CN107088353A - Industrial waste gas purifying processing system - Google Patents
Industrial waste gas purifying processing system Download PDFInfo
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- CN107088353A CN107088353A CN201710378817.6A CN201710378817A CN107088353A CN 107088353 A CN107088353 A CN 107088353A CN 201710378817 A CN201710378817 A CN 201710378817A CN 107088353 A CN107088353 A CN 107088353A
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- Prior art keywords
- chamber
- waste gas
- processing system
- industrial waste
- catalyst
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- 239000007789 gas Substances 0.000 title claims abstract description 35
- 239000002440 industrial waste Substances 0.000 title claims abstract description 21
- 239000003054 catalyst Substances 0.000 claims abstract description 61
- 230000005415 magnetization Effects 0.000 claims abstract description 36
- 238000010521 absorption reaction Methods 0.000 claims abstract description 34
- 230000029087 digestion Effects 0.000 claims abstract description 14
- 239000003595 mist Substances 0.000 claims abstract description 10
- 239000007788 liquid Substances 0.000 claims abstract description 8
- 238000003780 insertion Methods 0.000 claims abstract description 6
- 230000037431 insertion Effects 0.000 claims abstract description 6
- 238000006243 chemical reaction Methods 0.000 claims description 24
- CBENFWSGALASAD-UHFFFAOYSA-N Ozone Chemical compound [O-][O+]=O CBENFWSGALASAD-UHFFFAOYSA-N 0.000 claims description 11
- 238000006555 catalytic reaction Methods 0.000 claims description 9
- 230000004044 response Effects 0.000 claims description 8
- 239000010802 sludge Substances 0.000 claims description 5
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 5
- 239000003814 drug Substances 0.000 claims description 4
- 230000008859 change Effects 0.000 claims description 3
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims 2
- 229910052742 iron Inorganic materials 0.000 claims 1
- MWUXSHHQAYIFBG-UHFFFAOYSA-N nitrogen oxide Inorganic materials O=[N] MWUXSHHQAYIFBG-UHFFFAOYSA-N 0.000 abstract description 23
- 239000002912 waste gas Substances 0.000 abstract description 17
- UCKMPCXJQFINFW-UHFFFAOYSA-N Sulphide Chemical compound [S-2] UCKMPCXJQFINFW-UHFFFAOYSA-N 0.000 abstract description 6
- 239000002253 acid Substances 0.000 abstract description 4
- 239000003500 flue dust Substances 0.000 abstract description 4
- 239000002245 particle Substances 0.000 abstract description 4
- 239000000203 mixture Substances 0.000 abstract description 3
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 description 4
- KDLHZDBZIXYQEI-UHFFFAOYSA-N Palladium Chemical compound [Pd] KDLHZDBZIXYQEI-UHFFFAOYSA-N 0.000 description 4
- 238000010586 diagram Methods 0.000 description 4
- 230000000694 effects Effects 0.000 description 4
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 description 4
- 239000003546 flue gas Substances 0.000 description 3
- 238000000034 method Methods 0.000 description 3
- 230000009467 reduction Effects 0.000 description 3
- 239000010948 rhodium Substances 0.000 description 3
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 2
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 2
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 2
- 150000002500 ions Chemical class 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 230000003647 oxidation Effects 0.000 description 2
- 238000007254 oxidation reaction Methods 0.000 description 2
- 229910052763 palladium Inorganic materials 0.000 description 2
- 239000013618 particulate matter Substances 0.000 description 2
- 229910052697 platinum Inorganic materials 0.000 description 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 1
- RWSOTUBLDIXVET-UHFFFAOYSA-N Dihydrogen sulfide Chemical compound S RWSOTUBLDIXVET-UHFFFAOYSA-N 0.000 description 1
- KRHYYFGTRYWZRS-UHFFFAOYSA-M Fluoride anion Chemical compound [F-] KRHYYFGTRYWZRS-UHFFFAOYSA-M 0.000 description 1
- GRYLNZFGIOXLOG-UHFFFAOYSA-N Nitric acid Chemical compound O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 description 1
- IOVCWXUNBOPUCH-UHFFFAOYSA-N Nitrous acid Chemical compound ON=O IOVCWXUNBOPUCH-UHFFFAOYSA-N 0.000 description 1
- 238000003916 acid precipitation Methods 0.000 description 1
- 235000011114 ammonium hydroxide Nutrition 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 229910000892 beryllide Inorganic materials 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 239000001569 carbon dioxide Substances 0.000 description 1
- 229910002092 carbon dioxide Inorganic materials 0.000 description 1
- QGJOPFRUJISHPQ-NJFSPNSNSA-N carbon disulfide-14c Chemical compound S=[14C]=S QGJOPFRUJISHPQ-NJFSPNSNSA-N 0.000 description 1
- 229910002091 carbon monoxide Inorganic materials 0.000 description 1
- 238000007084 catalytic combustion reaction Methods 0.000 description 1
