CN107033728A - A kind of environmental protection coating material and preparation method thereof - Google Patents
A kind of environmental protection coating material and preparation method thereof Download PDFInfo
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- CN107033728A CN107033728A CN201710414473.XA CN201710414473A CN107033728A CN 107033728 A CN107033728 A CN 107033728A CN 201710414473 A CN201710414473 A CN 201710414473A CN 107033728 A CN107033728 A CN 107033728A
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- C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
- C08F220/10—Esters
- C08F220/12—Esters of monohydric alcohols or phenols
- C08F220/16—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms
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Abstract
The invention discloses a kind of environmental protection coating material, include the raw material of following parts by weight:15~35 parts of acrylonitrile, 13~24 parts of siloxanes, 15~35 parts of ethyl acrylate, 5~12 parts of aromatic hydrocarbons, 0.5~1.5 part of neopelex, 0.5~1.5 part of octylphenol ethoxylate, 0.3~0.8 part of ammonium persulfate, 1~2 part of ultra-violet absorber, 4~7 parts of plant extraction liquid, 5~8 parts of reactive diluent, 1~2 part of platinum catalyst, 0.1~0.5 part of Nano Silver powder, 13~18 parts of deionized water.The environmental protection coating material waterproof, favorable anti-corrosion effect, and with good anti-microbial property, be adapted to promote.
Description
Technical field
The invention belongs to building material technical field, and in particular to a kind of environmental protection coating material and preparation method thereof.
Background technology
There is building coating decoration functions, defencive function and livability to improve function.Proportion shared by various functions is because making
It is not quite similar with purpose difference.The function for the appearance value that decoration functions are the beautifications by building to improve it.Mainly
Design design and the design of three-dimensional pattern design in terms of including plane color, pattern and gloss.But will be with building in itself
The size and shape of moulding and base material in itself is engaged, and just can fully play out.Defencive function refers to protect building not
Protected from environmental and destruction function.Different types of content required by protective defencive function is also different.Such as
It is indoor just very big with index difference that is being reached required by outdoor application.Some buildings are to mould proof, fire prevention, insulation, corrosion resistant
Erosion etc. has particular/special requirement.Livability improves function mainly for indoor application, just contributes to improve the work(of living environment
Can, such as sound-proofing, sound absorption properties, anti-condensation.
Water-repellent paint and anticorrosive paint are broadly divided into architectural used coating, respectively with waterproof, seepage control and anti-corrosion
Function.In actual applications, often need dope layer that there is waterproof and corrosion-resistant function simultaneously.
The content of the invention
The invention provides a kind of environmental protection coating material and preparation method thereof, the environmental protection coating material waterproof, favorable anti-corrosion effect, and
With good anti-microbial property, it is adapted to promote, the preparation method is simple, pollution-free, energy-conserving and environment-protective.
In order to solve the problem of prior art is present, adopt the following technical scheme that:
A kind of environmental protection coating material, includes the raw material of following parts by weight:15~35 parts of acrylonitrile, 13~24 parts of siloxanes, acrylic acid second
15~35 parts of ester, 5~12 parts of aromatic hydrocarbons, 0.5~1.5 part of neopelex, octyl phenol ethoxylation
0.5~1.5 part of thing, 0.3~0.8 part of ammonium persulfate, 1~2 part of ultra-violet absorber, 4~7 parts of plant extraction liquid, activity dilution
5~8 parts of agent, 1~2 part of platinum catalyst, 0.1~0.5 part of Nano Silver powder, 13~18 parts of deionized water.
It is preferred that, the environmental protection coating material includes the raw material of following parts by weight:20~27 parts of acrylonitrile, siloxanes 18~22
Part, 22~28 parts of ethyl acrylate, 7~9 parts of aromatic hydrocarbons, 0.8~1.2 part of neopelex, octyl group
0.7~0.9 part of phenol ethoxylate, 0.5~0.7 part of ammonium persulfate, 1.3~1.6 parts of ultra-violet absorber, plant extraction liquid 5
~6 parts, 6~7.3 parts of reactive diluent, 1.1~1.3 parts of platinum catalyst, 0.2~0.4 part of Nano Silver powder, deionized water 15~
17 parts.
It is preferred that, the environmental protection coating material includes the raw material of following parts by weight:23 parts of acrylonitrile, 19 parts of siloxanes, acrylic acid
25 parts of ethyl ester, 8 parts of aromatic hydrocarbons, 0.9 part of neopelex, 0.8 part of octylphenol ethoxylate, over cure
Sour 0.6 part of ammonium, 1.5 parts of ultra-violet absorber, 5.6 parts of plant extraction liquid, 6.9 parts of reactive diluent, 1.2 parts of platinum catalyst, receive
0.3 part of silver powder of rice, 16 parts of deionized water.
