CN107055758A - A kind of tower biological filter 3 D elastic filler processing modified plastic particles - Google Patents

A kind of tower biological filter 3 D elastic filler processing modified plastic particles Download PDF

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Publication number
CN107055758A
CN107055758A CN201710058495.7A CN201710058495A CN107055758A CN 107055758 A CN107055758 A CN 107055758A CN 201710058495 A CN201710058495 A CN 201710058495A CN 107055758 A CN107055758 A CN 107055758A
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parts
powder
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plastic particles
biological filter
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王林
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HE COUNTY YIMAI COAL INDUSTRY Co Ltd
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HE COUNTY YIMAI COAL INDUSTRY Co Ltd
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    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F3/00Biological treatment of water, waste water, or sewage
    • C02F3/02Aerobic processes
    • C02F3/10Packings; Fillings; Grids
    • C02F3/104Granular carriers
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F3/00Biological treatment of water, waste water, or sewage
    • C02F3/02Aerobic processes
    • C02F3/10Packings; Fillings; Grids
    • C02F3/105Characterized by the chemical composition
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02WCLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
    • Y02W10/00Technologies for wastewater treatment
    • Y02W10/10Biological treatment of water, waste water, or sewage

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  • Life Sciences & Earth Sciences (AREA)
  • Chemical & Material Sciences (AREA)
  • Water Supply & Treatment (AREA)
  • Hydrology & Water Resources (AREA)
  • Engineering & Computer Science (AREA)
  • Environmental & Geological Engineering (AREA)
  • Microbiology (AREA)
  • Biodiversity & Conservation Biology (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Separation, Recovery Or Treatment Of Waste Materials Containing Plastics (AREA)

Abstract

The invention discloses a kind of tower biological filter 3 D elastic filler processing modified plastic particles, it is related to bio-filter stuffing technical field, is made up of the raw material of following parts by weight:15 20 parts of bimaleimide resin, 10 15 parts of styrene acrylonitrile copolymer, 5 10 parts of modified waste tire rubber powder, 5 10 parts of dicyclopentadiene phenol epoxy resin, 36 parts of C5 hydrogenated petroleum resins, 24 parts of part, nanometer the sepiolite composite powder of polyvinyl butyral resin 24,12 parts of superfine powder of polytetrafluoroethylene, 12 parts of molecular screen primary powder, 0.5 1 parts of petroleum coke micro mist, 0.5 1 parts of vinyl silicone oil, 0.3 0.5 parts of glass powder, 0.05 0.1 parts of yittrium oxide.The processing forming of modified plastic particles of the present invention is good, it is adaptable to be processed into tower biological filter 3 D elastic filler, and made packing specific area is big, and hole changeability is big, does not block, material long lifespan, and adhesion meets group and biofilm is rapid, to good sewage processing effect.