- 238000003421 catalytic decomposition reaction Methods 0.000 description 1
- 230000003197 catalytic effect Effects 0.000 description 1
- 238000005660 chlorination reaction Methods 0.000 description 1
- 239000000460 chlorine Substances 0.000 description 1
- 229910052801 chlorine Inorganic materials 0.000 description 1
- 238000002485 combustion reaction Methods 0.000 description 1
- 239000000356 contaminant Substances 0.000 description 1
- 230000001186 cumulative effect Effects 0.000 description 1
- 238000000354 decomposition reaction Methods 0.000 description 1
- 238000001514 detection method Methods 0.000 description 1
- 239000000428 dust Substances 0.000 description 1
- 239000000446 fuel Substances 0.000 description 1
- 230000036541 health Effects 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 125000004435 hydrogen atom Chemical class [H]* 0.000 description 1
- 229910000037 hydrogen sulfide Inorganic materials 0.000 description 1
- QSHDDOUJBYECFT-UHFFFAOYSA-N mercury Chemical compound [Hg] QSHDDOUJBYECFT-UHFFFAOYSA-N 0.000 description 1
- 229910052753 mercury Inorganic materials 0.000 description 1
- 239000002923 metal particle Substances 0.000 description 1
- 238000006386 neutralization reaction Methods 0.000 description 1
- 229910017604 nitric acid Inorganic materials 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- 230000008569 process Effects 0.000 description 1
- 238000003672 processing method Methods 0.000 description 1
- 210000002345 respiratory system Anatomy 0.000 description 1
- 229910052703 rhodium Inorganic materials 0.000 description 1
- MHOVAHRLVXNVSD-UHFFFAOYSA-N rhodium atom Chemical compound [Rh] MHOVAHRLVXNVSD-UHFFFAOYSA-N 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 239000000779 smoke Substances 0.000 description 1
- 239000011780 sodium chloride Substances 0.000 description 1
- 238000001179 sorption measurement Methods 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/34—Chemical or biological purification of waste gases
- B01D53/74—General processes for purification of waste gases; Apparatus or devices specially adapted therefor
- B01D53/75—Multi-step processes
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D47/00—Separating dispersed particles from gases, air or vapours by liquid as separating agent
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D47/00—Separating dispersed particles from gases, air or vapours by liquid as separating agent
- B01D47/02—Separating dispersed particles from gases, air or vapours by liquid as separating agent by passing the gas or air or vapour over or through a liquid bath
- B01D47/021—Separating dispersed particles from gases, air or vapours by liquid as separating agent by passing the gas or air or vapour over or through a liquid bath by bubbling the gas through a liquid bath
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/34—Chemical or biological purification of waste gases
- B01D53/46—Removing components of defined structure
- B01D53/54—Nitrogen compounds
- B01D53/56—Nitrogen oxides
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/34—Chemical or biological purification of waste gases
- B01D53/46—Removing components of defined structure
- B01D53/68—Halogens or halogen compounds
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/34—Chemical or biological purification of waste gases
- B01D53/74—General processes for purification of waste gases; Apparatus or devices specially adapted therefor
- B01D53/76—Gas phase processes, e.g. by using aerosols
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/34—Chemical or biological purification of waste gases
- B01D53/74—General processes for purification of waste gases; Apparatus or devices specially adapted therefor
- B01D53/77—Liquid phase processes
- B01D53/78—Liquid phase processes with gas-liquid contact
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/34—Chemical or biological purification of waste gases
- B01D53/74—General processes for purification of waste gases; Apparatus or devices specially adapted therefor
- B01D53/86—Catalytic processes
- B01D53/8603—Removing sulfur compounds
- B01D53/8606—Removing sulfur compounds only one sulfur compound other than sulfur oxides or hydrogen sulfide
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/34—Chemical or biological purification of waste gases
- B01D53/74—General processes for purification of waste gases; Apparatus or devices specially adapted therefor
- B01D53/86—Catalytic processes
- B01D53/8603—Removing sulfur compounds
- B01D53/8612—Hydrogen sulfide
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/34—Chemical or biological purification of waste gases
- B01D53/74—General processes for purification of waste gases; Apparatus or devices specially adapted therefor
- B01D53/86—Catalytic processes
- B01D53/8621—Removing nitrogen compounds
- B01D53/8625—Nitrogen oxides