It is preferred that, Nano Silver powder is Nano Silver more than 1000 mesh.
It is preferred that, the plant extraction liquid is the mixed liquor of golden cypress, corter pseudolaricis and the root bark of shaggy-fruited dittany.
It is preferred that, the ratio of the golden cypress, corter pseudolaricis and the root bark of shaggy-fruited dittany is 2:2:5.
A kind of method for preparing the environmental protection coating material, comprises the following steps:
(1)Acrylonitrile, siloxanes, ethyl acrylate, aromatic hydrocarbons, DBSA are weighed by above-mentioned formula
Sodium, octylphenol ethoxylate, ammonium persulfate, ultra-violet absorber, plant extraction liquid, reactive diluent, platinum catalyst, nanometer
Silver powder, deionized water, it is standby;
(2)Neopelex, octylphenol ethoxylate, ammonium persulfate and deionized water are placed in high speed dispersor
It is scattered 1~2 hour, obtain sodium dodecyl benzene sulfonate aqueous solution;
(3)By step(2)Obtained sodium dodecyl benzene sulfonate aqueous solution is placed in reactor, and addition propylene is fine, is warming up to 60
~80 DEG C, 40~50min is stirred, polymer A is obtained;
(4)To step(3)Ethyl acrylate is added in obtained polymer A, insulation reaction 1.5~2.5 hours obtains polymer B;
(5)Siloxanes is placed in reactor, aromatic hydrocarbons is added, platinum catalyst is added, reacts 2~3 hours, obtains
Polymer C;
(6)To step(5)Polymer B is added in obtained polymer C, is placed in high speed dispersor and disperses 20~30 minutes, mistake
Filter, reserved filtrate obtains polymer D;
(7)Ultra-violet absorber, plant extraction liquid, reactive diluent, Nano Silver powder are added into polymer D, ultrasound is placed in
Disperse 30~50 minutes in instrument, you can obtain the environmental protection coating material.
It is preferred that, the rotating speed of the high speed dispersor is 800~1200r/min.
Compared with prior art, it has the advantages that the present invention:
Environmental protection coating material waterproof of the present invention, favorable anti-corrosion effect, and with good anti-microbial property, be adapted to promote, it is described
Preparation method is simple, and pollution-free, energy-conserving and environment-protective are specific as follows:
(1)Environmental protection coating material of the present invention using neopelex, octylphenol ethoxylate, ammonium persulfate and,
Propylene is fine, ethyl acrylate as raw material, the neopelex, octylphenol ethoxylate, ammonium persulfate and, third
Alkene is fine, obtain that product resistance to acids and bases is relatively good after ethyl acrylate polymerisation, improves the corrosion resistance of the environmental protection coating material;
(2)Environmental protection coating material of the present invention adds siloxanes and aromatic hydrocarbons, aromatic hydrocarbons pair
Siloxanes is modified, and obtained product waterproof property is relatively good, improves the water proofing property of the environmental protection coating material;
(3)Environmental protection coating material of the present invention adds Nano Silver powder and plant extraction liquid, improves the environmental protection coating material
Water proofing property;
(4)Preparation method of the present invention, process is simple, pollution-free, can environmental protection, suitable popularization.
Embodiment
With reference to specific embodiment, the present invention is expanded on further.These embodiments be merely to illustrate the present invention and without
In limitation the scope of the present invention.
Embodiment 1
The present embodiment is related to a kind of environmental protection coating material, includes the raw material of following parts by weight:15 parts of acrylonitrile, 13 parts of siloxanes, propylene
15 parts of acetoacetic ester, 5 parts of aromatic hydrocarbons, 0.5 part of neopelex, 0.5 part of octylphenol ethoxylate, mistake
0.3 part of ammonium sulfate, 1 part of ultra-violet absorber, 4 parts of plant extraction liquid, 5 parts of reactive diluent, 1 part of platinum catalyst, nano-silver powder
Last 0.1 part, 13 parts of deionized water.
Wherein, Nano Silver powder is Nano Silver more than 1000 mesh.
Wherein, the plant extraction liquid is the mixed liquor of golden cypress, corter pseudolaricis and the root bark of shaggy-fruited dittany, the golden cypress, corter pseudolaricis and white
The ratio of fresh hide is 2:2:5.
