CN106978108A - A kind of GRP pipe adhesive - Google Patents

A kind of GRP pipe adhesive Download PDF

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Publication number
CN106978108A
CN106978108A CN201710286436.5A CN201710286436A CN106978108A CN 106978108 A CN106978108 A CN 106978108A CN 201710286436 A CN201710286436 A CN 201710286436A CN 106978108 A CN106978108 A CN 106978108A
Authority
CN
China
Prior art keywords
parts
adhesive
grp pipe
filler
curing agent
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201710286436.5A
Other languages
Chinese (zh)
Inventor
孟飞
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Guangxi Beihai Yueda Frp Product Co Ltd
Original Assignee
Guangxi Beihai Yueda Frp Product Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Guangxi Beihai Yueda Frp Product Co Ltd filed Critical Guangxi Beihai Yueda Frp Product Co Ltd
Priority to CN201710286436.5A priority Critical patent/CN106978108A/en
Publication of CN106978108A publication Critical patent/CN106978108A/en
Pending legal-status Critical Current

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Classifications

    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J127/00Adhesives based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Adhesives based on derivatives of such polymers
    • C09J127/02Adhesives based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Adhesives based on derivatives of such polymers not modified by chemical after-treatment
    • C09J127/04Adhesives based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Adhesives based on derivatives of such polymers not modified by chemical after-treatment containing chlorine atoms
    • C09J127/06Homopolymers or copolymers of vinyl chloride
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G59/00Polycondensates containing more than one epoxy group per molecule; Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups
    • C08G59/18Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing
    • C08G59/40Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing characterised by the curing agents used
    • C08G59/50Amines
    • C08G59/5006Amines aliphatic
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J11/00Features of adhesives not provided for in group C09J9/00, e.g. additives
    • C09J11/02Non-macromolecular additives
    • C09J11/04Non-macromolecular additives inorganic
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J11/00Features of adhesives not provided for in group C09J9/00, e.g. additives
    • C09J11/02Non-macromolecular additives
    • C09J11/06Non-macromolecular additives organic
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J11/00Features of adhesives not provided for in group C09J9/00, e.g. additives
    • C09J11/08Macromolecular additives
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2201/00Properties
    • C08L2201/08Stabilised against heat, light or radiation or oxydation
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2203/00Applications
    • C08L2203/18Applications used for pipes

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Inorganic Chemistry (AREA)
  • Adhesives Or Adhesive Processes (AREA)

Abstract

The present invention provides a kind of GRP pipe adhesive, and the adhesive includes the component of following parts by weight:20 30 parts of Corvic;5 10 parts of curing agent;16 20 parts of adhesive for polyurethane;23 parts of milled glass fiber;0.2 1 parts of coupling agent;13 parts of filler;0.3 2 parts of plasticizer.The adhesive cost of the present invention is low, and reduction is simple to operate using limitation, easy to use;The characteristics of also there is high corrosion-resistant, intensity, steady quality in addition.

