A kind of Water filtration structure
Technical field
The present invention relates to a kind of Water filtration structure.
Background technology
Common Household water tap does not have a filter effect, and the filter effect of traditional anion filtering tap compared with
Difference, it is impossible to effectively get rid of the particulate matter and harmful substance in water.As industry is developed rapidly, in factory's three wastes and sanitary sewage
Contained substantial amounts of toxic organicses and heavy metal ion, seriously pollute poisonous and harmfulization in drinking water source, water body
Pollutant load is learned year by year to rise.The conventional water treatment process of drinking water can not efficiently go dissolubility in water removal poisonous and harmful
Material, needs badly develop a kind of new Water filtration structure at present.Polypropylene has a good chemical stability, acid and alkali-resistance, resistance to
High temperature, corrosion-resistant and cheap, biologic packing material, microporous barrier for being made using polypropylene as raw material etc. have been widely used for
In water treatment field.Polypropylene superfine fiber melt-blown filter is a kind of novel microporous filter medium that developed recently gets up.It by
The hot melt entanglement of superfine polypropylene fiber is made, and superfine fibre is by itself bonding and tangles, and forms space random mixed and disorderly three-dimensional micro-
Pore structure, and radial fiber changes in gradient, is the synthesis of porous type and textile type filter medium, can with filtering accuracy
Lean on, the rate of filtration is high, pollutant carrying capacity big, length filter cycle, easy backwash, operating cost is low, bulk density is small and changes filter
The advantages of core is convenient.It has been widely used in Drinking Water purification, the filtering of industrial pure water and the filtering of other fluids.
The invention provides Water filtration structure, PP cottons used in Water filtration structure have good bactericidal property and heavy metal from
Sub- absorption property.
The content of the invention
The technical problem to be solved in the present invention is to provide a kind of particulate matter and harmful substance that can effectively get rid of in water
Water filtration structure.
To solve the above problems, the present invention is adopted the following technical scheme that:
Water inlet pipe is provided with a kind of Water filtration structure, including screen pipe, the lower end shaft core position of the screen pipe, it is described
External screw thread is provided with the outer wall position of that one end of water inlet pipe away from the screen pipe, and is connected by the external screw thread with unification
The flexible pipe of water receiving net, the flexible pipe, which has, coordinates externally threaded thread bush, and upper end cover is internally provided with the screen pipe
And bottom end cover, the bottom of the upper end cover is provided with core, PP cottons is combined between the upper end cover and the bottom end cover, described
Interference fits between PP cottons and the core, in the granulated carbon that is internally provided with of the PP cottons, the lower surface of the bottom end cover is equal
Inlet opening is furnished with, the water inlet pipe is relative with the inlet opening, the surface annular of the upper end cover is provided with multiple apopores, institute
The outside that apopore is located at the PP cottons is stated, the first dividing plate and second partition is provided with above the upper end cover, described the
The surface of one dividing plate and the second partition is evenly equipped with the first apopore, is combined between first dividing plate and the upper end cover
Medical stone, is combined with NACF, in the top of the second partition between first dividing plate and the second partition
Milipore filter is provided with, the top of the screen pipe connects an end cap, is threadedly coupled between the end cap and the screen pipe, in institute
State and depotition cock is provided with the top of end cap, the depotition cock has the valve of water management.
Preferably, the preparation method of the PP cottons comprises the following steps, and described part is parts by weight:
S1:5-10 parts of PP, 1-4 parts of diatomite, 0.005-0.05 parts of zinc oxide are poured into screw extruder and extruded, and
Cut into master batch;
S2:The masterbatch that 10-70 parts of PP and S1 steps are obtained is well mixed, and PP fibers are meltblown into using melt-blowing equipment, and
PP cottons are wound in, PP cotton products are obtained.
Preferably, the preparation method of the PP cottons comprises the following steps, and described part is parts by weight:
S1:The diatomite of 5-10 parts of PP, 1-4 parts of modifications, 0.005-0.05 parts of zinc oxide are poured into screw extruder to carry out
Extrusion, and cut into master batch;The diatomaceous preparation method of the modification is as follows:10-15 parts of diatomite are added to 80-100
In part water, 20-40 DEG C, 500-800rpm stirring 1-2h add 0.5-1.5 parts of modifying agent, 50-150W power, 30-60kHz frequencies
Rate ultrasound 30-50min, 1000-3000rpm centrifugation 40-80min, removes clear liquid, the solid 300- that centrifugation is obtained after centrifugation
500 parts of water are rinsed, and the solid after flushing obtains modified diatomite in 50-80 DEG C of dry 12-24h;The modifying agent is marine alga
Sour sodium;
S2:The masterbatch that 10-70 parts of PP and S1 steps are obtained is well mixed, and PP fibers are meltblown into using melt-blowing equipment, and
PP cottons are wound in, PP cotton products are obtained.
