CN107057102A - A kind of scratch resistant weather-proof PVC plastic buckle - Google Patents
A kind of scratch resistant weather-proof PVC plastic buckle Download PDFInfo
- Publication number
- CN107057102A CN107057102A CN201710313574.8A CN201710313574A CN107057102A CN 107057102 A CN107057102 A CN 107057102A CN 201710313574 A CN201710313574 A CN 201710313574A CN 107057102 A CN107057102 A CN 107057102A
- Authority
- CN
- China
- Prior art keywords
- parts
- plastic buckle
- pvc plastic
- resin
- scratch resistant
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Withdrawn
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J7/00—Chemical treatment or coating of shaped articles made of macromolecular substances
- C08J7/04—Coating
- C08J7/042—Coating with two or more layers, where at least one layer of a composition contains a polymer binder
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L27/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers
- C08L27/02—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L27/04—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment containing chlorine atoms
- C08L27/06—Homopolymers or copolymers of vinyl chloride
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D4/00—Coating compositions, e.g. paints, varnishes or lacquers, based on organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond ; Coating compositions, based on monomers of macromolecular compounds of groups C09D183/00 - C09D183/16
- C09D4/06—Organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond in combination with a macromolecular compound other than an unsaturated polymer of groups C09D159/00 - C09D187/00
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/18—Fireproof paints including high temperature resistant paints
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/63—Additives non-macromolecular organic
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2327/00—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers
- C08J2327/02—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers not modified by chemical after-treatment
- C08J2327/04—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers not modified by chemical after-treatment containing chlorine atoms
- C08J2327/06—Homopolymers or copolymers of vinyl chloride
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2433/00—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Derivatives of such polymers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2477/00—Characterised by the use of polyamides obtained by reactions forming a carboxylic amide link in the main chain; Derivatives of such polymers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
Abstract
The invention belongs to ornament materials processing technique field, and in particular to a kind of scratch resistant weather-proof PVC plastic buckle, and the PVC buckles are externally provided with the functional membrane that thickness is 0.4 0.8mm, and its processing method is：By the processing wheel acrylic resin bottoming of 120 140 mesh, then 85 90 DEG C of oven for drying is passed through, then function batch mixing is handled on PVC plastic buckle surface using the method for intaglio printing with the processing wheel of 100 120 mesh, by oven for drying, it is 20 30g/ ㎡ to handle the amount on PVC plastic buckle surface.The present invention has advantages below compared with prior art：Rational proportion functional membrane raw material components in the present invention, make gained functional membrane in PVC board surface close adhesion, change in size is smaller at high operating temperatures, product bubble-free, crack and pit, with stronger weather-proof scratch resistant performance, it can be used indoors more than 15 years, according to the ISO standard no color differnece, can be promoted the use of.
Description
Technical field
The invention belongs to ornament materials processing technique field, and in particular to a kind of scratch resistant weather-proof PVC plastic buckle.
Background technology
PVC plastic buckle using PVC as raw material, it is processed turn into groove and tognue type section bar, with lightweight, easy for installation, waterproof,
The characteristics of moistureproof, Anti-moth-eating, its surface color pattern is also very more, and have that resistance to soiling is good, clean well, there is sound insulation, it is heat-insulated
Superperformance, particularly new technology adds fire proofing, can be gone out from fire, safer, in present interior decoration
It is middle to use extensively, but as long-time is used, it may appear that aging is even turned to be yellow, influence decorative effect, if while run into sharply
Hard thing is scratched, then be able to not can be remedied, it is therefore desirable to how Reinforced PVC plastic button board weatherability and scratch resistance enter traveling one
Step research.
The content of the invention
The purpose of the present invention is that there is provided a kind of scratch resistant weather-proof PVC plastic buckle the problem of being directed to existing.
