CN107010773A - Ore deposit magnetic pipeline type water purifier - Google Patents
Ore deposit magnetic pipeline type water purifier Download PDFInfo
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- CN107010773A CN107010773A CN201611148439.4A CN201611148439A CN107010773A CN 107010773 A CN107010773 A CN 107010773A CN 201611148439 A CN201611148439 A CN 201611148439A CN 107010773 A CN107010773 A CN 107010773A
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N59/00—Biocides, pest repellants or attractants, or plant growth regulators containing elements or inorganic compounds
- A01N59/06—Aluminium; Calcium; Magnesium; Compounds thereof
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N59/00—Biocides, pest repellants or attractants, or plant growth regulators containing elements or inorganic compounds
- A01N59/16—Heavy metals; Compounds thereof
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N59/00—Biocides, pest repellants or attractants, or plant growth regulators containing elements or inorganic compounds
- A01N59/16—Heavy metals; Compounds thereof
- A01N59/20—Copper
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- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F9/00—Multistage treatment of water, waste water or sewage
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/001—Processes for the treatment of water whereby the filtration technique is of importance
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- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/46—Treatment of water, waste water, or sewage by electrochemical methods
- C02F1/461—Treatment of water, waste water, or sewage by electrochemical methods by electrolysis
- C02F1/46104—Devices therefor; Their operating or servicing
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- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/48—Treatment of water, waste water, or sewage with magnetic or electric fields
- C02F1/481—Treatment of water, waste water, or sewage with magnetic or electric fields using permanent magnets
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- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/50—Treatment of water, waste water, or sewage by addition or application of a germicide or by oligodynamic treatment
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- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/68—Treatment of water, waste water, or sewage by addition of specified substances, e.g. trace elements, for ameliorating potable water
- C02F1/683—Treatment of water, waste water, or sewage by addition of specified substances, e.g. trace elements, for ameliorating potable water by addition of complex-forming compounds
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- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2101/00—Nature of the contaminant
- C02F2101/10—Inorganic compounds
- C02F2101/20—Heavy metals or heavy metal compounds
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- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2301/00—General aspects of water treatment
- C02F2301/08—Multistage treatments, e.g. repetition of the same process step under different conditions
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2303/00—Specific treatment goals
- C02F2303/04—Disinfection
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- Agronomy & Crop Science (AREA)
- General Health & Medical Sciences (AREA)
- Pest Control & Pesticides (AREA)
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Abstract
The present invention relates to water purifier field, one kind ore deposit magnetic pipeline type water purifier, including the one-level ore deposit magnetic filter cylinder being sequentially connected are disclosed；Including：Upper lid；Outer filter cylinder；Interior filter cylinder；Interior cartridge top portion is connected with water inlet；Permeable chimney filter；In outer filter cylinder, top is connected with delivery port；Monopole magnetic focusing arrangement；Monopole magnetic focusing arrangement is sheathed on interior filter cylinder surface and forms magnetic field；Mineralization ball；It is filled in interior filter cylinder；Two grades of ore deposit magnetic filter cylinders；Ceramic filter drum；Including：Covered on three-level filter cylinder；The outer filter cylinder of three-level；Its top is connected with water inlet；Ceramic element；In filter cylinder outside three-level, its top is connected with the production mouth of a river；Purifying ball；It is filled in the outer filter cylinder of three-level.The present invention can low cost, high efficiency remove the harmful substances such as Heavy Metals in Waters element, bacterial virus.Meanwhile, generation be conducive to health cleaning, magnetization, mineralization activity water, and produce, installation cost relative moderate, it is easy to promote.
Description
Technical field
The present invention relates to water purifier field, more particularly to a kind of ore deposit magnetic pipeline type water purifier.
Background technology
Drinking public water supply, reclaimed water and other industrial waters, by the long-distance fortune of river, water treatment plant and the pipe network in city
After defeated, substantial amounts of mineral matter and various salts are dissolved in water body, have been concluded into big water clusters, while can also grow various
Bacterium, before point of use is reached, already close to saturation state, loses dissolving and cleaning capacity.
In the case where healthy and environmental protection the society of today's society leads trend, large quantities of scientific researches and engineers and technicians are right
The purification of water has carried out substantial amounts of research and development, wherein being also no lack of monograph, paper and practical product.And develop a series of
Product：
Filer element type water purifier, uses filter cartridge construction, according to different demands, and can arrange in pairs or groups different filter cores, advantage
It is that price is relatively cheap, filtering accuracy is higher (containing ultrafiltration core).Have the disadvantage filter element life shorter (such as longevity of PP cottons
Life was at 3-5 months, and the activated carbon life-span is in or so half a year, ultrafiltration life-span 1-2), water yield is small, is only suitable for drinking.
Water purification machine, uses RO reverse osmosis technologies, appears in earliest in aviation industry, be in order to be aviator solve drink
Researched and developed with water, advantage is that water outlet precision is high (except hydrone, any material all cannot get through), has the disadvantage the water mistake after purification
Yu Chun, lacks the trace element beneficial to human body, averages out one glass of pure water, to produce 3 glasss of waste water, while must electricity consumption.
Ion water machine, is two kinds of water of soda acid by water electrolysis by way of electrolysis, alkaline water is used for drinking (because human body
People is acid structure, often drinks alkaline water, can adjust acid-base balance, enhance metabolism), acid water be used for bathing (or
Person is used for sterilizing), while by electrolysis, changing the micel (subset that water is changed into 6 micels) of water.
Water magnetizing machine, advantage：By magnetization, change the micel of water, more conducively absorption of human body.Shortcoming：There is gastrointestinal disease
People use with caution because magnetized water has certain stimulation to stomach.