Preferably, the preparation method of the PP cottons comprises the following steps, and described part is parts by weight:
S1:The diatomite of 5-10 parts of PP, 1-4 parts of modifications, 0.005-0.05 parts of zinc oxide are poured into screw extruder to carry out
Extrusion, and cut into master batch;
The diatomaceous preparation method of the modification is as follows:10-15 parts of diatomite are added in 80-100 parts of water, 20-
40 DEG C, 500-800rpm stirring 1-2h, add 0.5-1.5 parts of modifying agent, 50-150W power, 30-60kHz frequency ultrasounds 30-
50min, 1000-3000rpm centrifuge 40-80min, remove clear liquid after centrifugation, obtain solid, 2-4 parts of glacial acetic acid are added into 60-
In 100 parts of water, 30-50 DEG C, 500-800rpm stirring 3-5min add 0.5-5 parts of chitosans, 30-50 DEG C, 500-800rpm stirs
30-60min is mixed, chitosan solution is obtained, the solid after centrifugation is added in chitosan solution, 30-50 DEG C, 500-800rpm
3-5h, 1000-3000rpm centrifugation 40-80min are stirred, clear liquid is removed after centrifugation, obtained solid will be centrifuged with 300-500 parts
Water is rinsed, and the solid after flushing obtains modified diatomite in 50-80 DEG C of dry 12-24h;The modifying agent is sodium alginate;
S2:The masterbatch that 10-70 parts of PP and S1 steps are obtained is well mixed, and PP fibers are meltblown into using melt-blowing equipment, and
PP cottons are wound in, PP cotton products are obtained.
Preferably, the preparation method of the PP cottons comprises the following steps, and described part is parts by weight:
S1:The diatomite of 5-10 parts of PP, 1-4 parts of modifications, 0.005-0.05 parts of zinc oxide are poured into screw extruder to carry out
Extrusion, and cut into master batch;
The diatomaceous preparation method of the modification is as follows:10-15 parts of diatomite are added in 80-100 parts of water, 20-
40 DEG C, 500-800rpm stirring 1-2h, add 0.5-1.5 parts of modifying agent, 50-150W power, 30-60kHz frequency ultrasounds 30-
50min, 1000-3000rpm centrifuge 40-80min, remove clear liquid after centrifugation, obtain solid, 2-4 parts of glacial acetic acid are added into 60-
In 100 parts of water, 30-50 DEG C, 500-800rpm stirring 3-5min add 0.5-5 parts of chitosans, 30-50 DEG C, 500-800rpm stirs
30-60min is mixed, chitosan solution is obtained, the solid after centrifugation is added in chitosan solution, 30-50 DEG C, 500-800rpm
3-5h, 1000-3000rpm centrifugation 40-80min are stirred, clear liquid is removed after centrifugation, obtained solid will be centrifuged with 300-500 parts
Water is rinsed, and the solid after flushing obtains modified diatomite in 50-80 DEG C of dry 12-24h;The modifying agent is sodium alginate
And/or acetoglyceride;Described modifying agent is preferably sodium alginate and acetoglyceride mass ratio 1:1-3:1 mixture;
S2:The masterbatch that 10-70 parts of PP and S1 steps are obtained is well mixed, and PP fibers are meltblown into using melt-blowing equipment, and
It is wound in PP cottons;
S3:1-5 parts of citric acids, 3-9 parts of tartaric acid are added in 50-100 parts of water, 25-40 DEG C, 500-800rpm stirrings
5-15min, obtains acid etch liquid, and the PP cottons that S2 steps are obtained are immersed in into 20-50min in acid etch liquid, by the PP after dipping
Cotton is rinsed with 300-500 parts of water, in 50-80 DEG C of dry 12-24h, obtains PP cotton products.
It is highly preferred that the temperature of the S1 steps screw extruder is:One area's temperature is 155-165 DEG C, two area's temperature are
175-185 DEG C, three area's temperature be 195-205 DEG C, four area's temperature be 195-205 DEG C, five area's temperature be 190-200 DEG C.
It is highly preferred that the S1 steps master batch is 3mm × 3mm × 3mm particle.
It is highly preferred that the melt-blown temperature of the S2 steps is 230-270 DEG C, hot air temperature is 260-280 DEG C, hot-air
The spacing that pressure is 14-20Pa, spinneret orifice diameter is 0.15-0.25mm, shower nozzle and reception roller is 18-24cm, receives roller
Rotating speed be 500-1000m/min.
Preferably, set at the top of a connecting tube for connecting platform basin, the connecting tube and set in the lower section of the screen pipe
Spacing collar is equipped with, the water inlet pipe is penetrated at the inside of the connecting tube, the tube wall of the connecting tube with unification nut, the company
On the pipe shaft of adapter, it is provided with seal washer, the pipe shaft of the water inlet pipe and is combined with the lower surface of the spacing collar
Stop washer, the stop washer coordinates between the screen pipe and the spacing collar.
Preferably, flanging is set at the bottom position of the end cap, is combined between the flanging and the screen pipe
First seal washer.
Preferably, the outer surface annular of the end cap is provided with anti-slip tank.
Preferably, it is provided with annular at the outer ring position of the upper end cover, bottom end cover, the first dividing plate and second partition
Groove, sets rubber seal in the annular groove, and sealing is formed between the rubber seal and the inwall of the screen pipe.
