CN107034482B - A kind of overturning-preventing Instant hydrogen generator - Google Patents

A kind of overturning-preventing Instant hydrogen generator Download PDF

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Publication number
CN107034482B
CN107034482B CN201710287324.1A CN201710287324A CN107034482B CN 107034482 B CN107034482 B CN 107034482B CN 201710287324 A CN201710287324 A CN 201710287324A CN 107034482 B CN107034482 B CN 107034482B
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China
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hydrogen
water
hydrogen generator
electrolysis cells
overturning
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Expired - Fee Related
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CN201710287324.1A
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Chinese (zh)
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CN107034482A (en
Inventor
阮国洪
周陈兴
李永琳
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Fujian Ospring Technology Development Co Ltd
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Fujian Ospring Technology Development Co Ltd
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Priority to CN201710287324.1A priority Critical patent/CN107034482B/en
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    • CCHEMISTRY; METALLURGY
    • C25ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25BELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
    • C25B1/00Electrolytic production of inorganic compounds or non-metals
    • C25B1/01Products
    • C25B1/02Hydrogen or oxygen
    • C25B1/04Hydrogen or oxygen by electrolysis of water
    • CCHEMISTRY; METALLURGY
    • C25ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25BELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
    • C25B9/00Cells or assemblies of cells; Constructional parts of cells; Assemblies of constructional parts, e.g. electrode-diaphragm assemblies; Process-related cell features
    • C25B9/70Assemblies comprising two or more cells
    • C25B9/73Assemblies comprising two or more cells of the filter-press type
    • CCHEMISTRY; METALLURGY
    • C25ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25BELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
    • C25B9/00Cells or assemblies of cells; Constructional parts of cells; Assemblies of constructional parts, e.g. electrode-diaphragm assemblies; Process-related cell features
    • CCHEMISTRY; METALLURGY
    • C25ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25BELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
    • C25B9/00Cells or assemblies of cells; Constructional parts of cells; Assemblies of constructional parts, e.g. electrode-diaphragm assemblies; Process-related cell features
    • C25B9/17Cells comprising dimensionally-stable non-movable electrodes; Assemblies of constructional parts thereof
    • C25B9/19Cells comprising dimensionally-stable non-movable electrodes; Assemblies of constructional parts thereof with diaphragms
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/30Hydrogen technology
    • Y02E60/36Hydrogen production from non-carbon containing sources, e.g. by water electrolysis

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Electrochemistry (AREA)
  • Materials Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Electrolytic Production Of Non-Metals, Compounds, Apparatuses Therefor (AREA)

Abstract

The present invention relates to a kind of overturning-preventing Instant hydrogen generator, explosion easy to form when for solving the problems, such as to occur during hydrogen-rich water generator manufactures hydrogen the phenomenon that toppling over, junction spilling water and hydrogen and more oxygen.Hydrogen generator ontology most starts to live after adsorption plane using hydraulic sucker suction, as the process of electrolysis cells electrolysis water is goed deep into, generate a large amount of hydrogen and oxygen, water in bottle boils gas stone, hydraulic flow-path tube by minerals and pressure is passed to hydraulic sucker, i.e. constantly pressure is to hydraulic sucker, so that hydrogen generator ontology will not generate inclined situation in the hydrogen production process and occur.In view of the above reason, hydrogen-rich water manufacturing field present invention can be widely used to.

