CN107053388A - A kind of production method decorated with fire-retardant bamboo plywood - Google Patents
A kind of production method decorated with fire-retardant bamboo plywood Download PDFInfo
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- CN107053388A CN107053388A CN201710318118.2A CN201710318118A CN107053388A CN 107053388 A CN107053388 A CN 107053388A CN 201710318118 A CN201710318118 A CN 201710318118A CN 107053388 A CN107053388 A CN 107053388A
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- Prior art keywords
- bamboo
- fiber bundle
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- fire
- retardant
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Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B27—WORKING OR PRESERVING WOOD OR SIMILAR MATERIAL; NAILING OR STAPLING MACHINES IN GENERAL
- B27J—MECHANICAL WORKING OF CANE, CORK, OR SIMILAR MATERIALS
- B27J1/00—Mechanical working of cane or the like
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B27—WORKING OR PRESERVING WOOD OR SIMILAR MATERIAL; NAILING OR STAPLING MACHINES IN GENERAL
- B27K—PROCESSES, APPARATUS OR SELECTION OF SUBSTANCES FOR IMPREGNATING, STAINING, DYEING, BLEACHING OF WOOD OR SIMILAR MATERIALS, OR TREATING OF WOOD OR SIMILAR MATERIALS WITH PERMEANT LIQUIDS, NOT OTHERWISE PROVIDED FOR; CHEMICAL OR PHYSICAL TREATMENT OF CORK, CANE, REED, STRAW OR SIMILAR MATERIALS
- B27K3/00—Impregnating wood, e.g. impregnation pretreatment, for example puncturing; Wood impregnation aids not directly involved in the impregnation process
- B27K3/16—Inorganic impregnating agents
- B27K3/32—Mixtures of different inorganic impregnating agents
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B27—WORKING OR PRESERVING WOOD OR SIMILAR MATERIAL; NAILING OR STAPLING MACHINES IN GENERAL
- B27L—REMOVING BARK OR VESTIGES OF BRANCHES; SPLITTING WOOD; MANUFACTURE OF VENEER, WOODEN STICKS, WOOD SHAVINGS, WOOD FIBRES OR WOOD POWDER
- B27L11/00—Manufacture of wood shavings, chips, powder, or the like; Tools therefor
- B27L11/08—Manufacture of wood shavings, chips, powder, or the like; Tools therefor of wood fibres, e.g. produced by tearing
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B27—WORKING OR PRESERVING WOOD OR SIMILAR MATERIAL; NAILING OR STAPLING MACHINES IN GENERAL
- B27N—MANUFACTURE BY DRY PROCESSES OF ARTICLES, WITH OR WITHOUT ORGANIC BINDING AGENTS, MADE FROM PARTICLES OR FIBRES CONSISTING OF WOOD OR OTHER LIGNOCELLULOSIC OR LIKE ORGANIC MATERIAL
- B27N1/00—Pretreatment of moulding material
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B27—WORKING OR PRESERVING WOOD OR SIMILAR MATERIAL; NAILING OR STAPLING MACHINES IN GENERAL
- B27N—MANUFACTURE BY DRY PROCESSES OF ARTICLES, WITH OR WITHOUT ORGANIC BINDING AGENTS, MADE FROM PARTICLES OR FIBRES CONSISTING OF WOOD OR OTHER LIGNOCELLULOSIC OR LIKE ORGANIC MATERIAL
- B27N1/00—Pretreatment of moulding material
- B27N1/02—Mixing the material with binding agent
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B27—WORKING OR PRESERVING WOOD OR SIMILAR MATERIAL; NAILING OR STAPLING MACHINES IN GENERAL
- B27N—MANUFACTURE BY DRY PROCESSES OF ARTICLES, WITH OR WITHOUT ORGANIC BINDING AGENTS, MADE FROM PARTICLES OR FIBRES CONSISTING OF WOOD OR OTHER LIGNOCELLULOSIC OR LIKE ORGANIC MATERIAL
- B27N3/00—Manufacture of substantially flat articles, e.g. boards, from particles or fibres
- B27N3/08—Moulding or pressing
- B27N3/10—Moulding of mats
- B27N3/14—Distributing or orienting the particles or fibres
- B27N3/143—Orienting the particles or fibres
Abstract
The invention discloses a kind of production method decorated with fire-retardant bamboo plywood, comprise the following steps：(1) fresh bamboo is taken；(2) a part of bamboo chip is squeezed by roll-in crusher, bamboo chip is become bamboo fiber bundle, then bamboo fiber bundle and another part bamboo chip are put into the fire retardant aqueous solution that mass concentration is 30 50%；(3) bamboo fiber bundle and bamboo chip are dried：(4) bamboo fiber bundle and bamboo chip are immersed in viscose glue mixture；(5) by bamboo fiber bundle veneer stacked group embryo, plate embryo is composited by multilayer bamboo fiber bundle veneer is overlapping from top to down, and adjacent bamboo fiber bundle veneer or bamboo fiber bundle veneer arrange for vertical texture direction；(6) bamboo clappers after group embryo is subjected to precompressed, then carries out hot rolling；(7) cool down, bamboo clappers superposition is displayed, obtain decoration and use fire-retardant bamboo plywood.The fire-retardant bamboo plywood of the decoration that the present invention is prepared, with good fire resistance, bamboo plywood comes unglued, and rate is low, and timber intensity is high.
