CN107011593A - A kind of expansibility flame-proof polyvinyl chloride cable - Google Patents

A kind of expansibility flame-proof polyvinyl chloride cable Download PDF

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Publication number
CN107011593A
CN107011593A CN201710288426.5A CN201710288426A CN107011593A CN 107011593 A CN107011593 A CN 107011593A CN 201710288426 A CN201710288426 A CN 201710288426A CN 107011593 A CN107011593 A CN 107011593A
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CN
China
Prior art keywords
parts
polyvinyl chloride
cable
proof polyvinyl
expansibility
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201710288426.5A
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Chinese (zh)
Inventor
吴善同
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Chengdu Xinsan Electric Wire Factory
Original Assignee
Chengdu Xinsan Electric Wire Factory
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Chengdu Xinsan Electric Wire Factory filed Critical Chengdu Xinsan Electric Wire Factory
Priority to CN201710288426.5A priority Critical patent/CN107011593A/en
Publication of CN107011593A publication Critical patent/CN107011593A/en
Pending legal-status Critical Current

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    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K13/00Use of mixtures of ingredients not covered by one single of the preceding main groups, each of these compounds being essential
    • C08K13/02Organic and inorganic ingredients
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/02Elements
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/18Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20Oxides; Hydroxides
    • C08K3/22Oxides; Hydroxides of metals
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/18Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/24Acids; Salts thereof
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00Use of organic ingredients
    • C08K5/49Phosphorus-containing compounds
    • C08K5/5399Phosphorus bound to nitrogen
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01BCABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
    • H01B3/00Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties
    • H01B3/18Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances
    • H01B3/30Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances plastics; resins; waxes
    • H01B3/44Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances plastics; resins; waxes vinyl resins; acrylic resins
    • H01B3/443Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances plastics; resins; waxes vinyl resins; acrylic resins from vinylhalogenides or other halogenoethylenic compounds
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/02Elements
    • C08K2003/026Phosphorus
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/18Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20Oxides; Hydroxides
    • C08K3/22Oxides; Hydroxides of metals
    • C08K2003/2255Oxides; Hydroxides of metals of molybdenum
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00Specific properties of additives
    • C08K2201/002Physical properties
    • C08K2201/003Additives being defined by their diameter
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2201/00Properties
    • C08L2201/02Flame or fire retardant/resistant
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2203/00Applications
    • C08L2203/20Applications use in electrical or conductive gadgets
    • C08L2203/202Applications use in electrical or conductive gadgets use in electrical wires or wirecoating

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Physics & Mathematics (AREA)
  • Spectroscopy & Molecular Physics (AREA)
  • Insulated Conductors (AREA)
  • Compositions Of Macromolecular Compounds (AREA)

Abstract

The invention discloses a kind of expansibility flame-proof polyvinyl chloride cable, the external insulation layer of cable is made up of the raw material of following parts by weight:100 parts of polyvinyl chloride, 20 30 parts of expansion type flame retardant, 15 20 parts of zinc molybdate, 5 10 parts of red phosphorus, 10 20 parts of the molybdenum sesquioxide crystallization water.The present invention is acted on by zinc molybdate, the cooperative flame retardant of red phosphorus and the molybdenum sesquioxide crystallization water and suppression cigarette so that cable can effectively play fire-retardant effect.