The beneficial effects of the invention are as follows:The present apparatus can realize fixed installation between platform basin, after installation, pass through mistake
Chimney filter can realize the filtering of water quality, and preferably, the water after filtering is capable of direct drinking, and the structure of the present apparatus is more simple for degree of filtration
Single, cost is more cheap, is adapted to promote the use of.The preparation technology of the PP cottons of Water filtration structure is optimized the present invention,
Modified diatomite is with the addition of in raw material, the PP cottons prepared carry out that PP cotton products are made after acid etch processing, present invention system
Standby PP cotton products have good fracture strength, bacteriostasis property and heavy metal ion adsorbed performance.
Brief description of the drawings
In order to illustrate more clearly about the embodiment of the present invention or technical scheme of the prior art, below will be to embodiment or existing
There is the accompanying drawing used required in technology description to be briefly described, it should be apparent that, drawings in the following description are only this
Some embodiments of invention, for those of ordinary skill in the art, on the premise of not paying creative work, can be with
Other accompanying drawings are obtained according to these accompanying drawings.
Fig. 1 is structural representation of the invention;
Fig. 2 is the cut-away view of screen pipe.
Embodiment
The preferred embodiments of the present invention are described in detail below in conjunction with the accompanying drawings, so that advantages and features of the invention energy
It is easier to be readily appreciated by one skilled in the art, apparent is clearly defined so as to be made to protection scope of the present invention.
PP cotton products ultimate strength is tested:Method of testing is carried out according to FZ/T 60005-91, general using DXLL-20000
Material Testing Machine, style size:205mm × 50mm, draw speed 100mm/min.
PP fibre antibacterial performance tests:The Escherichia coli ATYCC25922 of cryopreservation, golden yellow grape are taken with oese
Coccus ATCC6538 bacterial strains, are transferred in nutrient broth nutrient solution respectively, after 37 DEG C of culture 24h, are with aseptic quality fraction
The 0.9% NaCl aqueous solution is diluted to the initial bacterium solution that cell concentration is the 103CFU/ml orders of magnitude.Experimental group:Take
0.01g, a diameter of 6 μm, length for 35cm PP cotton fibers treat test sample in sterilizing conical flask in, with sterilizing measuring pipette draw
The initial bacterium solutions of 1.0ml, slowly and equably drop on NACF, seal bottleneck.50ml is added without mycoplasma in bottle after 1h
The NaCl aqueous solution that fraction is 0.9% is measured, 2min is acutely shaken, takes appropriate 1ml solution to do total number of bacteria survey with gradient dilution method
It is fixed.The initial bacterium solution groups of one group of 1.0ml for not adding PP cotton fibers are set to test total number of bacteria as a control group.Bacteriostasis rate=(1-
Experimental group total number of bacteria/control group total number of bacteria) × 100%, experimental result is the average value of three experiments.
PP cotton products Cs d2+Adsorption capacity is tested:In 1000ml, 40mg/L Cd2+0.5g PP cottons are added in solion,
15min is impregnated at 20 DEG C, with the concentration C (mg/L) of Cd2+ in solution after the absorption of TAS-990 types atomic absorption spectrometry, meter
Calculate adsorption rate, adsorption rate=(40-C)/40 × 100%.
Each raw material introduction in embodiment:
PP, it is specific that the food-grade PP particles that plasticizing Co., Ltd provides, MI=1200g/10min are extensively contained using Yuyao City.
Diatomite, Lingshou County is good for stone ore powder factory and provided, the mesh of particle diameter 800.
Zinc oxide, Shanghai jump river titanium white heavy chemicals Co., Ltd, the mesh of particle diameter 1250.
Sodium alginate, No. CAS:9005-38-3, Henan Feng Tai chemical products Co., Ltd provides, food-grade.
Glacial acetic acid, No. CAS:64-19-7.
Acetoglyceride, i.e. glyceryl monoacetate, No. CAS:26446-35-5, Hangzhou great Yang Chemical Co., Ltd.s provide,
Food-grade.
Chitosan, No. CAS:9012-76-4, Shandong Hao Yao new materials Co., Ltd provides, food-grade.
Citric acid, No. CAS:77-92-9.
Tartaric acid, No. CAS:526-83-0.
Embodiment 1
Refering to a kind of Water filtration structure shown in Fig. 1 and Fig. 2, including screen pipe 1, the lower end axle center position of the screen pipe 1
The place of putting is provided with water inlet pipe 2, the outer wall position of that one end of the water inlet pipe 2 away from the screen pipe 1 and is provided with external screw thread
201, and by flexible pipe 3 of the external screw thread 201 with the unification connection network of rivers, the flexible pipe 3 has the spiral shell for coordinating external screw thread 201
Line set 301, is internally provided with upper end cover 4 and bottom end cover 5, the bottom of the upper end cover 4 is provided with core in the screen pipe 1
411, PP cottons 6 are combined between the upper end cover 4 and the bottom end cover 5, transition is matched somebody with somebody between the PP cottons 6 and the core 411
Close, be internally provided with granulated carbon 7 in the PP cottons 6, the lower surface of the bottom end cover 5 is evenly equipped with inlet opening 501, the water inlet
Pipe 2 is relative with the inlet opening 501, and the surface annular of the upper end cover 4 is provided with multiple apopores 401, the apopore 401
Positioned at the outside of the PP cottons 6, be provided with the first dividing plate 8 and second partition 9 in the top of the upper end cover 4, described first every
The surface of plate 8 and the second partition 9 is evenly equipped with the first apopore 10, coordinates between first dividing plate 8 and the upper end cover 4
Have medical stone 11, NACF 12 be combined between first dividing plate 8 and the second partition 9, described second every
The top of plate 9 is provided with milipore filter 13, and the top of the screen pipe 1 connects an end cap 14, the end cap 14 and the screen pipe 1
Between be threadedly coupled, be provided with depotition cock 15 at the top of the end cap 14, the depotition cock 15 has water management to use
Valve 16.
