CN106978073B - A kind of acrylate modified abietyl alkyd resin anticorrosion paint and preparation method thereof - Google Patents
A kind of acrylate modified abietyl alkyd resin anticorrosion paint and preparation method thereof Download PDFInfo
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- CN106978073B CN106978073B CN201710283995.0A CN201710283995A CN106978073B CN 106978073 B CN106978073 B CN 106978073B CN 201710283995 A CN201710283995 A CN 201710283995A CN 106978073 B CN106978073 B CN 106978073B
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- Prior art keywords
- parts
- alkyd
- acrylate modified
- rosin based
- abietyl
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- 229920000180 alkyd Polymers 0.000 title claims abstract description 131
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 title claims abstract description 72
- 239000003973 paint Substances 0.000 title claims abstract description 48
- 238000002360 preparation method Methods 0.000 title claims abstract description 17
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 claims abstract description 66
- RSWGJHLUYNHPMX-UHFFFAOYSA-N Abietic-Saeure Natural products C12CCC(C(C)C)=CC2=CCC2C1(C)CCCC2(C)C(O)=O RSWGJHLUYNHPMX-UHFFFAOYSA-N 0.000 claims abstract description 62
- KHPCPRHQVVSZAH-HUOMCSJISA-N Rosin Natural products O(C/C=C/c1ccccc1)[C@H]1[C@H](O)[C@@H](O)[C@@H](O)[C@@H](CO)O1 KHPCPRHQVVSZAH-HUOMCSJISA-N 0.000 claims abstract description 62
- KHPCPRHQVVSZAH-UHFFFAOYSA-N trans-cinnamyl beta-D-glucopyranoside Natural products OC1C(O)C(O)C(CO)OC1OCC=CC1=CC=CC=C1 KHPCPRHQVVSZAH-UHFFFAOYSA-N 0.000 claims abstract description 62
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims abstract description 25
- 239000002904 solvent Substances 0.000 claims abstract description 24
- TZCXTZWJZNENPQ-UHFFFAOYSA-L barium sulfate Chemical compound [Ba+2].[O-]S([O-])(=O)=O TZCXTZWJZNENPQ-UHFFFAOYSA-L 0.000 claims abstract description 23
- 239000012752 auxiliary agent Substances 0.000 claims abstract description 14
- FPAFDBFIGPHWGO-UHFFFAOYSA-N dioxosilane;oxomagnesium;hydrate Chemical compound O.[Mg]=O.[Mg]=O.[Mg]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O FPAFDBFIGPHWGO-UHFFFAOYSA-N 0.000 claims abstract description 12
- 239000004408 titanium dioxide Substances 0.000 claims abstract description 12
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims description 22
- 238000000034 method Methods 0.000 claims description 22
- 239000002994 raw material Substances 0.000 claims description 22
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 claims description 21
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 claims description 14
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims description 12
- WPYMKLBDIGXBTP-UHFFFAOYSA-N benzoic acid Chemical compound OC(=O)C1=CC=CC=C1 WPYMKLBDIGXBTP-UHFFFAOYSA-N 0.000 claims description 10
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 claims description 9
- 230000015572 biosynthetic process Effects 0.000 claims description 9
- 239000002270 dispersing agent Substances 0.000 claims description 9
- 238000003786 synthesis reaction Methods 0.000 claims description 9
- DKPFZGUDAPQIHT-UHFFFAOYSA-N Butyl acetate Natural products CCCCOC(C)=O DKPFZGUDAPQIHT-UHFFFAOYSA-N 0.000 claims description 8
- 238000006243 chemical reaction Methods 0.000 claims description 8
- FUZZWVXGSFPDMH-UHFFFAOYSA-N hexanoic acid Chemical compound CCCCCC(O)=O FUZZWVXGSFPDMH-UHFFFAOYSA-N 0.000 claims description 8
- FEPCMSPFPMPWJK-OLPJDRRASA-N maleopimaric acid Chemical compound C([C@]12C=C([C@H](C[C@@H]11)[C@H]3C(OC(=O)[C@@H]23)=O)C(C)C)C[C@@H]2[C@]1(C)CCC[C@@]2(C)C(O)=O FEPCMSPFPMPWJK-OLPJDRRASA-N 0.000 claims description 8
- 239000007788 liquid Substances 0.000 claims description 7
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 claims description 6
- VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical compound COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 claims description 6
- 239000002253 acid Substances 0.000 claims description 6
- 238000010438 heat treatment Methods 0.000 claims description 6
- 239000001257 hydrogen Substances 0.000 claims description 6
- 229910052739 hydrogen Inorganic materials 0.000 claims description 6
- 125000004435 hydrogen atom Chemical class [H]* 0.000 claims description 6
- 229910052757 nitrogen Inorganic materials 0.000 claims description 6
- WXZMFSXDPGVJKK-UHFFFAOYSA-N pentaerythritol Chemical compound OCC(CO)(CO)CO WXZMFSXDPGVJKK-UHFFFAOYSA-N 0.000 claims description 6
- RIZUCYSQUWMQLX-UHFFFAOYSA-N 2,3-dimethylbenzoic acid Chemical compound CC1=CC=CC(C(O)=O)=C1C RIZUCYSQUWMQLX-UHFFFAOYSA-N 0.000 claims description 5
- 239000005711 Benzoic acid Substances 0.000 claims description 5
- 235000010233 benzoic acid Nutrition 0.000 claims description 5
- 239000006185 dispersion Substances 0.000 claims description 5
- 238000001914 filtration Methods 0.000 claims description 5
- 235000015112 vegetable and seed oil Nutrition 0.000 claims description 5
- 239000008158 vegetable oil Substances 0.000 claims description 5
- 150000002148 esters Chemical class 0.000 claims description 4
- 150000001336 alkenes Chemical class 0.000 claims description 3
- 238000001816 cooling Methods 0.000 claims description 3
- 238000007599 discharging Methods 0.000 claims description 3
- 238000002156 mixing Methods 0.000 claims description 3
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 claims description 3
- 238000004321 preservation Methods 0.000 claims description 3
- 238000010792 warming Methods 0.000 claims description 3
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 claims 1
- 239000005864 Sulphur Substances 0.000 claims 1
- 229910052788 barium Inorganic materials 0.000 claims 1
