CN107056331A - A kind of ceramic tile of resin glue filling porous ceramics formation and preparation method thereof - Google Patents
A kind of ceramic tile of resin glue filling porous ceramics formation and preparation method thereof Download PDFInfo
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- CN107056331A CN107056331A CN201710412757.5A CN201710412757A CN107056331A CN 107056331 A CN107056331 A CN 107056331A CN 201710412757 A CN201710412757 A CN 201710412757A CN 107056331 A CN107056331 A CN 107056331A
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- resin glue
- porous ceramics
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- ceramic tile
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/45—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements
- C04B41/46—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements with organic materials
- C04B41/48—Macromolecular compounds
- C04B41/4853—Epoxides
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/009—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone characterised by the material treated
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/45—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements
- C04B41/46—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements with organic materials
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/45—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements
- C04B41/46—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements with organic materials
- C04B41/48—Macromolecular compounds
- C04B41/4811—Condensation polymers of aldehydes or ketones
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/45—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements
- C04B41/46—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements with organic materials
- C04B41/48—Macromolecular compounds
- C04B41/488—Other macromolecular compounds obtained otherwise than by reactions only involving unsaturated carbon-to-carbon bonds
- C04B41/4884—Polyurethanes; Polyisocyanates
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/80—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone of only ceramics
- C04B41/81—Coating or impregnation
- C04B41/82—Coating or impregnation with organic materials
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/80—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone of only ceramics
- C04B41/81—Coating or impregnation
- C04B41/82—Coating or impregnation with organic materials
- C04B41/83—Macromolecular compounds
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- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Ceramic Engineering (AREA)
- Materials Engineering (AREA)
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- Organic Chemistry (AREA)
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Abstract
The invention discloses a kind of ceramic tile of resin glue filling porous ceramics formation, by brick body and be overlying on the coating on brick body surface and constitute, described brick body by porous ceramics brick skeleton, the middle film layer being attached on ceramic hole and be filled into outside middle film layer, the resin glue of fill ceramics hole is constituted.
Description
Technical field
The present invention relates to the ceramic tile and its system in ceramic technology field, more particularly to a kind of filling porous ceramics formation of resin glue
Preparation Method.
Background technology
Ceramic Tiles are seen everywhere in daily life, are a kind of important construction materials, and traditional Ceramic Tiles are by clay
With other inorganic non-metallic raw materials, tabular or Bulk ceramic product through technique productions such as shaping, sintering, for decorating and protecting
Building, the metope of structures and ground.Generally it is molded at room temperature by dry-pressing, extruding or other forming methods, Ran Hougan
It is dry, burn till at a certain temperature.It is right because the preparation of traditional ceramic tile needs to consume the native natural resources of substantial amounts of ore deposit and fossil fuel
Environment has irreversible harm；In addition, traditional Ceramic Tiles are held from great when being pasted onto on metope after keel stress
Yielding, displacement, the length of time one being the problems such as may result in hollowing, drop, and not only influences attractive in appearance also there is potential safety hazard.
Given birth to improve the defect of traditional ceramics brick, the ceramic-like light brick application of non-sintered, this kind of material is relied primarily on
Organic or inorganic sizing material replaces high temperature sintering, the imitative ceramic tile that is prepared with some inorganic fillers under normal temperature or relatively low temperature
Product, this product reduces the consumption of fossil fuel, and the range of choice to inorganic filler is wider, not only reduces production cost
Also so that color and the kind more horn of plenty of ceramic tile, the market competitiveness are stronger.《Total utilization of PCA》Printed on 01 phases in 2013
" preparation of flyash polyurethane ceramic tile imitation and performance study " one text gone out is using flyash as filler, and polyurethane is used as adhesive
A kind of non-sintered imitative ceramic tile is prepared for, although needed for this imitative ceramic tile can meet production and living in mechanical property,
Corrosion resistance, wear-resistant scratch resistant etc. are poor, and contain some poisonous and harmful substances inside flyash, using being limited in scope.