The preparation method of the PP cottons (6) comprises the following steps, and described part is parts by weight:
S1:5 parts of PP, 1.2 parts of diatomite, 0.005 part of zinc oxide are poured into screw extruder and extruded, and cut into
3mm × 3mm × 3mm master batch;The temperature of the screw extruder is:One area's temperature is 160 DEG C, two area's temperature are 180 DEG C, three
Area's temperature is 200 DEG C, four area's temperature are 200 DEG C, five area's temperature are 195 DEG C;
S2:The masterbatch that 50 parts of PP and S1 steps are obtained is well mixed, and is meltblown into PP fibers using melt-blowing equipment, and wind
Into PP cottons, PP cotton products are obtained;The average diameter of fiber is 6 μm, average fiber length is 35cm, and PP cottons product thickness is 8mm,
Average pore size is 1.5 μm, surface density is 55g/m2;Melt-blown operating condition be melt-blown temperature be 250 DEG C, hot air temperature be 270
DEG C, heat air pressure be that 18Pa, spinneret orifice diameter are that the spacing of 0.18mm, shower nozzle with receiving roller is 20cm, receives roller
Rotating speed is 800m/min.
Embodiment 2
Refering to a kind of Water filtration structure shown in Fig. 1 and Fig. 2, including screen pipe 1, the lower end axle center position of the screen pipe 1
The place of putting is provided with water inlet pipe 2, the outer wall position of that one end of the water inlet pipe 2 away from the screen pipe 1 and is provided with external screw thread
201, and by flexible pipe 3 of the external screw thread 201 with the unification connection network of rivers, the flexible pipe 3 has the spiral shell for coordinating external screw thread 201
Line set 301, is internally provided with upper end cover 4 and bottom end cover 5, the bottom of the upper end cover 4 is provided with core in the screen pipe 1
411, PP cottons 6 are combined between the upper end cover 4 and the bottom end cover 5, transition is matched somebody with somebody between the PP cottons 6 and the core 411
Close, be internally provided with granulated carbon 7 in the PP cottons 6, the lower surface of the bottom end cover 5 is evenly equipped with inlet opening 501, the water inlet
Pipe 2 is relative with the inlet opening 501, and the surface annular of the upper end cover 4 is provided with multiple apopores 401, the apopore 401
Positioned at the outside of the PP cottons 6, be provided with the first dividing plate 8 and second partition 9 in the top of the upper end cover 4, described first every
The surface of plate 8 and the second partition 9 is evenly equipped with the first apopore 10, coordinates between first dividing plate 8 and the upper end cover 4
Have medical stone 11, NACF 12 be combined between first dividing plate 8 and the second partition 9, described second every
The top of plate 9 is provided with milipore filter 13, and the top of the screen pipe 1 connects an end cap 14, the end cap 14 and the screen pipe 1
Between be threadedly coupled, be provided with depotition cock 15 at the top of the end cap 14, the depotition cock 15 has water management to use
Valve 16.
The preparation method of the PP cottons (6) comprises the following steps, and described part is parts by weight:
S1:5 parts of PP, 1.2 parts of modified diatomite, 0.005 part of zinc oxide are poured into screw extruder and extruded, and cut
It is cut into 3mm × 3mm × 3mm master batch;The temperature of the screw extruder is:One area's temperature is 160 DEG C, two area's temperature are 180
DEG C, three area's temperature be 200 DEG C, four area's temperature be 200 DEG C, five area's temperature be 195 DEG C;
The diatomaceous preparation method of the modification is as follows:10 parts of diatomite are added in 80 parts of water, 25 DEG C, 500rpm
2h is stirred, 0.5 part of modifying agent is added, 50W power, 30kHz frequency ultrasounds 30min, 1000rpm centrifugation 40min remove after centrifugation
Clear liquid, the solid that centrifugation is obtained is rinsed with 300 parts of water, and the solid after flushing obtains modified diatom in 50 DEG C of dry 12h
Soil;The modifying agent is sodium alginate;
S2:The masterbatch that 50 parts of PP and S1 steps are obtained is well mixed, and is meltblown into PP fibers using melt-blowing equipment, and wind
Into PP cottons, PP cotton products are obtained;The average diameter of fiber is 6 μm, average fiber length is 35cm, and PP cottons product thickness is 8mm,
Average pore size is 1.5 μm, surface density is 55g/m2;Melt-blown operating condition be melt-blown temperature be 250 DEG C, hot air temperature be 270
DEG C, heat air pressure be that 18Pa, spinneret orifice diameter are that the spacing of 0.18mm, shower nozzle with receiving roller is 20cm, receives roller
Rotating speed is 800m/min.