The present invention is achieved by the following technical solutions：A kind of scratch resistant weather-proof PVC plastic buckle, the PVC buckles
The functional membrane that thickness is 0.4-0.8mm is externally provided with, its processing method is：The processing wheel of 120-140 mesh is beaten with acrylic resin
Bottom, then by 85-90 DEG C of oven for drying, drying time is 4-5 minutes, then with the processing wheel of 100-120 mesh by function
Batch mixing is using the method processing of intaglio printing on PVC plastic buckle surface, and by oven for drying, drying temperature is 140-150 DEG C,
Drying time is 2-3 minutes, and it is 20-30g/ ㎡ to handle the amount on PVC plastic buckle surface；
The function batch mixing is made up of the raw material of following parts by weight, 25-30 parts of epoxy grafted and modified acrylic resin resin, polyamide resin
10-15 parts of fat, 4-7 parts of modified fluoride-containing resin, 25-30 parts of glycerine, 2-4 parts of butyl methacrylate, nano titanium oxide 8-12
Part, 2-5 parts of dibenzoyl peroxide, vinyl double 1-3 parts of hard amide, 2-3 parts of HPMA, urea 1.2-2.2
Part, 0.2-0.5 parts of barium stearate, 0.4-0.7 parts of eight bromo ether, 0.2-0.5 parts of aluminium nitride；Its preparation method is：Epoxy is grafted
Acrylic resin modified, polyamide and modified fluoride-containing resin add reactor, under conditions of temperature is 55-60 DEG C, with
30-50 revs/min is stirred 2-3 hours, and other components then are poured into reactor, is vulcanized 4-6 hours at 100 DEG C, is produced.
As further improvement of these options, the modified fluoride-containing resin is modified fluoride-containing acrylic resin.
As further improvement of these options, the molecular mass of the modified fluoride-containing acrylic resin Mn is
5222.9, Mw branch's quality is 165236.9, and corresponding decentralization is 31.637.
As further improvement of these options, the PVC buckles are made up of the raw material of following parts by weight：Polyvinyl chloride resin
88-95 parts, 8-12 parts of maleic anhydride grafted polyethylene, 4-7 parts of sierozem power, the 2-3 parts of stearic acid, anion surfactant 1-
2 parts, 0.2-0.4 parts of soybean oil, 0.1-0.3 parts of itaconic anhydride；Its preparation method is：Will be poly- except polyvinyl chloride resin, maleic anhydride grafting
Premixed in raw material input hot pot beyond ethene, itaconic anhydride, maleic anhydride is added when temperature is to 70-75 DEG C and is grafted poly- second
Alkene, temperature to 85-90 DEG C be add polyvinyl chloride resin blending, to temperature be 120-125 DEG C when blanking to cold pot, chilling temperature is 45-
50 DEG C, when being cooled to 55-60 DEG C, itaconic anhydride blending is added, continues to be cooled to after 45-50 DEG C blanking to extruder, tentatively
Vacuumized again by shaper after sizing, water cooling sizing rear haulage cuts into PVC buckles, hauling speed is 2-3.5m/s.
As further improvement of these options, in the anion surfactant position soap and phosphate ester salt
Any one.
The present invention has advantages below compared with prior art：Rational proportion functional membrane raw material components in the present invention, make gained
Functional membrane is in PVC board surface close adhesion, ageing-resistant performance more than 6000 hours significantly, and surface abrasion resistance is more than 6000 turns,
Fire resistance meets GB/8624-1997 technical requirements, and change in size is smaller at high operating temperatures, product bubble-free, crack and fiber crops
Point, with stronger weather-proof scratch resistant performance, can be used more than 15 years, according to the ISO standard no color differnece, can be promoted the use of indoors.
Embodiment
Embodiment 1
A kind of scratch resistant weather-proof PVC plastic buckle, the PVC buckles are externally provided with the functional membrane that thickness is 0.4mm, its processing method
For：By the processing wheel acrylic resin bottoming of 130 mesh, then by 85 DEG C of oven for drying, drying time is 5 minutes, so
Function batch mixing is handled on PVC plastic buckle surface using the method for intaglio printing with the processing wheel of 100 mesh afterwards, dried by baking oven
Dry, drying temperature is 145 DEG C, and drying time is 2 minutes, and it is 25g/ ㎡ to handle the amount on PVC plastic buckle surface；
The function batch mixing is made up of the raw material of following parts by weight, 25 parts of epoxy grafted and modified acrylic resin resin, polyamide
15 parts, 4 parts of modified fluoride-containing acrylic resin, 30 parts of glycerine, 2 parts of butyl methacrylate, 12 parts of nano titanium oxide, peroxidating
2 parts of dibenzoyl, vinyl double 3 parts of hard amide, 2 parts of HPMA, 1.8 parts of urea, 0.2 part of barium stearate, eight
0.7 part of bromo-ether, 0.2 part of aluminium nitride；Its preparation method is：By epoxy grafted and modified acrylic resin resin, polyamide and modification
Fluorine resin adds reactor, under conditions of temperature is 60 DEG C, is stirred 3 hours, then falls other components with 30 revs/min
Enter reactor, vulcanize 6 hours at 100 DEG C, produce.
