CN107083833A - Graphene composite material far-infrared negative-ion warms up core electric heating floor and its manufacture craft - Google Patents
Graphene composite material far-infrared negative-ion warms up core electric heating floor and its manufacture craft Download PDFInfo
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- CN107083833A CN107083833A CN201710400871.6A CN201710400871A CN107083833A CN 107083833 A CN107083833 A CN 107083833A CN 201710400871 A CN201710400871 A CN 201710400871A CN 107083833 A CN107083833 A CN 107083833A
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- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 title claims abstract description 130
- 229910021389 graphene Inorganic materials 0.000 title claims abstract description 123
- 239000002131 composite material Substances 0.000 title claims abstract description 83
- 238000005485 electric heating Methods 0.000 title claims abstract description 31
- 238000004519 manufacturing process Methods 0.000 title claims abstract description 17
- 239000000835 fiber Substances 0.000 claims abstract description 85
- 229920000049 Carbon (fiber) Polymers 0.000 claims abstract description 23
- 239000004917 carbon fiber Substances 0.000 claims abstract description 23
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 claims abstract description 23
- 239000002023 wood Substances 0.000 claims abstract description 21
- 239000007787 solid Substances 0.000 claims abstract description 20
- 238000009413 insulation Methods 0.000 claims abstract description 8
- 239000000843 powder Substances 0.000 claims description 102
- 239000003292 glue Substances 0.000 claims description 30
- 238000003756 stirring Methods 0.000 claims description 25
- RSWGJHLUYNHPMX-UHFFFAOYSA-N Abietic-Saeure Natural products C12CCC(C(C)C)=CC2=CCC2C1(C)CCCC2(C)C(O)=O RSWGJHLUYNHPMX-UHFFFAOYSA-N 0.000 claims description 23
- KHPCPRHQVVSZAH-HUOMCSJISA-N Rosin Natural products O(C/C=C/c1ccccc1)[C@H]1[C@H](O)[C@@H](O)[C@@H](O)[C@@H](CO)O1 KHPCPRHQVVSZAH-HUOMCSJISA-N 0.000 claims description 23
- KHPCPRHQVVSZAH-UHFFFAOYSA-N trans-cinnamyl beta-D-glucopyranoside Natural products OC1C(O)C(O)C(CO)OC1OCC=CC1=CC=CC=C1 KHPCPRHQVVSZAH-UHFFFAOYSA-N 0.000 claims description 23
- 241000196324 Embryophyta Species 0.000 claims description 21
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims description 21
- 235000017166 Bambusa arundinacea Nutrition 0.000 claims description 20
- 235000017491 Bambusa tulda Nutrition 0.000 claims description 20
- 241001330002 Bambuseae Species 0.000 claims description 20
- 235000015334 Phyllostachys viridis Nutrition 0.000 claims description 20
- 239000011425 bamboo Substances 0.000 claims description 20
- 150000002500 ions Chemical class 0.000 claims description 15
- 239000000839 emulsion Substances 0.000 claims description 13
- 239000000203 mixture Substances 0.000 claims description 11
- 150000001450 anions Chemical class 0.000 claims description 10
- IDGUHHHQCWSQLU-UHFFFAOYSA-N ethanol;hydrate Chemical compound O.CCO IDGUHHHQCWSQLU-UHFFFAOYSA-N 0.000 claims description 10
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 10
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 9
- 238000000034 method Methods 0.000 claims description 9
- 239000002002 slurry Substances 0.000 claims description 9
- 238000001035 drying Methods 0.000 claims description 8
- 244000007853 Sarothamnus scoparius Species 0.000 claims description 7
- 150000001336 alkenes Chemical class 0.000 claims description 7
- 230000008569 process Effects 0.000 claims description 7
- 238000002156 mixing Methods 0.000 claims description 6
- 238000003556 assay Methods 0.000 claims description 4
- 239000004575 stone Substances 0.000 claims description 4
- -1 string Substances 0.000 claims description 4
- 239000007864 aqueous solution Substances 0.000 claims description 3
- 229910002804 graphite Inorganic materials 0.000 claims description 3
- 239000010439 graphite Substances 0.000 claims description 3
- 239000003610 charcoal Substances 0.000 claims 1
- 125000000325 methylidene group Chemical group [H]C([H])=* 0.000 claims 1
- 239000002121 nanofiber Substances 0.000 claims 1
- HIEHAIZHJZLEPQ-UHFFFAOYSA-M sodium;naphthalene-1-sulfonate Chemical compound [Na+].C1=CC=C2C(S(=O)(=O)[O-])=CC=CC2=C1 HIEHAIZHJZLEPQ-UHFFFAOYSA-M 0.000 claims 1
- 238000010438 heat treatment Methods 0.000 abstract description 13
- 239000000463 material Substances 0.000 abstract description 10
- 230000005855 radiation Effects 0.000 abstract description 5
- 239000002041 carbon nanotube Substances 0.000 abstract description 2
- 238000006243 chemical reaction Methods 0.000 abstract description 2
- 239000002305 electric material Substances 0.000 abstract description 2
- 239000002994 raw material Substances 0.000 abstract description 2