Embodiment 3
Refering to a kind of Water filtration structure shown in Fig. 1 and Fig. 2, including screen pipe 1, the lower end axle center position of the screen pipe 1
The place of putting is provided with water inlet pipe 2, the outer wall position of that one end of the water inlet pipe 2 away from the screen pipe 1 and is provided with external screw thread
201, and by flexible pipe 3 of the external screw thread 201 with the unification connection network of rivers, the flexible pipe 3 has the spiral shell for coordinating external screw thread 201
Line set 301, is internally provided with upper end cover 4 and bottom end cover 5, the bottom of the upper end cover 4 is provided with core in the screen pipe 1
411, PP cottons 6 are combined between the upper end cover 4 and the bottom end cover 5, transition is matched somebody with somebody between the PP cottons 6 and the core 411
Close, be internally provided with granulated carbon 7 in the PP cottons 6, the lower surface of the bottom end cover 5 is evenly equipped with inlet opening 501, the water inlet
Pipe 2 is relative with the inlet opening 501, and the surface annular of the upper end cover 4 is provided with multiple apopores 401, the apopore 401
Positioned at the outside of the PP cottons 6, be provided with the first dividing plate 8 and second partition 9 in the top of the upper end cover 4, described first every
The surface of plate 8 and the second partition 9 is evenly equipped with the first apopore 10, coordinates between first dividing plate 8 and the upper end cover 4
Have medical stone 11, NACF 12 be combined between first dividing plate 8 and the second partition 9, described second every
The top of plate 9 is provided with milipore filter 13, and the top of the screen pipe 1 connects an end cap 14, the end cap 14 and the screen pipe 1
Between be threadedly coupled, be provided with depotition cock 15 at the top of the end cap 14, the depotition cock 15 has water management to use
Valve 16.
The preparation method of the PP cottons (6) comprises the following steps, and described part is parts by weight:
S1:5 parts of PP, 1.2 parts of modified diatomite, 0.005 part of zinc oxide are poured into screw extruder and extruded, and cut
It is cut into 3mm × 3mm × 3mm master batch;The temperature of the screw extruder is:One area's temperature is 160 DEG C, two area's temperature are 180
DEG C, three area's temperature be 200 DEG C, four area's temperature be 200 DEG C, five area's temperature be 195 DEG C;
The diatomaceous preparation method of the modification is as follows:10 parts of diatomite are added in 80 parts of water, 25 DEG C, 500rpm
2h is stirred, 0.5 part of modifying agent is added, 50W power, 30kHz frequency ultrasounds 30min, 1000rpm centrifugation 40min remove after centrifugation
Clear liquid, obtains solid, and 2 parts of glacial acetic acid are added in 60 parts of water, 40 DEG C, 500rpm stirring 3min, adds 0.5 part of chitosan,
40 DEG C, 500rpm stirring 30min, obtain chitosan solution, the solid after centrifugation are added in chitosan solution, 40 DEG C,
500rpm stirs 3h, 1000rpm centrifugation 40min, removes clear liquid after centrifugation, the solid that centrifugation is obtained is rinsed with 300 parts of water, rushes
Solid after washing obtains modified diatomite in 50 DEG C of dry 12h;The modifying agent is sodium alginate;
S2:The masterbatch that 50 parts of PP and S1 steps are obtained is well mixed, and is meltblown into PP fibers using melt-blowing equipment, and wind
Into PP cottons, PP cotton products are obtained;The average diameter of fiber is 6 μm, average fiber length is 35cm, and PP cottons product thickness is 8mm,
Average pore size is 1.5 μm, surface density is 55g/m2;Melt-blown operating condition be melt-blown temperature be 250 DEG C, hot air temperature be 270
DEG C, heat air pressure be that 18Pa, spinneret orifice diameter are that the spacing of 0.18mm, shower nozzle with receiving roller is 20cm, receives roller
Rotating speed is 800m/min.
Embodiment 4
It is substantially the same manner as Example 3, differ only in:The consumption of chitosan described in the present embodiment 4 is 1.5 parts.
Embodiment 5
It is substantially the same manner as Example 3, differ only in:The consumption of chitosan described in the present embodiment 5 is 2.5 parts.
Embodiment 6
It is substantially the same manner as Example 3, differ only in:The consumption of chitosan described in the present embodiment 6 is 3.5 parts.
