CN107083001A - A kind of door and window advanced composite material (ACM) - Google Patents
A kind of door and window advanced composite material (ACM) Download PDFInfo
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- CN107083001A CN107083001A CN201710448329.8A CN201710448329A CN107083001A CN 107083001 A CN107083001 A CN 107083001A CN 201710448329 A CN201710448329 A CN 201710448329A CN 107083001 A CN107083001 A CN 107083001A
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L33/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
- C08L33/04—Homopolymers or copolymers of esters
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2217—Oxides; Hydroxides of metals of magnesium
- C08K2003/2224—Magnesium hydroxide
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2227—Oxides; Hydroxides of metals of aluminium
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/24—Acids; Salts thereof
- C08K3/26—Carbonates; Bicarbonates
- C08K2003/265—Calcium, strontium or barium carbonate
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/02—Flame or fire retardant/resistant
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/14—Polymer mixtures characterised by other features containing polymeric additives characterised by shape
- C08L2205/16—Fibres; Fibrils
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2312/00—Crosslinking
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- Chemical Kinetics & Catalysis (AREA)
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- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
The invention provides a kind of door and window advanced composite material (ACM), including:30 60 parts of mixed rubber resin, 27 32 parts of thermosetting resin, 10 20 parts of thermoplastic resin, 30 50 parts of phenylethylene ethene cyanogen analog copolymer, 42 49 parts of basalt fibre, 35 50 parts of glass fibre, 10 15 parts of string, 12 parts of 25 parts of fire retardant, 5 15 parts of silica, 13 parts of lauryl sodium sulfate and Sodium Polyacrylate.Door and window advanced composite material (ACM) provided by the present invention has that corrosion-resistant, high temperature resistant, anti-aging, heat transfer coefficient be low, lightweight feature, and manufacturing cost is cheap and is able to ensure that mechanical-physical character, processing characteristics and machinability that door-window section bar should possess.
Description
Technical field
The present invention relates to sash stuff technical field, and in particular to a kind of door and window advanced composite material (ACM).
Background technology
It is used for the material for preparing door and window in the prior art, mainly has aluminium alloy, stainless steel, glass fiber compound material etc. several
Type, but the door-window section bar such as aluminium alloy and stainless steel is not corrosion-resistant, and its heat transfer coefficient is high, make its combination property it is poor,
Energy-saving effect is general and heavier-weight.The heat transfer coefficient of glass fiber compound material door and window is although lower, but glass fibers
The corrosion resistance and ageing resistace for tieing up composite door-window section bar are poor.Because materials'use is improper, profile structure can be caused to set
Meter problem, such as：Complicated, cost is high, is easily damaged and weares and teares between part and part, and in installation process,
Need extra installation tool to be assembled, assembling process is cumbersome, consolidate the problems such as performance is bad.Therefore need to study a kind of use
In the material of door-window section bar, with corrosion-resistant, high temperature resistant, anti-aging, heat transfer coefficient be low, lightweight feature, manufacturing cost is cheap
And it is able to ensure that the door and window composite of mechanical-physical character, processing characteristics and machinability that door-window section bar should possess.
The content of the invention
The purpose of the present invention is that there is provided a kind of door and window advanced composite material (ACM) for problem of the prior art.
In order to achieve the above object, the present invention is achieved through the following technical solutions：
A kind of door and window advanced composite material (ACM), including following raw material:
30-60 parts of mixed rubber resin,
27-32 parts of thermosetting resin,
10-20 parts of thermoplastic resin,
Phenylethylene -30-50 parts of ethene cyanogen analog copolymer,
42-49 parts of basalt fibre,
35-50 parts of glass fibre,
10-15 parts of string,
2-5 parts of fire retardant,
5-15 parts of silica,
1-3 parts of lauryl sodium sulfate,
1-2 parts of Sodium Polyacrylate.
Further, the fire retardant is one or more kinds of combinations in magnesium hydroxide, aluminium hydroxide or calcium carbonate.
Further, the mixed rubber resin is acrylic rubber graft resin and butadiene type grafting rubbers resin
Mix, wherein the weight ratio of acrylic rubber and butadiene type rubber is 10：1.
Further, the thermosetting resin is phenolic resin, Lauxite, melamine formaldehyde resin or polyurethane
In one or more kinds of combinations.