- 150000001875 compounds Chemical class 0.000 description 7
- 229910052799 carbon Inorganic materials 0.000 description 5
- 239000000976 ink Substances 0.000 description 4
- 230000008859 change Effects 0.000 description 3
- 238000005516 engineering process Methods 0.000 description 3
- 230000036541 health Effects 0.000 description 3
- 238000002360 preparation method Methods 0.000 description 3
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 2
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 2
- 238000005034 decoration Methods 0.000 description 2
- 239000000428 dust Substances 0.000 description 2
- 238000005286 illumination Methods 0.000 description 2
- 238000005259 measurement Methods 0.000 description 2
- 239000011347 resin Substances 0.000 description 2
- 229920005989 resin Polymers 0.000 description 2
- 229910052708 sodium Inorganic materials 0.000 description 2
- 239000011734 sodium Substances 0.000 description 2
- 238000010792 warming Methods 0.000 description 2
- 229920000742 Cotton Polymers 0.000 description 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
- 240000007594 Oryza sativa Species 0.000 description 1
- 235000007164 Oryza sativa Nutrition 0.000 description 1
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 1
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- 238000004026 adhesive bonding Methods 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000005540 biological transmission Effects 0.000 description 1
- 229910021393 carbon nanotube Inorganic materials 0.000 description 1
- 239000003245 coal Substances 0.000 description 1
- 229910052802 copper Inorganic materials 0.000 description 1
- 239000010949 copper Substances 0.000 description 1
- 239000011889 copper foil Substances 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 230000005611 electricity Effects 0.000 description 1
- 238000000227 grinding Methods 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 239000004745 nonwoven fabric Substances 0.000 description 1
- 239000011368 organic material Substances 0.000 description 1
- 239000011120 plywood Substances 0.000 description 1
- 238000007639 printing Methods 0.000 description 1
- 238000000746 purification Methods 0.000 description 1
- 230000009467 reduction Effects 0.000 description 1
- 235000009566 rice Nutrition 0.000 description 1
- 238000005070 sampling Methods 0.000 description 1
- 239000000741 silica gel Substances 0.000 description 1
- 229910002027 silica gel Inorganic materials 0.000 description 1
- 230000001954 sterilising effect Effects 0.000 description 1
Classifications
-
- E—FIXED CONSTRUCTIONS
- E04—BUILDING
- E04F—FINISHING WORK ON BUILDINGS, e.g. STAIRS, FLOORS
- E04F15/00—Flooring
- E04F15/02—Flooring or floor layers composed of a number of similar elements
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21F—PAPER-MAKING MACHINES; METHODS OF PRODUCING PAPER THEREON
- D21F11/00—Processes for making continuous lengths of paper, or of cardboard, or of wet web for fibre board production, on paper-making machines
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H11/00—Pulp or paper, comprising cellulose or lignocellulose fibres of natural origin only
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
- D21H17/02—Material of vegetable origin
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
- D21H17/03—Non-macromolecular organic compounds
- D21H17/05—Non-macromolecular organic compounds containing elements other than carbon and hydrogen only
- D21H17/06—Alcohols; Phenols; Ethers; Aldehydes; Ketones; Acetals; Ketals
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
- D21H17/03—Non-macromolecular organic compounds
- D21H17/05—Non-macromolecular organic compounds containing elements other than carbon and hydrogen only
- D21H17/12—Organo-metallic compounds
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
- D21H17/62—Rosin; Derivatives thereof
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
- D21H17/63—Inorganic compounds
- D21H17/64—Alkaline compounds
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H21/00—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties
- D21H21/06—Paper forming aids
- D21H21/08—Dispersing agents for fibres
-
- E—FIXED CONSTRUCTIONS
- E04—BUILDING
- E04F—FINISHING WORK ON BUILDINGS, e.g. STAIRS, FLOORS
- E04F15/00—Flooring
- E04F15/02—Flooring or floor layers composed of a number of similar elements
- E04F15/04—Flooring or floor layers composed of a number of similar elements only of wood or with a top layer of wood, e.g. with wooden or metal connecting members
-
- E—FIXED CONSTRUCTIONS
- E04—BUILDING
- E04F—FINISHING WORK ON BUILDINGS, e.g. STAIRS, FLOORS
- E04F15/00—Flooring
- E04F15/18—Separately-laid insulating layers; Other additional insulating measures; Floating floors