Description

A kind of tower biological filter 3 D elastic filler processing modified plastic particles
Technical field:
The present invention relates to bio-filter stuffing technical field, and in particular to a kind of tower biological filter 3 D elastic filler adds Work modified plastic particles.
Background technology:
Tower biological filter is on the basis of biofilter, with reference to the packed tower mode in chemical industry, to have built straight Footpath is with height than being 1:6-1:8, up to 8-24 meters of filter tank.Tower biological filter handles sewage also with aerobic microbiological A kind of structures, are a kind of basic skills of biomembrance process processing sanitary sewage and organic industry sewage, at present in oil Applied in terms of the sewage disposal of the industries such as work, coking, chemical fibre, papermaking, metallurgy.By in recent years practice have shown that, tower Formula filter tank is preferable containing poison sewage effects such as cyanogen, phenol, nitrile, aldehyde to processing, and processing water outlet can meet the requirements.One it is because it has Row advantage, is widely applied so having obtained comparing.
Filler is the important composition part of tower biological filter, and because tower body is high, if filtrate is very heavy, tower body must increase Load-carrying members are reinforced, cost is not only added, and construction and installation are more complicated.For this problem, plastics are used at present Type filler substitutes traditional coke, clinker, ceramics filling.
3 D elastic filler uses special wire drawing, strand system hair technique, anchors at corrosion resistant, high intensity by strand is interspersed On axial cord, hard and soft appropriateness makes strand spatially evenly distributed radiation regimes.3 D elastic filler can be three-dimensional in effective coverage Omnibearing even is unfolded, make gas and water, biomembrane obtain it is fully mixed ooze contact and exchange, biomembrane can not only equably implantation every On a piece strand, good activity and space changeability are kept, and more and more big ratio surface can be obtained in the process of running Product, and good metabolism can be carried out, it is that domestic other fillers at present are incomparable.Usually used 3 D elastic filler Substantially all there is certain corrosion resistance, and specific surface area is big, but it is tight for wastewater treatment strand easily occur after for a period of time The phenomenon deformed again, reduces its space changeability, so as to influence the treatment effect to waste water.
The content of the invention:
The technical problems to be solved by the invention are to provide the tower life that a kind of processing forming is good, performance is excellent Thing filter tank 3 D elastic filler processing modified plastic particles.
The technical problems to be solved by the invention are realized using following technical scheme:
A kind of tower biological filter 3 D elastic filler processing modified plastic particles, by the raw material system of following parts by weight Into:
15-20 parts of bimaleimide resin, 10-15 parts of SAN, modified waste tire rubber powder 5-10 parts, 5-10 parts of dicyclopentadiene phenol epoxy resin, 3-6 parts of C5 hydrogenated petroleum resins, 2-4 parts of polyvinyl butyral resin, 2-4 parts of sepiolite composite powder of nanometer, 1-2 parts of superfine powder of polytetrafluoroethylene, 1-2 parts of molecular screen primary powder, petroleum coke micro mist 0.5-1 Part, 0.5-1 parts of vinyl silicone oil, 0.3-0.5 parts of glass powder, 0.05-0.1 parts of yittrium oxide.
Its preparation method comprises the following steps:
(1) modified waste tire rubber powder and C5 hydrogenated petroleum resins are added into bimaleimide resin, with 5 DEG C/ Min programming rate is warming up to 130-135 DEG C of insulation mixing 25min, adds nanometer sepiolite composite powder and a polytetrafluoroethylene (PTFE) Superfine powder, is continuously maintained at 130-135 DEG C of insulation mixing 15min, then naturally cools to room temperature, produce material I;
(2) dicyclopentadiene phenol epoxy resin and polyvinyl butyral resin are added into SAN, 125-130 DEG C of insulation mixing 20min is warming up to 5 DEG C/min programming rate, petroleum coke micro mist and vinyl silicone oil is added, 125-130 DEG C of insulation mixing 15min is continuously maintained at, room temperature is then cooled to 10 DEG C/min cooling rate, material is produced II;
(3) material II, molecular screen primary powder, glass powder and yittrium oxide are added into material I, extruder is sent into after being sufficiently mixed In, 120-125 DEG C of head temperature, one section 90-95 DEG C of barrel zone temperature, two sections 105-110 DEG C, three sections 120-125 DEG C, extrusion are set Bar sent into after cooling and shaping in pulverizer, particle diameter 2-3mm particle is made.
