CN107057605A - A kind of cold-resistant hot-fusible pressure-sensitive adhesive preparation method - Google Patents
A kind of cold-resistant hot-fusible pressure-sensitive adhesive preparation method Download PDFInfo
- Publication number
- CN107057605A CN107057605A CN201610146944.9A CN201610146944A CN107057605A CN 107057605 A CN107057605 A CN 107057605A CN 201610146944 A CN201610146944 A CN 201610146944A CN 107057605 A CN107057605 A CN 107057605A
- Authority
- CN
- China
- Prior art keywords
- sensitive adhesive
- cold
- rubber
- fusible pressure
- adhesive preparation
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J107/00—Adhesives based on natural rubber
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/08—Macromolecular additives
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
Abstract
The invention discloses a kind of cold-resistant hot-fusible pressure-sensitive adhesive preparation method, its constitute by weight percentage including：25~27% natural rubber, 10~11% SIS oil rubber, 20~22% C5 Petropols, 20~22% terpene resin, 2~4% polyisobutene, 14~15% naphthenic oil, 2~4% rubber accelerator, 1~3% age resistor.The cold-resistant hot-fusible pressure-sensitive adhesive preparation method of the present invention, with low temperature resistant, peel strength it is high, be bonded firm advantage, also there is good tack in low temperature, there is good adhesive force to substrate surface.
Description
Technical field
The present invention relates to PUR field, more particularly to a kind of cold-resistant hot-fusible pressure-sensitive adhesive preparation method.
Background technology
Pressure sensitive adhesive is mainly the solvent-borne type or latex type adhesive of acrylic acid series and rubber series.In order to realize high speed operation, rationally it is coated with, the need for the problems such as excluding solvent public hazards, has developed hot-fusible pressure-sensitive adhesive, it is the characteristics of hot-fusible pressure-sensitive adhesive integrates PUR and pressure sensitive adhesive, solvent-free, pollution-free, easy to use.
Now widely used thermotropic pressure sensitive glue, initial bonding strength and peel strength are low during low temperature, have the shortcomings that bonding loosely, and under northern China winter severe cold temperature condition, problem is especially protruded.
The content of the invention
In view of the shortcomings of the prior art, it is an object of the invention to provide a kind of cold-resistant hot-fusible pressure-sensitive adhesive preparation method, the existing frigolabile shortcoming of thermotropic pressure sensitive glue is overcome.
In order to achieve the above object, the present invention uses following technical scheme：A kind of cold-resistant hot-fusible pressure-sensitive adhesive preparation method, by weight percentage composition include：25~27% natural rubber, 10~11% SIS oil rubber, 20~22% C5 Petropols, 20~22% terpene resin, 2~4% polyisobutene, 14~15% naphthenic oil, 2~4% rubber accelerator, 1~3% age resistor.
The natural rubber is 2.5 with the weight ratio of SIS oil rubber:1.
The C5 Petropols are 1 with the weight ratio of terpene resin:1.
In the present invention, C5 Petropols have good cementability, and C5 Petropols are added in adhesive and pressure sensitive adhesive tape can improve bonding force, acid resistance, alkali resistance and the water resistance of adhesive, and can effectively reduce production cost；Terpene resin is some thermoplastic block copolymers, has the advantages that shallow color, low smell, high adhesion force, high antioxidant and heat endurance is good, compatibility and dissolubility are good；Naphthenic oil, both there is aromatic series sector of breakdown property, there are some properties of straight-chain hydrocarbons again, with low pour point, high density, high viscosity, have no toxic side effect the features such as, and with high dissolving power, good low temperature performance, the excellent compatibility with some resins and polymer, good speedup and intersolubility with rubber.
The beneficial effects of the invention are as follows：The cold-resistant hot-fusible pressure-sensitive adhesive preparation method of the present invention, with low temperature resistant, peel strength it is high, be bonded firm advantage, also there is good tack in low temperature, there is good adhesive force to substrate surface.
Embodiment
Embodiment 1
A kind of hot-fusible pressure-sensitive adhesive, by weight percentage composition include：25% natural rubber, 10% oil rubber, 22% C5 Petropols, 22% terpene resin, 2.1% polyisobutene, 14.2% naphthenic oil, 2.7% rubber accelerator, 2% age resistor.
Embodiment 2
A kind of hot-fusible pressure-sensitive adhesive, by weight percentage composition include：27% natural rubber, 11% oil rubber, 20% Petropols, 20% terpene resin, 4.0% polyisobutene, 14.2% naphthenic oil, 2.0% rubber accelerator, 1.8% age resistor.
Embodiment 3
A kind of hot-fusible pressure-sensitive adhesive, by weight percentage composition include：26% natural rubber, 10.5% oil rubber, 21% Petropols, 21% terpene resin, 3% polyisobutene, 14.5% naphthenic oil, 2.5% rubber accelerator, 1.5% age resistor.
Claims (3)
1. a kind of cold-resistant hot-fusible pressure-sensitive adhesive preparation method, it is characterised in that：Composition includes by weight percentage：25~27% natural rubber, 10~11% SIS oil rubber, 20~22% C5 Petropols, 20~22% terpene resin, 2~4% polyisobutene, 14~15% naphthenic oil, 2~4% rubber accelerator, 1~3% age resistor.
2. cold-resistant hot-fusible pressure-sensitive adhesive preparation method according to claim 1, it is characterised in that：The natural rubber is 2.5 with the weight ratio of SIS oil rubber:1.