Description

A kind of overturning-preventing Instant hydrogen generator
Technical field
The present invention relates to hydrogen-rich water manufacturing fields, especially with regard to a kind of overturning-preventing Instant hydrogen generator.
Background technique
Hydrogen is a kind of colourless, tasteless, nontoxic and odorless gas.The peculiar property of hydrogen determines hydrogen in biology On have many advantages.The primary efficacy of hydrogen are as follows: anti-oxidant, as a kind of selective antioxidant, hydrogen is to many diseases With therapeutic effect, be widely used prospect.
Hydrogen-rich water, as the term suggests it is exactly the water rich in hydrogen.English is hydrogenRich water, and Japanese is " water element Water ".In recent years, hydrogen-rich water, water element aquatic products are gradually more on domestic market, and hydrogen-rich water, the cup of water element water and manufacturing device also have Finding, wherein the technology using electrolytic hydrogen production occupies significant proportion.
Especially Chinese invention: a kind of portable hydrogen-rich water generator CN204873955U, the invention connect cushion Connect on the shell of hydrogen-rich water generator, make hydrogen-rich water generator tank house and water bottle internal combustion and form sealing space. But when this device carries out water electrolysis, generated hydrogen, oxygen rise, and most of hydrogen or oxygen gas includes that bottle body stands upside down When and a small amount of air for bringing into can be deposited in the closed cavity of water bottle top, when air pressure is higher, hydrogen or oxygen gas will be hindered It generates, even stops so that water electrolysis eases up.This reason can chemically understand in equation: H2O → H2 ↑+O2 ↑, work as generation When gas can not export, chemical reaction would not be carried out to product direction.
And during hydrogen-rich water generator manufacture hydrogen, with the promotion of air pressure in water bottle, easy pressure is excessive in bottle, It is easy to produce following two aspects problem:
1) due to being usually all to turn hydrogen manufacturing around, the water in water bottle is accordingly used in upper, formation " top-heavy ", hydrogen manufacturing It is easy to topple in journey;
2) the phenomenon that hydrogen generator is with water bottle junction spilling water;
3) hydrogen and explosion is easy when more oxygen.
Summary of the invention
The technical problem to be solved by the present invention is in order to solve hydrogen-rich water generator in the prior art in the process of manufacture hydrogen In there is the problem of explosion easy to form when the phenomenon that toppling over, junction spilling water and hydrogen and more oxygen, the present invention mentions It solves the above problems for a kind of overturning-preventing Instant hydrogen generator.
The technical solution adopted by the present invention to solve the technical problems is: a kind of overturning-preventing Instant hydrogen generator, Be characterized in that: it includes hydrogen generator ontology, and groove is provided in the hydrogen generator ontology, and the groove is provided with interior Screw thread, the internal screw thread are matched with the external screw thread of water bottle bottle mouth position, and the two is connected through a screw thread integrally;Setting in the groove There are electrolysis cells, the electrolysis cells form hydrogen and oxygen for electrolysis water, and the electrolysis cells connect touch controlled key, described Touch controlled key is used to control the opening and closing of the electrolysis cells;Hydraulic flow-path tube, institute is arranged in the center of the electrolysis cells The upper surface of hydraulic flow-path tube connection minerals boiling gas stone is stated, and minerals boiling gas stone is covered on the electrolysis cells, institute It states and connects hydraulic sucker below hydraulic flow-path tube, and the hydraulic sucker is arranged in the hydrogen generator body exterior;Institute The electrolysis cells lower part setting pellosil in groove is stated, the pellosil and the electrolysis cells interval are arranged, the silicon The pressure-sensitive spring of setting in glue film, the pressure-sensitive spring connect pressing switch, and the pressing switch connects the touch controlled key.
The electrolysis cells include negative electrode tab, positive plate and selectivity through film, and the selectivity is arranged through film Between the negative electrode tab and the positive plate;The negative electrode tab connects power cathode for generating hydrogen;The positive plate is used for Oxygen is generated, positive pole is connected, the electrolysis cells are also connected with the touch controlled key.
The selectivity uses proton exchange membrane through film.
The shape of the minerals boiling gas stone uses hemispherical.
The hydrogen generator ontology week sets up several non-slip mats.
The beneficial effects of the present invention are: the lid of mineral water water bottle is unscrewed, hydrogen generator ontology or mineral spring are rotated Water water bottle realizes mineral spring so that being connected through a screw thread between internal screw thread in the external screw thread and groove of mineral water water bottle bottle mouth position Water water bottle links into an integrated entity with hydrogen generator ontology;The on & off switch on electric-controlled plate is pressed, touch controlled key control is electrolysis cells Power supply, so that battery starts as electrolysis cells power supply.Electrolysis cells start electrolysis water: negative electrode tab connection -7V electricity, positive plate connect + 7V electricity is connect, negative electrode tab electrolysis water generates hydrogen, which is minute bubbles, can largely be well soluble