CN107011837A - Composited aluminum and plastic decking adhesive resin composition and preparation method thereof - Google Patents
Composited aluminum and plastic decking adhesive resin composition and preparation method thereof Download PDFInfo
- Publication number
- CN107011837A CN107011837A CN201710289287.8A CN201710289287A CN107011837A CN 107011837 A CN107011837 A CN 107011837A CN 201710289287 A CN201710289287 A CN 201710289287A CN 107011837 A CN107011837 A CN 107011837A
- Authority
- CN
- China
- Prior art keywords
- resin composition
- composited aluminum
- plastic decking
- adhesive resin
- parts
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J151/00—Adhesives based on graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Adhesives based on derivatives of such polymers
- C09J151/06—Adhesives based on graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Adhesives based on derivatives of such polymers grafted on to homopolymers or copolymers of aliphatic hydrocarbons containing only one carbon-to-carbon double bond
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F255/00—Macromolecular compounds obtained by polymerising monomers on to polymers of hydrocarbons as defined in group C08F10/00
- C08F255/02—Macromolecular compounds obtained by polymerising monomers on to polymers of hydrocarbons as defined in group C08F10/00 on to polymers of olefins having two or three carbon atoms
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/02—Non-macromolecular additives
- C09J11/04—Non-macromolecular additives inorganic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/02—Non-macromolecular additives
- C09J11/06—Non-macromolecular additives organic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/08—Macromolecular additives
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
Abstract
The present invention proposes a kind of composited aluminum and plastic decking adhesive resin composition, is made up of following raw material：High density polyethylene (HDPE), grafted monomers, initiator, hydrogenated petroleum resin, cyanate, BMI, super-fine silicon micro-powder, hindered phenol and viscosity-controlling agent.Preparation method：Heating melting high density polyethylene (HDPE), then adds grafted monomers and initiator first at 150 DEG C~180 DEG C, after being well mixed, obtains graft copolymer；Hydrogenated petroleum resin, cyanate, BMI, hindered phenol and super-fine silicon micro-powder are continuously added, melting stirs, finally add viscosity-controlling agent, melting is uniform, and discharge to obtain adhering resin composition.The composited aluminum and plastic decking may insure that obtained composited aluminum and plastic decking has good weatherability and persistence with adhesive resin composition.
Description
Technical field
The invention belongs to field of adhesive technology, and in particular to a kind of composited aluminum and plastic decking adhesive resin composition and its system
Preparation Method.
Background technology
The construction of plastic-aluminum composite pressure pipe (abbreviation aluminium-plastic pipe) be each layer of polyethylene of inside and outside wall, intermediate layer be PUR and
The composite material tube of the formable layer of aluminium alloy 5.Plastic-aluminum combined Manifold technology is to be applied in late 1970s by British scholar KITI
Patent, was studied after the industrialization of 10 years, and industrialized production is realized first by Germany and Britain in phase late 1980s.
The maximum advantage of PAP is combined with the strong point of metal and plastics, with high-low temperature resistant, pressure-resistant, corrosion resistant
It is the advantages of erosion, light weight, high-strength, anti-gas osmosising, and mesh ductility is good, also flexible not rebound, therefore, product once appearance,
Obtain and rapidly promote the use, since 1992, the annual growth of this novel tube abroad was all more than 20%, extensively
It is general to be applied to a variety of civilian and industrial uses such as hot and cold water conveying, floor panel heating, fuel gas transmission and medical oxygen conveying.
It is made up of, is there is viscous metal and the completely different material of nonmetallic two kinds of property due to composited aluminum and plastic decking
Knot problem is, it is necessary to from specific binder resin, just can ensure that obtained composited aluminum and plastic decking has good weatherability and lasting
Property.In real life application, aluminium-plastic pipe often occurs after using 1 year, ground leak, this is mainly aluminium-plastic pipe in length
In the case of phase high temperature, what the adhering resin in the middle of tube layer was caused with tube layer degumming.
The content of the invention
The present invention proposes a kind of composited aluminum and plastic decking adhesive resin composition, the composited aluminum and plastic decking adhesive resin composition
It may insure that obtained composited aluminum and plastic decking has good weatherability and persistence.
The technical proposal of the invention is realized in this way：
A kind of composited aluminum and plastic decking adhesive resin composition, is prepared from the following raw materials in parts by weight：
80~90 parts of high density polyethylene (HDPE), 0.8~2.4 part of grafted monomers, 0.05~0.15 part of initiator, non-hydrogenated petroleum tree
10~25 parts of fat, 1~5 part of cyanate, 5~10 parts of BMI, 1~4 part of super-fine silicon micro-powder, 8~16 parts of hindered phenol with
And 1~3 part of viscosity-controlling agent.
