CN107012687A - A kind of antistatic additive of yarn fabric - Google Patents
A kind of antistatic additive of yarn fabric Download PDFInfo
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- CN107012687A CN107012687A CN201710353105.9A CN201710353105A CN107012687A CN 107012687 A CN107012687 A CN 107012687A CN 201710353105 A CN201710353105 A CN 201710353105A CN 107012687 A CN107012687 A CN 107012687A
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- antistatic additive
- type
- antistatic
- good
- yarn fabric
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
- D06M13/224—Esters of carboxylic acids; Esters of carbonic acid
- D06M13/2243—Mono-, di-, or triglycerides
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/244—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing sulfur or phosphorus
- D06M13/282—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing sulfur or phosphorus with compounds containing phosphorus
- D06M13/292—Mono-, di- or triesters of phosphoric or phosphorous acids; Salts thereof
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/322—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
- D06M13/325—Amines
- D06M13/342—Amino-carboxylic acids; Betaines; Aminosulfonic acids; Sulfo-betaines
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/322—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
- D06M13/35—Heterocyclic compounds
- D06M13/352—Heterocyclic compounds having five-membered heterocyclic rings
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/322—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
- D06M13/35—Heterocyclic compounds
- D06M13/355—Heterocyclic compounds having six-membered heterocyclic rings
- D06M13/358—Triazines
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/322—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
- D06M13/402—Amides imides, sulfamic acids
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/322—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
- D06M13/46—Compounds containing quaternary nitrogen atoms
- D06M13/463—Compounds containing quaternary nitrogen atoms derived from monoamines
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/507—Polyesters
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/53—Polyethers
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/564—Polyureas, polyurethanes or other polymers having ureide or urethane links; Precondensation products forming them
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/61—Polyamines polyimines
Landscapes
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
- Multicomponent Fibers (AREA)
Abstract
The present invention discloses a kind of antistatic additive of yarn fabric, belongs to textile processing field.Antistatic additive disclosed by the invention is the cruel amine of ethyoxyl bay or glyceryl monostearate (GMS), polyoxyethylene alkylphenol ether sulfuric ester, alkyl phosphate, polyamine class, polyester polyethers, triazines, polyurethane-type, aminocarboxylic acid type, betaine type or imidazoline type antistatic additive；Above-mentioned antistatic additive o.w.f is 0.06.The preparation method of antistatic additive disclosed by the invention is simple, fabric antistatic property that is making is good, washing performance is good.
Description
Technical field
The present invention discloses a kind of antistatic additive, in particular to a kind of antistatic additive of yarn fabric.
Background technology
In dry autumn, in daily life, we often run into this phenomenon：The sleep that undress in the evening when
Wait, crack the sound is often heard in dark, and with blue light, when meeting is shaken hands, finger can be felt to refer to upon contact other side
Shouting pain as prong thorn；Often the sound of ", " is sent.And these are exactly to occur the electrostatic in human body.Above-mentioned electrostatic is in day
Some harm often occur in life and influence.In autumn, the skin young man that compares is drier by the elderly, due to and the elderly
The aging of cardiovascular system, antijamming capability such as weaken at the factor, therefore the elderly is easier to be influenceed by electrostatic.But it is cardiovascular
System natively has a elderly of various lesions, and electrostatic can more aggravate disease or induce the arrhythmia cordis such as VPB.It is too high
Electrostatic can also make one lather, headache, it is uncomfortable in chest, expiratory dyspnea, cough.
