CN107057202A - A kind of cable for ship material of high temperature resistant and excellent fireproof performance and preparation method thereof - Google Patents
A kind of cable for ship material of high temperature resistant and excellent fireproof performance and preparation method thereof Download PDFInfo
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- CN107057202A CN107057202A CN201710441247.0A CN201710441247A CN107057202A CN 107057202 A CN107057202 A CN 107057202A CN 201710441247 A CN201710441247 A CN 201710441247A CN 107057202 A CN107057202 A CN 107057202A
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/16—Elastomeric ethene-propene or ethene-propene-diene copolymers, e.g. EPR and EPDM rubbers
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01B—CABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
- H01B3/00—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties
- H01B3/18—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances
- H01B3/28—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances natural or synthetic rubbers
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2227—Oxides; Hydroxides of metals of aluminium
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/30—Sulfur-, selenium- or tellurium-containing compounds
- C08K2003/3009—Sulfides
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/011—Nanostructured additives
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/014—Additives containing two or more different additives of the same subgroup in C08K
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/02—Flame or fire retardant/resistant
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/08—Stabilised against heat, light or radiation or oxydation
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2203/00—Applications
- C08L2203/20—Applications use in electrical or conductive gadgets
- C08L2203/202—Applications use in electrical or conductive gadgets use in electrical wires or wirecoating
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
Abstract
The invention discloses a kind of high temperature resistant and the cable for ship material of excellent fireproof performance, it is made up of following raw material：The adjacent dicarboxylic acid anhydride of ethylene propylene diene rubber, 4 third fluorubber, polyisoprene rubber, benzoyl peroxide, cumyl peroxide, GDMA, calcium lignosulfonate, monoalkoxy unrighted acid titanate esters, wollastonite in powder, nano-aluminum hydroxide, molybdenum trioxide, tetrabromo, white carbon, melamine condensed phosphate, antioxidant, anti-aging agent RD.The invention also discloses the high temperature resistant and the preparation method of the cable for ship material of excellent fireproof performance.CABLE MATERIALS prepared by the present invention has good mechanical property, and shows excellent in terms of anti-flammability and resistance to elevated temperatures, market is disclosure satisfy that to the higher and higher performance requirement of cable for ship, with wide market prospects.
Description
Technical field
The present invention relates to CABLE MATERIALS technical field, specifically a kind of high temperature resistant and the cable for ship material of excellent fireproof performance and
Its preparation method.
Background technology
Investigation display, world shipbuilding center is accelerating to China's transfer.Current China Yangtze River Delta Area, by its gold
The geo-advantage that water channel crosses with Gold Coast, has become the Nesting Zone of world's shipbuilding industry investment transfer.International market is by outer
Portion's economic environment and influence, the depression that will have short-term compared with several years ago.But domestic shipping industry will continue prosperity, by
To the influence of China's ocean development strategy implementation, domestic shipping industry faces great development space.It is new that China can successfully manufacture
Type ship species is continuously increased, for example：Product carrier, chemical tanker, ocean engineering vehicle, ocean fishing vessel, Large Container Ship, visitor
Roll ship, roll-on-roll-off ship, liquified gas carries, LNG carrier, large-scale refrigerated carrier, bulk freighter, fisheries administration ship, naval ship, self-discharging ship,
Big hatch multi-purpose cargo ship, shuttle tanker, high speed Hatchcoverless container ship, high speed hydrofoil passenger boat, marine oil storage ship, very large crude carrier and
Inland navigation craft etc.；Also have in addition and the spitkit naval vessels such as revenue cutter, lifeboat, yacht.
The fast development of China's shipping industry, will further pull on the market demand of cable for ship.By marine environment
Influence, cable used on ship is substantially the special cable of fire-retardant, low cigarette type.With the development in epoch, market pair
The fire resistance of cable for ship proposes higher and higher requirement, and the performance of the existing cable for ship of in the market can not gradually expire
The demand in sufficient market.
The content of the invention
It is an object of the invention to provide cable for ship material of a kind of high temperature resistant and excellent fireproof performance and preparation method thereof,
To solve the problems mentioned in the above background technology.