Description

A kind of expansibility flame-proof polyvinyl chloride cable
Technical field
The present invention relates to power industry field, and in particular to a kind of expansibility flame-proof polyvinyl chloride cable.
Background technology
Electric wire is to transmit electromagnetic energy, information and the wire product for realizing electromagnetic energy conversion.Electric wire and cable is simultaneously There is no strict boundary.Generally by core number is few, product diameter is small, product simple in construction is referred to as electric wire, what is do not insulated is referred to as Luodian County, others are referred to as cable.
Cable is more and more diversified in modern use environment, high temperature, low temperature, harsh climate, rugged environment etc. Use all to normal cable proposes various problems.To tackle the requirement of existing use environment, cable tool of the present invention There is good fire resistance.
The content of the invention
It is an object of the invention to provide a kind of expansibility flame-proof polyvinyl chloride cable.Expansibility flame-proof polyvinyl chloride electricity Cable can play good flame retardant effect, be adapted to the use of harsh weather and environment.
The present invention is achieved through the following technical solutions:
A kind of expansibility flame-proof polyvinyl chloride cable, the external insulation layer of cable is made up of the raw material of following parts by weight:Polychlorostyrene 100 parts of ethene, 20-30 parts of expansion type flame retardant, 15-20 parts of zinc molybdate, 5-10 parts of red phosphorus, molybdenum sesquioxide crystallization water 10-20 Part.
The external insulation layer of cable is made up of the raw material of following parts by weight:100 parts of polyvinyl chloride, 20 parts of expansion type flame retardant, 18 parts of zinc molybdate, 8 parts of red phosphorus, 15 parts of the molybdenum sesquioxide crystallization water.
Also include 5-8 parts of antimony oxide.
The expansion type flame retardant is two neopentyl glycol m-phenylene diamine (MPD) phosphates or the phosphonitrile of hydroxyl ring three.
The particle diameter of the zinc molybdate is 300-500 microns.The zinc molybdate of micron grain size more can be contacted with extraneous, and It will not excessively reunite during cable is prepared, cause material uneven.
The present invention compared with prior art, has the following advantages and advantages:
The present invention is acted on by zinc molybdate, the cooperative flame retardant of red phosphorus and the molybdenum sesquioxide crystallization water and suppression cigarette so that cable Fire-retardant effect can be effectively played.
Embodiment
For the object, technical solutions and advantages of the present invention are more clearly understood, with reference to embodiment, to present invention work Further to describe in detail, exemplary embodiment and its explanation of the invention is only used for explaining the present invention, is not intended as to this The restriction of invention.
Embodiment 1
A kind of expansibility flame-proof polyvinyl chloride cable, the external insulation layer of cable is made up of the raw material of following parts by weight:Polychlorostyrene 100 parts of ethene, 22 parts of expansion type flame retardant, 15 parts of zinc molybdate, 5 parts of red phosphorus, 10 parts of the molybdenum sesquioxide crystallization water.
Embodiment 2
A kind of expansibility flame-proof polyvinyl chloride cable, the external insulation layer of cable is made up of the raw material of following parts by weight:Polychlorostyrene 100 parts of ethene, 20 parts of expansion type flame retardant, 18 parts of zinc molybdate, 8 parts of red phosphorus, 15 parts of the molybdenum sesquioxide crystallization water.
Embodiment 3
A kind of expansibility flame-proof polyvinyl chloride cable, the external insulation layer of cable is made up of the raw material of following parts by weight:Polychlorostyrene 100 parts of ethene, 30 parts of expansion type flame retardant, 20 parts of zinc molybdate, 10 parts of red phosphorus, 20 parts of the molybdenum sesquioxide crystallization water.
Embodiment 4
A kind of expansibility flame-proof polyvinyl chloride cable, the external insulation layer of cable is made up of the raw material of following parts by weight:Polychlorostyrene 100 parts of ethene, 20 parts of expansion type flame retardant, 18 parts of zinc molybdate, 8 parts of red phosphorus, 15 parts of the molybdenum sesquioxide crystallization water, antimony oxide 5 parts.
Embodiment 5
A kind of expansibility flame-proof polyvinyl chloride cable, the external insulation layer of cable is made up of the raw material of following parts by weight:Polychlorostyrene 100 parts of ethene, 20 parts of expansion type flame retardant, 18 parts of zinc molybdate, 8 parts of red phosphorus, 15 parts of the molybdenum sesquioxide crystallization water, antimony oxide 8 parts.
The particle diameter of zinc molybdate is 300-500 microns.
Expansion type flame retardant is two neopentyl glycol m-phenylene diamine (MPD) phosphates or the phosphonitrile of hydroxyl ring three.
Above-described embodiment, has been carried out further to the purpose of the present invention, technical scheme and beneficial effect Describe in detail, should be understood that the embodiment that the foregoing is only the present invention, be not intended to limit the present invention Protection domain, within the spirit and principles of the invention, any modification, equivalent substitution and improvements done etc. all should be included Within protection scope of the present invention.

