CN106989404A - The incinerating method of the organic mixed waste liquor of saliferous - Google Patents

The incinerating method of the organic mixed waste liquor of saliferous Download PDF

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Publication number
CN106989404A
CN106989404A CN201710259182.8A CN201710259182A CN106989404A CN 106989404 A CN106989404 A CN 106989404A CN 201710259182 A CN201710259182 A CN 201710259182A CN 106989404 A CN106989404 A CN 106989404A
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CN
China
Prior art keywords
waste
burning
saliferous
liquor
organic
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201710259182.8A
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Chinese (zh)
Inventor
陈霞
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Nantong Botai Art Graphic Design Co Ltd
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Nantong Botai Art Graphic Design Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
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Publication date
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Priority to CN201710259182.8A priority Critical patent/CN106989404A/en
Publication of CN106989404A publication Critical patent/CN106989404A/en
Pending legal-status Critical Current

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Classifications

    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F23COMBUSTION APPARATUS; COMBUSTION PROCESSES
    • F23GCREMATION FURNACES; CONSUMING WASTE PRODUCTS BY COMBUSTION
    • F23G7/00Incinerators or other apparatus for consuming industrial waste, e.g. chemicals
    • F23G7/04Incinerators or other apparatus for consuming industrial waste, e.g. chemicals of waste liquors, e.g. sulfite liquors
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F23COMBUSTION APPARATUS; COMBUSTION PROCESSES
    • F23JREMOVAL OR TREATMENT OF COMBUSTION PRODUCTS OR COMBUSTION RESIDUES; FLUES 
    • F23J15/00Arrangements of devices for treating smoke or fumes
    • F23J15/02Arrangements of devices for treating smoke or fumes of purifiers, e.g. for removing noxious material
    • F23J15/04Arrangements of devices for treating smoke or fumes of purifiers, e.g. for removing noxious material using washing fluids
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F23COMBUSTION APPARATUS; COMBUSTION PROCESSES
    • F23JREMOVAL OR TREATMENT OF COMBUSTION PRODUCTS OR COMBUSTION RESIDUES; FLUES 
    • F23J15/00Arrangements of devices for treating smoke or fumes
    • F23J15/06Arrangements of devices for treating smoke or fumes of coolers
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F23COMBUSTION APPARATUS; COMBUSTION PROCESSES
    • F23LSUPPLYING AIR OR NON-COMBUSTIBLE LIQUIDS OR GASES TO COMBUSTION APPARATUS IN GENERAL ; VALVES OR DAMPERS SPECIALLY ADAPTED FOR CONTROLLING AIR SUPPLY OR DRAUGHT IN COMBUSTION APPARATUS; INDUCING DRAUGHT IN COMBUSTION APPARATUS; TOPS FOR CHIMNEYS OR VENTILATING SHAFTS; TERMINALS FOR FLUES
    • F23L15/00Heating of air supplied for combustion
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F23COMBUSTION APPARATUS; COMBUSTION PROCESSES
    • F23GCREMATION FURNACES; CONSUMING WASTE PRODUCTS BY COMBUSTION
    • F23G2205/00Waste feed arrangements
    • F23G2205/20Waste feed arrangements using airblast or pneumatic feeding
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F23COMBUSTION APPARATUS; COMBUSTION PROCESSES
    • F23GCREMATION FURNACES; CONSUMING WASTE PRODUCTS BY COMBUSTION
    • F23G2206/00Waste heat recuperation
    • F23G2206/20Waste heat recuperation using the heat in association with another installation
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F23COMBUSTION APPARATUS; COMBUSTION PROCESSES
    • F23GCREMATION FURNACES; CONSUMING WASTE PRODUCTS BY COMBUSTION
    • F23G2207/00Control
    • F23G2207/10Arrangement of sensing devices
    • F23G2207/101Arrangement of sensing devices for temperature
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F23COMBUSTION APPARATUS; COMBUSTION PROCESSES
    • F23GCREMATION FURNACES; CONSUMING WASTE PRODUCTS BY COMBUSTION
    • F23G2209/00Specific waste
    • F23G2209/10Liquid waste
    • F23G2209/101Waste liquor
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F23COMBUSTION APPARATUS; COMBUSTION PROCESSES
    • F23JREMOVAL OR TREATMENT OF COMBUSTION PRODUCTS OR COMBUSTION RESIDUES; FLUES 
    • F23J2215/00Preventing emissions
    • F23J2215/20Sulfur; Compounds thereof
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F23COMBUSTION APPARATUS; COMBUSTION PROCESSES
    • F23JREMOVAL OR TREATMENT OF COMBUSTION PRODUCTS OR COMBUSTION RESIDUES; FLUES 
    • F23J2217/00Intercepting solids
    • F23J2217/50Intercepting solids by cleaning fluids (washers or scrubbers)
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E20/00Combustion technologies with mitigation potential
    • Y02E20/34Indirect CO2mitigation, i.e. by acting on non CO2directly related matters of the process, e.g. pre-heating or heat recovery

