CN107033660A - A kind of magnesia ink - Google Patents

A kind of magnesia ink Download PDF

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Publication number
CN107033660A
CN107033660A CN201611127504.5A CN201611127504A CN107033660A CN 107033660 A CN107033660 A CN 107033660A CN 201611127504 A CN201611127504 A CN 201611127504A CN 107033660 A CN107033660 A CN 107033660A
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CN
China
Prior art keywords
parts
magnesia
ink
present
polyamide
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201611127504.5A
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Chinese (zh)
Inventor
邹健
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Sichuan Withub Zirconium Industry Co Ltd
Original Assignee
Sichuan Withub Zirconium Industry Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Sichuan Withub Zirconium Industry Co Ltd filed Critical Sichuan Withub Zirconium Industry Co Ltd
Priority to CN201611127504.5A priority Critical patent/CN107033660A/en
Publication of CN107033660A publication Critical patent/CN107033660A/en
Pending legal-status Critical Current

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Classifications

    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D11/00Inks
    • C09D11/02Printing inks
    • C09D11/03Printing inks characterised by features other than the chemical nature of the binder
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D11/00Inks
    • C09D11/02Printing inks
    • C09D11/10Printing inks based on artificial resins
    • C09D11/102Printing inks based on artificial resins containing macromolecular compounds obtained by reactions other than those only involving unsaturated carbon-to-carbon bonds
    • C09D11/104Polyesters
    • C09D11/105Alkyd resins

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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Inks, Pencil-Leads, Or Crayons (AREA)

Abstract

The present invention relates to technical field of ink, and in particular to a kind of magnesia ink.Include the composition of following parts by weight:Magnesia:14 22 parts;Carbon dust:25 35 parts;Alkyd resin:15 25 parts;Water soluble acrylic resin:58 parts;Polyamide:18 26 parts;Ethyl acetate:28 parts;Crosslinking agent:13 parts.Ink of the present invention has that glossiness is good, bright in luster, firmness is high, there is good water-fast, refractory, anti-wear performance, and Simultaneous Stabilization is good, and difficult for drop-off, printing is clear.