Further, the thermosetting resin is made up of melamine formaldehyde resin with polyurethane, and the melamine-
The weight ratio of formaldehyde resin and polyurethane is 3：11.
Further, the thermoplastic resin includes the acrylic rubber that mass percent is 10-35%, quality hundred
Divide the aromatic ethylene compound that ratio is 39-72% and the ethene cyanogen compound that mass percent is 13-35%.
Further, the phenylethylene-ethene cyanogen analog copolymer is the tree that mean molecule quantity is 200000-300000
Fat.
Further, the string is 20-100 μm of fiber footpath, length 1-5mm chopped fiber.
The present invention compared with prior art, with following beneficial effect：
The present invention is made using mixed rubber resin, thermosetting resin, thermoplastic resin and phenylethylene-ethene cyanogen analog copolymer
Composite has high heat distortion temperature, and mechanical-physical character is high, good as the extrusion processing characteristics of door and window material, with
Existing several lipid door and windows are compared with synthetic resin, and physical property is excellent.Basalt fibre, glass fibre and string plus
Enter, the long-chain of fiber molecule is intertwined, be cross-linked to each other into network, reach on the whole firm, crosslinking net
Fiber can play enhancing, resistance split, toughness reinforcing and heat-insulated effect, prevent stress concentration, reduction composite stress cracking can
Can property, add after fire retardant, silica and lauryl sodium sulfate, further enhance the mechanical strength of composite and fire-retardant
Property, it is easy to the reprocessing in later stage.Aluminium alloy, stainless steel and the glass fibre of the present invention is used simultaneously raw material and traditional door and window
Compared Deng material, quality mitigates significantly, be easy to carry and install.
Embodiment
With reference to embodiment, the invention will be further described.
Embodiment 1
A kind of door and window advanced composite material (ACM), including the following raw material:
30 grams of mixed rubber resin,
27 grams of thermosetting resin,
10 grams of thermoplastic resin,
Phenylethylene -30 grams of ethene cyanogen analog copolymer,
42 grams of basalt fibre,
35 grams of glass fibre,
10 grams of string,
2 grams of fire retardant,
5 grams of silica,
1 gram of lauryl sodium sulfate,
1 gram of Sodium Polyacrylate.
Above-mentioned fire retardant is the mixture of magnesium hydroxide, aluminium hydroxide and calcium carbonate.
Above-mentioned mixed rubber resin is that acrylic rubber graft resin is formed with butadiene type grafting rubbers mixed with resin,
Wherein the weight ratio of acrylic rubber and butadiene type rubber is 10：1.
Above-mentioned thermosetting resin is the mixture of phenolic resin, Lauxite, melamine formaldehyde resin and polyurethane.
Above-mentioned thermosetting resin is made up of melamine formaldehyde resin with polyurethane, melamine formaldehyde resin and poly- ammonia
The weight ratio of ester is 3：11.
Above-mentioned thermoplastic resin includes the acrylic rubber that mass percent is 10%, and mass percent is 39%
Aromatic ethylene compound and the ethene cyanogen compound that mass percent is 13%.
Above-mentioned phenylethylene-ethene cyanogen analog copolymer is the resin that mean molecule quantity is 200000.
Above-mentioned string is 20 μm of fiber footpath, length 1mm chopped fiber.
Embodiment 2
A kind of door and window advanced composite material (ACM), including following raw material:
60 grams of mixed rubber resin,
32 grams of thermosetting resin,
20 grams of thermoplastic resin,
Phenylethylene -50 grams of ethene cyanogen analog copolymer,
49 grams of basalt fibre,
50 grams of glass fibre,
15 grams of string,
5 grams of fire retardant,
5 grams of silica 1,
3 grams of lauryl sodium sulfate,
2 grams of Sodium Polyacrylate.
Above-mentioned fire retardant is the mixture of magnesium hydroxide, aluminium hydroxide and calcium carbonate.
Above-mentioned mixed rubber resin is that acrylic rubber graft resin is formed with butadiene type grafting rubbers mixed with resin,
Wherein the weight ratio of acrylic rubber and butadiene type rubber is 10：1.
Above-mentioned thermosetting resin is the mixture of phenolic resin, Lauxite, melamine formaldehyde resin and polyurethane.