To achieve the above object, the present invention provides following technical scheme：
The cable for ship material of a kind of high temperature resistant and excellent fireproof performance, is made up of the raw material below according to parts by weight：Ternary
100-110 parts of EP rubbers, 35-39 parts of 4 third fluorubber, 21-25 parts of polyisoprene rubber, 3-5 parts of benzoyl peroxide,
2-3 parts of cumyl peroxide, 1-2 parts of GDMA, 3-5 parts of calcium lignosulfonate, monoalkoxy insatiable hunger
It is adjacent with 0.3-0.6 parts of aliphatic acid titanate esters, 6-10 parts of wollastonite in powder, 4-7 parts of nano-aluminum hydroxide, 2-3 parts of molybdenum trioxide, tetrabromo
1-2 parts of dicarboxylic acid anhydride, 2-3 parts of white carbon, 5-7 parts of melamine condensed phosphate, 0.5-1.0 parts of antioxidant 1076, age resistor
0.8-1.2 parts of RD.
It is used as further scheme of the invention：It is made up of the raw material below according to parts by weight：Ethylene propylene diene rubber 103-107
Part, 36-38 parts of 4 third fluorubber, 22-24 parts of polyisoprene rubber, 3.5-4.5 parts of benzoyl peroxide, peroxidating diisopropyl
2.2-2.8 parts of benzene, 1.3-1.7 parts of GDMA, 3.5-4.5 parts of calcium lignosulfonate, monoalkoxy insatiable hunger
With 0.4-0.5 parts of aliphatic acid titanate esters, 7-9 parts of wollastonite in powder, 5-6 parts of nano-aluminum hydroxide, 2.1-2.8 parts of molybdenum trioxide, four
1.2-1.7 parts of dicarboxylic acid anhydride of bromine neighbour, 2.3-2.7 parts of white carbon, 5.5-6.5 parts of melamine condensed phosphate, antioxidant 1076
0.6-0.9 parts, 0.9-1.1 parts of anti-aging agent RD.
It is used as further scheme of the invention：It is made up of the raw material below according to parts by weight：Ethylene propylene diene rubber 105
Part, 37 parts of 4 third fluorubber, 23 parts of polyisoprene rubber, 4 parts of benzoyl peroxide, 2.4 parts of cumyl peroxide, diformazan
1.5 parts of base acrylic acid glycol ester, 4 parts of calcium lignosulfonate, 0.5 part of monoalkoxy unrighted acid titanate esters, wollastonite
Adjacent 1.5 parts of the dicarboxylic acid anhydride of 8 parts of powder, 5.3 parts of nano-aluminum hydroxide, 2.4 parts of molybdenum trioxide, tetrabromo, 2.6 parts of white carbon, melamine
5 parts of amine condensed phosphate, 0.8 part of antioxidant 1076,1 part of anti-aging agent RD.
The preparation method of the cable for ship material of the high temperature resistant and excellent fireproof performance, step is as follows：
1) weigh wollastonite in powder, add into its weight 60-65% citric acid solution, then put into calcium lignosulfonate and
Molybdenum trioxide, stirring mixing 15-20min, is then placed in ultrasonic processor, ultrasonically treated 50-60min, quiet at 70-75 DEG C
15-20h is put, lower sediment is taken, mixture A is obtained；
2) mixture A after calcination processing 40-45min, natural cooling, is crushed at 650-670 DEG C, crosses 300-400 mesh
Sieve, obtains mixture B；
3) when banbury being preheated into 100-110 DEG C, ethylene propylene diene rubber, 4 third fluorubber, monoalkoxy insatiable hunger are weighed
With aliphatic acid titanate esters, nano-aluminum hydroxide, the adjacent dicarboxylic acid anhydride of tetrabromo, white carbon and melamine condensed phosphate, and add
Into banbury, 2-3min is kneaded, the first mixture is obtained；
4) polyisoprene rubber, GDMA, antioxidant 1076 and anti-aging agent RD are weighed, will be poly- different
Pentadiene rubber, GDMA, antioxidant 1076, anti-aging agent RD and mixture B are put into banbury,
5-6min is kneaded, the second mixture is obtained；
5) benzoyl peroxide and cumyl peroxide are weighed, is added into banbury, 1-2min is kneaded, discharging is obtained
Obtain granulation material；
6) granulation material is sent to extruding pelletization in double screw extruder, you can.
