CN107055699A - A kind of strong basicity electrolytic water generating device of control electrolyte temperature - Google Patents

A kind of strong basicity electrolytic water generating device of control electrolyte temperature Download PDF

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Publication number
CN107055699A
CN107055699A CN201710246629.8A CN201710246629A CN107055699A CN 107055699 A CN107055699 A CN 107055699A CN 201710246629 A CN201710246629 A CN 201710246629A CN 107055699 A CN107055699 A CN 107055699A
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China
Prior art keywords
electrolyte solution
holding tank
cryogenic fluid
electrolyte
refrigeration heat
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Pending
Application number
CN201710246629.8A
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Chinese (zh)
Inventor
舒芹
李长春
颜兰
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Chongqing Seven Kouquan Environmental Technology Co Ltd
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Chongqing Seven Kouquan Environmental Technology Co Ltd
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Priority to CN201710246629.8A priority Critical patent/CN107055699A/en
Publication of CN107055699A publication Critical patent/CN107055699A/en
Pending legal-status Critical Current

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    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/46Treatment of water, waste water, or sewage by electrochemical methods
    • C02F1/461Treatment of water, waste water, or sewage by electrochemical methods by electrolysis
    • C02F1/46104Devices therefor; Their operating or servicing
    • C02F1/4618Devices therefor; Their operating or servicing for producing "ionised" acidic or basic water
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/46Treatment of water, waste water, or sewage by electrochemical methods
    • C02F1/461Treatment of water, waste water, or sewage by electrochemical methods by electrolysis
    • C02F1/46104Devices therefor; Their operating or servicing
    • C02F1/4618Devices therefor; Their operating or servicing for producing "ionised" acidic or basic water
    • C02F2001/4619Devices therefor; Their operating or servicing for producing "ionised" acidic or basic water only cathodic or alkaline water, e.g. for reducing
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2201/00Apparatus for treatment of water, waste water or sewage
    • C02F2201/46Apparatus for electrochemical processes
    • C02F2201/461Electrolysis apparatus
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2201/00Apparatus for treatment of water, waste water or sewage
    • C02F2201/46Apparatus for electrochemical processes
    • C02F2201/461Electrolysis apparatus
    • C02F2201/46105Details relating to the electrolytic devices
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2201/00Apparatus for treatment of water, waste water or sewage
    • C02F2201/46Apparatus for electrochemical processes
    • C02F2201/461Electrolysis apparatus
    • C02F2201/46105Details relating to the electrolytic devices
    • C02F2201/46155Heating or cooling
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2209/00Controlling or monitoring parameters in water treatment
    • C02F2209/02Temperature
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2209/00Controlling or monitoring parameters in water treatment
    • C02F2209/06Controlling or monitoring parameters in water treatment pH

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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Electrochemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Hydrology & Water Resources (AREA)
  • Engineering & Computer Science (AREA)
  • Environmental & Geological Engineering (AREA)
  • Water Supply & Treatment (AREA)
  • Organic Chemistry (AREA)
  • Electrolytic Production Of Non-Metals, Compounds, Apparatuses Therefor (AREA)
  • Water Treatment By Electricity Or Magnetism (AREA)

Abstract

A kind of strong basicity electrolytic water generating device of control electrolyte temperature, belongs to electrolysis water production technical field, it is characterised in that electrolyte solution cooling device is additionally provided with electrolyte solution holding tank;Wherein described refrigeration heat-exchanger coil is arranged on inside refrigerating plant, pyrosol efferent duct connects electrolyte solution holding tank and refrigeration heat-exchanger coil, cryogenic fluid input pipe connection refrigeration heat-exchanger coil and electrolyte solution holding tank by hydrothermal solution rear pump;I.e. electrolyte solution holding tank, pyrosol efferent duct, hydrothermal solution rear pump, refrigeration heat-exchanger coil and cryogenic fluid input pipe collectively form electrolyte solution cooling circuit, wherein refrigeration heat-exchanger coil is arranged in refrigerating plant;Its advantage is the temperature that can effectively control electrolyte solution in electrolytic process, it is ensured that the pH value of electrolysis water meets desired value, improves the quality of production;Damage is reduced simultaneously, and the stability of increase equipment operation extends the service life of electrolytic film.