A kind of method for preparing the environmental protection coating material, comprises the following steps:
(1)Acrylonitrile, siloxanes, ethyl acrylate, aromatic hydrocarbons, DBSA are weighed by above-mentioned formula
Sodium, octylphenol ethoxylate, ammonium persulfate, ultra-violet absorber, plant extraction liquid, reactive diluent, platinum catalyst, nanometer
Silver powder, deionized water, it is standby;
(2)Neopelex, octylphenol ethoxylate, ammonium persulfate and deionized water are placed in high speed dispersor
It is scattered 1 hour, obtain sodium dodecyl benzene sulfonate aqueous solution;
(3)By step(2)Obtained sodium dodecyl benzene sulfonate aqueous solution is placed in reactor, and addition propylene is fine, is warming up to 60
DEG C, 40min is stirred, polymer A is obtained;
(4)To step(3)Ethyl acrylate is added in obtained polymer A, insulation reaction 1.5 hours obtains polymer B;
(5)Siloxanes is placed in reactor, aromatic hydrocarbons is added, platinum catalyst is added, reacts 2 hours, obtains poly-
Compound C;
(6)To step(5)Polymer B is added in obtained polymer C, is placed in high speed dispersor and disperses 20 minutes, filtering is stayed
Filtrate, obtains polymer D;
(7)Ultra-violet absorber, plant extraction liquid, reactive diluent, Nano Silver powder are added into polymer D, ultrasound is placed in
Disperse 30 minutes in instrument, you can obtain the environmental protection coating material.
Wherein, the rotating speed of high speed dispersor is 800r/min.
Embodiment 2
The present embodiment is related to a kind of environmental protection coating material, includes the raw material of following parts by weight:35 parts of acrylonitrile, 24 parts of siloxanes, propylene
35 parts of acetoacetic ester, 12 parts of aromatic hydrocarbons, 1.5 parts of neopelex, 1.5 parts of octylphenol ethoxylate,
0.8 part of ammonium persulfate, 2 parts of ultra-violet absorber, 7 parts of plant extraction liquid, 8 parts of reactive diluent, 2 parts of platinum catalyst, Nano Silver
0.5 part of powder, 18 parts of deionized water.
Wherein, Nano Silver powder is Nano Silver more than 1000 mesh.
Wherein, the plant extraction liquid is the mixed liquor of golden cypress, corter pseudolaricis and the root bark of shaggy-fruited dittany, the golden cypress, corter pseudolaricis and white
The ratio of fresh hide is 2:2:5.
A kind of method for preparing the environmental protection coating material, comprises the following steps:
(1)Acrylonitrile, siloxanes, ethyl acrylate, aromatic hydrocarbons, DBSA are weighed by above-mentioned formula
Sodium, octylphenol ethoxylate, ammonium persulfate, ultra-violet absorber, plant extraction liquid, reactive diluent, platinum catalyst, nanometer
Silver powder, deionized water, it is standby;
(2)Neopelex, octylphenol ethoxylate, ammonium persulfate and deionized water are placed in high speed dispersor
It is scattered 2 hours, obtain sodium dodecyl benzene sulfonate aqueous solution;
(3)By step(2)Obtained sodium dodecyl benzene sulfonate aqueous solution is placed in reactor, and addition propylene is fine, is warming up to 80
DEG C, 50min is stirred, polymer A is obtained;
(4)To step(3)Ethyl acrylate is added in obtained polymer A, insulation reaction 2.5 hours obtains polymer B;
(5)Siloxanes is placed in reactor, aromatic hydrocarbons is added, platinum catalyst is added, reacts 3 hours, obtains poly-
Compound C;
(6)To step(5)Polymer B is added in obtained polymer C, is placed in high speed dispersor and disperses 30 minutes, filtering is stayed
Filtrate, obtains polymer D;
(7)Ultra-violet absorber, plant extraction liquid, reactive diluent, Nano Silver powder are added into polymer D, ultrasound is placed in
Disperse 50 minutes in instrument, you can obtain the environmental protection coating material.
Wherein, the rotating speed of high speed dispersor is 1200r/min.
Embodiment 3
The present embodiment is related to a kind of environmental protection coating material, includes the raw material of following parts by weight:20 parts of acrylonitrile, 18 parts of siloxanes, propylene
22 parts of acetoacetic ester, 7 parts of aromatic hydrocarbons, 0.8 part of neopelex, 0.7 part of octylphenol ethoxylate, mistake
0.5 part of ammonium sulfate, 1.3 parts of ultra-violet absorber, 5 parts of plant extraction liquid, 6 parts of reactive diluent, platinum catalyst 1.1 part, nanometer
0.2 part of silver powder, 15 parts of deionized water.