It is used as further scheme of the invention：Step 1) in, the concentration of the citric acid solution is 13-15%.
It is used as further scheme of the invention：Step 1) in, sonification power is 1100W.
Compared with prior art, the beneficial effects of the invention are as follows：
CABLE MATERIALS prepared by the present invention has good mechanical property, and shows excellent in terms of anti-flammability and resistance to elevated temperatures
It is different, market is disclosure satisfy that to the higher and higher performance requirement of cable for ship, with wide market prospects.
Embodiment
Technical scheme is described in more detail with reference to embodiment.
Embodiment 1
The cable for ship material of a kind of high temperature resistant and excellent fireproof performance, is made up of the raw material below according to parts by weight：Ternary
100 parts of EP rubbers, 35 parts of 4 third fluorubber, 21 parts of polyisoprene rubber, 3 parts of benzoyl peroxide, peroxidating diisopropyl
2 parts of benzene, 1 part of GDMA, 3 parts of calcium lignosulfonate, monoalkoxy unrighted acid titanate esters 0.3
Part, adjacent 1 part of the dicarboxylic acid anhydride of 6 parts of wollastonite in powder, 4 parts of nano-aluminum hydroxide, 2 parts of molybdenum trioxide, tetrabromo, 2 parts of white carbon, melamine
5 parts of amine condensed phosphate, 0.5 part of antioxidant 1076,0.8 part of anti-aging agent RD.
In the present embodiment, the preparation method of the cable for ship material of the high temperature resistant and excellent fireproof performance, step is as follows：
1) wollastonite in powder is weighed, is added into the citric acid solution of its weight 60%, then put into calcium lignosulfonate and three
Molybdenum oxide, stirring mixing 15min, is then placed in ultrasonic processor, the ultrasonically treated 50min at 70 DEG C, stands 15h, remove
Layer precipitation, obtains mixture A, wherein, the concentration of the citric acid solution is 13%, and sonification power is 1100W；
2) mixture A after calcination processing 40min, natural cooling, is crushed at 650 DEG C, crosses 300 mesh sieves, mixed
Thing B；
3) when banbury being preheated into 100 DEG C, ethylene propylene diene rubber, 4 third fluorubber, monoalkoxy unsaturated lipid are weighed
Fat acid titanate esters, nano-aluminum hydroxide, the adjacent dicarboxylic acid anhydride of tetrabromo, white carbon and melamine condensed phosphate, and add to close
In mill, 2min is kneaded, the first mixture is obtained；
4) polyisoprene rubber, GDMA, antioxidant 1076 and anti-aging agent RD are weighed, will be poly- different
Pentadiene rubber, GDMA, antioxidant 1076, anti-aging agent RD and mixture B are put into banbury,
5min is kneaded, the second mixture is obtained；
5) benzoyl peroxide and cumyl peroxide are weighed, is added into banbury, 1min is kneaded, discharged, is obtained
Granulation material；
6) granulation material is sent to extruding pelletization in double screw extruder, you can.
Embodiment 2
The cable for ship material of a kind of high temperature resistant and excellent fireproof performance, is made up of the raw material below according to parts by weight：Ternary
103 parts of EP rubbers, 36 parts of 4 third fluorubber, 22 parts of polyisoprene rubber, 3.5 parts of benzoyl peroxide, peroxidating two are different
2.8 parts of propyl benzene, 1.7 parts of GDMA, 4.5 parts of calcium lignosulfonate, monoalkoxy unrighted acid titanium
Adjacent 1.7 parts of the dicarboxylic acid anhydride of 0.5 part of acid esters, 7 parts of wollastonite in powder, 5 parts of nano-aluminum hydroxide, 2.1 parts of molybdenum trioxide, tetrabromo, hard charcoal
Black 2.7 parts, 6.5 parts of melamine condensed phosphate, 0.6 part of antioxidant 1076,1.1 parts of anti-aging agent RD.