Description

A kind of strong basicity electrolytic water generating device of control electrolyte temperature
Technical field
The present invention relates to electrolysis water production technical field, particularly a kind of strong basicity electrolysis for controlling electrolyte temperature is aquatic Into device.
Background technology
Electrolysis water is also known as electrolytic ionic water or electrolyzed oxidizing water, is in electricity by certain density NaCl or KaCO3 solution Under solution effect, micro energy is consumed, the acidic electrolytic water or the general name of electrolyzed alkaline water for being separated and being generated with barrier film.Electrolysis water one As be divided into strong acidic electrolyzed water, strong basicity electrolysis water, subacidity electrolysis water and alkalescent electrolysis water.The electrolysis water of different pH values There are different applications in daily life.The main function of strong basicity electrolysis water be oil removing grease removal, degerming, deodorization, go agriculture it is residual, Formaldehyde is removed, to eating vegetables raw can sterilize during sterilizing and Edible Fungi;Strong acidic electrolyzed water is main It act as killing bacterium, can prevent and treat powdery mildew of strawberry can substantially reduce chemical pesticide while preferable prevention effect is obtained Consumption;Acidic electrolytic water is also applied to the sterilization of hemodialysis apparatus, and achieves preferable effect.Alkaline ionized water can be with Reduce acidic materials to produce, eliminate acidifying constitution, active cell function improves a variety of chronic diseases;Weakly alkaline electrolysis water conduct Drinking water can also obtain the effect different from light water.
Electrolytic water generating device include electrolytic cell, by ionic membrane by electrolyte bath progress isolation divide into cathode chamber and Anode chamber, carries out electrolysis to obtain alkaline electrolysis reductive water from cathode chamber, or obtain acid from anode chamber by being powered to water Property electrolytic oxidation water.
So-called electrolysis is exactly effect by direct current, by the electrochemical dissolution in solution into novel substance process;In life It is that direct current is passed through in water when producing electrolysis water, neutral water is generated into alkali ion water or acid electrolyzed functional water;But due to pure water Degree of ionization very little, conductive capability is low, it is necessary to add electrolyte, as electrolyte aqueous solution, to increase the conductive capability of water, improves Electrolytic efficiency.
Because potassium ion is that activity in aqueous is stronger, relatively current method is in life in electrolysis water at present Solution of potassium carbonate is added during production and is used as electrolyte aqueous solution.
That electrolyte no matter is added, amount of heat can be produced in electrolytic process, makes the temperature liter of electrolyte solution It is high.When using solution of potassium carbonate, such as take no action to, its temperature can reach 50 DEG C or so.
And in the production of electrolysis water, solution of potassium carbonate is when within 25 DEG C, the stability and efficiency of electrolysis installation are most It is good;When electrolyte solution temperature is more than 25 DEG C, the pH value for the product being electrolysed out and the error of desired value are larger;More than 40 DEG C When, production must be stopped.
It is that power-up fan blowing cooling, lasting blowing allows the temperature of electrolyte to raise slowly by the way of at present; When the temperature of solution of potassium carbonate reaches 35 DEG C, with regard to the operation of arrestment, stop production, carry out Temperature fall.But That ineffective mode, the temperature of electrolyte solution can not all keep constant, the result is that it is very big to equipment damage, to product Quality influence is also very big, and stopping production can also reduce production efficiency.
The content of the invention
The technical problems to be solved by the invention are to be directed to above-mentioned technical problem, on existing electrolytic water generating device basis On add electrolyte solution cooling device, so that the temperature of electrolyte meets required optimal electrolysis temperature at any time, carry High electrolysis effectiveness.
In order to solve the above technical problems, the technical solution adopted in the present invention is a kind of strong basicity of control electrolyte temperature Electrolytic water generating device, including pure water water inlet pipe, electrolytic cell, electrolyte solution holding tank, woven hose, infusion pump, alkali ion Water outlet pipe, wherein pure water water inlet pipe and alkali ion water outlet pipe are connected with electrolytic cell respectively, electrolyte solution holding tank, Woven hose, infusion pump, electrolytic cell are sequentially connected the logical electrolyte solution that constitutes and circulate loop, it is characterised in that electrolyte solution Electrolyte solution cooling device is additionally provided with holding tank.