- B01D53/8628—Processes characterised by a specific catalyst
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/34—Chemical or biological purification of waste gases
- B01D53/74—General processes for purification of waste gases; Apparatus or devices specially adapted therefor
- B01D53/86—Catalytic processes
- B01D53/8621—Removing nitrogen compounds
- B01D53/8625—Nitrogen oxides
- B01D53/8631—Processes characterised by a specific device
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2255/00—Catalysts
- B01D2255/10—Noble metals or compounds thereof
- B01D2255/102—Platinum group metals
- B01D2255/1021—Platinum
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2255/00—Catalysts
- B01D2255/10—Noble metals or compounds thereof
- B01D2255/102—Platinum group metals
- B01D2255/1023—Palladium
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2255/00—Catalysts
- B01D2255/10—Noble metals or compounds thereof
- B01D2255/102—Platinum group metals
- B01D2255/1025—Rhodium
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02A—TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE
- Y02A50/00—TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE in human health protection, e.g. against extreme weather
- Y02A50/20—Air quality improvement or preservation, e.g. vehicle emission control or emission reduction by using catalytic converters
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P70/00—Climate change mitigation technologies in the production process for final industrial or consumer products
- Y02P70/10—Greenhouse gas [GHG] capture, material saving, heat recovery or other energy efficient measures, e.g. motor control, characterised by manufacturing processes, e.g. for rolling metal or metal working
Abstract
A kind of industrial waste gas purifying processing system, including catalyst chamber, magnetization chamber, clear up absorption plant;The catalyst chamber, magnetization chamber are hollow columnar, and catalyst chamber connect with magnetization chamber, and catalyst chamber one end is exhaust gas inlet, and the magnetization chamber other end clears up absorption plant built with clearing up absorbing liquid by being cleared up described in exhaust piping insertion in absorption plant.By waste gas step by step by catalyst chamber, magnetization chamber, clear up absorption plant, first the nitrogen oxides in waste gas, sulfide are removed, while reducing the content of PM10, PM2.5 in flue dust, neutralized again by clearing up absorption plant and the acid mist generated in magnetization chamber and filter out big particle, the concentration and formula of the liquid proportion of digestion pool are determined by the composition of waste gas, flexible modulation, the various harmful components that can be effectively gone in removing exhaust gas by the present invention, while apparatus structure is simple, put into low.
Description
Technical field
The present invention relates to technical field of waste gas treatment, and in particular to a kind of industrial waste gas purifying processing system.
Background technology
Industrial waste gas is that produce in plant area of enterprise fuel combustion and production process various are discharged into containing for air
The general name of contaminant gases.These waste gas have:Carbon dioxide, carbon disulfide, hydrogen sulfide, fluoride, nitrogen oxides, chlorine, chlorination
Hydrogen, carbon monoxide, sulfuric acid (mist) lead mercury, beryllide, flue dust and industrial dust, are discharged into air, can pollute air.These materials
The internal of people is entered by different approach respiratory tracts, the direct generation harm having, what is had also has cumulative effect, can be more serious
Harm people health.
Industrial waste gas processing the active carbon adsorption of principle, Production by Catalytic Combustion Process, catalytic oxidation, acid-base neutralization method, etc.
A variety of principles such as ion method, due to industrial waste gas complicated component, various processing methods are difficult to effectively go being harmful in removing exhaust gas
Material.
The content of the invention
The present invention is in order to solve the above technical problems, provide a kind of industrial waste gas purifying processing system.
The technical problems to be solved by the invention are realized using following technical scheme.
A kind of industrial waste gas purifying processing system, including catalyst chamber, magnetization chamber, clear up absorption plant;The catalyst chamber, magnetic
Change room is hollow columnar, and catalyst chamber is connected with magnetization chamber, and catalyst chamber one end is exhaust gas inlet, and the magnetization chamber other end passes through flue gas leading
Cleared up described in road insertion in absorption plant, clear up absorption plant built with clearing up absorbing liquid.
