CN107090253A - A kind of antiultraviolet insulation film and its manufacture method - Google Patents

A kind of antiultraviolet insulation film and its manufacture method Download PDF

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Publication number
CN107090253A
CN107090253A CN201710294005.3A CN201710294005A CN107090253A CN 107090253 A CN107090253 A CN 107090253A CN 201710294005 A CN201710294005 A CN 201710294005A CN 107090253 A CN107090253 A CN 107090253A
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Prior art keywords
glue
line
uvioresistant
film
layer
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CN201710294005.3A
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Inventor
杨忠芝
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Dongguan Nali Optical Material Co Ltd
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Dongguan Nali Optical Material Co Ltd
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Priority to CN201710294005.3A priority Critical patent/CN107090253A/en
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    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J7/00—Adhesives in the form of films or foils
    • C09J7/20—Adhesives in the form of films or foils characterised by their carriers
    • C09J7/22—Plastics; Metallised plastics
    • C09J7/24—Plastics; Metallised plastics based on macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
    • C09J7/245—Vinyl resins, e.g. polyvinyl chloride [PVC]
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J7/00—Adhesives in the form of films or foils
    • C09J7/20—Adhesives in the form of films or foils characterised by their carriers
    • C09J7/22—Plastics; Metallised plastics
    • C09J7/25—Plastics; Metallised plastics based on macromolecular compounds obtained otherwise than by reactions involving only carbon-to-carbon unsaturated bonds
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J7/00—Adhesives in the form of films or foils
    • C09J7/20—Adhesives in the form of films or foils characterised by their carriers
    • C09J7/29—Laminated material
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/30—Sulfur-, selenium- or tellurium-containing compounds
    • C08K2003/3009—Sulfides
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/04—Oxygen-containing compounds
    • C08K5/07—Aldehydes; Ketones
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/04—Oxygen-containing compounds
    • C08K5/13—Phenols; Phenolates
    • C08K5/134—Phenols containing ester groups
    • C08K5/1345—Carboxylic esters of phenolcarboxylic acids
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/16—Nitrogen-containing compounds
    • C08K5/17—Amines; Quaternary ammonium compounds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/16—Nitrogen-containing compounds
    • C08K5/315—Compounds containing carbon-to-nitrogen triple bonds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/16—Nitrogen-containing compounds
    • C08K5/34—Heterocyclic compounds having nitrogen in the ring
    • C08K5/3467—Heterocyclic compounds having nitrogen in the ring having more than two nitrogen atoms in the ring
    • C08K5/3472—Five-membered rings
    • C08K5/3475—Five-membered rings condensed with carbocyclic rings
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/16—Nitrogen-containing compounds
    • C08K5/34—Heterocyclic compounds having nitrogen in the ring
    • C08K5/3467—Heterocyclic compounds having nitrogen in the ring having more than two nitrogen atoms in the ring
    • C08K5/3477—Six-membered rings
    • C08K5/3492—Triazines
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J2301/00—Additional features of adhesives in the form of films or foils
    • C09J2301/10—Additional features of adhesives in the form of films or foils characterized by the structural features of the adhesive tape or sheet
    • C09J2301/12—Additional features of adhesives in the form of films or foils characterized by the structural features of the adhesive tape or sheet by the arrangement of layers
    • C09J2301/122—Additional features of adhesives in the form of films or foils characterized by the structural features of the adhesive tape or sheet by the arrangement of layers the adhesive layer being present only on one side of the carrier, e.g. single-sided adhesive tape
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J2301/00—Additional features of adhesives in the form of films or foils
    • C09J2301/30—Additional features of adhesives in the form of films or foils characterized by the chemical, physicochemical or physical properties of the adhesive or the carrier
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J2301/00—Additional features of adhesives in the form of films or foils
    • C09J2301/30—Additional features of adhesives in the form of films or foils characterized by the chemical, physicochemical or physical properties of the adhesive or the carrier
    • C09J2301/312—Additional features of adhesives in the form of films or foils characterized by the chemical, physicochemical or physical properties of the adhesive or the carrier parameters being the characterizing feature
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J2301/00—Additional features of adhesives in the form of films or foils
    • C09J2301/40—Additional features of adhesives in the form of films or foils characterized by the presence of essential components
    • C09J2301/408—Additional features of adhesives in the form of films or foils characterized by the presence of essential components additives as essential feature of the adhesive layer
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J2301/00—Additional features of adhesives in the form of films or foils
    • C09J2301/40—Additional features of adhesives in the form of films or foils characterized by the presence of essential components
    • C09J2301/41—Additional features of adhesives in the form of films or foils characterized by the presence of essential components additives as essential feature of the carrier layer
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J2423/00—Presence of polyolefin
    • C09J2423/04—Presence of homo or copolymers of ethene
    • C09J2423/045—Presence of homo or copolymers of ethene in the release coating
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J2427/00—Presence of halogenated polymer
    • C09J2427/005—Presence of halogenated polymer in the release coating
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J2433/00—Presence of (meth)acrylic polymer
    • C09J2433/006—Presence of (meth)acrylic polymer in the substrate
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J2467/00—Presence of polyester
    • C09J2467/005—Presence of polyester in the release coating
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J2467/00—Presence of polyester
    • C09J2467/006—Presence of polyester in the substrate
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J2469/00—Presence of polycarbonate
    • C09J2469/005—Presence of polycarbonate in the release coating
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
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    • C09J2483/00—Presence of polysiloxane
    • C09J2483/006—Presence of polysiloxane in the substrate