The content of the invention
The present invention provides a kind of cost low, safe Antistatic Fabric, and it is realized by following technical scheme：It is described anti-
Electrostatic agent is the cruel amine of ethyoxyl bay or glyceryl monostearate (GMS), polyoxyethylene alkylphenol ether sulfuric ester, alkyl phosphoric acid
Ester, polyamine class, polyester polyethers, triazines, polyurethane-type, aminocarboxylic acid type, betaine type or imidazoline type antistatic additive；On
It is 0.06 to state antistatic additive o.w.f;Ethoxylated alkylamine is effectively antistatic additive, even in the low feelings of relative humidity
Condition antistatic effect remains unchanged very well, and permanently effective.The cruel amine of ethyoxyl bay is poly- suitable for what is used in the small environment of humidity
Ethene and polypropylene, and require the occasion of long-acting anti-static function of having immediate effect;Anion surfactant, such as alkylphenol
Ethylene oxide ether sulfate, alkyl phosphate etc. can on fiber oriented attachment, lipophilic group towards fiber, anion it is hydrophilic
Property group towards air, and with water associate, improve fiber surface conductance, electric charge is revealed rapidly, anlistatig effect is reached;Sun
Ionic surface active agent：Quaternary representative products have antistatic additive SN, TM etc..Just have in low concentration excellent antistatic
Performance, because most of high polymer materials all carry negative electrical charge so that cationic antistatic agent is highly effective;Amophoteric surface active
Agent, such as aminocarboxylic acid type, betaine type, imidazoline type;In fiber surface formation oriented attachment, the ionization of its own is utilized
And hydrophily, and then improve conductance;
Durable antistatic agent have polyamine class, polyester polyethers (terephthalic acid (TPA), ethylene glycol, the block copolymer of polyethylene glycol,
Its basic structure is similar with terylene) there is excellent durable antistatic and soft effect;Polyacrylate (methacrylic acid and
Acrylate) can be in fiber surface formation anionic hydrophilic film with the copolymer of hydrophilic monomer.Due to polyacrylate
There is hydrophily very strong carboxyl in molecule, so antistatic effect is pretty good, washability very well, is well suited for terylene;Above-mentioned triazine
Class is, using melamine as skeleton, to connect polyester, polyether group, with good antistatic behaviour and washability.Above-mentioned polyurethane
Type antistatic additive, its basic structure is NHCOO- (EO) nCONHR, and wherein polyether segment and amide segment is all good moisture absorption
Antistatic group.Polyurethane-type antistatic additive is often used in combination with other kinds of antistatic additive, to obtain more preferable effect；Macromolecule
The mechanism of action of permanent antistatic agent：It is after it is blended with macromolecule matrix, on the one hand due to the locomitivity of strand
It is relatively strong, it is intermolecular to be easy to proton to move, the electrostatic charge produced is conducted and discharged by ionic conduction；On the other hand, it is antistatic
Ability is embodied by its special dispersing morphology.Research shows：Macromolecule permanent type electrostatic agent is mainly in article topsheet
It is distributed in fine stratiform or tendon shape, constitutes electric conductivity top layer；And be in almost spherical distribution in core, formed so-called
" core shell structure ", and electrostatic charge is revealed with this path；Because macromolecule permanent antistatic agent is to reduce material volume resistance
Rate reaches antistatic effect, does not complete to rely on water absorbent surface, so influenceed smaller by the humidity of environment.
Antistatic additive preparation method that the present invention is provided is simple, fabric antistatic property that is making is good, washing performance is good.
Embodiment
The description of the invention is carried out below in conjunction with specific embodiment.The antistatic additive is the cruel amine of ethyoxyl bay
Or glyceryl monostearate (GMS), polyoxyethylene alkylphenol ether sulfuric ester, alkyl phosphate, polyamine class, polyester polyethers,
Triazines, polyurethane-type, aminocarboxylic acid type, betaine type or imidazoline type antistatic additive；Above-mentioned antistatic additive o.w.f is
0.06;Ethoxylated alkylamine is effectively antistatic additive, even being remained unchanged in the low situation antistatic effect of relative humidity
Very well, it is and permanently effective.The cruel amine of ethyoxyl bay is applied to the polyethylene and polypropylene used in the small environment of humidity, and
It is required that the occasion for the long-acting anti-static function that has immediate effect;Anion surfactant, such as polyoxyethylene alkylphenol ether sulfuric ester,
Alkyl phosphate etc. can on fiber oriented attachment, lipophilic group towards fiber, the hydrophilic radical of anion towards air, and
Associated with water, improve fiber surface conductance, electric charge is revealed rapidly, anlistatig effect is reached;Cationic surfactant：Season