The catalyst chamber two ends are provided with the front shroud of manhole, back shroud respectively, and annular catalyst reaction hood is placed in
In catalyst chamber, the annular catalyst reaction hood central axis is overlapped with catalyst chamber central axis, the end seal of annular catalyst reaction hood one
Close, another end opening, openend is fixed on back shroud, annular catalyst reaction hood blind end sets aperture, ring towards front shroud
Vortex generator is set on shape catalytic reaction cover blind end inwall.
Manhole diameter on the catalyst chamber front shroud is more than the manhole diameter on back shroud.
The catalysis chamber interior walls set atomizer close to front shroud.
Secondary response cover is set in the annular catalyst reaction hood, and the secondary response cover opening end is fixed on back shroud
On, quadric catalysis is carried out to gas by secondary response cover.
Backflow preventer is set on the catalyst chamber back shroud outer wall, it is to avoid waste gas is flow backwards into catalyst chamber.
The atomizer includes setting water inlet on high-pressure pump, the high pressure pump side wall, and high-pressure pump delivery port one end is set
Cover plate, high-pressure pump delivery port is connected with core body, and mist cover is set on the outside of the core body, and described mist cover one end is fixed on the cover board.
The magnetization chamber interior walls set ozone generator close to catalyst chamber junction, and magnet is close to magnetization chamber interior walls
On, magnetization chamber interior walls, which are located at, sets apparatus for eliminating sludge between ozone generator and magnet.
The magnetization chamber interior walls, which are located on different cross section, is respectively separated 2-4 ozone generator of setting, magnet, scale removal dress
Put.
The absorption plant of clearing up includes clearing up absorption cell, digestion solution be placed in it is described clear up in absorption cell, the flue gas leading
It is connected in road end insertion digestion solution and with blast pipe, clears up and PH meters, thermometer, pressure gauge are set respectively on absorption cell inwall,
The PH meters, thermometer, pressure gauge are connected with data acquisition controller respectively, and the data acquisition controller connects with controller
Connect, the controller is connected with dosing pump, dosing pump discharge pipe, which is stretched into, to be cleared up in absorption cell, and medicament enters from dosing pump inlet tube
Enter.
Beneficial effects of the present invention are:By waste gas step by step by catalyst chamber, magnetization chamber, absorption plant is cleared up, first by waste gas
In nitrogen oxides, sulfide remove, while reduce flue dust in PM10, PM2.5 content, then by clear up absorption plant neutralize
Fall the acid mist generated in magnetization chamber and filter out big particle, the concentration and formula of the liquid proportion of digestion pool by waste gas composition
Determine, flexible modulation, the various harmful components that can be effectively gone in removing exhaust gas by the present invention, while apparatus structure is simple, throw
Enter low.
Brief description of the drawings
Fig. 1 is simplified schematic diagram of the present invention;
Fig. 2 is catalyst chamber schematic cross-section of the present invention;
Fig. 3 is atomizer schematic diagram of the present invention;
Fig. 4 is magnetization chamber schematic diagram of the present invention;
Fig. 5 is that the present invention clears up absorption cell schematic diagram.
Embodiment
In order that the technical means, the inventive features, the objects and the advantages of the present invention are easy to understand, tie below
Conjunction is specifically illustrating, and the present invention is expanded on further.
As shown in figure 1, a kind of industrial waste gas purifying processing system, including catalyst chamber 1, magnetization chamber 2, clear up absorption plant 3;
Catalyst chamber 1, magnetization chamber 2 are hollow columnar, and catalyst chamber 1 is connected with magnetization chamber 2, and the one end of catalyst chamber 1 is exhaust gas inlet, magnetization chamber 2
The other end is cleared up in absorption plant 3 by the insertion of exhaust piping 4, clears up absorption plant 3 built with clearing up absorbing liquid.
Catalyst chamber 1, the section of magnetization chamber 2 are circular or square.
As shown in Fig. 2 the two ends of catalyst chamber 1 are provided with the front shroud 18 of manhole, back shroud 19, front shroud 18 respectively
On manhole diameter be more than manhole diameter on back shroud 19, annular catalyst reaction hood 13 is placed in catalyst chamber 1, ring
The central axis of shape catalytic reaction cover 13 is overlapped with the central axis of catalyst chamber 1, and the one end of annular catalyst reaction hood 13 closing, the other end is opened
Mouthful, openend is fixed on back shroud 19, and the blind end of annular catalyst reaction hood 13 sets aperture 16 towards front shroud 18, and annular is urged
Change and vortex generator 12 is set on the blind end inwall of reaction hood 13, waste gas enters in annular catalyst reaction hood 13 from aperture 16 to be driven
Vortex generator 12 is rotated so as to produce vortex in annular catalyst reaction hood 13, and the inwall of catalyst chamber 1 is set close to the interval of front shroud 18
Atomizer 11 is put, is atomized the waste gas entered in catalyst chamber 1 by atomizer 11, further in annular catalyst reaction hood 13
Interior setting secondary response cover 14, the openend of secondary response cover 14 is fixed on back shroud 19, by secondary response cover 14 to gas
Carry out setting backflow preventer 15 on quadric catalysis, the outer wall of 1 back shroud of catalyst chamber 19, it is to avoid waste gas is flow backwards into catalyst chamber 1.