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Laminated Bodies (AREA)

Abstract

The invention discloses a kind of antiultraviolet insulation film and its manufacture method, to reduce the freezing time of the indoor ultraviolet of extremely frigid zones and window.The present invention includes cuticular layer, stripping film, uses layer, it is made up of using layer heat absorption glue-line, base film, uvioresistant glue-line, in base film heat absorption glue-line incorporated above, cuticular layer is set on heat absorption glue-line, uvioresistant glue-line is introduced below base film, stripping film is provided below in uvioresistant glue-line.The present invention is film of the Pasting on window, with good UVResistant effect and good endothermic effect.

Description

A kind of antiultraviolet insulation film and its manufacture method
Technical field
The invention belongs to adhesive foil field of material technology, specifically, a kind of antiultraviolet insulation film is particularly to.
Background technology
In some extremely frigid zones, ultraviolet is stronger；Day and night temperature is big simultaneously, and evening window easily freezes.Existing folder Layer glass be to be made up of a sheet glass together with one or more pieces glass or plastics, although laminated glass have shock resistance, every The performances such as sound, safety, but ultraviolet can not be prevented so that ultraviolet is directly through glassy layer.
The content of the invention
The invention aims to overcome a kind of film of the deficiencies in the prior art there is provided Pasting on window, with Reduce the freezing time of the indoor ultraviolet of extremely frigid zones and window.
To reach above-mentioned purpose, the present invention uses following scheme：
A kind of antiultraviolet insulation film, comprising cuticular layer, stripping film is thin by heat absorption glue-line, base material using layer using layer Film, uvioresistant glue-line composition, in base film heat absorption glue-line incorporated above, set cuticular layer, in base on heat absorption glue-line Uvioresistant glue-line is introduced below material film, stripping film is provided below in uvioresistant glue-line；
Cuticular layer thickness is 25~100 μm, and light transmittance is more than 90%；
Base film thickness is 25~100 μm；
The bondline thickness that absorbs heat is 2~8 μm；
The material component of heat absorption glue of glue-line of absorbing heat is with weight proportion：
Resin is：Silica gel, acrylic glue, pressure sensitive adhesive, one kind of OCA glue；
Heat absorption material be：One kind in FeMnC μm of Ox, Fe3C μm of O5, PbS and combinations thereof；
Auxiliary agent is：Polyoxyethylated alkyl phenol, polyoxyethylene aliphatic alcohol ether, the fatty acid ester compounded thing of higher alcohols, polyoxy second One kind and mixture in alkene polyoxy propyl alcohol amidogen ether；
Solvent is：One kind and mixture in ethyl acetate, toluene, propylene glycol methyl ether acetate；
Vapored away after solvent, preparation are added in preparation；
The material component of uvioresistant glue-line is with weight proportion：
Glue is：Silica gel, acrylic glue, pressure sensitive adhesive, one kind of OCA glue；
Uvioresistant material is：Salicylic acid esters, benzophenone class, benzotriazole, group-substituted acrylonitrile, triazines are with being obstructed One kind or its combination in amine；
Auxiliary agent is：Polyoxyethylated alkyl phenol, polyoxyethylene aliphatic alcohol ether, the fatty acid ester compounded thing of higher alcohols, polyoxy second One kind and mixture in alkene polyoxy propyl alcohol amidogen ether；
Solvent is：One kind and mixture in ethyl acetate, toluene, propylene glycol methyl ether acetate；