Preferably, grafted monomers are a kind of or many in maleic anhydride, carbic anhydride, epoxy acrylate
Kind.
Preferably, initiator is cumyl peroxide or benzoyl peroxide.
Preferably, viscosity-controlling agent is Tissuemat E or paraffin.
It is a further object to provide a kind of preparation method of composited aluminum and plastic decking adhesive resin composition, first
Heating melting high density polyethylene (HDPE), then adds grafted monomers and initiator at 150 DEG C~180 DEG C, after being well mixed, obtains
Graft copolymer；Hydrogenated petroleum resin, cyanate, BMI, hindered phenol and super-fine silicon micro-powder are continuously added, melting is stirred
Mix uniform, finally add viscosity-controlling agent, melting is uniform, and discharge to obtain adhering resin composition.
Beneficial effects of the present invention：
Present invention heating melting high density polyethylene (HDPE) at 150 DEG C~180 DEG C, then adds grafted monomers and initiator,
After well mixed, graft copolymer is obtained, polar group (such as maleic anhydride) is introduced on apolar substance, to increase bonding tree
The bonding force of fat.Further, graft copolymer, hydrogenated petroleum resin, cyanate, BMI, super-fine silicon micro-powder, be obstructed
Phenol and viscosity-controlling agent collocation so that obtained composited aluminum and plastic decking adhesive resin composition reach may insure it is obtained
Composited aluminum and plastic decking has good weatherability and persistent purpose.
Embodiment
Embodiment 1
A kind of composited aluminum and plastic decking adhesive resin composition, is prepared from the following raw materials in parts by weight：
85 parts of high density polyethylene (HDPE), 1.8 parts of maleic anhydride, 0.11 part of cumyl peroxide, 18 parts of hydrogenated petroleum resin,
2 parts of 3 parts of cyanate, 8 parts of BMI, 3 parts of super-fine silicon micro-powder, 12 parts of hindered phenol and Tissuemat E.
Preparation method, heating melting high density polyethylene (HDPE), then adds maleic anhydride and peroxidating two first at 175 DEG C
Isopropylbenzene, after being well mixed, obtains graft copolymer；Continuously add hydrogenated petroleum resin, cyanate, BMI, by
Phenol and super-fine silicon micro-powder are hindered, melting stirs, finally add Tissuemat E, melting is uniform, and discharge to obtain adhering resin composition.
The present embodiment composited aluminum and plastic decking adhesive resin composition reaches 8.5N/mm to the adhesive strength of metallic aluminium, when it
For preparing during composited aluminum and plastic decking, it can be ensured that obtained composited aluminum and plastic decking has good weatherability and persistence.
Embodiment 2
A kind of composited aluminum and plastic decking adhesive resin composition, is prepared from the following raw materials in parts by weight：
80 parts of high density polyethylene (HDPE), 0.8 part of carbic anhydride, 0.05 part of benzoyl peroxide, hydrogenated petroleum resin
1 part of 10 parts, 5 parts of cyanate, 10 parts of BMI, 1 part of super-fine silicon micro-powder, 16 parts of hindered phenol and paraffin.
Preparation method, heating melting high density polyethylene (HDPE), then adds carbic anhydride and mistake first at 150 DEG C
BP, after being well mixed, obtains graft copolymer；Continuously add hydrogenated petroleum resin, cyanate, bismaleimide
Amine, hindered phenol and super-fine silicon micro-powder, melting stir, and finally add paraffin, and melting is uniform, and discharge to obtain adhering resin combination
Thing.
The present embodiment composited aluminum and plastic decking adhesive resin composition reaches 8N/mm to the adhesive strength of metallic aluminium, when its use
When composited aluminum and plastic decking is prepared, it can be ensured that obtained composited aluminum and plastic decking has good weatherability and persistence.
Embodiment 3
A kind of composited aluminum and plastic decking adhesive resin composition, is prepared from the following raw materials in parts by weight：
90 parts of high density polyethylene (HDPE), 2.4 parts of maleic anhydride, 0.15 part of cumyl peroxide, 25 parts of hydrogenated petroleum resin,
3 parts of 1 part of cyanate, 5 parts of BMI, 4 parts of super-fine silicon micro-powder, 8 parts of hindered phenol and Tissuemat E.
Preparation method, heating melting high density polyethylene (HDPE), then adds maleic anhydride and peroxidating two first at 180 DEG C
Isopropylbenzene, after being well mixed, obtains graft copolymer；Continuously add hydrogenated petroleum resin, cyanate, BMI, by
Phenol and super-fine silicon micro-powder are hindered, melting stirs, finally add Tissuemat E, melting is uniform, and discharge to obtain adhering resin composition.
