CN107090215A - A kind of polystyrene protective paint coating - Google Patents

A kind of polystyrene protective paint coating Download PDF

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Publication number
CN107090215A
CN107090215A CN201710477582.6A CN201710477582A CN107090215A CN 107090215 A CN107090215 A CN 107090215A CN 201710477582 A CN201710477582 A CN 201710477582A CN 107090215 A CN107090215 A CN 107090215A
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CN
China
Prior art keywords
polystyrene
protective paint
paint coating
polystyrene protective
present
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201710477582.6A
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Chinese (zh)
Inventor
冯智勇
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Individual
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Individual
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Filing date
Publication date
Application filed by Individual filed Critical Individual
Priority to CN201710477582.6A priority Critical patent/CN107090215A/en
Publication of CN107090215A publication Critical patent/CN107090215A/en
Pending legal-status Critical Current

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Classifications

    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D125/00Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring; Coating compositions based on derivatives of such polymers
    • C09D125/02Homopolymers or copolymers of hydrocarbons
    • C09D125/04Homopolymers or copolymers of styrene
    • C09D125/06Polystyrene
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/08Anti-corrosive paints
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/60Additives non-macromolecular
    • C09D7/61Additives non-macromolecular inorganic
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/66Additives characterised by particle size
    • C09D7/69Particle size larger than 1000 nm
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/03Polymer mixtures characterised by other features containing three or more polymers in a blend

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Nanotechnology (AREA)
  • Inorganic Chemistry (AREA)
  • Paints Or Removers (AREA)

Abstract

The invention discloses a kind of polystyrene protective paint coating, the invention belongs to chemical technology field, its formula is characterized in:It is made up of polystyrene, butanone, dichloromethane, toluene, silicon carbide micro-powder, ultra-fine polytetrafluoroethylwax wax micro mist, fatty acid polyethylene glycol ester, white carbon, methyl tertiary butyl ether(MTBE).The finished product of the present invention can apply to steel anti-corrosion, wood preservation erosion, concrete carbonization preventing and ship, bridge, the surface of all kinds of outdoor indoor hardware equipment, be the coating that its work is protected.The present invention has micron order and the dual coarse structure of nanoscale simultaneously, so just having the super-hydrophobic self-cleaning function of lotus leaf effect, after product using the present invention, the surface long term of object need not manually be cleaned and returned newly from overcoating brush, save substantial amounts of manpower and materials, also do not corroded simultaneously by wind and rain, the service life of 3 times of ordinary polystyrene protective paints, strictly a kind of service life is permanent and super-hydrophobic polystyrene protective paint coating of excellent performance.

Description

A kind of polystyrene protective paint coating
Technical field
The invention belongs to chemical field, the present invention relates to a kind of protective paint coating, and in particular to be a kind of polystyrene Protective paint coating.
Background technology
The work of antirust and protection is always one of great scientific research task both domestic and external.Common polystyrene type protective paint Coating is that one kind can apply to steel anti-corrosion, wood preservation erosion, concrete carbonization preventing, the anti-planktonic organism of hull bottom, deck abrasionproof The protective coating of the structures such as damage.But the polystyrene type of prior art protection lacquer coat does not have hydrophobic self-cleaning function, in short term Manually to clean and be returned newly from overcoating brush, service life is not long, wastes manpower and materials.
The content of invention
The purpose of the present invention is:There is provided it is a kind of there is self-cleaning function, need not manually clean for a long time and from overcoating brush return newly, A large amount of manpower and materials can be saved, not by erosion by wind and rain, service life is permanent and super-hydrophobic polystyrene protective paint of excellent performance Coating.
To achieve the above object, the technical solution adopted in the present invention is a kind of polystyrene protective paint coating, and it is formulated It is characterized in:By polystyrene, butanone, dichloromethane, toluene, silicon carbide micro-powder (0.25um~0.86um particle diameters), ultra-fine poly- What tetrafluoroethene wax micro mist (18nm~88nm particle diameters), fatty acid polyethylene glycol ester, white carbon, methyl tertiary butyl ether(MTBE) were constituted.
The percentage by weight of its component is:
Beneficial effects of the present invention:The present invention is silicon carbide micro-powder (0.25um~0.86um particle diameters), ultra-fine polytetrafluoro The peptizaiton that ethylene waxes micro mist (18nm~88nm particle diameters) is risen by dispersant fatty acid polyethylene glycol ester, is highly dispersed in In polystyrene protective paint, distributive law is more than 97%, after the finished product using the present invention, and paint film formation has the super thin of lotus leaf effect Water self-cleaning surface, the paint film sample of multiple polystyrene protective paints is determined with half ball, the contact angle of its paint film sample and water More than 150 °;Moreover, the observation that sample is carried out by using electron microscope, finds its surface while having micron order and receiving The dual coarse structure of meter level.The finished product of the present invention can apply to steel anti-corrosion, wood preservation erosion, concrete carbonization preventing and ship Oceangoing ship, bridge, the surface of all kinds of outdoor indoor hardware equipment, make the surface of object have the super-hydrophobic self-cleaning function of lotus leaf effect, It need not can manually clean and be returned newly from overcoating brush for a long time, save substantial amounts of manpower and materials, and do not corroded by wind and rain, 3 The service life of times ordinary polystyrene class protective paint, is that a kind of service life is permanent and super-hydrophobic polyphenyl second of excellent performance Alkene protective paint coating.
Embodiment
The following examples are that the present invention is made further to prove, the invention is not restricted to this.
Embodiment one
A kind of polystyrene protective paint coating, its component and weight proportion are as follows:
Embodiment two
A kind of polystyrene protective paint coating, its component and weight proportion are as follows:
Embodiment three
A kind of polystyrene protective paint coating, its component and weight proportion are as follows:
Finished product obtained by the three above embodiment of the present invention is respectively coated on three pieces of slides, surveyed with half ball The contact angle of fixed these three samples and water:
1st, the contact angle of the slide sample of embodiment one and water is 153.1 °
2nd, the contact angle of the slide sample of embodiment two and water is 151.2 °
3rd, the contact angle of the slide sample of embodiment three and water is 152.1 °
The sample of three above embodiment is determined with half ball, finished product its surface wettability of the present invention is all showed For superhydrophobic characteristic.
A kind of polystyrene protective paint coating of the present invention, applies in western district of Guangdong, Duo Jia advertising companies has been supplied, at it Used on the surface of outdoor large advertisement metal structure skeleton;Made comparisons with common polystyrene type protective paint, it is of the invention Product has the super-hydrophobic self-cleaning function of lotus leaf effect, makes the surface of metal structure not by erosion by wind and rain, and permanent light is such as new, Substantial amounts of manpower and materials are saved, product of the invention has the service life of 3 times of ordinary polystyrene protective paints, strictly one Kind of service life is permanent and super-hydrophobic polystyrene protective paint coating of excellent performance.

