CN1070027C - Emulsified oil of phoxim-chlorfluazuron as pesticide - Google Patents
Emulsified oil of phoxim-chlorfluazuron as pesticide Download PDFInfo
- Publication number
- CN1070027C CN1070027C CN98113986A CN98113986A CN1070027C CN 1070027 C CN1070027 C CN 1070027C CN 98113986 A CN98113986 A CN 98113986A CN 98113986 A CN98113986 A CN 98113986A CN 1070027 C CN1070027 C CN 1070027C
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- China
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- phoxim
- present
- hexaflumuron
- bell urea
- pesticide
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Abstract
The present invention relates to an emulsifiable solution pesticide which is compounded from hexaflumuron and phoxim in the weight ratio of 1: (10 to 25), wherein the emulsifiable solution of the present invention comprises 40% to 45% of the hexaflumuron and the phoxim. The present invention has the reasonable mixing of the chemicals, and the cotoxicity coefficient (CTC) value is obviously larger than 100; the present invention has the advantages of low toxicity, broad disinsection spectrum, small use amount, fast knockdown speed of destructive insects, high disinsection activity and high ovicidal activity by contact; the shortage of the hexaflumuron that the action speed is slow is overcome, the phoxim obtains a new use method, and obvious synergistic effect is generated compared with the independent use of both of the chemicals.
Description
What the present invention relates to is agricultural chemical insecticide, particularly by organic phosphor and benzoyl urea agricultural chemicals through the composite preparation that forms.
For agricultural production, agricultural chemicals is indispensable, yet pesticide species is dangerous to people and non-target biology owing to the big residence time length of toxicity, use the back that ecology and environment are had harm, use the biological reasons such as some defective is arranged in resistance and the use that produce of target repeatedly in a large number, constantly needs to update.Insecticide particularly, this problem is particularly serious, will stop using too by force because of toxicity as the insecticide methamidophos of present China consumption maximum.
At the problem that insecticide exists at present, the present invention is intended to be re-dubbed with existing pesticide species the insecticide variety of better insecticidal effect.
Phoxim (Phoxim, also the name Phoxim, phoxim, phoxim)
Having stomach toxicity and action of contace poison, is a kind of low toxicity broad-spectrum organophosphorous pesticide, yet plant does not have systemic action and see that light easily decomposes to it, thereby the longevity of residure is too short.
Fluorine bell urea (Hexaflumuron, code name are XRD-473)
Be a kind of process for preparation of benzoylurea compounds, have very high desinsection and contact ovicidal activity that its effect is to suppress the insect decortication and kill it, can also suppress the insect eating speed simultaneously, its insecticidal spectrum is wide, toxicity is low.But the quick-acting difference is the big shortcoming of one.
The present invention carries out two kinds of dissimilar agricultural chemicals composite and reaches mutually the purpose of covering the shortage, increase effect.Fluorine bell urea is an insect growth regulator, IGR, main effect is to disturb the insect epidermal growth, the mechanism of action that swashs the acetylcholinesterase in the property conduction with the inhibition choline of phoxim is different, meets the principle of complex preparation, and the two is used with certain proportion has obvious synergistic effect.This conclusion is confirmed with following experiment: be the mixture determining lethality of target insect with the phoxim of fluorine bell urea and different proportion with the cotton bollworm, with the LC of Polo calculating