Central water purifier, water purifier is installed on water inlet manifold at home, the useful water of institute of family is all purified, advantage
It is life-span of filtering material length (most short also has 5 years), it is easy to operate, simultaneous with backwashing function, life-span of filtering material can be extended.Shortcoming
It is that purification precision is not especially high, if for handling drinking water, effect is not especially good.
Found by many experiments, existing product has a variety of shortcomings, such as filter element life is shorter, purification
Water afterwards is excessively pure, lacks beneficial to human body trace element, wastewater flow rate big, it is impossible to sufficiently absorb heavy metal and bacterium,
The small items such as virus.
The content of the invention
In order to solve the above-mentioned technical problem, the invention provides a kind of ore deposit magnetic pipeline type water purifier.The present invention is directed in water
The existing water purification technology of the small items such as heavy metal and bacterium, virus is difficult to the drawbacks of low cost is removed, and creatively employs
High-intensity magnetic field combination mineral reduction is adsorbed, and realizes low cost, high efficiency removal Heavy Metals in Waters element, bacterial virus etc. small
Harmful substance.The present invention makes water pass through multistage mine magnetizing method using the method for pipeline type, Adsorption of Heavy Metals and bacterium,
The small items such as virus, improve the quality of water.The present invention is added in can also being fed water by the way of the mineralising micro to be had to human body
The element of benefit, strengthens the mouthfeel of water.
The present invention concrete technical scheme be：A kind of ore deposit magnetic pipeline type water purifier, including be sequentially connected by water (flow) direction
One-level ore deposit magnetic filter cylinder；The one-level ore deposit magnetic filter cylinder includes：
Upper lid；The upper lid is provided with the water inlet and delivery port separated；
Outer filter cylinder；The outer cartridge top portion connects with top cap；
Interior filter cylinder；The interior filter cylinder is in outer filter cylinder, and interior cartridge top portion connects with top cap and connected with upper lid water inlet,
Interior filter cylinder bottom is blind end；
Permeable chimney filter；The permeable chimney filter connect in the outer filter cylinder, at the top of permeable chimney filter with top cap and with upper lid water outlet
Mouth connection；
Monopole magnetic focusing arrangement；Some monopole magnetic focusing arrangement spacer sleeves are complete to be formed on the interior filter cylinder surface
The magnetic field of filter cylinder in covering；Monopole magnetic focusing arrangement includes：
Magnet clamp；The inner peripheral surface of the Magnet clamp provided with axial direction dividing plate, the inwall of the Magnet clamp, every
Plate, interior cartridge exine surround the space to be formed and constitute permanent magnet trough；
Permanent magnet blocks；The permanent magnet blocks are in the permanent magnet trough；
Mineralization ball；The mineralization ball is filled in interior filter cylinder；
Two grades of ore deposit magnetic filter cylinders；The structure of two grades of ore deposits magnetic filter cylinder is identical with one-level ore deposit magnetic filter cylinder；
Ceramic filter drum；The ceramic filter drum includes：
Covered on three-level filter cylinder；Lid is provided with the water inlet and the production mouth of a river separated on the three-level filter cylinder；
The outer filter cylinder of three-level；The outer cartridge top portion of the three-level connects with three-level filter cylinder top cap and connected with water inlet；
Ceramic element；The ceramic element connects in the outer filter cylinder of three-level at the top of ceramic element with three-level filter cylinder top cap
And connected with the production mouth of a river；
Purifying ball；The purifying ball is filled in the outer filter cylinder of three-level.
, being capable of low cost, high efficiency removal Heavy Metals in Waters present invention employs the absorption of high-intensity magnetic field combination mineral reduction
The small harmful substance such as element, bacterial virus.
1. mineralisings operation principle
The present invention forms a mineralising interval by adding appropriate mineralization ball in filtration cartridges.Wherein mineralization ball not only may be used
With the mineralogical character of itself formation galvanic effect, to form a light electrolysis in water, and under permanent magnetism field action,
Electric field action is enhanced.The heavy metal in absorption water and bacterial virus effect are actively caught, can be with micro constant
The dissolution macro- and trace-element beneficial to health.
2. magnetizes operation principle
The present invention realizes the magnetization to water by monopole magnetic focusing arrangement, is packed into by the magnetic screen being placed on interior filter cylinder
Row shielding, and allow permanent magnet blocks to wrap filter cylinder in whole, and make the permanent magnetic field direction of each monopole magnetic focusing arrangement every
It is axially extending along interior filter cylinder under the left and right of plate.Different magnetic are put in interior filter cylinder symmetry direction according to the quantity of permanent magnet blocks
Pole, the principle according to magnetic induction line from N grades to S grades, so that interior filter cylinder is completely covered in magnetic field.
During due to needing water by interior filter cylinder, sufficient magnetization can be reached, so in design using two grades of magnetization, water enters
Enter after interior filter cylinder, by a magnetic field in interior filter cylinder, it is sufficiently magnetized in the region.By filling, moving back twice
The square process of magnetic makes the angle of the hydrogen bond in water offset about 6 °.The macromolecular mass in water is fully set to become subset.
Water there occurs that series of physicochemical is reacted by magnetized area：
Reaction one：
Chlorine residue in water reacts with water in the presence of high-intensity magnetic field and generates hydrochloric acid and hypochlorous acid, and hypochlorous acid is by decomposing
Hydrochloric acid and nascent oxygen (ozone Ο3), nascent oxygen can be sterilized, algae removal, sterilization.