Wherein, Nano Silver powder is Nano Silver more than 1000 mesh.
Wherein, the plant extraction liquid is the mixed liquor of golden cypress, corter pseudolaricis and the root bark of shaggy-fruited dittany, the golden cypress, corter pseudolaricis and white
The ratio of fresh hide is 2:2:5.
A kind of method for preparing the environmental protection coating material, comprises the following steps:
(1)Acrylonitrile, siloxanes, ethyl acrylate, aromatic hydrocarbons, DBSA are weighed by above-mentioned formula
Sodium, octylphenol ethoxylate, ammonium persulfate, ultra-violet absorber, plant extraction liquid, reactive diluent, platinum catalyst, nanometer
Silver powder, deionized water, it is standby;
(2)Neopelex, octylphenol ethoxylate, ammonium persulfate and deionized water are placed in high speed dispersor
It is scattered 1.5 hours, obtain sodium dodecyl benzene sulfonate aqueous solution;
(3)By step(2)Obtained sodium dodecyl benzene sulfonate aqueous solution is placed in reactor, and addition propylene is fine, is warming up to 70
DEG C, 45min is stirred, polymer A is obtained;
(4)To step(3)Ethyl acrylate is added in obtained polymer A, insulation reaction 2 hours obtains polymer B;
(5)Siloxanes is placed in reactor, aromatic hydrocarbons is added, platinum catalyst is added, reacts 2.5 hours, obtains
Polymer C;
(6)To step(5)Polymer B is added in obtained polymer C, is placed in high speed dispersor and disperses 25 minutes, filtering is stayed
Filtrate, obtains polymer D;
(7)Ultra-violet absorber, plant extraction liquid, reactive diluent, Nano Silver powder are added into polymer D, ultrasound is placed in
Disperse 40 minutes in instrument, you can obtain the environmental protection coating material.
Wherein, the rotating speed of high speed dispersor is 1000r/min.
Embodiment 4
The present embodiment is related to a kind of environmental protection coating material, includes the raw material of following parts by weight:27 parts of acrylonitrile, 22 parts of siloxanes, propylene
28 parts of acetoacetic ester, 9 parts of aromatic hydrocarbons, 1.2 parts of neopelex, 0.9 part of octylphenol ethoxylate, mistake
0.7 part of ammonium sulfate, 1.6 parts of ultra-violet absorber, 6 parts of plant extraction liquid, 7.3 parts of reactive diluent, 1.3 parts of platinum catalyst, receive
0.4 part of silver powder of rice, 17 parts of deionized water.
Wherein, Nano Silver powder is Nano Silver more than 1000 mesh.
Wherein, the plant extraction liquid is the mixed liquor of golden cypress, corter pseudolaricis and the root bark of shaggy-fruited dittany, the golden cypress, corter pseudolaricis and white
The ratio of fresh hide is 2:2:5.
A kind of method for preparing the environmental protection coating material, comprises the following steps:
(1)Acrylonitrile, siloxanes, ethyl acrylate, aromatic hydrocarbons, DBSA are weighed by above-mentioned formula
Sodium, octylphenol ethoxylate, ammonium persulfate, ultra-violet absorber, plant extraction liquid, reactive diluent, platinum catalyst, nanometer
Silver powder, deionized water, it is standby;
(2)Neopelex, octylphenol ethoxylate, ammonium persulfate and deionized water are placed in high speed dispersor
It is scattered 1.2 hours, obtain sodium dodecyl benzene sulfonate aqueous solution;
(3)By step(2)Obtained sodium dodecyl benzene sulfonate aqueous solution is placed in reactor, and addition propylene is fine, is warming up to 65
DEG C, 40min is stirred, polymer A is obtained;
(4)To step(3)Ethyl acrylate is added in obtained polymer A, insulation reaction 1.8 hours obtains polymer B;
(5)Siloxanes is placed in reactor, aromatic hydrocarbons is added, platinum catalyst is added, reacts 2.3 hours, obtains
Polymer C;
(6)To step(5)Polymer B is added in obtained polymer C, is placed in high speed dispersor and disperses 28 minutes, filtering is stayed
Filtrate, obtains polymer D;
(7)Ultra-violet absorber, plant extraction liquid, reactive diluent, Nano Silver powder are added into polymer D, ultrasound is placed in
Disperse 35 minutes in instrument, you can obtain the environmental protection coating material.