Wherein, the PVC buckles are made up of the raw material of following parts by weight：95 parts of polyvinyl chloride resin, maleic anhydride grafted polyethylene
12 parts, 4 parts of sierozem power, this 3 parts of stearic acid, 1 part of anion surfactant, 0.3 part of soybean oil, 0.2 part of itaconic anhydride；It is made
Preparation Method is：It will be premixed in raw material input hot pot in addition to polyvinyl chloride resin, maleic anhydride grafted polyethylene, itaconic anhydride, work as temperature
Maleic anhydride grafted polyethylene is added when spending to 75 DEG C, temperature is to add polyvinyl chloride resin blending to 85 DEG C, when to temperature being 125 DEG C
Blanking is to cold pot, and chilling temperature is 50 DEG C, when being cooled to 55 DEG C, adds itaconic anhydride blending, continues under being cooled to after 45 DEG C
Material is vacuumized, water cooling sizing rear haulage cuts into PVC buckles, traction speed by shaper again to extruder after preliminary sizing
Spend for 3.2m/s.
After testing, anti-flammability reaches B1 grades to the PVC plastic buckle prepared in the present invention, and it is small that ageing-resistant performance is more than 7000
When, surface abrasion resistance is more than 6000 turns, and fire resistance meets GB/8624-1997 technical requirements, is in visible ray, i.e. wavelength
Radiated 48 hours in the case of 0.4-0.78 μm, no yellowing phenomenon, wearability keeps preferable.
Embodiment 2
A kind of scratch resistant weather-proof PVC plastic buckle, the PVC buckles are externally provided with the functional membrane that thickness is 0.6mm, its processing method
For：By the processing wheel acrylic resin bottoming of 120 mesh, then by 90 DEG C of oven for drying, drying time is 5 minutes, so
Function batch mixing is handled on PVC plastic buckle surface using the method for intaglio printing with the processing wheel of 120 mesh afterwards, dried by baking oven
Dry, drying temperature is 150 DEG C, and drying time is 2 minutes, and it is 30g/ ㎡ to handle the amount on PVC plastic buckle surface；
The function batch mixing is made up of the raw material of following parts by weight, 30 parts of epoxy grafted and modified acrylic resin resin, polyamide
10 parts, 7 parts of modified fluoride-containing acrylic resin, 25 parts of glycerine, 4 parts of butyl methacrylate, 8 parts of nano titanium oxide, peroxidating
5 parts of dibenzoyl, vinyl double 3 parts of hard amide, 2 parts of HPMA, 2.2 parts of urea, 0.2 part of barium stearate, eight
0.7 part of bromo-ether, 0.2 part of aluminium nitride；Its preparation method is：By epoxy grafted and modified acrylic resin resin, polyamide and modification
Fluorine resin adds reactor, under conditions of temperature is 55 DEG C, is stirred 2 hours, then falls other components with 50 revs/min
Enter reactor, vulcanize 4 hours at 100 DEG C, produce.
Wherein, the PVC buckles are made up of the raw material of following parts by weight：88 parts of polyvinyl chloride resin, maleic anhydride grafted polyethylene
12 parts, 4 parts of sierozem power, this 3 parts of stearic acid, 2 parts of anion surfactant, 0.2 part of soybean oil, 0.3 part of itaconic anhydride；It is made
Preparation Method is：It will be premixed in raw material input hot pot in addition to polyvinyl chloride resin, maleic anhydride grafted polyethylene, itaconic anhydride, work as temperature
Maleic anhydride grafted polyethylene is added when spending to 75 DEG C, temperature is to add polyvinyl chloride resin blending to 90 DEG C, when to temperature being 125 DEG C
Blanking is to cold pot, and chilling temperature is 50 DEG C, when being cooled to 60 DEG C, adds itaconic anhydride blending, continues under being cooled to after 50 DEG C
Material is vacuumized, water cooling sizing rear haulage cuts into PVC buckles, traction speed by shaper again to extruder after preliminary sizing
Spend for 2m/s.