And calcium, magnesium, sodium, potassium plasma generation calcium salt in hydrochloric acid ionization generation chlorion and hydrogen ion, chlorion and water,
Magnesium salts, sodium salt and sylvite etc..The generation material beneficial to people, here it is the magical place of magnetized water.Running water after magnetization
The advantage of running water is remained, the deficiency of running water is overcome, the quality of running water is improved, ordinary tap water is more convenient,
Fast, it is safe to be transformed into the healthy good water that huge numbers of families drink raw.
Water is after magnetization, and running water also there occurs other a series of reactions：
1st, hydrogen bond angle has changed over 99 degree from 105 degree；
2nd, running water becomes subset (4-6) from macromolecular mass (13-15)；
3rd, hydrone obtains energy, ordered arrangement；
4th, activity, dissolving power, penetration, surface tension are enhanced.
Reaction two：
Incrustation scale (calcium carbonate) reacts with magnetized water in the case where heating is brisk, so as to reach the effect of scale removal.
Preferably, the magnetic field intensity formed in the interior filter cylinder is 5000 Gausses.
Preferably, the Magnet clamp, dividing plate are zinc-plated iron material.
Preferably, the quantity of the permanent magnet blocks is at least 4 pieces.
Preferably, the permanent magnet blocks are NdFeB material.
Preferably, the material of the purifying ball is activated carbon.
Preferably, the permeable chimney filter bottom is opening.Bottom opening can speed up Water warfare speed,
Preferably, the mineralization ball is by carbonic acid silicon, medical stone, diatomite, Tourmaline in mass ratio 1:1:5:1 compound pressure
System is formed.
Preferably, the ceramic element is made by the raw material of following mass parts：
100-200 parts of kaolin,
50-100 parts of mild-clay,
50-100 parts of attaclay,
50-100 parts of quartz sand,
200-300 parts of diatomite in powder,
45-55 parts of activated carbon,
45-55 parts of silica,
50-100 parts of polybasic ion anti-biotic material,
The water of above-mentioned 1.4-1.6 times of raw material gross mass each in addition to polybasic ion anti-biotic material.
Preferably, the moisture content of the mild-clay, attaclay is 15-25%.
Preferably, the kaolinic fineness is 400-600 mesh.
Contain polybasic ion anti-biotic material in the ceramic element of the present invention, it utilizes ion antibacterial principle and micro- magnetoelectricity skill
Art principle, stability is good, and antibacterial activity is high, and with adsorption capacity；The anti-microbial property of filter core can be effectively improved and used
In the life-span, it is to avoid the antibiotic property of anti-biotic material is poor in conventional matrix material, service life is low and the problems such as temperature dependency too strong.
The reason for its antibacterial activity is high is：Due to containing many kinds of metal ions inside filter core, it is internally formed in filter core
Price difference between galvanic effect, this several metal causes to form potential difference between them, so may result in current
By when can because potential difference formation electric current, under the function of current the various metals in water can be caught, reduce water in respectively
Plant the content of metal.Fiber be carbonized simultaneously after has powerful adsorption capacity and vigor, can play the effect of antiseptic
To maximum.
Preferably, the preparation method of the polybasic ion anti-biotic material is：
(1) first 0.5-0.6 in mass ratio:1 mixes silica with water, then adds it to 0.4-0.6 times of quality
In water, stirring obtains suspension；By silver nitrate, zinc nitrate and magnesia each with suspension 1.5-2 in mass ratio:1 mixing, is obtained
To three kinds of solution；Three kinds of solution are controlled into ionic adsorption temperature with water-bath respectively, then three kinds of solution are mixed and continue stirring
To being completely dissolved, solution A is obtained.
Silica is first mixed with a part of water, is then then added in water, stable suspension can be so formed,
If directly mixed silica with whole water, suspension just can not be formed.After silica is combined with each metal ion, make
For carrier, stability is good.
(2) first copper is melted, then adding zinc makes zinc and copper melting mixing, then adds charcoal powder, wherein copper, zinc, wood
The mass ratio of powdered carbon is 1:1.4-1.6:2.8-3.2；Cooling down after well mixed, grinding obtains composite brass powder.
When Zn content is less than 35% in composite brass, zinc, which can be dissolved in copper, forms single-phase, as alpha brass.This Huang
Copper plasticity is good, suitable for cold and hot pressure processing, contributes to the performance of stabilizing material in the material, it helps antiseptic it is steady
It is fixed.
Note needing first to dissolve copper in preparation process, because copper is different from the solution temperature of zinc, if first solving zinc
Words can cause the zinc when not reaching the solution temperature of copper also just to be consumed by evaporation.Charcoal is added in brass, anti-biotic material can be made
There is absorption affinity under original antibacterial effect, and charcoal is as the carrier and skeleton in anti-biotic material, allow in anti-biotic material
Each metal ion species are adsorbed, for application in the material, are even more to form antibacterial film on surface, are improved sterilization rate.
(3) 1.1-1.3 in mass ratio:2 are added to composite brass powder in solution A, form mixture B；Secure ph is
In 4.2-5 salpeter solution, the salpeter solution that mixture B is added to its 1.8-2.2 times of quality；It is warming up to 100-140 DEG C；Match somebody with somebody
Ice making acetic acid and the solution that diethanol amine total concentration is 30-40wt%, added in salpeter solution, produce and precipitate and wash heavy
Form sediment, then heat up, wash repeatedly；The titanium dioxide of 0.3-0.4 times of solution quality is added into solution, is dried, after cooling,
Obtain polybasic ion anti-biotic material.
Composite brass powder is mixed with solution A, is then made in polybasic ion anti-biotic material, anti-biotic material and adds titanium dioxide
Titanium, can not only play antibacterial action, and can increase the stabilization of powder whiteness and resistance to elevated temperatures.
