CN107055949A - It is a kind of flexibly to switch the efficient low-consume Rubber Industrial Wastewater processing method and system of technique - Google Patents

It is a kind of flexibly to switch the efficient low-consume Rubber Industrial Wastewater processing method and system of technique Download PDF

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Publication number
CN107055949A
CN107055949A CN201710142729.6A CN201710142729A CN107055949A CN 107055949 A CN107055949 A CN 107055949A CN 201710142729 A CN201710142729 A CN 201710142729A CN 107055949 A CN107055949 A CN 107055949A
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water
waste water
pond
pipeline
techniques
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CN107055949B (en
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周志明
叶长兵
岳树刚
李嘉
李方志
刘晓艳
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Yunnan Yunnan Environmental Technology Co Ltd
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Yunnan Yunnan Environmental Technology Co Ltd
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    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F9/00Multistage treatment of water, waste water or sewage
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/001Processes for the treatment of water whereby the filtration technique is of importance
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/24Treatment of water, waste water, or sewage by flotation
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/30Treatment of water, waste water, or sewage by irradiation
    • C02F1/32Treatment of water, waste water, or sewage by irradiation with ultraviolet light
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/46Treatment of water, waste water, or sewage by electrochemical methods
    • C02F1/461Treatment of water, waste water, or sewage by electrochemical methods by electrolysis
    • C02F1/46104Devices therefor; Their operating or servicing
    • C02F1/46176Galvanic cells
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/50Treatment of water, waste water, or sewage by addition or application of a germicide or by oligodynamic treatment
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/52Treatment of water, waste water, or sewage by flocculation or precipitation of suspended impurities
    • C02F1/5236Treatment of water, waste water, or sewage by flocculation or precipitation of suspended impurities using inorganic agents
    • C02F1/5245Treatment of water, waste water, or sewage by flocculation or precipitation of suspended impurities using inorganic agents using basic salts, e.g. of aluminium and iron
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/52Treatment of water, waste water, or sewage by flocculation or precipitation of suspended impurities
    • C02F1/54Treatment of water, waste water, or sewage by flocculation or precipitation of suspended impurities using organic material
    • C02F1/56Macromolecular compounds
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/72Treatment of water, waste water, or sewage by oxidation
    • C02F1/76Treatment of water, waste water, or sewage by oxidation with halogens or compounds of halogens
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F2001/007Processes including a sedimentation step
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2103/00Nature of the water, waste water, sewage or sludge to be treated
    • C02F2103/34Nature of the water, waste water, sewage or sludge to be treated from industrial activities not provided for in groups C02F2103/12 - C02F2103/32
    • C02F2103/36Nature of the water, waste water, sewage or sludge to be treated from industrial activities not provided for in groups C02F2103/12 - C02F2103/32 from the manufacture of organic compounds
    • C02F2103/38Polymers
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2209/00Controlling or monitoring parameters in water treatment
    • C02F2209/005Processes using a programmable logic controller [PLC]
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2209/00Controlling or monitoring parameters in water treatment
    • C02F2209/08Chemical Oxygen Demand [COD]; Biological Oxygen Demand [BOD]
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2209/00Controlling or monitoring parameters in water treatment
    • C02F2209/14NH3-N
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2209/00Controlling or monitoring parameters in water treatment
    • C02F2209/16Total nitrogen (tkN-N)
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2301/00General aspects of water treatment
    • C02F2301/04Flow arrangements
    • C02F2301/046Recirculation with an external loop
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2303/00Specific treatment goals
    • C02F2303/14Maintenance of water treatment installations
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F3/00Biological treatment of water, waste water, or sewage
    • C02F3/30Aerobic and anaerobic processes

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  • Life Sciences & Earth Sciences (AREA)
  • Hydrology & Water Resources (AREA)
  • Engineering & Computer Science (AREA)
  • Environmental & Geological Engineering (AREA)
  • Water Supply & Treatment (AREA)
  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Water Treatment By Electricity Or Magnetism (AREA)

Abstract

The invention belongs to method of wastewater treatment field, disclose it is a kind of can flexibly switch the efficient low-consume Rubber Industrial Wastewater processing method and system of technique, processing method includes:When entering the Rubber Industrial Wastewater in processing system after pretreatment link, according to actual amount of water size it can be realized in IDEA techniques, D A2O techniques and A2Flexibly switch in O techniques;By inflow QIt is real< 1/2QIfWhen be IDEA process operation patterns;Inflow 1/2QIf≦QIt is real< QIfWhen be D A2O (A, B side alternate run) process operation pattern;Inflow QIf≦QIt is real≦QIfIt is A when (1+20%)2O process operation patterns.The present invention is solved because sewage disposal system causes excessive equipment to participate in system operation in the case of non-design water for a long time and causes the problem of utilization rate of equipment and installations is low, energy consumption is wasted, the final automatic energy-saving processing for realizing sewage disposal system on the premise of water quality reaching standard is ensured.

Description

It is a kind of flexibly to switch the efficient low-consume Rubber Industrial Wastewater processing method and system of technique
Method field
The invention belongs to method of wastewater treatment field, more particularly to a kind of efficient low-consume rubber that can flexibly switch technique are useless Method for treating water and system.
