CN107057607B - A kind of butyl rubber hot-fusible pressure-sensitive adhesive and preparation method thereof of cohesion enhancing - Google Patents
A kind of butyl rubber hot-fusible pressure-sensitive adhesive and preparation method thereof of cohesion enhancing Download PDFInfo
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- CN107057607B CN107057607B CN201710383323.7A CN201710383323A CN107057607B CN 107057607 B CN107057607 B CN 107057607B CN 201710383323 A CN201710383323 A CN 201710383323A CN 107057607 B CN107057607 B CN 107057607B
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- butyl rubber
- sensitive adhesive
- mill
- fusible pressure
- butyl
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- 229920005549 butyl rubber Polymers 0.000 title claims abstract description 64
- 239000004820 Pressure-sensitive adhesive Substances 0.000 title claims abstract description 43
- 230000002708 enhancing effect Effects 0.000 title claims abstract description 16
- 238000002360 preparation method Methods 0.000 title claims abstract description 10
- 229920005989 resin Polymers 0.000 claims abstract description 50
- 239000011347 resin Substances 0.000 claims abstract description 50
- 239000003963 antioxidant agent Substances 0.000 claims abstract description 19
- 230000003078 antioxidant effect Effects 0.000 claims abstract description 19
- 239000004014 plasticizer Substances 0.000 claims abstract description 19
- 239000011159 matrix material Substances 0.000 claims abstract description 13
- 239000012763 reinforcing filler Substances 0.000 claims abstract description 12
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 claims description 16
- 229920002367 Polyisobutene Polymers 0.000 claims description 12
- -1 2- ethyl imidazol Chemical compound 0.000 claims description 11
- 150000003505 terpenes Chemical class 0.000 claims description 9
- 235000007586 terpenes Nutrition 0.000 claims description 9
- 229910000019 calcium carbonate Inorganic materials 0.000 claims description 8
- 239000003292 glue Substances 0.000 claims description 8
- 239000005995 Aluminium silicate Substances 0.000 claims description 5
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 5
- 235000012211 aluminium silicate Nutrition 0.000 claims description 5
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 claims description 5
- 229920000468 styrene butadiene styrene block copolymer Polymers 0.000 claims description 5
- MCMFEZDRQOJKMN-UHFFFAOYSA-N 1-butylimidazole Chemical class CCCCN1C=CN=C1 MCMFEZDRQOJKMN-UHFFFAOYSA-N 0.000 claims description 4
- XBDQKXXYIPTUBI-UHFFFAOYSA-N dimethylselenoniopropionate Natural products CCC(O)=O XBDQKXXYIPTUBI-UHFFFAOYSA-N 0.000 claims description 4
- OSSNTDFYBPYIEC-UHFFFAOYSA-N 1-ethenylimidazole Chemical class C=CN1C=CN=C1 OSSNTDFYBPYIEC-UHFFFAOYSA-N 0.000 claims description 3
- WKBOTKDWSSQWDR-UHFFFAOYSA-N Bromine atom Chemical compound [Br] WKBOTKDWSSQWDR-UHFFFAOYSA-N 0.000 claims description 3
- GDTBXPJZTBHREO-UHFFFAOYSA-N bromine Substances BrBr GDTBXPJZTBHREO-UHFFFAOYSA-N 0.000 claims description 3
- 229910052794 bromium Inorganic materials 0.000 claims description 3
- 239000006229 carbon black Substances 0.000 claims description 3
- FPAFDBFIGPHWGO-UHFFFAOYSA-N dioxosilane;oxomagnesium;hydrate Chemical compound O.[Mg]=O.[Mg]=O.[Mg]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O FPAFDBFIGPHWGO-UHFFFAOYSA-N 0.000 claims description 3
- 125000002883 imidazolyl group Chemical group 0.000 claims description 3
- 239000000203 mixture Substances 0.000 claims description 2
- 150000008301 phosphite esters Chemical class 0.000 claims description 2
- 235000019260 propionic acid Nutrition 0.000 claims description 2
- IUVKMZGDUIUOCP-BTNSXGMBSA-N quinbolone Chemical compound O([C@H]1CC[C@H]2[C@H]3[C@@H]([C@]4(C=CC(=O)C=C4CC3)C)CC[C@@]21C)C1=CCCC1 IUVKMZGDUIUOCP-BTNSXGMBSA-N 0.000 claims description 2
- VSKJLJHPAFKHBX-UHFFFAOYSA-N 2-methylbuta-1,3-diene;styrene Chemical compound CC(=C)C=C.C=CC1=CC=CC=C1.C=CC1=CC=CC=C1 VSKJLJHPAFKHBX-UHFFFAOYSA-N 0.000 claims 1