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  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • General Engineering & Computer Science (AREA)
  • Environmental & Geological Engineering (AREA)
  • Chemical & Material Sciences (AREA)
  • Combustion & Propulsion (AREA)
  • Heat Treatment Of Water, Waste Water Or Sewage (AREA)

Abstract

The invention discloses the incinerating method of the organic mixed waste liquor of saliferous, including separation, burning, waste heat recovery and tail gas clean-up step, wherein burn down step is unlatching air blower and burner, burning furnace temperature is set to reach 500 1200 DEG C, compressed air is passed through into waste liquid, controls compressed air intake for 0.6~0.7L, waste-liquor burner is put into after Waste liquid atomization, high-temp combustion furnace temperature is 1,150 1900 DEG C, and the burning time is 12 27s.The incinerating method of the organic mixed waste liquor of this saliferous of the present invention, burning time is short, and high combustion efficiency, energy-saving, method can be with continuous and steady operations;High-temperature hot air is guided to burning burner by the present invention, so as to ensure the combustion period of the organic salt bearing liquid wastes of high concentration efficiently, stable;The present invention is with compressed air spray burning high concentration salty organic waste liquid, the organic brine waste of high concentration or waste oil, and treatment effect is excellent.

Description

The incinerating method of the organic mixed waste liquor of saliferous
Technical field
The present invention relates to the incinerating method of a kind of incinerating method of waste liquid, more particularly to the organic mixed waste liquor of saliferous, belong to Field of waste liquid treatment.
Background technology
High concentration salty organic waste liquid is widely present in new varieties agricultural chemicals and pharmaceutical manufacturing device, due to dirty containing part The material of environment is contaminated, it is necessary to discharge and can not be directly discharged again after being handled.
Solve coking, slagging, the corrosion caused during organic waste liquid containing salt burning by the low melting point salt such as alkali metal salt Deng harm.Process and method:Evaporative crystallization --- burning process is applied to the salt bearing liquid wastes rich in low-boiling-point organic compound and handled, energy Desalination and the effect of reduction auxiliary fuel consumption are reached simultaneously.Raffinate backflow is evaporated to continue to evaporate.The phenol of such as sodium chloride-containing Simulated wastewater is produced in evaporation process containing the organic liquid waste steam that organic matter is dense, Na ion concentration is micro.Organic matter Volatility be higher than 99.00%, Na+Clearance reach 99.88%.Organic liquid waste steam is directly entered fluidized bed incinerator and entered Row burning disposal, can reach very high firing efficiency.Firing efficiency is with organic concentration in incineration temperature, air quantity and steam Change and change.Incineration temperature is 850 DEG C, and air quantity is 20m3During/h, 320ml organic liquid wastes produce 200ml through pervaporation and steamed Vapour simultaneously carries out the disposable organic removal rate after burning disposal and can reach 96.03%.
At present, the general burning disposal equipment used is sequentially connected with lower component:Incinerator (successively including horizontal chamber furnace (oven), Vertical heater I and vertical heater II)+fire tube waste heat boiler+air-introduced machine+scrubbing tower+chimney, its handling process is:Along horizontal chamber furnace (oven) axial direction Hydrojet, along the bottom hydrojet of vertical heater I, along the top hydrojet of vertical heater II, fire tube waste heat boiler is walked using flue gas in pipe and water walks pipe Flue gas is introduced scrubbing tower and carries out desulfurization by outer mode, air-introduced machine, is then discharged by chimney.The spy of current this mode Point is to carry out multi-point liquid spraying burning at each position of incinerator, and the treating capacity of each burner is smaller, respectively less than 0.4t/h, total processing Ability is less than 1.2t/h, and whole incinerator is direct current channel so that the high-temperature flue gas residence time is smaller, simultaneously because incinerator is each Spot temperature difference is big, therefore vertical heater I and the usual ignition temperature of vertical heater II are less than 1110 DEG C, and the residence time is short, organic matter Reaction is not thorough.And walked in pipe and by the way of water walked outside pipe, made containing inorganic using flue gas using fire tube waste heat boiler heating surface The flue gas of salt easily blocks pipeline so that the package unit steady and continuous cycle of operation is no more than 7 days;Gas consumption reaches 100m3/ ton waste liquid, the energy recovery amount of waste liquid per ton is more than 1.5 tons.