in water, and small part enters There is no the part of water in mineral water water bottle;Proton enters positive plate through film by selectivity, forms electric current, positive plate electrolysis water Oxygen is generated, the air pocket of generation enters in mineral water water bottle, into not having the part of water in mineral water water bottle.The oxygen of manufacture Pass through the minerals being arranged thereon with hydrogen and boil gas stone, hydrogen and oxygen are not only resolved into smaller gas by minerals boiling gas stone Bubble, to be dissolved in water rapidly;And the by-product in water is eliminated and adds minerals into water, that is, oxidizing substance is eliminated, Such as chlorine residue or ozone, to reach double effects;Hydrogen generator ontology and mineral water water bottle are inverted, hydraulic sucker suction On surface to be adsorbed.Conventional sucker in absorption most starts that vacuum firmly is presented in the air discharge between sucker and adsorption plane State, to complete the absorption between sucker and adsorption plane.However, the long period after absorption, week of the air from sucker It encloses and enters between sucker and adsorption plane, to cause to separate between sucker and adsorption plane.However hydrogen generator ontology most starts After living adsorption plane using hydraulic sucker suction, as the process of electrolysis cells electrolysis water is goed deep into, a large amount of hydrogen and oxygen are generated Gas, the water in bottle boil gas stone, hydraulic flow-path tube by minerals and pressure are passed to hydraulic sucker, i.e., constantly pressure is to hydraulic suction Disk, so that hydrogen generator ontology will not generate inclined situation in the hydrogen production process and occur.With electrolysis cells electrolysis water Process is goed deep into, and the pressure of mineral water water bottle and hydrogen generator ontology junction is gradually increased, and pellosil generates deformation, pellosil Deformation drive the pressure-sensitive spring in it to generate deformation, pressure-sensitive spring encounters pressing switch after generating deformation, pressing switch The free end of elastic element generates displacement, pushes directly on touch controlled key, changes the on off operating mode of touch controlled key, and touch controlled key breaks After opening, electrolysis cells power-off, electrolysis cells no longer electrolysis water, therefore the pressure in the bottle no longer changes, to avoid mineral water water The explosion phenomenon that bottle is excessive with hydrogen in hydrogen generator ontology junction spilling water or mineral water water bottle and oxygen and causes.Mirror In the above reason, hydrogen-rich water manufacturing field present invention can be widely used to.
Detailed description of the invention
Present invention will be further explained below with reference to the attached drawings and examples.
Fig. 1 is top view of the invention;
Fig. 2 is side view of the invention.
Specific embodiment
In conjunction with the accompanying drawings, the present invention is further explained in detail.These attached drawings are simplified schematic diagram, only with Illustration illustrates basic structure of the invention, therefore it only shows the composition relevant to the invention.
As depicted in figs. 1 and 2, the present invention includes hydrogen generator ontology 100, is provided in hydrogen generator ontology 100 Groove 101, the groove 101 are provided with internal screw thread, which matches with the external screw thread of water bottle bottle mouth position, and the two passes through screw thread It links into an integrated entity.Above-mentioned water bottle generallys use common mineral water water bottle.
Electrolysis cells 102 are provided in groove 101, electrolysis cells 102 include negative electrode tab 103, positive plate 104 and selectivity Through film 105, and selectivity is arranged between negative electrode tab 103 and positive plate 104 through film 105, for penetrating therebetween Proton, to form electric current.Negative electrode tab 103 is used to generate the hydrogen of minute bubbles, and the hydrogen of minute bubbles is dissolved in water, is arranged upper Side connects power cathode (usually -7V);Positive plate 104 is used to generate the oxygen of air pocket, and the oxygen of air pocket does not dissolve in Water is arranged below, and is connected positive pole (usually+7V), and electrolysis cells 102 are also connected with touch controlled key 200, touch controlled key 200 for controlling the opening and closing of electrolysis cells 102.
In above-described embodiment, selectivity uses proton exchange membrane through film 105.
Hydraulic flow-path tube 106 is arranged in the center of electrolysis cells 102, and the upper surface of hydraulic flow-path tube 106 is connected to minerals and boils gas Stone 107, and minerals boiling gas stone 107 is covered on electrolysis cells 102.Hydraulic sucker is connected below hydraulic flow-path tube 106 108, and hydraulic sucker 108 is arranged outside hydrogen generator ontology 100.Above-mentioned hydraulic sucker 108 uses common sucker, It is not limited here.
In above-described embodiment, the shape that minerals boil gas stone 107 can be using including but not limited to hemispherical, and preferred mine The diameter that substance boils gas stone 107 is equal with 102 diameter of electrolysis cells.It is the gas being made into using minerals that minerals, which boil gas stone 107, Afrodite is existing product, therefore is no longer described in detail.
102 lower part of electrolysis cells in groove 101 is arranged in pellosil 109, and between pellosil 109 and electrolysis cells 102 Every the pressure-sensitive spring 110 of setting in setting, pellosil 109, pressure-sensitive spring 110 connects pressing switch 111, and pressing switch 111 connects Touch controlled key 200.