50Calculate CTC (co-toxicity coefficient) value with proportioning, draw table 1, table 2.The CTC value is an antagonism less than 100, and greater than 100 for synergistic effect, about 100 is summation action.Table 1. fluorine bell urea and phoxim are used the toxicity test result with
*
*LC
50Unit is that mg/L table 2. fluorine bell urea and phoxim are used co-toxicity coefficient (CTC) statistical form (LC with
50)
| Insecticide | B value ± Se | LC 50(95% confidence limit) |
| Fluorine bell urea (A) | 1.3426±0.4213 | 19.8022(5.5870-70.1864) |
| Phoxim (B) | 3.0204±0.5006 | 68.5822(41.8869-112.2912) |
| A+B(1∶2.5) | 1.6500±0.2859 | 63.7663(38.3769-105.9529) |
| A+B(1∶5) | 2.9167±0.4771 | 57.7658(35.7710-93.2847) |
| A+B(1∶10) | 0.6760±0.2940 | 5.9371(2.1323-26.3792) |
| A+B(1∶15) | 1.1121±0.2994 | 18.7931(4.4651-79.0983) |
| A+B(1∶20) | 2.0053±0.5899 | 14.7100(5.9661-36.2687) |
| Insecticide | LC 50(mg/L) or proportioning | The toxicity index | Co-toxicity coefficient |
| Fluorine bell urea (A) | 19.8022 | TIa100 | CTC63.1 |
| Phoxim (B) | 68.5822 | TIb28.8737 | |
| A+B | 63.7663 | ATI31.0544 | |
| Proportioning | 0.2857 | TTI49.1945 | |
| 0.7143 | |||
| Fluorine bell urea (A) | 19.8022 | TIa100 | CTC84.2 |
| Phoxim (B) | 68.5822 | TIb28.8737 | |
| A+B | 57.7658 | ATI34.2802 | |
| Proportioning | 0.1667 | TTI40.7304 | |
| 0.8333 | |||
| Fluorine bell urea (A) | 19.8022 | TIa100 | CTC945.5 |
| Phoxim (B) | 68.5822 | TIb28.8737 | |
| A+B | 5.9371 | ATI333.5335 | |
| Proportioning | 0.09 | TTI35.2751 | |
| 0.91 | |||
| Fluorine bell urea (A) | 19.8022 | TIa100 | CTC316.2 |
| Phoxim (B) | 68.5822 | TIb28.8737 | |
| A+B | 18.7931 | ATI105.3697 | |
| Proportioning | 0.0625 | TTI33.3191 | |
| 0.9375 | |||
| Fluorine bell urea (A) | 19.8022 | TIa100 | CTC417.3 |
| Phoxim (B) | 68.5822 | TIb28.8737 | |
| A+B | 14.7100 | ATI134.6173 | |
| Proportioning | 0.0476 | TTI32.2593 | |
| 0.9524 |
Therefore technical scheme of the present invention is: the weight ratio of ammonia fluorine bell urea and phoxim is that 1: 10～25 ratio is mixed with mixture, is good with 1: 19～20.This mixture is added solvent, emulsifier, and auxiliary elements such as spreader-sticker are mixed with the missible oil of fluorine-containing bell urea and phoxim 40～45%.Missible oil is brown or the purple homogeneous liquid, water content≤0.5%, and acidity is (with H
2SO
4Meter)≤0.4%.It is very remarkable to convert water control farmland insect pest effect with this missible oil.
Suffering of the present invention (sulphur phosphorus)-fluorine (bell urea) compound agricultural insecticide, its prescription rationally, the CTC value is significantly greater than 100, its toxicity is low, insecticidal spectrum is wide, consumption is few, to insect knock down speed fast, very high desinsection is arranged and contacts ovicidal activity, remedy the slow deficiency of fluorine bell urea speed of action, make phoxim obtain new life again, than single separately with obvious synergistic effect has been arranged at present.
Example
The preparation of the hot missible oil of 42% fluoro-.
The former medicine 6.2kg of fluorine bell urea, the purity of getting purity 98% is that 85% phoxim 141kg under agitation adds assistant agent 153kg such as solvent, emulsifier in the preparation still, and mixing gets the 297.5kg product after filtering.Wherein contain phoxim 40.65, fluorine-containing bell urea 2.03%, moisture content 0.22%, acidity is (with H
2SO
4Meter) 0.16%, emulsion stability is good.