The modified waste tire rubber powder is formed by the modified processing of rubber powder of waste tire, and specific preparation method is: Turpentine oil and hydrogenated rosin pentaerythritol ester are added into rubber powder of waste tire, be sufficiently mixed after microwave frequency 2450MHz, Microwave treatment 10min under power output 700W, and be transferred in 0-5 DEG C of environment and stand 30min, add allyl glycidol Ether, HPMA and sulfurized lard, microwave treatment 10min is continued after being well mixed, then with 5 DEG C/min cooling speed Degree is cooled to 50-55 DEG C of sealing thermal insulation and stood in 30min, gained mixture feeding ball mill, and the ground fineness that is made is less than 20 μ M micro mist.
The rubber powder of waste tire, turpentine oil, hydrogenated rosin pentaerythritol ester, allyl glycidyl ether, hydrolysis are poly- The amount ratio of maleic anhydride and sulfurized lard is 45-50:1-2:0.5-1:0.5-1:0.3-0.5:0.1-0.2.
Rubber powder of waste tire improves its blending phase with plastics high molecular polymer after above-mentioned modification, not only Capacitive, it is to avoid agglomeration occur, to make full use of the filling capacity that its is excellent;Its elasticity can also be significantly increased, to assign The appropriate elastic deformability of made filler.
The nanometer sepiolite composite powder is made up of the raw material of following parts by weight:5-10 parts of sepiolite fibre, flake asbestos 2-3 parts, 2-3 parts of ceramic, 1-2 parts of poly alpha methylstyrene resin, 0.5-1 parts of chliorinated polyvinyl chloride, hexamethylol trimerization 0.5-1 parts of cyanamide pregnancy ether, 0.3-0.5 parts of portland cement, 0.1-0.3 parts of nano zine oxide, its preparation method is:To Hai Pao Ceramic, poly alpha methylstyrene resin and chliorinated polyvinyl chloride are added in mineral wool, is sufficiently mixed after microwave frequency Microwave treatment 10min under 2450MHz, power output 700W, adds hexamethylolmelamine pregnancy ether and nano zine oxide, Continue microwave treatment 5min after well mixed, flake asbestos and portland cement, gained mixture feeding nanometer are then added while hot In grinder, ground obtained nanometer sepiolite composite powder.
The addition of above-mentioned nanometer sepiolite composite powder, can effectively strengthen the stereo-elastic being made through made modified plastic particles The mechanical property of filler, prevents it to be permanently deformed.
The beneficial effects of the invention are as follows:The processing forming of modified plastic particles of the present invention is good, it is adaptable to be processed into tower Formula biofilter 3 D elastic filler, made filler is compared with rigid class honeycomb filler, and specific surface area is big, and hole changeability is big, Do not block;Compared with soft class filler, material long lifespan, adhesion meets group and biofilm is rapid, to good sewage processing effect;Can have Effect removes the pollutant in sewage, including COD, BOD, ammonia nitrogen and organophosphor, moreover it is possible to mitigate the colourity and peculiar smell of sewage.
Embodiment:
In order that the technical means, the inventive features, the objects and the advantages of the present invention are easy to understand, tie below Specific embodiment is closed, the present invention is expanded on further.
Embodiment 1
(1) 5 parts of modified waste tire rubber powders and 3 parts of C5 hydrotreated petroleum trees are added into 20 parts of bimaleimide resins Fat, is warming up to 130-135 DEG C of insulation mixing 25min with 5 DEG C/min programming rate, adds 2 parts of nanometer sepiolite composite powders With 2 parts of superfine powder of polytetrafluoroethylene, 130-135 DEG C of insulation mixing 15min is continuously maintained at, room temperature is then naturally cooled to, i.e., Obtain material I;
(2) 5 parts of dicyclopentadiene phenol epoxy resins and 2 parts of poly- second are added into 10 parts of SANs Enol butyral, is warming up to 125-130 DEG C of insulation mixing 20min with 5 DEG C/min programming rate, adds 0.5 part of petroleum coke Micro mist and 0.5 part of vinyl silicone oil, are continuously maintained at 125-130 DEG C of insulation mixing 15min, then with 10 DEG C/min cooling speed Degree is cooled to room temperature, produces material II;
(3) material II, 2 parts of molecular screen primary powders, 0.5 part of glass powder and 0.05 part of yittrium oxide are added into material I, it is fully mixed Sent into after conjunction in extruder, 120-125 DEG C of head temperature, one section 90-95 DEG C, two sections 105-110 DEG C, three sections of barrel zone temperature are set 120-125 DEG C, the bar of extrusion is sent into pulverizer after cooling and shaping, and particle diameter 2-3mm particle is made.