- DSAJWYNOEDNPEQ-UHFFFAOYSA-N barium atom Chemical compound [Ba] DSAJWYNOEDNPEQ-UHFFFAOYSA-N 0.000 claims 1
- 238000000576 coating method Methods 0.000 abstract description 27
- 239000011248 coating agent Substances 0.000 abstract description 26
- 239000000853 adhesive Substances 0.000 abstract description 6
- 230000001070 adhesive effect Effects 0.000 abstract description 6
- 239000003085 diluting agent Substances 0.000 abstract description 6
- 239000000758 substrate Substances 0.000 abstract description 5
- 238000010612 desalination reaction Methods 0.000 abstract description 3
- 238000005553 drilling Methods 0.000 abstract description 3
- 239000003595 mist Substances 0.000 abstract description 2
- 239000003755 preservative agent Substances 0.000 abstract description 2
- 230000002335 preservative effect Effects 0.000 abstract description 2
- 150000003839 salts Chemical class 0.000 abstract description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 12
- 239000000463 material Substances 0.000 description 11
- 235000010215 titanium dioxide Nutrition 0.000 description 8
- 229920005989 resin Polymers 0.000 description 7
- 239000011347 resin Substances 0.000 description 7
- 239000000047 product Substances 0.000 description 6
- 238000001035 drying Methods 0.000 description 5
- 238000005516 engineering process Methods 0.000 description 5
- 239000007921 spray Substances 0.000 description 4
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 3
- 229920003180 amino resin Polymers 0.000 description 3
- 238000010276 construction Methods 0.000 description 3
- 230000007797 corrosion Effects 0.000 description 3
- 238000005260 corrosion Methods 0.000 description 3
- 238000004519 manufacturing process Methods 0.000 description 3
- 239000003921 oil Substances 0.000 description 3
- 235000019198 oils Nutrition 0.000 description 3
- 238000010189 synthetic method Methods 0.000 description 3
- 229910000831 Steel Inorganic materials 0.000 description 2
- 230000007812 deficiency Effects 0.000 description 2
- 238000009826 distribution Methods 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 238000002474 experimental method Methods 0.000 description 2
- 230000014759 maintenance of location Effects 0.000 description 2
- 229920001296 polysiloxane Polymers 0.000 description 2
- 125000002924 primary amino group Chemical group [H]N([H])* 0.000 description 2
- 238000012797 qualification Methods 0.000 description 2
- 239000007787 solid Substances 0.000 description 2
- 239000010959 steel Substances 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- BNCADMBVWNPPIZ-UHFFFAOYSA-N 2-n,2-n,4-n,4-n,6-n,6-n-hexakis(methoxymethyl)-1,3,5-triazine-2,4,6-triamine Chemical compound COCN(COC)C1=NC(N(COC)COC)=NC(N(COC)COC)=N1 BNCADMBVWNPPIZ-UHFFFAOYSA-N 0.000 description 1
- 239000004925 Acrylic resin Substances 0.000 description 1
- 229920000178 Acrylic resin Polymers 0.000 description 1
- DKPMIYXTUUMCLZ-UHFFFAOYSA-N CCCCC1=C(C(=C(C(=C1C)C)CCCC)CCCC)CCCC Chemical compound CCCCC1=C(C(=C(C(=C1C)C)CCCC)CCCC)CCCC DKPMIYXTUUMCLZ-UHFFFAOYSA-N 0.000 description 1
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 1
- 206010013786 Dry skin Diseases 0.000 description 1
- 229920000877 Melamine resin Polymers 0.000 description 1
- 239000004640 Melamine resin Substances 0.000 description 1
- LGRFSURHDFAFJT-UHFFFAOYSA-N Phthalic anhydride Natural products C1=CC=C2C(=O)OC(=O)C2=C1 LGRFSURHDFAFJT-UHFFFAOYSA-N 0.000 description 1
- 235000008331 Pinus X rigitaeda Nutrition 0.000 description 1
- 235000011613 Pinus brutia Nutrition 0.000 description 1
- 241000018646 Pinus brutia Species 0.000 description 1
- 229910002808 Si–O–Si Inorganic materials 0.000 description 1
- 230000001476 alcoholic effect Effects 0.000 description 1
- 125000001931 aliphatic group Chemical group 0.000 description 1
- 239000002518 antifoaming agent Substances 0.000 description 1
- IRERQBUNZFJFGC-UHFFFAOYSA-L azure blue Chemical compound [Na+].[Na+].[Na+].[Na+].[Na+].[Na+].[Na+].[Na+].[Al+3].[Al+3].[Al+3].[Al+3].[Al+3].[Al+3].[S-]S[S-].[O-][Si]([O-])([O-])[O-].[O-][Si]([O-])([O-])[O-].[O-][Si]([O-])([O-])[O-].[O-][Si]([O-])([O-])[O-].[O-][Si]([O-])([O-])[O-].[O-][Si]([O-])([O-])[O-] IRERQBUNZFJFGC-UHFFFAOYSA-L 0.000 description 1
- 230000004888 barrier function Effects 0.000 description 1
- 230000005540 biological transmission Effects 0.000 description 1
- JHIWVOJDXOSYLW-UHFFFAOYSA-N butyl 2,2-difluorocyclopropane-1-carboxylate Chemical compound CCCCOC(=O)C1CC1(F)F JHIWVOJDXOSYLW-UHFFFAOYSA-N 0.000 description 1
- 125000000484 butyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 229910052791 calcium Inorganic materials 0.000 description 1
- 239000011575 calcium Substances 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 239000013065 commercial product Substances 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 238000007334 copolymerization reaction Methods 0.000 description 1
- 125000004122 cyclic group Chemical group 0.000 description 1
- 230000007423 decrease Effects 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 230000002950 deficient Effects 0.000 description 1
- 239000008367 deionised water Substances 0.000 description 1
- 229910021641 deionized water Inorganic materials 0.000 description 1
- 239000000428 dust Substances 0.000 description 1
- 235000013399 edible fruits Nutrition 0.000 description 1
- 239000002320 enamel (paints) Substances 0.000 description 1
- 239000003822 epoxy resin Substances 0.000 description 1
- 230000003628 erosive effect Effects 0.000 description 1
- 230000009975 flexible effect Effects 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 229930195733 hydrocarbon Natural products 0.000 description 1
- 150000002430 hydrocarbons Chemical class 0.000 description 1
- 239000003999 initiator Substances 0.000 description 1