General, incineration technology of the prior art, the burning time is long, and incinerating method is complicated, and safety coefficient is not high, work It is less efficient, for a series of problem defect in existing method for treating waste liquid, it is badly in need of a kind of improved method to meet now The process requirements of society.
The content of the invention
It is an object of the invention to provide the incinerating method of the organic mixed waste liquor of saliferous, not yet solved with solving above-mentioned prior art Problem certainly.
The technical solution adopted by the present invention is:The incinerating method of the organic mixed waste liquor of saliferous, including separation, burning, waste heat Reclaim and tail gas clean-up step, it is characterised in that:The burn down step reaches burning furnace temperature to open air blower and burner To 500-1200 DEG C, compressed air is passed through into waste liquid, it is throwing after 0.6~0.7L, Waste liquid atomization to control compressed air intake Enter waste-liquor burner, high-temp combustion furnace temperature is 1150-1900 DEG C, and the burning time is 12-27s.
Further, the wind-force size of cooling air system in incinerator is adjusted after the burn down step, control flue gas is remaining The temperature of heat boiler import is 800 DEG C.
Further, the waste heat recovery is to enter the flue gas of high temperature incineration by air preheater in heat recovery boiler Row energy recovery.
Further, the tail gas clean-up step is that the flue gas input alkali lye that temperature is 255 DEG C -260 DEG C is carried out into desulfurization, And after except color odor removal, discharge purifying smoke.
Further, the compression pressure of the compressed air is 0.2-0.8MPa.
Beneficial effect:The incinerating method of the organic mixed waste liquor of this saliferous of the present invention, burning time is short, efficiency of combustion High, energy-saving, method can be with continuous and steady operation;High-temperature hot air is guided to burning burner by the present invention, so as to ensure The combustion period of the organic salt bearing liquid wastes of high concentration efficiently, stable;The present invention has with compressed air spray burning high concentration saliferous The organic brine waste of machine waste liquid, high concentration or waste oil, treatment effect are excellent.
Embodiment
Following implementation row can make those skilled in the art that the present invention is more completely understood, but not therefore by the present invention It is limited among described scope of embodiments.
Embodiment 1
The organic mixed waste liquor of saliferous is carried out after gas solid separation in separation chamber, air blower and the burning of incinerator is opened Device, makes burning furnace temperature reach 992 DEG C, compressed air is passed through into waste liquid, and it is 0.6L to control compressed air intake so that useless Liquid mist, then puts into waste-liquor burner, and high-temp combustion furnace temperature is 1900 DEG C, and the burning time is 13s;Adjust cold in incinerator But the wind-force size of wind system, it is 800 DEG C in the temperature of waste heat boiler import to control flue gas;It is finally 260 DEG C of cigarette by temperature Gas input alkali lye carries out desulfurization, and after except color odor removal, discharges purifying smoke.The wherein compression pressure of compressed air For 0.6MPa.
By the operating method of the present embodiment, the COD contained in waste gas drops to 63mg/L, reaches national row Put standard.
Embodiment 2
The organic mixed waste liquor of saliferous is carried out after gas solid separation in separation chamber, air blower and the burning of incinerator is opened Device, makes burning furnace temperature reach 1110 DEG C, compressed air is passed through into waste liquid, and it is 0.6L to control compressed air intake so that Waste liquid atomization, then puts into waste-liquor burner, and high-temp combustion furnace temperature is 1150 DEG C, and the burning time is 25s;Adjust in incinerator The wind-force size of cooling air system, it is 800 DEG C in the temperature of waste heat boiler import to control flue gas;It it is finally 255 DEG C by temperature Flue gas input alkali lye carries out desulfurization, and after except color odor removal, discharges purifying smoke.The wherein compression pressure of compressed air Power is 0.6MPa.
By the operating method of the present embodiment, the COD contained in waste gas drops to 66mg/L, reaches national row Put standard.