Embodiment 7
Refering to a kind of Water filtration structure shown in Fig. 1 and Fig. 2, including screen pipe 1, the lower end axle center position of the screen pipe 1
The place of putting is provided with water inlet pipe 2, the outer wall position of that one end of the water inlet pipe 2 away from the screen pipe 1 and is provided with external screw thread
201, and by flexible pipe 3 of the external screw thread 201 with the unification connection network of rivers, the flexible pipe 3 has the spiral shell for coordinating external screw thread 201
Line set 301, is internally provided with upper end cover 4 and bottom end cover 5, the bottom of the upper end cover 4 is provided with core in the screen pipe 1
411, PP cottons 6 are combined between the upper end cover 4 and the bottom end cover 5, transition is matched somebody with somebody between the PP cottons 6 and the core 411
Close, be internally provided with granulated carbon 7 in the PP cottons 6, the lower surface of the bottom end cover 5 is evenly equipped with inlet opening 501, the water inlet
Pipe 2 is relative with the inlet opening 501, and the surface annular of the upper end cover 4 is provided with multiple apopores 401, the apopore 401
Positioned at the outside of the PP cottons 6, be provided with the first dividing plate 8 and second partition 9 in the top of the upper end cover 4, described first every
The surface of plate 8 and the second partition 9 is evenly equipped with the first apopore 10, coordinates between first dividing plate 8 and the upper end cover 4
Have medical stone 11, NACF 12 be combined between first dividing plate 8 and the second partition 9, described second every
The top of plate 9 is provided with milipore filter 13, and the top of the screen pipe 1 connects an end cap 14, the end cap 14 and the screen pipe 1
Between be threadedly coupled, be provided with depotition cock 15 at the top of the end cap 14, the depotition cock 15 has water management to use
Valve 16.
The preparation method of the PP cottons (6) comprises the following steps, and described part is parts by weight:
S1:5 parts of PP, 1.2 parts of modified diatomite, 0.005 part of zinc oxide are poured into screw extruder and extruded, and cut
It is cut into 3mm × 3mm × 3mm master batch;The temperature of the screw extruder is:One area's temperature is 160 DEG C, two area's temperature are 180
DEG C, three area's temperature be 200 DEG C, four area's temperature be 200 DEG C, five area's temperature be 195 DEG C;
The diatomaceous preparation method of the modification is as follows:10 parts of diatomite are added in 80 parts of water, 25 DEG C, 500rpm
2h is stirred, 0.5 part of modifying agent is added, 50W power, 30kHz frequency ultrasounds 30min, 1000rpm centrifugation 40min remove after centrifugation
Clear liquid, obtains solid, and 2 parts of glacial acetic acid are added in 60 parts of water, 40 DEG C, 500rpm stirring 3min, adds 2.5 parts of chitosans,
40 DEG C, 500rpm stirring 30min, obtain chitosan solution, the solid after centrifugation are added in chitosan solution, 40 DEG C,
500rpm stirs 3h, 1000rpm centrifugation 40min, removes clear liquid after centrifugation, the solid that centrifugation is obtained is rinsed with 300 parts of water, rushes
Solid after washing obtains modified diatomite in 50 DEG C of dry 12h;The modifying agent is sodium alginate;
S2:The masterbatch that 50 parts of PP and S1 steps are obtained is well mixed, and is meltblown into PP fibers using melt-blowing equipment, and wind
Into PP cottons;The average diameter of fiber is 6 μm, average fiber length is 35cm;Melt-blown operating condition be melt-blown temperature be 250 DEG C,
Hot air temperature is 270 DEG C, heat air pressure is that 18Pa, spinneret orifice diameter are 0.18mm, shower nozzle and receive the spacing of roller and be
20cm, the rotating speed of reception roller are 800m/min;
S3:2 parts of citric acids, 5 parts of tartaric acid are added in 50 parts of water, 30 DEG C, 500rpm stirring 10min obtain harsh
Liquid is lost, the PP cottons that S2 steps are obtained are immersed in 30min in acid etch liquid, the PP cottons after dipping rinsed with 300 parts of water, 50
DEG C 12h is dried, obtain PP cotton products, PP cottons product thickness is 8mm, average pore size is 1.5 μm, surface density is 55g/m2。
Embodiment 8
It is substantially the same manner as Example 7, differ only in:Modifying agent described in the present embodiment 8 is acetoglyceride.
Embodiment 9
It is substantially the same manner as Example 7, differ only in:Modifying agent described in the present embodiment 9 is sodium alginate and vinegar
The mass ratio of the mixture of acid glyceride, sodium alginate and acetoglyceride is 3:2.
Ultimate strength test result:Longitudinal fracture strength 33.3N, Cross breaking strength 11.5N.Cd2+Adsorption capacity is tested
As a result:Cd2+Adsorption rate 97.9%.
Comparative example 1
Refering to a kind of Water filtration structure shown in Fig. 1 and Fig. 2, including screen pipe 1, the lower end axle center position of the screen pipe 1
The place of putting is provided with water inlet pipe 2, the outer wall position of that one end of the water inlet pipe 2 away from the screen pipe 1 and is provided with external screw thread
201, and by flexible pipe 3 of the external screw thread 201 with the unification connection network of rivers, the flexible pipe 3 has the spiral shell for coordinating external screw thread 201
Line set 301, is internally provided with upper end cover 4 and bottom end cover 5, the bottom of the upper end cover 4 is provided with core in the screen pipe 1
411, PP cottons 6 are combined between the upper end cover 4 and the bottom end cover 5, transition is matched somebody with somebody between the PP cottons 6 and the core 411
Close, be internally provided with granulated carbon 7 in the PP cottons 6, the lower surface of the bottom end cover 5 is evenly equipped with inlet opening 501, the water inlet
Pipe 2 is relative with the inlet opening 501, and the surface annular of the upper end cover 4 is provided with multiple apopores 401, the apopore 401
Positioned at the outside of the PP cottons 6, be provided with the first dividing plate 8 and second partition 9 in the top of the upper end cover 4, described first every
The surface of plate 8 and the second partition 9 is evenly equipped with the first apopore 10, coordinates between first dividing plate 8 and the upper end cover 4
Have medical stone 11, NACF 12 be combined between first dividing plate 8 and the second partition 9, described second every
The top of plate 9 is provided with milipore filter 13, and the top of the screen pipe 1 connects an end cap 14, the end cap 14 and the screen pipe 1
Between be threadedly coupled, be provided with depotition cock 15 at the top of the end cap 14, the depotition cock 15 has water management to use
Valve 16.