In the present embodiment, the preparation method of the cable for ship material of the high temperature resistant and excellent fireproof performance, step is as follows：
1) wollastonite in powder is weighed, is added into the citric acid solution of its weight 61%, then put into calcium lignosulfonate and three
Molybdenum oxide, stirring mixing 16min, is then placed in ultrasonic processor, the ultrasonically treated 52min at 70 DEG C, stands 16h, remove
Layer precipitation, obtains mixture A, wherein, the concentration of the citric acid solution is 13%, and sonification power is 1100W；
2) mixture A after calcination processing 42min, natural cooling, is crushed at 655 DEG C, crosses 300 mesh sieves, mixed
Thing B；
3) when banbury being preheated into 105 DEG C, ethylene propylene diene rubber, 4 third fluorubber, monoalkoxy unsaturated lipid are weighed
Fat acid titanate esters, nano-aluminum hydroxide, the adjacent dicarboxylic acid anhydride of tetrabromo, white carbon and melamine condensed phosphate, and add to close
In mill, 2min is kneaded, the first mixture is obtained；
4) polyisoprene rubber, GDMA, antioxidant 1076 and anti-aging agent RD are weighed, will be poly- different
Pentadiene rubber, GDMA, antioxidant 1076, anti-aging agent RD and mixture B are put into banbury,
5min is kneaded, the second mixture is obtained；
5) benzoyl peroxide and cumyl peroxide are weighed, is added into banbury, 1min is kneaded, discharged, is obtained
Granulation material；
6) granulation material is sent to extruding pelletization in double screw extruder, you can.
Embodiment 3
The cable for ship material of a kind of high temperature resistant and excellent fireproof performance, is made up of the raw material below according to parts by weight：Ternary
105 parts of EP rubbers, 37 parts of 4 third fluorubber, 23 parts of polyisoprene rubber, 4 parts of benzoyl peroxide, peroxidating diisopropyl
2.4 parts of benzene, 1.5 parts of GDMA, 4 parts of calcium lignosulfonate, monoalkoxy unrighted acid titanate esters
0.5 part, 8 parts of wollastonite in powder, 5.3 parts of nano-aluminum hydroxide, 2.4 parts of molybdenum trioxide, adjacent 1.5 parts of the dicarboxylic acid anhydride of tetrabromo, white carbon
2.6 parts, 5 parts of melamine condensed phosphate, 0.8 part of antioxidant 1076,1 part of anti-aging agent RD.
In the present embodiment, the preparation method of the cable for ship material of the high temperature resistant and excellent fireproof performance, step is as follows：
1) wollastonite in powder is weighed, is added into the citric acid solution of its weight 63%, then put into calcium lignosulfonate and three
Molybdenum oxide, stirring mixing 18min, is then placed in ultrasonic processor, the ultrasonically treated 55min at 73 DEG C, stands 17h, remove
Layer precipitation, obtains mixture A, wherein, the concentration of the citric acid solution is 14%, and sonification power is 1100W；
2) mixture A after calcination processing 43min, natural cooling, is crushed at 660 DEG C, crosses 400 mesh sieves, mixed
Thing B；
3) when banbury being preheated into 105 DEG C, ethylene propylene diene rubber, 4 third fluorubber, monoalkoxy unsaturated lipid are weighed
Fat acid titanate esters, nano-aluminum hydroxide, the adjacent dicarboxylic acid anhydride of tetrabromo, white carbon and melamine condensed phosphate, and add to close
In mill, 2.5min is kneaded, the first mixture is obtained；
4) polyisoprene rubber, GDMA, antioxidant 1076 and anti-aging agent RD are weighed, will be poly- different
Pentadiene rubber, GDMA, antioxidant 1076, anti-aging agent RD and mixture B are put into banbury,
5.5min is kneaded, the second mixture is obtained；
5) benzoyl peroxide and cumyl peroxide are weighed, is added into banbury, 1.5min is kneaded, discharging is obtained
Obtain granulation material；
6) granulation material is sent to extruding pelletization in double screw extruder, you can.