Description

A kind of magnesia ink
Technical field
The present invention relates to technical field of ink, and in particular to a kind of magnesia ink.
Background technology
Magnesia(Chemical formula:MgO)It is the oxide of magnesium, a kind of ionic compound.It is a kind of white solid under normal temperature.Oxygen Change magnesium in periclase form to be present in nature, be the raw material of smelting magnesium.
Magnesia is commonly called as magnesia, also referred to as magnesia, and magnesia is basic anhydride, and the general character with basic anhydride belongs to Binder materials.White powder(Faint yellow is magnesium nitride), it is odorless, tasteless, nontoxic, it is typical alkaline earth oxide, chemistry Formula MgO.White powder, fusing point is 2852 DEG C, and boiling point is 3600 DEG C.Acid and ammonium salt solution are dissolved in, insoluble in alcohol.
Exposure in atmosphere, easily absorbs moisture and carbon dioxide and is increasingly becoming basic magnesium carbonate, lightweight product heavier Product faster, are combined with water and generate magnesium hydroxide under certain condition, are reacted in alkalescence, and the pH of saturated aqueous solution is 10.3.It is molten Water is insoluble in acid and ammonium salt, its solution alkaline.Insoluble in ethanol.There is strong refraction in visible and near-ultraviolet range. Magnesite (MgCO3), dolomite (MgCO3CaCO3) and seawater are the primary raw materials for producing magnesia.Thermally decompose magnesite or Dolomite obtains magnesia.Magnesium hydrate precipitate is obtained with calcium hydroxide processing seawater, calcination magnesium hydroxide obtains magnesia.Also seawater can be used The magnesium chloride enriched bittern cake that is obtained in comprehensive utilization carries the bittern after bromine for raw material, the hydrogenation generation hydroxide such as sodium oxide molybdena or sodium carbonate Magnesium or basic carbonate magnesium precipitate, then calcination obtain magnesia.It is Chinese mainly to use using magnesite, dolomite, bittern or enriched bittern cake as original Material.
Magnesia has extremely fireproof insulating properties.It can be changed into crystal through 1000 DEG C of high temperature above calcinations, rise to 1500- 2000 DEG C then into dead roasting magnesia (namely described magnesia) or sintered magnesia.
Ink is the important materials for printing, and it is shown pattern, word on stock by printing or air brushing.Oil Ink includes main component and auxiliary element, and they equably mix and form a kind of stickiness colloidal fluid through repeat-rolling.By Link stuff(Resin), pigment, filler, the composition such as auxiliary agent and solvent.For books and periodicals, packing and decorating, building decoration and electronic circuit The various printings such as sheet material.As social demand increases, ink kind and yield also respective extension and growth.
With the requirement more and more higher to press quality, the fineness and purity of ink also increasingly attract attention.We know Road, the fineness of ink has direct relation with the size of pigment, the property of inserts and particle.For ordinary circumstance, with inorganic Pigment(Do not include carbon black)Made ink fineness is bad, and particle is relatively thick, and the rolling mill practice of this and ink has very big Relation.The number of times that ink is ground in technical process is rolled is more, and it more seems uniform, granules of pigments and link stuff contact surface Also bigger, the particle of ink is thinner, and its printing performance also just seems better, more stable.It will be apparent that the fineness and print of ink Brush quality has close relationship.
The content of the invention
It is an object of the present invention to propose that a kind of stability is strong, print clearly magnesia ink.
To achieve these goals, the technical solution adopted by the present invention is:
A kind of magnesia ink, includes the composition of following parts by weight:
Magnesia:14-22 parts;
Carbon dust:25-35 parts;
Alkyd resin:15-25 parts;
Water soluble acrylic resin:5-8 parts;
Polyamide:18-26 parts;
Ethyl acetate:2-8 parts;
Crosslinking agent:1-3 parts.
A kind of magnesia ink, includes the composition of following parts by weight:
Magnesia:18 parts;
Carbon dust:28 parts;
Alkyd resin:20 parts;
Water soluble acrylic resin:7 parts;
Polyamide:22 parts;
Ethyl acetate:5 parts;
Crosslinking agent:2 parts.
The average grain diameter of the magnesia is 60-100nm.
The average grain diameter of the magnesia is 80nm.
By adopting the above-described technical solution, the beneficial effects of the invention are as follows:
Ink of the present invention has that glossiness is good, bright in luster, firmness is high, has good water-fast, refractory, anti-wear performance, simultaneously Stability is good, difficult for drop-off, and printing is clear.
Embodiment
Embodiment 1
As a kind of preferred embodiment of the present invention, present embodiment discloses a kind of magnesia ink, including following parts by weight Composition:
Magnesia:14 parts;
Carbon dust:25 parts;
Alkyd resin:15 parts;
Water soluble acrylic resin:5 parts;
Polyamide:18 parts;
Ethyl acetate:2 parts;
Crosslinking agent:1 part.
Embodiment 2
As a kind of preferred embodiment of the present invention, present embodiment discloses a kind of magnesia ink, including following parts by weight Composition:
Magnesia:22 parts;
Carbon dust:35 parts;
Alkyd resin:25 parts;
Water soluble acrylic resin:8 parts;
Polyamide:26 parts;
Ethyl acetate:8 parts;
Crosslinking agent:3 parts.
Embodiment 3
As a kind of preferred embodiment of the present invention, present embodiment discloses a kind of magnesia ink, including following parts by weight Composition:
Magnesia:18 parts;
Carbon dust:28 parts;
Alkyd resin:20 parts;
Water soluble acrylic resin:7 parts;
Polyamide:22 parts;
Ethyl acetate:5 parts;
Crosslinking agent:2 parts.
Embodiment 4
As a kind of preferred embodiment of the present invention, present embodiment discloses a kind of magnesia ink, including following parts by weight Composition:
Magnesia:14 parts;
Carbon dust:25 parts;
Alkyd resin:15 parts;
Water soluble acrylic resin:5 parts;
Polyamide:18 parts;
Ethyl acetate:2 parts;
Crosslinking agent:1 part.
The average grain diameter of the magnesia is 60nm.
Embodiment 5
As a kind of preferred embodiment of the present invention, present embodiment discloses a kind of magnesia ink, including following parts by weight Composition:
Magnesia:22 parts;
Carbon dust:35 parts;
Alkyd resin:25 parts;
Water soluble acrylic resin:8 parts;
Polyamide:26 parts;
Ethyl acetate:8 parts;
Crosslinking agent:3 parts.
The average grain diameter of the magnesia is 80nm.
Embodiment 6
As a kind of preferred embodiment of the present invention, present embodiment discloses a kind of magnesia ink, including following parts by weight Composition:
Magnesia:18 parts;
Carbon dust:28 parts;
Alkyd resin:20 parts;
Water soluble acrylic resin:7 parts;
Polyamide:22 parts;
Ethyl acetate:5 parts;
Crosslinking agent:2 parts.
The average grain diameter of the magnesia is 100m.
Preparation side's method of the magnesia ink comprises the following steps:
A. alkyd resin, polyamide are mixed, stirred, be warming up to 60-80 DEG C, add ethyl acetate, stir 10-20 Minute;
B. the solution obtained in step a and water soluble acrylic resin are sent into reactor, stirring is warming up to 100-120 DEG C, Stirring 50-60 minutes;
C. carbon dust is added into reactor, is stirred 20-30 minutes;
D. magnesia and crosslinking agent are added, continues to stir 60-100 minutes, grinding distribution produces oxidation into 15-35um slurry Magnesium ink.
Embodiment described above only expresses the embodiment of the application, and it describes more specific and detailed, but simultaneously Therefore the limitation to the application protection domain can not be interpreted as.It should be pointed out that for one of ordinary skill in the art For, on the premise of technical scheme design is not departed from, various modifications and improvements can be made, these belong to this The protection domain of application.