- 238000012661 block copolymerization Methods 0.000 claims 1
- 238000007670 refining Methods 0.000 claims 1
- 230000002441 reversible effect Effects 0.000 abstract description 2
- 229920001971 elastomer Polymers 0.000 description 13
- 229920000346 polystyrene-polyisoprene block-polystyrene Polymers 0.000 description 8
- 125000000484 butyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 7
- 238000000034 method Methods 0.000 description 7
- 230000001070 adhesive effect Effects 0.000 description 6
- 238000005984 hydrogenation reaction Methods 0.000 description 6
- 239000000853 adhesive Substances 0.000 description 5
- 230000031709 bromination Effects 0.000 description 5
- 238000005893 bromination reaction Methods 0.000 description 5
- 239000003795 chemical substances by application Substances 0.000 description 5
- 150000002500 ions Chemical class 0.000 description 5
- 238000004073 vulcanization Methods 0.000 description 5
- 238000004132 cross linking Methods 0.000 description 4
- 239000012943 hotmelt Substances 0.000 description 4
- 150000002460 imidazoles Chemical class 0.000 description 4
- MYRTYDVEIRVNKP-UHFFFAOYSA-N 1,2-Divinylbenzene Chemical compound C=CC1=CC=CC=C1C=C MYRTYDVEIRVNKP-UHFFFAOYSA-N 0.000 description 2
- CPELXLSAUQHCOX-UHFFFAOYSA-M Bromide Chemical compound [Br-] CPELXLSAUQHCOX-UHFFFAOYSA-M 0.000 description 2
- 239000012752 auxiliary agent Substances 0.000 description 2
- 239000011248 coating agent Substances 0.000 description 2
- 238000000576 coating method Methods 0.000 description 2
- 230000000052 comparative effect Effects 0.000 description 2
- QXYJCZRRLLQGCR-UHFFFAOYSA-N dioxomolybdenum Chemical compound O=[Mo]=O QXYJCZRRLLQGCR-UHFFFAOYSA-N 0.000 description 2
- 238000009413 insulation Methods 0.000 description 2
- 230000002427 irreversible effect Effects 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- VXNZUUAINFGPBY-UHFFFAOYSA-N 1-Butene Chemical compound CCC=C VXNZUUAINFGPBY-UHFFFAOYSA-N 0.000 description 1
- KXGFMDJXCMQABM-UHFFFAOYSA-N 2-methoxy-6-methylphenol Chemical compound [CH]OC1=CC=CC([CH])=C1O KXGFMDJXCMQABM-UHFFFAOYSA-N 0.000 description 1
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- 244000147058 Derris elliptica Species 0.000 description 1
- 241000255925 Diptera Species 0.000 description 1
- 239000004743 Polypropylene Substances 0.000 description 1
- 239000004902 Softening Agent Substances 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 230000003712 anti-aging effect Effects 0.000 description 1
- 230000000712 assembly Effects 0.000 description 1
- 238000000429 assembly Methods 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 229940006460 bromide ion Drugs 0.000 description 1
- IAQRGUVFOMOMEM-UHFFFAOYSA-N butene Natural products CC=CC IAQRGUVFOMOMEM-UHFFFAOYSA-N 0.000 description 1
- 229910052791 calcium Inorganic materials 0.000 description 1
- 239000011575 calcium Substances 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 239000000945 filler Substances 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 229920000554 ionomer Polymers 0.000 description 1
- 125000000959 isobutyl group Chemical group [H]C([H])([H])C([H])(C([H])([H])[H])C([H])([H])* 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 1
- 125000004433 nitrogen atom Chemical group N* 0.000 description 1
- SSDSCDGVMJFTEQ-UHFFFAOYSA-N octadecyl 3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoate Chemical compound CCCCCCCCCCCCCCCCCCOC(=O)CCC1=CC(C(C)(C)C)=C(O)C(C(C)(C)C)=C1 SSDSCDGVMJFTEQ-UHFFFAOYSA-N 0.000 description 1
- WXZMFSXDPGVJKK-UHFFFAOYSA-N pentaerythritol Chemical class OCC(CO)(CO)CO WXZMFSXDPGVJKK-UHFFFAOYSA-N 0.000 description 1
- 229920001568 phenolic resin Polymers 0.000 description 1
- 229920001155 polypropylene Polymers 0.000 description 1
- 230000008092 positive effect Effects 0.000 description 1
- 239000012744 reinforcing agent Substances 0.000 description 1
