CN107056055A - A kind of photocatalysis antibacterial enamel - Google Patents
A kind of photocatalysis antibacterial enamel Download PDFInfo
- Publication number
- CN107056055A CN107056055A CN201710436693.2A CN201710436693A CN107056055A CN 107056055 A CN107056055 A CN 107056055A CN 201710436693 A CN201710436693 A CN 201710436693A CN 107056055 A CN107056055 A CN 107056055A
- Authority
- CN
- China
- Prior art keywords
- parts
- zinc oxide
- nano zinc
- photocatalysis antibacterial
- modified nano
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C8/00—Enamels; Glazes; Fusion seal compositions being frit compositions having non-frit additions
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C2204/00—Glasses, glazes or enamels with special properties
- C03C2204/02—Antibacterial glass, glaze or enamel
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Geochemistry & Mineralogy (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
The invention discloses a kind of photocatalysis antibacterial enamel for belonging to field of ceramic preparation technology.The photocatalysis antibacterial enamel, includes the component of following weight composition：SiO270 85 parts, Al 2O310 25 parts, 7 10 parts of CaO, 0.3 10 parts of modified nano zinc oxide, 27 parts of CuO, 3 10 parts of MgO, C6014 parts, 17 parts of BaO, B2O316 parts, Na2SiO33 10 parts.Photocatalysis antibacterial enamel of the present invention, carries silver-colored inorganic antibacterial material, the ceramic surface color burnt out will not distortion or discoloration due to being not used.The modified nano zinc oxide contained can play antibacterial action long-term effectively due to its durable antibiotic, under natural light, and the resistance for Escherichia coli and staphylococcus aureus can respectively reach more than 90%.
Description
Technical field
The present invention relates to a kind of photocatalysis antibacterial enamel, belong to field of ceramic preparation technology.
Background technology
Home environment and people's is healthy closely bound up, and ceramic has important work in home environment
With so the ceramics of research and development antibacterial are to reducing transmission, building up health is of great practical significance.
Enamel, also known as ceramic glaze, are the glassy state thin layers for the colorless or colored for being covered in ceramic surface.People are in porcelain
Antiseptic is added in glaze antibacterial glaze is made, reached the purpose of antibacterial., can be with by composition currently used for the antiseptic of ceramic
It is divided into organic and inorganic two major class, wherein inorganic antiseptic is with its broad spectrum antibacterial, lasting effect, water-fast, acidproof wash resistant, heat-resisting
Light resistance, security are paid attention to by researcher.
Inorganic antiseptic is mainly the system being carried on metal or metal ion with antibacterial ability on organic carrier
Agent.The conventional inorganic antiseptic of current antibacterial glaze mainly has two classes：Silver-series antibacterial agent and titanium oxide base conductor photocatalysis antibacterial
Agent.Contain silver compound or Ag-carried antibacterial material in silver-series antibacterial agent, wherein silver ion has antibacterial activity, can kill or
Suppress bacterium, virus, algae and fungi.Titanium oxide base light touch antiseptic in contain titanium oxide, zinc oxide, titanium dioxide three-iron,
The semi-conducting materials such as aluminum oxide, it is optically excited by the electronics on titanium atom during illumination, and its running track changes, so as to produce
Raw extremely strong oxidability.This oxidability can make organic matter resolve into carbon dioxide and hydrone, can also decompose part nothing
Machine compound, so that with very strong oxidability.
But above-mentioned antiseptic is in use, also tool has disadvantages that：With ceramics of the silver as main antiseptic elements
Glaze production cost is higher, so as to influence it promoting the use of on a large scale.In addition, the element such as silver, iron is quicker to light and heat
Easily blackening after sense, particularly glaze are irradiated through ultraviolet, so as to influence the outward appearance of white or light color ceramics.TiO 2 series resist
Bacterium material needs ultraviolet light, and anti-microbial property is poor in the environment of light dark place or without ultraviolet.Also part antiseptic is not
It can be combined well with glaze, the glaze layer formed by is not bright and clean, attractive in appearance, easily hides bacterium.