The antiseptic added in current matrix material is generally following three class：Quaternary ammonium salt antiseptic, quaternary phosphonium salt class
Antiseptic, the antiseptic containing organotin groups.But there is respective shortcoming in above-mentioned three kinds of antiseptics：
(1) antibacterial ability of the matrix material of the antiseptic containing quaternary ammonium salt is influenceed larger by chain alkyl.It is because of it
In R1The length of chain is larger to antibacterial capacity, when amount of carbon atom particularly therein is not between 10-16, antiseptic
There is no lethality substantially to bacterium, so just having to carbon atom control between, antiseptic just can be effective but this
Not only cost height is also difficult to reach for technology and this requirement.
(2) antiseptic containing the quaternary phosphonium salt class antibacterial activity in the case of ion is close is poor.This antiseptic only exists
In the case of forming free ion, antibacterial activity just can be enlivened more, also just said, be only improved the content of quaternary phosphonium salt monomer,
Its antibacterial activity can be improved.Although present technology can synthesize the polymer containing sulfonium group, than small molecule antibacterial activity
It is better, but the heat endurance of this antiseptic is poor.And not only effect difference is not more importantly for the antiseptic under this environment
Safety.
(3) antiseptic containing organotin groups is relatively low for the killing rate of gram-negative cells.Such case is caused to go out
Existing the reason for is because after monomer copolymerization, due to the decline of antibacterial radical concentration, antibacterial activity also declines therewith.This ion list
Body copolymerization is the reaction for making several monomer molecules activate into ion by the effect of catalyst and carrying out copolymerization, this be at this stage this
Plant the main synthetic method of antiseptic.Because this synthetic method has good killing rate to golden yellow grape coccus,
The problem of overcoming its killing rate to gram-negative cells low is the emphasis for being now to solve.
The polybasic ion anti-biotic material of the present invention utilizes ion antibacterial principle and micro- magnetoelectricity field technology principle, forms one kind
New and effective antibacterial added material.It is effectively improved the anti-microbial property and service life of matrix material, it is to avoid traditional antibacterial
The antibiotic property of material is low, low service life and the problems such as too strong temperature dependency, meets general magnetoelectricity matrix material
Social demand.Its advantage is specially：
(1) polybasic ion anti-biotic material improves antibacterial ability by the method for ion antibacterial.For above-mentioned three kinds of antibacterials
Agent produced problem, the polybasic ion anti-biotic material for matrix material is on the basis of magnetoelectricity, by the means of ion antibacterial,
Absorption exchanges various ions, stabilizes R1The length of chain, is controlled in controlled range, antibiotic property is reached most active shape
State.And close state occur for ion and cause the problem of antibacterial activity is poor, can be by single season phosphine in ion exchange
Salt monomer content improves to improve antibacterial activity.And ion monomer copolymerization can use ion-exchange to break this situation,
And various harmless ions can be added to improve anti-microbial property.
(2) polybasic ion anti-biotic material can effective interference cell wall synthesis.Bacteria cell wall important component is poly- for peptide
Sugar, ion antibacterial agent is to the interference effect of cell membrane, and the main polysaccharide chain that suppresses is crosslinked with linking with tetrapeptide, so that cell membrane loses
Integrality is gone, the protective effect to osmotic pressure is lost, thalline is damaged and dead.
Polybasic ion anti-biotic material can damaging cells film.Cell membrane is the important part of bacterial cell vital movement.
Therefore, such as damaged membrane wound, destruction, bacterial death will be caused.
Polybasic ion anti-biotic material can suppress the synthesis of protein.The building-up process of protein changes, stops, making bacterium
It is dead.Protein is material base for bacterium, is organic macromolecule, is the basic organic matter for constituting cell, is life
The main undertaker of activity.There is no protein just without life, and ion-exchange breaks the ring building-up process of protein, makes whole
Individual process change stops, and such bacterium just stops growing or dead.
Polybasic ion anti-biotic material can interfere with the synthesis of nucleic acid.It is in a word the duplication for hindering hereditary information, including
DNA, RNA synthesis, and DNA profiling transcript mRNA etc..
(3) service life of the matrix material added with polybasic ion anti-biotic material is long.The service life one of matrix material
As and it is anti-oxidant directly related, oxidation resistance is better, and service life is longer；It is on the contrary then opposite.And polybasic ion antibacterial material
The anti-oxidant reinforcement of material is realized by the technology of ion antibacterial, is strengthened oxidative resistance, can be allowed it within a certain period of time
Its intrinsic attribute is kept, it is not oxidized, extend its service life.And ion exchange can add oxidation resistant ion, make
Material starvation, anti-oxidant, the increase service life of lifting material.So in contrast to other materials, added with it is polynary from
The matrix material service life of sub- anti-biotic material can be long.
The present invention strengthens the ionization activity and intensity of composite metal ion by magnetic field, is effectively improved antibacterial sterilizing
Performance, effectively prevents the growth of bacterium.
Preferably, in step (1), heating water bath is to 28-35 DEG C.
Preferably, in step (3), the consumption of the solution of glacial acetic acid and diethanol amine is salpeter solution matter during washing every time
0.4-0.6 times of amount；In the solution of the glacial acetic acid and diethanol amine, the mass ratio of glacial acetic acid and diethanol amine is 1:1.5-
2.5。
Preferably, in step (3), drying temperature is 80-100 DEG C.
A kind of preparation method of ceramic element, comprises the following steps：
(A) dispensing：Kaolin, mild-clay, attaclay, quartz sand, diatomite in powder, activated carbon are weighed respectively by proportioning
Containers for future use is each positioned over silica.
(B) ball milling：Ready raw material is put into ball mill, added after the water of formula ratio, ball milling 8-12min, plus
Enter polybasic ion anti-biotic material, continue to take out after ball milling mixing 8-12min, cross 60-100 mesh sieves and obtain mud.
