CN107034482A - A kind of overturning-preventing Instant hydrogen generator - Google Patents

A kind of overturning-preventing Instant hydrogen generator Download PDF

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Publication number
CN107034482A
CN107034482A CN201710287324.1A CN201710287324A CN107034482A CN 107034482 A CN107034482 A CN 107034482A CN 201710287324 A CN201710287324 A CN 201710287324A CN 107034482 A CN107034482 A CN 107034482A
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CN
China
Prior art keywords
hydrogen
water
hydrogen generator
electrolysis cells
hydraulic pressure
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Application number
CN201710287324.1A
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Chinese (zh)
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CN107034482B (en
Inventor
阮国洪
周陈兴
李永琳
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Fujian Ospring Technology Development Co Ltd
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Fujian Ospring Technology Development Co Ltd
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    • CCHEMISTRY; METALLURGY
    • C25ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25BELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
    • C25B9/00Cells or assemblies of cells; Constructional parts of cells; Assemblies of constructional parts, e.g. electrode-diaphragm assemblies; Process-related cell features
    • C25B9/70Assemblies comprising two or more cells
    • C25B9/73Assemblies comprising two or more cells of the filter-press type
    • CCHEMISTRY; METALLURGY
    • C25ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25BELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
    • C25B1/00Electrolytic production of inorganic compounds or non-metals
    • C25B1/01Products
    • C25B1/02Hydrogen or oxygen
    • C25B1/04Hydrogen or oxygen by electrolysis of water
    • CCHEMISTRY; METALLURGY
    • C25ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25BELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
    • C25B9/00Cells or assemblies of cells; Constructional parts of cells; Assemblies of constructional parts, e.g. electrode-diaphragm assemblies; Process-related cell features
    • CCHEMISTRY; METALLURGY
    • C25ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25BELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
    • C25B9/00Cells or assemblies of cells; Constructional parts of cells; Assemblies of constructional parts, e.g. electrode-diaphragm assemblies; Process-related cell features
    • C25B9/17Cells comprising dimensionally-stable non-movable electrodes; Assemblies of constructional parts thereof
    • C25B9/19Cells comprising dimensionally-stable non-movable electrodes; Assemblies of constructional parts thereof with diaphragms
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/30Hydrogen technology
    • Y02E60/36Hydrogen production from non-carbon containing sources, e.g. by water electrolysis

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Electrochemistry (AREA)
  • Materials Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Electrolytic Production Of Non-Metals, Compounds, Apparatuses Therefor (AREA)

Abstract

The present invention relates to a kind of overturning-preventing Instant hydrogen generator, for solving hydrogen-rich water generator manufacture hydrogen during occur toppling over, the phenomenon of junction spilling water and the problem of easily form blast when hydrogen and many oxygen.Hydrogen generator body most starts to live after adsorption plane using hydraulic pressure sucker suction, go deep into the process of electrolysis cells electrolysis water, produce substantial amounts of hydrogen and oxygen, water in bottle boils gas stone, hydraulic pressure flow-path tube by mineral matter gives hydraulic pressure sucker by pressure transmission, constantly press and give hydraulic pressure sucker so that hydrogen generator body will not produce inclined situation in hydrogen production process to be occurred.In view of above reason, present invention can be widely used to hydrogen rich water manufacture field.