Wherein, the rotating speed of high speed dispersor is 900r/min.
Embodiment 5
The present embodiment is related to a kind of environmental protection coating material, includes the raw material of following parts by weight:23 parts of acrylonitrile, 19 parts of siloxanes, propylene
25 parts of acetoacetic ester, 8 parts of aromatic hydrocarbons, 0.9 part of neopelex, 0.8 part of octylphenol ethoxylate, mistake
0.6 part of ammonium sulfate, 1.5 parts of ultra-violet absorber, 5.6 parts of plant extraction liquid, 6.9 parts of reactive diluent, 1.2 parts of platinum catalyst,
0.3 part of Nano Silver powder, 16 parts of deionized water.
Wherein, Nano Silver powder is Nano Silver more than 1000 mesh.
Wherein, the plant extraction liquid is the mixed liquor of golden cypress, corter pseudolaricis and the root bark of shaggy-fruited dittany, the golden cypress, corter pseudolaricis and white
The ratio of fresh hide is 2:2:5.
A kind of method for preparing the environmental protection coating material, comprises the following steps:
(1)Acrylonitrile, siloxanes, ethyl acrylate, aromatic hydrocarbons, DBSA are weighed by above-mentioned formula
Sodium, octylphenol ethoxylate, ammonium persulfate, ultra-violet absorber, plant extraction liquid, reactive diluent, platinum catalyst, nanometer
Silver powder, deionized water, it is standby;
(2)Neopelex, octylphenol ethoxylate, ammonium persulfate and deionized water are placed in high speed dispersor
It is scattered 1.3 hours, obtain sodium dodecyl benzene sulfonate aqueous solution;
(3)By step(2)Obtained sodium dodecyl benzene sulfonate aqueous solution is placed in reactor, and addition propylene is fine, is warming up to 75
DEG C, 40~50min is stirred, polymer A is obtained;
(4)To step(3)Ethyl acrylate is added in obtained polymer A, insulation reaction 2.3 hours obtains polymer B;
(5)Siloxanes is placed in reactor, aromatic hydrocarbons is added, platinum catalyst is added, reacts 2.8 hours, obtains
Polymer C;
(6)To step(5)Polymer B is added in obtained polymer C, is placed in high speed dispersor and disperses 225 minutes, filtering,
Reserved filtrate, obtains polymer D;
(7)Ultra-violet absorber, plant extraction liquid, reactive diluent, Nano Silver powder are added into polymer D, ultrasound is placed in
Disperse 40 minutes in instrument, you can obtain the environmental protection coating material.
Wherein, the rotating speed of high speed dispersor is 1100r/min.
The specific embodiment of the present invention is described above.It is to be appreciated that the invention is not limited in above-mentioned
Particular implementation, those skilled in the art can make various deformations or amendments within the scope of the claims, this not shadow
Ring the substantive content of the present invention.
Claims (8)
1. a kind of environmental protection coating material, it is characterised in that include the raw material of following parts by weight:15~35 parts of acrylonitrile, siloxanes 13~
24 parts, it is 15~35 parts of ethyl acrylate, 5~12 parts of aromatic hydrocarbons, 0.5~1.5 part of neopelex, pungent
0.5~1.5 part of base phenol ethoxylate, 0.3~0.8 part of ammonium persulfate, 1~2 part of ultra-violet absorber, plant extraction liquid 4~7
Part, 5~8 parts of reactive diluent, 1~2 part of platinum catalyst, 0.1~0.5 part of Nano Silver powder, 13~18 parts of deionized water.
2. environmental protection coating material according to claim 1, it is characterised in that include the raw material of following parts by weight:Acrylonitrile 20~
27 parts, 18~22 parts of siloxanes, 22~28 parts of ethyl acrylate, 7~9 parts of aromatic hydrocarbons, DBSA
0.8~1.2 part of sodium, 0.7~0.9 part of octylphenol ethoxylate, 0.5~0.7 part of ammonium persulfate, ultra-violet absorber 1.3~
1.6 parts, 5~6 parts of plant extraction liquid, 6~7.3 parts of reactive diluent, 1.1~1.3 parts of platinum catalyst, Nano Silver powder 0.2~
0.4 part, 15~17 parts of deionized water.