- 239000012945 sealing adhesive Substances 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 238000006467 substitution reaction Methods 0.000 description 1
- 238000005987 sulfurization reaction Methods 0.000 description 1
- 239000004094 surface-active agent Substances 0.000 description 1
- XZZNDPSIHUTMOC-UHFFFAOYSA-N triphenyl phosphate Chemical compound C=1C=CC=CC=1OP(OC=1C=CC=CC=1)(=O)OC1=CC=CC=C1 XZZNDPSIHUTMOC-UHFFFAOYSA-N 0.000 description 1
- 229920002554 vinyl polymer Polymers 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
- 239000000080 wetting agent Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J123/00—Adhesives based on homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Adhesives based on derivatives of such polymers
- C09J123/02—Adhesives based on homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Adhesives based on derivatives of such polymers not modified by chemical after-treatment
- C09J123/18—Homopolymers or copolymers of hydrocarbons having four or more carbon atoms
- C09J123/20—Homopolymers or copolymers of hydrocarbons having four or more carbon atoms having four to nine carbon atoms
- C09J123/22—Copolymers of isobutene; Butyl rubber ; Homo- or copolymers of other iso-olefines
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F8/00—Chemical modification by after-treatment
- C08F8/30—Introducing nitrogen atoms or nitrogen-containing groups
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/02—Non-macromolecular additives
- C09J11/04—Non-macromolecular additives inorganic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/02—Non-macromolecular additives
- C09J11/06—Non-macromolecular additives organic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/08—Macromolecular additives
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/24—Acids; Salts thereof
- C08K3/26—Carbonates; Bicarbonates
- C08K2003/265—Calcium, strontium or barium carbonate
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
- C08L2205/025—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
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- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Inorganic Chemistry (AREA)
- Adhesives Or Adhesive Processes (AREA)
Abstract
The invention discloses a kind of butyl rubber hot-fusible pressure-sensitive adhesives of cohesion enhancing, and component and parts by weight are:Butyl rubber 10 35%, brombutyl 3 20%, other matrix resins 3 18%, imdazole derivatives 0.05 1%, tackifying resin 10 35%, plasticizer 5 35%, reinforcing filler 18 55%, antioxidant 0.1 0.6%.The invention also discloses preparation methods.The butyl rubber hot-fusible pressure-sensitive adhesive of the present invention has reversible hot-workability, has be coated with cohesive ability again in a heated state.
Description
Technical field
The present invention relates to butyl rubber hot-fusible pressure-sensitive adhesive fields, are heated more particularly to a kind of butyl rubber of cohesion enhancing
Pressure sensitive adhesive and preparation method thereof.
Background technology
Pressure sensitive adhesive is a kind of material for implementing interfacial adhesion by pressure.According to matrix resin ingredient can be divided into rubber-type and
Tackifying resin, plasticizer, filler, antioxygen will be also added in addition to main component is rubber in two class of resin type, rubber pressure sensitive adhesive
The auxiliary agents such as agent, anti-aging agent even vulcanizing agent.In rubber pressure sensitive adhesive, butyl type rubber pressure sensitive adhesive is because it is containing less unsaturation
The presence of double bond and methyl group has very excellent weatherability and watertightness.Therefore be mostly used building, medical treatment and
Industrial circle makees waterproof, be sealing adhesive materials'use.Belong to environment-friendly solvent-free, the weather-proof and excellent adhesive backers of adhesive property.