Fig. 3 show the atomizer 11 in the present invention, and atomizer 11 includes setting on high-pressure pump 112, the side wall of high-pressure pump 112
Water inlet 111, delivery port one end of high-pressure pump 112 sets cover plate 115, and the delivery port of high-pressure pump 112 is connected with core body 113, passes through core
The water that high-pressure pump 112 sprays from delivery port is atomized by body 113, and the outside of core body 113 sets mist cover 114, and the one end of mist cover 114 is consolidated
It is scheduled on cover plate 115.
Magnetization chamber 2 is as shown in figure 4, the inwall of magnetization chamber 2 sets ozone generator 21, magnet close to the junction of catalyst chamber 1
22 are close on the inwall of magnetization chamber 2, the preferred annular magnet of magnet 22, and the inwall of magnetization chamber 2 is located at ozone generator 21 and magnet 22
Between set apparatus for eliminating sludge 23, can the inwall of magnetization chamber 2 be located at different cross section on be respectively separated setting 2-4 ozone generator
21st, magnet 22, apparatus for eliminating sludge 23.
Fig. 4, which is shown in the present invention, clears up absorption plant 3, including clears up absorption cell 311, and digestion solution 301, which is placed in, to be cleared up
In absorption cell 311, it is connected in the end of exhaust piping 4 insertion digestion solution 301 and with blast pipe 304, blast pipe 304 is preferably rectangular
Shape tabular to increase waste gas and the contact area of digestion solution 301, clear up set on the inwall of absorption cell 311 PH count 306, thermometer 307,
Pressure gauge 308, PH meters 306, thermometer 307, pressure gauge 308 are connected with data acquisition controller 310 respectively, by PH meters 306,
Thermometer 307, the detection of pressure gauge 308 clear up in absorption cell 311 indices of digestion solution 301 and feed data back to data acquisition
Controller 310, data acquisition controller 310 is connected with controller 305, and controller 305 is connected with dosing pump 303, dosing pump 303
Outlet, which is stretched into, to be cleared up in absorption cell 311, the outlet pipe end connection guard 309, and medicament is from the inlet tube 302 of dosing pump 303
Into when PH, which counts 306, thermometer 307, pressure gauge 308, detects the indices of digestion solution 301 deviation setting value, by data
Data acquisition controller 310 is fed back to, data acquisition controller 310 sends signal to controller 305, and controller 305, which is sent, to be opened
Dynamic dosing pump 303 is ordered, so as to add medicament to clearing up in absorption cell 311.
Operation principle of the present invention:Industrial waste gas main component is nitrogen oxides (NOx), sulfide (SO2) etc., gas harm
For maximum, while PM10, PM2.5 content are also higher in flue dust.
High-temperature gas enters catalyst chamber 1, and the water smoke that atomizer 11 is generated makes high-temperature gas cool to suitable catalyst
Nitrogen oxides, sulfide in the temperature of reaction, waste gas enter catalyst chamber 1 by annular catalyst reaction hood 13 ((rhodium (Rh), palladium
(Pd), platinum (Pt)) catalytic decomposition.As decomposition reaction NO → 1/2N2+1/2O2, wherein Pt, Pd have to CO, HC oxidation removal
High activity, and Rh has the catalysis reduction excellent to NO, N0 selectively can be reduced to N2 and suppress NH3 generation by it.
Gas produces vortex, waste gas is repeated by catalytic reaction by the aperture high speed impact swirl vane of reaction hood, blade rotation
Reduction.