- E04F15/181—Insulating layers integrally formed with the flooring or the flooring elements
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F24—HEATING; RANGES; VENTILATING
- F24D—DOMESTIC- OR SPACE-HEATING SYSTEMS, e.g. CENTRAL HEATING SYSTEMS; DOMESTIC HOT-WATER SUPPLY SYSTEMS; ELEMENTS OR COMPONENTS THEREFOR
- F24D13/00—Electric heating systems
- F24D13/02—Electric heating systems solely using resistance heating, e.g. underfloor heating
- F24D13/022—Electric heating systems solely using resistance heating, e.g. underfloor heating resistances incorporated in construction elements
- F24D13/024—Electric heating systems solely using resistance heating, e.g. underfloor heating resistances incorporated in construction elements in walls, floors, ceilings
-
- H—ELECTRICITY
- H05—ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
- H05B—ELECTRIC HEATING; ELECTRIC LIGHT SOURCES NOT OTHERWISE PROVIDED FOR; CIRCUIT ARRANGEMENTS FOR ELECTRIC LIGHT SOURCES, IN GENERAL
- H05B3/00—Ohmic-resistance heating
- H05B3/10—Heating elements characterised by the composition or nature of the materials or by the arrangement of the conductor
- H05B3/12—Heating elements characterised by the composition or nature of the materials or by the arrangement of the conductor characterised by the composition or nature of the conductive material
- H05B3/14—Heating elements characterised by the composition or nature of the materials or by the arrangement of the conductor characterised by the composition or nature of the conductive material the material being non-metallic
-
- E—FIXED CONSTRUCTIONS
- E04—BUILDING
- E04F—FINISHING WORK ON BUILDINGS, e.g. STAIRS, FLOORS
- E04F2290/00—Specially adapted covering, lining or flooring elements not otherwise provided for
- E04F2290/02—Specially adapted covering, lining or flooring elements not otherwise provided for for accommodating service installations or utility lines, e.g. heating conduits, electrical lines, lighting devices or service outlets
- E04F2290/023—Specially adapted covering, lining or flooring elements not otherwise provided for for accommodating service installations or utility lines, e.g. heating conduits, electrical lines, lighting devices or service outlets for heating
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F24—HEATING; RANGES; VENTILATING
- F24D—DOMESTIC- OR SPACE-HEATING SYSTEMS, e.g. CENTRAL HEATING SYSTEMS; DOMESTIC HOT-WATER SUPPLY SYSTEMS; ELEMENTS OR COMPONENTS THEREFOR
- F24D2200/00—Heat sources or energy sources
- F24D2200/08—Electric heater
-
- H—ELECTRICITY
- H05—ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
- H05B—ELECTRIC HEATING; ELECTRIC LIGHT SOURCES NOT OTHERWISE PROVIDED FOR; CIRCUIT ARRANGEMENTS FOR ELECTRIC LIGHT SOURCES, IN GENERAL
- H05B2203/00—Aspects relating to Ohmic resistive heating covered by group H05B3/00
- H05B2203/017—Manufacturing methods or apparatus for heaters
Landscapes
- Engineering & Computer Science (AREA)
- Architecture (AREA)
- Structural Engineering (AREA)
- Civil Engineering (AREA)
- Chemical & Material Sciences (AREA)
- Mechanical Engineering (AREA)
- General Engineering & Computer Science (AREA)
- Life Sciences & Earth Sciences (AREA)
- Wood Science & Technology (AREA)
- Physics & Mathematics (AREA)
- Combustion & Propulsion (AREA)
- Thermal Sciences (AREA)
- Inorganic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Resistance Heating (AREA)
Abstract
The invention belongs to electrothemic floor field of heating, more particularly to a kind of graphene composite material far-infrared negative-ion warms up core electric heating floor and its manufacture craft.It is connected at the top of heat-insulation layer by glue-line with back side balance layer, it is connected at the top of the balance layer of the back side by glue-line with solid wood composite board or high-density plate, it is connected at the top of solid wood composite board or high-density plate by glue-line with graphene nano far-infrared negative-ion composite fibre conductive exothermal film, it is connected, is connected at the top of solid wood composite board or high-density plate by glue-line with decorative cover with solid wood composite board or high-density plate by glue-line at the top of graphene nano far-infrared negative-ion composite fibre conductive exothermal film.In order to preferably save and play the demand that electric heating floor wants expanded function, the present invention is using current advanced graphene raw material, as heater because grapheme material is the best material of generally acknowledged conductance, thermal conductivity, higher than thermo electric materials such as carbon fiber and CNTs, its electric conversion rate is higher, far infrared radiation is stronger.