The present embodiment composited aluminum and plastic decking adhesive resin composition reaches 9N/mm to the adhesive strength of metallic aluminium, when its use
When composited aluminum and plastic decking is prepared, it can be ensured that obtained composited aluminum and plastic decking has good weatherability and persistence.
The foregoing is merely illustrative of the preferred embodiments of the present invention, is not intended to limit the invention, all essences in the present invention
God is with principle, and any modification, equivalent substitution and improvements made etc. should be included in the scope of the protection.
Claims (5)
1. a kind of composited aluminum and plastic decking adhesive resin composition, it is characterised in that be prepared from the following raw materials in parts by weight：
80~90 parts of high density polyethylene (HDPE), 0.8~2.4 part of grafted monomers, 0.05~0.15 part of initiator, hydrogenated petroleum resin 10
~25 parts, 1~5 part of cyanate, 5~10 parts of BMI, 1~4 part of super-fine silicon micro-powder, 8~16 parts of hindered phenol and glutinous
Spend 1~3 part of conditioning agent.
2. composited aluminum and plastic decking adhesive resin composition according to claim 1, it is characterised in that grafted monomers are Malaysia
One or more in acid anhydrides, carbic anhydride, epoxy acrylate.
3. composited aluminum and plastic decking adhesive resin composition according to claim 1, it is characterised in that initiator is peroxidating
Diisopropylbenzene (DIPB) or benzoyl peroxide.
4. composited aluminum and plastic decking adhesive resin composition according to claim 1, it is characterised in that viscosity-controlling agent is poly-
Ethylene waxes or paraffin.
5. the preparation method of composited aluminum and plastic decking adhesive resin composition as claimed in claim 1, it is characterised in that exist first
Heating melting high density polyethylene (HDPE), then adds grafted monomers and initiator at 150 DEG C~180 DEG C, after being well mixed, is connect
Graft copolymer；Continuously add hydrogenated petroleum resin, cyanate, BMI, hindered phenol and super-fine silicon micro-powder, melting stirring
Uniformly, viscosity-controlling agent is finally added, melting is uniform, and discharge to obtain adhering resin composition.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710289287.8A CN107011837A (en) | 2017-04-27 | 2017-04-27 | Composited aluminum and plastic decking adhesive resin composition and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710289287.8A CN107011837A (en) | 2017-04-27 | 2017-04-27 | Composited aluminum and plastic decking adhesive resin composition and preparation method thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN107011837A true CN107011837A (en) | 2017-08-04 |
Family
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201710289287.8A Pending CN107011837A (en) | 2017-04-27 | 2017-04-27 | Composited aluminum and plastic decking adhesive resin composition and preparation method thereof |
Country Status (1)
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|---|---|
| CN (1) | CN107011837A (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107987759A (en) * | 2017-12-08 | 2018-05-04 | 苏州爱康薄膜新材料有限公司 | A kind of aluminum-plastic membrane used for packaging lithium battery corrosion resistant type adhesive |
| CN110746912A (en) * | 2019-10-18 | 2020-02-04 | 广东东方管业有限公司 | Hot melt adhesive for bonding polyethylene and steel wire, preparation method and pipe |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1323867A (en) * | 2001-06-13 | 2001-11-28 | 广州市鹿山化工材料有限公司 | Nanometer hot melt adhesive for aluminium-plastic tube |
| CN103740300A (en) * | 2013-12-24 | 2014-04-23 | 上海邦中高分子材料有限公司 | High-strength bonding resin for aluminum-plastic composite plate |
| CN104789168A (en) * | 2015-04-17 | 2015-07-22 | 广西藤县通轩立信化学有限公司 | Bonding resin composition for aluminum-plastic composite panel |
-
2017
- 2017-04-27 CN CN201710289287.8A patent/CN107011837A/en active Pending
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1323867A (en) * | 2001-06-13 | 2001-11-28 | 广州市鹿山化工材料有限公司 | Nanometer hot melt adhesive for aluminium-plastic tube |
| CN103740300A (en) * | 2013-12-24 | 2014-04-23 | 上海邦中高分子材料有限公司 | High-strength bonding resin for aluminum-plastic composite plate |
| CN104789168A (en) * | 2015-04-17 | 2015-07-22 | 广西藤县通轩立信化学有限公司 | Bonding resin composition for aluminum-plastic composite panel |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107987759A (en) * | 2017-12-08 | 2018-05-04 | 苏州爱康薄膜新材料有限公司 | A kind of aluminum-plastic membrane used for packaging lithium battery corrosion resistant type adhesive |
| CN110746912A (en) * | 2019-10-18 | 2020-02-04 | 广东东方管业有限公司 | Hot melt adhesive for bonding polyethylene and steel wire, preparation method and pipe |
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| PB01 | Publication | ||
| PB01 | Publication | ||
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Application publication date: 20170804 |