Effect of atomizer of the present invention:Make particulate matter in flue gas and by the nitrogen oxides and sulfide of catalysis reduction with
Vapor forms larger particle, similar to the formation of acid rain, NO->HNO3, HNO2, acid mist enter in reaction tank and digestion pool
Bases liquid neutralize into harmless salts substances.The effect of high intensity magnet has, adsorbing metal particle, adsorbs charged ion
Grain, further purifies the particulate matter in waste gas
Ozone generator in magnetization chamber, produces substantial amounts of ozone, is with nitrogen oxide reaction generation nitrogen reaction equation:
N2O+O--->N2+O2, N2+O2--->2NO
NO+O3--->NO2+O2, NO2+O--->NO+O2
O3+0--->202
Effect of digestion pool of the present invention:Neutralize remaining acid in magnetization chamber and filter out big particle, the liquid of digestion pool
The concentration and formula of body proportioning are determined by the composition of waste gas.Basis is ammoniacal liquor, sodium chloride etc..
General principle, principal character and the advantages of the present invention of the present invention has been shown and described above.The technology of the industry
Personnel are it should be appreciated that the present invention is not limited to the above embodiments, and that described in above-described embodiment and specification is only the present invention
Preference, be not intended to limit the present invention, without departing from the spirit and scope of the present invention, the present invention also have it is various
Changes and improvements, these changes and improvements all fall within the protetion scope of the claimed invention.The claimed scope of the invention is by institute
Attached claims and its equivalent thereof.
Claims (10)
1. a kind of industrial waste gas purifying processing system, it is characterised in that:Including catalyst chamber, magnetization chamber clears up absorption plant;It is described
Catalyst chamber, magnetization chamber are hollow columnar, and catalyst chamber is connected with magnetization chamber, and catalyst chamber one end is exhaust gas inlet, the magnetization chamber other end
By exhaust piping insert described in clear up in absorption plant, clear up absorption plant built with clearing up absorbing liquid.
2. industrial waste gas purifying processing system as claimed in claim 1, it is characterised in that:The catalyst chamber two ends are set respectively
Front shroud, back shroud with manhole, annular catalyst reaction hood are placed in catalyst chamber, the annular catalyst reaction hood center
Axis is overlapped with catalyst chamber central axis, the closing of annular catalyst reaction hood one end, another end opening, and openend is fixed on back shroud
On, annular catalyst reaction hood blind end sets towards front shroud and vortex is set on aperture, annular catalyst reaction hood blind end inwall
Generator.
3. industrial waste gas purifying processing system as claimed in claim 2, it is characterised in that:Circle on the catalyst chamber front shroud
Shape through-hole diameter is more than the manhole diameter on back shroud.
4. industrial waste gas purifying processing system as claimed in claim 2, it is characterised in that:The catalysis chamber interior walls are close to protecgulum
Plate sets atomizer.
5. industrial waste gas purifying processing system as claimed in claim 2, it is characterised in that:Set in the annular catalyst reaction hood
Secondary response cover is put, the secondary response cover opening end is fixed on back shroud.
6. industrial waste gas purifying processing system as claimed in claim 2, it is characterised in that:On the catalyst chamber back shroud outer wall
Backflow preventer is set.
7. industrial waste gas purifying processing system as claimed in claim 1, it is characterised in that:The atomizer includes high-pressure pump,
Water inlet is set on the high pressure pump side wall, and high-pressure pump delivery port one end sets cover plate, and high-pressure pump delivery port is connected with core body, institute
State and mist cover is set on the outside of core body, described mist cover one end is fixed on the cover board.
8. industrial waste gas purifying processing system as claimed in claim 1, it is characterised in that:The magnetization chamber interior walls are close to urging
Change room junction and ozone generator is set, magnet is close in magnetization chamber interior walls, and magnetization chamber interior walls are located at ozone generator and magnetic
Apparatus for eliminating sludge is set between iron.
9. industrial waste gas purifying processing system as claimed in claim 8, it is characterised in that:The magnetization chamber interior walls are located at difference
Setting 2-4 ozone generator, magnet, apparatus for eliminating sludge are respectively separated on section.
10. industrial waste gas purifying processing system as claimed in claim 1, it is characterised in that:The absorption plant of clearing up includes
Clear up absorption cell, digestion solution be placed in it is described clear up in absorption cell, in the exhaust piping end insertion digestion solution and and blast pipe
Connection, clear up and PH meters, thermometer, pressure gauge be set respectively on absorption cell inwall, the PH meters, thermometer, pressure gauge respectively with
Data acquisition controller is connected, and the data acquisition controller is connected with controller, and the controller is connected with dosing pump, dosing
Pump discharge pipe, which is stretched into, to be cleared up in absorption cell, and medicament enters from dosing pump inlet tube.
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