The method of traditional butyl rubber hot-fusible pressure-sensitive adhesive generally use unvulcanised makes, and such pressure sensitive adhesive has good
Good flowing wellability.Such as 102827557 A of patent CN are with butyl rubber, polyisobutene, random polypropylene, SBS, white oil,
Plasticizer, phenol-formaldehyde resin modified, light dydrocarbon resin and other auxiliary agents etc. make hot-fusible pressure-sensitive adhesive, have good leakproofness
Energy and mechanical property, can be used for solar energy solar double-glass assemblies rim seal, 1800 peel strengths reach 3.15-4.20N/mm.Specially
102277104 A of sharp CN provide a kind of preparation of the butyl pressure sensitive adhesive for self-adhering type rubber fastening band, wherein butyl rubber
100, polyisobutene 30-70, solid terpenes resin 30-90, liquid terpene resins 30-70, ultrafine kaolin 150-250.It is shelled
It is 1.84N/mm from intensity.Zhu Jinxin etc. (Chinese adhesive, 11 phases of volume 19 in 2010, page 10) is opposite with butyl rubber and height
The polyisobutene of molecular mass is aided with the additives such as tackifying resin, plasticizer and reinforcing filler as matrix resin, is prepared for
Good insulation preformance, the low telecommunications equipment waterproof insulation pressure sensitive adhesive of water absorption rate.In order to increase the cohesive strength of adhesive, also have
Take the method that vulcanization crosslinking is carried out to rubber.Such as 1521204 A of patent CN with butyl rubber, accelerating agent (sulfurization),
Softening agent, reinforcing agent and surfactant etc. prepare pressure-sensitive self-repairing waterproof rubber, are used for work China Democratic National Construction Association waterproof.Patent CN
105670534 A add molybdenum dioxide, divinylbenzene, triphenyl phosphate and wetting agent in butyl pressure sensitive adhesive, are keeping good
While good tack, the cohesive force for making glue have again catches mosquito for viscous.
The caking property of pressure sensitive adhesive is divided into tack and holds viscosity, these caking property are removed to be had outside the Pass with tackifying resin, and also and glue
Mobility and cohesive strength have much relations.Usual good fluidity, all right with the wellability of adhesive surface, adhesion strength is just high;
The cohesive strength of glue itself is high, and the cohesional failure power of glue is with regard to big.The molecular weight of wherein rubber matrix resin is higher, the cohesive force of glue
It is bigger, but mobility variation is easily caused, undesirable consequence can be all caused in the preparation and coating of glue and bonding process.Cause
This less rubber using high molecular weight or the method using vulcanization.So usually carrying out high temperature vulcanized method again after application
It realizes.Especially in terms of hot-fusible pressure-sensitive adhesive, good cohesive strength can be achieved using vulcanization.But chemical cure be it is irreversible,
After vulcanization bonds, it is impossible to remove bond again again, even if heating is also impossible to the bonding wellability having had again.
Invention content
It is an object of the invention to cannot be removed after solving the adhesion strength of prior art difference or irreversible vulcanization
Cohesive problem again.
Purpose of the present invention is to what is be achieved through the following technical solutions:
A kind of butyl rubber hot-fusible pressure-sensitive adhesive of cohesion enhancing, component and parts by weight are:Butyl rubber 10-35%, bromine
Change butyl rubber 3-20%, other matrix resin 3-18%, imdazole derivatives 0.05-1%, tackifying resin 10-35%, plasticizer
5-35%, reinforcing filler 18-55%, antioxidant 0.1-0.6%.
Can also be that a kind of butyl rubber hot-fusible pressure-sensitive adhesive of cohesion enhancing, component and parts by weight are:Butyl rubber
20-30%, brombutyl 5-15%, other matrix resin 5-15%, imdazole derivatives 0.1-0.5%, tackifying resin 15-
30%, plasticizer 10-30%, reinforcing filler 25-50%, antioxidant 0.2-0.4%.
Preferably, other matrix resins are polyisobutylene resin of the molecular weight in 20000-80000 high molecular weight,
Styrene-isoprene-styrene block copolymer (SIS), one in Styrene-Butadiene-Styrene Block Copolymer SBS
Kind is several.