Claims (5)

1. a kind of expansibility flame-proof polyvinyl chloride cable, it is characterised in that the external insulation layer of cable by following parts by weight raw material It is made:100 parts of polyvinyl chloride, 20-30 parts of expansion type flame retardant, 15-20 parts of zinc molybdate, 5-10 parts of red phosphorus, molybdenum sesquioxide knot Brilliant water 10-20 parts.
2. expansibility flame-proof polyvinyl chloride cable according to claim 1, it is characterised in that the external insulation layer of cable by with The raw material of lower parts by weight is made:100 parts of polyvinyl chloride, 20 parts of expansion type flame retardant, 18 parts of zinc molybdate, 8 parts of red phosphorus, three oxidations two 15 parts of the molybdenum crystallization water.
3. expansibility flame-proof polyvinyl chloride cable according to claim 1, it is characterised in that also including antimony oxide 5- 8 parts.
4. expansibility flame-proof polyvinyl chloride cable according to claim 1, it is characterised in that the expansion type flame retardant is Two neopentyl glycol m-phenylene diamine (MPD) phosphates or the phosphonitrile of hydroxyl ring three.
5. expansibility flame-proof polyvinyl chloride cable according to claim 1, it is characterised in that the particle diameter of the zinc molybdate is 300-500 microns.
CN201710288426.5A 2017-04-27 2017-04-27 A kind of expansibility flame-proof polyvinyl chloride cable Pending CN107011593A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201710288426.5A CN107011593A (en) 2017-04-27 2017-04-27 A kind of expansibility flame-proof polyvinyl chloride cable

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201710288426.5A CN107011593A (en) 2017-04-27 2017-04-27 A kind of expansibility flame-proof polyvinyl chloride cable

Publications (1)

Publication Number Publication Date
CN107011593A true CN107011593A (en) 2017-08-04

Family

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Family Applications (1)

Application Number Title Priority Date Filing Date
CN201710288426.5A Pending CN107011593A (en) 2017-04-27 2017-04-27 A kind of expansibility flame-proof polyvinyl chloride cable

Country Status (1)

Country Link
CN (1) CN107011593A (en)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107556830A (en) * 2017-10-17 2018-01-09 刘勇 A kind of cable fireproof coating
CN109082232A (en) * 2018-08-16 2018-12-25 东莞市万维电子科技有限公司 A kind of flame retardant type alkyd resin insulated paint

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1962746A (en) * 2006-12-07 2007-05-16 上海化工研究院 Expansion type flame-proof smoke-suppressing soft polyvinyl chloride composition and its preparation method
CN102993598A (en) * 2012-10-22 2013-03-27 江苏晨电太阳能光电科技有限公司 Flame-resistant polyvinyl chloride cable material
CN103524562A (en) * 2013-09-25 2014-01-22 江苏长顺高分子材料研究院有限公司 Cyclotriphosphazene compound with hydroxyl structure and preparation method thereof
CN104177736A (en) * 2014-09-17 2014-12-03 朱忠良 Polyvinyl chloride cable material and processing technique thereof

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1962746A (en) * 2006-12-07 2007-05-16 上海化工研究院 Expansion type flame-proof smoke-suppressing soft polyvinyl chloride composition and its preparation method
CN102993598A (en) * 2012-10-22 2013-03-27 江苏晨电太阳能光电科技有限公司 Flame-resistant polyvinyl chloride cable material
CN103524562A (en) * 2013-09-25 2014-01-22 江苏长顺高分子材料研究院有限公司 Cyclotriphosphazene compound with hydroxyl structure and preparation method thereof
CN104177736A (en) * 2014-09-17 2014-12-03 朱忠良 Polyvinyl chloride cable material and processing technique thereof

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
李巧玲等: "《新型磷-氮阻燃剂N,N′-双( 2-氧-5, 5-二甲基-1, 3, 2-二氧磷杂环己烷)-2, 2′-间苯二胺的合成研究》", 《化学世界》 *

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107556830A (en) * 2017-10-17 2018-01-09 刘勇 A kind of cable fireproof coating
CN109082232A (en) * 2018-08-16 2018-12-25 东莞市万维电子科技有限公司 A kind of flame retardant type alkyd resin insulated paint

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Application publication date: 20170804

RJ01 Rejection of invention patent application after publication