Description
Technical field
The present invention relates to glued board field, more particularly to a kind of production method decorated with fire-retardant bamboo plywood.
Background technology
Bamboo plywood is to decide to want framework and packing material with mao bamboon material, through high pressure into base building materials.Bamboo wood intensity is big,
Toughness, rigidity and anti-wear performance are good, can be used as excellent structural timber.The bamboo plywood mould manufactured by raw material of bamboo wood
Plate has good bending strength and rigidity, and overall structure is good, and breadth is big, easy to loading and unloading, and the demoulding is easy, and efficiency of construction is high,
With excellent technical qualities and economic benefit.Bamboo plywood is used for indoor various dresses due to exquisite appearance by increasing
Decorations, existing bamboo plywood is low due to fire-retardant rank, it is difficult to reach building interior Decoration Design code requirement, especially high-grade carriage
By the fire protection requirement of the public places such as place, hotel, office building.
The information for being disclosed in the background section is merely intended to understanding of the increase to the general background of the present invention, without answering
When the prior art for being considered as recognizing or implying the information structure in any form well known to persons skilled in the art.
The content of the invention
It is an object of the invention to provide a kind of production method decorated with fire-retardant bamboo plywood, so as to overcome existing bamboo glue
The shortcoming of plywood poor flame retardant properties.
To achieve the above object, the invention provides a kind of production method decorated with fire-retardant bamboo plywood, including it is following
Step：
(1) fresh bamboo is taken, fresh bamboo surface bamboo green grass or young crops is removed, then raw bamboo is cutd open into fresh bamboo internal layer is removed after 3-5 pieces, dissection
The membrane portions of tabasheer and ring；
(2) a part of bamboo chip is squeezed by roll-in crusher, bamboo chip is become bamboo fiber bundle, then by bamboo fiber bundle and another
Part bamboo chip is put into the fire retardant aqueous solution that mass concentration is 30-50%, and the fire retardant mainly has following quality proportioning
Component is made：35-55 parts of ammonium low polyphosphate, 11-18 parts of nano zine oxide, 7-15 parts of Firebrake ZB, 4-11 parts of magnesia powder, asbestos
9-18 parts of fiber, 3-7 parts of sodium metasilicate, 10-15 parts of ammonium pyrophosphate, 1-3 parts of ammonium heptamolybdate and 4-7 parts of Firebrake ZB and boric acid 9-16
Part；Control fire retardant aqueous temperature at 45-50 DEG C, impregnate 15-30min；
(3) bamboo fiber bundle and bamboo chip are dried, dry the moisture content to bamboo fiber bundle and bamboo chip below 10%：
(4) bamboo fiber bundle and bamboo chip are immersed in viscose glue mixture, the viscose glue for removing bamboo fiber bundle and bamboo chip excess surface is closed
Agent, then bamboo fiber bundle is dried；
(5) by bamboo fiber bundle veneer stacked group embryo, plate embryo is composited by multilayer bamboo fiber bundle veneer is overlapping from top to down, phase
Adjacent bamboo fiber bundle veneer or bamboo fiber bundle veneer arranges for vertical texture direction；
(6) bamboo clappers after group embryo is subjected to precompressed, then carries out hot rolling；
(7) after the completion of hot rolling, bamboo clappers superposition is displayed in cooling, is obtained decoration and is used fire-retardant bamboo plywood.