Preferably, the imdazole derivatives refer to the 2- ethyl imidazol(e)s containing imidazole group, N- butyl imidazoles, N- vinyl
The nitrogen-atoms such as imidazoles can show one kind in the imidazole derivative of positive charge.
Preferably, the tackifying resin is the blend for hydrogenating one or both of C5 Petropols, terpene resin.
Preferably, the plasticizer is molecular weight in the low molecular weight polyisobutylene oil of 500-2000, white oil, naphthenic oil
One or more of.
Preferably, the reinforcing filler is kaolin, talcum powder, calcium carbonate, white carbon, one kind in carbon black or several
Kind.
Preferably, the antioxidant be four [β-(3,5- di-tert-butyl-hydroxy phenyl) propionic acid] pentaerythritol esters, three
[2.4- di-tert-butyl-phenyls] phosphite ester, one kind in β-(3,5- di-tert-butyl-hydroxy phenyl) propionic acid octadecanol ester
Or it is several.
The preparation method of the butyl rubber hot-fusible pressure-sensitive adhesive of the cohesion enhancing, first by brombutyl and butyl
Rubber distinguishes mill on a mill;Then brombutyl and imidazoles after mill are added in 160-190 DEG C of kneader
Derivative;The butyl rubber after mill and other matrix resins are added after mediating 3-15 minutes;It is added after mediating 1-5 minutes mixed
There are the plasticizer and tackifying resin of antioxidant;It is eventually adding reinforcing filler, is discharged after being mixed 0.2-2 hours under vacuum state.
Preferably, the preparation method of the butyl rubber hot-fusible pressure-sensitive adhesive of cohesion enhancing, first by butyl rubber bromide
Glue and butyl rubber distinguish mill on a mill;Then in 180 DEG C of kneaders be added mill after brombutyl and
Imdazole derivatives;The butyl rubber after mill and other matrix resins are added after mediating 5-10 minutes;It is added after mediating 2 minutes
It is mixed with the plasticizer and tackifying resin of antioxidant;It is eventually adding reinforcing filler, is discharged after being mixed 0.5-1 hours under vacuum state.
Beneficial effects of the present invention are:
A kind of butyl rubber hot-fusible pressure-sensitive adhesive of cohesion enhancing of the present invention is using the ion association of thermoplasticity as object
The method of crosslinking points is managed to prepare hot-fusible pressure-sensitive adhesive, is had the positive effect that compared with traditional butyl pressure sensitive adhesive:
1) there is excellent cohesive strength butyl hot-melt pressure sensitive adhesive can be improved while tack hardly declines
Holding power and peel strength, its 180 ° of peel strengths reach 5.5N/mm at 23 DEG C;Its 180 ° of peel strengths reach 4.5N/mm at 50 DEG C,
With good heat resistance.
2) the butyl rubber hot-fusible pressure-sensitive adhesive has reversible hot-workability, and there is coating again to bond in a heated state
Ability;
3) contain certain polar group in the butyl hot-melt pressure sensitive adhesive, there is the energy for bonding polarity and apolar surfaces
Power;
4) the butyl hot-melt pressure sensitive adhesive has excellent weatherability, watertightness and air-tightness;
5) the butyl hot-melt pressure sensitive adhesive can be used for building, medical treatment, automobile, electric power, the industries such as petrochemical industry.
Suitable bromination fourth is added by means of Ionomer (referred to as " from aggressiveness ") method in the present invention in butyl rubber
Base rubber, and imdazole derivatives are added, ionizable side group on butyl rubber main chain, band are become with imdazole derivatives substitution bromine
The imidazole group of positive charge while meeting charge balance with negatively charged bromide ion multiple ions also form forming for ionic bond
It closes, i.e., forms the ion cluster of imidazoles side group at normal temperatures, these ion clusters become the physical crosslinking point of brombutyl, play
Crosslinking increases the effect of adhesive cohesive strength.Different from chemical cure, these ion clusters can dissociate under high temperature, and cross-bond disappears
It loses, there is thermoplasticity, mobility can be increased and be conducive to be coated with cohesive processing.