The content of the invention
The present invention in order to make up the defect of prior art there is provided a kind of ceramic tile of resin glue filling porous ceramics formation and its
Preparation method.
The present invention is achieved by the following technical solutions：
A kind of ceramic tile of resin glue filling porous ceramics formation, is made up of brick body and the coating for being overlying on brick body surface, described
Brick body is by porous ceramics brick skeleton, the middle film layer being attached on ceramic hole and is filled into outside middle film layer, fills ceramics
The resin glue composition of hole.
A kind of preparation method of the ceramic tile of described resin glue filling porous ceramics formation comprises the following steps：
（1）The porous pottery of different porosities and pore shape is made through being molded base, sintering in ceramic slurry according to needed for production
Ceramic tile skeleton；
（2）By immersion treatment 12-18h in the porous ceramics brick skeleton input film forming treatment fluid of gained, processing is taken out after terminating, used
Deionized water is dried after cleaning 2-3 times；
（3）Ceramic Tiles skeleton after processing is placed on the table, using glue-injection machine pressurization resin by injection glue, gone out after filling
Curing process in material, feeding solidification equipment, completes the solidification of resin glue；
（4）Brick body after being fully cured is polished, cleaning, after coating treatment, produce described Ceramic Tiles.
The porosity of described porous ceramics brick skeleton is 10-90%, aperture 1-10mm.
Described film forming treatment fluid is that the concentration being formulated by Dopamine hydrochloride, buffer reagent, water is many of 1-10g/L
Bar amine aqueous solution, pH value is 8-8.5.
Described resin glue is one kind in epoxylite glue, phenolic resinoid glue, polyurethane based resin glue.
The present invention is prepared for a kind of ceramics/resin being made up of porous ceramic skeleton, middle poly-dopamine film layer, resin glue
Composite ceramics is as the Ceramic Tiles of brick body, and this Ceramic Tiles had both had the advantages that full Ceramic Tiles, again anti-with light-weight refractory, cracking resistance
Shake, waterproof corrosion resistant, it is environment-protecting and non-poisonous the advantages of, using poly-dopamine film layer as intermediate layer in preparation process, effectively raise
Adhesion strength of the resin in hole, improves the stability of product, and the preparation method high-efficiency environment friendly of ceramic tile of the present invention is adapted to work
Industry metaplasia is produced.
Embodiment
A kind of ceramic tile of resin glue filling porous ceramics formation, is made up of, institute brick body and the coating for being overlying on brick body surface
The brick body stated is by porous ceramics brick skeleton, the middle film layer being attached on ceramic hole and is filled into outside middle film layer, fills
The resin glue composition of ceramic hole.
The preparation method of the embodiment ceramic tile comprises the following steps：
（1）The circular hole porous ceramics that porosity is 45% is made through being molded base, sintering in ceramic slurry according to needed for production
Brick skeleton, aperture is 2mm；
（2）By immersion treatment 12h in the porous ceramics brick skeleton input film forming treatment fluid of gained, processing is taken out after terminating, spent
Ionized water is dried after cleaning 2 times；
（3）Ceramic Tiles skeleton after processing is placed on the table, using glue-injection machine pressurization injection epoxide-resin glue, after filling
Curing process in discharging, feeding solidification equipment, completes the solidification of resin glue；
（4）Brick body after being fully cured is polished, cleaning, after coating treatment, produce described Ceramic Tiles.
Wherein film forming treatment fluid is the dopamine that the concentration being formulated by Dopamine hydrochloride, buffer reagent, water is 1g/L
Solution, pH value is 8.
Claims (5)
1. a kind of ceramic tile of resin glue filling porous ceramics formation, is made up of, it is special brick body and the coating for being overlying on brick body surface
Levy and be, described brick body is by porous ceramics brick skeleton, the middle film layer being attached on ceramic hole and is filled into intermediate coat
Layer is outer, the resin glue composition of the ceramic hole of filling.