Touch controlled key 200 is used to control the energization or power-off of electrolysis cells 102.Touch controlled key 200 passes through circuit connection electricity Control plate 300.Electric-controlled plate 300 uses touch panel, and finger is pressed to the on & off switch on electric-controlled plate 300, forms point capacitor Complete ON/OFF process (this process is consistent with the switching process on electromagnetic oven, is the prior art, therefore is no longer described in detail).Touch-control is pressed Key 200 is connected to electrolysis cells 102, so that battery starts as the power supply of electrolysis cells 102.Electric-controlled plate 300 is also connected with battery (figure In be not shown), with for electric-controlled plate and electrolysis cells 102 power supply.Charging hole 112 is also set up on hydrogen generator ontology 100, so as to When there is no electricity, to charge the battery.
Several non-slip mats 113 are also set up in the surface circumferential direction of hydrogen generator ontology 100, non-slip mat 113 uses at least four A contour small column, to prevent the plane as where the present invention it is wet and slippery or caused by excessively smooth frictional force is inadequate it is mobile existing As.
By taking the aquatic production hydrogen-rich water in common mineral water water bottle as an example, when the invention works:
1) lid of mineral water water bottle is unscrewed, hydrogen generator ontology 100 or mineral water water bottle is rotated, so that mineral spring It is connected through a screw thread between internal screw thread in the external screw thread and groove 101 of water water bottle bottle mouth position, realizes mineral water water bottle and hydrogen manufacturing Generator ontology 100 links into an integrated entity;
2) on & off switch on electric-controlled plate 300 is pressed, the control of touch controlled key 200 is that electrolysis cells 102 are powered, thus battery Start as the power supply of electrolysis cells 102.Electrolysis cells 102 start electrolysis water: 103 connection -7V of negative electrode tab is electric, and the connection of positive plate 104+ 7V electricity, 103 electrolysis water of negative electrode tab generate hydrogen, which is minute bubbles, can largely be well soluble in water, and small part enters There is no the part of water in mineral water water bottle;Proton enters positive plate 104 through film 105 by selectivity, forms electric current, positive plate 104 electrolysis waters generate oxygen, and the air pocket of generation enters in mineral water water bottle, into not having the part of water in mineral water water bottle;
The oxygen and hydrogen of manufacture pass through the minerals being arranged thereon and boil gas stone 107, and minerals boil gas stone 107 not only by hydrogen Gas and oxygen resolve into smaller bubble, to be dissolved in water rapidly;And the by-product in water is eliminated and adds mine into water Substance, i.e. elimination oxidizing substance, such as chlorine residue or ozone, to reach double effects;
3) hydrogen generator ontology 100 and mineral water water bottle are inverted, hydraulic sucker 108 is adsorbed on surface to be adsorbed.Often Sucker is advised in absorption, most starts that vacuum state firmly is presented in the air discharge between sucker and adsorption plane, to complete to inhale Absorption between disk and adsorption plane.However, the long period after absorption, air enters sucker and absorption around sucker Between face, to cause to separate between sucker and adsorption plane.However hydrogen generator ontology 100 most starts using hydraulic sucker After 108 adsorb adsorption plane, as the process of 102 electrolysis water of electrolysis cells is goed deep into, a large amount of hydrogen and oxygen are generated, in bottle Water boil gas stone 107 by minerals, pressure is passed to hydraulic sucker 108 by hydraulic flow-path tube 106, i.e., constantly pressure is to hydraulic Sucker 108, so that hydrogen generator ontology 100 will not generate inclined situation in the hydrogen production process and occur.
4) as the process of 102 electrolysis water of electrolysis cells is goed deep into, 100 junction of mineral water water bottle and hydrogen generator ontology Pressure be gradually increased, pellosil 109 generate deformation, the deformation of pellosil 109 drive the pressure-sensitive spring 110 in it generate shape Become, pressure-sensitive spring 110 encounters pressing switch 111 after generating deformation, and the free end of the elastic element of pressing switch 111 generates position It moves, pushes directly on touch controlled key 200, (control of pressing switch 111 is this field skill to the on off operating mode of change touch controlled key 200 Common technical knowledge well known to art personnel, therefore be no longer described in detail), after the disconnection of touch controlled key 200, electrolysis cells 102 are powered off, and electrolysis is single The no longer electrolysis water of member 102, therefore the pressure in the bottle no longer changes, so that mineral water water bottle and hydrogen generator ontology 100 be avoided to connect Connect that hydrogen and oxygen in place's spilling water or mineral water water bottle is excessive and the explosion phenomenon that causes.
Taking the above-mentioned ideal embodiment according to the present invention as inspiration, through the above description, relevant staff is complete Various changes and amendments can be carried out without departing from the scope of the technological thought of the present invention' entirely.The technology of this invention Property range is not limited to the contents of the specification, it is necessary to which the technical scope thereof is determined according to the scope of the claim.