Description
Technical field
The invention belongs to electrothemic floor field of heating, more particularly to a kind of graphene composite material far-infrared negative-ion warms up core
Electric heating floor and its manufacture craft.
Background technology
Haze phenomenon causes the replacement of consumption of coal, will promote the development of clean energy resource heating system, wherein just including electricity
Heating, is that electric heating industry creates wide development opportunity.The rise of electric heating, drives the zoarium on floor, a kind of new electrically heating
Warm core floor is quietly risen, and the various three-in-one electric heating floors for integrating health care decoration and warming oneself occurs in the market.
Though appearance is the same, function is simultaneously differed, and service life also all so it is different, be exactly because inner heat part not
Together.
For the kind of existing market, heater has metal, carbon dust ink, organic resin chip, carbon fibre paper layer patch
Pressure, it is good and bad different, such as：Metallic conductive inks, carbon dust electrically conductive ink have power attenuation after using a stage, while this
Electrode used in a little heaters, typically all conductive silver paste printing or conductive gluing copper foil, do electric heating floor compound tense and glue
Incessantly, so the time one long will arc of recess, it is important to which interior contact just has loosening, sparking power reduction floor is scrapped, and
The weaker effect for not having health care at all of far-infrared radiation intensity of these ink, organic resin piece is just more bad to be compounded in one
Rise because the requirement that organic material and wood materials are combined to glue is very high, once make moist i.e. with organic board arc of recess, make floor tight
Deformation can not be used again, and consequence is very serious.
The content of the invention
Core electric heating floor and its system are warmed up it is an object of the invention to provide a kind of graphene composite material far-infrared negative-ion
Make technique, solve present in prior art it is not durable in use enough, the problems such as healthcare function is poor.
The technical scheme is that：
A kind of graphene composite material far-infrared negative-ion warms up core electric heating floor, and the electric heating floor includes decorative cover, solid wood
Composite plate or high-density plate, graphene nano far-infrared negative-ion composite fibre conductive exothermal film, back side balance layer, heat-insulation layer,
Glue-line, concrete structure is as follows：
It is connected at the top of heat-insulation layer by glue-line with back side balance layer, glue-line and solid wood composite board is passed through at the top of the balance layer of the back side
Or high-density plate connection, solid wood composite board or high-density plate top pass through glue-line and the compound fibre of graphene nano far-infrared negative-ion
Tie up multiple by glue-line and solid wood at the top of the connection of conductive exothermal film, graphene nano far-infrared negative-ion composite fibre conductive exothermal film
It is connected at the top of plywood or high-density plate connection, solid wood composite board or high-density plate by glue-line with decorative cover.
Described graphene composite material far-infrared negative-ion warms up core electric heating floor, and graphene nano far-infrared negative-ion is answered
Condensating fiber conductive exothermal film includes：Plant fiber pulp, graphene powder glue, nanometer bamboo carbon fiber powder or nano-far-infrared bear from
Sub- powder, fiber diffusant, in parts by weight, 50~80 parts of plant fiber pulp, 10~30 parts of graphene powder glue, nanometer
5~10 parts of bamboo-carbon fibre powder or nano-far-infrared negative ion powder, 2~5 parts of fiber diffusant.
Described graphene composite material far-infrared negative-ion warms up core electric heating floor, and the composition of plant fiber pulp is as follows, presses
Parts by weight meter, 4~6 parts of sodium hydroxide, 55~65 parts of string, 30~50 parts of water；The composition of graphene powder glue is such as
Under, count by weight, 30~40 parts of graphene powder, 50~60 parts of ethanol water, modified rosin rubber powder emulsion 10~20
Part；In graphene powder, the percentage by weight containing 5~10 layer graphene powders is 30%~50%；Ethanol water is
The aqueous solution mixed by purity 80wt%~90wt% second alcohol and water by 10~20% percentage by weight；Modified rosin glue
Powder emulsion is by modified rosin and ethanol by weight proportion 1：The emulsion that (5~15) are mixed, modified rosin is gum rosin, hydrogen
Change rosin, disproportionated rosin or newtrex；A diameter of 10~100 microns of nanometer bamboo carbon fiber powder, 10~20 microns of length, transmitting
Far infrared release anion number is more than 6500/cubic centimetre；Fiber diffusant uses sodium metnylene bis-naphthalene sulfonate.