The preparation of modified waste tire rubber powder:1 part of turpentine oil and 0.5 part of hydrogen are added into 45 parts of rubber powder of waste tire Change pentalyn, be sufficiently mixed after microwave treatment 10min under microwave frequency 2450MHz, power output 700W, and turn Enter in 0-5 DEG C of environment and stand 30min, add 0.5 part of allyl glycidyl ether, 0.3 part of HPMA and 0.2 part Sulfurized lard, continues microwave treatment 10min after being well mixed, is then cooled to 50-55 DEG C of sealing with 5 DEG C/min cooling rate Insulation is stood in 30min, gained mixture feeding ball mill, ground that the micro mist that fineness is less than 20 μm is made.
The preparation of nanometer sepiolite composite powder:2 parts of ceramics, 1 part of poly- Alpha-Methyl are added into 10 parts of sepiolite fibres Styrene resin and 0.5 part of chliorinated polyvinyl chloride, are sufficiently mixed after microwave under microwave frequency 2450MHz, power output 700W 10min is handled, 0.5 part of hexamethylolmelamine pregnancy ether and 0.2 part of nano zine oxide is added, continues micro- after being well mixed Ripple handles 5min, then adds while hot in 2 parts of flake asbestos and 0.5 part of portland cement, gained mixture feeding nano-level grinder, Ground obtained nanometer sepiolite composite powder.
Embodiment 2
(1) 8 parts of modified waste tire rubber powders and 3 parts of C5 hydrotreated petroleum trees are added into 15 parts of bimaleimide resins Fat, is warming up to 130-135 DEG C of insulation mixing 25min with 5 DEG C/min programming rate, adds 3 parts of nanometer sepiolite composite powders With 1 part of superfine powder of polytetrafluoroethylene, 130-135 DEG C of insulation mixing 15min is continuously maintained at, room temperature is then naturally cooled to, i.e., Obtain material I;
(2) 5 parts of dicyclopentadiene phenol epoxy resins and 3 parts of poly- second are added into 15 parts of SANs Enol butyral, is warming up to 125-130 DEG C of insulation mixing 20min with 5 DEG C/min programming rate, adds 0.5 part of petroleum coke Micro mist and 0.5 part of vinyl silicone oil, are continuously maintained at 125-130 DEG C of insulation mixing 15min, then with 10 DEG C/min cooling speed Degree is cooled to room temperature, produces material II;
(3) material II, 1 part of molecular screen primary powder, 0.5 part of glass powder and 0.05 part of yittrium oxide are added into material I, it is fully mixed Sent into after conjunction in extruder, 120-125 DEG C of head temperature, one section 90-95 DEG C, two sections 105-110 DEG C, three sections of barrel zone temperature are set 120-125 DEG C, the bar of extrusion is sent into pulverizer after cooling and shaping, and particle diameter 2-3mm particle is made.
The preparation of modified waste tire rubber powder:2 parts of turpentine oil and 1 part of hydrogenation are added into 50 parts of rubber powder of waste tire Pentalyn, is sufficiently mixed after microwave treatment 10min under microwave frequency 2450MHz, power output 700W, and be transferred to 30min is stood in 0-5 DEG C of environment, 0.5 part of allyl glycidyl ether, 0.5 part of HPMA and 0.2 part of sulphur is added Change lard, microwave treatment 10min is continued after being well mixed, 50-55 DEG C of sealing guarantor is then cooled to 5 DEG C/min cooling rate Temperature is stood in 30min, gained mixture feeding ball mill, ground that the micro mist that fineness is less than 20 μm is made.
The preparation of nanometer sepiolite composite powder:3 parts of ceramics, 1 part of poly- Alpha-Methyl are added into 10 parts of sepiolite fibres Styrene resin and 1 part of chliorinated polyvinyl chloride, are sufficiently mixed after under microwave frequency 2450MHz, power output 700W at microwave 10min is managed, 0.5 part of hexamethylolmelamine pregnancy ether and 0.1 part of nano zine oxide is added, microwave is continued after being well mixed 5min is handled, is then added while hot in 3 parts of flake asbestos and 0.3 part of portland cement, gained mixture feeding nano-level grinder, warp Nanometer sepiolite composite powder is made in grinding.
Reference examples 1
(1) 5 parts of rubber powder of waste tire and 3 parts of C5 hydrogenated petroleum resins are added into 20 parts of bimaleimide resins, 130-135 DEG C of insulation mixing 25min is warming up to 5 DEG C/min programming rate, 2 parts of nanometer sepiolite composite powders and 2 are added Part superfine powder of polytetrafluoroethylene, is continuously maintained at 130-135 DEG C of insulation mixing 15min, then naturally cools to room temperature, produce thing Expect I;
(2) 5 parts of dicyclopentadiene phenol epoxy resins and 2 parts of poly- second are added into 10 parts of SANs Enol butyral, is warming up to 125-130 DEG C of insulation mixing 20min with 5 DEG C/min programming rate, adds 0.5 part of petroleum coke Micro mist and 0.5 part of vinyl silicone oil, are continuously maintained at 125-130 DEG C of insulation mixing 15min, then with 10 DEG C/min cooling speed Degree is cooled to room temperature, produces material II;