Zinc oxide equally has the characteristic of above-mentioned titanium dioxide antibiotic, but its optical range absorbed includes ultraviolet light and visible
Light.Nano zine oxide has the double grading of nano material and conventional oxidation zinc simultaneously, plays antibacterial activity and extinction characteristic is all excellent
In conventional oxidation zinc.And because its particle is thin, activity is high, the sintering temperature of glass and ceramics can be reduced, also with receiving
Ceramic glaze prepared by rice zinc oxide is brighter and cleaner, and has the effects such as antibacterial, anti-enzyme, deodorization.But with conventional oxidation zinc
Product is compared, and because nano zine oxide has specific surface area big and the features such as specific surface energy is big, itself easily reunites, and is difficult uniformly to divide
Dissipate.On the other hand, surface of nanometer zinc oxide polarity is stronger, is difficult in organic media dispersed, and this just significantly limit
The performance of its nano effect.
The content of the invention
It is an object of the invention to overcome antibacterial ceramic glaze surface color distortion in the prior art, discoloration；Antibacterial lasting effect
It is poor；Glaze layer poor quality, surface is imperfect, not bright and clean；And must the problem of can just be worked under conditions of ultraviolet light,
There is provided that a kind of anti-microbial property is good, Ceramic glaze is bright and clean, the antibacterial enamel that to be applicable illumination range wide.
In order to solve the above technical problems, technical scheme is as follows：
A kind of photocatalysis antibacterial enamel, includes the component of following weight composition：
SiO2 70-85 parts, Al 2O3 10-25 parts, 7-10 parts of CaO, 0.3-10 parts of modified nano zinc oxide,
3-10 parts of 2-7 parts of CuO, MgO, C601-4 parts, 1-7 parts of BaO, B2O31-6 parts, Na2SiO33-10 parts.
In above-mentioned photocatalysis antibacterial enamel, it is preferred that the component constituted including following weight：
SiO2 75-85 parts, Al 2O3 15-25 parts, 7-10 parts of CaO, 0.5-8 parts of modified nano zinc oxide,
3-8 parts of 2-5 parts of CuO, MgO, C601-2 parts, 1-6 parts of BaO, B2O32-5 parts, Na2SiO35-8 parts.
It is optimal in above-mentioned photocatalysis antibacterial enamel, include the component of following weight composition：
SiO2 80-83 parts, Al 2O3 20-25 parts, 7-9 parts of CaO, 1-5 parts of modified nano zinc oxide,
4-8 parts of 2-5 parts of CuO, MgO, C601-2 parts, 3-5 parts of BaO, B2O32-5 parts, Na2SiO35-8 parts.
In above-mentioned photocatalysis antibacterial enamel, the preparation method of the modified nano zinc oxide is：Nano zine oxide is disperseed
In 2-3wt% melamine acetic acid solution, nano zinc oxide fluid dispersion is obtained；Nano zine oxide and the melamine matter
Amount is than being 1:2-3；Obtained nano zinc oxide fluid dispersion is evaporated, roasting in Muffle furnace is placed into, is protected with inert gas
Gas, is warming up to 450-500 DEG C of holding 2-3h, obtains modified nano zinc oxide.
In above-mentioned photocatalysis antibacterial enamel, the temperature being evaporated is 80-85 DEG C.
In above-mentioned photocatalysis antibacterial enamel, the process of the heating is：It is warming up to 5 DEG C/min after 400 DEG C, then with 3
DEG C/min is warming up to 450-500 DEG C.
The preparation method of above-mentioned photocatalysis antibacterial enamel, including step are as follows：
（1）Each component is quantitatively weighed in proportion, and modified nano zinc oxide is pressed into mass volume ratio 1-1.2g:100mL is dispersed
In 30-40% ethanol water, then it is evaporated to solid-to-liquid ratio and reaches more than 75-85%, obtains the aqueous slurry of modified nano zinc oxide
Material；
（2）By the component after modified nano zinc oxide water paste and other smashings together ball milling, photocatalysis antibacterial enamel is obtained.
A kind of preparation method of photocatalysis antibacterial ceramics, including step are as follows：
By the slurry of the photocatalysis antibacterial enamel of above-mentioned preparation, equably spray, smear or be covered on ceramic plain embryo, dried
It is dry, then fire and obtain photocatalysis antibacterial ceramics.
In above-mentioned preparation method, the condition of the firing is：In 730-1200 DEG C, fire 2-8 hours.