The electrolyte solution cooling device includes pyrosol efferent duct, hydrothermal solution rear pump, refrigerating plant, refrigeration heat and handed over Helix tube and cryogenic fluid input pipe are changed, the refrigeration heat-exchanger coil is arranged on inside refrigerating plant, pyrosol output Pipe connects electrolyte solution holding tank and refrigeration heat-exchanger coil, cryogenic fluid input pipe connection refrigeration by hydrothermal solution rear pump Heat-exchanger coil and electrolyte solution holding tank;I.e. electrolyte solution holding tank, pyrosol efferent duct, hydrothermal solution rear pump, Refrigeration heat-exchanger coil and cryogenic fluid input pipe collectively form electrolyte solution cooling circuit, wherein heat exchange of freezing Helix tube is arranged in refrigerating plant.
High temp sensitive controller is provided with the electrolyte solution holding tank, the pipeline of pyrosol efferent duct is provided with warm Liquid rear pump, high temp sensitive controller is electrically connected with hydrothermal solution rear pump, when the liquid temperature in electrolyte solution holding tank is higher than setting During temperature, electrolyte solution is output in refrigerating plant and cooled down by hydrothermal solution rear pump automatic start.
Cryogenic fluid holding tank is also communicated between the refrigeration heat-exchanger coil and cryogenic fluid input pipe, low temperature is molten Liquid holding tank is arranged in refrigerating plant;Low temperature sensing controler is provided with cryogenic fluid holding tank, cryogenic fluid input pipe Pipeline is provided with cold liquid front pump, and low temperature sensing controler is electrically connected with cold liquid front pump, the liquid in cryogenic fluid holding tank When temperature is less than design temperature, the electrolyte solution in cryogenic fluid holding tank is input to electrolysis by cold liquid front pump automatic start In matter solution storage tank.
Refrigeration controler is additionally provided with the refrigerating plant, operating temperature and time for controlling refrigerating plant.
The refrigerating plant is refrigerator.
The beneficial effects of the invention are as follows can effectively control temperature of the electrolyte solution in electrolytic process, it is ensured that electrolysis water PH value meet desired value, improve the quality of production;Damage of the high-temperature electric electrolyte solution to electrolysis installation is reduced simultaneously, increases equipment The stability of operation, extends the service life of electrolytic film;Electrolysis installation can be made continuously to work, can be big without shutting down cooling again Big increase production yields.
Brief description of the drawings
Fig. 1 controls the overall structure diagram of the strong basicity electrolytic water generating device of electrolyte temperature for the present invention.
Fig. 2 automatically controls the overall structure diagram of the strong basicity electrolytic water generating device of electrolyte temperature for the present invention.
In figure:1. strong basicity electrolytic water generating device, 2. pure water water inlet pipes, 3. electrolytic cells, 4. electrolyte solution holding tanks, 5. woven hose, 6. infusion pumps, 7. alkali ion water outlet pipes, 9. electrolyte solution cooling devices, 10. pyrosol efferent ducts, 11. hydrothermal solution rear pump, 12. refrigerating plants, 13. refrigeration heat-exchanger coils, 14. cryogenic fluid input pipes, 15. high temp sensitive controls Device processed, 16. cryogenic fluid holding tanks, 17. low temperature sensing controlers, 18. cold liquid front pumps, 19. refrigeration controlers.
Embodiment
With reference to embodiment, the invention will be further described, and following examples are intended to illustrate invention rather than to this The further restriction of invention, should not be limited the scope of the invention with this.
Embodiment 1.
As shown in figure 1, making a kind of strong basicity electrolytic water generating device of control electrolyte temperature, i.e., in existing highly basic Electrolyte solution cooling device 9 is set up on property electrolytic water generating device 1.Existing strong basicity electrolytic water generating device 1 includes pure Water water inlet pipe 2, electrolytic cell 3, electrolyte solution holding tank 4, woven hose 5, infusion pump 6, alkali ion water outlet pipe 7, wherein pure Water water inlet pipe 2, alkali ion water outlet pipe 7 are connected with electrolytic cell 3 respectively, electrolyte solution holding tank 4, woven hose 5, transfusion Pump 6, electrolytic cell 7 be sequentially connected it is logical, constitute electrolyte solution circulate loop, the present embodiment is in electrolyte solution holding tank 4 On also increase electrolyte solution cooling device 9 is set.