Background method
What the handling process method currently for Rubber Industrial Wastewater was often related to is physical treatment method (such as isolation method, absorption Method, blow-off method, flocculence), biochemical treatment process method (such as anaerobism, anoxic, aerobic) and chemical treatment method (such as electrode polarization Method, Fe-C Micro Electrolysis Method), for above processing method, physical treatment method be primarily directed to can by (as isolation, Absorption, stripping, flocculation) etc. means just can realize the method and method for removing pollutant, and single physical treatment method can not Realize effective removal for dissolubility pollutant;Biochemical treatment process method is primarily directed to certain biochemical The degraded and removal of pollutant, general simple sanitary sewage that can be relatively low to pollutant matrix content are handled, the processing side Method has certain requirement to the degradable degree and biodegradability of dirty water pollutant matrix, when not degradable or difficult degradation has When machine thing proportion is larger, the numerous microbes of internal system lose the drop of pollutant because of too high pollutant impact load Solution ability, so can not ensure pollutant have removal effect;Chemical treatment method can pass through addition primarily directed to a certain class Medicament changes internal system reaction condition to cause dirty water pollutant matrix to occur conversion or transfer (as formed precipitation, gas Body etc.) a kind of processing method means, with reach remove pollutant matrix purpose, however, for many both do not participate in chemistry , only will by single chemical treatment means the rubber pollutant that reaction can not be removed by changing reaction condition again for Effective removal of dirty water pollutant matrix can not be realized.Based on this, for single above-mentioned processing method, it is multiple in reply Seem particularly not enough in terms of the pollutant control of miscellaneous composition, itself main reason is that, no matter taking physical treatment method, at biochemistry Any one of science and engineering process and chemical treatment method method handle the pollutant matrix in rubber sewage.It is mainly removed Dirty mechanism is the self-characteristic that is had according to different pollutants to determine, this is certainly existed in actual sewage to pollutant Matrix removes the limitation in effect.To embody physical treatment method, biochemical processing method simultaneously in same processing system With the common feature of chemical treatment method, this has just risen to the category of combined technical method, and its method, feature are relative to list One physical treatment method, biochemical treatment process method or chemical treatment method wants superior many.However, group technology is By the way that different processes is realized by the combination of certain way, this also necessarily result in sewage treatment process construction The problems such as increase, the intensification of device configuration complexity, the increase of handling process floor space and energy consumption increase of difficulty, although Assembled technological can show the processing of the Rubber Industrial Wastewater of complicated component stronger contaminant removal capacity, but this is also to sacrifice throwing It is cost to provide cost, increase system Construction difficulty, reduction utilization rate of equipment and installations, increase operation energy consumption, increase system O&M difficulty etc. And realize.
In summary, the problem of existing method is present be:With regard to single physical treatment, biochemical treatment and chemical treatment method For, existing method seems particularly not enough in terms of the pollutant control of reply complicated ingredient, itself main reason is that, no matter adopting Which kind of method in physical treatment method, biochemical treatment process method and chemical treatment method is taken to handle the pollutant in sewage Matrix, its main defouling mechanism is the self-characteristic that is had according to different pollutants to determine, this is certainly existed in reality The limitation in effect is removed in sewage to pollutant matrix;
The group technology of existing method exist sewage treatment process difficulty of construction increase, device configuration complexity deepen, The problems such as handling process floor space increases, although assembled technological can show the Rubber Industrial Wastewater of complicated component stronger pollution Thing removal ability, but this is also to run energy to sacrifice cost of investment, increase system Construction difficulty, reduce utilization rate of equipment and installations, increase Consumption, increase system O&M difficulty etc. are realized for cost;
Current most of sewage and wastewater treatment system facility is designed by design maximum water at a specified future date , even if there is a small amount of sewage to be required to start all set into processing system within one very long period under normal circumstances Standby, only the stain disease of a small amount of or normal volume enters in processing system in actual stain disease processing procedure is handled, this certainty It can cause under non-design maximum water state, the relevant device of design maximum parameter configuration is pressed in original sewage disposal system The problems such as low, the energy consumption waste of utilization rate of equipment and installations caused by process startup, frequent starting.
The content of the invention
The problem of existing for existing method, it is useless the invention provides a kind of efficient low-consume rubber that can flexibly switch technique Method for treating water and system.
The present invention is achieved in that a kind of efficient low-consume Rubber Industrial Wastewater processing method that can flexibly switch technique includes: After natural rubber production waste water removes oil removal, micelle debris through type mechanical grate foul remover, gravity flow enters setting pot, proportion compared with Big most of silts and particulate matter will precipitate;Waste water waste water flowing comprehensive adjustment pond, and being held by fixed spool successively To effective regulation of water to realize the equilibrium into pollutant concentration in processing system;Waste water quality and water quilt in the pond And, some organic pollutants in comprehensive wastewater again this simply hydrolyzed, make the biodegradability of comprehensive wastewater further Lifting;
Under the active state of regulating reservoir elevator pump, water outlet flows through dissolved air flotation device successively, after coagulating of offeing medicine The suspension material of part is removed, the suspension material of half dissolved state in waste water is removed, during which through air flotation effect The scum silica frost of generation is then swept by the machinery of Slag Scraping Device, is discharged into nearby in scum silica frost pond by scum silica frost pipeline;And then waste water solution Into 1# intermediate pools carry out further water quality and;And be continuously delivered to the waste water after homogeneous by lifting device In iron-carbon micro-electrolysis tower, with continuously entering for waste water, waste water medium start play its electrolyte effect, waste water solution with In the galvanic cell environment that the anodic-cathodic of iron-carbon micro-electrolysis filler is constituted, continuously enter along with the reaction of countless miniature galvanic cells OK, promote numerous persistent organic pollutants fully to degrade, with the increase of easily biodegradable organicses content, flow through iron-carbon micro-electrolysis The biodegradability of the waste water of tower is greatly improved, work of the scum silica frost that electrolytic process is produced then through its internal three phase separator set With solid phase scum silica frost is then periodically emitted into scum silica frost pond by deslagging pipeline;Go out to flow waste water immediately into A, B anaerobic pond;
And then, according to actual stain disease water situation, under the control of PLC control system, the sewage disposal system It can be achieved in IDEA techniques, D-A2O techniques and A2Flexible switching in O techniques;As inflow QIt is real< 1/2QIfWhen switch to IDEA techniques;As inflow 1/2QIf≦QIt is real< QIfWhen switch to D-A2O techniques;As inflow QIf≦QIt is real≦QIfWhen (1+20%) Switch to A2O techniques;Wherein, A sides, the synchronous continuous operation in B sides, intermittence aeration when switching to IDEA techniques;Switch to D-A2O A sides, B sides alternate run during technique;Switch to A2During O techniques, A sides, B sides are run simultaneously.