Preferably, in above-mentioned technical proposal, the fire retardant in the step (2) mainly has the component system of following quality proportioning
Into：45 parts of ammonium low polyphosphate, 14 parts of nano zine oxide, 11 parts of Firebrake ZB, 6 parts of magnesia powder, 13 parts of asbestos fibre, sodium metasilicate 5
Part, 12 parts of ammonium pyrophosphate, 2 parts of ammonium heptamolybdate and 11 parts of 5 parts of Firebrake ZB and boric acid.
Preferably, in above-mentioned technical proposal, viscose glue mixture is phenolic resin viscose glue mixture, impregnation resin content in the step (4)
For bamboo fiber bundle or the 5-10% of bamboo chip dry mass.
Preferably, in above-mentioned technical proposal, bamboo fiber bundle and bamboo chip dry to be 50-60 in temperature in the step (4)
Under conditions of DEG C, drying to moisture content is 9-12%.
Preferably, in above-mentioned technical proposal, the number of plies of bamboo fiber bundle veneer is 2-11 layers inside plate embryo.
Preferably, in above-mentioned technical proposal, precompressed is first in normal temperature, unit pressure 1-2MPa bar in the step (6)
Under part, cold pressing treatment 20-50min.
Preferably, in above-mentioned technical proposal, hot rolling is that pressure is 3-6MPa in 120-150 DEG C of temperature in the step (6)
Under conditions of, the hot rolling time is 1.2-1.5mm/min.
Preferably, in above-mentioned technical proposal, display bamboo plywood being cooled to temperature for 40- in the step (7)
50 DEG C, bamboo plywood is inserted in the quenched environment of damping and carries out wet-heat durability, displayed more than 15 days, bamboo plywood is controlled after displaying
Moisture content be 10-12%.
Compared with prior art, the present invention has the advantages that：The decoration that the present invention is prepared anti-flaming bamboo glue
Plywood, with good fire resistance, toughness is strong, and bamboo plywood comes unglued, and rate is low, and timber intensity is high.Preparation technology is simple, it is easy to
Implement and grasp, improve production efficiency.
Embodiment
With reference to specific embodiment, the embodiment to the present invention is described in detail, it is to be understood that this hair
Bright protection domain is not limited by embodiment.
Embodiment 1
A kind of production method decorated with fire-retardant bamboo plywood, comprises the following steps：
(1) fresh bamboo is taken, fresh bamboo surface bamboo green grass or young crops is removed, then raw bamboo is cutd open into fresh bamboo internal layer is removed after 3-5 pieces, dissection
The membrane portions of tabasheer and ring；
(2) a part of bamboo chip is squeezed by roll-in crusher, bamboo chip is become bamboo fiber bundle, then by bamboo fiber bundle and another
Part bamboo chip is put into the fire retardant aqueous solution that mass concentration is 40%, and the fire retardant mainly has the component of following quality proportioning
It is made：45 parts of ammonium low polyphosphate, 14 parts of nano zine oxide, 11 parts of Firebrake ZB, 6 parts of magnesia powder, 13 parts of asbestos fibre, sodium metasilicate
5 parts of 5 parts, 12 parts of ammonium pyrophosphate, 2 parts of ammonium heptamolybdate and Firebrake ZB and 11 parts of boric acid；Fire retardant aqueous temperature is controlled in 45-50
DEG C, impregnate 20min；
(3) bamboo fiber bundle and bamboo chip are dried, dry the moisture content to bamboo fiber bundle and bamboo chip 9%：
(4) bamboo fiber bundle and bamboo chip are immersed in viscose glue mixture, viscose glue mixture is phenolic resin viscose glue mixture, impregnation resin content is
The 7% of bamboo fiber bundle or bamboo chip dry mass, removes the viscose glue mixture of bamboo fiber bundle and bamboo chip excess surface, then bamboo fiber bundle is entered
It in temperature is that under conditions of 55 DEG C, drying to moisture content is 10% that row drying, bamboo fiber bundle and bamboo chip drying, which are,.