Each material mixture homogeneity is high after ball milling, and fineness is homogeneous, is easy to follow-up sintering process.
(C) sinter：Mud is mixed, is then placed in after molding in mould, the demoulding and obtains wet base, wet base is put
Fully dried at aeration-drying；Dried base substrate is sintered, at 22-28 DEG C of initial temperature, through 30-50min liters
Temperature is warming up to 800-950 DEG C to 400-600 DEG C, then through 30-50min, is most warming up to 1200-1300 DEG C through 30-50min afterwards；Protect
Room temperature is freely cooled to after warm 20-40min.
The present invention uses many gradient increased temperature sintering circuits, enables to the base substrate after sintering to be internally formed the three dimensional network of densification
Network structure, good filtration effect.
(D) post-process：After base substrate after cooling is polished and cut, ceramic element is made.
Preferably, in step (B), the quality of ball is kaolin, mild-clay, attaclay, stone in the ball mill
Sand, diatomite in powder, 1.25-1.75 times of activated carbon and silica gross mass.
Preferably, in step (C), patternmaking process is：Mould inner surface is soaked, mud is poured into mould, midge
After 30-50min, unnecessary mud, equating mould base mouthful are poured out, then stand the demoulding after 40-80min.
It is compared with the prior art, the beneficial effects of the invention are as follows：
1. the present invention is directed to the harmful toxic matter such as heavy metal and bacterium, virus in water, existing water purification technology is difficult to low cost
The drawbacks of removal, the absorption of high-intensity magnetic field combination mineral reduction is creatively employed, realize low cost, high efficiency and remove in water body
The harmful substances such as heavy metal element, bacterial virus.
, can be with big flow, low cost, efficient, by ordinary tap water 2. the present invention is using the method for pipeline type
Harmful toxic matter remove while, generation be conducive to health cleaning, magnetization, mineralization activity water, and produce, installation cost it is relative
It is cheap, it is easy to promote.
Brief description of the drawings
Fig. 1 is a kind of structural representation of the invention；
Fig. 2 is a kind of structural representation of monopole magnetic focusing arrangement of the present invention.
Reference is：One-level ore deposit magnetic filter cylinder 1, two grades of ore deposit magnetic filter cylinders 2, ceramic filter drum 3, upper lid 11, outer filter cylinder 12, interior filters
Cylinder 13, permeable chimney filter 14, monopole magnetic focusing arrangement 15, mineralization ball 16, lid 31, three-level outer filter cylinder 32, ceramic filtering on three-level filter cylinder
Core 33, purifying ball 34, water inlet 111, delivery port 112, Magnet clamp 151, dividing plate 152, permanent magnet blocks 153, water inlet 311,
Produce the mouth of a river 312.
Embodiment
With reference to embodiment, the invention will be further described.
Embodiment 1
As shown in figure 1, a kind of ore deposit magnetic pipeline type water purifier, including be sequentially connected by water (flow) direction
One-level ore deposit magnetic filter cylinder 1；The one-level ore deposit magnetic filter cylinder includes：
Upper lid 11；The upper lid is provided with the water inlet 111 and delivery port 112 separated；
Outer filter cylinder 12；The outer cartridge top portion connects with top cap；
Interior filter cylinder 13；The interior filter cylinder is in outer filter cylinder, and interior cartridge top portion connects with top cap and connected with upper lid water inlet
Logical, interior filter cylinder bottom is blind end；
Permeable chimney filter 14；The permeable chimney filter connects with top cap and covered out with the top of permeable chimney filter in outer filter cylinder
The mouth of a river is connected；Permeable chimney filter bottom is opening.
Monopole magnetic focusing arrangement 15；Some monopole magnetic focusing arrangement spacer sleeves are located on the interior filter cylinder surface to have been formed
The intensity of filter cylinder is the magnetic field of 5000 Gausses in all standing；As shown in Fig. 2 monopole magnetic focusing arrangement includes：
Magnet clamp 151；The inner peripheral surface of the Magnet clamp provided with axial direction dividing plate 152, the Magnet clamp it is interior
Wall, dividing plate, interior cartridge exine surround the space to be formed and constitute permanent magnet trough；The Magnet clamp, dividing plate are zinc-plated iron material.
Permanent magnet blocks (neodymium iron boron) 153；Eight pieces of permanent magnet blocks are in the permanent magnet trough；
Mineralization ball 16；The mineralization ball is filled in interior filter cylinder；Mineralization ball is by carbonic acid silicon, medical stone, diatomite, Tourmaline
In mass ratio 1:1:5:1 is compositely suppressed to form.
Two grades of ore deposit magnetic filter cylinders 2；The structure of two grades of ore deposits magnetic filter cylinder is identical with one-level ore deposit magnetic filter cylinder；
Ceramic filter drum 3；The three-level filter cylinder includes：
Lid 31 on three-level filter cylinder；Lid is provided with the water inlet 311 and the production mouth of a river 312 separated on the three-level filter cylinder；
The outer filter cylinder 32 of three-level；The outer cartridge top portion of the three-level connects with three-level filter cylinder top cap and connected with water inlet；
Ceramic element 33；The ceramic element is in the outer filter cylinder of three-level, with three-level filter cylinder top cap at the top of ceramic element
Connect and connected with the production mouth of a river；
Purifying ball (activated carbon) 34；The purifying ball is filled in the outer filter cylinder of three-level.
Embodiment 2
Ceramic element in embodiment 1, is made by the raw material of following mass parts：
150 parts of kaolin (fineness is 500 mesh),
75 parts of mild-clay (moisture content is 20%),
75 parts of attaclay (moisture content is 20%),
75 parts of quartz sand,
2500 parts of diatomite in powder,
50 parts of activated carbon,
50 parts of silica,
75 parts of polybasic ion anti-biotic material,
The water of above-mentioned 1.5 times of raw material gross mass each in addition to polybasic ion anti-biotic material.