The above-mentioned technical proposal of the present invention has advantages below compared with prior art：
（1）Photocatalysis antibacterial enamel of the present invention, silver-colored inorganic antibacterial material, the ceramic surface burnt out are carried due to being not used
Color will not distortion or discoloration.The modified nano zinc oxide contained can play antibacterial long-term effectively due to its durable antibiotic
Effect, and because its particle is thin, activity is high, can preferably be acted on other glazes, and in each composition of glaze
Under interaction, it is easy to combine together with ceramics, the sintering temperature of ceramics, the Ceramic glaze more light of preparation can be reduced
It is clean.
（2）Photocatalysis antibacterial enamel of the present invention, can play antibacterial action under conditions of natural light, be applicable illumination
Scope is wide.Under natural light, the resistance for Escherichia coli and staphylococcus aureus can respectively reach more than 90%.
Embodiment
The method of the present invention will be further described by instantiation below.Raw material, reagent, the instrument of the present invention
Unless otherwise specified, it is all commercially available.It is raw materials used in following examples, it is commercially available unless otherwise specified.In following embodiments
Component be to describe by weight, when can be weighed according to actual conditions select g or Kg units.
Embodiment 1
The preparation method of modified nano zinc oxide is：Nano zine oxide is scattered in 2wt% melamine acetic acid solution, obtained
To nano zinc oxide fluid dispersion；Nano zine oxide and the melamine mass ratio is 1:2, obtained nano zine oxide is disperseed
Liquid is evaporated in 80 DEG C, places into roasting in Muffle furnace, protection gas is made with inert gas, is warming up to 450 DEG C of holding 3h, temperature-rise period
For：It is warming up to 5 DEG C/min after 400 DEG C, then 450 DEG C is warming up to 3 DEG C/min, obtains modified nano zinc oxide.
A kind of photocatalysis antibacterial enamel, includes the component of following weight composition：SiO2 80 parts, Al 2O3 25 parts, CaO 9
Part, 0.5 part of modified nano zinc oxide prepared by the above method, 5 parts of CuO, 8 parts of MgO, C602 parts, 3 parts of BaO, B2O3 5
Part, Na2SiO35 parts.
The preparation method of above-mentioned photocatalysis antibacterial enamel, including step are as follows：
（1）Each component is quantitatively weighed in proportion, and modified nano zinc oxide is pressed into mass volume ratio 1g:100mL is dispersed in 30%
Ethanol water, be then evaporated to solid-to-liquid ratio and reach more than 75%, obtain modified nano zinc oxide water paste；
（2）By the component after modified nano zinc oxide water paste and other smashings together ball milling, photocatalysis antibacterial enamel is obtained.
Embodiment 2
A kind of photocatalysis antibacterial enamel, includes the component of following weight composition：SiO2 83 parts, Al 2O3 25 parts, 7 parts of CaO is real
Apply 1 part of the modified nano zinc oxide prepared in example 1,2 parts of CuO, 10 parts of MgO, C601 part, 5 parts of BaO, B2O32 parts,
Na2SiO38 parts.
The preparation method of above-mentioned photocatalysis antibacterial enamel, including step are as follows：
（1）Each component is quantitatively weighed in proportion, and modified nano zinc oxide is pressed into mass volume ratio 1.2g:100mL is dispersed in
35% ethanol water, is then evaporated to solid-to-liquid ratio and reaches more than 75%, obtain modified nano zinc oxide water paste；
（2）By the component after modified nano zinc oxide water paste and other smashings together ball milling, photocatalysis antibacterial enamel is obtained.
Embodiment 3
The preparation method of modified nano zinc oxide is：Nano zine oxide is scattered in 3wt% melamine acetic acid solution, obtained
To nano zinc oxide fluid dispersion；Nano zine oxide and the melamine mass ratio is 1:3；Obtained nano zine oxide is disperseed
Liquid is evaporated in 85 DEG C, places into roasting in Muffle furnace, protection gas is made with inert gas, is warming up to 500 DEG C of holding 2h, temperature-rise period
For：It is warming up to 5 DEG C/min after 400 DEG C, then 500 DEG C is warming up to 3 DEG C/min, obtains modified nano zinc oxide.
A kind of photocatalysis antibacterial enamel, includes the component of following weight composition：SiO2 70 parts, Al 2O3 25 parts, CaO 7
Part, 0.3 part of modified nano zinc oxide prepared by the above method, 2 parts of CuO, 4 parts of MgO, C604 parts, 7 parts of BaO, B2O3 2
Part, Na2SiO33 parts.