Further, realize that the method for IDEA process operations includes by PLC control system according to actual stain disease water:
Inflow is in QIt is real< 1/2QIfWhen, made by PLC control system by the production waste water of iron-carbon micro-electrolysis tower successively The anaerobic pond for entering A sides continuously, the anaerobic pond of anoxic pond and B sides, anoxic pond;And to the contact-oxidation pool of continuum micromeehanics Carry out intermittent aeration;And the operation of the aeration time and regulating reservoir elevator pump of contact-oxidation pool is controlled by PLC control system Time, realize that the intermittence of system strains water process, so that it is guaranteed that the high efficiency and stability of effluent quality;And by tube settler Use, further the suspension molecule in water outlet is effectively settled, final outflow water is through in 2# as ceramic filter Between pond (sterilization pool sterilize, and the processing through more medium filter flow through UV-device sterilization after, enter Treated sewage reusing water Pond is in case reuse.
Further, D-A is realized by PLC control system according to actual stain disease water2The method bag of O process operations Include:
Inflow is in 1/2QIf≦QIt is real< QIfWhen, the waste water for making to flow out by iron-carbon micro-electrolysis tower by PLC control system Continuous anaerobic pond, the anoxic pond for alternately entering A sides and B sides;And continuity, which is aerated, to be realized to the contact-oxidation pool of continuum micromeehanics, Make anaerobic pond, the anoxic pond continuous alternate run in the regular hour is interval of A sides and B sides by PLC control system;Water outlet is mixed Close liquid and enter tube settler, and realize in the presence of PAC, PAM flocculating agent feeding device mud-water separation, final outflow water warp 2# intermediate pools (after sterilization pool is sterilized, and the processing through more medium filter flows through UV-device sterilization, enter reclaimed water and returned Millpond is in case reuse.
Further, A is realized by PLC control system according to actual stain disease water2The method bag of O process operation formulas Include:
Inflow is in QIf≦QIt is real≦QIfWhen (1+20%), the useless of iron-carbon micro-electrolysis tower is flowed through by PLC control system Water continuously enters anaerobic pond, the anoxic pond of A sides and B sides simultaneously;And the contact-oxidation pool of continuum micromeehanics under the conditions of this is carried out Continuity is aerated;The waste water after contact-oxidation pool is handled is set to flow through tube settler by PLC control system, in the pond Stain disease after processing carries out mud-water separation under the booster action of PAC and PAM flocculants;Water outlet (disappears into 2# intermediate pools Malicious pond), adding for the disinfectants such as hypochlorous acid is quantitatively controlled into the pond by the setting to measuring pump parameter (0-50L/h) Amount;And be delivered to the stain disease after processing in more medium filter step by step by lifting device;Filter water outlet flows through ultraviolet Chlorination equipment is sterilized;Water outlet after final process is through pipeline into reuse pool in case production reuse.
Another object of the present invention is to provide a kind of as described above can flexibly switch at the efficient low-consume Rubber Industrial Wastewater of technique The processing system of reason method, including:
Mechanical grille for removing suspension in processing waste water, micelle debris;
It is connected with mechanical grille by pipeline, for the setting pot that heavy silt and particulate matter precipitate;
It is connected with setting pot by pipeline, for by the regulating reservoir of waste water quality and water sum;
It is connected with the regulating reservoir elevator pump of regulating reservoir, the air-dissolving air-float of scum silica frost is produced to the waste water after coagulating of offeing medicine Device;
It is connected with dissolved air flotation device by pipeline, for the 1# intermediate pools to the further water quality of waste water sum;
It is connected with 1# intermediate pools by pipeline, the iron-carbon micro-electrolysis tower for electrolysis wastewater;
It is connected with iron-carbon micro-electrolysis tower by pipeline, (A, B) anaerobic pond for carrying out anaerobic reaction to rich water;
It is connected with (A, B) anaerobic pond by pipeline, (A, B) anoxic pond for carrying out hypoxia response to waste water;
It is connected with (A, B) anoxic pond by pipeline, the contact-oxidation pool for entering Line Continuity aeration to waste water;
It is connected with contact-oxidation pool by pipeline, for the tube settler to waste water mud-water separation;
It is connected with tube settler by pipeline, for the 2# intermediate pools carried out disinfection to waste water;
It is connected with 2# intermediate pools by pipeline, for the more medium filter filtered to waste water;
It is connected with more medium filter by pipeline, the reuse pool for carrying out huge profit to the waste water after processing;
According to actual stain disease water situation, for carrying out IDEA techniques, D-A to waste water2O techniques and A2O techniques switch PLC control system.