3. cold-resistant hot-fusible pressure-sensitive adhesive preparation method according to claim 1, it is characterised in that：The C5 Petropols are 1 with the weight ratio of terpene resin:1.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610146944.9A CN107057605A (en) | 2016-03-15 | 2016-03-15 | A kind of cold-resistant hot-fusible pressure-sensitive adhesive preparation method |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610146944.9A CN107057605A (en) | 2016-03-15 | 2016-03-15 | A kind of cold-resistant hot-fusible pressure-sensitive adhesive preparation method |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN107057605A true CN107057605A (en) | 2017-08-18 |
Family
ID=59616918
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201610146944.9A Pending CN107057605A (en) | 2016-03-15 | 2016-03-15 | A kind of cold-resistant hot-fusible pressure-sensitive adhesive preparation method |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN107057605A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110643305A (en) * | 2019-10-12 | 2020-01-03 | 湖南省和祥润新材料有限公司 | Heat-resistant cold-resistant outdoor pressure-sensitive adhesive and preparation method thereof |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103074013A (en) * | 2013-02-07 | 2013-05-01 | 宁波申山新材料科技有限公司 | Hot-melt pressure-sensitive adhesive |
| CN103102854A (en) * | 2013-02-07 | 2013-05-15 | 宁波申山新材料科技有限公司 | High temperature resistance hot-melt pressure-sensitive adhesive |
| CN104479587A (en) * | 2014-12-23 | 2015-04-01 | 安徽助成信息科技有限公司 | Cold-resistant HMPSA (hot-melt pressure-sensitive adhesive) |
| CN104946178A (en) * | 2014-03-26 | 2015-09-30 | 江苏凯伦建材股份有限公司 | Novel hot-melt pressure-sensitive adhesive for waterproof materials and preparation method thereof |
-
2016
- 2016-03-15 CN CN201610146944.9A patent/CN107057605A/en active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103074013A (en) * | 2013-02-07 | 2013-05-01 | 宁波申山新材料科技有限公司 | Hot-melt pressure-sensitive adhesive |
| CN103102854A (en) * | 2013-02-07 | 2013-05-15 | 宁波申山新材料科技有限公司 | High temperature resistance hot-melt pressure-sensitive adhesive |
| CN104946178A (en) * | 2014-03-26 | 2015-09-30 | 江苏凯伦建材股份有限公司 | Novel hot-melt pressure-sensitive adhesive for waterproof materials and preparation method thereof |
| CN104479587A (en) * | 2014-12-23 | 2015-04-01 | 安徽助成信息科技有限公司 | Cold-resistant HMPSA (hot-melt pressure-sensitive adhesive) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110643305A (en) * | 2019-10-12 | 2020-01-03 | 湖南省和祥润新材料有限公司 | Heat-resistant cold-resistant outdoor pressure-sensitive adhesive and preparation method thereof |
| CN110643305B (en) * | 2019-10-12 | 2021-02-02 | 湖南省和祥润新材料有限公司 | Heat-resistant cold-resistant outdoor pressure-sensitive adhesive and preparation method thereof |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN102604570B (en) | Hot-melt pressure-sensitive adhesive for HDPE (high-density polyethylene) self-adhesive rolls and preparation method thereof | |
| CN111019575B (en) | High-temperature-resistant high-peeling-resistance hot-melt pressure-sensitive adhesive and preparation method thereof | |
| Khan et al. | Effect of molecular weight and testing rate on adhesion property of pressure-sensitive adhesives prepared from epoxidized natural rubber | |
| CN108192522B (en) | HDPE chemical bonding type self-adhesion waterproofing membrane | |
| CN109054688A (en) | Not inharmonious thermotropic pressure sensitive glue of heat ageing and preparation method thereof | |
| CN103102854B (en) | High temperature resistance hot-melt pressure-sensitive adhesive | |
| CN104479587A (en) | Cold-resistant HMPSA (hot-melt pressure-sensitive adhesive) | |
| CN102876256A (en) | Durable pressure-sensitive adhesive | |
| CN110734719A (en) | Modified hot-melt pressure-sensitive adhesive and preparation method thereof | |
| CN103194159B (en) | Hot-melt pressure-sensitive adhesive and preparation method thereof | |
| CN107603537A (en) | Thermotropic pressure sensitive glue and preparation method thereof | |
| CN103320067A (en) | Rapid bonding hot-melt pressure-sensitive adhesive for expressing waterproof bag and preparation method of rapid bonding hot-melt pressure-sensitive adhesive | |
| CN103214998B (en) | Preparation method of high-temperature resistant hot-melt pressure-sensitive adhesive | |
| CN104293255B (en) | A kind of high glue strong HDPE self-adhesive coiled material hot-fusible pressure-sensitive adhesive and preparation method thereof | |
| CN103074013A (en) | Hot-melt pressure-sensitive adhesive | |
| CN102086354A (en) | Rubber adhesive | |
| CN107057605A (en) | A kind of cold-resistant hot-fusible pressure-sensitive adhesive preparation method | |
| CN112126390B (en) | Film-coated box sealing adhesive and preparation method thereof | |
| CN108587497A (en) | Tack sealant composition, fluid sealant, sealed Cellophane and preparation method | |
| CN104449494A (en) | SIS-b-PEO hot-melt pressure-sensitive adhesive and preparation method thereof | |
| CN110628369B (en) | Hot melt adhesive capable of being repeatedly attached and preparation method thereof | |
| CN103361011B (en) | A kind of adhesive compound and a kind of joint sealing sealing tape | |
| CN109749677B (en) | Back adhesive capable of being applied at low temperature for hygienic products and preparation method thereof | |
| CN103773295B (en) | A kind of for PE thin film back painting pressure sensitive adhesive and preparation method thereof | |
| CN110408348A (en) | A kind of electrician's route plastics pressure sensitive adhesive |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| WD01 | Invention patent application deemed withdrawn after publication |
Application publication date: 20170818 |
|
| WD01 | Invention patent application deemed withdrawn after publication |