Vapored away after solvent, preparation are added in preparation.
Further, in certain embodiments, cuticular layer can be any one in PET, PVC, PC, OPP, PE, wherein Based on PET；
Base film can be any one in PET, PVC, PC, OPP, PE, wherein based on PET；
Stripping film can be any one in PET, PVC, PC, OPP, PE；
Uvioresistant bondline thickness is 15~75 μm.
A kind of preparation method of antiultraviolet insulation film, method is as follows：
With micro- one layer of glue (group added with heat absorption material of gravure roller coating on the base film (PET base material) of 50 μ m-thicks Point：42 parts of resin, absorb heat 15 parts of material, 8 parts of auxiliary agent, 35 parts of solvent), obtained after 150 DEG C of baking oven heat cures after one layer 5 μm Absorbed heat glue-line, and the cuticular layer (PET film) of the μ m-thick of last layer 50 is then covered on heat absorption glue-line；
One layer of silica gel glue (component for being added with uvioresistant auxiliary agent is coated with below base film (PET base material)：Tree 45 parts of fat, 3 parts of ultraviolet light material, 10 parts of auxiliary agent, 42 parts of solvent), obtained after 180 DEG C of baking oven heat cures after one layer 30 μm Uvioresistant glue-line, the stripping film (PET) of the μ m-thick of last layer 40 is then cladded with uvioresistant glue-line, insulation film is obtained.
The present invention is film of the Pasting on window, to reduce the knot of the indoor ultraviolet of extremely frigid zones and winter window The ice time, with good UVResistant effect and good endothermic effect.
Brief description of the drawings
Fig. 1 is the structural representation of the embodiment of the present invention.
Description of reference numerals：
Cuticular layer 11, stripping film 13, using layer 20, absorb heat glue-line 21, base film 22, uvioresistant glue-line 24.
Embodiment
For the feature, technological means and the specific purposes reached, function of the present invention can be further appreciated that, this hair is parsed Bright advantage and spirit, by the present invention is further elaborated by the following examples.
Cuticular layer can be any one in PET, PVC, PC, OPP, PE, wherein based on PET, thickness is 25~100 μm, light transmittance is more than 90%；
Base film 22 can be any one in PET, PVC, PC, OPP, PE, wherein based on PET, thickness is 25 ~100 μm μm.
The coated thereon one of base film 22 heat absorption glue-line 21, plays heat absorption insulation effect.
Main glue silica gel, acrylic glue, pressure sensitive adhesive, the OCA glue of heat absorption glue-line 21 can.Can be photocuring, Can be heat cure, wherein based on heat cure, thickness is 2~8 μm.
Glue-line 21 absorb heat containing heat absorption material, heat absorption material be mainly one kind in FeMnC μm of Ox, Fe3C μm O5, PbS or It is combined.
Below base film 22 one layer of uvioresistant glue-line 24 is scribbled (relative to scribbling above heat absorption glue).Uvioresistant The main glue silica gel of line glue-line 24, acrylic glue, pressure sensitive adhesive, OCA glue can, based on heat cure mode, thickness is 15-75 μm。
Uvioresistant glue-line 24 contains uvioresistant material, mainly salicylic acid esters, benzophenone class, benzotriazole, take For vinyl cyanide, triazines and one kind in hindered amines or its combine.
The lower section of uvioresistant glue-line 24 is covered with one layer of stripping film 13, during stripping film 13 can be PET, PVC, PC, OPP, PE Any one.
During preparation, step is as follows：