After testing, anti-flammability reaches B1 grades to the PVC plastic buckle prepared in the present invention, and it is small that ageing-resistant performance is more than 7000
When, surface abrasion resistance is more than 6000 turns, and fire resistance meets GB/8624-1997 technical requirements, is in visible ray, i.e. wavelength
Radiated 48 hours in the case of 0.4-0.78 μm, no yellowing phenomenon, wearability keeps preferable.
Embodiment 3
A kind of scratch resistant weather-proof PVC plastic buckle, the PVC buckles are externally provided with the functional membrane that thickness is 0.8mm, its processing method
For：By the processing wheel acrylic resin bottoming of 140 mesh, then by 88 DEG C of oven for drying, drying time is 4 minutes, so
Function batch mixing is handled on PVC plastic buckle surface using the method for intaglio printing with the processing wheel of 110 mesh afterwards, dried by baking oven
Dry, drying temperature is 145 DEG C, and drying time is 2 minutes, and it is 25g/ ㎡ to handle the amount on PVC plastic buckle surface；
The function batch mixing is made up of the raw material of following parts by weight, 28 parts of epoxy grafted and modified acrylic resin resin, polyamide
12 parts, 6 parts of modified fluoride-containing acrylic resin, 28 parts of glycerine, 3 parts of butyl methacrylate, 10 parts of nano titanium oxide, peroxidating
4 parts of dibenzoyl, vinyl double 2 parts of hard amide, 2 parts of HPMA, 1.8 parts of urea, 0.4 part of barium stearate, eight
0.5 part of bromo-ether, 0.4 part of aluminium nitride；Its preparation method is：By epoxy grafted and modified acrylic resin resin, polyamide and modification
Fluorine resin adds reactor, under conditions of temperature is 60 DEG C, is stirred 2 hours, then falls other components with 50 revs/min
Enter reactor, vulcanize 6 hours at 100 DEG C, produce.
Wherein, the PVC buckles are made up of the raw material of following parts by weight：92 parts of polyvinyl chloride resin, maleic anhydride grafted polyethylene
10 parts, 6 parts of sierozem power, this 2 parts of stearic acid, 2 parts of anion surfactant, 0.3 part of soybean oil, 0.2 part of itaconic anhydride；It is made
Preparation Method is：It will be premixed in raw material input hot pot in addition to polyvinyl chloride resin, maleic anhydride grafted polyethylene, itaconic anhydride, work as temperature
Maleic anhydride grafted polyethylene is added when spending to 74 DEG C, temperature is to add polyvinyl chloride resin blending to 88 DEG C, when to temperature being 125 DEG C
Blanking is to cold pot, and chilling temperature is 48 DEG C, when being cooled to 58 DEG C, adds itaconic anhydride blending, continues under being cooled to after 48 DEG C
Material is vacuumized, water cooling sizing rear haulage cuts into PVC buckles, traction speed by shaper again to extruder after preliminary sizing
Spend for 3.5m/s.
After testing, anti-flammability reaches B1 grades to the PVC plastic buckle prepared in the present invention, and it is small that ageing-resistant performance is more than 7000
When, surface abrasion resistance is more than 6000 turns, and fire resistance meets GB/8624-1997 technical requirements, is in visible ray, i.e. wavelength
Radiated 48 hours in the case of 0.4-0.78 μm, no yellowing phenomenon, wearability keeps preferable.