- FPYJFEHAWHCUMM-UHFFFAOYSA-N maleic anhydride Chemical compound O=C1OC(=O)C=C1 FPYJFEHAWHCUMM-UHFFFAOYSA-N 0.000 description 1
- -1 maleopimaric acid Acid anhydride Chemical class 0.000 description 1
- 150000004702 methyl esters Chemical class 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000002715 modification method Methods 0.000 description 1
- 239000000178 monomer Substances 0.000 description 1
- 238000011056 performance test Methods 0.000 description 1
- 239000002304 perfume Substances 0.000 description 1
- 230000035699 permeability Effects 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 238000006068 polycondensation reaction Methods 0.000 description 1
- 229920000647 polyepoxide Polymers 0.000 description 1
- 229920000728 polyester Polymers 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 229920000098 polyolefin Polymers 0.000 description 1
- 229920002635 polyurethane Polymers 0.000 description 1
- 239000004814 polyurethane Substances 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 230000008569 process Effects 0.000 description 1
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 1
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 1
- 230000001681 protective effect Effects 0.000 description 1
- 238000004080 punching Methods 0.000 description 1
- 238000007761 roller coating Methods 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- 150000005846 sugar alcohols Polymers 0.000 description 1
- 229920003002 synthetic resin Polymers 0.000 description 1
- 239000000057 synthetic resin Substances 0.000 description 1
- 239000005028 tinplate Substances 0.000 description 1
- 235000013799 ultramarine blue Nutrition 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
- 238000004260 weight control Methods 0.000 description 1
- 238000004383 yellowing Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D187/00—Coating compositions based on unspecified macromolecular compounds, obtained otherwise than by polymerisation reactions only involving unsaturated carbon-to-carbon bonds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F212/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring
- C08F212/02—Monomers containing only one unsaturated aliphatic radical
- C08F212/04—Monomers containing only one unsaturated aliphatic radical containing one ring
- C08F212/06—Hydrocarbons
- C08F212/08—Styrene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
- C08G63/02—Polyesters derived from hydroxycarboxylic acids or from polycarboxylic acids and polyhydroxy compounds
- C08G63/12—Polyesters derived from hydroxycarboxylic acids or from polycarboxylic acids and polyhydroxy compounds derived from polycarboxylic acids and polyhydroxy compounds
- C08G63/46—Polyesters chemically modified by esterification
- C08G63/48—Polyesters chemically modified by esterification by unsaturated higher fatty oils or their acids; by resin acids
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
- C08G63/02—Polyesters derived from hydroxycarboxylic acids or from polycarboxylic acids and polyhydroxy compounds
- C08G63/12—Polyesters derived from hydroxycarboxylic acids or from polycarboxylic acids and polyhydroxy compounds derived from polycarboxylic acids and polyhydroxy compounds
- C08G63/52—Polycarboxylic acids or polyhydroxy compounds in which at least one of the two components contains aliphatic unsaturation
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G81/00—Macromolecular compounds obtained by interreacting polymers in the absence of monomers, e.g. block polymers
- C08G81/02—Macromolecular compounds obtained by interreacting polymers in the absence of monomers, e.g. block polymers at least one of the polymers being obtained by reactions involving only carbon-to-carbon unsaturated bonds
- C08G81/024—Block or graft polymers containing sequences of polymers of C08C or C08F and of polymers of C08G
- C08G81/027—Block or graft polymers containing sequences of polymers of C08C or C08F and of polymers of C08G containing polyester or polycarbonate sequences
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/08—Anti-corrosive paints
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2237—Oxides; Hydroxides of metals of titanium
- C08K2003/2241—Titanium dioxide
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/30—Sulfur-, selenium- or tellurium-containing compounds
- C08K2003/3045—Sulfates
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/34—Silicon-containing compounds
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- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Polymers & Plastics (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Engineering & Computer Science (AREA)
- Life Sciences & Earth Sciences (AREA)
- Inorganic Chemistry (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- General Chemical & Material Sciences (AREA)
- Paints Or Removers (AREA)
Abstract
The present invention relates to a kind of acrylate modified abietyl alkyd resin anticorrosion paints and preparation method and application.The coating is made of acrylate modified rosin based alkyd, 100# solvent naphthas, dimethylbenzene, barium sulfate, titanium dioxide, talcum powder and auxiliary agent.Preparation method and application the present invention also provides acrylate modified abietyl alkyd resin anticorrosion paint.Diluent is added during use to be uniformly mixed, and is sprayed or is brushed to surface substrate to be coated in 8h, the adhesive force of coating, impact strength are good, and the resistance to mist of weatherability, salt tolerant is good；The anticorrosive paint of the present invention is used for the preservative treatment of the facilities such as petrochemical equipment, offshore drilling platforms, bridge spanning the sea, desalination plant, sea transport, generating equipment.