Further, the processing system also includes:Be plugged on the pretreatment Aeration fan above regulating reservoir, be plugged on (A, B) anaerobic pond and the diving mixer in (A, B) anoxic pond, the sludge reflux self priming pump being plugged on above tube settler, grafting Contact-oxidation pool Aeration fan in contact-oxidation pool, the constant pressure water supply unit for connecting by pipeline reuse pool, insert The backwash self priming pump being connected on above reuse pool and used wire connection PLC control system
Including:Trash rack canal, grid slag bath, setting pot, comprehensive adjustment pond, PAC, PAM chemicals dosing plant, air-dissolving air-float are set Standby, middle 1# ponds, iron-carbon micro-electrolysis tower, A anaerobic ponds, B anaerobic ponds, A anoxic ponds, B anoxic ponds, contact-oxidation pool, inclined tube sink Shallow lake pond, 2# intermediate pools (sterilization pool), hypochlorous acid chlorination equipment, more medium filter, apparatus for ultraviolet disinfection, reuse pool, dirt Mud sump, pretreatment Aeration fan, the submersible agitating being arranged in A, B anaerobic pond and A, B anoxic pond being arranged on above regulating reservoir Machine, the sludge reflux self priming pump being arranged on above sludge-tank, the PLC control system being arranged in equipment room, contact-oxidation pool expose Gas blower fan, constant pressure water supply unit, the backwash self priming pump being arranged on above reuse pool.
Advantages of the present invention and good effect are:Compared with immobilization group technology processing Rubber Industrial Wastewater method, the present invention And considering the factors such as the energy loss in real process, the inventive method can ensure system stable water outlet precondition up to standard Under at least save 20%-30% system operation energy consumption, power savings advantages are obvious.
For high concentration hard-degraded organic waste water processing, existing method it is difficult to ensure that the high efficiency of Waste Water Treatment and steady It is qualitative, the inventive method can make into water COD, BOD5, TN, ammonia nitrogen, TP contents respectively 3280mg/L, 2140mg/L, 624mg/L, 310mg/L, 26mg/L mean concentration level, degrade respectively to 50mg/L, 20mg/L, 15mg/L, 10mg/L, 1.5mg/L mean concentration is below horizontal, degradation rate respectively be up to 98.5%, 99.06%, 97.59%, 96.78%, 94.23%, and effect stability.
By the reasonable application of PLC programmed methods, the automaticity of sewage disposal system is greatly improved, and according to people Realize it in IDEA techniques, D-A for control2O techniques and A2Flexible switching in O techniques, this method power savings advantages, outlet effect Highlighted in terms of advantage, Automated condtrol advantage.
The present invention can be according to the actual amount of water situation of waste water, by the program setting of PLC control system, according to actual dirt The equipment of waste water water situation reasonably in start and stop sewage disposal system, it can be ensured that the discharge of sewage and wastewater treatment system stably reaching standard The energy-saving run of stain disease processing procedure can be realized again simultaneously.Change relatively large situation especially for water quality and quantity, lead to It reasonably optimizing PLC control program is crossed, just can realize stabilization, the energy-efficient treatment of stain disease, it is to avoid inside sewage and wastewater treatment system The redundancy of equipment starts and run.Processing method and method for high concentration natural rubber production waste water of the present invention is current not yet Report for work, actually initiate.
Brief description of the drawings
Fig. 1 is provided in an embodiment of the present invention can flexibly to switch the efficient low-consume Rubber Industrial Wastewater process flow of technique Figure.
Fig. 2 is IDEA process operations pattern (mode A) flow chart provided in an embodiment of the present invention.
Fig. 3 is D-A provided in an embodiment of the present invention2O (A, B side alternate run) process operation pattern (B-mode) flow chart.
Fig. 4 is a operational modes provided in an embodiment of the present invention while being embodied in a system from operation side (one side) table The A revealed2O process operation flow charts.
Fig. 5 is b operational modes provided in an embodiment of the present invention while being embodied in a system from quiet side of having a rest (one side) table The SBR process operation flow charts revealed.
Fig. 6 is A provided in an embodiment of the present invention2O process operations pattern (C mode) flow chart.
Fig. 7 is processing system schematic diagram provided in an embodiment of the present invention;
In figure:1st, mechanical grille;2nd, scum silica frost pond;3rd, setting pot;4th, regulating reservoir;5th, PAC, PAM chemicals dosing plant;6th, molten gas gas Floating device (air floatation machine);7th, 1# intermediate pools;8th, hydrolysis acidification coal equipment (iron-carbon micro-electrolysis tower);9th, (A, B) anaerobic pond;10、 (A, B) anoxic pond;11st, contact-oxidation pool;12nd, tube settler;13rd, 2# intermediate pools (sterilization pool);14th, multi-medium filtering Device;15th, apparatus for ultraviolet disinfection;16th, hypochlorous acid chlorination equipment;17th, reuse pool;18th, storage basin;19th, pretreatment aeration wind Machine;20th, diving mixer;21st, sludge reflux self priming pump;22nd, PLC control system;23rd, contact-oxidation pool Aeration fan;24th, become Frequency constant pressure water supply unit;25th, backwash self priming pump;26th, regulating reservoir elevator pump.
Fig. 8 is provided in an embodiment of the present invention can flexibly to switch the efficient low-consume Rubber Industrial Wastewater processing method technique stream of technique Journey block diagram.
Embodiment
In order that the purpose of the present invention, method scheme and advantage are more clearly understood, with reference to embodiments, to the present invention It is further elaborated.It should be appreciated that the specific embodiments described herein are merely illustrative of the present invention, it is not used to Limit the present invention.