The preparation method of above-mentioned ceramic element, comprises the following steps：
(A) dispensing：Kaolin, mild-clay, attaclay, quartz sand, diatomite in powder, activated carbon are weighed respectively by proportioning
Containers for future use is each positioned over silica.
(B) ball milling：Ready raw material is put into ball mill, added after the water of formula ratio, ball milling 10min, is added
Polybasic ion anti-biotic material, continues to take out after ball milling mixing 10min, crosses 80 mesh sieves and obtain mud.Wherein, ball in the ball mill
Quality be kaolin, mild-clay, attaclay, quartz sand, diatomite in powder, the 1.5 of activated carbon and silica gross mass
Times.
(C) sinter：Mud is mixed, then mould inner surface is soaked, mud is poured into mould, midge
After 40min, unnecessary mud, equating mould base mouthful are poured out, then stand the demoulding after 60min.Wet base is obtained after the demoulding, wet base is put in
Fully dried at aeration-drying；Dried base substrate is sintered, at 25 DEG C of initial temperature, 500 are warming up to through 40min
DEG C, then 875 DEG C are warming up to through 40min, most it is warming up to 1250 DEG C through 40min afterwards；Room temperature is freely cooled to after insulation 30min.
(D) post-process：After base substrate after cooling is polished and cut, ceramic element is made.
Wherein, the polybasic ion anti-biotic material, is made by following methods：
(1) first in mass ratio 0.55:1 mixes silica with water, then adds it in the water of 0.5 times of quality, stirs
Mix and obtain suspension；By silver nitrate, zinc nitrate and magnesia each with suspension in mass ratio 1.8:1 mixing, obtain three kinds it is molten
Liquid；Three kinds of solution are mixed and continued stirring until to 30 DEG C, then with heating water bath respectively by three kinds of solution and are completely dissolved, are obtained
Solution A.
(2) first copper is melted, then adding zinc makes zinc and copper melting mixing, then adds charcoal powder, wherein copper, zinc, wood
The mass ratio of powdered carbon is 1:1.5:3；Cooling down after well mixed, grinding obtains composite brass powder.
(3) in mass ratio 1.2:2 are added to composite brass powder in solution A, form mixture B；PH value is 4.6 nitric acid
In solution, the salpeter solution that mixture B is added to its 2 times of quality；It is warming up to 120 DEG C；Prepare glacial acetic acid and diethanol amine is total
(mass ratio of glacial acetic acid and diethanol amine is 1 to the solution that concentration is 35wt%:2), added in salpeter solution, precipitation is produced simultaneously
Washing precipitation, then heats up, washs in triplicate；The consumption of the solution of glacial acetic acid and diethanol amine is molten for nitric acid during washing every time
0.5 times of liquid quality.The titanium dioxide of solution quality 1/3 is added into solution, 90 DEG C of drying after cooling, obtain polybasic ion
Anti-biotic material.
Embodiment 3
Ceramic element in embodiment 1, can also be made by the raw material of following mass parts：
100 parts of kaolin (fineness is 400 mesh),
50- parts of mild-clay (moisture content is 15%),
50 parts of attaclay (moisture content is 15%),
50 parts of quartz sand,
200 parts of diatomite in powder,
45 parts of activated carbon,
45 parts of silica,
50 parts of polybasic ion anti-biotic material,
The water of above-mentioned 1.4 times of raw material gross mass each in addition to polybasic ion anti-biotic material.
The preparation method of above-mentioned ceramic element, comprises the following steps：
(A) dispensing：Kaolin, mild-clay, attaclay, quartz sand, diatomite in powder, activated carbon are weighed respectively by proportioning
Containers for future use is each positioned over silica.
(B) ball milling：Ready raw material is put into ball mill, added after the water of formula ratio, ball milling 8min, is added many
First ion antibacterial material, continues to take out after ball milling mixing 8min, crosses 60 mesh sieves and obtain mud.Wherein, ball in the ball mill
Quality is the 1.25 of kaolin, mild-clay, attaclay, quartz sand, diatomite in powder, activated carbon and silica gross mass
Times.
(C) sinter：Mud is mixed, then mould inner surface is soaked, mud is poured into mould, midge
After 30min, unnecessary mud, equating mould base mouthful are poured out, then stand the demoulding after 40min.Wet base is obtained after the demoulding, wet base is put in
Fully dried at aeration-drying；Dried base substrate is sintered, at 22 DEG C of initial temperature, 400 are warming up to through 30min
DEG C, then 800 DEG C are warming up to through 30min, most it is warming up to 1200 DEG C through 30min afterwards；Room temperature is freely cooled to after insulation 40min.
(D) post-process：After base substrate after cooling is polished and cut, ceramic element is made.
Wherein, polybasic ion anti-biotic material, is made by following methods：
(1) first in mass ratio 0.5:1 mixes silica with water, then adds it in the water of 0.4 times of quality, stirring
Obtain suspension；By silver nitrate, zinc nitrate and magnesia each with suspension in mass ratio 1.5:1 mixing, obtains three kinds of solution；
Three kinds of solution are mixed and continued stirring until to 28 DEG C, then with heating water bath respectively by three kinds of solution and are completely dissolved, obtain molten
Liquid A.
(2) first copper is melted, then adding zinc makes zinc and copper melting mixing, then adds charcoal powder, wherein copper, zinc, wood
The mass ratio of powdered carbon is 1:1.4:2.8；Cooling down after well mixed, grinding obtains composite brass powder.