Claims (5)
1. a kind of scratch resistant weather-proof PVC plastic buckle, it is characterised in that it is 0.4-0.8mm's that the PVC buckles, which are externally provided with thickness,
Functional membrane, its processing method is：By the processing wheel acrylic resin bottoming of 120-140 mesh, then pass through 85-90 DEG C of baking oven
Dry, drying time is 4-5 minutes, then used function batch mixing at the method for intaglio printing with the processing wheel of 100-120 mesh
Reason is on PVC plastic buckle surface, by oven for drying, and drying temperature is 140-150 DEG C, and drying time is 2-3 minutes, and processing exists
The amount on PVC plastic buckle surface is 20-30g/ ㎡；
The function batch mixing is made up of the raw material of following parts by weight, 25-30 parts of epoxy grafted and modified acrylic resin resin, polyamide resin
10-15 parts of fat, 4-7 parts of modified fluoride-containing resin, 25-30 parts of glycerine, 2-4 parts of butyl methacrylate, nano titanium oxide 8-12
Part, 2-5 parts of dibenzoyl peroxide, vinyl double 1-3 parts of hard amide, 2-3 parts of HPMA, urea 1.2-2.2
Part, 0.2-0.5 parts of barium stearate, 0.4-0.7 parts of eight bromo ether, 0.2-0.5 parts of aluminium nitride；Its preparation method is：Epoxy is grafted
Acrylic resin modified, polyamide and modified fluoride-containing resin add reactor, under conditions of temperature is 55-60 DEG C, with
30-50 revs/min is stirred 2-3 hours, and other components then are poured into reactor, is vulcanized 4-6 hours at 100 DEG C, is produced.
2. a kind of scratch resistant weather-proof PVC plastic buckle as claimed in claim 1, it is characterised in that the modified fluoride-containing resin is
Modified fluoride-containing acrylic resin.
3. a kind of scratch resistant weather-proof PVC plastic buckle as claimed in claim 3, it is characterised in that the modified fluoride-containing acrylic acid
Branch's quality that resin M n molecular mass is 5222.9, Mw is 165236.9, and corresponding decentralization is 31.637.
4. a kind of scratch resistant weather-proof PVC plastic buckle as any one of claim 1-3, it is characterised in that the PVC buttons
Plate is made up of the raw material of following parts by weight：88-95 parts of polyvinyl chloride resin, 8-12 parts of maleic anhydride grafted polyethylene, 4-7 parts of sierozem power,
The 2-3 parts of stearic acid, 1-2 parts of anion surfactant, 0.2-0.4 parts of soybean oil, 0.1-0.3 parts of itaconic anhydride；It is prepared
Method is：It will be premixed in raw material input hot pot in addition to polyvinyl chloride resin, maleic anhydride grafted polyethylene, itaconic anhydride, work as temperature
Maleic anhydride grafted polyethylene is added during to 70-75 DEG C, temperature is to add polyvinyl chloride resin blending to 85-90 DEG C, is 120- to temperature
Blanking is to cold pot at 125 DEG C, and chilling temperature is 45-50 DEG C, when being cooled to 55-60 DEG C, adds itaconic anhydride blending, continues to drop
Temperature is vacuumized, water cooling sizing rear haulage is cut into by shaper again to blanking after 45-50 DEG C to extruder after preliminary sizing
PVC buckles, hauling speed is 2-3.5m/s.
5. a kind of scratch resistant weather-proof PVC plastic buckle as claimed in claim 4, it is characterised in that the anion surface active
Agent position soap and phosphate ester salt in any one.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710313574.8A CN107057102A (en) | 2017-05-05 | 2017-05-05 | A kind of scratch resistant weather-proof PVC plastic buckle |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710313574.8A CN107057102A (en) | 2017-05-05 | 2017-05-05 | A kind of scratch resistant weather-proof PVC plastic buckle |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN107057102A true CN107057102A (en) | 2017-08-18 |
Family
ID=59597633
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201710313574.8A Withdrawn CN107057102A (en) | 2017-05-05 | 2017-05-05 | A kind of scratch resistant weather-proof PVC plastic buckle |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN107057102A (en) |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2001019857A (en) * | 1999-07-08 | 2001-01-23 | Toto Ltd | Antisweating ceiling |
| CN101597948A (en) * | 2009-07-13 | 2009-12-09 | 华浚塑料建材有限公司 | Environmental-friendly lead-free PVC ceiling sheet and manufacture method thereof and application |