It is provided in an embodiment of the present invention can flexibly switch technique efficient low-consume Rubber Industrial Wastewater processing method technological process be: Natural rubber production processing waste water-mechanical grille-regulating reservoir-air-floating apparatus -1# intermediate pool-iron-carbon micro-electrolysis towers - (A, B) anaerobic pond-(A, B) anoxic pond-contact-oxidation pool-tube settler -2# intermediate pools (sterilization pool)-multimediums The handling process of filter-reuse pool-frequency-conversion water supply system-standard water discharge discharge (refers to process flow diagram accompanying drawing 8)。
The application principle of the present invention is described in detail below in conjunction with the accompanying drawings:
As shown in figure 1, provided in an embodiment of the present invention can flexibly switch the efficient low-consume Rubber Industrial Wastewater processing method of technique, Including:
S101:After natural rubber production waste water removes oil removal, micelle debris through type mechanical grate foul remover, gravity flow enters Setting pot, the larger most of silts of proportion and particulate matter will precipitate;Waste water waste water flowing comprehensive adjustment pond successively, In the pond waste water quality and water by and;Some organic pollutants in comprehensive wastewater again this simply hydrolyzed, make comprehensive The biodegradability for closing waste water is further lifted and ensures the equilibrium of pollutant concentration in stain disease by the control to water;
S102:Under the active state of regulating reservoir elevator pump, water outlet flows through dissolved air flotation device successively, and through offeing medicine, coagulation is anti- The suspension material of part should be removed afterwards, the suspension material of half dissolved state in waste water is removed, during which through air supporting The scum silica frost that effect is produced then is swept by the machinery of Slag Scraping Device, is discharged into nearby in scum silica frost pond by scum silica frost pipeline;And then waste water Solution enter 1# intermediate pools carry out further water quality and;And it is by lifting device that the waste water after homogeneous is continuously defeated Deliver in iron-carbon micro-electrolysis tower, with continuously entering for waste water, waste water medium starts to play the effect of its electrolyte, molten in waste water In the galvanic cell environment that the anodic-cathodic of liquid and iron-carbon micro-electrolysis filler is constituted, react and connect along with countless miniature galvanic cells It is continuous to carry out, promote numerous persistent organic pollutants fully to degrade, with the increase of easily biodegradable organicses content, flow through iron carbon micro- The biodegradability for being electrolysed the waste water of tower is greatly improved, and the scum silica frost that electrolytic process is produced is then through its internal three phase separator set Effect, solid phase scum silica frost is then periodically emitted into scum silica frost pond by deslagging pipeline;Go out to flow waste water immediately into A, B anaerobic pond;
S103:And then, according to actual stain disease water situation, under the control of PLC control system, the sewage disposal System can realize it in IDEA techniques, D-A2O techniques and A2Flexible switching in O techniques;As inflow QIt is real< 1/2QIfWhen switch For IDEA techniques;As inflow 1/2QIf≦QIt is real< QIfWhen switch to D-A2O techniques;As inflow QIf≦QIt is real≦QIf(1+20%) When switch to A2O techniques;Wherein, A sides, the synchronous continuous operation in B sides, intermittence aeration when switching to IDEA techniques;Switch to D- A2A sides, B sides alternate run during O techniques;Switch to A2During O techniques, A sides, B sides are run simultaneously.
Dissolved air flotation device is air floatation machine.Iron-carbon micro-electrolysis tower includes hydrolysis acidification tower 1# and hydrolysis acidification tower 2#.
The invention will be further described with technological process below in conjunction with the accompanying drawings:
In Rubber Industrial Wastewater processing method provided in an embodiment of the present invention, when natural rubber production waste water is decontaminated through mechanical grille Machine is gone after the debris such as oil removal, micelle, and gravity flow enters setting pot, and the larger most of silts of proportion and particulate matter will be precipitated Get off, waste water waste water flowing comprehensive adjustment pond successively, in the pond waste water quality and water by and, the part in comprehensive wastewater Organic pollution again this simply hydrolyzed, the biodegradability of comprehensive wastewater is further lifted, and pass through the control to water System ensures the equilibrium of pollutant concentration in stain disease;Water outlet flows through dissolved air flotation device successively, is removed after coagulating of offeing medicine Partial suspension material, carries out effective removal, scum silica frost is by scraping slag to the suspension material of half dissolved state in waste water Machine is discharged into scum silica frost pond, and then waste water solution enter 1# intermediate pools carry out further water quality and, and pass through lifting device Waste water after homogeneous is delivered to iron-carbon micro-electrolysis tower, the anodic-cathodic constituted in iron-carbon micro-electrolysis filler is formed with waste water solution Electrolyte solution environment in, form countless galvanic interactions, promote numerous persistent organic pollutants degradation products degradable Organic matter, greatly improves the biodegradability of waste water, and the scum silica frost of generation then passes through the three phase separation of setting inside iron-carbon micro-electrolysis tower Device is periodically emitted into scum silica frost pond, and waste water enters back segment processing links immediately.This link will respectively be entered according to specific water situation Enter to IDEA process operations pattern, D-A2O process operations pattern or A2Handled in O process operation patterns.
1) IDEA process operations pattern (mode A):
When actual inflow is in (QIt is real< 1/2QIf) scope when, the system is full to be reached sufficient natural rubber production waste water is stable It is that from the aspect of sewage disposal system environmental protection and energy-saving run is realized, can pass through under the pattern and set on the basis of mark discharge PLC internal processes cause the production waste water by iron-carbon micro-electrolysis tower while entering the anaerobic pond of A sides, anoxic pond and B sides Anaerobic pond, anoxic pond, and intermittent aeration is carried out to the contact-oxidation pool of continuum micromeehanics under the conditions of this, and by rationally setting PLC program controls the aeration time of contact-oxidation pool and the run time of regulating reservoir elevator pump, the technique is integrally realized The operation characteristic of IDEA sewage treatment process, and the tube settler in original technique is used as ceramic filter, its mesh Be by taking corresponding measure restrictively to start the basis that fixing equipment makes it in the stably reaching standard for ensuring wastewater treatment On, realize whole sewage disposal system energy-saving run.The system just can be greatly played for whole sewage disposal system The service life advantage of power savings advantages and greatly prolongation equipment.