Embodiment 4
The cable for ship material of a kind of high temperature resistant and excellent fireproof performance, is made up of the raw material below according to parts by weight：Ternary
107 parts of EP rubbers, 38 parts of 4 third fluorubber, 24 parts of polyisoprene rubber, 4.5 parts of benzoyl peroxide, peroxidating two are different
2.2 parts of propyl benzene, 1.3 parts of GDMA, 3.5 parts of calcium lignosulfonate, monoalkoxy unrighted acid titanium
Adjacent 1.2 parts of the dicarboxylic acid anhydride of 0.4 part of acid esters, 9 parts of wollastonite in powder, 6 parts of nano-aluminum hydroxide, 2.8 parts of molybdenum trioxide, tetrabromo, hard charcoal
Black 2.3 parts, 5.5 parts of melamine condensed phosphate, 0.9 part of antioxidant 1076,0.9 part of anti-aging agent RD.
In the present embodiment, the preparation method of the cable for ship material of the high temperature resistant and excellent fireproof performance, step is as follows：
1) wollastonite in powder is weighed, is added into the citric acid solution of its weight 64%, then put into calcium lignosulfonate and three
Molybdenum oxide, stirring mixing 18min, is then placed in ultrasonic processor, the ultrasonically treated 60min at 74 DEG C, stands 18h, remove
Layer precipitation, obtains mixture A, wherein, the concentration of the citric acid solution is 14.5%, and sonification power is 1100W；
2) mixture A after calcination processing 43min, natural cooling, is crushed at 670 DEG C, crosses 400 mesh sieves, mixed
Thing B；
3) when banbury being preheated into 105 DEG C, ethylene propylene diene rubber, 4 third fluorubber, monoalkoxy unsaturated lipid are weighed
Fat acid titanate esters, nano-aluminum hydroxide, the adjacent dicarboxylic acid anhydride of tetrabromo, white carbon and melamine condensed phosphate, and add to close
In mill, 3min is kneaded, the first mixture is obtained；
4) polyisoprene rubber, GDMA, antioxidant 1076 and anti-aging agent RD are weighed, will be poly- different
Pentadiene rubber, GDMA, antioxidant 1076, anti-aging agent RD and mixture B are put into banbury,
5.5min is kneaded, the second mixture is obtained；
5) benzoyl peroxide and cumyl peroxide are weighed, is added into banbury, 2min is kneaded, discharged, is obtained
Granulation material；
6) granulation material is sent to extruding pelletization in double screw extruder, you can.
Embodiment 5
The cable for ship material of a kind of high temperature resistant and excellent fireproof performance, is made up of the raw material below according to parts by weight：Ternary
110 parts of EP rubbers, 39 parts of 4 third fluorubber, 25 parts of polyisoprene rubber, 5 parts of benzoyl peroxide, peroxidating diisopropyl
3 parts of benzene, 2 parts of GDMA, 5 parts of calcium lignosulfonate, monoalkoxy unrighted acid titanate esters 0.6
Part, adjacent 2 parts of the dicarboxylic acid anhydride of 10 parts of wollastonite in powder, 7 parts of nano-aluminum hydroxide, 3 parts of molybdenum trioxide, tetrabromo, 3 parts of white carbon, trimerization
7 parts of cyanamide condensed phosphate, 1.0 parts of antioxidant 1076,1.2 parts of anti-aging agent RD.
In the present embodiment, the preparation method of the cable for ship material of the high temperature resistant and excellent fireproof performance, step is as follows：
1) wollastonite in powder is weighed, is added into the citric acid solution of its weight 65%, then put into calcium lignosulfonate and three
Molybdenum oxide, stirring mixing 20min, is then placed in ultrasonic processor, the ultrasonically treated 60min at 75 DEG C, stands 20h, remove
Layer precipitation, obtains mixture A, wherein, the concentration of the citric acid solution is 15%, and sonification power is 1100W；
2) mixture A after calcination processing 45min, natural cooling, is crushed at 670 DEG C, crosses 400 mesh sieves, mixed
Thing B；
3) when banbury being preheated into 110 DEG C, ethylene propylene diene rubber, 4 third fluorubber, monoalkoxy unsaturated lipid are weighed
Fat acid titanate esters, nano-aluminum hydroxide, the adjacent dicarboxylic acid anhydride of tetrabromo, white carbon and melamine condensed phosphate, and add to close
In mill, 3min is kneaded, the first mixture is obtained；
4) polyisoprene rubber, GDMA, antioxidant 1076 and anti-aging agent RD are weighed, will be poly- different
Pentadiene rubber, GDMA, antioxidant 1076, anti-aging agent RD and mixture B are put into banbury,
6min is kneaded, the second mixture is obtained；
5) benzoyl peroxide and cumyl peroxide are weighed, is added into banbury, 2min is kneaded, discharged, is obtained
Granulation material；
6) granulation material is sent to extruding pelletization in double screw extruder, you can.