Described graphene composite material far-infrared negative-ion warms up the manufacture craft of core electric heating floor, and graphene nano is far red
The manufacturing process of outer anion composite fibre conductive exothermal film is as follows：
Passed through using plant fiber pulp, graphene powder glue, nanometer bamboo carbon fiber powder or nano-far-infrared negative ion powder
Break-in, mix, stir, the system of copying, drying, volume process is made in compacting；In manufacturing process, by break-in, mixing, stir as follows
Process, string is carried out after broom processing by disc mill, makes it easier to be combined with graphene powder glue, is added
Graphene powder glue is mixed, stirred, add fiber diffusant and nanometer bamboo carbon fiber powder or nano-far-infrared bear from
Sub- powder is stirred uniformly, regard graphene nano far-infrared negative-ion composite fibre conductive exothermal film as heat generating core main body.
Described graphene composite material far-infrared negative-ion warms up the manufacture craft of core electric heating floor, makes graphene nano
Far-infrared negative-ion composite fibre conductive exothermal film is comprised the following steps that：
(1) graphene powder surface is made to obtain fully after ethanol water soaks 1~5 hour graphene powder
Purification；
(2) after soak time is met, modified rosin rubber powder emulsion is added, graphene powder is sufficiently mixed, is sufficiently stirred for
Graphene powder glue, stand for standby use are formed afterwards；
(3) string has been ground into broom shape with disc mill to occur, sodium hydroxide, string, water is mixed, are put into
Stirring pool continues to stir, and forms plant fiber pulp；
(4) graphene powder glue is delivered into stirring pool, is mixed 1~5 hour with plant fiber pulp, make plant
Fiber is fully combined to be combined and is integrally formed with graphene powder, string is obtained the abundant parcel of graphene powder；
(5) fiber diffusant and nanometer bamboo carbon fiber powder or nano-far-infrared negative ion powder are added, continues 1~5 hour extremely
Stir, obtain the slurries for preparing graphene nano far-infrared negative-ion composite fibre conductive exothermal film；
(6) need to examine after the completion of mixing, stirring, after the assay was approved, through the system of copying, drying, compacting, form graphene nano
Far-infrared negative-ion composite fibre conductive exothermal film.
Described graphene composite material far-infrared negative-ion warms up the manufacture craft of core electric heating floor, and graphene nano is far red
The resistivity of outer anion composite fibre conductive exothermal film is 40 to 80 Ω cm.
Advantages of the present invention and beneficial effect are：
1st, in order to preferably save and play the demand that electric heating floor wants expanded function, the present invention is using current advanced stone
Black alkene raw material, as heater because grapheme material is the best material of generally acknowledged conductance, thermal conductivity, higher than carbon fiber
With the thermo electric material such as CNT, its electric conversion rate is higher, far infrared radiation is stronger.So, the present invention using graphene with
Other materials is compound to be used as exothermic material.
2nd, graphene be now it has been recognized that conductance highest, heat conduction maximum intensity most fast new material, be far above
Some new materials such as carbon fiber carbon nanotube.The present invention goes out graphite using graphene as heating material with string produced with combination
Alkene nano-far-infrared anion composite fibre conductive heating layer, then by organic silica gel and non-woven fabrics cotton etc. it is compound be made it is various
Shape, by the use of graphene electrically conducting transparent characteristic as electric heating film, with heating efficiency height, uniform distinguishing feature of generating heat.
3rd, the graphene nano far-infrared negative-ion composite fibre conductive heating layer that the present invention makes has surface resistivity
Adjustable the characteristics of, available for antistatic circuit, effectively electric charge can be discharged, while having far infrared transmission and anion to release
The function of putting, plays purifying sterilizing effect, plays a part of again to health.
4th, the present invention uses graphene nano far-infrared negative-ion composite fibre conductive heating layer, can improve electric conductivity, add
Strong thermal conductivity, these indexs are significantly larger than electric conduction of carbon fiber heating property.
5th, graphene nano far-infrared negative-ion composite fibre conductive heating layer of the present invention, with string and Graphene powder
Based on body, supplemented by nanometer bamboo carbon fiber and additive, by grinding, mixing, compound frying, drying compacting, it is compound after make
Form.