The electrolyte solution cooling device 9 include pyrosol efferent duct 10, hydrothermal solution rear pump 11, refrigerating plant 12, Heat-exchanger coil 13 of freezing and cryogenic fluid input pipe 14;Refrigerating plant 12 in the present embodiment uses refrigerator, will be described It is inside refrigerator that heat-exchanger coil 13 of freezing, which is arranged on refrigerating plant 12,;Pyrosol efferent duct 10 passes through hydrothermal solution rear pump 11 connection electrolyte solution holding tanks 4 and refrigeration heat-exchanger coil 13;The connection refrigeration heat exchange spiral shell of cryogenic fluid input pipe 14 Coil 13 and electrolyte solution holding tank 4;I.e. electrolyte solution holding tank 4, pyrosol efferent duct 10, hydrothermal solution rear pump 11, Refrigeration heat-exchanger coil 13 and cryogenic fluid input pipe 14 collectively form electrolyte solution cooling circuit, wherein refrigeration heat Helix tube 13 is exchanged to be arranged in refrigerating plant 12 i.e. refrigerator.The highly basic of control electrolyte temperature of the invention is thus made Property electrolytic water generating device.
In use, pure water is input in electrolytic cell 3 by pure water water inlet pipe 2, infusion pump 6 is by woven hose 5 by electricity Solution of potassium carbonate in electrolyte solution holding tank 4 is input in electrolytic cell 3, and the solution of potassium carbonate in electrolytic cell 3 passes through transfusion again Pipe 5 is back in electrolyte solution holding tank 4;After direct current is passed into electrolytic cell 3, by neutral water generation strong basicity electrolysis Water, strong basicity electrolysis water is flowed out by alkali ion water outlet pipe.At the same time, big calorimetric can be produced in electrolytic process Amount, raises the temperature of solution of potassium carbonate, at this moment solution of potassium carbonate is cooled by electrolyte solution cooling device 9, i.e. hydrothermal solution Rear pump 11 is exported the solution of potassium carbonate after the temperature rise in electrolyte solution holding tank 4 by pyrosol efferent duct 10 Into the refrigeration heat-exchanger coil 13 in refrigerating plant 12, make the solution of potassium carbonate in refrigeration heat-exchanger coil 13 in electric ice Heat exchange is carried out in case, until cooling, is then back to by cryogenic fluid input pipe 14 in electrolyte solution holding tank 4;This Sample can cool at any time so that the temperature of the solution of potassium carbonate used in electrolysis water generating process is in required shape all the time State, makes the pH value of electrolysis water be consistent with desired value;Equipment damage can be reduced, the stability of electrolysis installation is effectively improved, so Electrolysis installation can be made to work continuously, cooling is waited without shutting down, substantially increase production yields, increase economic benefit.
Embodiment 2.
As shown in Fig. 2 on the basis of embodiment 1, setting TEMP to control in the electrolyte solution holding tank 4 Device sets hydrothermal solution rear pump 11, by high temp sensitive as high temp sensitive controller 15 on the pipeline of pyrosol efferent duct 10 Controller 15 is electrically connected with hydrothermal solution rear pump 11, when the temperature of the solution of potassium carbonate in electrolyte solution holding tank 4 is higher than setting When temperature is 25 DEG C, electrolyte solution is output in refrigerating plant 12 and cooled down by the automatic start of hydrothermal solution rear pump 11.
Cryogenic fluid storage is also set up between the refrigeration heat-exchanger coil 13 and cryogenic fluid input pipe 14 simultaneously Groove 16 is simultaneously sequentially communicated, and cryogenic fluid holding tank 16 is arranged in refrigerating plant 12;Set in cryogenic fluid holding tank 16 Temperature sensing controller is put as low temperature sensing controler 17, cold liquid front pump is set on the pipeline of cryogenic fluid input pipe 14 18, low temperature sensing controler 17 is electrically connected with cold liquid front pump 18, when the liquid temperature in cryogenic fluid holding tank 16 is less than setting During temperature, such as the present embodiment is set as 20 DEG C, the cold automatic start of liquid front pump 18, by the electrolyte in cryogenic fluid holding tank 16 Solution is input in electrolyte solution holding tank 4.Thus made automatically control electrolyte temperature strong basicity electrolysis it is aquatic Into device.
In use, electrolyte solution cooling device can be cooled down according to the real time temperature of electrolyte solution.
It is that the strong basicity electrolysis water for being fitted without electrolyte solution cooling device is generated by apparatus of the present invention and existing apparatus Device carries out contrast electrolytic trial, it is found that the electrolysis water pH value of apparatus of the present invention production is high and stably, 13.0-13.5 it Between, and the electrolysis water pH value of existing apparatus production is unstable, some pH value have reached 13, and some are not reaching to 13.In addition, this hair The Acceptable life of electrolytic film has reached 8000 hours in bright device, and in existing apparatus electrolytic film Acceptable life only Have 5000 hours.On January 22nd, 2017, Chongqing City Metering Quality Test Inst.'s test report(Report number 2017- 18SP010222)It has been shown that, the pH value of the strong basic ion water of apparatus of the present invention production is 13.0.
It can be seen that, apparatus of the present invention can effectively extend the Acceptable life of electrolytic film, can make the strong basicity produced The pH stable of electrolysis water improves product quality more than 13.