2. a kind of preparation method of the ceramic tile of resin glue filling porous ceramics formation as claimed in claim 1, it is characterised in that
Comprise the following steps：
（1）The porous pottery of different porosities and pore shape is made through being molded base, sintering in ceramic slurry according to needed for production
Ceramic tile skeleton；
（2）By immersion treatment 12-18h in the porous ceramics brick skeleton input film forming treatment fluid of gained, processing is taken out after terminating, used
Deionized water is dried after cleaning 2-3 times；
（3）Ceramic Tiles skeleton after processing is placed on the table, using glue-injection machine pressurization resin by injection glue, gone out after filling
Curing process in material, feeding solidification equipment, completes the solidification of resin glue；
（4）Brick body after being fully cured is polished, cleaning, after coating treatment, produce described Ceramic Tiles.
3. a kind of preparation method of the ceramic tile of resin glue filling porous ceramics formation as claimed in claim 2, it is characterised in that
The porosity of described porous ceramics brick skeleton is 10-90%, aperture 1-10mm.
4. a kind of preparation method of the ceramic tile of resin glue filling porous ceramics formation as claimed in claim 2, it is characterised in that
Described film forming treatment fluid is that the concentration being formulated by Dopamine hydrochloride, buffer reagent, water is molten for 1-10g/L dopamine
Liquid, pH value is 8-8.5.
5. a kind of preparation method of the ceramic tile of resin glue filling porous ceramics formation as claimed in claim 2, it is characterised in that
Described resin glue is one kind in epoxylite glue, phenolic resinoid glue, polyurethane based resin glue.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710412757.5A CN107056331A (en) | 2017-06-05 | 2017-06-05 | A kind of ceramic tile of resin glue filling porous ceramics formation and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710412757.5A CN107056331A (en) | 2017-06-05 | 2017-06-05 | A kind of ceramic tile of resin glue filling porous ceramics formation and preparation method thereof |
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| Publication Number | Publication Date |
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| CN107056331A true CN107056331A (en) | 2017-08-18 |
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201710412757.5A Pending CN107056331A (en) | 2017-06-05 | 2017-06-05 | A kind of ceramic tile of resin glue filling porous ceramics formation and preparation method thereof |
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Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108571131A (en) * | 2018-04-16 | 2018-09-25 | 广东金意陶陶瓷集团有限公司 | A kind of porous ceramics dalle and preparation method thereof with air-cleaning function |
| CN113563116A (en) * | 2021-07-21 | 2021-10-29 | 佛山欧神诺陶瓷有限公司 | Composite ceramic tile and preparation method and application thereof |
| CN114990398A (en) * | 2021-03-01 | 2022-09-02 | 佳能株式会社 | Alloy member, sliding member, apparatus, and method of manufacturing alloy member |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102234187A (en) * | 2010-04-29 | 2011-11-09 | 比亚迪股份有限公司 | Ceramic composite material and preparation method thereof |
| CN105920668A (en) * | 2016-06-08 | 2016-09-07 | 西南交通大学 | Preparation method of antibacterial biological activity ceramic coating with magnetic responsiveness |
-
2017
- 2017-06-05 CN CN201710412757.5A patent/CN107056331A/en active Pending
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102234187A (en) * | 2010-04-29 | 2011-11-09 | 比亚迪股份有限公司 | Ceramic composite material and preparation method thereof |
| CN105920668A (en) * | 2016-06-08 | 2016-09-07 | 西南交通大学 | Preparation method of antibacterial biological activity ceramic coating with magnetic responsiveness |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108571131A (en) * | 2018-04-16 | 2018-09-25 | 广东金意陶陶瓷集团有限公司 | A kind of porous ceramics dalle and preparation method thereof with air-cleaning function |
| CN114990398A (en) * | 2021-03-01 | 2022-09-02 | 佳能株式会社 | Alloy member, sliding member, apparatus, and method of manufacturing alloy member |
| CN114990398B (en) * | 2021-03-01 | 2024-04-05 | 佳能株式会社 | Alloy member, sliding member, apparatus, and method of manufacturing alloy member |
| CN113563116A (en) * | 2021-07-21 | 2021-10-29 | 佛山欧神诺陶瓷有限公司 | Composite ceramic tile and preparation method and application thereof |
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Application publication date: 20170818 |