6th, compared with existing technology, it is more preferable with string that the technology of the present invention process program employs graphene powder
With reference to, it is combined the graphene nano far-infrared negative-ion composite fibre conductive heating layer electric current after being made and distributes more perfect, hair
Heat is more uniform, and stability is more preferable.Simultaneously as adding nanometer bamboo carbon fiber has far infrared and the function of anion, more
Plus it is environmentally friendly, more healthy.Moreover, bamboo-carbon fibre more has the title of dark fund, it is more perfect by rational technique in manufacturing process,
Increase amount of radiation to improve, the finished product that radiation intensity words are made more has development than existing product.
Brief description of the drawings
Fig. 1 is that graphene composite material far-infrared negative-ion of the present invention warms up core electric heating floor board structure schematic diagram.In figure, 1 dress
Facing；2 solid wood composite boards or high-density plate；3 graphene nano far-infrared negative-ion composite fibre conductive exothermal films；Put down at 4 back sides
Weigh layer；5 heat-insulation layers；6 glue-lines.
Embodiment
As shown in figure 1, graphene composite material far-infrared negative-ion of the present invention warms up core electric heating floor, mainly include：Decoration
Face 1, solid wood composite board or high-density plate 2, graphene nano far-infrared negative-ion composite fibre conductive exothermal film 3, back side balance
Layer 4, heat-insulation layer 5, glue-line 6 etc., concrete structure is as follows：
The top of heat-insulation layer 5 is connected by glue-line 6 with back side balance layer 4, and the top of back side balance layer 4 passes through glue-line 6 and solid wood
Composite plate or high-density plate 2 are connected, and solid wood composite board or the top of high-density plate 2 are born by glue-line 6 and graphene nano far infrared
Ion composite fibre conductive exothermal film 3 is connected, and the top of graphene nano far-infrared negative-ion composite fibre conductive exothermal film 3 passes through
Glue-line 6 is connected with solid wood composite board or high-density plate 2, and solid wood composite board or the top of high-density plate 2 pass through glue-line and decorative cover 1
Connection.
The present invention prepares graphene nano far infrared using Chinese invention patent application (application number 201710096589.3)
Anion composite fibre conductive exothermal film, regard graphene nano far-infrared negative-ion composite fibre conductive exothermal film as heat generating core
Main body, core electric heating floor is warmed up for graphene composite material far-infrared negative-ion.
The preparation method of the graphene nano far-infrared negative-ion composite fibre conductive exothermal film, using string
Slurry, graphene powder glue, nanometer bamboo carbon fiber powder (or nano-far-infrared negative ion powder) etc. by break-in, mix, stir, copy
System, drying, the process such as roll up in compacting and be made.In manufacturing process, by break-in, mix, following process stirred, by string
Carried out by disc mill after broom processing, make it easier to be combined with graphene powder glue, add graphene powder glue
Mixed, stirred, added fiber diffusant and nanometer bamboo carbon fiber powder (or nano-far-infrared negative ion powder) is stirred
Uniformly.Its specific preparation process is as follows：
1st, by graphene powder after ethanol water soaks 1~5 hour, obtain graphene powder surface fully net
Change；
2nd, after soak time is met, modified rosin rubber powder emulsion is added, is sufficiently mixed graphene powder, after being sufficiently stirred for
Form graphene powder glue, stand for standby use；
3rd, string has been ground into broom shape with disc mill to occur, sodium hydroxide, string, water is mixed, are put into
Stirring pool continues to stir, and forms plant fiber pulp；
4th, graphene powder glue is delivered into stirring pool, is mixed 1~5 hour with plant fiber pulp, make plant
Fiber is fully combined to be combined and is integrally formed with graphene powder, string is obtained the abundant parcel of graphene powder；
5th, fiber diffusant and nanometer bamboo carbon fiber powder (or nano-far-infrared negative ion powder) are added, is continued 1~5 hour
To stirring, the slurries for preparing graphene nano far-infrared negative-ion composite fibre conductive exothermal film are obtained；
6th, need to examine after the completion of mixing, stirring, after the assay was approved, through the system of copying, drying, compacting, form graphene nano
Far-infrared negative-ion composite fibre conductive exothermal film.Using 200~300 eye mesh screens in gained slurries 10 centimetres of depth below,
Whether sampling more than three times, press dry moisture, illumination and removes moisture removal, uniform by estimating.Then resistance measurement is carried out, it is desirable to three times
Error is within the scope of 2~5% is interior between above resistance, and resistivity, can be as needed in the range of 2~2000 Ω cm
It is adjusted.
Below, the present invention is further elaborated on by embodiment.