Performance test is carried out to the CABLE MATERIALS prepared by 1-5 of the embodiment of the present invention, test result is as shown in the table.
The result of the test table of table 1
Note：Fire retardancy test standard performs IEC60332-3-22, and fire resistance test standard performs IEC60331.1-2009.
As can be seen from the above table, the CABLE MATERIALS that prepared by the present invention has good mechanical property, and in anti-flammability and resistance to height
Warm aspect of performance performance is excellent, market is disclosure satisfy that to the higher and higher performance requirement of cable for ship, before wide market
Scape.
The better embodiment to the present invention is explained in detail above, but the present invention is not limited to above-mentioned embodiment party
, can also be on the premise of present inventive concept not be departed from formula, the knowledge that one skilled in the relevant art possesses
Various changes can be made.
Claims (6)
1. the cable for ship material of a kind of high temperature resistant and excellent fireproof performance, it is characterised in that by below according to the raw material of parts by weight
It is made：100-110 parts of ethylene propylene diene rubber, 35-39 parts of 4 third fluorubber, 21-25 parts of polyisoprene rubber, benzoyl peroxide first
3-5 parts of acyl, 2-3 parts of cumyl peroxide, 1-2 parts of GDMA, 3-5 parts of calcium lignosulfonate, single alkane
0.3-0.6 parts of epoxide unrighted acid titanate esters, 6-10 parts of wollastonite in powder, 4-7 parts of nano-aluminum hydroxide, molybdenum trioxide 2-3
Part, adjacent 1-2 parts of the dicarboxylic acid anhydride of tetrabromo, 2-3 parts of white carbon, 5-7 parts of melamine condensed phosphate, antioxidant 1076 0.5-1.0
Part, 0.8-1.2 parts of anti-aging agent RD.
2. the cable for ship material of high temperature resistant according to claim 1 and excellent fireproof performance, it is characterised in that by pressing below
It is made according to the raw material of parts by weight：103-107 parts of ethylene propylene diene rubber, 36-38 parts of 4 third fluorubber, polyisoprene rubber 22-
24 parts, 3.5-4.5 parts of benzoyl peroxide, 2.2-2.8 parts of cumyl peroxide, GDMA 1.3-
1.7 parts, 3.5-4.5 parts of calcium lignosulfonate, 0.4-0.5 parts of monoalkoxy unrighted acid titanate esters, wollastonite in powder 7-9
Part, adjacent 1.2-1.7 parts of the dicarboxylic acid anhydride of 5-6 parts of nano-aluminum hydroxide, 2.1-2.8 parts of molybdenum trioxide, tetrabromo, white carbon 2.3-2.7
Part, 5.5-6.5 parts of melamine condensed phosphate, 0.6-0.9 parts of antioxidant 1076,0.9-1.1 parts of anti-aging agent RD.
3. the cable for ship material of high temperature resistant according to claim 2 and excellent fireproof performance, it is characterised in that by pressing below
It is made according to the raw material of parts by weight：105 parts of ethylene propylene diene rubber, 37 parts of 4 third fluorubber, 23 parts of polyisoprene rubber, peroxidating
4 parts of benzoyl, 2.4 parts of cumyl peroxide, 1.5 parts of GDMA, 4 parts of calcium lignosulfonate, single alkane
0.5 part of epoxide unrighted acid titanate esters, 8 parts of wollastonite in powder, 5.3 parts of nano-aluminum hydroxide, 2.4 parts of molybdenum trioxide, tetrabromo
Adjacent 1.5 parts of dicarboxylic acid anhydride, 2.6 parts of white carbon, 5 parts of melamine condensed phosphate, 0.8 part of antioxidant 1076, anti-aging agent RD 1
Part.