Description

A kind of overturning-preventing Instant hydrogen generator
Technical field
Field is manufactured the present invention relates to hydrogen rich water, especially with regard to a kind of overturning-preventing Instant hydrogen generator.
Background technology
Hydrogen is a kind of colourless, tasteless, nontoxic and odorless gas.The peculiar property of hydrogen, determines hydrogen in biology On have many advantages.The primary efficacy of hydrogen is:Anti-oxidant, as a kind of selective polyphenoils, hydrogen is to many diseases With therapeutic action, be widely used prospect.
Hydrogen rich water, as the term suggests it is exactly the water rich in hydrogen.English is hydrogenRich water, and Japanese is " water element Water ".In recent years, the plain aquatic products of hydrogen rich water, water are gradually more on domestic market, and the cup and manufacture device of the plain water of hydrogen rich water, water also have Finding, wherein occupying significant proportion using the technology of electrolytic hydrogen production.
Particularly Chinese invention:A kind of portable hydrogen-rich water generator CN204873955U, the invention connects cushion On the housing for being connected on hydrogen-rich water generator, make the tank house and water bottle internal combustion of hydrogen-rich water generator and form sealing space. But, when this device carries out water electrolysis, produced hydrogen, oxygen rise, and most of hydrogen or oxygen gas includes bottle handstand When and a small amount of air for bringing into can be deposited in the closed cavity of water bottle top, when air pressure is higher, hydrogen or oxygen gas will be hindered Produce, so that water electrolysis eases up or even stopped.This reason chemically can be understood in equation:H2O → H2 ↑+O2 ↑, work as generation When gas can not be exported, chemical reaction would not be carried out to product direction.
And during hydrogen-rich water generator manufacture hydrogen, with the lifting of air pressure in water bottle, easily pressure is excessive in bottle, Easily produce following two aspect problems:
1) all it is to turn hydrogen manufacturing around due to generally, the water that thus be accordingly used in water bottle is in upper, formation " top-heavy ", hydrogen manufacturing Easily topple in journey;
2) phenomenon of hydrogen generator and water bottle junction spilling water;
3) hydrogen and easily explode when many oxygen.
The content of the invention
The technical problem to be solved in the present invention is:In order to solve process of the hydrogen-rich water generator in manufacture hydrogen in the prior art It is middle occur toppling over, the phenomenon of junction spilling water and the problem of easily form blast when hydrogen and many oxygen, the present invention is carried Solved the above problems for a kind of overturning-preventing Instant hydrogen generator.
The technical solution adopted for the present invention to solve the technical problems is:A kind of overturning-preventing Instant hydrogen generator, its It is characterised by:It includes being provided with groove in hydrogen generator body, the hydrogen generator body, and the groove is provided with interior Screw thread, the internal thread is engaged with the external screw thread of water bottle bottle mouth position, and the two is connected through a screw thread integrally;Set in the groove There are electrolysis cells, the electrolysis cells are used for electrolysis water formation hydrogen and oxygen, and the electrolysis cells connect touch controlled key, described Touch controlled key is used for the opening and closing for controlling the electrolysis cells;The centrally disposed hydraulic pressure flow-path tube of the electrolysis cells, institute State and mineral matter boiling gas stone is connected above hydraulic pressure flow-path tube, and mineral matter boiling gas stone is covered on the electrolysis cells, institute Connection hydraulic pressure sucker below hydraulic pressure flow-path tube is stated, and the hydraulic pressure sucker is arranged on the hydrogen generator body exterior;Institute State the electrolysis cells bottom in groove and pellosil is set, the pellosil is arranged at intervals with the electrolysis cells, the silicon Pressure-sensitive spring is set in glued membrane, and the pressure-sensitive spring connection pressing switch, the pressing switch connects the touch controlled key.
The electrolysis cells include negative plate, positive plate and selectivity and pass through film, and the selectivity is arranged on through film Between the negative plate and the positive plate;The negative plate is used to produce hydrogen, connects power cathode;The positive plate is used for Oxygen is produced, positive source is connected, the electrolysis cells are also connected with the touch controlled key.
The selectivity uses PEM through film.
The shape of the mineral matter boiling gas stone uses hemispherical.
The hydrogen generator body week sets up some slipmat.