Specific implementation mode
Following embodiment and comparative example are not limited to the scope of the present invention for illustrating the present invention.
Embodiment 1
A kind of butyl rubber hot-fusible pressure-sensitive adhesive of cohesion enhancing, component and parts by weight are:Butyl rubber 10%, bromination fourth
Base rubber 9%, the polyisobutylene resin 5% of 40000 molecular weight, N- vinyl imidazoles 0.8%, hydrogenation C5 Petropols 20%,
2000 low molecular weight polyisobutylene oil 10%, kaolin 45%, 1076 antioxidant 0.2%;
Brombutyl and butyl rubber are distinguished into mill on a mill first;Then add in 190 DEG C of kneaders
Enter the brombutyl after mill and N- vinyl imidazoles;It mediates the butyl rubber after mill is added after five minutes and gathers different
Butene resins resin;It mediates and the plasticizer polyisobutylene oil for being mixed with antioxidant 1076 and hydrogenation C5 Petropols is added after five minutes;
It is eventually adding kaolin, is discharged after being mixed 2 hours under vacuum state.
Embodiment 2
A kind of butyl rubber hot-fusible pressure-sensitive adhesive of cohesion enhancing, component and parts by weight are:Butyl rubber 17%, bromination fourth
Base rubber 10%, SIS resins 10%, 2- ethyl imidazol(e)s 0.5%, terpene resin 18%, white oil 15%, calcium carbonate 29%, antioxygen
Agent 1010,168 each 0.25%;
Brombutyl and butyl rubber are distinguished into mill on a mill first;Then add in 180 DEG C of kneaders
Enter the brombutyl after mill and 2- ethyl imidazol(e)s;Mediate the butyl rubber after mill is added after ten minutes and SIS trees
Fat;It is added after mediating 2 minutes and is mixed with antioxidant 1010,168 plasticizer white oil and terpene resin;It is eventually adding calcium carbonate, very
It discharges after being mixed 1 hour under dummy status.
Embodiment 3
A kind of butyl rubber hot-fusible pressure-sensitive adhesive of cohesion enhancing, component and parts by weight are:Butyl rubber 19%, bromination fourth
Base rubber 13%, SBS resins 3%, 2- ethyl imidazol(e)s 0.1%, hydrogenation C5 Petropols 24%, naphthenic oil 20%, calcium carbonate
10.5%, white carbon 10%, antioxidant 1010,168 each 0.2%;
Brombutyl and butyl rubber are distinguished into mill on a mill first;Then add in 170 DEG C of kneaders
Enter the brombutyl after mill and 2- ethyl imidazol(e)s;Mediate the butyl rubber after mill is added after ten minutes and SBS trees
Fat;It is added after mediating 3 minutes and is mixed with antioxidant 1010,168 plasticizer naphthenic oil and hydrogenation C5 Petropols;It is eventually adding carbon
Sour calcium and white carbon discharge after mixing 1 hour under vacuum state.
Embodiment 4
A kind of butyl rubber hot-fusible pressure-sensitive adhesive of cohesion enhancing, component and parts by weight are:Butyl rubber 15%, bromination fourth
Base rubber 20%, polyisobutene 3%, SIS resins 2%, N- butyl imidazoles 1%, hydrogenation C5 Petropols 5%, terpene resin
5%, polyisobutylene oil 15%, white oil 15%, talcum powder 15%, carbon black 3.9%, 1076 antioxidant 0.1%;
Brombutyl and butyl rubber are distinguished into mill on a mill first;Then add in 160 DEG C of kneaders
Enter the brombutyl after mill and N- butyl imidazoles;The butyl rubber after mill and poly- isobutyl are added after mediating 15 minutes
Olefine resin and SIS resins;It mediates to be added after five minutes and is mixed with antioxidant 1010,168 plasticizer naphthenic oil and hydrogenation C5 oil trees
Fat;It is eventually adding calcium carbonate and white carbon, is discharged after being mixed 1 hour under vacuum state.