(5) by bamboo fiber bundle veneer and bamboo chip ply stacked group embryo, surface layer is bamboo chip veneer above and below plate embryo, plate embryo inside
Plate embryo is composited by 9 layers of bamboo fiber bundle veneer are overlapping from top to down, adjacent bamboo fiber bundle veneer or bamboo fiber bundle veneer with
Bamboo chip veneer arranges for vertical texture direction；
(6) bamboo clappers after group embryo is subjected to precompressed, precompressed under conditions of normal temperature, unit pressure 1.5MPa, is cold-pressed to be first
Handle 30min；Carry out hot rolling again, hot rolling is that, in 140 DEG C of temperature, under conditions of pressure is 5MPa, the hot rolling time is 1.2-
1.5mm/min。
(7) after the completion of hot rolling, bamboo plywood is cooled to temperature for 45 DEG C, bamboo plywood is inserted into damping quenched by cooling
Wet-heat durability is carried out in environment, is displayed 22 days, the moisture content that bamboo plywood is controlled after displaying is 11%.Obtain decoration anti-flaming bamboo
Glued board.
By detection, the product oxygen index value that the present embodiment is obtained is 53.16%, reaches fire-retardant B grades of coefficient national standard
The requirement of fire-protection rating.This product without using fire retardant compared with handling the glued board being made, and its mechanical property is only reduced
4.22%.
Embodiment 2
A kind of production method decorated with fire-retardant bamboo plywood, comprises the following steps：
(1) fresh bamboo is taken, fresh bamboo surface bamboo green grass or young crops is removed, then raw bamboo is cutd open into fresh bamboo internal layer is removed after 3-5 pieces, dissection
The membrane portions of tabasheer and ring；
(2) a part of bamboo chip is squeezed by roll-in crusher, bamboo chip is become bamboo fiber bundle, then by bamboo fiber bundle and another
Part bamboo chip is put into the fire retardant aqueous solution that mass concentration is 30%, and the fire retardant mainly has the component of following quality proportioning
It is made：55 parts of ammonium low polyphosphate, 11 parts of nano zine oxide, 15 parts of Firebrake ZB, 4 parts of magnesia powder, 18 parts of asbestos fibre, sodium metasilicate
7 parts of 7 parts, 10 parts of ammonium pyrophosphate, 1 part of ammonium heptamolybdate and Firebrake ZB and 16 parts of boric acid；Fire retardant aqueous temperature is controlled in 45-50
DEG C, impregnate 15min；
(3) bamboo fiber bundle and bamboo chip are dried, dry the moisture content to bamboo fiber bundle and bamboo chip 10%：
(4) bamboo fiber bundle and bamboo chip are immersed in viscose glue mixture, viscose glue mixture is phenolic resin viscose glue mixture, impregnation resin content is
The 5% of bamboo fiber bundle or bamboo chip dry mass, removes the viscose glue mixture of bamboo fiber bundle and bamboo chip excess surface, then bamboo fiber bundle is entered
It in temperature is that under conditions of 60 DEG C, drying to moisture content is 9% that row drying, bamboo fiber bundle and bamboo chip drying, which are,.
(5) by bamboo fiber bundle veneer and bamboo chip ply stacked group embryo, surface layer is bamboo chip veneer above and below plate embryo, plate embryo inside
Plate embryo is composited by 9 layers of bamboo fiber bundle veneer are overlapping from top to down, adjacent bamboo fiber bundle veneer or bamboo fiber bundle veneer with
Bamboo chip veneer arranges for vertical texture direction；
(6) bamboo clappers after group embryo is subjected to precompressed, precompressed is first under conditions of normal temperature, unit pressure 2MPa, at cold pressing
Manage 20min；Carry out hot rolling again, hot rolling is that, in 120 DEG C of temperature, under conditions of pressure is 6MPa, the hot rolling time is 1.2-1.5mm/
min。
(7) after the completion of hot rolling, bamboo plywood is cooled to temperature for 40 DEG C, bamboo plywood is inserted into damping quenched by cooling
Wet-heat durability is carried out in environment, is displayed 18 days, the moisture content that bamboo plywood is controlled after displaying is 12%.Obtain decoration anti-flaming bamboo
Glued board.