Above-mentioned thermosetting resin is made up of melamine formaldehyde resin with polyurethane, melamine formaldehyde resin and poly- ammonia
The weight ratio of ester is 3：11.
Above-mentioned thermoplastic resin includes the acrylic rubber that mass percent is 35%, and mass percent is 72%
Aromatic ethylene compound and the ethene cyanogen compound that mass percent is 35%.
Above-mentioned phenylethylene-ethene cyanogen analog copolymer is the resin that mean molecule quantity is 300000.
Above-mentioned string is 100 μm of fiber footpath, length 5mm chopped fiber.
Embodiment 3
A kind of door and window advanced composite material (ACM), including following weight in grams raw material:
45 grams of mixed rubber resin,
30 grams of thermosetting resin,
15 grams of thermoplastic resin,
Phenylethylene -40 grams of ethene cyanogen analog copolymer,
46 grams of basalt fibre,
43 grams of glass fibre,
13 grams of string,
3 grams of fire retardant,
0 gram of silica 1,
2 grams of lauryl sodium sulfate,
1 gram of Sodium Polyacrylate.
Above-mentioned fire retardant is the mixture of magnesium hydroxide, aluminium hydroxide and calcium carbonate.
Above-mentioned mixed rubber resin is that acrylic rubber graft resin is formed with butadiene type grafting rubbers mixed with resin,
Wherein the weight ratio of acrylic rubber and butadiene type rubber is 10：1.
Above-mentioned thermosetting resin is the mixture of phenolic resin, Lauxite, melamine formaldehyde resin and polyurethane.
Above-mentioned thermosetting resin is made up of melamine formaldehyde resin with polyurethane, melamine formaldehyde resin and poly- ammonia
The weight ratio of ester is 3：11.
Above-mentioned thermoplastic resin includes the acrylic rubber that mass percent is 20%, and mass percent is 50%
Aromatic ethylene compound and the ethene cyanogen compound that mass percent is 23%.
Above-mentioned phenylethylene-ethene cyanogen analog copolymer is the resin that mean molecule quantity is 200000-300000.
Above-mentioned string is 60 μm of fiber footpath, length 3mm chopped fiber.
Embodiment 4
The door and window composite provided using embodiment 1-3 enters row index test and appraisal, as a result as shown in table 1：
| Tensile strength（N/mm2) | Corrosion resistance | Average grain size（mm） | Vickers hardness（HV, kg/mm2） | |
| Embodiment 1 | 550 | EA | 0.02 | 630 |
| Embodiment 2 | 548 | EA | 0.02 | 632 |
| Embodiment 3 | 557 | EA | 0.02 | 641 |
Table 1
Wherein, corrosion resistance is provided by national standard GB/T6892-2006, and small blister scar, crackle, thin slice or powder occurs in surface,
It is qualified only with phenomenon (EA) level being slightly separated；There is obvious layering in surface, and penetrates phenomenon (EB-ED) level into metal
To be unqualified.
The present invention is using mixed rubber resin, thermosetting resin, thermoplastic resin and phenylethylene-ethene cyanogen class copolymerization
Thing, makes composite have high heat distortion temperature, and mechanical-physical character is high, good as the extrusion processing characteristics of door and window material
Good, compared with existing several lipid door and window synthetic resin, physical property is excellent.Basalt fibre, glass fibre and string
Addition, the long-chain of fiber molecule is intertwined, be cross-linked to each other into network, reach firm, cross-linked network on the whole
The fiber of shape can play enhancing, resistance split, toughness reinforcing and heat-insulated effect, prevent stress concentration, reduce composite stress cracking
Possibility, add after fire retardant, silica and lauryl sodium sulfate, further enhance composite mechanical strength and
Anti-flammability, while the raw material that the present invention is used is compared with the materials such as the aluminium alloy, stainless steel and glass fibre of traditional door and window, matter
Amount mitigates significantly, is easy to carry and installs.
The preferred embodiments of the present invention are these are only, are not intended to limit the invention, although with reference to the foregoing embodiments
The present invention is described in detail, for those skilled in the art, it still can be to foregoing embodiments institute
The technical scheme of record is modified, or carries out equivalent substitution to which part technical characteristic.It is all the present invention spirit and
Within principle, any modification, equivalent substitution and improvements made etc. should be included in the scope of the protection.