Description
Technical field
The present invention relates to a kind of acrylate modified abietyl alkyd resin anticorrosion paints and preparation method and application, belong to
In anticorrosive paint technology field.
Background technology
The object being exposed in atmospheric environment can be corroded by various corrosion factors, contact the container of various corrosive mediums
Inner wall, treatment tank, harbour facility etc. often receive various machinery punchings in erosion state, all products and equipment throughout the year
Hit, scratch, the washing away of violent storm, the corrosion of dust storm etc., be required to coating and protected.At present, existing anticorrosive paint master
There are alkyd resin class, epoxy resin, polyurethanes, polyesters, chlorinated polyolefin hydro carbons etc., wherein alkyd resin class coating is
A kind of coating of domestic production amount maximum at present.With cheap, construction is simple, of less demanding to construction environment, film is rich
The advantages that full hard, durability and preferable, decorative and protective all relatively good weatherability.
Alkyd resin is prepared by passing through polycondensation reaction one using polyalcohol, polyacid and aliphatic acid as primary raw material
Since synthetic technology is ripe, raw material is easy to get, resin coating film good combination property, alkyd resin has become in synthetic resin kind polymer
One of kind that dosage is maximum, purposes is most wide.Alkyd resin anticorrosion paint has following characteristic:(1) application is easy, uses no gas
Spraying is brushed, and roller coating can.(2) wettability is good.Surface adhesion force is good, and permeability is strong.(3) weather resistance is good, surface light
Pool and color stability are good.(4) usually easier than two-component paint use, construction period easily repaiies film defect
It mends, good leveling property.But alkyd resin anticorrosion paint water resistance is limited, is generally resistant to common outdoor moisture, but not
It is used in environment that can be under water or especially moist.Alkyd resin coating film thickness is limited, difference of hardness, usually 30-50 microns, special
Different coating is up to 80 microns.This also significantly limits the use limitation of alkyd resin anticorrosion paint.
At present, it has been reported that and makes up the deficiency of alkyd resin anticorrosion paint by being modified to alkyd resin.Such as water
The amino modified alkyd resin of dissolubility is to add in amino resins in water soluble alkyd resin to be modified manufactured modified resin.
Modified amino resins used is mainly hexamethoxymethyl melamine resin.The addition of amino resins 10%-30% it
Between, it is adjusted according to the difference of alkyd resin oil content.With coating made of the resin, hardness of film, gloss and anticorrosion
Property all increases, but paint film embrittlement, and adhesive force, light resistance are all to be improved.
CN 104449287A (CN201410675158.9) disclose alkyd resin coating and its preparation side of a kind of modification
Method, modified alkyd resin coating it be made of the raw material of following weight parts：Long oil alkyd：140~160；200# solvents：
50~60；EFKA-5054：1.5~2.5；BYK-052：0.3~0.7；Calcium iso-octoate -4%：4~6；Organobentonite：2~
3；Ultramarine blue 08：0.2~0.4；Titanium dioxide R-996：140~160；Blanc fixe：80~100.Preparation method includes：It is standby
Material, pretreatment, premixing are sanded.The enamel paint has excellent anticorrosive property, water resistance, weatherability, frost resistance.The patent is not
Foot part is the long oil alkyd used in raw material for market purchasing, and quality stability is difficult to ensure that, cost of material compared with
It is high；Be divided into this method stock, pretreatment, premix, be sanded and etc. technique it is more complicated, low production efficiency. CN105602388A
(CN201610037893.6) alkyd resin modified acroleic acid anticorrosive paint of a kind of nucleocapsid and preparation method thereof is disclosed,
The invention belongs to chemical anticorrosion paint fields.The anticorrosive paint is prepared by following component by weight：Aqueous alcoholic
Acid resin 40~50, reaction monomers 45~63, pigment 15~20, deionized water 64~131, antifoaming agent 1~2, initiator 0.12
~0.38.The barrier propterty of anticorrosive paint prepared by the present invention has adhesive force better than acrylic acid and the anticorrosive paint of alkyd
By force, the features such as mechanical strength is good, corrosion resistant performance is excellent, splendid weatherability.The patent is disadvantageous in that water resistance is poor,
And cost is higher；The more difficult technology requirement for meeting industrial anticorrosive paint of paint film property.
In addition, the modified alkyd resin coating occurred in succession in recent years further includes styrenated alkyd coating, third
Olefin(e) acid modified alkyd resin coating, phenol-modified alkyd resin coating, silicone alkyd coating etc..What these were modified
Phthalic resin coating respectively has feature, also each defective.For example, the hardness of paint film of phenol-modified alkyd resin, water resistance improve,
But solvent resistance and yellowing resistance decline；For another example, silicone alkyd improves weather-proof due to introducing Si-O-Si keys
Property, but the adhesive force of coating declines.Therefore, improving the comprehensive performance of phthalic resin coating becomes a technology difficulty of the industry
Topic.
Invention content
In view of the deficiencies of the prior art, the present invention provide a kind of acrylate modified abietyl alkyd resin anticorrosion paint and
Preparation method.
The present invention also provides a kind of applications of acrylate modified abietyl alkyd resin anticorrosion paint.