By detection, the product oxygen index value that the present embodiment is obtained is 53.34%, reaches fire-retardant B grades of coefficient national standard
The requirement of fire-protection rating.This product without using fire retardant compared with handling the glued board being made, and its mechanical property is only reduced
4.52%.
Embodiment 3
A kind of production method decorated with fire-retardant bamboo plywood, comprises the following steps：
(1) fresh bamboo is taken, fresh bamboo surface bamboo green grass or young crops is removed, then raw bamboo is cutd open into fresh bamboo internal layer is removed after 3-5 pieces, dissection
The membrane portions of tabasheer and ring；
(2) a part of bamboo chip is squeezed by roll-in crusher, bamboo chip is become bamboo fiber bundle, then by bamboo fiber bundle and another
Part bamboo chip is put into the fire retardant aqueous solution that mass concentration is 50%, and the fire retardant mainly has the component of following quality proportioning
It is made：35 parts of ammonium low polyphosphate, 18 parts of nano zine oxide, 7 parts of Firebrake ZB, 11 parts of magnesia powder, 9 parts of asbestos fibre, sodium metasilicate 3
Part, 15 parts of ammonium pyrophosphate, 3 parts of ammonium heptamolybdate and 9 parts of 4 parts of Firebrake ZB and boric acid；Fire retardant aqueous temperature is controlled in 45-50
DEG C, impregnate 30min；
(3) bamboo fiber bundle and bamboo chip are dried, dry the moisture content to bamboo fiber bundle and bamboo chip 8%：
(4) bamboo fiber bundle and bamboo chip are immersed in viscose glue mixture, viscose glue mixture is phenolic resin viscose glue mixture, impregnation resin content is
The 10% of bamboo fiber bundle or bamboo chip dry mass, removes the viscose glue mixture of bamboo fiber bundle and bamboo chip excess surface, then by bamboo fiber bundle
Dried, it in temperature is that under conditions of 50 DEG C, drying to moisture content is 9% that bamboo fiber bundle and bamboo chip drying, which are,.
(5) by bamboo fiber bundle veneer and bamboo chip ply stacked group embryo, surface layer is bamboo chip veneer above and below plate embryo, plate embryo inside
Plate embryo is composited by 9 layers of bamboo fiber bundle veneer are overlapping from top to down, adjacent bamboo fiber bundle veneer or bamboo fiber bundle veneer with
Bamboo chip veneer arranges for vertical texture direction；
(6) bamboo clappers after group embryo is subjected to precompressed, precompressed is first under conditions of normal temperature, unit pressure 1MPa, at cold pressing
Manage 50min；Carry out hot rolling again, hot rolling is that, in 150 DEG C of temperature, under conditions of pressure is 3MPa, the hot rolling time is 1.2-1.5mm/
min。
(7) after the completion of hot rolling, bamboo plywood is cooled to temperature for 50 DEG C, bamboo plywood is inserted into damping quenched by cooling
Wet-heat durability is carried out in environment, is displayed 22 days, the moisture content that bamboo plywood is controlled after displaying is 10%.Obtain decoration anti-flaming bamboo
Glued board.
By detection, the product oxygen index value that the present embodiment is obtained is 56.42%, reaches fire-retardant B grades of coefficient national standard
The requirement of fire-protection rating.This product without using fire retardant compared with handling the glued board being made, and its mechanical property is only reduced
4.82%.
It is foregoing to the present invention specific illustrative embodiment description be in order to illustrate and illustration purpose.These descriptions
It is not wishing to limit the invention to disclosed precise forms, and it will be apparent that according to above-mentioned teaching, can be much changed
And change.The purpose of selecting and describing the exemplary embodiment is that explaining that the certain principles and its reality of the present invention should
With so that those skilled in the art can realize and using the present invention a variety of exemplaries and
A variety of selections and change.The scope of the present invention is intended to be limited by claims and its equivalents.
