CN106995373A - 以碘化铵为硝基源一锅合成α,β‑不饱和硝基烯烃衍生物的方法 - Google Patents
以碘化铵为硝基源一锅合成α,β‑不饱和硝基烯烃衍生物的方法 Download PDFInfo
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- CN106995373A CN106995373A CN201710345441.9A CN201710345441A CN106995373A CN 106995373 A CN106995373 A CN 106995373A CN 201710345441 A CN201710345441 A CN 201710345441A CN 106995373 A CN106995373 A CN 106995373A
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- Prior art keywords
- unsaturation
- reaction
- ammonium iodide
- nitroolefin
- step synthesis
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- 0 CCCC(CC=**CC(C1CCCCC1)C(C)(C*CCC*)*C)=* Chemical compound CCCC(CC=**CC(C1CCCCC1)C(C)(C*CCC*)*C)=* 0.000 description 3
Classifications
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- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C201/00—Preparation of esters of nitric or nitrous acid or of compounds containing nitro or nitroso groups bound to a carbon skeleton
- C07C201/06—Preparation of nitro compounds
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- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D213/00—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members
- C07D213/02—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members
- C07D213/04—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen or carbon atoms directly attached to the ring nitrogen atom
- C07D213/24—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen or carbon atoms directly attached to the ring nitrogen atom with substituted hydrocarbon radicals attached to ring carbon atoms
- C07D213/26—Radicals substituted by halogen atoms or nitro radicals
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D333/00—Heterocyclic compounds containing five-membered rings having one sulfur atom as the only ring hetero atom
- C07D333/02—Heterocyclic compounds containing five-membered rings having one sulfur atom as the only ring hetero atom not condensed with other rings
- C07D333/04—Heterocyclic compounds containing five-membered rings having one sulfur atom as the only ring hetero atom not condensed with other rings not substituted on the ring sulphur atom
- C07D333/06—Heterocyclic compounds containing five-membered rings having one sulfur atom as the only ring hetero atom not condensed with other rings not substituted on the ring sulphur atom with only hydrogen atoms, hydrocarbon or substituted hydrocarbon radicals, directly attached to the ring carbon atoms
- C07D333/12—Radicals substituted by halogen atoms or nitro or nitroso radicals
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07B—GENERAL METHODS OF ORGANIC CHEMISTRY; APPARATUS THEREFOR
- C07B2200/00—Indexing scheme relating to specific properties of organic compounds
- C07B2200/09—Geometrical isomers
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- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Abstract
Description
Claims (10)
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
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CN201710345441.9A CN106995373B (zh) | 2017-05-17 | 2017-05-17 | 以碘化铵为硝基源一锅合成α,β-不饱和硝基烯烃衍生物的方法 |
Applications Claiming Priority (1)
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CN201710345441.9A CN106995373B (zh) | 2017-05-17 | 2017-05-17 | 以碘化铵为硝基源一锅合成α,β-不饱和硝基烯烃衍生物的方法 |
Publications (2)
Publication Number | Publication Date |
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CN106995373A true CN106995373A (zh) | 2017-08-01 |
CN106995373B CN106995373B (zh) | 2019-01-11 |
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CN201710345441.9A Active CN106995373B (zh) | 2017-05-17 | 2017-05-17 | 以碘化铵为硝基源一锅合成α,β-不饱和硝基烯烃衍生物的方法 |
Country Status (1)
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CN (1) | CN106995373B (zh) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN111217707A (zh) * | 2020-03-17 | 2020-06-02 | 西北师范大学 | 一种β-反式硝基烯烃的制备方法 |
Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN1438977A (zh) * | 2000-06-28 | 2003-08-27 | 萨宝集团公司 | 制备硝基烯烃的方法 |
CN104710315A (zh) * | 2013-12-11 | 2015-06-17 | 中国科学院大连化学物理研究所 | 一种α,β-不饱和硝基烯烃化合物的绿色合成方法 |
-
2017
- 2017-05-17 CN CN201710345441.9A patent/CN106995373B/zh active Active
Patent Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN1438977A (zh) * | 2000-06-28 | 2003-08-27 | 萨宝集团公司 | 制备硝基烯烃的方法 |
CN104710315A (zh) * | 2013-12-11 | 2015-06-17 | 中国科学院大连化学物理研究所 | 一种α,β-不饱和硝基烯烃化合物的绿色合成方法 |
Non-Patent Citations (1)
Title |
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WING-WAH SY,ET AL.: ""NITRATION OF SUBSTITUTED STYRENES WITH MTRYL IODIDE"", 《TETRAHEDRON LETTERS》 * |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN111217707A (zh) * | 2020-03-17 | 2020-06-02 | 西北师范大学 | 一种β-反式硝基烯烃的制备方法 |
CN111217707B (zh) * | 2020-03-17 | 2022-09-16 | 西北师范大学 | 一种β-反式硝基烯烃的制备方法 |
Also Published As
Publication number | Publication date |
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CN106995373B (zh) | 2019-01-11 |
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