Embodiment 1
In the present embodiment, graphene composite material far-infrared negative-ion warms up the manufacture craft of core electric heating floor, referring to China
Application for a patent for invention (publication number：CN103982937A), its difference is, the compound fibre of graphene nano far-infrared negative-ion
The manufacturing process for tieing up conductive exothermal film is as follows：
Graphene nano far-infrared negative-ion is prepared using Chinese invention patent application (application number 201710096589.3)
Composite fibre conductive exothermal film, regard graphene nano far-infrared negative-ion composite fibre conductive exothermal film as heat generating core main body.
Graphene nano far-infrared negative-ion composite fibre conductive exothermal film, including plant fiber pulp, graphene powder glue
Liquid, nanometer bamboo carbon fiber powder (or nano-far-infrared negative ion powder) and fiber diffusant, in parts by weight, string
(such as：Virgin fibers) 80 parts of slurry, 10 parts of graphene powder glue, nanometer bamboo carbon fiber powder (or nano-far-infrared negative ion powder) 7
Part, 3 parts of fiber diffusant.
The composition of plant fiber pulp is as follows, counts by weight, 5 parts of sodium hydroxide, 60 parts of string, 35 parts of water.Stone
The composition of black alkene powder glue is as follows, counts by weight, 35 parts of graphene powder, 50 parts of ethanol water, modified rosin glue
15 parts of powder emulsion.In graphene powder, the percentage by weight containing 5~10 layer graphene powders is 40%.Ethanol water
It is the aqueous solution with purity 85wt% percentage by weight of the second alcohol and water by 15%.Modified rosin rubber powder emulsion is by changing
Property rosin and ethanol by weight proportion 1：15 emulsions mixed, modified rosin is disproportionated rosin.Nanometer bamboo carbon fiber powder is straight
Footpath is 10~100 microns, 10~20 microns of length, and fiber diffusant uses sodium metnylene bis-naphthalene sulfonate.
In the present embodiment, the preparation process of graphene nano far-infrared negative-ion composite fibre conductive exothermal film is as follows：
(1), by graphene powder after ethanol water soaks 2 hours, obtain graphene powder surface fully net
Change；
(2) after, soak time is met, modified rosin rubber powder emulsion is added, graphene powder is sufficiently mixed, is sufficiently stirred for
Graphene powder glue, stand for standby use are formed afterwards；
(3) string, has been ground into broom shape with disc mill to occur, sodium hydroxide, string, water are mixed, put
Continue to stir to stirring pool, form plant fiber pulp；
(4), graphene powder glue is delivered into stirring pool, mixed 3 hours with plant fiber pulp, makes plant fine
Dimension is fully combined to be combined and is integrally formed with graphene powder, string is obtained the abundant parcel of graphene powder；
(5) fiber diffusant and nanometer bamboo carbon fiber powder (or nano-far-infrared negative ion powder), are added, continues 2 hours extremely
Stir, obtain the slurries for preparing graphene nano far-infrared negative-ion composite fibre conductive exothermal film；
(6), need to examine after the completion of mixing, stirring, after the assay was approved, through the system of copying, drying, compacting, form graphene and receive
Rice far-infrared negative-ion composite fibre conductive exothermal film.Using 300 eye mesh screens in gained slurries 10 centimetres of depth below, take
Whether sample five times, press dry moisture, illumination and removes moisture removal, uniform by estimating.Then carry out resistance measurement, it is desirable to five resistances it
Between error in 2~5% within the scope of.
The present embodiment graphene nano far-infrared negative-ion composite fibre conductive exothermal film, resistivity is 40 to 80 Ω
Cm, can be used as electric heater for warming floor.Using above-mentioned graphene nano far-infrared negative-ion composite fibre conductive exothermal film, on demand
Size is cut out, and electrode is riveted on both sides.Electrode selects the mm wide of copper strips 10~15, and thickness selects 0.05 millimeter, by electrode
It is stand-by after riveting is on graphene nano far-infrared negative-ion composite fibre conductive exothermal film.
Claims (6)
1. a kind of graphene composite material far-infrared negative-ion warms up core electric heating floor, it is characterised in that the electric heating floor includes dress
Facing, solid wood composite board or high-density plate, graphene nano far-infrared negative-ion composite fibre conductive exothermal film, back side balance
Layer, heat-insulation layer, glue-line, concrete structure are as follows：
It is connected at the top of heat-insulation layer by glue-line with back side balance layer, glue-line and solid wood composite board or height is passed through at the top of the balance layer of the back side
Density board is connected, and is led at the top of solid wood composite board or high-density plate by glue-line with graphene nano far-infrared negative-ion composite fibre
Electric heating film is connected, and glue-line and solid wood composite board are passed through at the top of graphene nano far-infrared negative-ion composite fibre conductive exothermal film
Or high-density plate connection, solid wood composite board or high-density plate top are connected by glue-line with decorative cover.