3. environmental protection coating material according to claim 1, it is characterised in that include the raw material of following parts by weight:23 parts of acrylonitrile,
19 parts of siloxanes, 25 parts of ethyl acrylate, 8 parts of aromatic hydrocarbons, 0.9 part of neopelex, octyl phenol second
0.8 part of epoxide compound, 0.6 part of ammonium persulfate, 1.5 parts of ultra-violet absorber, 5.6 parts of plant extraction liquid, reactive diluent 6.9
Part, 1.2 parts of platinum catalyst, 0.3 part of Nano Silver powder, 16 parts of deionized water.
4. environmental protection coating material according to claim 1, it is characterised in that Nano Silver powder is Nano Silver more than 1000 mesh.
5. environmental protection coating material according to claim 1, it is characterised in that the plant extraction liquid is golden cypress, corter pseudolaricis and white
The mixed liquor of fresh hide.
6. environmental protection coating material according to claim 5, it is characterised in that the ratio of the golden cypress, corter pseudolaricis and the root bark of shaggy-fruited dittany is
2:2:5。
7. a kind of method for preparing any one of claim 1~6 environmental protection coating material, it is characterised in that comprise the following steps:
(1)Acrylonitrile, siloxanes, ethyl acrylate, aromatic hydrocarbons, DBSA are weighed by above-mentioned formula
Sodium, octylphenol ethoxylate, ammonium persulfate, ultra-violet absorber, plant extraction liquid, reactive diluent, platinum catalyst, nanometer
Silver powder, deionized water, it is standby;
(2)Neopelex, octylphenol ethoxylate, ammonium persulfate and deionized water are placed in high speed dispersor
It is scattered 1~2 hour, obtain sodium dodecyl benzene sulfonate aqueous solution;
(3)By step(2)Obtained sodium dodecyl benzene sulfonate aqueous solution is placed in reactor, and addition propylene is fine, is warming up to 60
~80 DEG C, 40~50min is stirred, polymer A is obtained;
(4)To step(3)Ethyl acrylate is added in obtained polymer A, insulation reaction 1.5~2.5 hours obtains polymer B;
(5)Siloxanes is placed in reactor, aromatic hydrocarbons is added, platinum catalyst is added, reacts 2~3 hours, obtains
Polymer C;
(6)To step(5)Polymer B is added in obtained polymer C, is placed in high speed dispersor and disperses 20~30 minutes, mistake
Filter, reserved filtrate obtains polymer D;
(7)Ultra-violet absorber, plant extraction liquid, reactive diluent, Nano Silver powder are added into polymer D, ultrasound is placed in
Disperse 30~50 minutes in instrument, you can obtain the environmental protection coating material.
8. preparation method according to claim 7, it is characterised in that the rotating speed of the high speed dispersor is 800~
1200r/min。
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Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN108912766A (en) * | 2018-07-31 | 2018-11-30 | 杭州中齐新材料科技有限公司 | A kind of building interior trim water paint and preparation method thereof |
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CN102690385A (en) * | 2012-06-01 | 2012-09-26 | 安徽省金盾涂料有限责任公司 | Method for polymerizing water-borne acrylate coating |
CN102702967A (en) * | 2012-06-12 | 2012-10-03 | 天长市巨龙车船涂料有限公司 | Waterproof coating |
CN103333556A (en) * | 2013-05-31 | 2013-10-02 | 东莞市康博士装饰材料有限公司 | Multi-functional glutinous rice plant liquid coating |
CN104449076A (en) * | 2014-12-18 | 2015-03-25 | 贵州科新应化工贸有限公司 | Preparation method of environment-friendly coating |
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2017
- 2017-06-05 CN CN201710414473.XA patent/CN107033728A/en not_active Withdrawn
Patent Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
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CN102690385A (en) * | 2012-06-01 | 2012-09-26 | 安徽省金盾涂料有限责任公司 | Method for polymerizing water-borne acrylate coating |
CN102702967A (en) * | 2012-06-12 | 2012-10-03 | 天长市巨龙车船涂料有限公司 | Waterproof coating |
CN103333556A (en) * | 2013-05-31 | 2013-10-02 | 东莞市康博士装饰材料有限公司 | Multi-functional glutinous rice plant liquid coating |
CN104449076A (en) * | 2014-12-18 | 2015-03-25 | 贵州科新应化工贸有限公司 | Preparation method of environment-friendly coating |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
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CN108912766A (en) * | 2018-07-31 | 2018-11-30 | 杭州中齐新材料科技有限公司 | A kind of building interior trim water paint and preparation method thereof |
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Application publication date: 20170811 |