(3) in mass ratio 1.2:2 are added to composite brass powder in solution A, form mixture B；Secure ph is 4.2
In salpeter solution, the salpeter solution that mixture B is added to its 1.8 times of quality；It is warming up to 100 DEG C；Prepare glacial acetic acid and diethyl
(mass ratio of glacial acetic acid and diethanol amine is 1 to the solution that hydramine total concentration is 30wt%:1.5), added in salpeter solution, production
It is raw to precipitate and wash precipitation, then heat up, wash repetition three；The consumption of the solution of glacial acetic acid and diethanol amine is during washing every time
0.4 times of salpeter solution quality.The titanium dioxide of 0.3 times of solution quality is added into solution, 80 DEG C of drying after cooling, are obtained
Polybasic ion anti-biotic material.
Embodiment 4
Ceramic element in embodiment 1, can also be made by the raw material of following mass parts：
200 parts of kaolin (fineness is 600 mesh),
50-100 parts of mild-clay (moisture content is 25%),
100 parts of attaclay (moisture content is 25%),
100 parts of quartz sand,
300 parts of diatomite in powder,
55 parts of activated carbon,
55 parts of silica,
100 parts of polybasic ion anti-biotic material,
The water of above-mentioned 1.6 times of raw material gross mass each in addition to polybasic ion anti-biotic material.
The preparation method of above-mentioned ceramic element, comprises the following steps：
(A) dispensing：Kaolin, mild-clay, attaclay, quartz sand, diatomite in powder, activated carbon are weighed respectively by proportioning
Containers for future use is each positioned over silica.
(B) ball milling：Ready raw material is put into ball mill, added after the water of formula ratio, ball milling 12min, is added
Polybasic ion anti-biotic material, continues to take out after ball milling mixing 12min, crosses 100 mesh sieves and obtain mud.Wherein, in the ball mill
The quality of ball is kaolin, mild-clay, attaclay, quartz sand, diatomite in powder, activated carbon and silica gross mass
1.75 again.
(C) sinter：Mud is mixed, then mould inner surface is soaked, mud is poured into mould, midge
After 50min, unnecessary mud, equating mould base mouthful are poured out, then stand the demoulding after 80min.Wet base is obtained after the demoulding, wet base is put in
Fully dried at aeration-drying；Dried base substrate is sintered, at -28 DEG C of initial temperature, 600 are warming up to through 50min
DEG C, then 950 DEG C are warming up to through 50min, most it is warming up to 1300 DEG C through 50min afterwards；Room temperature is freely cooled to after insulation 20min.
(D) post-process：After base substrate after cooling is polished and cut, ceramic element is made.
Wherein, polybasic ion anti-biotic material, is made by following methods：
(1) first in mass ratio 0.6:1 mixes silica with water, then adds it in the water of 0.6 times of quality, stirring
Obtain suspension；By silver nitrate, zinc nitrate and magnesia each with suspension in mass ratio 2:1 mixing, obtains three kinds of solution；Will
Three kinds of solution are mixed and continued stirring until to 35 DEG C, then with heating water bath respectively and are completely dissolved by three kinds of solution, obtain solution
A。
(2) first copper is melted, then adding zinc makes zinc and copper melting mixing, then adds charcoal powder, wherein copper, zinc, wood
The mass ratio of powdered carbon is 1:1.6:3.2；Cooling down after well mixed, grinding obtains composite brass powder.
(3) 1.1-1.3 in mass ratio:2 are added to composite brass powder in solution A, form mixture B；Secure ph is 5
Salpeter solution, in the salpeter solution that mixture B is added to its 2.2 times of quality；It is warming up to 140 DEG C；Prepare glacial acetic acid and two
(mass ratio of glacial acetic acid and diethanol amine is 1 to the solution that monoethanolamine total concentration is 40wt%:2.5), added in salpeter solution,
Produce and precipitate and wash precipitation, then heat up, wash in triplicate；The use of the solution of glacial acetic acid and diethanol amine when washing every time
Measure as 0.6 times of salpeter solution quality.The titanium dioxide of 0.4 times of solution quality is added into solution, 100 DEG C dry, after cooling,
Obtain polybasic ion anti-biotic material.
Raw materials used in the present invention, equipment, is the conventional raw material, equipment of this area unless otherwise noted；In the present invention
Method therefor, is the conventional method of this area unless otherwise noted.
It is described above, only it is presently preferred embodiments of the present invention, not the present invention is imposed any restrictions, it is every according to the present invention
Any simple modification, change and equivalent transformation that technical spirit is made to above example, still fall within the technology of the present invention side
The protection domain of case.