(3) material II, 2 parts of molecular screen primary powders, 0.5 part of glass powder and 0.05 part of yittrium oxide are added into material I, it is fully mixed Sent into after conjunction in extruder, 120-125 DEG C of head temperature, one section 90-95 DEG C, two sections 105-110 DEG C, three sections of barrel zone temperature are set 120-125 DEG C, the bar of extrusion is sent into pulverizer after cooling and shaping, and particle diameter 2-3mm particle is made.
The preparation of nanometer sepiolite composite powder:3 parts of ceramics, 1 part of poly- Alpha-Methyl are added into 10 parts of sepiolite fibres Styrene resin and 1 part of chliorinated polyvinyl chloride, are sufficiently mixed after under microwave frequency 2450MHz, power output 700W at microwave 10min is managed, 0.5 part of hexamethylolmelamine pregnancy ether and 0.1 part of nano zine oxide is added, microwave is continued after being well mixed 5min is handled, is then added while hot in 3 parts of flake asbestos and 0.3 part of portland cement, gained mixture feeding nano-level grinder, warp Nanometer sepiolite composite powder is made in grinding.
Reference examples 2
(1) 8 parts of modified waste tire rubber powders and 3 parts of C5 hydrotreated petroleum trees are added into 15 parts of bimaleimide resins Fat, is warming up to 130-135 DEG C of insulation mixing 25min with 5 DEG C/min programming rate, adds 3 parts of nanometer sepiolite fibre powder With 1 part of superfine powder of polytetrafluoroethylene, 130-135 DEG C of insulation mixing 15min is continuously maintained at, room temperature is then naturally cooled to, i.e., Obtain material I;
(2) 5 parts of dicyclopentadiene phenol epoxy resins and 3 parts of poly- second are added into 15 parts of SANs Enol butyral, is warming up to 125-130 DEG C of insulation mixing 20min with 5 DEG C/min programming rate, adds 0.5 part of petroleum coke Micro mist and 0.5 part of vinyl silicone oil, are continuously maintained at 125-130 DEG C of insulation mixing 15min, then with 10 DEG C/min cooling speed Degree is cooled to room temperature, produces material II;
(3) material II, 1 part of molecular screen primary powder, 0.5 part of glass powder and 0.05 part of yittrium oxide are added into material I, it is fully mixed Sent into after conjunction in extruder, 120-125 DEG C of head temperature, one section 90-95 DEG C, two sections 105-110 DEG C, three sections of barrel zone temperature are set 120-125 DEG C, the bar of extrusion is sent into pulverizer after cooling and shaping, and particle diameter 2-3mm particle is made.
The preparation of modified waste tire rubber powder:2 parts of turpentine oil and 1 part of hydrogenation are added into 50 parts of rubber powder of waste tire Pentalyn, is sufficiently mixed after microwave treatment 10min under microwave frequency 2450MHz, power output 700W, and be transferred to 30min is stood in 0-5 DEG C of environment, 0.5 part of allyl glycidyl ether, 0.5 part of HPMA and 0.2 part of sulphur is added Change lard, microwave treatment 10min is continued after being well mixed, 50-55 DEG C of sealing guarantor is then cooled to 5 DEG C/min cooling rate Temperature is stood in 30min, gained mixture feeding ball mill, ground that the micro mist that fineness is less than 20 μm is made.
Embodiment 3
Physical dimension is made using embodiment 1, embodiment 2, reference examples 1 and the made modified plastic particles of reference examples 2 complete Identical 3 D elastic filler, and tower biological filter is built, to being handled with batch sanitary sewage, the treatment effect such as institute of table 1 Show.
The present invention of table 1 builds the wastewater treatment efficiency of tower biological filter
Project Embodiment 1 Embodiment 2 Reference examples 1 Reference examples 2
COD reduced rates/% 94.8 95.3 89.6 87.2
BOD reduced rates/% 95.7 94.9 86.8 83.5
Ammonia nitrogen reduced rate/% 96.3 96.8 90.2 88.6
Organophosphor reduced rate/% 97.7 96.9 85.8 82.4
Colourity Basic clarification Basic clarification Still show muddiness Still show muddiness
Peculiar smell Substantially tasteless Substantially tasteless Slight peculiar smell Slight peculiar smell
The general principle and principal character and advantages of the present invention of the present invention has been shown and described above.The technology of the industry Personnel are it should be appreciated that the present invention is not limited to the above embodiments, and the simply explanation described in above-described embodiment and specification is originally The principle of invention, without departing from the spirit and scope of the present invention, various changes and modifications of the present invention are possible, these changes Change and improvement all fall within the protetion scope of the claimed invention.The claimed scope of the invention by appended claims and its Equivalent thereof.