Claims (6)

1. a kind of overturning-preventing Instant hydrogen generator, it is characterised in that: it includes hydrogen generator ontology (100), the system Fluted (101) are set in hydrogen generator ontology (100), the groove (101) is provided with internal screw thread, the internal screw thread and water bottle bottle External screw thread at mouthful matches, and the two is connected through a screw thread integrally;Electrolysis cells (102) are provided in the groove (101), The electrolysis cells (102) form hydrogen and oxygen for electrolysis water, and the electrolysis cells (102) connect touch controlled key (200), The touch controlled key (200) is used to control the opening and closing of the electrolysis cells (102);In the electrolysis cells (102) Hydraulic flow-path tube (106) is arranged in the heart, and the upper surface of described hydraulic flow-path tube (106) is connected to minerals boiling gas stone (107), and the mine Substance boiling gas stone (107) is covered on the electrolysis cells (102), connects hydraulic suction below the hydraulic flow-path tube (106) Disk (108), and the hydraulic sucker (108) setting is external in the hydrogen generator ontology (100);
Pellosil (109) are arranged in the electrolysis cells (102) lower part in the groove (101), the pellosil (109) and institute The setting of electrolysis cells (102) interval is stated, the pressure-sensitive spring (110) of setting, the pressure-sensitive spring (110) in the pellosil (109) It connects pressing switch (111), the pressing switch (111) connects the touch controlled key (200).
2. a kind of overturning-preventing Instant hydrogen generator as described in claim 1, it is characterised in that: the electrolysis cells It (102) include negative electrode tab (103), positive plate (104) and selectivity through film (105), and the selectivity is set through film (105) It sets between the negative electrode tab (103) and the positive plate (104);The negative electrode tab (103) connects power supply for generating hydrogen Cathode;The positive plate (104) connects positive pole, the electrolysis cells (102) are also connected with the touch-control for generating oxygen Key (200).
3. a kind of overturning-preventing Instant hydrogen generator as claimed in claim 2, it is characterised in that: the selectivity penetrates film (105) proton exchange membrane is used.
4. a kind of overturning-preventing Instant hydrogen generator as described in claims 1 or 2 or 3, it is characterised in that: the minerals The shape for boiling gas stone (107) uses hemispherical.
5. a kind of overturning-preventing Instant hydrogen generator as described in claims 1 or 2 or 3, it is characterised in that: the hydrogen manufacturing hair Life sets up several non-slip mats (113) in device ontology (100) week.
6. a kind of overturning-preventing Instant hydrogen generator as claimed in claim 4, it is characterised in that: the hydrogen generator sheet Body (100) week sets up several non-slip mats (113).
CN201710287324.1A 2017-04-27 2017-04-27 A kind of overturning-preventing Instant hydrogen generator Expired - Fee Related CN107034482B (en)