Summary of the invention：
The present invention introduces abietyl, and pass through acrylate to rosin using maleopimaric anhydride in alkyd resin synthesis
Based alkyd is modified, and the more traditional alkyd resin of the modified alkyd resin synthesized has shorter surface drying, does solid work.Gained
The anticorrosive paint of acrylate modified rosin based alkyd composition has better impact resistance, adhesive force and resistance to medium etc.
Property.
Detailed description of the invention：
A kind of acrylate modified abietyl alkyd resin anticorrosion paint, is made of the raw material of following parts by weight：
A. 45-75 parts of acrylic acid modified rosin based alkyd,
B.100# solvent naphtha, 3-8 parts,
C. dimethylbenzene, 4-10 parts,
D. barium sulfate, 3-8 parts,
E. titanium dioxide, 5-30 parts,
F. talcum powder, 1-7 parts,
G. auxiliary agent, 0.1-0.2 parts；
Wherein, the acrylic acid modified rosin based alkyd is acrylate and rosin based alkyd by (10-
12)：(88-90 parts) weight ratio mixes, and is synthesized at a temperature of 230~250 DEG C, and it is 40-60s that form tube method, which measures viscosity, with opening
Thin liquid opens dilute to acrylic acid modified rosin based alkyd mass fraction 50~60%；
The auxiliary agent is this 983 dispersant of hamming.Commercial disignation Disponer983.
According to currently preferred, the thin liquid of opening is 200# solvent naphthas, butyl acetate, dimethylbenzene by (6~9):(1~
1.5):The combination of the weight ratio of (1~1.5).
According to a kind of currently preferred, acrylate modified abietyl alkyd resin anticorrosion paint, by following weight
The raw material of part is made：
A. 50-70 parts of acrylic acid modified rosin based alkyd,
B.100# solvent naphtha, 4-8 parts,
C. dimethylbenzene, 5-10 parts
D. barium sulfate, 4-8 parts,
E. titanium dioxide, 10-20 parts,
F. talcum powder, 2-6 parts,
G. auxiliary agent, 0.1-0.2 parts.
According to a kind of currently preferred, acrylate modified abietyl alkyd resin anticorrosion paint, by following weight
The raw material of part is made：
60 parts of acrylate modified rosin based alkyd, 6 parts of 100# solvents, 8.8 parts of dimethylbenzene, 16 parts of titanium dioxide,
6 parts of barium sulfate, 3 parts of talcum powder, auxiliary agent are 0.2 part of hamming this -983 dispersant.
According to currently preferred, the acrylic acid modified rosin based alkyd number-average molecular weight 1500~
3000, the further preferred acrylic acid modified rosin based alkyd number-average molecular weight 1500~2000,2000~2500
Or 2500~3000.
According to the present invention, commercial products may be used in the acrylate raw material.The acrylic acid of stable quality in order to obtain
Ester raw material, present invention preferably employs following methods to be synthesized：
A kind of synthetic method of acrylate, including：Under nitrogen protection, dimethylbenzene, methyl-prop are added in into reactor
E pioic acid methyl ester, is heated to 70~80 DEG C, and tetrabutyl xylic acid hydrogen ammonium, this exothermic heat of reaction is then slowly added dropwise, and control temperature exists
140 DEG C or so, after reacting a period of time, after temperature falls back to 90 DEG C, acrylic acid and styrene are added in, is warming up to 110~125
DEG C heat preservation is to 300~360s of viscosity, discharging；The parts by weight of raw materials proportioning is as follows：
8~10 parts of acrylic acid, 20~30 parts of styrene, 40~50 parts of dimethylbenzene, 10~20 parts of methyl methacrylate, four
0.8~2 part of butyl xylic acid hydrogen ammonium.
In the present invention, the rosin based alkyd raw material may be used commercial products or be synthesized by the prior art.For
Obtain the rosin based alkyd raw material of stable quality, present invention preferably employs following methods to be synthesized：
A kind of synthetic method of rosin based alkyd, including：By vegetable oil, pentaerythrite, dimethylbenzene, maleopimaric acid
Acid anhydride, benzoic acid are added in reaction kettle, and nitrogen protection 10-20min is rapidly heated to 160~170 DEG C, is then to slowly warm up to again
It 220~240 DEG C, keeps the temperature to viscosity and reaches 20-30s, form tube method is measured to get rosin based alkyd；The raw material weight
Part proportioning is as follows：
45-52 parts of vegetable oil, 15-20 parts of pentaerythrite, 4-10 parts of dimethylbenzene, 20-25 parts of maleopimaric anhydride, benzoic acid
2-4 parts.
In more than rosin based alkyd synthetic method, the heating rate being rapidly heated is 40~50 DEG C/h；It is described
The heating rate slowly to heat up is 8~10 DEG C/h.Slow heating is intended to enough time and brings out the moisture in reaction system.
According to the present invention, a kind of preparation method of acrylate modified abietyl alkyd resin anticorrosion paint, including step
It is as follows：
(1) synthesis of acrylate modified rosin based alkyd
At a temperature of 140~150 DEG C, acrylate is added in rosin based alkyd by proportioning, is to slowly warm up to 230
It~250 DEG C, keeps the temperature to viscosity 40-60s, form tube method measures, and obtains acrylate modified rosin based alkyd；
The acrylate modified rosin based alkyd of gained, is first cooled to 160~180 DEG C, with 200# solvent naphthas, acetic acid fourth
Ester, dimethylbenzene press (6~9):(1~1.5):The thin liquid of opening of (1~1.5) weight ratio opens dilute to mass fraction 50~60%, cooling
It is spare afterwards；
(2) by proportioning, dilute rear spare acrylic acid modified rosin based alkyd, 100# solvents, dimethylbenzene, titanium white will be opened
Powder, barium sulfate, talcum powder and auxiliary agent mixing, ground, high speed dispersion, filtering to get.