The preparation method of above-mentioned photocatalysis antibacterial enamel, including step are as follows：
（1）Each component is quantitatively weighed in proportion, and modified nano zinc oxide is pressed into mass volume ratio 1.2g:100mL is dispersed in
40% ethanol water, is then evaporated to solid-to-liquid ratio and reaches more than 85%, obtain modified nano zinc oxide water paste；
（2）By the component after modified nano zinc oxide water paste and other smashings together ball milling, photocatalysis antibacterial enamel is obtained.
Embodiment 4
A kind of photocatalysis antibacterial enamel, includes the component of following weight composition：SiO2 85 parts, Al 2O3 10 parts, 10 parts of CaO is real
Apply 5 parts of the modified nano zinc oxide of the preparation of example 3,7 parts of CuO, 10 parts of MgO, C601 part, 6 parts of BaO, B2O36 parts, Na2SiO3
10 parts.
The preparation method of above-mentioned photocatalysis antibacterial enamel, including step are as follows：
（1）Each component is quantitatively weighed in proportion, and modified nano zinc oxide is pressed into the g of mass volume ratio 1:100mL is dispersed in
30% ethanol water, is then evaporated to solid-to-liquid ratio and reaches more than 75%, obtain modified nano zinc oxide water paste；
（2）By the component after modified nano zinc oxide water paste and other smashings together ball milling, photocatalysis antibacterial enamel is obtained.
Embodiment 5
A kind of photocatalysis antibacterial enamel, includes the component of following weight composition：SiO2 85 parts, Al 2O3 25 parts, 7 parts of CaO is real
Apply 2 parts of the modified nano zinc oxide of the preparation of example 3,5 parts of CuO, 8 parts of MgO, C604 parts, 2 parts of BaO, B2O32 parts, Na2SiO3
3 parts.
The preparation method of above-mentioned photocatalysis antibacterial enamel, including step are as follows：
（1）Each component is quantitatively weighed in proportion, and modified nano zinc oxide is pressed into the g of mass volume ratio 1.2:100mL is dispersed in
30% ethanol water, is then evaporated to solid-to-liquid ratio and reaches more than 75%, obtain modified nano zinc oxide water paste；
（2）By the component after modified nano zinc oxide water paste and other smashings together ball milling, photocatalysis antibacterial enamel is obtained.
Comparative example 1
Antibacterial enamel, includes the component of following weight composition：SiO2 80 parts, Al 2O3 25 parts, 9 parts of CaO, 0.5 part of zinc oxide,
8 parts of 5 parts of CuO, MgO, C602 parts, 3 parts of BaO, B2O35 parts, Na2SiO35 parts.
The preparation method of above-mentioned photocatalysis antibacterial enamel, including step are as follows：Each component is quantitatively weighed in proportion, after smashing
Ball milling, obtains photocatalysis antibacterial enamel.
Comparative example 2
Antibacterial enamel, includes the component of following weight composition：SiO2 80 parts, Al 2O3 25 parts, 9 parts of CaO, nano zine oxide
0.5 part, 5 parts of CuO, 8 parts of MgO, C602 parts, 3 parts of BaO, B2O35 parts, Na2SiO35 parts.
The preparation method of above-mentioned photocatalysis antibacterial enamel, including step are as follows：Each component is quantitatively weighed in proportion, after smashing
Ball milling, obtains antibacterial enamel.
Embodiment 6
By the slurry of embodiment 1-5, comparative example 1-2 the antibacterial enamel prepared, ceramic plain embryo is equably sprayed, smears or is covered in
On, dried, then in 1030 DEG C, fired 4 hours.The surface coating antibacterial enamel of preparation glaze layer glaze is smooth, color
Damp lime is clear, flawless.
Embodiment 7
Antibacterial, degerming performance test：
Surface manufactured in the present embodiment coating cold glaze ceramic body is subjected to antibacterial, degerming performance test, according to document
（Journal of Chemical Technology and Metallurgy, 2013,48,154-161）Method, will train
Supporting has 105cfu（Bacterium number）/ ml Escherichia coli and staphylococcus aureus are coated in glaze layer surface, natural lighting 1 hour
Afterwards, the sterilization rate of Escherichia coli and the sterilization rate of staphylococcus aureus such as following table.