Claims (4)

1. a kind of magnesia ink, it is characterised in that include the composition of following parts by weight:
Magnesia:14-22 parts;
Carbon dust:25-35 parts;
Alkyd resin:15-25 parts;
Water soluble acrylic resin:5-8 parts;
Polyamide:18-26 parts;
Ethyl acetate:2-8 parts;
Crosslinking agent:1-3 parts.
2. a kind of magnesia ink according to claim 1, it is characterised in that include the composition of following parts by weight:
Magnesia:18 parts;
Carbon dust:28 parts;
Alkyd resin:20 parts;
Water soluble acrylic resin:7 parts;
Polyamide:22 parts;
Ethyl acetate:5 parts;
Crosslinking agent:2 parts.
3. a kind of magnesia ink according to claim 1, it is characterised in that:The average grain diameter of the magnesia is 60- 100nm。
4. a kind of magnesia ink according to claim 1 or 3, it is characterised in that:The average grain diameter of the magnesia is 80nm。
CN201611127504.5A 2016-12-09 2016-12-09 A kind of magnesia ink Pending CN107033660A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201611127504.5A CN107033660A (en) 2016-12-09 2016-12-09 A kind of magnesia ink

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201611127504.5A CN107033660A (en) 2016-12-09 2016-12-09 A kind of magnesia ink

Publications (1)

Publication Number Publication Date
CN107033660A true CN107033660A (en) 2017-08-11

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CN201611127504.5A Pending CN107033660A (en) 2016-12-09 2016-12-09 A kind of magnesia ink

Country Status (1)

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Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104449035A (en) * 2014-11-26 2015-03-25 成都锦汇科技有限公司 Water-based ink with condensation prevention capacity
CN105062204A (en) * 2015-07-20 2015-11-18 苏州宇希新材料科技有限公司 Nano-titanium dioxide printing ink and preparation method thereof

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104449035A (en) * 2014-11-26 2015-03-25 成都锦汇科技有限公司 Water-based ink with condensation prevention capacity
CN105062204A (en) * 2015-07-20 2015-11-18 苏州宇希新材料科技有限公司 Nano-titanium dioxide printing ink and preparation method thereof

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Application publication date: 20170811

RJ01 Rejection of invention patent application after publication