Claims (5)

1. the incinerating method of the organic mixed waste liquor of saliferous, including separation, burning, waste heat recovery and tail gas clean-up step, its feature It is:The burn down step makes burning furnace temperature reach 500-1200 DEG C, is passed through into waste liquid to open air blower and burner Compressed air, controls compressed air intake for 0.6~0.7L, waste-liquor burner, high-temp combustion furnace temperature is put into after Waste liquid atomization Spend for 1150-1900 DEG C, the burning time is 12-27s.
2. the incinerating method of the organic mixed waste liquor of saliferous according to claim 1, it is characterised in that:After the burn down step The wind-force size of cooling air system in incinerator is adjusted, it is 800 DEG C in the temperature of waste heat boiler import to control flue gas.
3. the incinerating method of the organic mixed waste liquor of saliferous according to claim 1, it is characterised in that:The waste heat recovery is The flue gas of high temperature incineration is subjected to energy recovery by air preheater in heat recovery boiler.
4. the incinerating method of the organic mixed waste liquor of saliferous according to claim 1, it is characterised in that:The tail gas clean-up step Rapid is that the flue gas input alkali lye that temperature is 255 DEG C -260 DEG C is carried out into desulfurization, and after except color odor removal, discharge purification Flue gas.
5. the incinerating method of the organic mixed waste liquor of saliferous according to claim 1, it is characterised in that:The compressed air Compression pressure is 0.2-0.8MPa.
CN201710259182.8A 2017-04-20 2017-04-20 The incinerating method of the organic mixed waste liquor of saliferous Pending CN106989404A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201710259182.8A CN106989404A (en) 2017-04-20 2017-04-20 The incinerating method of the organic mixed waste liquor of saliferous

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Application Number Priority Date Filing Date Title
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Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS51130067A (en) * 1975-05-06 1976-11-12 Jgc Corp Method for simultaneously treating organic waster wate and heavy metal -con -taining waster wate
CN103017177A (en) * 2012-12-25 2013-04-03 北京机电院高技术股份有限公司 Incineration disposal method for high-salinity wastewater
CN103822216A (en) * 2014-03-18 2014-05-28 江苏星瑞化工工程科技有限公司 Incineration method for saliferous organic mixed effluent
CN104964289A (en) * 2015-06-05 2015-10-07 朱卫 Incineration method of organic mixed waste liquid containing salt
CN106122981A (en) * 2016-07-15 2016-11-16 南通纺都置业有限公司 The incinerating method of the organic mixed waste liquor of saliferous

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS51130067A (en) * 1975-05-06 1976-11-12 Jgc Corp Method for simultaneously treating organic waster wate and heavy metal -con -taining waster wate
CN103017177A (en) * 2012-12-25 2013-04-03 北京机电院高技术股份有限公司 Incineration disposal method for high-salinity wastewater
CN103822216A (en) * 2014-03-18 2014-05-28 江苏星瑞化工工程科技有限公司 Incineration method for saliferous organic mixed effluent
CN104964289A (en) * 2015-06-05 2015-10-07 朱卫 Incineration method of organic mixed waste liquid containing salt
CN106122981A (en) * 2016-07-15 2016-11-16 南通纺都置业有限公司 The incinerating method of the organic mixed waste liquor of saliferous

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Application publication date: 20170728