The anti-Escherichia coli of antibacterial enamel and the performance of staphylococcus aureus
Shown according to the above results, antibacterial enamel prepared by method of the invention has good anti-microbial property.
Obviously, above-described embodiment is only intended to clearly illustrate example, and the not restriction to embodiment.It is right
For those of ordinary skill in the art, can also make on the basis of the above description it is other it is various forms of change or
Change.There is no necessity and possibility to exhaust all the enbodiments.And the obvious change thus extended out or
Among changing still in the protection domain of the invention.
Claims (9)
1. a kind of photocatalysis antibacterial enamel, it is characterised in that the component constituted including following weight：SiO270-85 parts, Al2O3
10-25 parts, 7-10 parts of CaO, 0.3-10 parts of modified nano zinc oxide, 2-7 parts of CuO, 3-10 parts of MgO, C601-4 parts, BaO
1-7 parts, B2O31-6 parts, Na2SiO33-10 parts.
2. photocatalysis antibacterial enamel according to claim 1, it is characterised in that the component constituted including following weight：
SiO2 75-85 parts, Al 2O3 15-25 parts, 7-10 parts of CaO, 0.5-8 parts of modified nano zinc oxide, 2-5 parts of CuO, MgO
3-8 parts, C601-2 parts, 1-6 parts of BaO, B2O32-5 parts, Na2SiO35-8 parts.
3. photocatalysis antibacterial enamel according to claim 2, it is characterised in that the component constituted including following weight：
SiO2 80-83 parts, Al 2O3 20-25 parts, 7-9 parts of CaO, 1-5 parts of modified nano zinc oxide, 2-5 parts of CuO, MgO 4-8
Part, C601-2 parts, 3-5 parts of BaO, B2O32-5 parts, Na2SiO35-8 parts.
4. the photocatalysis antibacterial enamel according to claim 1-3, it is characterised in that the preparation of the modified nano zinc oxide
Method is：Nano zine oxide is scattered in 2-3wt% melamine acetic acid solution, nano zinc oxide fluid dispersion is obtained；It is described
Nano zine oxide and melamine mass ratio are 1:2-3, obtained nano zinc oxide fluid dispersion is evaporated, placed into Muffle furnace
Roasting, protection gas is made with inert gas, is warming up to 450-500 DEG C of holding 2-3h, is obtained modified nano zinc oxide.
5. photocatalysis antibacterial enamel according to claim 4, it is characterised in that the temperature being evaporated is 80-85 DEG C.
6. photocatalysis antibacterial enamel according to claim 4, it is characterised in that the process of the heating is：With 5 DEG C/
Min is warming up to after 400 DEG C, then is warming up to 450-500 DEG C with 3 DEG C/min.
7. the preparation method of the photocatalysis antibacterial enamel described in claim 1-6, it is characterised in that as follows including step：
（1）Each component is quantitatively weighed in proportion, and modified nano zinc oxide is pressed into mass volume ratio 1-1.2g:100mL is dispersed
In 30-40% ethanol water, then it is evaporated to solid-to-liquid ratio and reaches more than 75-85%, obtains the aqueous slurry of modified nano zinc oxide
Material；
（2）By the component after modified nano zinc oxide water paste and other smashings together ball milling, photocatalysis antibacterial enamel is obtained.
8. a kind of preparation method of photocatalysis antibacterial ceramics, it is characterised in that as follows including step：
The slurry of photocatalysis antibacterial enamel prepared by claim 7 is equably sprayed, smeared or is covered on ceramic plain embryo, is entered
Row drying, then fires and obtains photocatalysis antibacterial ceramics.