Claims (6)

1. a kind of strong basicity electrolytic water generating device of control electrolyte temperature(1), including pure water water inlet pipe(2), electrolytic cell (3), electrolyte solution holding tank(4), woven hose(5), infusion pump(6), alkali ion water outlet pipe(7), wherein pure water water inlet Pipe 2 and alkali ion water outlet pipe(7)Respectively with electrolytic cell(3)It is connected, electrolyte solution holding tank(4), woven hose(5)、 Infusion pump(6), electrolytic cell(7)It is sequentially connected the logical electrolyte solution that constitutes and circulates loop, it is characterised in that electrolyte solution Holding tank(4)On be additionally provided with electrolyte solution cooling device(9).
2. the strong basicity electrolytic water generating device of control electrolyte temperature according to claim 1, it is characterised in that described Electrolyte solution cooling device(9)Including pyrosol efferent duct(10), hydrothermal solution rear pump(11), refrigerating plant(12), refrigeration Heat-exchanger coil(13)With cryogenic fluid input pipe(14), the refrigeration heat-exchanger coil(13)Installed in refrigerating plant (12)Inside, pyrosol efferent duct(10)Pass through hydrothermal solution rear pump(11)Connect electrolyte solution holding tank(4)With refrigeration heat Exchange helix tube(13), cryogenic fluid input pipe(14)Connection refrigeration heat-exchanger coil(13)With electrolyte solution holding tank (4).
3. the strong basicity electrolytic water generating device of control electrolyte temperature according to claim 2, it is characterised in that described Electrolyte solution holding tank(4)It is interior to be provided with high temp sensitive controller(15), pyrosol efferent duct(10)Pipeline provided with heat Liquid rear pump(11), high temp sensitive controller(15)With hydrothermal solution rear pump(11)Electrical connection.
4. the strong basicity electrolytic water generating device of control electrolyte temperature according to claim 3, it is characterised in that described Refrigeration heat-exchanger coil(13)With cryogenic fluid input pipe(14)Between be also communicated with cryogenic fluid holding tank(16), low temperature is molten Liquid holding tank(14)Installed in refrigerating plant(12)In;Cryogenic fluid holding tank(16)It is interior to be provided with low temperature sensing controler(17), Cryogenic fluid input pipe(14)Pipeline be provided with cold liquid front pump(18), low temperature sensing controler(17)With cold liquid front pump (18)Electrical connection.
5. the strong basicity electrolytic water generating device of the control electrolyte temperature according to any one in claim 1-4, its It is characterised by the refrigerating plant(12)On be additionally provided with refrigeration controler(19).
6. the strong basicity electrolytic water generating device of control electrolyte temperature according to claim 5, it is characterised in that described Refrigerating plant is refrigerator.
CN201710246629.8A 2017-04-16 2017-04-16 A kind of strong basicity electrolytic water generating device of control electrolyte temperature Pending CN107055699A (en)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108358281A (en) * 2018-02-07 2018-08-03 何毅 A kind of strong basicity electrolysis water production system

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH07299457A (en) * 1994-05-09 1995-11-14 Hoshizaki Electric Co Ltd Electrolyzed water producing device
US20020036134A1 (en) * 1997-10-22 2002-03-28 Kazuhiro Shirota Manufacturing method and apparatus for making alkaline ionized water and acidic water
CN1613787A (en) * 2003-11-07 2005-05-11 三洋电机株式会社 Electrolyzed water generator
CN203112632U (en) * 2012-12-26 2013-08-07 王玉华 System device utilizing electrical functional acid ionized water to perform cleaning and disinfecting
CN103601269A (en) * 2013-11-11 2014-02-26 郑平林 System device for generating high-concentration electrolyzed water and control method of system device

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH07299457A (en) * 1994-05-09 1995-11-14 Hoshizaki Electric Co Ltd Electrolyzed water producing device
US20020036134A1 (en) * 1997-10-22 2002-03-28 Kazuhiro Shirota Manufacturing method and apparatus for making alkaline ionized water and acidic water
CN1613787A (en) * 2003-11-07 2005-05-11 三洋电机株式会社 Electrolyzed water generator
CN203112632U (en) * 2012-12-26 2013-08-07 王玉华 System device utilizing electrical functional acid ionized water to perform cleaning and disinfecting
CN103601269A (en) * 2013-11-11 2014-02-26 郑平林 System device for generating high-concentration electrolyzed water and control method of system device

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108358281A (en) * 2018-02-07 2018-08-03 何毅 A kind of strong basicity electrolysis water production system

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