At new city subarea, Shenyang City rural area 840m
2Prevent and treat the wild cabbage diamond-back moth test of pesticide effectiveness on the soil, use missible oil such as 5% fluorine bell urea, 40% phoxim, 20% Belmark simultaneously and contrast.Its result such as following table:
42% protects rich missible oil control wild cabbage diamond-back moth drug effect table 1 as a result
| Handle | Dose (g.ml/ mu) | Borer population alive before the medicine | The rate that goes down (%) | Output | ||||
| Behind the medicine 1 day | Behind the medicine 3 days | Behind the medicine 7 days | Behind the medicine 10 days | Kg/ mu | Rate of growth (%) | |||
| 42% protects rich missible oil | 50 | 41.3 | 77.0 | 79.9 | 72.6 | 71.4 | 4678.0 | 7.5 |
| 42% protects rich missible oil | 80 | 41.5 | 93.3 | 96.9 | 100 | 93.3 | 5004.7 | 15.0 |
| 42% protects rich missible oil | 110 | 38.5 | 94.8 | 100 | 100 | 92.7 | 5018.0 | 15.3 |
| 5% 5 percent of hexaflumuron emulsifiable concentrate | 50 | 38.0 | 21.1 | 71.1 | 94.7 | 90.0 | 4900.2 | 12.6 |
| 40% phoxim emulsifiable concentrate | 80 | 40.0 | 80.5 | 89.3 | 90.0 | 86.8 | 4904.7 | 12.7 |
| 20% sumicidin missible oil | 40 | 39.3 | 96.2 | 100 | 100 | 97.5 | 4884.7 | 12.3 |
| CK | - | 36.3 | -15.2 | -26.7 | -23.4 | -27.6 | 4351.3 | - |
Investigate Wu Wu village, the sub-township of test site Shenyang City on the 16,18th, 22,25 new city subarea new city in May on date May 15 dispenser date
Claims (2)
1, a kind of cream pesticide, it is characterized by is that a kind of the weight ratio of fluorine bell urea and phoxim is 1: 10～25 by phoxim and hexaflumuron compounded and missible oil that make, fluorine-containing bell urea and phoxim are 40～45% in the missible oil, contain to send out≤0.5%, with H
2SO
4Acidity≤0.4% of meter, missible oil is brown or the purple homogeneous liquid.
2, cream pesticide according to claim 1, the weight ratio that it is characterized by fluorine bell urea and phoxim is 1: 19～20.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN98113986A CN1070027C (en) | 1998-05-12 | 1998-05-12 | Emulsified oil of phoxim-chlorfluazuron as pesticide |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN98113986A CN1070027C (en) | 1998-05-12 | 1998-05-12 | Emulsified oil of phoxim-chlorfluazuron as pesticide |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1238129A CN1238129A (en) | 1999-12-15 |
| CN1070027C true CN1070027C (en) | 2001-08-29 |
Family
ID=5223672
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN98113986A Expired - Fee Related CN1070027C (en) | 1998-05-12 | 1998-05-12 | Emulsified oil of phoxim-chlorfluazuron as pesticide |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN1070027C (en) |
Families Citing this family (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1332607C (en) * | 2002-07-17 | 2007-08-22 | 倪正刚 | Composite insecticide |
| CN100382698C (en) * | 2005-08-12 | 2008-04-23 | 南京第一农药有限公司 | Synergistic compound pesticide contg. flufenoxuron |
| CN101180971B (en) * | 2007-12-19 | 2010-06-09 | 海南利蒙特生物农药有限公司 | Compounded pesticide of quinalphos and hexaflumuron |
| CN108552227A (en) * | 2018-06-02 | 2018-09-21 | 彭春剑 | A kind of agricultural insecticide and preparation method thereof |
-
1998
- 1998-05-12 CN CN98113986A patent/CN1070027C/en not_active Expired - Fee Related
Non-Patent Citations (1)
| Title |
|---|
| 新编农药手册 1989.10.1 农业部农药检定所，农业出版社 * |
Also Published As
| Publication number | Publication date |
|---|---|
| CN1238129A (en) | 1999-12-15 |
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| C14 | Grant of patent or utility model | ||
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