Under the operational mode, from the point of view of whole sewage and wastewater treatment system, (A, B) both sides show as intermittent operation shape simultaneously State (i.e. IDEA process characteristics).
Its process operation feature is:Water inlet-pre-reaction-aerobic-precipitation-water outlet.
Its technological process is as shown in Figure 2.
2)D-A2O (A, B side alternate run) process operation pattern (B-mode):
When actual inflow is in (1/2QIf≦QIt is real< QIf) scope, can be by setting PLC internal processes to cause under the pattern The waste water flowed out by iron-carbon micro-electrolysis tower continuously alternately enters anaerobic pond, the anoxic pond of A sides and B sides, and under the conditions of this The contact-oxidation pool of continuum micromeehanics realizes that continuity is aerated, by rationally setting PLC program to make the operational mode table of the technique Reveal into water continuously into the A sides of alternate run and anaerobic pond, the anoxic pond of B sides in the regular hour is interval, it is overall Realize D-A2The operation characteristic of O sewage treatment process (shows SBR techniques and A simultaneously inside sewage and wastewater treatment system2O techniques Operation characteristic), its main purpose is to ensure that wastewater treatment is stable can realize whole sewage disposal system again while reaching Energy-saving run.For whole sewage disposal system, its power savings advantages just can be greatly played.In other words, it is intended to meet waste water One big advantage of the integrated cost, actually current stain disease process field of reduction wastewater treatment of being tried one's best while processing qualified discharge Method.
Under the operational mode, from the point of view of whole sewage and wastewater treatment system, A, B both sides show as continuity alternate run state (i.e. D-A2O process characteristics), its technological process is as shown in Figure 3.
Two kinds of operational modes of a and b are embodied in a system and become D-A simultaneously2O techniques.
A. from operation, side (one side) show is A2O process operation features:Water inlet-anaerobic- anoxic- oxic-is precipitated-gone out Water.Its partial process flow is as shown in Figure 4.
B. what is shown from quiet side of having a rest (one side) is SBR process operation features:Water inlet-aeration (reaction)-precipitation-water outlet- It is idle.Its partial process flow is as shown in Figure 5.
3)A2O process operations pattern (C mode)
When actual inflow is in QIf≦QIt is real≦QIfCan be by setting PLC internal processes under (1+20%) scope, the pattern The waste water of iron-carbon micro-electrolysis tower is passed through while continuously entering anaerobic pond, the anoxic pond of A sides and B sides, and under the conditions of this The contact-oxidation pool of continuum micromeehanics enters Line Continuity aeration, by rationally setting PLC program the technique is integrally realized A2O is dirty The operation characteristic of water treatment technology, the waste water after contact-oxidation pool is handled flows through tube settler, after being handled in the pond Stain disease carry out effective mud-water separation under the booster action of the flocculants such as PAC and PAM, water outlet enters 2# intermediate pools (sterilization pool), quantitatively controls the dosage of the disinfectants such as (0-50L/h scopes) hypochlorous acid, it is ensured that waste water has for a long time in the pond The bactericidal effect of effect, and be delivered to the stain disease after handling well in more medium filter step by step by lifting device, its water outlet Flow through ultra violet sterilizer, further ensure that the steady in a long-term of its Disinfection Effect, the water outlet after final process through pipeline extremely In case production reuse in reuse pool.
Under the operational mode, from the point of view of whole sewage and wastewater treatment system, A, B both sides show as continuous running status simultaneously (i.e. A2O process characteristics), its technological process is as shown in Figure 6.
To sum up, the present invention can be according to the actual amount of water situation of waste water, by the program setting of PLC control system, according to reality The equipment of the stain disease water situation on border reasonably in start and stop sewage disposal system, it can be ensured that sewage and wastewater treatment system stably reaching standard The energy-saving run of stain disease processing procedure can be realized while discharge again.Change relatively large feelings especially for water quality and quantity Condition, by suitably optimizing PLC control program, just can realize stabilization, the energy-efficient treatment of stain disease, significantly reduce because at sewage The high cost that equipment redundancy runs and produced in reason system, means a great.
As shown in fig. 7, processing system provided in an embodiment of the present invention, including:Mechanical grille 1, scum silica frost pond 2, setting pot 3, Regulating reservoir 4, PAC, PAM chemicals dosing plant 5, air-dissolving air-float equipment 6, centre 1# ponds 7, iron-carbon micro-electrolysis tower 8, (A, B) anaerobic pond 9th, (A, B) anoxic pond 10, contact-oxidation pool 11, tube settler 12, intermediate pool 2# (sterilization pool) 13, more medium filter 14, Apparatus for ultraviolet disinfection 15, hypochlorous acid chlorination equipment 16, reuse pool 17, sludge-tank 18, the pre- place being arranged on above regulating reservoir Aeration fan 19 is managed, (A, B) anaerobic pond 9, the diving mixer 20 in (A, B) anoxic pond 10 is arranged on, is arranged on tube settling Sludge reflux self priming pump 21, the PLC control system 22 being arranged in equipment room, the contact-oxidation pool Aeration fan 23 of the top of pond 12 With constant pressure water supply unit 24, the backwash self priming pump 25 being arranged on above reuse pool 17;Also include passing through pipeline and sand setting The storage basin 18 that pond 3 is connected.Regulating reservoir elevator pump 26 is also plugged with regulating reservoir 4.
A anaerobic ponds, B anaerobic ponds are anaerobic pond 1#, anaerobic pond 2#;A anoxic ponds, B anoxic ponds are anoxic pond 1#, anoxic pond 2#。
Dissolved air flotation device is air floatation machine.Iron-carbon micro-electrolysis tower includes hydrolysis acidification tower 1# and hydrolysis acidification tower 2#.
The more medium filter includes 1#~4# filters.