The preparation method of the PP cottons (6) comprises the following steps, and described part is parts by weight:
S1:5 parts of PP, 1.2 parts of modified diatomite, 0.005 part of zinc oxide are poured into screw extruder and extruded, and cut
It is cut into 3mm × 3mm × 3mm master batch;The temperature of the screw extruder is:One area's temperature is 160 DEG C, two area's temperature are 180
DEG C, three area's temperature be 200 DEG C, four area's temperature be 200 DEG C, five area's temperature be 195 DEG C;
The diatomaceous preparation method of the modification is as follows:2 parts of glacial acetic acid are added in 60 parts of water, 40 DEG C, 500rpm
3min is stirred, 2.5 parts of chitosans are added, 40 DEG C, 500rpm stirring 30min obtain chitosan solution, 10 parts of diatomite added
Into chitosan solution, 40 DEG C, 500rpm stirring 3h, 1000rpm centrifugation 40min remove clear liquid after centrifugation, will centrifuge what is obtained
Solid is rinsed with 300 parts of water, and the solid after flushing obtains modified diatomite in 50 DEG C of dry 12h;The modifying agent is marine alga
Sour sodium;
S2:The masterbatch that 50 parts of PP and S1 steps are obtained is well mixed, and is meltblown into PP fibers using melt-blowing equipment, and wind
Into PP cottons, PP cotton products are obtained;The average diameter of fiber is 6 μm, average fiber length is 35cm, and PP cottons product thickness is 8mm,
Average pore size is 1.5 μm, surface density is 55g/m2;Melt-blown operating condition be melt-blown temperature be 250 DEG C, hot air temperature be 270
DEG C, heat air pressure be that 18Pa, spinneret orifice diameter are that the spacing of 0.18mm, shower nozzle with receiving roller is 20cm, receives roller
Rotating speed is 800m/min.
Embodiment 10
Refering to a kind of Water filtration structure shown in Fig. 1 and Fig. 2, including screen pipe 1, the lower end axle center position of the screen pipe 1
The place of putting is provided with water inlet pipe 2, the outer wall position of that one end of the water inlet pipe 2 away from the screen pipe 1 and is provided with external screw thread
201, and by flexible pipe 3 of the external screw thread 201 with the unification connection network of rivers, the flexible pipe 3 has the spiral shell for coordinating external screw thread 201
Line set 301, is internally provided with upper end cover 4 and bottom end cover 5, the bottom of the upper end cover 4 is provided with core in the screen pipe 1
411, PP cottons 6 are combined between the upper end cover 4 and the bottom end cover 5, transition is matched somebody with somebody between the PP cottons 6 and the core 411
Close, be internally provided with granulated carbon 7 in the PP cottons 6, the lower surface of the bottom end cover 5 is evenly equipped with inlet opening 501, the water inlet
Pipe 2 is relative with the inlet opening 501, and the surface annular of the upper end cover 4 is provided with multiple apopores 401, the apopore 401
Positioned at the outside of the PP cottons 6, be provided with the first dividing plate 8 and second partition 9 in the top of the upper end cover 4, described first every
The surface of plate 8 and the second partition 9 is evenly equipped with the first apopore 10, coordinates between first dividing plate 8 and the upper end cover 4
Have medical stone 11, NACF 12 be combined between first dividing plate 8 and the second partition 9, described second every
The top of plate 9 is provided with milipore filter 13, and the top of the screen pipe 1 connects an end cap 14, the end cap 14 and the screen pipe 1
Between be threadedly coupled, be provided with depotition cock 15 at the top of the end cap 14, the depotition cock 15 has water management to use
Valve 16.The preparation method be the same as Example 9 of the PP cottons (6).
A preferred embodiment in the present invention, a connecting tube for connecting platform basin is set in the lower section of the screen pipe 1
17, the top of the connecting tube 17 is provided with spacing collar 18, and the water inlet pipe 2 penetrates the inside of the connecting tube 17, the company
With unification nut 19 at the tube wall of adapter 17, set on the pipe shaft of the connecting tube 17, at the lower surface of the spacing collar 18
It is equipped with seal washer 20, the pipe shaft of the water inlet pipe 2 and is combined with stop washer 21, the stop washer 21 coordinates in the mistake
Between chimney filter 1 and the spacing collar 18.
Flanging 141 is set at a preferred embodiment in the present invention, the bottom position of the end cap 14, in the flanging
The first seal washer 151 is combined between 141 and the screen pipe 1.