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Citations (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103628083A (en) * 2013-09-29 2014-03-12 孙金良 Multifunctional hydrogen-oxygen separation generator
JP2014118618A (en) * 2012-12-18 2014-06-30 Mitsubishi Heavy Ind Ltd Water electrolytic hydrogen-oxygen energy storage system and method for storing water electrolytic hydrogen-oxygen energy
CN204959046U (en) * 2015-09-16 2016-01-13 李志林 Safe portable multi -functional oxygen hydrogen all -in -one
CN205222762U (en) * 2015-11-25 2016-05-11 周锋 Water treatment device
CN205500867U (en) * 2016-04-20 2016-08-24 深圳市贝利斯科技发展有限公司 Hydrogen hydrogenesis appearance
CN205548215U (en) * 2016-01-26 2016-09-07 福州品行科技发展有限公司 Hydrogen -rich water cup
CN106063664A (en) * 2016-07-29 2016-11-02 南京中脉科技发展有限公司 A kind of sterilization hydrogen-rich water tumbler
CN106073392A (en) * 2016-08-08 2016-11-09 福州品行科技发展有限公司 A kind of hydrogen-rich water tumbler
CN106186207A (en) * 2016-08-08 2016-12-07 广东工业大学 A kind of portable prepares the water tumbler of hydrogen rich water

Patent Citations (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2014118618A (en) * 2012-12-18 2014-06-30 Mitsubishi Heavy Ind Ltd Water electrolytic hydrogen-oxygen energy storage system and method for storing water electrolytic hydrogen-oxygen energy
CN103628083A (en) * 2013-09-29 2014-03-12 孙金良 Multifunctional hydrogen-oxygen separation generator
CN204959046U (en) * 2015-09-16 2016-01-13 李志林 Safe portable multi -functional oxygen hydrogen all -in -one
CN205222762U (en) * 2015-11-25 2016-05-11 周锋 Water treatment device
CN205548215U (en) * 2016-01-26 2016-09-07 福州品行科技发展有限公司 Hydrogen -rich water cup
CN205500867U (en) * 2016-04-20 2016-08-24 深圳市贝利斯科技发展有限公司 Hydrogen hydrogenesis appearance
CN106063664A (en) * 2016-07-29 2016-11-02 南京中脉科技发展有限公司 A kind of sterilization hydrogen-rich water tumbler
CN106073392A (en) * 2016-08-08 2016-11-09 福州品行科技发展有限公司 A kind of hydrogen-rich water tumbler
CN106186207A (en) * 2016-08-08 2016-12-07 广东工业大学 A kind of portable prepares the water tumbler of hydrogen rich water

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Granted publication date: 20190301