With micro- one layer of glue added with heat absorption material of gravure roller coating on the base film 22 (PET base material) of 65 μ m-thicks (component：46 parts of resin, absorb heat 9 parts of material, 10 parts of auxiliary agent, 40 parts of solvent), one layer 3 μm are obtained after 150 DEG C of baking oven heat cures Heat absorption glue-line 21 afterwards, then covers the PET film (cuticular layer 11) of the μ m-thick of last layer 40 on heat absorption glue-line 21；
Solvent is mainly one kind and mixture in ethyl acetate, toluene, propylene glycol methyl ether acetate；
Vapored away after solvent, preparation are added in preparation；
Auxiliary agent is mainly polyoxyethylated alkyl phenol, polyoxyethylene aliphatic alcohol ether, the fatty acid ester compounded thing of higher alcohols, polyoxy One kind and mixture in ethene polyoxy propyl alcohol amidogen ether.
One layer of silica gel glue (component for being added with uvioresistant auxiliary agent is coated with below base film 22 (PET base material)： 60 parts of resin, 1 part of ultraviolet light material, 9 parts of auxiliary agent, 50 parts of solvent), obtained after 180 DEG C of baking oven heat cures after one layer 45 μm Uvioresistant glue-line 24, the stripping film 13 (PET mould release membrances) of the μ m-thick of last layer 50 is then cladded with uvioresistant glue-line 24.It is molten Agent is mainly one kind and mixture in ethyl acetate, toluene, propylene glycol methyl ether acetate；Solvent is added in preparation, after preparation Vapor away.
Auxiliary agent is mainly polyoxyethylated alkyl phenol, polyoxyethylene aliphatic alcohol ether, the fatty acid ester compounded thing of higher alcohols, polyoxy One kind and mixture in ethene polyoxy propyl alcohol amidogen ether.
The ultraviolet protective test of antiultraviolet insulation film of the present invention：
One hundred yuan of banknote is placed in " standard sources is to color case ", Μ MV light sources is opened, treats to show clearly on banknote After watermark, antiultraviolet insulation film (sample thin film) is covered in above banknote, antiultraviolet insulation film (sample is as a result shown Product film) banknote watermark can be shielded completely, show that sample thin film has good UVResistant effect.
The heat absorption experiment test of antiultraviolet insulation film of the present invention：
6 150ml Clear glass bottles and jars are taken, load 100ml pure water, is placed in refrigerator after freezing completely and takes out, immediately Cover rubber stopper, and antiultraviolet insulation film (sample thin film) is sticked outside 3 vials wherein, then in other 3 The individual vial for not pasting sample thin film is together positioned under the same position of sunlight, the same terms, the thawing of ice in observation bottle Time (environment temperature is measured as 23 DEG C)；
As a result it is as shown in the table：
1. 2. 3. it is the vial for having pasted antiultraviolet insulation film, is 4. 5. 6. the vial for not pasting sample thin film；
As a result show after glass bottle sticker antiultraviolet insulation film (sample thin film), the thawing speed of ice substantially adds in bottle It hurry up, it is shown that the good endothermic effect of film.
Embodiment described above only expresses some embodiments of the present invention, and it describes more specific and detailed, but simultaneously Therefore limitation of the scope of the invention can not be interpreted as.It should be pointed out that for the person of ordinary skill of the art, Without departing from the inventive concept of the premise, various modifications and improvements can be made, these belong to the protection model of the present invention Enclose.Therefore, protection scope of the present invention should be determined by the appended claims.