Description

A kind of GRP pipe adhesive
Technical field
The invention belongs to GRP pipe technical field, and in particular to a kind of GRP pipe adhesive.
Background technology
GRP pipe occurs that the various cause for quality such as layering, external impacts draw caused by winged insect in process of production The pipeline risen is truncated phenomenon, also occurs in erecting bed because installation is actually needed and GRP pipe is blocked and used. In this case, in order to connect needs, while meeting GRP pipe bears the requirement of external force, it is necessary to bond.
This adhesive will not only have good plybonding effect, while also corrosion-resistant, high intensity, performance are stable.At present GRP pipe adhesive used in the market is largely bis-epoxy component, and quantitative, price is high, is mainly using process In have to timely use, it is easy to produce waste.
The content of the invention
It is an object of the invention to provide a kind of GRP pipe adhesive, cost is low, and reduction is simple to operate using limitation, It is easy to use.
The technical scheme is that:A kind of GRP pipe adhesive, the adhesive includes following parts by weight Component:
20-30 parts of Corvic;
5-10 parts of curing agent;
16-20 parts of adhesive for polyurethane;
2-3 parts of milled glass fiber;
0.2-1 parts of coupling agent;
1-3 parts of filler;
0.3-2 parts of plasticizer.
Preferably, the parts by weight of the adhesive are:
30 parts of Corvic;
6 parts of curing agent;
17 parts of adhesive for polyurethane;
2 parts of milled glass fiber;
0.5 part of coupling agent;
2 parts of filler;
1 part of plasticizer.
Preferably, the curing agent is triethylene tetramine.
Preferably, the filler is cataloid.
Preferably, the coupling agent is silane coupler.
Beneficial effects of the present invention:The adhesive cost of the present invention is low, and reduction is simple to operate using limitation, easy to use; The characteristics of also there is high corrosion-resistant, intensity, steady quality in addition.
Embodiment
Following embodiment facilitates a better understanding of the present invention, but does not limit the present invention.
Embodiment 1
The parts by weight of adhesive of the present invention are:
30 parts of Corvic;
6 parts of curing agent;
17 parts of adhesive for polyurethane;
2 parts of milled glass fiber;
0.5 part of coupling agent;
2 parts of filler;
1 part of plasticizer.
Wherein, curing agent is that active hydrogen activity on triethylene tetramine, triethylene tetramine nitrogen-atoms is larger, can be made in room temperature Cross linking of epoxy resin solidifies.
Filler is cataloid, can accelerate curing rate, improves bond effect, while increasing the sealing of product Property and barrier properties.In addition, as a kind of additive, increasing toughness of material, heat resistance is also greatly improved.
Embodiment 2
The parts by weight of adhesive of the present invention are:
28 parts of Corvic;
6 parts of curing agent;
18 parts of adhesive for polyurethane;
2 parts of milled glass fiber;
0.5 part of coupling agent;
2 parts of filler;
1 part of plasticizer.
Wherein, curing agent is that active hydrogen activity on triethylene tetramine, triethylene tetramine nitrogen-atoms is larger, can be made in room temperature Cross linking of epoxy resin solidifies.
Filler is cataloid, can accelerate curing rate, improves bond effect, while increasing the sealing of product Property and barrier properties.In addition, as a kind of additive, increasing toughness of material, heat resistance is also greatly improved.
Test proves that, adhesive of the invention not only has good gluing and sealing effectiveness, also good power Learn performance.Fully meet the use demand of GRP pipe.
Finally it should be noted that:The preferred embodiments of the present invention are the foregoing is only, are not intended to limit the invention, Although the present invention is described in detail with reference to the foregoing embodiments, for those skilled in the art, it still may be used To be modified to the technical scheme described in foregoing embodiments, or equivalent substitution is carried out to which part technical characteristic. Within the spirit and principles of the invention, any modification, equivalent substitution and improvements made etc., should be included in the present invention's Within protection domain.

Claims (5)

1. a kind of GRP pipe adhesive, it is characterised in that the adhesive includes the component of following parts by weight:
20-30 parts of Corvic;
5-10 parts of curing agent;
16-20 parts of adhesive for polyurethane;
2-3 parts of milled glass fiber;
0.2-1 parts of coupling agent;
1-3 parts of filler;
0.3-2 parts of plasticizer.
2. GRP pipe adhesive according to claim 1, it is characterised in that the parts by weight of the adhesive are:
30 parts of Corvic;
6 parts of curing agent;
17 parts of adhesive for polyurethane;
2 parts of milled glass fiber;
0.5 part of coupling agent;
2 parts of filler;
1 part of plasticizer.
3. GRP pipe adhesive according to claim 1, it is characterised in that the curing agent is triethylene tetramine.
4. GRP pipe adhesive according to claim 1, it is characterised in that the filler is colloidal silica Silicon.
5. GRP pipe adhesive according to claim 1, it is characterised in that the coupling agent is silane coupler.
CN201710286436.5A 2017-04-27 2017-04-27 A kind of GRP pipe adhesive Pending CN106978108A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201710286436.5A CN106978108A (en) 2017-04-27 2017-04-27 A kind of GRP pipe adhesive

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201710286436.5A CN106978108A (en) 2017-04-27 2017-04-27 A kind of GRP pipe adhesive

Publications (1)

Publication Number Publication Date
CN106978108A true CN106978108A (en) 2017-07-25

Family

ID=59341446

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201710286436.5A Pending CN106978108A (en) 2017-04-27 2017-04-27 A kind of GRP pipe adhesive

Country Status (1)

Country Link
CN (1) CN106978108A (en)

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103709984A (en) * 2013-12-31 2014-04-09 中材金晶玻纤有限公司 In-situ thread adhesive for fiber reinforced plastic pipeline
CN104004474A (en) * 2014-05-26 2014-08-27 芜湖市华泰实业有限公司 Filter element adhesive for filter element connection
CN107699162A (en) * 2017-09-08 2018-02-16 张家港爱科思汽车配件有限公司 A kind of weld seam glue

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103709984A (en) * 2013-12-31 2014-04-09 中材金晶玻纤有限公司 In-situ thread adhesive for fiber reinforced plastic pipeline
CN104004474A (en) * 2014-05-26 2014-08-27 芜湖市华泰实业有限公司 Filter element adhesive for filter element connection
CN107699162A (en) * 2017-09-08 2018-02-16 张家港爱科思汽车配件有限公司 A kind of weld seam glue

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PB01 Publication
SE01 Entry into force of request for substantive examination
SE01 Entry into force of request for substantive examination
RJ01 Rejection of invention patent application after publication

Application publication date: 20170725

RJ01 Rejection of invention patent application after publication