Claims (5)

1. a kind of tower biological filter 3 D elastic filler processing modified plastic particles, it is characterised in that by following parts by weight Several raw materials are made:
15-20 parts of bimaleimide resin, 10-15 parts of SAN, modified waste tire rubber powder 5-10 Part, 5-10 parts of dicyclopentadiene phenol epoxy resin, 3-6 parts of C5 hydrogenated petroleum resins, 2-4 parts of polyvinyl butyral resin, nanometer 2-4 parts of sepiolite composite powder, 1-2 parts of superfine powder of polytetrafluoroethylene, 1-2 parts of molecular screen primary powder, 0.5-1 parts of petroleum coke micro mist, second 0.5-1 parts of alkenyl silicone oil, 0.3-0.5 parts of glass powder, 0.05-0.1 parts of yittrium oxide.
2. 3 D elastic filler processing modified plastic particles in tower biological filter according to claim 1, its feature exists In its preparation method comprises the following steps:
(1) modified waste tire rubber powder and C5 hydrogenated petroleum resins are added into bimaleimide resin, with 5 DEG C/min's Programming rate is warming up to 130-135 DEG C of insulation mixing 25min, adds nanometer sepiolite composite powder and polytetrafluoroethylene (PTFE) is ultra-fine Powder, is continuously maintained at 130-135 DEG C of insulation mixing 15min, then naturally cools to room temperature, produce material I;
(2) dicyclopentadiene phenol epoxy resin and polyvinyl butyral resin are added into SAN, with 5 DEG C/min programming rate is warming up to 125-130 DEG C of insulation mixing 20min, adds petroleum coke micro mist and vinyl silicone oil, after It is continuous to maintain 125-130 DEG C of insulation mixing 15min, room temperature is then cooled to 10 DEG C/min cooling rate, material II is produced;
(3) material II, molecular screen primary powder, glass powder and yittrium oxide are added into material I, is sent into after being sufficiently mixed in extruder, Set 120-125 DEG C of head temperature, one section 90-95 DEG C of barrel zone temperature, two sections 105-110 DEG C, three sections 120-125 DEG C, extrusion Bar is sent into pulverizer after cooling and shaping, and particle diameter 2-3mm particle is made.
3. 3 D elastic filler processing modified plastic particles in tower biological filter according to claim 1 or 2, its feature It is:The modified waste tire rubber powder is formed by the modified processing of rubber powder of waste tire, and specific preparation method is:To useless Turpentine oil and hydrogenated rosin pentaerythritol ester are added in old tire rubber powder, is sufficiently mixed after microwave frequency 2450MHz, output Microwave treatment 10min under power 700W, and be transferred in 0-5 DEG C of environment and stand 30min, add allyl glycidyl ether, water HPMA and sulfurized lard are solved, continues microwave treatment 10min after being well mixed, is then dropped with 5 DEG C/min cooling rate Temperature to 50-55 DEG C of sealing thermal insulation is stood in 30min, gained mixture feeding ball mill, and the ground fineness that is made is less than 20 μm Micro mist.
4. 3 D elastic filler processing modified plastic particles in tower biological filter according to claim 3, its feature exists In:The rubber powder of waste tire, turpentine oil, hydrogenated rosin pentaerythritol ester, allyl glycidyl ether, hydrolyzed polymaleic anhydride The amount ratio of acid anhydride and sulfurized lard is 45-50:1-2:0.5-1:0.5-1:0.3-0.5:0.1-0.2.
5. 3 D elastic filler processing modified plastic particles in tower biological filter according to claim 1 or 2, its feature It is, the nanometer sepiolite composite powder is made up of the raw material of following parts by weight:5-10 parts of sepiolite fibre, flake asbestos 2-3 Part, 2-3 parts of ceramic, 1-2 parts of poly alpha methylstyrene resin, 0.5-1 parts of chliorinated polyvinyl chloride, hexamethylolmelamine 0.5-1 parts of pregnancy ether, 0.3-0.5 parts of portland cement, 0.1-0.3 parts of nano zine oxide, its preparation method is:It is fine to sepiolite Ceramic, poly alpha methylstyrene resin and chliorinated polyvinyl chloride are added in dimension, is sufficiently mixed after microwave frequency Microwave treatment 10min under 2450MHz, power output 700W, adds hexamethylolmelamine pregnancy ether and nano zine oxide, Continue microwave treatment 5min after well mixed, flake asbestos and portland cement, gained mixture feeding nanometer are then added while hot In grinder, ground obtained nanometer sepiolite composite powder.
CN201710058495.7A 2017-01-23 2017-01-23 A kind of tower biological filter 3 D elastic filler processing modified plastic particles Withdrawn CN107055758A (en)