A preferred embodiment in the present invention, the outer surface annular of the end cap 14 is provided with anti-slip tank 161.
A preferred embodiment in the present invention, the upper end cover 4, bottom end cover 5, the first dividing plate 8 and second partition 9 it is outer
Circle is provided with annular groove (not shown) at position, and rubber seal 22, the rubber seal are set in the annular groove
Sealing is formed between 22 and the inwall of the screen pipe 1.
After water enters in screen pipe, PP cottons are entered by the inlet opening at bottom end cover by water inlet tube of intaking for the present apparatus
Inner ring position at, preliminary purification is realized by granulated carbon, granulated carbon has fabulous effect to purification of water quality, and it can not only be removed
Odor smell, improves the degree of purity of water.Also have to such as harmful substance such as chlorine, phenol, arsenic, lead, cyanide, agricultural chemicals of various impurity in water
Very high clearance, the water after then filtering passes through PP cottons, and it is miscellaneous that PP cottons can filter colloid of the diameter more than 5 microns in running water
Matter, micro- mud, iron rust, bacterial virus, organic contamination mineral matter debris, then water quality sequentially pass through activated carbon fiber and ultrafiltration again
Film, be purified, and improves clean-up effect, it can be ensured that water drinks health degree.
The beneficial effects of the invention are as follows:The present apparatus can realize fixed installation between platform basin, after installation, pass through mistake
Chimney filter can realize the filtering of water quality, and preferably, the water after filtering is capable of direct drinking, and the structure of the present apparatus is more simple for degree of filtration
Single, cost is more cheap, is adapted to promote the use of.
Test case 1
The ultimate strength of PP cotton products to preparing is tested.Specific test result is shown in Table 1.Cross breaking strength
Production mainly due to the bonding point produced between fiber;And longitudinal fracture strength will caused by the ultimate strength of many single fibers,
Therefore longitudinal fracture strength is greater than Cross breaking strength.
Table 1:PP cotton product ultimate strength test result tables
Compared with embodiment 1 uses natural diatomaceous earth, embodiment 2-6 improves the fracture of PP cottons using modified diatomite
Strongly.Compared with embodiment 2 and comparative example 1, embodiment 3-6 is modified the disconnected of the obtained PP cottons of diatomite that method is modified using two steps
Split strength further to improve, possible cause is functional group's increase on modified diatomite surface, and pore structure changes, in micropore
The impurity contained is removed, therefore with PP compatibilities more preferably, beneficial to the raising of mechanical property.Inventor has found, with the phase of embodiment 5
Than the PP cottons that 7 pairs of embodiment is prepared have carried out acid etch processing, and the fracture that acid etch processing can strengthen PP cotton products is strong
Power.
Test case 2
The anti-microbial property of PP fibers is tested.Specific test result is shown in Table 2.
Table 2:PP fibre antibacterial the performance test results tables
|
Escherichia coli bacteriostasis rate/% |
Staphylococcus aureus bacteriostasis rate/% |
Embodiment 1 |
80.2 |
78.5 |
Embodiment 2 |
84.3 |
82.8 |
Embodiment 3 |
85.2 |
84.1 |
Embodiment 4 |
88.7 |
86.0 |
Embodiment 5 |
93.8 |
91.2 |
Embodiment 6 |
89.4 |
85.6 |
Comparative example 1 |
84.9 |
83.5 |
Diatomite is used to prepare PP fibers by modified, and the anti-microbial property of PP fibers is improved.Diatomite plays zinc oxide
The effect of carrier, compared with embodiment 2 and comparative example 1, the diatomaceous specific surface area and pore structure that embodiment 3-6 is modified occur
It is larger to change, make the dispersiveness enhancing of zinc oxide over celite, therefore improve the bactericidal effect of PP fibers.By PP fiber systems
Into PP cottons there is preferable antibiotic property.
Test case 3
To the PP cotton products Cs d prepared2+Adsorption capacity is tested.Specific test result is shown in Table 3.
Table 3:Cd2+Adsorption capacity test result table
|
Cd2+Adsorption rate/% |
Embodiment 1 |
85.2 |
Embodiment 2 |
87.4 |
Embodiment 3 |
89.3 |
Embodiment 4 |
91.9 |
Embodiment 5 |
92.5 |
Embodiment 6 |
92.1 |
Embodiment 7 |
95.5 |
Embodiment 8 |
94.7 |
Comparative example 1 |
88.5 |
Compared with Example 1, embodiment 2-6 is using modified diatomite, and PP cottons are to Cd2+Adsorption capacity strengthens.Inventor
Have been surprisingly found that, the Cd of PP cottons can be further improved after carrying out acid etch processing to PP cottons2+Adsorption capacity.
General principle, principal character and the advantages of the present invention of the present invention has been shown and described above.The technology of the industry
Personnel are it should be appreciated that the present invention is not limited to the above embodiments, and the simply explanation described in above-described embodiment and specification is originally
The principle of invention, various changes and modifications of the present invention are possible without departing from the spirit and scope of the present invention, these changes
Change and improvement all fall within the protetion scope of the claimed invention.The claimed scope of the invention by appended claims and its
Equivalent is defined.