4. a kind of preparation method of the cable for ship material of high temperature resistant and excellent fireproof performance as described in claim 1-3 is any,
Characterized in that, step is as follows：
1) wollastonite in powder is weighed, is added into its weight 60-65% citric acid solution, then put into calcium lignosulfonate and three oxygen
Change molybdenum, stirring mixing 15-20min is then placed in ultrasonic processor, the ultrasonically treated 50-60min at 70-75 DEG C, stood
15-20h, takes lower sediment, obtains mixture A；
2) mixture A after calcination processing 40-45min, natural cooling, is crushed at 650-670 DEG C, crosses 300-400 mesh sieves, obtain
Obtain mixture B；
3) when banbury being preheated into 100-110 DEG C, ethylene propylene diene rubber, 4 third fluorubber, monoalkoxy unsaturated lipid are weighed
Fat acid titanate esters, nano-aluminum hydroxide, the adjacent dicarboxylic acid anhydride of tetrabromo, white carbon and melamine condensed phosphate, and add to close
In mill, 2-3min is kneaded, the first mixture is obtained；
4) polyisoprene rubber, GDMA, antioxidant 1076 and anti-aging agent RD are weighed, by poly- isoamyl two
Alkene rubber, GDMA, antioxidant 1076, anti-aging agent RD and mixture B are put into banbury, mixing
5-6min, obtains the second mixture；
5) benzoyl peroxide and cumyl peroxide are weighed, is added into banbury, 1-2min is kneaded, discharging is made
Pellet；
6) granulation material is sent to extruding pelletization in double screw extruder, you can.
5. the preparation method of the cable for ship material of high temperature resistant according to claim 4 and excellent fireproof performance, its feature exists
In step 1) in, the concentration of the citric acid solution is 13-15%.
6. the preparation method of the cable for ship material of high temperature resistant according to claim 4 and excellent fireproof performance, its feature exists
In step 1) in, sonification power is 1100W.
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN107573555A (en) * | 2017-11-01 | 2018-01-12 | 安徽美腾特种电缆材料有限公司 | A kind of high performance cable material |
| CN114106473A (en) * | 2021-12-07 | 2022-03-01 | 湖南昶力轨道交通设备有限公司 | Heat-resistant high-strength rubber material prepared from blend |
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| CN105419185A (en) * | 2015-12-30 | 2016-03-23 | 崇夕山 | Shaft end O-shaped sealing ring with hot air ageing resistance |
| CN106519521A (en) * | 2016-11-18 | 2017-03-22 | 广西大学 | Waterproof flame-retardant cable material and preparation method thereof |
| CN106674831A (en) * | 2016-12-29 | 2017-05-17 | 关正顺 | Ethylene propylene rubber-fluororubber blending and mixing rubber capable of resisting high-temperature steam |
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| CN103187126A (en) * | 2013-03-26 | 2013-07-03 | 江苏远洋东泽电缆股份有限公司 | Double-shielded instrument cable for flame-resistant and fire-resistant ship and manufacture method thereof |
| CN105419185A (en) * | 2015-12-30 | 2016-03-23 | 崇夕山 | Shaft end O-shaped sealing ring with hot air ageing resistance |
| CN106519521A (en) * | 2016-11-18 | 2017-03-22 | 广西大学 | Waterproof flame-retardant cable material and preparation method thereof |
| CN106674831A (en) * | 2016-12-29 | 2017-05-17 | 关正顺 | Ethylene propylene rubber-fluororubber blending and mixing rubber capable of resisting high-temperature steam |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN107573555A (en) * | 2017-11-01 | 2018-01-12 | 安徽美腾特种电缆材料有限公司 | A kind of high performance cable material |
| CN114106473A (en) * | 2021-12-07 | 2022-03-01 | 湖南昶力轨道交通设备有限公司 | Heat-resistant high-strength rubber material prepared from blend |
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Application publication date: 20170818 |