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Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107541042A (en) * 2017-08-26 2018-01-05 安徽胜利精密制造科技有限公司 A kind of notebook computer casing injection molding flame-retardant additive
CN108212070A (en) * 2018-02-02 2018-06-29 和县伊迈炭业有限责任公司 A kind of organic-biological filter tank filler
CN109926015A (en) * 2017-12-19 2019-06-25 宜兴市江华环保科技有限公司 A kind of water process inclined tube filler
CN114085657A (en) * 2021-12-06 2022-02-25 中石化石油工程技术服务有限公司 Temporary plugging material for shale gas well and preparation method thereof

Citations (1)

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Publication number Priority date Publication date Assignee Title
CN106243588A (en) * 2016-08-23 2016-12-21 安徽海德石油化工有限公司 A kind of alkylation acid hydrocarbon separation coalescent pack

Patent Citations (1)

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Publication number Priority date Publication date Assignee Title
CN106243588A (en) * 2016-08-23 2016-12-21 安徽海德石油化工有限公司 A kind of alkylation acid hydrocarbon separation coalescent pack

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107541042A (en) * 2017-08-26 2018-01-05 安徽胜利精密制造科技有限公司 A kind of notebook computer casing injection molding flame-retardant additive
CN109926015A (en) * 2017-12-19 2019-06-25 宜兴市江华环保科技有限公司 A kind of water process inclined tube filler
CN108212070A (en) * 2018-02-02 2018-06-29 和县伊迈炭业有限责任公司 A kind of organic-biological filter tank filler
CN114085657A (en) * 2021-12-06 2022-02-25 中石化石油工程技术服务有限公司 Temporary plugging material for shale gas well and preparation method thereof

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