The present invention can realize sewage disposal system in IDEA techniques, D-A according to project actual waste water amount situation2O techniques and A2Flexible switching under the plurality of operating modes such as O techniques, with floor space is small, utilization rate of equipment and installations is high, stain disease treatment effeciency The features such as high and operation maintenance management facilitates, and energy-saving run are with the obvious advantage, system overall merit steady in a long-term.
With reference to effect, the invention will be further described.
In Rubber Industrial Wastewater processing method provided in an embodiment of the present invention, integrated wastewater and discharge standard such as table 1.
Table 1《Integrated wastewater and discharge standard》(GB8978-1996)
(unit built before on December 31st, 1997) unit:1mg/L
Each organic pollutant removal effect list under the sewage and wastewater treatment system each unit of table 2 difference switching technique
Operation energy consumption analysis list under the sewage and wastewater treatment system of table 3 difference operational mode
Data of data comparison table 1 in analytical table 2 and table 3 understand, a kind of in this programme can flexibly switch the height of technique Low consumption Rubber Industrial Wastewater processing method is imitated, is shown really in terms of high concentration native rubber processing waste water is handled efficient, stably Removal effect.In addition, making the sewage and wastewater treatment system can be according to actual wastewater flow rate feelings by the setting to PLC control program Condition is reasonably controlled the operation of sewage and wastewater treatment system internal unit and resting, and makes whole system respectively in IDEA (Intermittent Decanted Extended Aeration) technique, D-A2O (A, B side alternate run) techniques and A2O(A、 Run simultaneously B sides) flexibly switch in technique.The function of this kind of operational mode realizes that its maximum advantage is, efficiently solves Sewage disposal device redundancy running and non-productive work cause utilization rate of equipment and installations under fixed mode in existing sewage and wastewater treatment system The a series of problem such as low, operating cost increase and operation maintenance complexity.Effluent quality will be effectively ensured in the appearance of the invention On the basis of effect, the operation energy consumption of sewage disposal system is effectively reduced, its operating cost is expected to be greatly reduced.
The foregoing is merely illustrative of the preferred embodiments of the present invention, is not intended to limit the invention, all essences in the present invention Any modifications, equivalent substitutions and improvements made within refreshing and principle etc., should be included in the scope of the protection.

Claims (6)

1. a kind of can flexibly switch the efficient low-consume Rubber Industrial Wastewater processing method of technique, it is characterised in that described flexibly to switch The efficient low-consume Rubber Industrial Wastewater processing method of technique includes:
After natural rubber production waste water removes oil removal, micelle debris through type mechanical grate foul remover, gravity flow enters setting pot, than Great most of silts and particulate matter will precipitate;Waste water flows through regulating reservoir successively, and passes through the fixation in regulating reservoir Pond is to effective regulation of water for entering the equilibrium of pollutant concentration in processing system;Waste water quality and water in regulating reservoir Amount by and, some organic pollutants in waste water again this simply hydrolyzed, make the biodegradability of comprehensive wastewater further Lifting;
Under the active state of regulating reservoir elevator pump, water outlet flows through dissolved air flotation device successively, is removed after coagulating of offeing medicine Partial suspension material, the suspension material of half dissolved state in waste water is removed, during which produced through air flotation effect Scum silica frost then swept by the machinery of Slag Scraping Device, be discharged into nearby in scum silica frost pond by scum silica frost pipeline;And then waste water solution enters 1# intermediate pools carry out further water quality and;And the waste water after homogeneous is continuously delivered to by iron carbon by lifting device In light electrolysis tower, with continuously entering for waste water, waste water medium starts to play the effect of its electrolyte, in waste water solution and iron carbon In the galvanic cell environment that the anodic-cathodic of micro-electrolysis stuffing is constituted, it is carried out continuously along with the reaction of countless miniature galvanic cells, Promote numerous persistent organic pollutants fully to degrade, with the increase of easily biodegradable organicses content, flow through iron-carbon micro-electrolysis tower The biodegradability of waste water greatly improve, effect of the scum silica frost that electrolytic process is produced then through its internal three phase separator set, Solid phase scum silica frost is then periodically emitted into scum silica frost pond by deslagging pipeline;Go out to flow waste water immediately and enter (A, B) anaerobic pond;
And then, according to actual stain disease water situation, under the control of PLC control system, the sewage disposal system is realized It is in IDEA techniques, D-A2O techniques and A2Flexible switching in O techniques;As inflow QIt is real< 1/2QIfWhen switch to IDEA techniques; As inflow 1/2QIf≦QIt is real< QIfWhen switch to D-A2O techniques;As inflow QIf≦QIt is real≦QIfA is switched to when (1+20%)2O works Skill;Wherein, A sides, the synchronous continuous operation in B sides, intermittence aeration when switching to IDEA techniques;Switch to D-A2A sides, B during O techniques Side alternate run;Switch to A2During O techniques, A sides, B sides are run simultaneously.
2. it can flexibly switch the efficient low-consume Rubber Industrial Wastewater processing method of technique as claimed in claim 1, it is characterised in that root Factually the stain disease water on border realizes that the method for IDEA process operations includes by PLC control system:
Inflow is in QIt is real< 1/2QIfWhen, made by PLC control system continuous successively by the production waste water of iron-carbon micro-electrolysis tower The anaerobic pond for entering A sides on ground, the anaerobic pond of anoxic pond and B sides, anoxic pond;And the contact-oxidation pool of continuum micromeehanics is carried out Intermittence aeration;And aeration time and the run time of regulating reservoir elevator pump by PLC control system control contact-oxidation pool, Realize that the intermittence of system strains water process, so that it is guaranteed that the high efficiency and stability of effluent quality;And using tube settler as Ceramic filter is used, and further the suspension molecule in water outlet is effectively settled, and final outflow water is through water in the middle of 2# After pond is sterilized, and the processing through more medium filter flows through UV-device sterilization, Treated sewage reusing pond is entered in case reuse.
