司 | Anti-counterfeiting cigarette tipping paper, preparation method thereof, filter element and smoking product |
| CN112962353A (en) * | 2021-01-29 | 2021-06-15 | 安徽集友纸业包装有限公司 | Cigarette tipping paper and preparation method and application thereof |
| CN113818280B (en) * | 2021-09-29 | 2022-11-29 | 福建中烟工业有限责任公司 | Cigarette tipping paper, preparation method thereof, tobacco product and application |
| CN115726223B (en) * | 2022-12-01 | 2023-10-31 | 安徽集友纸业包装有限公司 | Tipping paper for cigarettes and preparation method and application thereof |
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Inventor after: Xu Shanshui Inventor after: Wang Yunlong Inventor after: Yang Jiangtao Inventor after: Yang Lixin Inventor after: Cao E Inventor after: Yang Erguo Inventor after: Zhao Rongyan Inventor after: Wang Chao Inventor after: Yu Sijun Inventor before: Shu Shanshui Inventor before: Wang Yunlong Inventor before: Yang Jiangtao Inventor before: Yang Lixin Inventor before: Cao E Inventor before: Yang Erguo Inventor before: Zhao Rongyan Inventor before: Wang Chao Inventor before: Yu Sijun |
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