| CN101967336A (en) * | 2010-11-03 | 2011-02-09 | 苏州凯康化工科技有限公司 | UV overprinting varnish of polyvinyl chloride PVC fastening plate and preparation method thereof |
| CN102863589A (en) * | 2012-09-27 | 2013-01-09 | 黄山金质丽科技有限公司 | Chlorinated-polypropylene-modified fluorine-containing acrylic resin and preparation method thereof |
| CN103850120A (en) * | 2014-02-18 | 2014-06-11 | 苏州贝斯特装饰新材料有限公司 | Formula, preparation method and application of antifouling treating agent for decorative material |
-
2017
- 2017-05-05 CN CN201710313574.8A patent/CN107057102A/en not_active Withdrawn
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2001019857A (en) * | 1999-07-08 | 2001-01-23 | Toto Ltd | Antisweating ceiling |
| CN101597948A (en) * | 2009-07-13 | 2009-12-09 | 华浚塑料建材有限公司 | Environmental-friendly lead-free PVC ceiling sheet and manufacture method thereof and application |
| CN101967336A (en) * | 2010-11-03 | 2011-02-09 | 苏州凯康化工科技有限公司 | UV overprinting varnish of polyvinyl chloride PVC fastening plate and preparation method thereof |
| CN102863589A (en) * | 2012-09-27 | 2013-01-09 | 黄山金质丽科技有限公司 | Chlorinated-polypropylene-modified fluorine-containing acrylic resin and preparation method thereof |
| CN103850120A (en) * | 2014-02-18 | 2014-06-11 | 苏州贝斯特装饰新材料有限公司 | Formula, preparation method and application of antifouling treating agent for decorative material |
Non-Patent Citations (1)
| Title |
|---|
| 王春艳: "环氧接枝改性水性丙烯酸树脂", 《应用化工》 * |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN104031344B (en) | The preparation method of decoration bar section moulded by a kind of wood-grain imitating PVC wood | |
| CN105968673B (en) | A kind of resin concentrates of imitation marble effect and its preparation method and application | |
| CN103788555B (en) | The production method of the coated co-extrusion wood plastic composite of a kind of polyvinyl | |
| CN103214766A (en) | Wear-resistant and ageing-resistant PVC (polyvinyl chloride) reinforced hose pipe and preparation method of hose pipe | |
| CN103265768B (en) | Production method of wood-plastic floorboard | |
| CN104231646A (en) | Preparation method of high-strength wood-plastic composite material and high-strength wood-plastic composite material | |
| CN107474430A (en) | A kind of PVC Modified wood plastic section bars of door and window and preparation method thereof | |
| CN101857703A (en) | Formula of straw composite imitation solid wood board | |
| CN102321376A (en) | A kind of highly effective flame-retardant Wood plastic composite sheet material and preparation method thereof | |
| CN108149340A (en) | A kind of flame retardant type Polywoven Bag and its preparation process | |
| CN106751209A (en) | A kind of weatherability polyvinyl chloride Masterbatch | |
| CN103773042A (en) | Plastic-wood section material prepared from bamboo powder and preparation method thereof | |
| CN107057102A (en) | A kind of scratch resistant weather-proof PVC plastic buckle | |
| CN106496690A (en) | A kind of nitrile butadiene rubber cable material and preparation method thereof | |
| CN106432887A (en) | Polyolefin foaming masterbatch composition and preparation method and application | |
| CN104194374B (en) | A kind of fretting map wood plastic composite board and preparation method thereof | |
| CN103739914B (en) | A kind of synthetic wood material and manufacture method thereof | |
| CN102746685B (en) | Novel material for decoration of aluminum alloy doors and windows and manufacturing process thereof | |
| CN111607116A (en) | TPU film for plastic uptake process and preparation method thereof | |
| CN108586985A (en) | The preparation method of anti-aging high-ductility PVC composite materials | |
| CN106188738A (en) | A kind of wear-resisting composite fibre of high-strength anti-corrosion/PE wood plastic composite and preparation method thereof | |
| CN110041698A (en) | A kind of high-strength injection plastic material formula | |
| CN104861249A (en) | Polyethylene wholly plastic wood-imitating material and preparation method thereof | |
| CN102492239B (en) | AM mixture used for wood plastic products, and application methods thereof | |
| CN108059782A (en) | A kind of igelite particle and preparation method thereof |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| WW01 | Invention patent application withdrawn after publication | ||
| WW01 | Invention patent application withdrawn after publication |
Application publication date: 20170818 |