Claims (8)
1. a kind of production method decorated with fire-retardant bamboo plywood, it is characterised in that comprise the following steps：
(1) fresh bamboo is taken, fresh bamboo surface bamboo green grass or young crops is removed, then raw bamboo is cutd open into the tabasheer that fresh bamboo internal layer is removed after 3-5 pieces, dissection
With the membrane portions of ring；
(2) a part of bamboo chip is squeezed by roll-in crusher, bamboo chip is become bamboo fiber bundle, then by bamboo fiber bundle and another part
Bamboo chip is put into the fire retardant aqueous solution that mass concentration is 30-50%, and the fire retardant mainly has the component of following quality proportioning
It is made：35-55 parts of ammonium low polyphosphate, 11-18 parts of nano zine oxide, 7-15 parts of Firebrake ZB, 4-11 parts of magnesia powder, asbestos fibre
4-7 parts of 9-18 parts, 3-7 parts of sodium metasilicate, 10-15 parts of ammonium pyrophosphate, 1-3 parts of ammonium heptamolybdate and Firebrake ZB；Control fire retardant water-soluble
Liquid temperature degree impregnates 15-30min at 45-50 DEG C；
(3) bamboo fiber bundle and bamboo chip are dried, dry the moisture content to bamboo fiber bundle and bamboo chip below 10%：
(4) bamboo fiber bundle and bamboo chip are immersed in viscose glue mixture, removes the viscose glue mixture of bamboo fiber bundle and bamboo chip excess surface, then
Bamboo fiber bundle is dried；
(5) by bamboo fiber bundle veneer stacked group embryo, plate embryo is composited by multilayer bamboo fiber bundle veneer is overlapping from top to down, adjacent
Bamboo fiber bundle veneer or bamboo fiber bundle veneer arrange for vertical texture direction；
(6) bamboo clappers after group embryo is subjected to precompressed, then carries out hot rolling；
(7) after the completion of hot rolling, bamboo clappers superposition is displayed in cooling, is obtained decoration and is used fire-retardant bamboo plywood.
2. the production method of the fire-retardant bamboo plywood of decoration according to claim 1, it is characterised in that the step (2)
In the fire retardant component that mainly has following quality proportioning be made：45 parts of ammonium low polyphosphate, 14 parts of nano zine oxide, Firebrake ZB 11
Part, 6 parts of magnesia powder, 13 parts of asbestos fibre, 5 parts of sodium metasilicate, 12 parts of ammonium pyrophosphate, 2 parts of ammonium heptamolybdate and 5 parts of Firebrake ZB and boron
11 parts of acid.
3. the production method of the fire-retardant bamboo plywood of decoration according to claim 1, it is characterised in that the step (4)
Middle viscose glue mixture is phenolic resin viscose glue mixture, and impregnation resin content is the 5-10% of bamboo fiber bundle or bamboo chip dry mass.
4. the production method of the fire-retardant bamboo plywood of decoration according to claim 1, it is characterised in that the step (4)
It in temperature is that under conditions of 50-60 DEG C, drying to moisture content is 9-12% that the drying of middle bamboo fiber bundle and bamboo chip, which is,.
5. the production method of the fire-retardant bamboo plywood of decoration according to claim 1, it is characterised in that plate embryo bamboo fiber bundle
The number of plies of veneer is 3-11 layers.
6. the production method of the fire-retardant bamboo plywood of decoration according to claim 1, it is characterised in that the step (6)
Middle precompressed is the cold pressing treatment 20-50min first under conditions of normal temperature, unit pressure 1-2MPa.
7. the production method of the fire-retardant bamboo plywood of decoration according to claim 1, it is characterised in that the step (6)
Middle hot rolling is that, in 120-150 DEG C of temperature, under conditions of pressure is 3-6MPa, the hot rolling time is 1.2-1.5mm/min.
8. the production method of the fire-retardant bamboo plywood of decoration according to claim 1, it is characterised in that the step (7)
In display for, bamboo plywood is cooled to temperature for 40-50 DEG C, bamboo plywood is inserted carried out in the quenched environment of damping it is damp and hot
Balance, is displayed more than 15 days, and the moisture content that bamboo plywood is controlled after displaying is 10-12%.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710318118.2A CN107053388A (en) | 2017-05-08 | 2017-05-08 | A kind of production method decorated with fire-retardant bamboo plywood |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710318118.2A CN107053388A (en) | 2017-05-08 | 2017-05-08 | A kind of production method decorated with fire-retardant bamboo plywood |
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Family
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| CN201710318118.2A Pending CN107053388A (en) | 2017-05-08 | 2017-05-08 | A kind of production method decorated with fire-retardant bamboo plywood |
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