The method according to the invention by the viscosity for controlling acrylate modified rosin based alkyd different, obtains respectively
To different molecular weight ranges product, it is preferred that the acrylate modified rosin based alkyd number-average molecular weight of gained for 1500~
2000th, 2000~2500,2500~3000.
According to currently preferred, acrylate modified rosin based alkyd, is first cooled to obtained by above step (1)
180 DEG C, then 8 are pressed with 200# solvent naphthas, butyl acetate, dimethylbenzene:1:1 weight ratio is opened dilute to 50~60% mass point
Number, it is spare after cooling, in case making finished product paint below, post-coatings production efficiency can be improved.Acrylate obtained by step (1) changes
Property rosin based alkyd can not also open it is dilute, because the resin viscosity is big, when paint need to add out again dilute dose carry out out it is dilute.
The application of the acrylate modified abietyl alkyd resin anticorrosion paint of the present invention, wherein, when in use, it need to add dilute
It releases agent to be uniformly mixed, be sprayed in 8h or brushes to surface substrate to be coated.The preferred dimethylbenzene of the diluent or 100# solvent naphthas.
The diluent dosage is generally 10-25wt%, in terms of the weight of acrylate modified abietyl alkyd resin anticorrosion paint.It presses
This field routine techniques.
The application of the acrylate modified abietyl alkyd resin anticorrosion paint of the present invention, for petrochemical equipment, city
Infrastructure, offshore drilling platforms, bridge spanning the sea, water desalination apparatus, sea transport, generating equipment and power transmission and distribution steel tower,
The preservative treatment of the facilities such as port and pier machinery and equipment.
The technical characterstic and advantageous effect of the present invention：
1st, the present invention is using acrylic acid, methyl methacrylate (MMA) and styrene as the third of material copolymerization synthesis modification
Olefin(e) acid ester, using maleopimaric anhydride, pentaerythrite as main Material synthesis rosin based alkyd, then with acrylate to pine
Perfume base alkyd resin is modified, and obtains that viscosity is controllable, modified rosin based alkyd of adjustable molecular weight control, can be replaced traditional
Modified alkyd resin is widely used.
2nd, acrylic resin has excellent guarantor's color gloss retention and durability but richness is poor, application property is poor；Alkyd tree
Fat is with application property is good, film richness is high, flexibility is good, but drying time is long, hardness is low, poor water resistance, protects light colour retention
Difference.Maleopimaric anhydride (MPA) of the invention synthesizes rosin based alkyd, not only changes the single characteristic of phthalic anhydride, also draws
The excellent performance of rosin and maleic anhydride is entered, the rosin based alkyd of synthesis easily forms reticular structure and hands over
Connection is conducive to improve the rate of drying of film, while the cyclic structure in molecule can improve the hardness of film, water resistance etc..
The more traditional modified alkyd resin of acrylate modified rosin based alkyd has shorter surface drying, does solid work, better impact resistance
Property.
3rd, the impact strength of the acrylate modified abietyl alkyd resin anticorrosion paint coating of present invention gained is good, flexible
Property is good, and the resistance to mist of weatherability, salt tolerant is good, the excellent combination properties such as adhesive force and resistance to medium, can be widely applied to petrochemical industry
Equipment, urban infrastructure, offshore drilling platforms, bridge spanning the sea, water desalination apparatus, sea transport, generating equipment with it is defeated
The fields such as distribution steel tower, port and pier machinery and equipment.
Specific embodiment
With reference to embodiment, the present invention will be further described, but not limited to this.
In addition to special instruction, raw materials used in embodiment is commercial product, the raw material dosage be parts by weight or
Weight ratio.This -983 dispersant (the modest dispersant 983, Disponer983 of this moral of hamming) Shanghai butterfly woods chemical industry of hamming used is limited
Company is on sale.
First, acrylate used is prepared as follows in embodiment：
Under nitrogen protection, dimethylbenzene, methyl methacrylate are added in into reaction kettle, is heated to 75 DEG C, then slowly
Tetrabutyl xylic acid hydrogen ammonium is added dropwise, this exothermic heat of reaction, control temperature is at 140 DEG C or so, after reacting a period of time, treats that temperature is returned
After falling on 90 DEG C, acrylic acid and styrene are added in, is warming up to 120 DEG C of heat preservations to 320~340s of viscosity, discharging；The raw material weight
It is as follows to measure part proportioning：10 parts of acrylic acid, 29 parts of styrene, 45 parts of dimethylbenzene, 15 parts of methyl methacrylate, tetrabutyl dimethylbenzene
Sour 1 part of hydrogen ammonium.
The present inventor has found that commercial acrylate quality is susceptible to fluctuation during the experiment, influences modified effect below
Fruit, the acrylate quality more easy to control prepared by the above process.
2nd, rosin based alkyd used is prepared as follows in embodiment：
49 parts of vegetable oil, 18 parts of pentaerythrite, 7 parts of dimethylbenzene, 23 parts of maleopimaric anhydride, 3 parts of benzoic acid are added in anti-
It answers in kettle, heats up after nitrogen protection 15min, be rapidly heated to 165 DEG C, then be to slowly warm up to 230 ± 5 DEG C, keep the temperature to viscosity and reach
To 20~30s (form tube method measure) to get rosin based alkyd；Raw material as embodiment 1-3.
Embodiment 1：The preparation of the acrylate modified rosin based alkyd of 1500~2000 molecular weight
The rosin based alkyd of synthesis is cooled to 150 DEG C, adds in acrylate, acrylate and abietyl alkyd tree
The weight ratio of fat is 12:88,240 ± 5 DEG C are to slowly warm up to, is kept the temperature to 40~50s of viscosity qualification (form tube method measure), gained
Acrylate modified rosin based alkyd molecular weight ranges are about 1500~2000.