Claims (2)

1. a kind of polystyrene protective paint coating, it is characterised in that:The percentage by weight of the formula each component is:Polystyrene 25%--38%, butanone 7%--25%, dichloromethane 6%--23%, toluene 22%--38%, silicon carbide micro-powder 5%-- 25%th, ultra-fine polytetrafluoroethylwax wax micro mist 5%--25%, fatty acid polyethylene glycol ester 4%--23%, white carbon 6%--24%, Methyl tertiary butyl ether(MTBE) 6%--24%.
2. a kind of polystyrene protective paint coating according to claim 1, it is characterized in that:Silicon carbide micro-powder 0.25um~ 0.86um particle diameters, ultra-fine polytetrafluoroethylwax wax micro mist 18nm~88nm particle diameters, are risen by dispersant fatty acid polyethylene glycol ester Peptizaiton, be highly dispersed in polystyrene protective paint, distributive law is more than 97%, and using after this finished product, paint film is formed Have the super-hydrophobic self-cleaning surface of lotus leaf effect, the paint film sample of multiple polystyrene protective paints, its paint film are determined with half ball The contact angle of sample and water is more than 150 °.
CN201710477582.6A 2017-06-12 2017-06-12 A kind of polystyrene protective paint coating Pending CN107090215A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201710477582.6A CN107090215A (en) 2017-06-12 2017-06-12 A kind of polystyrene protective paint coating

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201710477582.6A CN107090215A (en) 2017-06-12 2017-06-12 A kind of polystyrene protective paint coating

Publications (1)

Publication Number Publication Date
CN107090215A true CN107090215A (en) 2017-08-25

Family

ID=59640252

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201710477582.6A Pending CN107090215A (en) 2017-06-12 2017-06-12 A kind of polystyrene protective paint coating

Country Status (1)

Country Link
CN (1) CN107090215A (en)

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101456016A (en) * 2008-12-30 2009-06-17 上海纳米技术及应用国家工程研究中心有限公司 Preparation method of polymer hydrophobic surface
CN103409028A (en) * 2013-07-29 2013-11-27 复旦大学 Photocatalytic type self-repairing super-hydrophobic coating and preparation method thereof
CN104046152A (en) * 2014-06-23 2014-09-17 清华大学 Superhydrophobic paint, superhydrophobic coating and preparation method thereof
CN104403453A (en) * 2014-11-16 2015-03-11 重庆大学 Semiconductor superhydrophobic paint and preparation method thereof
CN105315801A (en) * 2015-11-06 2016-02-10 河南大学 Preparation method of SiO2/polymer combined superhydrophobic coating

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101456016A (en) * 2008-12-30 2009-06-17 上海纳米技术及应用国家工程研究中心有限公司 Preparation method of polymer hydrophobic surface
CN103409028A (en) * 2013-07-29 2013-11-27 复旦大学 Photocatalytic type self-repairing super-hydrophobic coating and preparation method thereof
CN104046152A (en) * 2014-06-23 2014-09-17 清华大学 Superhydrophobic paint, superhydrophobic coating and preparation method thereof
CN104403453A (en) * 2014-11-16 2015-03-11 重庆大学 Semiconductor superhydrophobic paint and preparation method thereof
CN105315801A (en) * 2015-11-06 2016-02-10 河南大学 Preparation method of SiO2/polymer combined superhydrophobic coating

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Application publication date: 20170825