Claims (10)
1. a kind of ore deposit magnetic pipeline type water purifier, it is characterised in that：Including what is be sequentially connected by water (flow) direction
One-level ore deposit magnetic filter cylinder (1)；The one-level ore deposit magnetic filter cylinder includes：
Upper lid (11)；The upper lid is provided with the water inlet (111) and delivery port (112) separated；
Outer filter cylinder (12)；The outer cartridge top portion connects with top cap；
Interior filter cylinder (13)；The interior filter cylinder is in outer filter cylinder, and interior cartridge top portion connects with top cap and connected with upper lid water inlet,
Interior filter cylinder bottom is blind end；
Permeable chimney filter (14)；The permeable chimney filter connect in the outer filter cylinder, at the top of permeable chimney filter with top cap and with upper lid water outlet
Mouth connection；
Monopole magnetic focusing arrangement (15)；Some monopole magnetic focusing arrangement spacer sleeves are complete to be formed on the interior filter cylinder surface
The magnetic field of filter cylinder in covering；Monopole magnetic focusing arrangement includes：
Magnet clamp (151)；The inner peripheral surface of the Magnet clamp provided with axial direction dividing plate (152), the Magnet clamp it is interior
Wall, dividing plate, interior cartridge exine surround the space to be formed and constitute permanent magnet trough；
Permanent magnet blocks (153)；The permanent magnet blocks are in the permanent magnet trough；
Mineralization ball (16)；The mineralization ball is filled in interior filter cylinder；
Two grades of ore deposit magnetic filter cylinders (2)；The structure of two grades of ore deposits magnetic filter cylinder is identical with one-level ore deposit magnetic filter cylinder；
Ceramic filter drum (3)；The ceramic filter drum includes：
(31) are covered on three-level filter cylinder；Lid is provided with the water inlet (311) and the production mouth of a river (312) separated on the three-level filter cylinder；
The outer filter cylinder (32) of three-level；The outer cartridge top portion of the three-level connects with three-level filter cylinder top cap and connected with water inlet；
Ceramic element (33)；The ceramic element connects in the outer filter cylinder of three-level at the top of ceramic element with three-level filter cylinder top cap
And connected with the production mouth of a river；
Purifying ball (34)；The purifying ball is filled in the outer filter cylinder of three-level.
2. ore deposit magnetic pipeline type water purifier as claimed in claim 1, it is characterised in that the magnetic field intensity formed in the interior filter cylinder
For 5000 Gausses.
3. ore deposit magnetic pipeline type water purifier as claimed in claim 1, it is characterised in that the Magnet clamp, dividing plate are galvanized iron
Material.
4. ore deposit magnetic pipeline type water purifier as claimed in claim 1, it is characterised in that the quantity of the permanent magnet blocks is at least 4
Block.
5. ore deposit magnetic pipeline type water purifier as claimed in claim 1, it is characterised in that the permanent magnet blocks are NdFeB material.
6. ore deposit magnetic pipeline type water purifier as claimed in claim 1, it is characterised in that the material of the purifying ball is activated carbon.
7. ore deposit magnetic pipeline type water purifier as claimed in claim 1, it is characterised in that the permeable chimney filter bottom is opening.
8. ore deposit magnetic pipeline type water purifier as claimed in claim 1, it is characterised in that the mineralization ball by carbonic acid silicon, medical stone,
Diatomite, Tourmaline in mass ratio 1:1:5:1 is compositely suppressed to form.
9. ore deposit magnetic pipeline type water purifier as claimed in claim 1, it is characterised in that the ceramic element is by following mass parts
Raw material is sequentially passed through and is made after batch mixing, ball milling, sintering, post processing：
100-200 parts of kaolin,
50-100 parts of mild-clay,
50-100 parts of attaclay,
50-100 parts of quartz sand,
200-300 parts of diatomite in powder,
45-55 parts of activated carbon,
45-55 parts of silica,
50-100 parts of polybasic ion anti-biotic material,
The water of above-mentioned 1.4-1.6 times of raw material gross mass each in addition to polybasic ion anti-biotic material.
10. ore deposit magnetic pipeline type water purifier as claimed in claim 1, it is characterised in that the system of the polybasic ion anti-biotic material
Preparation Method is：
(1) first 0.5-0.6 in mass ratio:1 mixes silica with water, then adds it in the water of 0.4-0.6 times of quality,
Stirring obtains suspension；By silver nitrate, zinc nitrate and magnesia each with suspension 1.5-2 in mass ratio:1 mixing, obtains three
Plant solution；Three kinds of solution are controlled into ionic adsorption temperature with water-bath respectively, then three kinds of solution are mixed and continued stirring until
Fully dissolved, obtains solution A；
(2) first copper is melted, then adding zinc makes zinc and copper melting mixing, then adds charcoal powder, wherein copper, zinc, charcoal powder
Mass ratio be 1:1.4-1.6:2.8-3.2；Cooling down after well mixed, grinding obtains composite brass powder；
(3) 1.1-1.3 in mass ratio:2 are added to composite brass powder in solution A, form mixture B；Secure ph is 4.2-5
Salpeter solution, in the salpeter solution that mixture B is added to its 1.8-2.2 times of quality；It is warming up to 100-140 DEG C；With ice making
Acetic acid and the solution that diethanol amine total concentration is 30-40wt%, added in salpeter solution, produce and precipitate and wash precipitation, so
Heat up, washed repeatedly afterwards；The titanium dioxide of 0.3-0.4 times of solution quality is added into solution, drying after cooling, is obtained
Polybasic ion anti-biotic material.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201611148439.4A CN107010773A (en) | 2016-12-13 | 2016-12-13 | Ore deposit magnetic pipeline type water purifier |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201611148439.4A CN107010773A (en) | 2016-12-13 | 2016-12-13 | Ore deposit magnetic pipeline type water purifier |
Publications (1)
| Publication Number | Publication Date |
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| CN107010773A true CN107010773A (en) | 2017-08-04 |
Family
ID=59440073
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201611148439.4A Pending CN107010773A (en) | 2016-12-13 | 2016-12-13 | Ore deposit magnetic pipeline type water purifier |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110104850A (en) * | 2019-05-30 | 2019-08-09 | 南京公诚节能新材料研究院有限公司 | Intelligent multi-section type running water water purifier |
-
2016
- 2016-12-13 CN CN201611148439.4A patent/CN107010773A/en active Pending
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110104850A (en) * | 2019-05-30 | 2019-08-09 | 南京公诚节能新材料研究院有限公司 | Intelligent multi-section type running water water purifier |
| WO2020237812A1 (en) * | 2019-05-30 | 2020-12-03 | 南京公诚节能新材料研究院有限公司 | Intelligent multi-section water activation purifier |
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Application publication date: 20170804 |