8 are pressed with 200# solvent naphthas, butyl acetate, dimethylbenzene:1:1 ratio is opened dilute to acrylate modified abietyl alkyd
Resin quality score 60% is spare.
Embodiment 2：The preparation of the acrylate modified rosin based alkyd of 2000~2500 molecular weight
The rosin based alkyd of synthesis is cooled to 150 DEG C, adds in acrylate, acrylate and abietyl alkyd tree
The weight ratio of fat is 11:89,240 ± 5 DEG C are to slowly warm up to, is kept the temperature to viscosity in 50~55s (form tube method measure), gained
Acrylate modified rosin based alkyd molecular weight ranges are about 2000~2500, with 200# solvent naphthas, butyl acetate, two
Toluene presses 8:1:1 ratio is opened dilute spare to acrylate modified rosin based alkyd mass fraction 60%.
Embodiment 3：The preparation of the acrylate modified rosin based alkyd of 2500~3000 molecular weight
The rosin based alkyd of synthesis is cooled to 150 DEG C, adds in acrylate, acrylate and abietyl alkyd tree
The weight ratio of fat is 10:90,240 ± 5 DEG C are to slowly warm up to, is kept the temperature to 55~60s of viscosity qualification (form tube method measure), institute
It is about 2500~3000 to obtain acrylate modified rosin based alkyd molecular weight ranges, with 200# solvent naphthas, butyl acetate, two
Toluene presses 8:1:1 ratio is opened dilute spare to acrylate modified rosin based alkyd mass fraction 60%.
The preparation of embodiment 4, acrylate modified abietyl alkyd resin anticorrosion paint
Dilute rear acrylate modified rosin based alkyd (molecular weight 1500~2000) 65 is opened by prepared by embodiment 1
Part, 4 parts of 100# solvents, 8 parts of dimethylbenzene, 14.9 parts of titanium dioxide, 4 parts of barium sulfate, 2 parts of talcum powder, auxiliary agent for hamming this -983
Modified alkyd resin anticorrosion coating material is obtained by filtration in 0.1 part of dispersant, ground, high speed dispersion；
It is mixed in application, obtained modified alkyd resin anticorrosion coating material is added in 15wt% diluents dimethylbenzene
It is even, it sprays or is brushed to surface substrate to be coated in 8h.By this field routine techniques.
Embodiment 5,
Dilute rear acrylate modified rosin based alkyd (molecular weight 2000~2500) 60 is opened by prepared by embodiment 2
Part, 6 parts of 100# solvents, 7 parts of dimethylbenzene, 15.8 parts of titanium dioxide, 6 parts of barium sulfate, 5 parts of talcum powder, auxiliary agent be hamming this -983
Modified alkyd resin anticorrosion coating material is obtained by filtration in 0.2 part of dispersant, ground, high speed dispersion；
It is mixed in application, obtained modified alkyd resin anticorrosion coating material is added in 15wt% diluents dimethylbenzene
It is even, it sprays or is brushed to surface substrate to be coated in 8h.By this field routine techniques.
Embodiment 6,
Dilute rear acrylate modified rosin based alkyd (molecular weight 2500~3000) 58 is opened by prepared by embodiment 3
Part, 5 parts of 100# solvents, 10 parts of dimethylbenzene, 16 parts of titanium dioxide, 6 parts of barium sulfate, 4.8 parts of talcum powder, auxiliary agent be hamming this -983
Modified alkyd resin anticorrosion coating material is obtained by filtration in 0.2 part of dispersant, ground, high speed dispersion；
It is mixed in application, obtained modified alkyd resin anticorrosion coating material is added in 15wt% diluents dimethylbenzene
It is even, it sprays or is brushed to surface substrate to be coated in 8h.By this field routine techniques.
The properties of product experiment of above-described embodiment 1-3, is listed in the table below in 1.Comparative example is the shore board propylene of conventional commercial
Sour modified alkyd resin anticorrosive paint.The base material of this performance test is (50mm × 120mm for the size as defined in GB/T 9271
× 0.2~0.30mm) tinplate, it is (30 ± 5) μm that paint film preparation method sprays twice thickness of dry film by GB/T 1727, is painted
Film is tested in 9278 times dryings of rated condition GB/T after 72 hours.
Table 1,
Claims (10)
1. a kind of acrylate modified abietyl alkyd resin anticorrosion paint, it is characterised in that by the raw material system of following parts by weight
Into：
A. 45-75 parts of acrylic acid modified rosin based alkyd,
B. 100# solvent naphthas, 3-8 parts,
C. dimethylbenzene, 4-10 parts,
D. barium sulfate, 3-8 parts,
E. titanium dioxide, 5-30 parts,
F. talcum powder, 1-7 parts,
G. auxiliary agent, 0.1-0.2 parts；
Wherein, the acrylic acid modified rosin based alkyd be acrylate with rosin based alkyd by（10-12）：
（88-90）Part weight ratio mixing, synthesizes, it is 40-60s that form tube method, which measures viscosity, is opened with thin liquid is opened at a temperature of 230 ~ 250 DEG C
Dilute to acrylic acid modified rosin based alkyd mass fraction 50~60%；
The auxiliary agent is this 983 dispersant of hamming.
2. acrylate modified abietyl alkyd resin anticorrosion paint as described in claim 1, it is characterised in that described to open
Thin liquid be 200# solvent naphthas, butyl acetate, dimethylbenzene by（6~9）:（1~1.5）:（1~1.5）Weight ratio combination.