Ammonium salt type representative products have antistatic additive SN, TM etc..Just there is excellent antistatic property in low concentration, due to most of high
Molecular material all carries negative electrical charge so that cationic antistatic agent is highly effective;Amphoteric surfactant, such as aminocarboxylic acid type,
Betaine type, imidazoline type etc.;In fiber surface formation oriented attachment, ionization and hydrophily using its own, Jin Erti
High conductivity;Durable antistatic agent has polyamine class, polyester polyethers, and (terephthalic acid (TPA), ethylene glycol, the block of polyethylene glycol are total to
Polymers, its basic structure is similar with terylene) there is excellent durable antistatic and soft effect;Polyacrylate (methyl-prop
Olefin(e) acid and acrylate) can be in fiber surface formation anionic hydrophilic film with the copolymer of hydrophilic monomer.Due to poly- third
There is hydrophily very strong carboxyl in olefin(e) acid ester molecule, so antistatic effect is pretty good, washability very well, is well suited for terylene;On
It is, using melamine as skeleton, to connect polyester, polyether group to state triazines, with good antistatic behaviour and washability.It is above-mentioned
Polyurethane-type antistatic additive, its basic structure is NHCOO- (EO) nCONHR, and wherein polyether segment and amide segment is all fine
The antistatic group of moisture absorption.Polyurethane-type antistatic additive is often used in combination with other kinds of antistatic additive, to obtain more preferable effect；
The mechanism of action of macromolecule permanent antistatic agent：It is after it is blended with macromolecule matrix, on the one hand due to the fortune of strand
Kinetic force is stronger, intermolecular to be easy to proton to move, and the electrostatic charge produced is conducted and discharged by ionic conduction；On the other hand,
Antistatic effect is embodied by its special dispersing morphology.Research shows：Macromolecule permanent type electrostatic agent is mainly in system
Product top layer is distributed in fine stratiform or tendon shape, constitutes electric conductivity top layer；And be in almost spherical distribution in core, form institute
" core shell structure " of meaning, and electrostatic charge is revealed with this path；Because macromolecule permanent antistatic agent is to reduce material volume
Resistivity reaches antistatic effect, does not complete to rely on water absorbent surface, so influenceed smaller by the humidity of environment；It is described anti-quiet
1 parts by weight of electric agent (the cruel amine of ethyoxyl bay) add into the spandex stoste of 100 parts by weight well mixed.Spandex makes fabric
Technique is melt-spinning technology.Specifically, high polymer is heated to more than fusing point turn into the method that melt forms silk.The present invention is provided
Antistatic additive preparation method it is simple, fabric antistatic property that is making is good, washing performance is good.
Above-described embodiment is merely illustrative of the technical solution of the present invention, rather than design and protection domain progress to the present invention
Limit, one of ordinary skill in the art modifies or equivalent substitution to technical scheme, without departing from technology
The objective and scope of scheme, it all should cover in scope of the presently claimed invention.
Claims (1)
1. a kind of antistatic additive of yarn fabric, it is characterised in that：The antistatic additive is that the cruel amine of ethyoxyl bay or glycerine list are hard
Resin acid ester (GMS), polyoxyethylene alkylphenol ether sulfuric ester, alkyl phosphate, polyamine class, polyester polyethers, triazines, poly- ammonia
Ester type, aminocarboxylic acid type, betaine type or imidazoline type antistatic additive；Above-mentioned antistatic additive o.w.f is 0.06.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710353105.9A CN107012687A (en) | 2017-05-18 | 2017-05-18 | A kind of antistatic additive of yarn fabric |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710353105.9A CN107012687A (en) | 2017-05-18 | 2017-05-18 | A kind of antistatic additive of yarn fabric |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN107012687A true CN107012687A (en) | 2017-08-04 |
Family
ID=59450310
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201710353105.9A Withdrawn CN107012687A (en) | 2017-05-18 | 2017-05-18 | A kind of antistatic additive of yarn fabric |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN107012687A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108457076A (en) * | 2018-02-12 | 2018-08-28 | 周华 | A kind of composite spinning auxiliary agent and preparation method thereof improving textile antistatic property |
-
2017
- 2017-05-18 CN CN201710353105.9A patent/CN107012687A/en not_active Withdrawn
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108457076A (en) * | 2018-02-12 | 2018-08-28 | 周华 | A kind of composite spinning auxiliary agent and preparation method thereof improving textile antistatic property |
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Application publication date: 20170804 |