Claims (3)

1. a kind of antiultraviolet insulation film, comprising：Cuticular layer, stripping film uses layer, it is characterised in that using layer by absorbing heat Glue-line, base film, uvioresistant glue-line composition, in base film heat absorption glue-line incorporated above, are set on heat absorption glue-line Cuticular layer, uvioresistant glue-line is introduced below base film, stripping film is provided below in uvioresistant glue-line；
Cuticular layer thickness is 25~100 μm, and light transmittance is more than 90%；
Base film thickness is 25~100 μm；
The bondline thickness that absorbs heat is 2~8 μm；
The material component of heat absorption glue of glue-line of absorbing heat is with weight proportion：
Resin is：Silica gel, acrylic glue, pressure sensitive adhesive, one kind of OCA glue；
Heat absorption material be：One kind in FeMnC μm of Ox, Fe3C μm of O5, PbS and combinations thereof；
Auxiliary agent is：Polyoxyethylated alkyl phenol, polyoxyethylene aliphatic alcohol ether, the fatty acid ester compounded thing of higher alcohols, polyoxyethylene gather One kind and mixture in oxygen propyl alcohol amidogen ether；
Solvent is：One kind and mixture in ethyl acetate, toluene, propylene glycol methyl ether acetate；
Vapored away after solvent, preparation are added in preparation；
The material component of uvioresistant glue-line is with weight proportion：
Glue is：Silica gel, acrylic glue, pressure sensitive adhesive, one kind of OCA glue；
Uvioresistant material is：Salicylic acid esters, benzophenone class, benzotriazole, group-substituted acrylonitrile, triazines and hindered amines In one kind or its combination；
Auxiliary agent is：Polyoxyethylated alkyl phenol, polyoxyethylene aliphatic alcohol ether, the fatty acid ester compounded thing of higher alcohols, polyoxyethylene gather One kind and mixture in oxygen propyl alcohol amidogen ether；
Solvent is：One kind and mixture in ethyl acetate, toluene, propylene glycol methyl ether acetate；
Vapored away after solvent, preparation are added in preparation.
2. a kind of antiultraviolet insulation film according to claim 1, it is characterised in that the cuticular layer is：PET、 Any one in PVC, PC, OPP, PE；
Base film is：Any one in PET, PVC, PC, OPP, PE；
Stripping film is：Any one in PET, PVC, PC, OPP, PE；
Uvioresistant bondline thickness is 15~75 μm.
3. a kind of preparation method of the antiultraviolet insulation film as described in any one of claim 1~2, it is characterised in that method It is as follows：
With micro- one layer of glue added with heat absorption material of gravure roller coating on the base film of 50 μ m-thicks, through 150 DEG C of baking oven thermosettings The glue-line that absorbs heat is obtained after change, then cuticular layer is covered with heat absorption glue-line；
One layer of silica gel glue for being added with uvioresistant auxiliary agent is coated with below base film, after 180 DEG C of baking oven heat cures Uvioresistant glue-line is obtained, then stripping film is covered with outside uvioresistant glue-line, obtains insulation film.
CN201710294005.3A 2017-04-28 2017-04-28 A kind of antiultraviolet insulation film and its manufacture method Pending CN107090253A (en)

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Application Number Priority Date Filing Date Title
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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107901546A (en) * 2017-11-07 2018-04-13 东莞市纳利光学材料有限公司 A kind of anlistatig two-sided cured film of anti-pollution and preparation method thereof
CN108274786A (en) * 2018-01-19 2018-07-13 全椒光太胶粘制品有限公司 A kind of automobile-used barrier material quick forming fabri-cation technique

Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105385377A (en) * 2015-12-30 2016-03-09 常州山由帝杉防护材料制造有限公司 Heat-insulating protective film capable of preventing blue light and ultraviolet light and resisting fog

Patent Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105385377A (en) * 2015-12-30 2016-03-09 常州山由帝杉防护材料制造有限公司 Heat-insulating protective film capable of preventing blue light and ultraviolet light and resisting fog

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107901546A (en) * 2017-11-07 2018-04-13 东莞市纳利光学材料有限公司 A kind of anlistatig two-sided cured film of anti-pollution and preparation method thereof
CN108274786A (en) * 2018-01-19 2018-07-13 全椒光太胶粘制品有限公司 A kind of automobile-used barrier material quick forming fabri-cation technique

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