The beneficial effects of the invention are as follows:The lid of mineral water water bottle is turned on, rotation hydrogen generator body or mineral spring Water water bottle so that be connected through a screw thread between the internal thread in the external screw thread and groove of mineral water water bottle bottle mouth position, realize mineral spring Water water bottle links into an integrated entity with hydrogen generator body;The on & off switch on electric-controlled plate is pressed, touch controlled key control is electrolysis cells Power supply, so that battery starts to power for electrolysis cells.Electrolysis cells start electrolysis water:Negative plate connection -7V electricity, positive plate connects + 7V electricity is connect, negative plate electrolysis water produces hydrogen, and the hydrogen is minute bubbles, can largely be well soluble in water, and small part enters There is no the part of water in mineral water water bottle;Proton enters positive plate by selectivity through film, forms electric current, positive plate electrolysis water Oxygen is produced, the air pocket of generation enters in mineral water water bottle, does not have the part of water into mineral water water bottle.The oxygen of manufacture Gas stone is boiled by the mineral matter set thereon with hydrogen, mineral matter boiling gas stone not only resolves into hydrogen and oxygen in smaller gas Bubble, to be dissolved in water rapidly;And the accessory substance in water is eliminated and mineral matter is added into water, that is, oxidizing substance is eliminated, Such as chlorine residue or ozone, so as to reach double effectses;Hydrogen generator body and mineral water water bottle are inverted, hydraulic pressure sucker suction On surface to be adsorbed.Conventional sucker in absorption most starts that the air discharge between sucker and adsorption plane firmly is presented into vacuum State, so as to complete the absorption between sucker and adsorption plane.However, passing through long period, week of the air from sucker after absorption Enclose between sucker and adsorption plane, so as to cause to separate between sucker and adsorption plane.But hydrogen generator body most starts Lived using hydraulic pressure sucker suction after adsorption plane, go deep into the process of electrolysis cells electrolysis water, produce substantial amounts of hydrogen and oxygen Water in gas, bottle boils gas stone, hydraulic pressure flow-path tube by mineral matter gives hydraulic pressure sucker by pressure transmission, i.e., constantly press and inhaled to hydraulic pressure Disk so that hydrogen generator body will not produce inclined situation in hydrogen production process to be occurred.With electrolysis cells electrolysis water Process is goed deep into, and the pressure of mineral water water bottle and hydrogen generator body junction gradually increases, and pellosil produces deformation, pellosil Deformation drive pressure-sensitive spring in it to produce deformation, pressure-sensitive spring encounters pressing switch after producing deformation, pressing switch The free end of flexible member produces displacement, pushes directly on touch controlled key, changes the on off operating mode of touch controlled key, touch controlled key it is disconnected After opening, electrolysis cells are powered off, electrolysis cells no longer electrolysis water, therefore the pressure in the bottle no longer changes, so as to avoid mineral water water The explosion phenomenon that hydrogen and oxygen excessively trigger in bottle and hydrogen generator body junction spilling water or mineral water water bottle.Mirror In above reason, hydrogen rich water manufacture field present invention can be widely used to.
Brief description of the drawings
The present invention is further described with reference to the accompanying drawings and examples.
Fig. 1 is the top view of the present invention;
Fig. 2 is the side view of the present invention.
Embodiment
In conjunction with the accompanying drawings, the present invention is further explained in detail.These accompanying drawings are simplified schematic diagram, only with Illustration illustrates the basic structure of the present invention, therefore it only shows the composition relevant with the present invention.
As depicted in figs. 1 and 2, the present invention includes being provided with hydrogen generator body 100, hydrogen generator body 100 Groove 101, the groove 101 is provided with internal thread, and the internal thread is engaged with the external screw thread of water bottle bottle mouth position, and the two passes through screw thread Link into an integrated entity.Above-mentioned water bottle generally uses common mineral water water bottle.
Electrolysis cells 102 are provided with groove 101, electrolysis cells 102 include negative plate 103, positive plate 104 and selectivity Through film 105, and selectively it is arranged on through film 105 between negative plate 103 and positive plate 104, for passing through therebetween Proton, so as to form electric current.Negative plate 103 is used for the hydrogen for producing minute bubbles, and the hydrogen of minute bubbles is dissolved in water, is arranged on Side, connection power cathode (being usually -7V);Positive plate 104 is used for the oxygen for producing air pocket, and the oxygen of air pocket is not dissolved in Water, is arranged below, connection positive source (being usually+7V), and electrolysis cells 102 are also connected with touch controlled key 200, touch controlled key 200 opening and closing for controlling electrolysis cells 102.
In above-described embodiment, selectivity uses PEM through film 105.
Mineral matter boiling gas is connected above the centrally disposed hydraulic pressure flow-path tube 106 of electrolysis cells 102, hydraulic pressure flow-path tube 106 Stone 107, and mineral matter boiling gas stone 107 is covered on electrolysis cells 102.Hydraulic pressure sucker is connected below hydraulic pressure flow-path tube 106 108, and hydraulic pressure sucker 108 is arranged on outside hydrogen generator body 100.Above-mentioned hydraulic pressure sucker 108 uses common sucker, Do not limit herein.
In above-described embodiment, the shape of mineral matter boiling gas stone 107 can use including but not limited to hemispherical, and preferably ore deposit The diameter of material boiling gas stone 107 is equal with the diameter of electrolysis cells 102.Mineral matter boiling gas stone 107 is the gas made using mineral matter Afrodite, it is existing product, therefore is no longer described in detail.
Pellosil 109 is arranged on the bottom of electrolysis cells 102 in groove 101, and between pellosil 109 and electrolysis cells 102 Every setting pressure-sensitive spring 110 in setting, pellosil 109, pressure-sensitive spring 110 connects pressing switch 111, and pressing switch 111 is connected Touch controlled key 200.