2. warm up core electric heating floor according to the graphene composite material far-infrared negative-ion described in claim 1, it is characterised in that stone
Black alkene nano-far-infrared anion composite fibre conductive exothermal film includes：Plant fiber pulp, graphene powder glue, bamboo charcoal nano
Fiber powder or nano-far-infrared negative ion powder, fiber diffusant, in parts by weight, 50~80 parts of plant fiber pulp, graphite
5~10 parts of 10~30 parts of alkene powder glue, nanometer bamboo carbon fiber powder or nano-far-infrared negative ion powder, fiber diffusant 2~5
Part.
3. warm up core electric heating floor according to the graphene composite material far-infrared negative-ion described in claim 2, it is characterised in that plant
The composition of fibres slurry is as follows, counts by weight, 4~6 parts of sodium hydroxide, 55~65 parts of string, 30~50 parts of water；Stone
The composition of black alkene powder glue is as follows, counts by weight, 30~40 parts of graphene powder, and 50~60 parts of ethanol water changes
10~20 parts of property rosin rubber powder emulsion；In graphene powder, the percentage by weight containing 5~10 layer graphene powders is 30%
~50%；Ethanol water is to be mixed by purity 80wt%~90wt% second alcohol and water by 10~20% percentage by weight
The aqueous solution；Modified rosin rubber powder emulsion is by modified rosin and ethanol by weight proportion 1：The emulsion that (5~15) are mixed, changes
Property rosin be gum rosin, hydrogenated rosin, disproportionated rosin or newtrex；A diameter of 10~100 microns of nanometer bamboo carbon fiber powder, length
10~20 microns of degree, transmitting far infrared release anion number is more than 6500/cubic centimetre；Fiber diffusant uses methylene two
Sodium naphthalene sulfonate.
4. the graphene composite material far-infrared negative-ion described in a kind of one of claims 1 to 3 warms up the making of core electric heating floor
Technique, it is characterised in that the manufacturing process of graphene nano far-infrared negative-ion composite fibre conductive exothermal film is as follows：
Using plant fiber pulp, graphene powder glue, nanometer bamboo carbon fiber powder or nano-far-infrared negative ion powder by break-in,
Mix, stir, the system of copying, drying, volume process is made in compacting；In manufacturing process, by break-in, mix, stir following process,
String is carried out after broom processing by disc mill, makes it easier to be combined with graphene powder glue, graphite is added
Alkene powder glue is mixed, stirred, and adds fiber diffusant and nanometer bamboo carbon fiber powder or nano-far-infrared negative ion powder
It is stirred uniformly, regard graphene nano far-infrared negative-ion composite fibre conductive exothermal film as heat generating core main body.
5. the manufacture craft of core electric heating floor is warmed up according to the graphene composite material far-infrared negative-ion described in claim 4, its
It is characterised by, makes comprising the following steps that for graphene nano far-infrared negative-ion composite fibre conductive exothermal film：
(1) graphene powder surface is made to be fully purified after ethanol water soaks 1~5 hour graphene powder；
(2) after soak time is met, modified rosin rubber powder emulsion is added, graphene powder is sufficiently mixed, is sufficiently stirred for rear shape
Into graphene powder glue, stand for standby use；
(3) string has been ground into broom shape with disc mill to occur, sodium hydroxide, string, water is mixed, stirring is put into
Pond continues to stir, and forms plant fiber pulp；
(4) graphene powder glue is delivered into stirring pool, is mixed 1~5 hour with plant fiber pulp, make string
Fully combined to be combined with graphene powder and be integrally formed, string is obtained the abundant parcel of graphene powder；
(5) fiber diffusant and nanometer bamboo carbon fiber powder or nano-far-infrared negative ion powder are added, continues 1~5 hour to stirring
Uniformly, the slurries for preparing graphene nano far-infrared negative-ion composite fibre conductive exothermal film are obtained；
(6) need to examine after the completion of mixing, stirring, after the assay was approved, through the system of copying, drying, compacting, form graphene nano far red
Outer anion composite fibre conductive exothermal film.
6. the manufacture craft of core electric heating floor is warmed up according to the graphene composite material far-infrared negative-ion described in claim 4 or 5,
Characterized in that, the resistivity of graphene nano far-infrared negative-ion composite fibre conductive exothermal film is 40 to 80 Ω cm.
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