3. acrylate modified abietyl alkyd resin anticorrosion paint as described in claim 1, which is characterized in that by following
The raw material of parts by weight is made：
A. 50-70 parts of acrylic acid modified rosin based alkyd,
B. 100# solvent naphthas, 4-8 parts,
C. dimethylbenzene, 5-10 parts
D. barium sulfate, 4-8 parts,
E. titanium dioxide, 10-20 parts,
F. talcum powder, 2-6 parts,
G. auxiliary agent, 0.1-0.2 parts.
4. acrylate modified abietyl alkyd resin anticorrosion paint as described in claim 1, which is characterized in that by following
The raw material of parts by weight is made：
60 parts of acrylate modified rosin based alkyd, 6 parts of 100# solvent naphthas, 8.8 parts of dimethylbenzene, 16 parts of titanium dioxide, sulphur
Sour 6 parts of barium, 3 parts of talcum powder, auxiliary agent are 0.2 part of hamming this 983 dispersant.
5. such as the acrylate modified abietyl alkyd resin anticorrosion paint of Claims 1 to 4 any one of them, feature exists
In, the acrylate modified rosin based alkyd number-average molecular weight for 1500~2000,2000~2500 or 2500~
3000。
6. acrylate modified abietyl alkyd resin anticorrosion paint as described in claim 1, which is characterized in that described third
Olefin(e) acid ester synthesizes by the following method：
Under nitrogen protection, dimethylbenzene, methyl methacrylate are added in into reactor, is heated to 70 ~ 80 DEG C, is then slowly dripped
Add tetrabutyl xylic acid hydrogen ammonium, this exothermic heat of reaction, control temperature is at 140 DEG C or so, after reacting a period of time, treats that temperature is fallen after rise
To after 90 DEG C, acrylic acid and styrene are added in, is warming up to 110 ~ 125 DEG C of heat preservations to 300~360s of viscosity, discharging；The raw material
Weight is as follows：
8~10 parts of acrylic acid, 20~30 parts of styrene, 40~50 parts of dimethylbenzene, 10~20 parts of methyl methacrylate, the tetrabutyl
0.8~2 part of xylic acid hydrogen ammonium.
7. acrylate modified abietyl alkyd resin anticorrosion paint as described in claim 1, which is characterized in that the institute
Rosin based alkyd is stated to synthesize by the following method：
Vegetable oil, pentaerythrite, dimethylbenzene, maleopimaric anhydride, benzoic acid are added in reaction kettle, nitrogen protection 10-
20min is rapidly heated to 160 ~ 170 DEG C, is then to slowly warm up to 220 ~ 240 DEG C again, keeps the temperature to viscosity and reach 20-30s, form
Tube method is measured to get rosin based alkyd；The parts by weight of raw materials proportioning is as follows：
45-52 parts of vegetable oil, 15-20 parts of pentaerythrite, 4-10 parts of dimethylbenzene, 20-25 parts of maleopimaric anhydride, benzoic acid 2-4
Part.
8. acrylate modified abietyl alkyd resin anticorrosion paint as claimed in claim 7, which is characterized in that described fast
The heating rate of speed heating is 40~50 DEG C/h；The heating rate slowly to heat up is 8~10 DEG C/h.
9. a kind of preparation method of acrylate modified abietyl alkyd resin anticorrosion paint, as follows including step：
（1）The synthesis of acrylate modified rosin based alkyd
At a temperature of 140 ~ 150 DEG C, acrylate is added in rosin based alkyd by proportioning, is to slowly warm up to 230 ~ 250
DEG C, it keeps the temperature to viscosity 40-60s, form tube method measures, and obtains acrylate modified rosin based alkyd；
The acrylate modified rosin based alkyd of gained, is first cooled to 160 ~ 180 DEG C, with 200# solvent naphthas, butyl acetate, two
Toluene is pressed（6~9）:（1~1.5）:（1~1.5）The thin liquid of opening of weight ratio opens dilute to acrylate modified rosin based alkyd quality
Score 50~60%, it is spare after cooling；
（2）By proportioning, will open it is dilute after spare acrylic acid modified rosin based alkyd, 100# solvents, dimethylbenzene, titanium dioxide,
Barium sulfate, talcum powder and auxiliary agent mixing, ground, high speed dispersion, filtering to get.
10. the preparation method of acrylate modified abietyl alkyd resin anticorrosion paint as claimed in claim 9, feature exist
In step（1）Described in open thin liquid proportioning be 200# solvent naphthas：Butyl acetate：Dimethylbenzene=8:1:1 weight ratio.
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Effective date of registration: 20180329 Address after: No. 4, No. 4, No. 858, the Yellow River five road, the Yellow River, Shandong Province, 101 Applicant after: Shandong Binzhou Jiayuan Environmental Protection Co.,Ltd. Applicant after: BEFAR GROUP Co.,Ltd. Address before: No. 4, No. 4, No. 858, the Yellow River five road, the Yellow River, Shandong Province, 101 Applicant before: Shandong Binzhou Jiayuan Environmental Protection Co.,Ltd. |
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Denomination of invention: Acrylate modified rosin based alkyd resin anticorrosive coating and its preparation method Effective date of registration: 20220613 Granted publication date: 20180629 Pledgee: Binzhou Bincheng Branch of China Construction Bank Co.,Ltd. Pledgor: BEFAR GROUP Co.,Ltd. Registration number: Y2022980007697 |
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Denomination of invention: A kind of acrylate-modified rosin-based alkyd resin anti-corrosion coating and preparation method thereof Effective date of registration: 20220914 Granted publication date: 20180629 Pledgee: Binzhou Bincheng Branch of China Construction Bank Co.,Ltd. Pledgor: BEFAR GROUP Co.,Ltd. Registration number: Y2022980015166 |
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