Touch controlled key 200 is used for the energization or power-off for controlling electrolysis cells 102.Touch controlled key 200 connects electricity by circuit Control plate 300.Electric-controlled plate 300 uses contact panel, and finger is pressed to the on & off switch on electric-controlled plate 300, forms point electric capacity, you can Complete ON/OFF process (this process is consistent with the switching process on electromagnetic oven, and it is prior art, therefore is no longer described in detail).Touch-control is pressed Key 200 connects electrolysis cells 102, so that battery starts to power for electrolysis cells 102.Electric-controlled plate 300 is also connected with battery (figure Not shown in), think that electric-controlled plate and electrolysis cells 102 are powered.Charging hole 112 is also set up on hydrogen generator body 100, so as to It is battery charging when no electric.
Some slipmat 113 are also set up in the surface circumference of hydrogen generator body 100, slipmat 113 uses at least four Individual contour small column, to prevent being showed due to the movement that the plane where the present invention is wet and slippery or excessively smooth frictional force is not enough caused As.
By taking the aquatic production hydrogen rich water in common mineral water water bottle as an example, during present invention work:
1) lid of mineral water water bottle is turned on, rotation hydrogen generator body 100 or mineral water water bottle so that mineral spring It is connected through a screw thread between internal thread in the external screw thread and groove 101 of water water bottle bottle mouth position, realizes mineral water water bottle and hydrogen manufacturing Generator body 100 links into an integrated entity;
2) on & off switch on electric-controlled plate 300 is pressed, the control of touch controlled key 200 is powered for electrolysis cells 102, so that battery Start to power for electrolysis cells 102.Electrolysis cells 102 start electrolysis water:Negative plate 103 connects -7V electricity, and positive plate 104 connects+ 7V electricity, the electrolysis water of negative plate 103 produces hydrogen, and the hydrogen is minute bubbles, can largely be well soluble in water, and small part enters There is no the part of water in mineral water water bottle;Proton enters positive plate 104 by selectivity through film 105, forms electric current, positive plate 104 electrolysis waters produce oxygen, and the air pocket of generation enters in mineral water water bottle, does not have the part of water into mineral water water bottle;
The oxygen and hydrogen of manufacture boil gas stone 107 by the mineral matter set thereon, and mineral matter boils gas stone 107 not only by hydrogen Gas and oxygen resolve into smaller bubble, to be dissolved in water rapidly;And the accessory substance in water is eliminated and ore deposit is added into water Material, that is, eliminate oxidizing substance, such as chlorine residue or ozone, so as to reach double effectses;
3) hydrogen generator body 100 and mineral water water bottle are inverted, hydraulic pressure sucker 108 is adsorbed on surface to be adsorbed.Often Sucker is advised in absorption, most starts that the air discharge between sucker and adsorption plane firmly is presented into vacuum state, so as to complete to inhale Absorption between disk and adsorption plane.However, passing through the long period after absorption, air enters sucker and absorption around sucker Between face, so as to cause to separate between sucker and adsorption plane.But hydrogen generator body 100 most starts to use hydraulic pressure sucker After 108 adsorb adsorption plane, go deep into the process of the electrolysis water of electrolysis cells 102, produce in substantial amounts of hydrogen and oxygen, bottle Water gas stone 107, hydraulic pressure flow-path tube 106 are boiled by mineral matter pressure transmission to hydraulic pressure sucker 108, i.e., constantly press to hydraulic pressure Sucker 108 so that hydrogen generator body 100 will not produce inclined situation in hydrogen production process to be occurred.
4) go deep into the process of the electrolysis water of electrolysis cells 102, mineral water water bottle and the junction of hydrogen generator body 100 Pressure gradually increase, pellosil 109 produces deformation, and the deformation of pellosil 109 drives the pressure-sensitive spring 110 in it to produce shape Become, pressure-sensitive spring 110 encounters pressing switch 111 after producing deformation, and the free end of the flexible member of pressing switch 111 produces position Move, push directly on touch controlled key 200, (control of pressing switch 111 is this area skill to the on off operating mode of change touch controlled key 200 Common technical knowledge known to art personnel, therefore be no longer described in detail), after the disconnection of touch controlled key 200, electrolysis cells 102 are powered off, and electrolysis is single The no longer electrolysis water of member 102, therefore the pressure in the bottle no longer changes, so as to avoid mineral water water bottle and hydrogen generator body 100 from connecting Connect the explosion phenomenon that hydrogen and oxygen excessively trigger in place's spilling water or mineral water water bottle.
Using the above-mentioned desirable embodiment according to the present invention as enlightenment, by above-mentioned description, relevant staff is complete Various changes and amendments can be carried out without departing from the scope of the technological thought of the present invention' entirely.The technology of this invention Property scope is not limited to the content on specification, it is necessary to its technical scope is determined according to right.