Comparative example
Butyl rubber 22%, SIS resins 10.5%, terpene resin 25%, white oil 20%, calcium carbonate 22%, antioxidant
1010,168 each 0.25%;
First by butyl rubber mill on a mill;Then the butyl rubber after mill is added in 180 DEG C of kneaders
And SIS resins, it is added after mediating 2 minutes and is mixed with antioxidant 1010,168 plasticizer white oil and terpene resin;It is eventually adding
Calcium carbonate discharges after mixing 1 hour under vacuum state.Performance comparison is shown in Table 1.
1 performance comparison of table
Claims (9)
1. a kind of butyl rubber hot-fusible pressure-sensitive adhesive of cohesion enhancing, it is characterised in that:Its component and parts by weight are:Butyl rubber
10-35%, brombutyl 3-20%, other matrix resin 3-18%, imdazole derivatives 0.05-1%, tackifying resin 10-
35%, plasticizer 5-35%, reinforcing filler 18-55%, antioxidant 0.1-0.6%;The imdazole derivatives refer to containing imidazole group
2- ethyl imidazol(e)s, N- butyl imidazoles, one kind in N- vinyl imidazoles.
2. butyl rubber hot-fusible pressure-sensitive adhesive as described in claim 1, it is characterised in that:Its component and parts by weight are:Butyl rubber
Glue 20-30%, brombutyl 5-15%, other matrix resin 5-15%, imdazole derivatives 0.1-0.5%, tackifying resin 15-
30%, plasticizer 10-30%, reinforcing filler 25-50%, antioxidant 0.2-0.4%.
3. the butyl rubber hot-fusible pressure-sensitive adhesive as described in claim 1 to 2 is any, it is characterised in that:Other matrix trees
Fat is molecular weight in the polyisobutylene resin of 20000-80000 high molecular weight, styrene-isoprene-phenylethene block copolymerization
Object, one or more of Styrene-Butadiene-Styrene Block Copolymer.
4. the butyl rubber hot-fusible pressure-sensitive adhesive as described in claim 1 to 2 is any, it is characterised in that:The tackifying resin is
Hydrogenate the blend of one or both of C5 Petropols, terpene resin.
5. the butyl rubber hot-fusible pressure-sensitive adhesive as described in claim 1 to 2 is any, it is characterised in that:The plasticizer is point
Son amount is in one or more of the low molecular weight polyisobutylene oil of 500-2000, white oil, naphthenic oil.
6. the butyl rubber hot-fusible pressure-sensitive adhesive as described in claim 1 to 2 is any, it is characterised in that:The reinforcing filler is
One or more of kaolin, talcum powder, calcium carbonate, white carbon, carbon black.
7. butyl rubber hot-fusible pressure-sensitive adhesive as claimed in claim 1 or 2, it is characterised in that:The antioxidant is four [β-
(3,5- di-tert-butyl-hydroxy phenyl) propionic acid] pentaerythritol ester, three(2,4- di-tert-butyl-phenyls)Phosphite ester, β-
One or more of (3,5- di-tert-butyl-hydroxy phenyls) propionic acid octadecanol ester.
8. the preparation method of the butyl rubber hot-fusible pressure-sensitive adhesive of cohesion enhancing as claimed in claim 1 or 2, it is characterised in that:
Brombutyl and butyl rubber are distinguished into mill on a mill first;Then it is added and opens in 160-190 DEG C of kneader
Brombutyl after refining and imdazole derivatives;The butyl rubber after mill and other matrixes are added after mediating 3-15 minutes
Resin;The plasticizer and tackifying resin for being mixed with antioxidant are added after mediating 1-5 minutes;It is eventually adding reinforcing filler, vacuum state
Lower mixing discharges after 0.2-2 hours.
9. the preparation method of the butyl rubber hot-fusible pressure-sensitive adhesive of cohesion enhancing as claimed in claim 8, it is characterised in that:First
Brombutyl and butyl rubber are distinguished into mill on a mill;Then the bromine after mill is added in 180 DEG C of kneaders
Change butyl rubber and imdazole derivatives;The butyl rubber after mill and other matrix resins are added after mediating 5-10 minutes;It pinches
The plasticizer and tackifying resin for being mixed with antioxidant are added after closing 2 minutes;It is eventually adding reinforcing filler, 0.5- is mixed under vacuum state
It discharges after 1 hour.
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