Claims (8)
1. a kind of door and window advanced composite material (ACM), it is characterised in that including following raw material:
30-60 parts of mixed rubber resin,
27-32 parts of thermosetting resin,
10-20 parts of thermoplastic resin,
Phenylethylene -30-50 parts of ethene cyanogen analog copolymer,
42-49 parts of basalt fibre,
35-50 parts of glass fibre,
10-15 parts of string,
2-5 parts of fire retardant,
5-15 parts of silica,
1-3 parts of lauryl sodium sulfate,
1-2 parts of Sodium Polyacrylate.
2. a kind of door and window advanced composite material (ACM) according to claim 1, it is characterised in that the fire retardant is hydroxide
One or more kinds of combinations in magnesium, aluminium hydroxide or calcium carbonate.
3. a kind of door and window advanced composite material (ACM) according to claim 1, it is characterised in that the mixed rubber resin is
Acrylic rubber graft resin is formed with butadiene type grafting rubbers mixed with resin, wherein acrylic rubber and butadiene type
The weight ratio of rubber is 10：1.
4. a kind of door and window advanced composite material (ACM) according to claim 1, it is characterised in that the thermosetting resin is phenol
One or more kinds of combinations in urea formaldehyde, Lauxite, melamine formaldehyde resin or polyurethane.
5. a kind of door and window advanced composite material (ACM) according to claim 1, it is characterised in that the thermosetting resin is by three
Poly cyanamid-formaldehyde resin is constituted with polyurethane, and the weight ratio of the melamine formaldehyde resin and polyurethane is 3：11.
6. a kind of door and window advanced composite material (ACM) according to claim 1, it is characterised in that wrapped in the thermoplastic resin
Include the acrylic rubber that mass percent is 10-35%, aromatic ethylene compound and matter that mass percent is 39-72%
Measure the ethene cyanogen compound that percentage is 13-35%.
7. a kind of door and window advanced composite material (ACM) according to claim 1, it is characterised in that the phenylethylene-ethene
Cyanogen analog copolymer is the resin that mean molecule quantity is 200000-300000.
8. a kind of door and window advanced composite material (ACM) according to claim 1, it is characterised in that the string is fiber
20-100 μm of footpath, length 1-5mm chopped fiber.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710448329.8A CN107083001A (en) | 2017-06-14 | 2017-06-14 | A kind of door and window advanced composite material (ACM) |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710448329.8A CN107083001A (en) | 2017-06-14 | 2017-06-14 | A kind of door and window advanced composite material (ACM) |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN107083001A true CN107083001A (en) | 2017-08-22 |
Family
ID=59605684
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201710448329.8A Withdrawn CN107083001A (en) | 2017-06-14 | 2017-06-14 | A kind of door and window advanced composite material (ACM) |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN107083001A (en) |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103421255A (en) * | 2012-05-22 | 2013-12-04 | 韩国锦湖石油化学株式会社 | Composition for environmentally friendly door and window materials and with excellent heat resistance and dyeing properties |
| CN103421256A (en) * | 2012-05-22 | 2013-12-04 | 韩国锦湖石油化学株式会社 | Composition containing inorganic filling materials and fiber reinforced materials and for environmentally friendly door and window materials and preparation method |
| CN104059326A (en) * | 2014-06-23 | 2014-09-24 | 四川航天五源复合材料有限公司 | Basalt fiber composite door and window section bar |
-
2017
- 2017-06-14 CN CN201710448329.8A patent/CN107083001A/en not_active Withdrawn
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103421255A (en) * | 2012-05-22 | 2013-12-04 | 韩国锦湖石油化学株式会社 | Composition for environmentally friendly door and window materials and with excellent heat resistance and dyeing properties |
| CN103421256A (en) * | 2012-05-22 | 2013-12-04 | 韩国锦湖石油化学株式会社 | Composition containing inorganic filling materials and fiber reinforced materials and for environmentally friendly door and window materials and preparation method |
| CN104059326A (en) * | 2014-06-23 | 2014-09-24 | 四川航天五源复合材料有限公司 | Basalt fiber composite door and window section bar |
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Application publication date: 20170822 |
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