Claims (6)

1. a kind of overturning-preventing Instant hydrogen generator, it is characterised in that:It includes hydrogen generator body (100), the system Fluted (101) are set in hydrogen generator body (100), the groove (101) is provided with internal thread, the internal thread and water bottle bottle External screw thread at mouthful is engaged, and the two is connected through a screw thread integrally;Electrolysis cells (102) are provided with the groove (101), The electrolysis cells (102) are used for electrolysis water formation hydrogen and oxygen, and the electrolysis cells (102) connect touch controlled key (200), The touch controlled key (200) is used for the opening and closing for controlling the electrolysis cells (102);In the electrolysis cells (102) The heart sets connection mineral matter boiling gas stone (107) above hydraulic pressure flow-path tube (106), the hydraulic pressure flow-path tube (106), and the ore deposit Material boiling gas stone (107) is covered on the electrolysis cells (102), and hydraulic pressure is connected below the hydraulic pressure flow-path tube (106) and is inhaled Disk (108), and the hydraulic pressure sucker (108) is arranged on hydrogen generator body (100) outside;
The electrolysis cells (102) bottom in the groove (101) sets pellosil (109), the pellosil (109) and institute State in electrolysis cells (102) interval setting, the pellosil (109) and pressure-sensitive spring (109), the pressure-sensitive spring (109) are set Pressing switch (110) is connected, the pressing switch (110) connects the touch controlled key (200).
2. a kind of overturning-preventing Instant hydrogen generator as claimed in claim 1, it is characterised in that:The electrolysis cells (102) include negative plate (103), positive plate (104) and selectivity to set through film (105) through film (105), and the selectivity Put between the negative plate (103) and the positive plate (104);The negative plate (103) is used to produce hydrogen, connects power supply Negative pole;The positive plate (104) is used to produce oxygen, connects positive source, and the electrolysis cells (102) are also connected with the touch-control Button (200).
3. a kind of overturning-preventing Instant hydrogen generator as claimed in claim 2, it is characterised in that:The selectivity passes through film (105) PEM is used.
4. a kind of overturning-preventing Instant hydrogen generator as described in claim 1 or 2 or 3, it is characterised in that:The mineral matter The shape of boiling gas stone (107) uses hemispherical.
5. a kind of overturning-preventing Instant hydrogen generator as described in claim 1 or 2 or 3, it is characterised in that:The hydrogen manufacturing hair Life sets up some slipmat (113) in device body (100) week.
6. a kind of overturning-preventing Instant hydrogen generator as claimed in claim 4, it is characterised in that:The hydrogen generator sheet Body (100) week sets up some slipmat (113).
CN201710287324.1A 2017-04-27 2017-04-27 A kind of overturning-preventing Instant hydrogen generator Expired - Fee Related CN107034482B (en)