9. preparation method according to claim 8, it is characterised in that the condition of the firing is：In 730-1200 DEG C,
Fire 2-8 hours.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710436693.2A CN107056055A (en) | 2017-06-12 | 2017-06-12 | A kind of photocatalysis antibacterial enamel |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710436693.2A CN107056055A (en) | 2017-06-12 | 2017-06-12 | A kind of photocatalysis antibacterial enamel |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN107056055A true CN107056055A (en) | 2017-08-18 |
Family
ID=59594988
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201710436693.2A Pending CN107056055A (en) | 2017-06-12 | 2017-06-12 | A kind of photocatalysis antibacterial enamel |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN107056055A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN112047630A (en) * | 2020-07-27 | 2020-12-08 | 科立视材料科技有限公司 | Black ceramic with antibacterial property and glaze thereof |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103265335A (en) * | 2013-05-30 | 2013-08-28 | 浙江华仁科技有限公司 | Ceramic glaze with composite mold resistance |
| CN105348865A (en) * | 2015-10-29 | 2016-02-24 | 南京理工大学常熟研究院有限公司 | Modification method of nanometer zinc oxide powder material |
| CN105731798A (en) * | 2016-01-05 | 2016-07-06 | 大埔县佳联陶瓷厂 | Ceramic glaze and preparation method thereof |
| CN106242297A (en) * | 2016-08-29 | 2016-12-21 | 佛山市高明区明城镇新能源新材料产业技术创新中心 | A kind of antibacterial and deodouring Ceramic Tiles and preparation method thereof |
-
2017
- 2017-06-12 CN CN201710436693.2A patent/CN107056055A/en active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103265335A (en) * | 2013-05-30 | 2013-08-28 | 浙江华仁科技有限公司 | Ceramic glaze with composite mold resistance |
| CN105348865A (en) * | 2015-10-29 | 2016-02-24 | 南京理工大学常熟研究院有限公司 | Modification method of nanometer zinc oxide powder material |
| CN105731798A (en) * | 2016-01-05 | 2016-07-06 | 大埔县佳联陶瓷厂 | Ceramic glaze and preparation method thereof |
| CN106242297A (en) * | 2016-08-29 | 2016-12-21 | 佛山市高明区明城镇新能源新材料产业技术创新中心 | A kind of antibacterial and deodouring Ceramic Tiles and preparation method thereof |
Non-Patent Citations (1)
| Title |
|---|
| 邹小平等: "《纳米材料与敏化太阳电池》", 31 December 2014, 上海：上海交通大学出版社 * |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN112047630A (en) * | 2020-07-27 | 2020-12-08 | 科立视材料科技有限公司 | Black ceramic with antibacterial property and glaze thereof |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN110776257B (en) | Ceramic glaze with antibacterial function and preparation method and application thereof | |
| CN109704579A (en) | A kind of ceramic glaze and preparation method thereof with antibacterial functions | |
| CN109896839B (en) | Antibacterial and mildewproof ceramic tile and preparation method thereof | |
| CN101648824B (en) | Applique antibacterial ceramic cutter | |
| CN107129149A (en) | A kind of solar ray photocatalysis antibacterial ceramic glaze | |
| CN103382328B (en) | Antibacterial ink for ceramic ink-jet printing and ceramic tile with antibacterial function | |
| CN105669035B (en) | A kind of self-cleaning antibacterial ceramic glaze and preparation method thereof | |
| CN107603315B (en) | The preparation method of child's bicycle specific complex antibiotic paint and complex antimicrobials and complex antimicrobials | |
| CN101955352B (en) | Preparation method of carbon ceramic container for containing water | |
| JP2024508554A (en) | How to make antibacterial ceramic tiles | |
| JP2008508405A5 (en) | ||
| RU2541703C1 (en) | Coloured glaze | |
| GB2521405A (en) | A surface coating | |
| CN101611718B (en) | Dragon spring celadon antibacterial agent and application thereof | |
| WO2021006680A1 (en) | Antimicrobial glass composition and production method thereof | |
| CN100395204C (en) | Antibacterial float glass | |
| CN108516683B (en) | Crystal glazed tile capable of continuously generating negative ions and preparation method thereof | |
| CN104892032A (en) | Lasting and easy cleaning surface glaze formula and method for preparing sanitary ware | |
| JP2000053451A (en) | Antibacterial glass product and its production | |
| CN107082565A (en) | A kind of photocatalysis antibacterial glaze | |
| CN107056055A (en) | A kind of photocatalysis antibacterial enamel | |
| CN104324052B (en) | A kind of inorganic antiseptic and preparation method thereof | |
| KR101934634B1 (en) | A Glaze Composition With An Excellent Far Infrared Radiation And Antibiosis And A Pottery Manufactured Using The Same | |
| JP4130950B2 (en) | Silver-based antibacterial composition and method for producing the same | |
| CN111732411B (en) | Antibacterial ceramic tile containing photocatalyst and preparation method thereof |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20170818 |