3. it can flexibly switch the efficient low-consume Rubber Industrial Wastewater processing method of technique as claimed in claim 1, it is characterised in that root Factually the stain disease water on border realizes D-A by PLC control system2The method of O process operations includes:
Inflow is in 1/2QIf≦QIt is real< QIfWhen, make the waste water flowed out by iron-carbon micro-electrolysis tower continuous by PLC control system Alternately enter anaerobic pond, the anoxic pond of A sides and B sides;And continuity, which is aerated, to be realized to the contact-oxidation pool of continuum micromeehanics, pass through PLC control system makes the anaerobic pond of A sides and B sides, the anoxic pond continuous alternate run in the regular hour is interval;Go out water mixed liquid Tube settler is entered, and mud-water separation is realized in the presence of PAC, PAM flocculating agent feeding device, final outflow water is through in 2# Between pond (sterilization pool sterilize, and the processing through more medium filter flow through UV-device sterilization after, enter Treated sewage reusing water Pond is in case reuse.
4. it can flexibly switch the efficient low-consume Rubber Industrial Wastewater processing method of technique as claimed in claim 1, it is characterised in that root Factually the stain disease water on border realizes A by PLC control system2The method of O process operation formulas includes:
Inflow is in QIf≦QIt is real≦QIfWhen (1+20%), the waste water for flowing through iron-carbon micro-electrolysis tower by PLC control system is same When continuously enter anaerobic pond, the anoxic pond of A sides and B sides;And the contact-oxidation pool of continuum micromeehanics under the conditions of this is carried out continuously Property aeration;The waste water after contact-oxidation pool is handled is flowed through tube settler by PLC control system, handled in the pond Stain disease afterwards carries out mud-water separation under the booster action of PAC and PAM flocculants;Water outlet enters 2# intermediate pools, by right The setting of measuring pump parameter quantitatively controls the dosage of the disinfectants such as hypochlorous acid into the pond;And will be handled by lifting device Stain disease afterwards is delivered in more medium filter step by step;Filter water outlet flows through ultra violet sterilizer sterilization;After final process Water outlet through pipeline into reuse pool in case production reuse.
5. a kind of processing system for the efficient low-consume Rubber Industrial Wastewater processing method that can flexibly switch technique as claimed in claim 1, Characterized in that, the processing system includes:
Mechanical grille for removing suspension in processing waste water, micelle debris;
It is connected with mechanical grille by pipeline, for the setting pot that heavy silt and particulate matter precipitate;
It is connected with setting pot by pipeline, for by the regulating reservoir of waste water quality and water sum;
It is connected with the regulating reservoir elevator pump of regulating reservoir, the air-dissolving air-float that the waste water after coagulating of offeing medicine produces scum silica frost is filled Put;
It is connected with dissolved air flotation device by pipeline, for the 1# intermediate pools to the further water quality of waste water sum;
It is connected with 1# intermediate pools by pipeline, the iron-carbon micro-electrolysis tower for electrolysis wastewater;
It is connected with iron-carbon micro-electrolysis tower by pipeline, (A, B) anaerobic pond for carrying out anaerobic reaction to waste water;
It is connected with (A, B) anaerobic pond by pipeline, (A, B) anoxic pond for carrying out hypoxia response to waste water;
It is connected with (A, B) anoxic pond by pipeline, the contact-oxidation pool for entering Line Continuity aeration to waste water;
It is connected with contact-oxidation pool by pipeline, for the tube settler to waste water mud-water separation;
It is connected with tube settler by pipeline, for the 2# intermediate pools carried out disinfection to waste water;
It is connected with 2# intermediate pools by pipeline, for the more medium filter filtered to waste water;
It is connected with more medium filter by pipeline, the reuse pool for carrying out huge profit to the waste water after processing;
According to actual stain disease water situation, for carrying out IDEA techniques, D-A to waste water2O techniques and A2The switching of O techniques PLC control system.
6. processing system as claimed in claim 5, it is characterised in that the processing system also includes:It is plugged on regulating reservoir The pretreatment Aeration fan of side, the diving mixer being plugged in (A, B) anaerobic pond and (A, B) anoxic pond, it is plugged on inclined tube and sinks Sludge reflux self priming pump above the pond of shallow lake, the contact-oxidation pool Aeration fan being plugged in contact-oxidation pool, connected by pipeline The constant pressure water supply unit of reuse pool, the backwash self priming pump being plugged on above reuse pool and used wire connection PLC control system.
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CN111470722A (en) * 2020-04-16 2020-07-31 江苏南大华兴环保科技股份公司 Treatment method of rubber processing wastewater difficult to biodegrade
CN112897821A (en) * 2021-04-07 2021-06-04 天津市华宇膜技术有限公司 System and method suitable for distributed domestic sewage treatment

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CN104944701A (en) * 2015-06-17 2015-09-30 昆明滇池水务股份有限公司 Method for enhancing sewage nitrogen and phosphorus removal and saving energy and reducing consumption based on pulse aeration

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CN101130447A (en) * 2007-06-08 2008-02-27 北京工业大学 Method for optimizing controlling denitrification and phosphorus release in double precipitation pool by A*/O technique
CN103979682A (en) * 2013-11-25 2014-08-13 玉溪师范学院 Divisional water feed type D-A2O sewage treatment device
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CN111470722A (en) * 2020-04-16 2020-07-31 江苏南大华兴环保科技股份公司 Treatment method of rubber processing wastewater difficult to biodegrade
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