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Citations (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103628083A (en) * 2013-09-29 2014-03-12 孙金良 Multifunctional hydrogen-oxygen separation generator
JP2014118618A (en) * 2012-12-18 2014-06-30 Mitsubishi Heavy Ind Ltd Water electrolytic hydrogen-oxygen energy storage system and method for storing water electrolytic hydrogen-oxygen energy
CN204959046U (en) * 2015-09-16 2016-01-13 李志林 Safe portable multi -functional oxygen hydrogen all -in -one
CN205222762U (en) * 2015-11-25 2016-05-11 周锋 Water treatment device
CN205500867U (en) * 2016-04-20 2016-08-24 深圳市贝利斯科技发展有限公司 Hydrogen hydrogenesis appearance
CN205548215U (en) * 2016-01-26 2016-09-07 福州品行科技发展有限公司 Hydrogen -rich water cup
CN106063664A (en) * 2016-07-29 2016-11-02 南京中脉科技发展有限公司 A kind of sterilization hydrogen-rich water tumbler
CN106073392A (en) * 2016-08-08 2016-11-09 福州品行科技发展有限公司 A kind of hydrogen-rich water tumbler
CN106186207A (en) * 2016-08-08 2016-12-07 广东工业大学 A kind of portable prepares the water tumbler of hydrogen rich water

Patent Citations (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2014118618A (en) * 2012-12-18 2014-06-30 Mitsubishi Heavy Ind Ltd Water electrolytic hydrogen-oxygen energy storage system and method for storing water electrolytic hydrogen-oxygen energy
CN103628083A (en) * 2013-09-29 2014-03-12 孙金良 Multifunctional hydrogen-oxygen separation generator
CN204959046U (en) * 2015-09-16 2016-01-13 李志林 Safe portable multi -functional oxygen hydrogen all -in -one
CN205222762U (en) * 2015-11-25 2016-05-11 周锋 Water treatment device
CN205548215U (en) * 2016-01-26 2016-09-07 福州品行科技发展有限公司 Hydrogen -rich water cup
CN205500867U (en) * 2016-04-20 2016-08-24 深圳市贝利斯科技发展有限公司 Hydrogen hydrogenesis appearance
CN106063664A (en) * 2016-07-29 2016-11-02 南京中脉科技发展有限公司 A kind of sterilization hydrogen-rich water tumbler
CN106073392A (en) * 2016-08-08 2016-11-09 福州品行科技发展有限公司 A kind of hydrogen-rich water tumbler
CN106186207A (en) * 2016-08-08 2016-12-07 广东工业大学 A kind of portable prepares the water tumbler of hydrogen rich water

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